#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:08:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180413 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/82/7208287.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208287
loop_
_publ_author_name
'Liu, Qing-Xiang'
'Wang, Hong'
'Zhao, Xiao-Jun'
'Yao, Zhao-Quan'
'Wang, Zhi-Qiang'
'Chen, Ai-Hui'
'Wang, Xiu-Guang'
_publ_section_title
;
 N-Heterocyclic carbene silver(i), palladium(ii) and mercury(ii)
 complexes: synthesis, structural studies and catalytic activity
;
_journal_issue                   16
_journal_name_full               CrystEngComm
_journal_page_first              5330
_journal_paper_doi               10.1039/c2ce25365h
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C34 H34 Ag2 Cl2 N4 O2'
_chemical_formula_weight         817.29
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.3410(10)
_cell_angle_beta                 91.0380(10)
_cell_angle_gamma                108.9110(10)
_cell_formula_units_Z            2
_cell_length_a                   9.7774(6)
_cell_length_b                   11.1171(7)
_cell_length_c                   15.9735(10)
_cell_measurement_reflns_used    6058
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      0.00
_cell_measurement_theta_min      0.00
_cell_volume                     1597.40(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0137
_diffrn_reflns_av_sigmaI/netI    0.0218
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            8201
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.99
_exptl_absorpt_coefficient_mu    1.431
_exptl_absorpt_correction_T_max  0.773
_exptl_absorpt_correction_T_min  0.737
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLOURLESS
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             820
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.740
_refine_diff_density_min         -1.797
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     419
_refine_ls_number_reflns         5615
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0384P)²+3.0699P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0908
_refine_ls_wR_factor_ref         0.0953
_reflns_number_gt                4964
_reflns_number_total             5640
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25365h.txt
_cod_data_source_block           90509c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7208287
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.72508(3) 0.15390(3) 0.706070(19) 0.04601(11) Uani 1 1 d . . .
Ag2 Ag 0.43906(6) 0.05170(7) 0.59936(3) 0.1084(2) Uani 1 1 d U . .
C1 C 0.9733(4) 0.5591(4) 0.7246(3) 0.0443(9) Uani 1 1 d . A .
C2 C 0.8770(4) 0.5767(3) 0.7843(2) 0.0372(8) Uani 1 1 d . A .
C3 C 0.8775(5) 0.7009(4) 0.8244(3) 0.0461(9) Uani 1 1 d . . .
H3 H 0.8113 0.7132 0.8636 0.055 Uiso 1 1 calc R . .
C4 C 0.9811(5) 0.8046(4) 0.8032(3) 0.0568(11) Uani 1 1 d . . .
H4 H 0.9837 0.8890 0.8281 0.068 Uiso 1 1 calc R . .
C5 C 1.0816(5) 0.7876(4) 0.7459(3) 0.0612(12) Uani 1 1 d . . .
H5 H 1.1517 0.8608 0.7351 0.073 Uiso 1 1 calc R . .
C6 C 1.0802(5) 0.6651(4) 0.7045(3) 0.0593(11) Uani 1 1 d . . .
H6 H 1.1466 0.6534 0.6654 0.071 Uiso 1 1 calc R . .
C7 C 0.8237(4) 0.3586(3) 0.7326(2) 0.0415(8) Uani 1 1 d . A .
C8 C 1.0288(19) 0.371(2) 0.6347(8) 0.067(6) Uani 0.494(13) 1 d PD A 1
H8A H 1.0062 0.2787 0.6315 0.081 Uiso 0.494(13) 1 calc PR A 1
H8B H 1.1305 0.4157 0.6554 0.081 Uiso 0.494(13) 1 calc PR A 1
C9 C 0.9994(15) 0.3931(15) 0.5474(7) 0.103(5) Uani 0.494(13) 1 d PD A 1
H9A H 0.8965 0.3673 0.5335 0.154 Uiso 0.494(13) 1 calc PR A 1
H9B H 1.0392 0.3419 0.5051 0.154 Uiso 0.494(13) 1 calc PR A 1
H9C H 1.0437 0.4840 0.5479 0.154 Uiso 0.494(13) 1 calc PR A 1
C8' C 0.9803(17) 0.354(2) 0.6155(7) 0.056(4) Uani 0.506(13) 1 d PD A 2
H8'1 H 1.0048 0.4082 0.5742 0.068 Uiso 0.506(13) 1 calc PR A 2
H8'2 H 0.9018 0.2741 0.5891 0.068 Uiso 0.506(13) 1 calc PR A 2
C9' C 1.1099(14) 0.3230(17) 0.6429(8) 0.107(6) Uani 0.506(13) 1 d PD A 2
H9'1 H 1.1858 0.4026 0.6702 0.160 Uiso 0.506(13) 1 calc PR A 2
H9'2 H 1.1435 0.2790 0.5934 0.160 Uiso 0.506(13) 1 calc PR A 2
H9'3 H 1.0835 0.2676 0.6828 0.160 Uiso 0.506(13) 1 calc PR A 2
C10 C 0.6706(4) 0.4256(3) 0.8443(2) 0.0371(8) Uani 1 1 d . A .
