#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:08:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180413 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/82/7208223.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208223
loop_
_publ_author_name
'Yan, Xuhuan'
'Yan, Zhenzhong'
'Zhang, Ye'
'Liu, Weisheng'
'Tang, Yu'
'Tan, Minyu'
_publ_section_title
;
 Anions make the difference: conversion from zero- to one-dimensional
 structures and luminescent properties of lanthanide-based complexes
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              4989
_journal_paper_doi               10.1039/c2ce25210d
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C59 H51 N12 O26 Tb'
_chemical_formula_weight         1503.04
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.651(2)
_cell_angle_beta                 109.062(2)
_cell_angle_gamma                114.164(2)
_cell_formula_units_Z            2
_cell_length_a                   13.6842(15)
_cell_length_b                   15.8378(17)
_cell_length_c                   17.4990(18)
_cell_measurement_temperature    294(2)
_cell_volume                     3130.6(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_sigmaI/netI    0.0768
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            15456
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.29
_exptl_absorpt_coefficient_mu    1.226
_exptl_absorpt_correction_T_max  0.7916
_exptl_absorpt_correction_T_min  0.7657
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            block
_exptl_crystal_density_diffrn    1.595
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       yellow
_exptl_crystal_F_000             1524
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.712
_refine_diff_density_min         -0.708
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     888
_refine_ls_number_reflns         11380
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.006
_refine_ls_R_factor_all          0.0879
_refine_ls_R_factor_gt           0.0562
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0735P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1247
_refine_ls_wR_factor_ref         0.1463
_reflns_number_gt                8077
_reflns_number_total             11380
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25210d.txt
_cod_data_source_block           852909
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7208223
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O26 O 1.1477(3) 0.7279(3) 0.8190(3) 0.0532(10) Uani 1 1 d .
C2 C 1.1835(6) 1.0445(4) 0.6411(4) 0.0556(16) Uani 1 1 d .
H2 H 1.2560 1.0867 0.6428 0.067 Uiso 1 1 calc R
C3 C 1.1687(5) 0.9635(4) 0.6657(4) 0.0488(15) Uani 1 1 d .
C4 C 1.0595(5) 0.8957(4) 0.6652(4) 0.0478(14) Uani 1 1 d .
C5 C 0.5728(5) 0.3921(4) 0.7855(4) 0.0500(15) Uani 1 1 d .
C6 C 0.8768(5) 1.4429(4) 0.7207(4) 0.0474(14) Uani 1 1 d .
C7 C 0.5899(5) 0.4895(4) 0.6942(4) 0.0498(15) Uani 1 1 d .
C8 C 0.7536(6) 1.3719(4) 0.6598(4) 0.0511(15) Uani 1 1 d .
C9 C 1.1430(5) 1.4519(4) 0.8435(4) 0.0524(15) Uani 1 1 d .
C10 C 1.3165(5) 0.7214(4) 0.9012(4) 0.0539(16) Uani 1 1 d .
C11 C 0.7142(5) 0.5508(4) 0.7450(4) 0.0481(15) Uani 1 1 d .
C12 C 0.9987(5) 0.8925(5) 0.8581(4) 0.0557(16) Uani 1 1 d .
C13 C 1.2512(5) 0.6774(4) 0.7523(4) 0.0462(14) Uani 1 1 d .
C14 C 1.3427(5) 0.6564(4) 0.7609(4) 0.0567(16) Uani 1 1 d .
H14 H 1.3525 0.6350 0.7136 0.068 Uiso 1 1 calc R
C15 C 0.5218(5) 0.4121(4) 0.7135(4) 0.0536(16) Uani 1 1 d .
H15 H 0.4424 0.3737 0.6786 0.064 Uiso 1 1 calc R
C16 C 1.0524(6) 1.4803(5) 0.8458(4) 0.0608(17) Uani 1 1 d .
H16A H 1.0484 1.4812 0.9002 0.073 Uiso 1 1 calc R
H16B H 1.0766 1.5453 0.8406 0.073 Uiso 1 1 calc R
C17 C 1.1103(6) 0.9795(5) 0.8743(4) 0.0612(18) Uani 1 1 d .
C18 C 1.2304(5) 0.7090(4) 0.8217(4) 0.0450(14) Uani 1 1 d .
C19 C 0.6801(5) 1.2905(5) 0.6760(4) 0.0576(17) Uani 1 1 d .
C20 C 0.9689(5) 0.9215(4) 0.6368(4) 0.0514(15) Uani 1 1 d .
C21 C 0.6886(5) 0.4471(4) 0.8392(4) 0.0542(16) Uani 1 1 d .
H21 H 0.7202 0.4324 0.8883 0.065 Uiso 1 1 calc R
C22 C 0.7077(7) 1.3901(5) 0.5848(4) 0.075(2) Uani 1 1 d .
H22 H 0.7554 1.4436 0.5729 0.090 Uiso 1 1 calc R
C23 C 0.7580(5) 0.5251(4) 0.8193(4) 0.0488(15) Uani 1 1 d .
C24 C 1.4183(5) 0.6679(5) 0.8402(4) 0.0568(16) Uani 1 1 d .
C25 C 0.7025(6) 0.8466(5) 0.8261(5) 0.0614(18) Uani 1 1 d .
C26 C 0.9835(6) 1.0031(5) 0.6117(4) 0.0576(16) Uani 1 1 d .
H26 H 0.9215 1.0171 0.5935 0.069 Uiso 1 1 calc R
C27 C 0.7872(7) 1.1078(5) 0.6592(5) 0.0676(19) Uani 1 1 d .
C28 C 1.0907(6) 1.0639(4) 0.6137(4) 0.0592(17) Uani 1 1 d .
C29 C 1.4054(6) 0.6996(5) 0.9104(4) 0.0640(18) Uani 1 1 d .
H29 H 1.4566 0.7062 0.9638 0.077 Uiso 1 1 calc R
C30 C 0.8228(7) 1.0916(5) 0.7452(5) 0.081(2) Uani 1 1 d .
