#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:08:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180413 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/82/7208217.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208217
loop_
_publ_author_name
'Yan, Xuhuan'
'Yan, Zhenzhong'
'Zhang, Ye'
'Liu, Weisheng'
'Tang, Yu'
'Tan, Minyu'
_publ_section_title
;
 Anions make the difference: conversion from zero- to one-dimensional
 structures and luminescent properties of lanthanide-based complexes
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              4989
_journal_paper_doi               10.1039/c2ce25210d
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C84 H92 Eu2 N14 O28'
_chemical_formula_weight         2049.64
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.0960(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.6144(3)
_cell_length_b                   14.0677(2)
_cell_length_c                   19.7534(3)
_cell_measurement_reflns_used    5350
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      22.19
_cell_measurement_theta_min      2.22
_cell_volume                     4514.39(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0483
_diffrn_reflns_av_sigmaI/netI    0.0625
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            27499
_diffrn_reflns_theta_full        27.56
_diffrn_reflns_theta_max         27.56
_diffrn_reflns_theta_min         1.79
_exptl_absorpt_coefficient_mu    1.462
_exptl_absorpt_correction_T_max  0.9046
_exptl_absorpt_correction_T_min  0.6935
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2088
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.652
_refine_diff_density_min         -0.481
_refine_diff_density_rms         0.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         10188
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0798
_refine_ls_R_factor_gt           0.0417
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0339P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0759
_refine_ls_wR_factor_ref         0.0881
_reflns_number_gt                6675
_reflns_number_total             10188
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25210d.txt
_cod_data_source_block           666993
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        4514.39(12)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7208217
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.3872(2) 1.0324(3) 0.40527(18) 0.0390(9) Uani 1 1 d .
C2 C 0.4500(2) 1.0651(3) 0.3745(2) 0.0464(10) Uani 1 1 d .
C3 C 0.5221(3) 1.0146(3) 0.3795(2) 0.0540(11) Uani 1 1 d .
C4 C 0.5322(3) 0.9289(3) 0.4143(2) 0.0527(11) Uani 1 1 d .
C5 C 0.4709(2) 0.8942(3) 0.4446(2) 0.0470(10) Uani 1 1 d .
H5 H 0.4782 0.8366 0.4681 0.056 Uiso 1 1 calc R
C6 C 0.3982(2) 0.9446(3) 0.4402(2) 0.0431(9) Uani 1 1 d .
C7 C 0.3116(2) 1.0910(3) 0.39608(19) 0.0415(9) Uani 1 1 d .
C8 C 0.3420(3) 0.8199(3) 0.4996(2) 0.0580(12) Uani 1 1 d .
H8A H 0.3826 0.8203 0.5427 0.070 Uiso 1 1 calc R
H8B H 0.3587 0.7738 0.4687 0.070 Uiso 1 1 calc R
C9 C 0.2579(3) 0.7945(3) 0.5128(2) 0.0626(13) Uani 1 1 d .
H9A H 0.2404 0.8429 0.5415 0.075 Uiso 1 1 calc R
H9B H 0.2182 0.7923 0.4691 0.075 Uiso 1 1 calc R
C10 C 0.2506(3) 0.6233(4) 0.5013(3) 0.108(2) Uani 1 1 d D
H10A H 0.2053 0.5866 0.5117 0.129 Uiso 1 1 calc R
H10B H 0.2318 0.6486 0.4550 0.129 Uiso 1 1 calc R
C11 C 0.3411(3) 0.6694(3) 0.7788(2) 0.0582(11) Uani 1 1 d .
H11 H 0.3410 0.6047 0.7884 0.070 Uiso 1 1 calc R
C12 C 0.2800(3) 0.7272(4) 0.7944(3) 0.0768(15) Uani 1 1 d .
H12 H 0.2393 0.7010 0.8146 0.092 Uiso 1 1 calc R
C13 C 0.2788(3) 0.8221(5) 0.7803(3) 0.0770(15) Uani 1 1 d .
H13 H 0.2375 0.8606 0.7906 0.092 Uiso 1 1 calc R
C14 C 0.3388(4) 0.8597(4) 0.7511(3) 0.0807(15) Uani 1 1 d .
H14 H 0.3385 0.9244 0.7414 0.097 Uiso 1 1 calc R
C15 C 0.4000(3) 0.8027(4) 0.7358(3) 0.0711(14) Uani 1 1 d .