H10A H 0.6191 0.3322 0.8313 0.045 Uiso 1 1 calc R . .
H10B H 0.6028 0.4674 0.8304 0.045 Uiso 1 1 calc R . .
C11 C 0.7174(3) 0.4719(3) 0.9395(2) 0.0327(7) Uani 1 1 d . . .
C12 C 0.7992(4) 0.4148(3) 0.9803(2) 0.0333(7) Uani 1 1 d . . .
C13 C 0.8357(4) 0.4545(3) 1.0688(2) 0.0398(8) Uani 1 1 d . . .
H13 H 0.8922 0.4176 1.0953 0.048 Uiso 1 1 calc R . .
C14 C 0.7875(4) 0.5490(4) 1.1173(3) 0.0454(9) Uani 1 1 d . . .
H14 H 0.8107 0.5746 1.1766 0.055 Uiso 1 1 calc R . .
C15 C 0.7057(4) 0.6056(4) 1.0786(3) 0.0463(9) Uani 1 1 d . . .
H15 H 0.6730 0.6688 1.1114 0.056 Uiso 1 1 calc R . .
C16 C 0.6725(4) 0.5675(4) 0.9903(3) 0.0417(8) Uani 1 1 d . . .
H16 H 0.6186 0.6070 0.9643 0.050 Uiso 1 1 calc R . .
C17 C 0.9186(4) 0.2567(3) 0.9668(2) 0.0359(8) Uani 1 1 d . . .
H17A H 0.8694 0.2237 1.0136 0.043 Uiso 1 1 calc R . .
H17B H 1.0140 0.3186 0.9898 0.043 Uiso 1 1 calc R . .
C18 C 0.9326(4) 0.1465(3) 0.8989(3) 0.0377(8) Uani 1 1 d . . .
H18A H 0.9785 0.1810 0.8517 0.045 Uiso 1 1 calc R . .
H18B H 0.9952 0.1076 0.9228 0.045 Uiso 1 1 calc R . .
C19 C 0.7172(4) -0.0224(3) 0.9207(2) 0.0319(7) Uani 1 1 d . . .
C20 C 0.5715(4) -0.0896(3) 0.8916(2) 0.0333(7) Uani 1 1 d . . .
C21 C 0.4859(4) -0.1611(3) 0.9440(3) 0.0416(8) Uani 1 1 d . . .
H21 H 0.3889 -0.2083 0.9251 0.050 Uiso 1 1 calc R . .
C22 C 0.5399(5) -0.1647(4) 1.0235(3) 0.0465(9) Uani 1 1 d . . .
H22 H 0.4795 -0.2123 1.0580 0.056 Uiso 1 1 calc R . .
C23 C 0.6837(4) -0.0972(4) 1.0513(3) 0.0444(9) Uani 1 1 d . . .
H23 H 0.7208 -0.0987 1.1050 0.053 Uiso 1 1 calc R . .
C24 C 0.7732(4) -0.0272(3) 0.9997(2) 0.0389(8) Uani 1 1 d . . .
H24 H 0.8711 0.0167 1.0181 0.047 Uiso 1 1 calc R . .
C25 C 0.5072(4) -0.0774(4) 0.8085(2) 0.0395(8) Uani 1 1 d . . .
H25A H 0.4035 -0.1247 0.8019 0.047 Uiso 1 1 calc R . .
H25B H 0.5206 0.0139 0.8120 0.047 Uiso 1 1 calc R . .
C26 C 0.6565(4) -0.0518(3) 0.6849(2) 0.0386(8) Uani 1 1 d . . .
C27 C 0.5577(4) -0.2584(3) 0.7025(2) 0.0400(8) Uani 1 1 d . . .
C28 C 0.4810(5) -0.3709(4) 0.7286(3) 0.0511(10) Uani 1 1 d . . .
H28 H 0.4243 -0.3685 0.7746 0.061 Uiso 1 1 calc R . .
C29 C 0.4932(6) -0.4870(4) 0.6826(3) 0.0623(13) Uani 1 1 d . . .
H29 H 0.4437 -0.5645 0.6982 0.075 Uiso 1 1 calc R . .