H30A H 0.7571 1.0362 0.7459 0.097 Uiso 1 1 calc R
H30B H 0.8871 1.0766 0.7552 0.097 Uiso 1 1 calc R
C31 C 1.1499(7) 1.4205(6) 0.7715(5) 0.075(2) Uani 1 1 d .
H31 H 1.0954 1.4150 0.7200 0.090 Uiso 1 1 calc R
C32 C 0.8530(7) 1.1890(6) 0.6444(5) 0.072(2) Uani 1 1 d .
H32 H 0.9224 1.2358 0.6889 0.087 Uiso 1 1 calc R
C33 C 1.2040(6) 0.9622(6) 0.8813(5) 0.080(2) Uani 1 1 d .
H33 H 1.1947 0.9001 0.8778 0.096 Uiso 1 1 calc R
C34 C 0.6868(7) 1.0381(6) 0.5920(6) 0.090(2) Uani 1 1 d .
H34 H 0.6400 0.9807 0.5999 0.108 Uiso 1 1 calc R
C35 C 0.7638(10) 1.1746(6) 0.8330(6) 0.106(3) Uani 1 1 d .
H35A H 0.7961 1.2283 0.8826 0.128 Uiso 1 1 calc R
H35B H 0.7270 1.1154 0.8470 0.128 Uiso 1 1 calc R
C36 C 0.5669(7) 1.2330(6) 0.6179(6) 0.083(2) Uani 1 1 d .
H36 H 0.5183 1.1786 0.6282 0.100 Uiso 1 1 calc R
C37 C 1.2265(7) 1.4608(6) 0.9189(5) 0.078(2) Uani 1 1 d .
H37 H 1.2230 1.4812 0.9695 0.093 Uiso 1 1 calc R
C38 C 0.7979(6) 0.8196(6) 0.8503(6) 0.092(3) Uani 1 1 d .
H38A H 0.7799 0.7669 0.8049 0.111 Uiso 1 1 calc R
H38B H 0.8021 0.7973 0.9001 0.111 Uiso 1 1 calc R
C39 C 1.3116(8) 1.0372(9) 0.8933(5) 0.116(4) Uani 1 1 d .
H39 H 1.3756 1.0264 0.9006 0.139 Uiso 1 1 calc R
C40 C 1.3220(10) 1.1264(10) 0.8944(6) 0.132(5) Uani 1 1 d .
H40 H 1.3931 1.1757 0.8998 0.158 Uiso 1 1 calc R
C41 C 1.2338(9) 1.1462(7) 0.8879(6) 0.123(5) Uani 1 1 d .
H41 H 1.2436 1.2079 0.8880 0.148 Uiso 1 1 calc R
C42 C 1.1248(8) 1.0720(6) 0.8807(5) 0.092(3) Uani 1 1 d .
C43 C 0.8238(11) 1.2064(8) 0.5684(8) 0.103(3) Uani 1 1 d .
H43 H 0.8709 1.2644 0.5616 0.123 Uiso 1 1 calc R
C44 C 0.7253(13) 1.1382(12) 0.5028(7) 0.121(4) Uani 1 1 d .
H44 H 0.7054 1.1496 0.4504 0.145 Uiso 1 1 calc R
C45 C 0.6538(10) 1.0526(10) 0.5111(7) 0.118(4) Uani 1 1 d .
H45 H 0.5860 1.0057 0.4654 0.142 Uiso 1 1 calc R
C46 C 0.9509(11) 1.1853(7) 0.8941(6) 0.126(4) Uani 1 1 d .
H46A H 0.9760 1.2455 0.9343 0.151 Uiso 1 1 calc R
H46B H 0.9142 1.1333 0.9162 0.151 Uiso 1 1 calc R
C47 C 1.3152(8) 1.4396(7) 0.9201(7) 0.099(3) Uani 1 1 d .
H47 H 1.3714 1.4470 0.9715 0.119 Uiso 1 1 calc R
C48 C 1.3213(9) 1.4085(8) 0.8482(9) 0.118(4) Uani 1 1 d .
H48 H 1.3821 1.3955 0.8497 0.142 Uiso 1 1 calc R
C49 C 1.2378(9) 1.3961(7) 0.7730(7) 0.108(3) Uani 1 1 d .
H49 H 1.2391 1.3714 0.7227 0.130 Uiso 1 1 calc R
C50 C 0.5938(9) 1.3318(7) 0.5275(6) 0.103(3) Uani 1 1 d .
H50 H 0.5654 1.3457 0.4772 0.124 Uiso 1 1 calc R
C51 C 0.5234(8) 1.2547(8) 0.5436(7) 0.107(3) Uani 1 1 d .
H51 H 0.4455 1.2159 0.5052 0.128 Uiso 1 1 calc R
C52 C 1.0515(10) 1.1840(6) 0.8914(7) 0.141(5) Uani 1 1 d .
H52A H 1.1189 1.2248 0.9443 0.169 Uiso 1 1 calc R
H52B H 1.0672 1.2092 0.8463 0.169 Uiso 1 1 calc R
C53 C 0.6711(7) 1.1815(5) 0.7627(6) 0.086(3) Uani 1 1 d .
H53A H 0.6401 1.1305 0.7114 0.103 Uiso 1 1 calc R
H53B H 0.6069 1.1755 0.7778 0.103 Uiso 1 1 calc R
C54 C 0.6855(7) 0.8965(5) 0.8861(5) 0.074(2) Uani 1 1 d .
H54 H 0.7337 0.9125 0.9429 0.088 Uiso 1 1 calc R
C55 C 0.6013(10) 0.9223(7) 0.8642(9) 0.118(4) Uani 1 1 d .
H55 H 0.5947 0.9591 0.9058 0.141 Uiso 1 1 calc R
C56 C 0.5395(12) 0.8496(12) 0.7245(10) 0.162(8) Uani 1 1 d .