H15 H 0.4407 0.8296 0.7159 0.085 Uiso 1 1 calc R
C16 C 0.4020(2) 0.7073(3) 0.7491(2) 0.0494(11) Uani 1 1 d .
C17 C 0.1201(4) 0.6790(4) 0.5744(3) 0.0832(17) Uani 1 1 d .
C18 C 0.2107(3) 0.6961(4) 0.5993(3) 0.0803(16) Uani 1 1 d .
H18A H 0.2175 0.7545 0.6260 0.096 Uiso 1 1 calc R
H18B H 0.2327 0.6450 0.6307 0.096 Uiso 1 1 calc R
C19 C 0.0686(4) 0.7437(5) 0.5364(4) 0.107(2) Uani 1 1 d .
H19 H 0.0905 0.8014 0.5258 0.129 Uiso 1 1 calc R
C20 C 0.0845(5) 0.5955(5) 0.5905(4) 0.126(3) Uani 1 1 d .
H20 H 0.1172 0.5496 0.6168 0.151 Uiso 1 1 calc R
C21 C 0.1111(4) 1.0237(4) 0.3249(3) 0.0862(17) Uani 1 1 d .
H21 H 0.1566 1.0360 0.3058 0.103 Uiso 1 1 calc R
C22 C 0.1092(3) 1.0578(3) 0.3903(3) 0.0613(12) Uani 1 1 d .
C23 C 0.0426(3) 1.0352(4) 0.4176(3) 0.0979(19) Uani 1 1 d .
H23 H 0.0413 1.0553 0.4622 0.117 Uiso 1 1 calc R
C24 C 0.0458(5) 0.9711(4) 0.2874(4) 0.119(2) Uani 1 1 d .
H24 H 0.0471 0.9483 0.2435 0.143 Uiso 1 1 calc R
C25 C 0.1774(2) 1.1199(3) 0.4283(2) 0.0556(11) Uani 1 1 d .
H25A H 0.1775 1.1793 0.4034 0.067 Uiso 1 1 calc R
H25B H 0.1673 1.1344 0.4739 0.067 Uiso 1 1 calc R
C26 C 0.0000(6) 0.5791(7) 0.5678(5) 0.154(4) Uani 1 1 d .
H26 H -0.0227 0.5219 0.5783 0.185 Uiso 1 1 calc R
C27 C -0.0483(6) 0.6457(8) 0.5308(6) 0.154(4) Uani 1 1 d .
H27 H -0.1047 0.6354 0.5178 0.184 Uiso 1 1 calc R
C28 C -0.0159(5) 0.7275(6) 0.5123(4) 0.131(3) Uani 1 1 d .
H28 H -0.0488 0.7718 0.4844 0.157 Uiso 1 1 calc R
C29 C -0.0228(4) 0.9833(6) 0.3809(5) 0.131(3) Uani 1 1 d .
H29 H -0.0676 0.9694 0.4005 0.157 Uiso 1 1 calc R
C30 C -0.0213(5) 0.9535(5) 0.3173(5) 0.136(3) Uani 1 1 d .
H30 H -0.0662 0.9201 0.2923 0.163 Uiso 1 1 calc R
C31 C 0.0781(3) 1.2180(4) 0.2121(3) 0.0817(16) Uani 1 1 d .
H31 H 0.0912 1.2044 0.1696 0.098 Uiso 1 1 calc R
C32 C 0.5310(2) 0.6536(3) 0.6305(2) 0.0432(9) Uani 1 1 d .
C33 C 0.5208(3) 0.6441(3) 0.5540(2) 0.0503(11) Uani 1 1 d .
C34 C 0.5866(4) 0.6733(4) 0.5254(3) 0.0637(13) Uani 1 1 d .
C35 C 0.3086(3) 0.5627(5) 0.4974(4) 0.174(4) Uani 1 1 d D
H35A H 0.3134 0.5590 0.4494 0.209 Uiso 1 1 calc R
H35B H 0.2909 0.5007 0.5101 0.209 Uiso 1 1 calc R
C36 C 0.4696(3) 0.6451(3) 0.7332(2) 0.0639(13) Uani 1 1 d .
H36A H 0.5225 0.6694 0.7573 0.077 Uiso 1 1 calc R
H36B H 0.4635 0.5812 0.7498 0.077 Uiso 1 1 calc R
C37 C 0.5839(4) 0.6681(4) 0.4554(3) 0.0920(19) Uani 1 1 d .