C30 C 0.5772(6) -0.4906(4) 0.6140(3) 0.0668(14) Uani 1 1 d . . .
H30 H 0.5835 -0.5704 0.5851 0.080 Uiso 1 1 calc R . .
C31 C 0.6520(6) -0.3792(4) 0.5871(3) 0.0604(12) Uani 1 1 d . . .
H31 H 0.7074 -0.3822 0.5405 0.072 Uiso 1 1 calc R . .
C32 C 0.6403(4) -0.2624(4) 0.6332(2) 0.0443(9) Uani 1 1 d . . .
C33 C 0.7993(5) -0.0924(5) 0.5616(3) 0.0554(11) Uani 1 1 d . . .
H33A H 0.7984 -0.0086 0.5535 0.066 Uiso 1 1 calc R . .
H33B H 0.7681 -0.1553 0.5067 0.066 Uiso 1 1 calc R . .
C34 C 0.9511(6) -0.0805(7) 0.5907(4) 0.092(2) Uani 1 1 d . . .
H34A H 0.9505 -0.1605 0.6046 0.137 Uiso 1 1 calc R . .
H34B H 0.9872 -0.0098 0.6408 0.137 Uiso 1 1 calc R . .
H34C H 1.0127 -0.0635 0.5454 0.137 Uiso 1 1 calc R . .
Cl1 Cl 0.34534(16) 0.15021(12) 0.72279(8) 0.0717(3) Uani 1 1 d . . .
Cl2 Cl 0.37225(17) -0.17128(14) 0.49889(10) 0.0829(4) Uani 1 1 d . . .
N1 N 0.9366(4) 0.4238(3) 0.6938(2) 0.0516(9) Uani 1 1 d D . .
N2 N 0.7889(3) 0.4518(3) 0.78888(19) 0.0346(6) Uani 1 1 d . . .
N3 N 0.5709(3) -0.1273(3) 0.73246(19) 0.0372(7) Uani 1 1 d . . .
N4 N 0.6986(4) -0.1339(3) 0.6241(2) 0.0425(7) Uani 1 1 d . . .
O1 O 0.8367(3) 0.3188(2) 0.92757(16) 0.0382(5) Uani 1 1 d . . .
O2 O 0.7966(3) 0.0477(2) 0.86637(16) 0.0382(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C7 Ag1 C26 171.61(15) . .
C7 Ag1 Ag2 114.40(11) . .
C26 Ag1 Ag2 73.65(10) . .
Cl1 Ag2 Cl2 136.41(6) . .
Cl1 Ag2 Cl2 127.62(5) . 2_656
Cl2 Ag2 Cl2 94.79(5) . 2_656
Cl1 Ag2 Ag1 86.49(4) . .
Cl2 Ag2 Ag1 117.61(4) . .
Cl2 Ag2 Ag1 75.19(4) 2_656 .
C2 C1 N1 106.2(3) . .
C2 C1 C6 121.7(4) . .
N1 C1 C6 132.1(4) . .
C1 C2 C3 121.4(3) . .
C1 C2 N2 106.2(3) . .
C3 C2 N2 132.3(4) . .
C4 C3 C2 116.5(4) . .
C4 C3 H3 121.7 . .
C2 C3 H3 121.7 . .
C3 C4 C5 122.3(4) . .
C3 C4 H4 118.9 . .
C5 C4 H4 118.9 . .
C6 C5 C4 121.6(4) . .
C6 C5 H5 119.2 . .
C4 C5 H5 119.2 . .
C5 C6 C1 116.4(4) . .
C5 C6 H6 121.8 . .
C1 C6 H6 121.8 . .
N1 C7 N2 105.7(3) . .
N1 C7 Ag1 125.4(3) . .
N2 C7 Ag1 128.9(3) . .
N1 C8 C9 107.9(9) . .
N1 C8 H8A 110.1 . .
C9 C8 H8A 110.1 . .
N1 C8 H8B 110.1 . .
C9 C8 H8B 110.1 . .
H8A C8 H8B 108.4 . .
N1 C8' C9' 106.7(9) . .
N1 C8' H8'1 110.4 . .
C9' C8' H8'1 110.4 . .
N1 C8' H8'2 110.4 . .
C9' C8' H8'2 110.4 . .
H8'1 C8' H8'2 108.6 . .
C8' C9' H9'1 109.5 . .
C8' C9' H9'2 109.5 . .
H9'1 C9' H9'2 109.5 . .
C8' C9' H9'3 109.5 . .
H9'1 C9' H9'3 109.5 . .
H9'2 C9' H9'3 109.5 . .
N2 C10 C11 114.8(3) . .