H56 H 0.4884 0.8346 0.6686 0.195 Uiso 1 1 calc R
C57 C 0.6283(9) 0.8215(7) 0.7431(6) 0.103(3) Uani 1 1 d .
H57 H 0.6360 0.7872 0.7005 0.123 Uiso 1 1 calc R
C58 C 0.8552(8) 0.6457(7) 0.5121(6) 0.102(3) Uani 1 1 d .
H58A H 0.9335 0.6998 0.5311 0.123 Uiso 1 1 calc R
H58B H 0.7993 0.6645 0.4794 0.123 Uiso 1 1 calc R
C59 C 0.8460(10) 0.5623(9) 0.4580(6) 0.134(4) Uani 1 1 d .
H59A H 0.8968 0.5404 0.4912 0.201 Uiso 1 1 calc R
H59B H 0.8689 0.5809 0.4137 0.201 Uiso 1 1 calc R
H59C H 0.7663 0.5111 0.4338 0.201 Uiso 1 1 calc R
C60 C 0.5280(12) 0.8971(12) 0.7857(13) 0.161(9) Uani 1 1 d .
H60 H 0.4671 0.9126 0.7725 0.193 Uiso 1 1 calc R
N1 N 1.2707(5) 0.9473(4) 0.6937(4) 0.0642(15) Uani 1 1 d .
N2 N 0.8531(5) 0.8604(4) 0.6335(4) 0.0687(16) Uani 1 1 d .
N3 N 1.5125(6) 0.6423(5) 0.8493(5) 0.0762(18) Uani 1 1 d .
N4 N 1.3031(6) 0.7551(6) 0.9762(4) 0.0775(18) Uani 1 1 d .
N5 N 1.1724(5) 0.6637(4) 0.6663(3) 0.0535(13) Uani 1 1 d .
N6 N 0.5306(6) 0.5122(5) 0.6211(4) 0.0771(18) Uani 1 1 d .
N7 N 0.5025(6) 0.3085(4) 0.8073(5) 0.0747(18) Uani 1 1 d .
N8 N 0.8803(5) 0.5807(4) 0.8816(4) 0.0621(15) Uani 1 1 d .
N9 N 1.1066(7) 1.1498(5) 0.5853(5) 0.085(2) Uani 1 1 d .
N10 N 0.8594(6) 1.1756(4) 0.8138(4) 0.0752(17) Uani 1 1 d .
N11 N 0.9352(4) 1.4158(3) 0.7793(3) 0.0542(13) Uani 1 1 d .
H11 H 0.9024 1.3561 0.7785 0.065 Uiso 1 1 calc R
N12 N 0.9134(5) 0.9027(4) 0.8683(4) 0.0750(18) Uani 1 1 d .
H12 H 0.9246 0.9602 0.8862 0.090 Uiso 1 1 calc R
O1 O 0.7759(5) 0.8756(5) 0.5974(6) 0.148(3) Uani 1 1 d .
O2 O 0.8371(5) 0.7950(5) 0.6654(4) 0.103(2) Uani 1 1 d .
O3 O 1.0465(4) 0.8200(3) 0.6878(3) 0.0627(12) Uani 1 1 d .
O4 O 1.2592(5) 0.8709(4) 0.7022(5) 0.132(3) Uani 1 1 d .
O5 O 1.3653(4) 1.0125(4) 0.7039(4) 0.0940(18) Uani 1 1 d .
O6 O 1.5176(5) 0.6101(5) 0.7858(5) 0.107(2) Uani 1 1 d .
O7 O 1.5801(5) 0.6563(5) 0.9202(4) 0.108(2) Uani 1 1 d .
O8 O 1.2091(5) 0.6612(4) 0.6113(3) 0.0907(17) Uani 1 1 d .
O9 O 1.0743(4) 0.6538(3) 0.6519(3) 0.0602(11) Uani 1 1 d .
O10 O 1.2336(6) 0.6953(6) 0.9963(4) 0.130(3) Uani 1 1 d .
O11 O 1.3570(8) 0.8379(6) 1.0129(5) 0.142(3) Uani 1 1 d .
O12 O 0.5860(6) 0.5674(5) 0.5909(4) 0.133(3) Uani 1 1 d .
O13 O 0.4270(5) 0.4722(7) 0.5897(5) 0.158(4) Uani 1 1 d .
O14 O 0.4034(5) 0.2530(4) 0.7566(4) 0.111(2) Uani 1 1 d .
O15 O 0.5459(5) 0.3009(5) 0.8773(5) 0.127(3) Uani 1 1 d .
O16 O 0.9082(5) 0.5657(5) 0.9506(3) 0.116(2) Uani 1 1 d .
O17 O 0.9531(4) 0.6390(3) 0.8644(3) 0.0658(12) Uani 1 1 d .
O18 O 0.7764(4) 0.6198(3) 0.7238(3) 0.0603(11) Uani 1 1 d .
O19 O 0.8330(4) 0.6252(3) 0.5839(3) 0.0660(13) Uani 1 1 d .
O20 O 0.9224(4) 1.5262(3) 0.7130(3) 0.0589(11) Uani 1 1 d .
O21 O 0.9878(4) 0.8107(3) 0.8362(3) 0.0599(11) Uani 1 1 d .
O22 O 1.0232(7) 1.1631(5) 0.5575(5) 0.129(3) Uani 1 1 d .
O23 O 1.2023(6) 1.2017(5) 0.5882(5) 0.127(3) Uani 1 1 d .
O24 O 0.7274(4) 1.2745(3) 0.7506(3) 0.0624(12) Uani 1 1 d .
O25 O 1.0341(6) 1.0875(3) 0.8773(4) 0.112(2) Uani 1 1 d .
Tb1 Tb 0.96315(3) 0.69043(2) 0.73114(2) 0.04792(12) Uani 1 1 d .