H37 H 0.6283 0.6887 0.4374 0.110 Uiso 1 1 calc R
C38 C 0.4507(3) 0.6090(3) 0.5093(3) 0.0690(15) Uani 1 1 d .
C39 C 0.4487(4) 0.6037(4) 0.4380(3) 0.104(2) Uani 1 1 d .
H39 H 0.4022 0.5807 0.4079 0.124 Uiso 1 1 calc R
C40 C 0.5155(5) 0.6326(5) 0.4132(3) 0.112(3) Uani 1 1 d .
H40 H 0.5140 0.6278 0.3660 0.134 Uiso 1 1 calc R
C41 C -0.0289(4) 1.2261(4) 0.2794(3) 0.112(2) Uani 1 1 d .
H41A H 0.0160 1.2479 0.3149 0.168 Uiso 1 1 calc R
H41B H -0.0505 1.1681 0.2942 0.168 Uiso 1 1 calc R
H41C H -0.0713 1.2735 0.2711 0.168 Uiso 1 1 calc R
C42 C -0.0608(4) 1.1826(6) 0.1560(3) 0.147(3) Uani 1 1 d .
H42A H -0.0334 1.1646 0.1198 0.220 Uiso 1 1 calc R
H42B H -0.0965 1.2356 0.1410 0.220 Uiso 1 1 calc R
H42C H -0.0927 1.1300 0.1668 0.220 Uiso 1 1 calc R
N7 N -0.0001(2) 1.2091(3) 0.2172(2) 0.0728(12) Uani 1 1 d .
Eu1 Eu 0.274569(11) 1.275193(14) 0.268680(10) 0.03985(7) Uani 1 1 d .
N1 N 0.2063(2) 1.4262(3) 0.3413(2) 0.0557(9) Uani 1 1 d .
N2 N 0.2612(2) 1.3870(3) 0.1417(2) 0.0618(10) Uani 1 1 d .
N3 N 0.3171(3) 1.1088(3) 0.1960(2) 0.0682(11) Uani 1 1 d .
N4 N 0.2608(2) 0.7031(2) 0.54692(18) 0.0531(9) Uani 1 1 d .
N5 N 0.25806(19) 1.0745(2) 0.43589(17) 0.0522(9) Uani 1 1 d .
H5A H 0.2718 1.0338 0.4688 0.063 Uiso 1 1 calc R
N6 N 0.4680(2) 0.6419(3) 0.65915(18) 0.0608(10) Uani 1 1 d .
H6 H 0.4212 0.6313 0.6320 0.073 Uiso 1 1 calc R
O1 O 0.22797(17) 1.3484(2) 0.37091(15) 0.0610(8) Uani 1 1 d .
O2 O 0.22071(19) 1.4368(2) 0.28130(17) 0.0648(8) Uani 1 1 d .
O3 O 0.1728(2) 1.4882(2) 0.36817(18) 0.0867(11) Uani 1 1 d .
O4 O 0.32608(17) 1.3870(2) 0.18856(15) 0.0606(8) Uani 1 1 d .
O5 O 0.20662(19) 1.3270(3) 0.14905(15) 0.0700(9) Uani 1 1 d .
O6 O 0.2440(2) 1.1233(2) 0.20211(18) 0.0775(10) Uani 1 1 d .
O7 O 0.36861(19) 1.1742(2) 0.21746(15) 0.0633(8) Uani 1 1 d .
O8 O 0.3367(3) 1.0350(3) 0.1719(2) 0.1034(13) Uani 1 1 d .
O9 O 0.29878(16) 1.1563(2) 0.35196(14) 0.0544(7) Uani 1 1 d .
O10 O 0.60070(15) 0.6734(2) 0.66707(13) 0.0519(7) Uani 1 1 d .
O11 O 0.13311(18) 1.2423(2) 0.25894(17) 0.0633(9) Uani 1 1 d .
O12 O 0.2518(2) 1.4418(3) 0.09271(18) 0.0951(12) Uani 1 1 d .
O13 O 0.33537(16) 0.91225(19) 0.46879(15) 0.0560(8) Uani 1 1 d .
O14 O 0.3884(2) 0.5801(3) 0.5383(2) 0.0960(13) Uani 1 1 d .
H2 H 0.4444(19) 1.126(2) 0.3523(16) 0.036(10) Uiso 1 1 d .
H3 H 0.565(2) 1.041(2) 0.3595(17) 0.041(10) Uiso 1 1 d .