H19 H 0.762(5) 0.608(4) 0.603(3) 0.050(16) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C18 O26 Tb1 140.8(4) . .
C3 C2 C28 119.7(6) . .
C3 C2 H2 120.2 . .
C28 C2 H2 120.2 . .
C2 C3 C4 123.0(6) . .
C2 C3 N1 116.7(5) . .
C4 C3 N1 120.3(5) . .
O3 C4 C20 123.8(5) . .
O3 C4 C3 122.5(6) . .
C20 C4 C3 113.7(5) . .
C21 C5 C15 122.8(6) . .
C21 C5 N7 117.3(6) . .
C15 C5 N7 120.0(6) . .
O20 C6 N11 121.8(6) . .
O20 C6 C8 118.9(5) . .
N11 C6 C8 119.3(5) . .
C15 C7 C11 123.4(6) . .
C15 C7 N6 116.7(6) . .
C11 C7 N6 119.9(6) . .
C22 C8 C19 117.9(6) . .
C22 C8 C6 117.9(6) . .
C19 C8 C6 124.1(6) . .
C31 C9 C37 117.9(7) . .
C31 C9 C16 123.4(6) . .
C37 C9 C16 118.7(6) . .
C29 C10 C18 124.3(6) . .
C29 C10 N4 118.9(6) . .
C18 C10 N4 116.8(6) . .
O18 C11 C23 124.3(6) . .
O18 C11 C7 122.1(6) . .
C23 C11 C7 113.6(5) . .
O21 C12 N12 120.3(6) . .
O21 C12 C17 119.9(6) . .
N12 C12 C17 119.8(6) . .
C14 C13 C18 123.2(6) . .
C14 C13 N5 117.1(5) . .
C18 C13 N5 119.7(5) . .
C24 C14 C13 119.1(6) . .
C24 C14 H14 120.4 . .
C13 C14 H14 120.4 . .
C7 C15 C5 118.6(6) . .
C7 C15 H15 120.7 . .
C5 C15 H15 120.7 . .
N11 C16 C9 113.6(5) . .
N11 C16 H16A 108.8 . .
C9 C16 H16A 108.8 . .
N11 C16 H16B 108.8 . .
C9 C16 H16B 108.8 . .
H16A C16 H16B 107.7 . .
C42 C17 C33 119.7(7) . .
C42 C17 C12 125.3(7) . .
C33 C17 C12 115.0(7) . .
O26 C18 C13 127.1(6) . .
O26 C18 C10 120.0(5) . .
C13 C18 C10 112.9(5) . .
O24 C19 C36 123.9(7) . .
O24 C19 C8 116.7(6) . .
C36 C19 C8 119.4(7) . .
C26 C20 C4 123.4(6) . .
C26 C20 N2 116.4(6) . .
C4 C20 N2 120.2(5) . .
C5 C21 C23 118.7(6) . .
C5 C21 H21 120.6 . .
C23 C21 H21 120.6 . .
C50 C22 C8 121.8(8) . .
C50 C22 H22 119.1 . .
C8 C22 H22 119.1 . .
C21 C23 C11 123.0(6) . .
C21 C23 N8 114.6(6) . .
C11 C23 N8 122.5(5) . .
C29 C24 C14 121.2(6) . .
C29 C24 N3 119.6(7) . .
C14 C24 N3 119.2(7) . .
C57 C25 C54 118.2(8) . .
C57 C25 C38 120.5(8) . .
C54 C25 C38 121.3(8) . .
C28 C26 C20 119.3(6) . .
C28 C26 H26 120.4 . .
C20 C26 H26 120.4 . .
C32 C27 C34 117.4(8) . .
C32 C27 C30 121.9(7) . .
C34 C27 C30 120.7(8) . .
C26 C28 C2 121.0(6) . .
C26 C28 N9 119.8(6) . .
C2 C28 N9 119.2(6) . .
C10 C29 C24 119.2(6) . .
C10 C29 H29 120.4 . .
C24 C29 H29 120.4 . .
N10 C30 C27 112.9(6) . .
N10 C30 H30A 109.0 . .
C27 C30 H30A 109.0 . .
N10 C30 H30B 109.0 . .
C27 C30 H30B 109.0 . .
H30A C30 H30B 107.8 . .
C9 C31 C49 121.1(8) . .
C9 C31 H31 119.5 . .
C49 C31 H31 119.5 . .
C27 C32 C43 123.6(9) . .
C27 C32 H32 118.2 . .
C43 C32 H32 118.2 . .
C17 C33 C39 120.3(9) . .
C17 C33 H33 119.9 . .
C39 C33 H33 119.9 . .
C27 C34 C45 120.9(9) . .
C27 C34 H34 119.6 . .
C45 C34 H34 119.6 . .
N10 C35 C53 114.5(7) . .
N10 C35 H35A 108.6 . .
C53 C35 H35A 108.6 . .
N10 C35 H35B 108.6 . .
C53 C35 H35B 108.6 . .
H35A C35 H35B 107.6 . .
C19 C36 C51 121.0(8) . .
C19 C36 H36 119.5 . .
C51 C36 H36 119.5 . .
C47 C37 C9 120.7(8) . .
C47 C37 H37 119.6 . .
C9 C37 H37 119.6 . .
C25 C38 N12 111.4(6) . .
C25 C38 H38A 109.4 . .
N12 C38 H38A 109.4 . .
C25 C38 H38B 109.4 . .
N12 C38 H38B 109.4 . .
H38A C38 H38B 108.0 . .
C40 C39 C33 119.0(11) . .
C40 C39 H39 120.5 . .
C33 C39 H39 120.5 . .
C41 C40 C39 122.5(10) . .
C41 C40 H40 118.7 . .
C39 C40 H40 118.7 . .
C40 C41 C42 119.5(11) . .
C40 C41 H41 120.2 . .
C42 C41 H41 120.2 . .
O25 C42 C17 118.5(7) . .
O25 C42 C41 122.8(9) . .
C17 C42 C41 118.7(10) . .
C44 C43 C32 118.8(10) . .
C44 C43 H43 120.6 . .
C32 C43 H43 120.6 . .
C43 C44 C45 121.9(11) . .
C43 C44 H44 119.1 . .
C45 C44 H44 119.1 . .
C44 C45 C34 117.4(10) . .
C44 C45 H45 121.3 . .
C34 C45 H45 121.3 . .
C52 C46 N10 117.7(9) . .
C52 C46 H46A 107.9 . .
N10 C46 H46A 107.9 . .
C52 C46 H46B 107.9 . .
N10 C46 H46B 107.9 . .
H46A C46 H46B 107.2 . .
C48 C47 C37 120.8(9) . .
C48 C47 H47 119.6 . .
C37 C47 H47 119.6 . .
C47 C48 C49 119.6(10) . .
C47 C48 H48 120.2 . .
C49 C48 H48 120.2 . .
C48 C49 C31 119.8(10) . .
C48 C49 H49 120.1 . .
C31 C49 H49 120.1 . .
C51 C50 C22 120.1(9) . .
C51 C50 H50 120.0 . .
C22 C50 H50 120.0 . .
C50 C51 C36 119.8(8) . .
C50 C51 H51 120.1 . .
C36 C51 H51 120.1 . .
C46 C52 O25 109.6(9) . .
C46 C52 H52A 109.7 . .
O25 C52 H52A 109.7 . .
C46 C52 H52B 109.7 . .
O25 C52 H52B 109.7 . .
H52A C52 H52B 108.2 . .
O24 C53 C35 106.4(6) . .
O24 C53 H53A 110.5 . .
C35 C53 H53A 110.5 . .
O24 C53 H53B 110.5 . .
C35 C53 H53B 110.5 . .
H53A C53 H53B 108.6 . .
C55 C54 C25 121.3(9) . .
C55 C54 H54 119.4 . .
C25 C54 H54 119.4 . .
C60 C55 C54 121.4(13) . .
C60 C55 H55 119.3 . .
C54 C55 H55 119.3 . .
C60 C56 C57 120.8(15) . .
C60 C56 H56 119.6 . .
C57 C56 H56 119.6 . .
C25 C57 C56 117.5(11) . .
C25 C57 H57 121.2 . .
C56 C57 H57 121.2 . .
O19 C58 C59 112.1(7) . .
O19 C58 H58A 109.2 . .
C59 C58 H58A 109.2 . .
O19 C58 H58B 109.2 . .
C59 C58 H58B 109.2 . .
H58A C58 H58B 107.9 . .
C58 C59 H59A 109.5 . .
C58 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C58 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C55 C60 C56 120.7(16) . .
C55 C60 H60 119.6 . .
C56 C60 H60 119.6 . .
O4 N1 O5 121.9(6) . .
O4 N1 C3 120.0(5) . .
O5 N1 C3 117.9(6) . .
O1 N2 O2 121.4(7) . .
O1 N2 C20 117.8(6) . .
O2 N2 C20 120.7(6) . .
O6 N3 O7 124.8(7) . .
O6 N3 C24 117.7(7) . .
O7 N3 C24 117.5(7) . .
O11 N4 O10 123.6(7) . .
O11 N4 C10 118.9(8) . .
O10 N4 C10 117.5(7) . .
O9 N5 O8 122.9(5) . .
O9 N5 C13 119.9(5) . .
O8 N5 C13 117.2(5) . .
O13 N6 O12 120.8(7) . .
O13 N6 C7 118.5(7) . .
O12 N6 C7 120.5(6) . .
O14 N7 O15 123.6(7) . .
O14 N7 C5 118.4(7) . .
O15 N7 C5 117.9(6) . .
O17 N8 O16 120.3(6) . .
O17 N8 C23 120.2(6) . .
O16 N8 C23 119.5(6) . .
O22 N9 O23 123.6(7) . .
O22 N9 C28 118.4(7) . .
O23 N9 C28 117.9(7) . .
C35 N10 C30 113.6(7) . .
C35 N10 C46 106.6(7) . .
C30 N10 C46 112.8(6) . .
C6 N11 C16 124.3(5) . .
C6 N11 H11 117.9 . .
C16 N11 H11 117.9 . .
C12 N12 C38 123.0(6) . .
C12 N12 H12 118.5 . .
C38 N12 H12 118.5 . .
C4 O3 Tb1 157.5(4) . .
N5 O9 Tb1 139.0(4) . .
N8 O17 Tb1 136.7(4) . .
C11 O18 Tb1 137.4(4) . .
C58 O19 Tb1 129.9(4) . .
C58 O19 H19 137(3) . .
Tb1 O19 H19 87(3) . .
C6 O20 Tb1 155.8(4) . 1_565
C12 O21 Tb1 147.9(4) . .
C19 O24 C53 120.0(6) . .
C42 O25 C52 118.9(8) . .
O3 Tb1 O26 86.96(15) . .
O3 Tb1 O18 126.94(15) . .
O26 Tb1 O18 139.71(15) . .
O3 Tb1 O21 80.59(16) . .
O26 Tb1 O21 83.37(15) . .
O18 Tb1 O21 82.04(15) . .
O3 Tb1 O20 141.69(16) . 1_545
O26 Tb1 O20 85.61(15) . 1_545
O18 Tb1 O20 79.08(15) . 1_545
O21 Tb1 O20 135.44(15) . 1_545
O3 Tb1 O19 81.25(16) . .
O26 Tb1 O19 140.53(16) . .
O18 Tb1 O19 73.39(16) . .
O21 Tb1 O19 130.73(16) . .
O20 Tb1 O19 80.98(15) 1_545 .
O3 Tb1 O9 72.16(15) . .
O26 Tb1 O9 67.84(14) . .
O18 Tb1 O9 137.01(16) . .
O21 Tb1 O9 140.80(15) . .
O20 Tb1 O9 70.22(14) 1_545 .