H4 H 0.579(2) 0.894(3) 0.4140(19) 0.058(13) Uiso 1 1 d .
H34 H 0.631(2) 0.695(2) 0.5527(18) 0.033(11) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C6 118.1(3) . .
C2 C1 C7 117.2(4) . .
C6 C1 C7 124.6(3) . .
C3 C2 C1 121.3(4) . .
C3 C2 H2 119.5(19) . .
C1 C2 H2 119.0(19) . .
C2 C3 C4 119.8(4) . .
C2 C3 H3 119(2) . .
C4 C3 H3 121(2) . .
C5 C4 C3 120.3(4) . .
C5 C4 H4 121(2) . .
C3 C4 H4 119(2) . .
C4 C5 C6 120.4(4) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
O13 C6 C5 122.4(4) . .
O13 C6 C1 117.6(3) . .
C5 C6 C1 120.0(3) . .
O9 C7 N5 120.3(4) . .
O9 C7 C1 120.6(3) . .
N5 C7 C1 119.1(4) . .
O13 C8 C9 107.2(3) . .
O13 C8 H8A 110.3 . .
C9 C8 H8A 110.3 . .
O13 C8 H8B 110.3 . .
C9 C8 H8B 110.3 . .
H8A C8 H8B 108.5 . .
N4 C9 C8 110.4(3) . .
N4 C9 H9A 109.6 . .
C8 C9 H9A 109.6 . .
N4 C9 H9B 109.6 . .
C8 C9 H9B 109.6 . .
H9A C9 H9B 108.1 . .
C35 C10 N4 124.2(5) . .
C35 C10 H10A 106.3 . .
N4 C10 H10A 106.3 . .
C35 C10 H10B 106.3 . .
N4 C10 H10B 106.3 . .
H10A C10 H10B 106.4 . .
C16 C11 C12 120.4(5) . .
C16 C11 H11 119.8 . .
C12 C11 H11 119.8 . .
C13 C12 C11 120.6(5) . .
C13 C12 H12 119.7 . .
C11 C12 H12 119.7 . .
C14 C13 C12 119.2(5) . .
C14 C13 H13 120.4 . .
C12 C13 H13 120.4 . .
C13 C14 C15 120.5(5) . .
C13 C14 H14 119.8 . .
C15 C14 H14 119.8 . .
C16 C15 C14 121.2(5) . .
C16 C15 H15 119.4 . .
C14 C15 H15 119.4 . .
C15 C16 C11 118.1(4) . .
C15 C16 C36 121.2(4) . .
C11 C16 C36 120.7(4) . .
C19 C17 C20 116.4(7) . .
C19 C17 C18 123.0(6) . .
C20 C17 C18 120.6(7) . .
N4 C18 C17 117.3(4) . .
N4 C18 H18A 108.0 . .
C17 C18 H18A 108.0 . .
N4 C18 H18B 108.0 . .
C17 C18 H18B 108.0 . .
H18A C18 H18B 107.2 . .
C17 C19 C28 123.1(7) . .
C17 C19 H19 118.5 . .
C28 C19 H19 118.5 . .
C17 C20 C26 121.1(8) . .
C17 C20 H20 119.5 . .
C26 C20 H20 119.5 . .
C22 C21 C24 120.9(6) . .
C22 C21 H21 119.6 . .
C24 C21 H21 119.6 . .
C23 C22 C21 117.7(5) . .
C23 C22 C25 121.8(5) . .
C21 C22 C25 120.5(4) . .
C22 C23 C29 122.0(7) . .
C22 C23 H23 119.0 . .
C29 C23 H23 119.0 . .
C30 C24 C21 118.4(7) . .
C30 C24 H24 120.8 . .
C21 C24 H24 120.8 . .
N5 C25 C22 112.1(3) . .
N5 C25 H25A 109.2 . .
C22 C25 H25A 109.2 . .
N5 C25 H25B 109.2 . .
C22 C25 H25B 109.2 . .
H25A C25 H25B 107.9 . .
C27 C26 C20 120.1(9) . .
C27 C26 H26 119.9 . .
C20 C26 H26 119.9 . .
C26 C27 C28 120.9(10) . .
C26 C27 H27 119.5 . .
C28 C27 H27 119.5 . .
C27 C28 C19 118.3(9) . .
C27 C28 H28 120.9 . .
C19 C28 H28 120.9 . .
C30 C29 C23 119.6(8) . .
C30 C29 H29 120.2 . .
C23 C29 H29 120.2 . .
C29 C30 C24 121.3(8) . .
C29 C30 H30 119.3 . .
C24 C30 H30 119.3 . .
O11 C31 N7 124.3(5) . .
O11 C31 H31 117.8 . .
N7 C31 H31 117.8 . .
O10 C32 N6 120.3(4) . .
O10 C32 C33 119.8(4) . .
N6 C32 C33 119.9(4) . .
C34 C33 C38 117.9(5) . .
C34 C33 C32 116.9(4) . .
C38 C33 C32 125.1(4) . .
C37 C34 C33 122.0(6) . .
C37 C34 H34 119(3) . .
C33 C34 H34 119(2) . .
C10 C35 O14 117.9(5) . .
C10 C35 H35A 107.8 . .
O14 C35 H35A 107.8 . .
C10 C35 H35B 107.8 . .
O14 C35 H35B 107.8 . .
H35A C35 H35B 107.2 . .
N6 C36 C16 111.7(3) . .
N6 C36 H36A 109.3 . .
C16 C36 H36A 109.3 . .
N6 C36 H36B 109.3 . .
C16 C36 H36B 109.3 . .
H36A C36 H36B 107.9 . .
C40 C37 C34 118.9(6) . .
C40 C37 H37 120.5 . .
C34 C37 H37 120.5 . .
O14 C38 C33 116.8(5) . .
O14 C38 C39 123.5(5) . .
C33 C38 C39 119.7(6) . .
C40 C39 C38 119.7(6) . .
C40 C39 H39 120.2 . .
C38 C39 H39 120.2 . .
C37 C40 C39 121.8(6) . .
C37 C40 H40 119.1 . .
C39 C40 H40 119.1 . .
N7 C41 H41A 109.5 . .
N7 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
N7 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
N7 C42 H42A 109.5 . .
N7 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
N7 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C31 N7 C41 123.9(5) . .
C31 N7 C42 118.7(5) . .
C41 N7 C42 117.4(5) . .
O10 Eu1 O9 80.41(10) 3_676 .
O10 Eu1 O11 150.36(10) 3_676 .
O9 Eu1 O11 86.47(10) . .
O10 Eu1 O2 87.65(10) 3_676 .
O9 Eu1 O2 127.09(10) . .
O11 Eu1 O2 79.25(10) . .
O10 Eu1 O7 80.43(10) 3_676 .
O9 Eu1 O7 81.14(10) . .
O11 Eu1 O7 123.76(11) . .
O2 Eu1 O7 147.11(10) . .
O10 Eu1 O6 128.01(11) 3_676 .
O9 Eu1 O6 75.14(11) . .
O11 Eu1 O6 72.64(11) . .
O2 Eu1 O6 143.01(11) . .
O7 Eu1 O6 51.14(11) . .
O10 Eu1 O5 127.09(10) 3_676 .
O9 Eu1 O5 148.82(11) . .
O11 Eu1 O5 74.71(11) . .
O2 Eu1 O5 74.13(11) . .
O7 Eu1 O5 88.85(11) . .
O6 Eu1 O5 75.60(11) . .
O10 Eu1 O4 76.39(9) 3_676 .
O9 Eu1 O4 150.29(9) . .
O11 Eu1 O4 122.47(10) . .
O2 Eu1 O4 70.46(10) . .
O7 Eu1 O4 76.95(10) . .
O6 Eu1 O4 105.21(11) . .
O5 Eu1 O4 50.75(10) . .
O10 Eu1 O1 79.81(9) 3_676 .
O9 Eu1 O1 76.35(10) . .
O11 Eu1 O1 71.27(10) . .
O2 Eu1 O1 50.78(10) . .
O7 Eu1 O1 152.13(10) . .
O6 Eu1 O1 134.79(11) . .
O5 Eu1 O1 118.81(10) . .
O4 Eu1 O1 116.80(10) . .
O3 N1 O1 122.3(4) . .
O3 N1 O2 121.2(4) . .
O1 N1 O2 116.5(3) . .
O12 N2 O4 121.8(4) . .
O12 N2 O5 122.3(4) . .
O4 N2 O5 115.9(4) . .
O8 N3 O6 121.2(5) . .
O8 N3 O7 122.3(5) . .
O6 N3 O7 116.5(4) . .
C10 N4 C9 114.6(4) . .
C10 N4 C18 112.6(4) . .
C9 N4 C18 114.9(4) . .
C7 N5 C25 125.2(3) . .