O19 Tb1 O9 72.69(15) . .
O3 Tb1 O17 142.54(16) . .
O26 Tb1 O17 72.45(14) . .
O18 Tb1 O17 67.28(15) . .
O21 Tb1 O17 66.50(15) . .
O20 Tb1 O17 68.99(14) 1_545 .
O19 Tb1 O17 133.88(15) . .
O9 Tb1 O17 124.08(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O26 C18 1.272(7) .
O26 Tb1 2.263(4) .
C2 C3 1.359(8) .
C2 C28 1.375(9) .
C2 H2 0.9300 .
C3 C4 1.436(8) .
C3 N1 1.459(8) .
C4 O3 1.267(7) .
C4 C20 1.417(8) .
C5 C21 1.364(8) .
C5 C15 1.369(8) .
C5 N7 1.463(8) .
C6 O20 1.253(7) .
C6 N11 1.313(7) .
C6 C8 1.497(8) .
C7 C15 1.360(8) .
C7 C11 1.445(8) .
C7 N6 1.447(8) .
C8 C22 1.378(9) .
C8 C19 1.401(9) .
C9 C31 1.346(9) .
C9 C37 1.382(9) .
C9 C16 1.492(9) .
C10 C29 1.362(9) .
C10 C18 1.428(8) .
C10 N4 1.455(8) .
C11 O18 1.262(6) .
C11 C23 1.425(8) .
C12 O21 1.240(7) .
C12 N12 1.306(8) .
C12 C17 1.488(9) .
C13 C14 1.388(8) .
C13 C18 1.417(8) .
C13 N5 1.465(7) .
C14 C24 1.371(9) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 N11 1.461(8) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C42 1.380(10) .
C17 C33 1.389(10) .
C19 O24 1.360(8) .
C19 C36 1.365(9) .
C20 C26 1.372(8) .
C20 N2 1.457(8) .
C21 C23 1.379(8) .
C21 H21 0.9300 .
C22 C50 1.369(11) .
C22 H22 0.9300 .
C23 N8 1.465(8) .
C24 C29 1.365(9) .
C24 N3 1.470(8) .
C25 C57 1.368(11) .
C25 C54 1.379(10) .
C25 C38 1.484(9) .
C26 C28 1.371(9) .
C26 H26 0.9300 .
C27 C32 1.347(10) .
C27 C34 1.375(10) .
C27 C30 1.511(10) .
C28 N9 1.460(8) .
C29 H29 0.9300 .
C30 N10 1.466(9) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 C49 1.400(12) .
C31 H31 0.9300 .
C32 C43 1.354(12) .
C32 H32 0.9300 .
C33 C39 1.389(11) .
C33 H33 0.9300 .
C34 C45 1.415(13) .
C34 H34 0.9300 .
C35 N10 1.448(10) .
C35 C53 1.503(12) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 C51 1.389(12) .
C36 H36 0.9300 .
C37 C47 1.380(11) .
C37 H37 0.9300 .
C38 N12 1.486(8) .
C38 H38A 0.9700 .
C38 H38B 0.9700 .
C39 C40 1.359(16) .
C39 H39 0.9300 .
C40 C41 1.341(16) .
C40 H40 0.9300 .
C41 C42 1.424(12) .
C41 H41 0.9300 .
C42 O25 1.346(11) .
C43 C44 1.345(14) .
C43 H43 0.9300 .
C44 C45 1.367(14) .
C44 H44 0.9300 .
C45 H45 0.9300 .
C46 C52 1.402(15) .
C46 N10 1.486(11) .
C46 H46A 0.9700 .
C46 H46B 0.9700 .
C47 C48 1.337(13) .
C47 H47 0.9300 .
C48 C49 1.360(14) .
C48 H48 0.9300 .
C49 H49 0.9300 .
C50 C51 1.339(13) .
C50 H50 0.9300 .
C51 H51 0.9300 .
C52 O25 1.425(10) .
C52 H52A 0.9700 .
C52 H52B 0.9700 .
C53 O24 1.434(7) .
C53 H53A 0.9700 .
C53 H53B 0.9700 .
C54 C55 1.332(11) .
C54 H54 0.9300 .
C55 C60 1.302(18) .
C55 H55 0.9300 .
C56 C60 1.33(2) .
C56 C57 1.414(17) .
C56 H56 0.9300 .
C57 H57 0.9300 .
C58 O19 1.427(9) .
C58 C59 1.467(13) .
C58 H58A 0.9700 .
C58 H58B 0.9700 .
C59 H59A 0.9600 .
C59 H59B 0.9600 .
C59 H59C 0.9600 .
C60 H60 0.9300 .
N1 O4 1.188(7) .
N1 O5 1.219(6) .
N2 O1 1.175(7) .
N2 O2 1.208(7) .
N3 O6 1.204(8) .
N3 O7 1.210(8) .
N4 O11 1.174(8) .
N4 O10 1.217(8) .
N5 O9 1.220(6) .
N5 O8 1.225(6) .
N6 O13 1.178(7) .
N6 O12 1.202(8) .
N7 O14 1.207(7) .
N7 O15 1.218(8) .
N8 O17 1.202(6) .
N8 O16 1.224(7) .
N9 O22 1.201(8) .
N9 O23 1.208(8) .
N11 H11 0.8600 .
N12 H12 0.8600 .
O3 Tb1 2.258(4) .
O9 Tb1 2.548(5) .
O17 Tb1 2.584(5) .
O18 Tb1 2.283(4) .
O19 Tb1 2.400(4) .
O19 H19 1.08(6) .
O20 Tb1 2.384(4) 1_565
O21 Tb1 2.319(4) .
Tb1 O20 2.384(4) 1_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C28 C2 C3 C4 -0.4(10) .
C28 C2 C3 N1 179.7(6) .
C2 C3 C4 O3 179.5(6) .
N1 C3 C4 O3 -0.6(9) .
C2 C3 C4 C20 -0.1(9) .
N1 C3 C4 C20 179.7(5) .
O20 C6 C8 C22 18.5(9) .
N11 C6 C8 C22 -160.0(6) .
O20 C6 C8 C19 -158.4(6) .
N11 C6 C8 C19 23.1(9) .
C15 C7 C11 O18 177.0(6) .
N6 C7 C11 O18 -6.3(9) .
C15 C7 C11 C23 -2.5(8) .
N6 C7 C11 C23 174.2(6) .
C18 C13 C14 C24 -1.0(9) .
N5 C13 C14 C24 -179.8(5) .
C11 C7 C15 C5 1.3(9) .
N6 C7 C15 C5 -175.5(6) .
C21 C5 C15 C7 0.9(9) .
N7 C5 C15 C7 -179.0(6) .
C31 C9 C16 N11 41.3(9) .
C37 C9 C16 N11 -140.6(6) .
O21 C12 C17 C42 165.0(7) .
N12 C12 C17 C42 -16.1(11) .
O21 C12 C17 C33 -13.5(9) .
N12 C12 C17 C33 165.4(7) .
Tb1 O26 C18 C13 25.2(10) .
Tb1 O26 C18 C10 -156.5(4) .
C14 C13 C18 O26 -178.6(5) .
N5 C13 C18 O26 0.1(9) .
C14 C13 C18 C10 2.9(8) .
N5 C13 C18 C10 -178.3(5) .
C29 C10 C18 O26 177.3(6) .
N4 C10 C18 O26 0.6(9) .
C29 C10 C18 C13 -4.1(9) .
N4 C10 C18 C13 179.2(6) .
C22 C8 C19 O24 -179.7(6) .
C6 C8 C19 O24 -2.8(9) .
C22 C8 C19 C36 -0.3(9) .
C6 C8 C19 C36 176.6(6) .
O3 C4 C20 C26 -179.3(6) .
C3 C4 C20 C26 0.3(9) .
O3 C4 C20 N2 1.0(10) .
C3 C4 C20 N2 -179.3(6) .
C15 C5 C21 C23 -1.5(9) .
N7 C5 C21 C23 178.4(5) .
C19 C8 C22 C50 0.5(11) .
C6 C8 C22 C50 -176.6(7) .
C5 C21 C23 C11 -0.1(9) .
C5 C21 C23 N8 178.9(5) .
O18 C11 C23 C21 -177.7(6) .
C7 C11 C23 C21 1.9(8) .
O18 C11 C23 N8 3.5(9) .
C7 C11 C23 N8 -176.9(5) .
C13 C14 C24 C29 -0.2(10) .
C13 C14 C24 N3 177.7(5) .
C4 C20 C26 C28 0.0(10) .
N2 C20 C26 C28 179.7(6) .
C20 C26 C28 C2 -0.5(10) .
C20 C26 C28 N9 178.6(6) .
C3 C2 C28 C26 0.7(10) .
C3 C2 C28 N9 -178.4(6) .
C18 C10 C29 C24 3.2(10) .
N4 C10 C29 C24 179.9(7) .
C14 C24 C29 C10 -0.9(10) .
N3 C24 C29 C10 -178.8(6) .
C32 C27 C30 N10 46.8(10) .
C34 C27 C30 N10 -134.8(8) .
C37 C9 C31 C49 1.0(11) .
C16 C9 C31 C49 179.1(7) .
C34 C27 C32 C43 2.0(11) .
C30 C27 C32 C43 -179.6(7) .
C42 C17 C33 C39 -1.0(11) .
C12 C17 C33 C39 177.6(7) .
C32 C27 C34 C45 -0.9(12) .
C30 C27 C34 C45 -179.4(8) .
O24 C19 C36 C51 178.6(7) .
C8 C19 C36 C51 -0.7(11) .
C31 C9 C37 C47 1.1(11) .
C16 C9 C37 C47 -177.1(7) .
C57 C25 C38 N12 101.1(9) .
C54 C25 C38 N12 -79.5(9) .
C17 C33 C39 C40 -3.0(13) .
C33 C39 C40 C41 3.0(17) .
C39 C40 C41 C42 0.9(18) .
C33 C17 C42 O25 -177.3(7) .
C12 C17 C42 O25 4.3(12) .
C33 C17 C42 C41 4.8(12) .
C12 C17 C42 C41 -173.7(7) .
C40 C41 C42 O25 177.3(9) .
C40 C41 C42 C17 -4.8(15) .
C27 C32 C43 C44 -1.9(14) .
C32 C43 C44 C45 0.7(16) .
C43 C44 C45 C34 0.3(16) .
C27 C34 C45 C44 -0.1(14) .
C9 C37 C47 C48 -1.1(14) .
C37 C47 C48 C49 -1.2(16) .
C47 C48 C49 C31 3.3(16) .
C9 C31 C49 C48 -3.2(14) .
C8 C22 C50 C51 0.4(14) .
C22 C50 C51 C36 -1.4(15) .
C19 C36 C51 C50 1.6(13) .
N10 C46 C52 O25 -91.6(11) .
N10 C35 C53 O24 -64.4(9) .
C57 C25 C54 C55 -1.9(11) .
C38 C25 C54 C55 178.7(7) .
C25 C54 C55 C60 3.6(15) .
C54 C25 C57 C56 0.7(12) .
C38 C25 C57 C56 -179.9(8) .
C60 C56 C57 C25 -1.1(19) .
C54 C55 C60 C56 -4(2) .
C57 C56 C60 C55 3(2) .
C2 C3 N1 O4 -167.1(8) .
C4 C3 N1 O4 13.0(10) .
C2 C3 N1 O5 9.5(9) .
C4 C3 N1 O5 -170.4(6) .
C26 C20 N2 O1 12.2(11) .
C4 C20 N2 O1 -168.1(8) .
C26 C20 N2 O2 -169.5(7) .
C4 C20 N2 O2 10.2(10) .