C7 N5 H5A 117.4 . .
C25 N5 H5A 117.4 . .
C32 N6 C36 125.8(4) . .
C32 N6 H6 117.1 . .
C36 N6 H6 117.1 . .
N1 O1 Eu1 95.1(2) . .
N1 O2 Eu1 97.4(2) . .
N2 O4 Eu1 96.3(2) . .
N2 O5 Eu1 96.3(2) . .
N3 O6 Eu1 95.5(3) . .
N3 O7 Eu1 96.5(3) . .
C7 O9 Eu1 179.0(3) . .
C32 O10 Eu1 174.5(3) . 3_676
C31 O11 Eu1 134.3(4) . .
C6 O13 C8 118.8(3) . .
C38 O14 C35 121.3(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.391(5) .
C1 C6 1.409(5) .
C1 C7 1.481(5) .
C2 C3 1.379(5) .
C2 H2 0.96(3) .
C3 C4 1.380(6) .
C3 H3 0.95(3) .
C4 C5 1.374(5) .
C4 H4 0.92(4) .
C5 C6 1.387(5) .
C5 H5 0.9300 .
C6 O13 1.365(4) .
C7 O9 1.253(4) .
C7 N5 1.326(4) .
C8 O13 1.429(4) .
C8 C9 1.516(5) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 N4 1.448(5) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C35 1.301(6) .
C10 N4 1.427(5) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C16 1.379(5) .
C11 C12 1.385(6) .
C11 H11 0.9300 .
C12 C13 1.363(7) .
C12 H12 0.9300 .
C13 C14 1.359(6) .
C13 H13 0.9300 .
C14 C15 1.378(6) .
C14 H14 0.9300 .
C15 C16 1.368(6) .
C15 H15 0.9300 .
C16 C36 1.508(5) .
C17 C19 1.362(8) .
C17 C20 1.382(7) .
C17 C18 1.502(7) .
C18 N4 1.462(5) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C28 1.404(9) .
C19 H19 0.9300 .
C20 C26 1.400(10) .
C20 H20 0.9300 .
C21 C22 1.385(7) .
C21 C24 1.391(8) .
C21 H21 0.9300 .
C22 C23 1.366(6) .
C22 C25 1.501(6) .
C23 C29 1.382(8) .
C23 H23 0.9300 .
C24 C30 1.389(9) .
C24 H24 0.9300 .
C25 N5 1.464(4) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.346(12) .
C26 H26 0.9300 .
C27 C28 1.352(10) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.329(9) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 O11 1.206(6) .
C31 N7 1.330(6) .
C31 H31 0.9300 .
C32 O10 1.261(4) .
C32 N6 1.301(5) .
C32 C33 1.490(5) .
C33 C34 1.393(6) .
C33 C38 1.396(6) .
C34 C37 1.375(6) .
C34 H34 0.87(3) .
C35 O14 1.422(5) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 N6 1.457(5) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 C40 1.357(9) .
C37 H37 0.9300 .
C38 O14 1.347(6) .
C38 C39 1.404(7) .
C39 C40 1.366(9) .
C39 H39 0.9300 .
C40 H40 0.9300 .
C41 N7 1.430(6) .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 N7 1.451(7) .
C42 H42A 0.9600 .
C42 H42B 0.9600 .
C42 H42C 0.9600 .
Eu1 O10 2.308(3) 3_676
Eu1 O9 2.321(3) .
Eu1 O11 2.363(3) .
Eu1 O2 2.475(3) .
Eu1 O7 2.479(3) .
Eu1 O6 2.504(3) .
Eu1 O5 2.505(3) .
Eu1 O4 2.506(3) .
Eu1 O1 2.529(3) .
N1 O3 1.215(4) .
N1 O1 1.257(4) .
N1 O2 1.266(4) .
N2 O12 1.221(4) .
N2 O4 1.265(4) .
N2 O5 1.269(4) .
N3 O8 1.215(4) .
N3 O6 1.263(5) .
N3 O7 1.267(5) .
N5 H5A 0.8600 .
N6 H6 0.8600 .
O10 Eu1 2.308(3) 3_676
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -1.8(6) . .
C7 C1 C2 C3 -179.1(4) . .
C1 C2 C3 C4 1.4(7) . .
C2 C3 C4 C5 -0.6(7) . .
C3 C4 C5 C6 0.4(6) . .
C4 C5 C6 O13 179.2(4) . .
C4 C5 C6 C1 -0.8(6) . .
C2 C1 C6 O13 -178.5(3) . .
C7 C1 C6 O13 -1.4(6) . .
C2 C1 C6 C5 1.5(6) . .
C7 C1 C6 C5 178.6(3) . .
C2 C1 C7 O9 13.3(5) . .
C6 C1 C7 O9 -163.8(4) . .
C2 C1 C7 N5 -165.7(4) . .
C6 C1 C7 N5 17.2(6) . .
O13 C8 C9 N4 -177.5(4) . .
C16 C11 C12 C13 0.3(8) . .
C11 C12 C13 C14 -0.4(8) . .
C12 C13 C14 C15 0.1(8) . .
C13 C14 C15 C16 0.2(8) . .
C14 C15 C16 C11 -0.3(7) . .
C14 C15 C16 C36 -179.2(5) . .
C12 C11 C16 C15 0.0(6) . .
C12 C11 C16 C36 178.9(4) . .
C19 C17 C18 N4 -66.2(7) . .
C20 C17 C18 N4 114.9(6) . .
C20 C17 C19 C28 -1.8(10) . .
C18 C17 C19 C28 179.3(5) . .
C19 C17 C20 C26 0.7(10) . .
C18 C17 C20 C26 179.7(6) . .
C24 C21 C22 C23 2.4(8) . .
C24 C21 C22 C25 -175.9(5) . .
C21 C22 C23 C29 -2.6(9) . .
C25 C22 C23 C29 175.6(6) . .
C22 C21 C24 C30 -0.2(10) . .
C23 C22 C25 N5 125.7(5) . .
C21 C22 C25 N5 -56.0(6) . .
C17 C20 C26 C27 -1.3(13) . .
C20 C26 C27 C28 3.0(16) . .
C26 C27 C28 C19 -3.9(14) . .
C17 C19 C28 C27 3.4(11) . .
C22 C23 C29 C30 0.6(12) . .
C23 C29 C30 C24 1.8(13) . .
C21 C24 C30 C29 -2.0(12) . .
O10 C32 C33 C34 -10.3(5) . .
N6 C32 C33 C34 169.3(4) . .
O10 C32 C33 C38 170.0(4) . .
N6 C32 C33 C38 -10.4(6) . .
C38 C33 C34 C37 0.0(7) . .
C32 C33 C34 C37 -179.8(4) . .
N4 C10 C35 O14 -3.9(13) . .
C15 C16 C36 N6 -64.0(5) . .
C11 C16 C36 N6 117.1(4) . .
C33 C34 C37 C40 -0.7(8) . .
C34 C33 C38 O14 179.1(4) . .
C32 C33 C38 O14 -1.2(6) . .
C34 C33 C38 C39 0.2(6) . .
C32 C33 C38 C39 179.9(4) . .
O14 C38 C39 C40 -178.5(5) . .
C33 C38 C39 C40 0.3(8) . .
C34 C37 C40 C39 1.4(9) . .
C38 C39 C40 C37 -1.2(9) . .
O11 C31 N7 C41 -1.1(8) . .
O11 C31 N7 C42 177.7(6) . .
C35 C10 N4 C9 111.3(8) . .
C35 C10 N4 C18 -114.8(8) . .
C8 C9 N4 C10 -84.9(5) . .
C8 C9 N4 C18 142.3(4) . .
C17 C18 N4 C10 -53.5(6) . .
C17 C18 N4 C9 80.2(6) . .
O9 C7 N5 C25 7.3(6) . .
C1 C7 N5 C25 -173.7(4) . .
C22 C25 N5 C7 99.0(5) . .
O10 C32 N6 C36 -3.0(6) . .
C33 C32 N6 C36 177.3(4) . .
C16 C36 N6 C32 132.0(4) . .
O3 N1 O1 Eu1 175.1(4) . .
O2 N1 O1 Eu1 -4.4(4) . .
O10 Eu1 O1 N1 97.9(2) 3_676 .
O9 Eu1 O1 N1 -179.6(2) . .
O11 Eu1 O1 N1 -88.7(2) . .
O2 Eu1 O1 N1 2.6(2) . .
O7 Eu1 O1 N1 143.4(3) . .
O6 Eu1 O1 N1 -127.4(2) . .
O5 Eu1 O1 N1 -29.0(3) . .
O4 Eu1 O1 N1 29.0(3) . .
O3 N1 O2 Eu1 -175.0(3) . .
O1 N1 O2 Eu1 4.5(4) . .