C29 C24 N3 O6 176.4(7) .
C14 C24 N3 O6 -1.5(10) .
C29 C24 N3 O7 -4.5(10) .
C14 C24 N3 O7 177.6(7) .
C29 C10 N4 O11 86.2(10) .
C18 C10 N4 O11 -96.8(9) .
C29 C10 N4 O10 -95.5(9) .
C18 C10 N4 O10 81.4(9) .
C14 C13 N5 O9 159.2(5) .
C18 C13 N5 O9 -19.7(8) .
C14 C13 N5 O8 -19.7(8) .
C18 C13 N5 O8 161.5(6) .
C15 C7 N6 O13 10.2(11) .
C11 C7 N6 O13 -166.7(8) .
C15 C7 N6 O12 -166.4(8) .
C11 C7 N6 O12 16.7(11) .
C21 C5 N7 O14 -172.3(7) .
C15 C5 N7 O14 7.6(10) .
C21 C5 N7 O15 10.6(10) .
C15 C5 N7 O15 -169.5(7) .
C21 C23 N8 O17 166.8(6) .
C11 C23 N8 O17 -14.3(9) .
C21 C23 N8 O16 -11.4(9) .
C11 C23 N8 O16 167.6(7) .
C26 C28 N9 O22 -2.9(12) .
C2 C28 N9 O22 176.2(8) .
C26 C28 N9 O23 179.8(8) .
C2 C28 N9 O23 -1.1(11) .
C53 C35 N10 C30 -64.5(8) .
C53 C35 N10 C46 170.5(7) .
C27 C30 N10 C35 90.0(8) .
C27 C30 N10 C46 -148.4(8) .
C52 C46 N10 C35 177.5(8) .
C52 C46 N10 C30 52.0(12) .
O20 C6 N11 C16 6.3(10) .
C8 C6 N11 C16 -175.3(5) .
C9 C16 N11 C6 -118.7(7) .
O21 C12 N12 C38 -3.4(11) .
C17 C12 N12 C38 177.7(7) .
C25 C38 N12 C12 -152.0(7) .
C20 C4 O3 Tb1 -18.4(15) .
C3 C4 O3 Tb1 162.0(8) .
O8 N5 O9 Tb1 -160.3(5) .
C13 N5 O9 Tb1 21.0(8) .
O16 N8 O17 Tb1 170.7(5) .
C23 N8 O17 Tb1 -7.5(9) .
C23 C11 O18 Tb1 36.0(9) .
C7 C11 O18 Tb1 -143.5(5) .
C59 C58 O19 Tb1 113.5(7) .
N11 C6 O20 Tb1 -98.5(10) 1_565
C8 C6 O20 Tb1 83.1(11) 1_565
N12 C12 O21 Tb1 108.6(8) .
C17 C12 O21 Tb1 -72.5(10) .
C36 C19 O24 C53 17.3(9) .
C8 C19 O24 C53 -163.4(6) .
C35 C53 O24 C19 158.5(6) .
C17 C42 O25 C52 174.5(8) .
C41 C42 O25 C52 -7.7(14) .
C46 C52 O25 C42 -173.6(9) .
C4 O3 Tb1 O26 -138.6(11) .
C4 O3 Tb1 O18 17.7(12) .
C4 O3 Tb1 O21 -54.8(11) .
C4 O3 Tb1 O20 142.4(11) 1_545
C4 O3 Tb1 O19 79.2(11) .
C4 O3 Tb1 O9 153.7(12) .
C4 O3 Tb1 O17 -83.1(11) .
C18 O26 Tb1 O3 -92.0(6) .
C18 O26 Tb1 O18 117.8(6) .
C18 O26 Tb1 O21 -172.9(6) .
C18 O26 Tb1 O20 50.4(6) 1_545
C18 O26 Tb1 O19 -19.7(7) .
C18 O26 Tb1 O9 -20.0(6) .
C18 O26 Tb1 O17 119.7(6) .
C11 O18 Tb1 O3 -178.2(5) .
C11 O18 Tb1 O26 -36.5(7) .
C11 O18 Tb1 O21 -106.4(6) .
C11 O18 Tb1 O20 33.1(6) 1_545
C11 O18 Tb1 O19 116.8(6) .
C11 O18 Tb1 O9 77.7(6) .
C11 O18 Tb1 O17 -38.6(6) .
C12 O21 Tb1 O3 24.4(8) .
C12 O21 Tb1 O26 112.4(8) .
C12 O21 Tb1 O18 -105.3(8) .
C12 O21 Tb1 O20 -170.8(7) 1_545
C12 O21 Tb1 O19 -45.4(8) .
C12 O21 Tb1 O9 70.4(8) .
C12 O21 Tb1 O17 -173.9(8) .
C58 O19 Tb1 O3 30.1(7) .
C58 O19 Tb1 O26 -44.2(7) .
C58 O19 Tb1 O18 163.0(7) .
C58 O19 Tb1 O21 99.6(7) .
C58 O19 Tb1 O20 -115.8(7) 1_545
C58 O19 Tb1 O9 -43.8(6) .
C58 O19 Tb1 O17 -164.8(6) .
N5 O9 Tb1 O3 89.5(6) .
N5 O9 Tb1 O26 -4.6(5) .
N5 O9 Tb1 O18 -145.0(5) .
N5 O9 Tb1 O21 41.3(7) .
N5 O9 Tb1 O20 -97.9(6) 1_545
N5 O9 Tb1 O19 175.6(6) .
N5 O9 Tb1 O17 -52.6(6) .
N8 O17 Tb1 O3 145.8(6) .
N8 O17 Tb1 O26 -154.5(6) .
N8 O17 Tb1 O18 24.1(6) .
N8 O17 Tb1 O21 115.2(6) .
N8 O17 Tb1 O20 -62.5(6) 1_545
N8 O17 Tb1 O19 -9.5(7) .
N8 O17 Tb1 O9 -108.2(6) .