O10 Eu1 O2 N1 -81.4(2) 3_676 .
O9 Eu1 O2 N1 -5.3(3) . .
O11 Eu1 O2 N1 71.9(2) . .
O7 Eu1 O2 N1 -149.7(2) . .
O6 Eu1 O2 N1 112.7(3) . .
O5 Eu1 O2 N1 148.9(2) . .
O4 Eu1 O2 N1 -157.8(2) . .
O1 Eu1 O2 N1 -2.6(2) . .
O12 N2 O4 Eu1 171.2(4) . .
O5 N2 O4 Eu1 -8.5(4) . .
O10 Eu1 O4 N2 -172.5(3) 3_676 .
O9 Eu1 O4 N2 147.9(2) . .
O11 Eu1 O4 N2 -17.6(3) . .
O2 Eu1 O4 N2 -80.1(3) . .
O7 Eu1 O4 N2 104.4(3) . .
O6 Eu1 O4 N2 61.3(3) . .
O5 Eu1 O4 N2 5.0(2) . .
O1 Eu1 O4 N2 -101.5(3) . .
O12 N2 O5 Eu1 -171.2(4) . .
O4 N2 O5 Eu1 8.5(4) . .
O10 Eu1 O5 N2 -1.9(3) 3_676 .
O9 Eu1 O5 N2 -149.7(2) . .
O11 Eu1 O5 N2 155.4(3) . .
O2 Eu1 O5 N2 72.5(3) . .
O7 Eu1 O5 N2 -79.0(3) . .
O6 Eu1 O5 N2 -129.0(3) . .
O4 Eu1 O5 N2 -5.0(2) . .
O1 Eu1 O5 N2 97.4(3) . .
O8 N3 O6 Eu1 172.5(4) . .
O7 N3 O6 Eu1 -6.1(4) . .
O10 Eu1 O6 N3 -22.2(3) 3_676 .
O9 Eu1 O6 N3 -87.0(3) . .
O11 Eu1 O6 N3 -177.9(3) . .
O2 Eu1 O6 N3 139.8(2) . .
O7 Eu1 O6 N3 3.6(2) . .
O5 Eu1 O6 N3 103.9(3) . .
O4 Eu1 O6 N3 62.3(3) . .
O1 Eu1 O6 N3 -139.5(2) . .
O8 N3 O7 Eu1 -172.4(4) . .
O6 N3 O7 Eu1 6.2(4) . .
O10 Eu1 O7 N3 156.1(3) 3_676 .
O9 Eu1 O7 N3 74.4(3) . .
O11 Eu1 O7 N3 -5.2(3) . .
O2 Eu1 O7 N3 -133.6(3) . .
O6 Eu1 O7 N3 -3.6(2) . .
O5 Eu1 O7 N3 -75.9(3) . .
O4 Eu1 O7 N3 -125.8(3) . .
O1 Eu1 O7 N3 110.7(3) . .
N5 C7 O9 Eu1 -109(14) . .
C1 C7 O9 Eu1 72(14) . .
O10 Eu1 O9 C7 -130(14) 3_676 .
O11 Eu1 O9 C7 77(14) . .
O2 Eu1 O9 C7 151(14) . .
O7 Eu1 O9 C7 -48(14) . .
O6 Eu1 O9 C7 4(14) . .
O5 Eu1 O9 C7 25(14) . .
O4 Eu1 O9 C7 -91(14) . .
O1 Eu1 O9 C7 148(14) . .
N6 C32 O10 Eu1 -97(3) . 3_676
C33 C32 O10 Eu1 83(3) . 3_676
N7 C31 O11 Eu1 -175.4(3) . .
O10 Eu1 O11 C31 175.0(4) 3_676 .
O9 Eu1 O11 C31 -121.5(5) . .
O2 Eu1 O11 C31 109.7(5) . .
O7 Eu1 O11 C31 -44.6(5) . .
O6 Eu1 O11 C31 -46.0(5) . .
O5 Eu1 O11 C31 33.4(5) . .
O4 Eu1 O11 C31 51.3(5) . .
O1 Eu1 O11 C31 161.7(5) . .
C5 C6 O13 C8 -5.0(6) . .
C1 C6 O13 C8 175.0(4) . .
C9 C8 O13 C6 -168.1(3) . .
C33 C38 O14 C35 166.2(4) . .
C39 C38 O14 C35 -14.9(7) . .
C10 C35 O14 C38 -107.6(8) . .