N2 C10 H10A 108.6 . .
C11 C10 H10A 108.6 . .
N2 C10 H10B 108.6 . .
C11 C10 H10B 108.6 . .
H10A C10 H10B 107.5 . .
C16 C11 C12 117.8(3) . .
C16 C11 C10 120.6(3) . .
C12 C11 C10 121.4(3) . .
O1 C12 C13 124.0(3) . .
O1 C12 C11 115.3(3) . .
C13 C12 C11 120.7(3) . .
C14 C13 C12 119.7(4) . .
C14 C13 H13 120.2 . .
C12 C13 H13 120.2 . .
C15 C14 C13 120.6(4) . .
C15 C14 H14 119.7 . .
C13 C14 H14 119.7 . .
C14 C15 C16 119.3(4) . .
C14 C15 H15 120.4 . .
C16 C15 H15 120.4 . .
C15 C16 C11 121.9(4) . .
C15 C16 H16 119.0 . .
C11 C16 H16 119.0 . .
O1 C17 C18 107.5(3) . .
O1 C17 H17A 110.2 . .
C18 C17 H17A 110.2 . .
O1 C17 H17B 110.2 . .
C18 C17 H17B 110.2 . .
H17A C17 H17B 108.5 . .
O2 C18 C17 113.0(3) . .
O2 C18 H18A 109.0 . .
C17 C18 H18A 109.0 . .
O2 C18 H18B 109.0 . .
C17 C18 H18B 109.0 . .
H18A C18 H18B 107.8 . .
O2 C19 C24 124.1(3) . .
O2 C19 C20 115.2(3) . .
C24 C19 C20 120.7(3) . .
C21 C20 C19 117.7(3) . .
C21 C20 C25 121.1(3) . .
C19 C20 C25 121.1(3) . .
C22 C21 C20 122.1(4) . .
C22 C21 H21 119.0 . .
C20 C21 H21 119.0 . .
C23 C22 C21 119.4(3) . .
C23 C22 H22 120.3 . .
C21 C22 H22 120.3 . .
C22 C23 C24 120.1(4) . .
C22 C23 H23 119.9 . .
C24 C23 H23 119.9 . .
C23 C24 C19 120.0(3) . .
C23 C24 H24 120.0 . .
C19 C24 H24 120.0 . .
N3 C25 C20 113.6(3) . .
N3 C25 H25A 108.8 . .
C20 C25 H25A 108.8 . .
N3 C25 H25B 108.8 . .
C20 C25 H25B 108.8 . .
H25A C25 H25B 107.7 . .
N3 C26 N4 105.9(3) . .
N3 C26 Ag1 127.5(3) . .
N4 C26 Ag1 126.5(3) . .
C32 C27 C28 121.7(4) . .
C32 C27 N3 105.7(3) . .
C28 C27 N3 132.6(4) . .
C29 C28 C27 116.6(4) . .
C29 C28 H28 121.7 . .
C27 C28 H28 121.7 . .
C30 C29 C28 121.6(4) . .
C30 C29 H29 119.2 . .
C28 C29 H29 119.2 . .
C31 C30 C29 121.9(4) . .
C31 C30 H30 119.0 . .
C29 C30 H30 119.0 . .
C30 C31 C32 116.7(4) . .
C30 C31 H31 121.7 . .
C32 C31 H31 121.7 . .
C27 C32 C31 121.4(4) . .
C27 C32 N4 106.3(3) . .
C31 C32 N4 132.2(4) . .
N4 C33 C34 111.3(4) . .
N4 C33 H33A 109.4 . .
C34 C33 H33A 109.4 . .
N4 C33 H33B 109.4 . .
C34 C33 H33B 109.4 . .
H33A C33 H33B 108.0 . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
Ag2 Cl2 Ag2 85.21(5) . 2_656
C7 N1 C1 110.9(3) . .
C7 N1 C8' 119.5(9) . .
C1 N1 C8' 127.7(9) . .
C7 N1 C8 128.9(10) . .
C1 N1 C8 119.8(10) . .
C8' N1 C8 20.2(9) . .
C7 N2 C2 111.0(3) . .
C7 N2 C10 124.7(3) . .
C2 N2 C10 124.3(3) . .
C26 N3 C27 111.3(3) . .
C26 N3 C25 124.5(3) . .
C27 N3 C25 124.2(3) . .
C26 N4 C32 110.8(3) . .
C26 N4 C33 124.4(3) . .
C32 N4 C33 124.7(3) . .
C12 O1 C17 117.2(3) . .
C19 O2 C18 119.3(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C7 2.107(4) .
Ag1 C26 2.112(3) .
Ag1 Ag2 2.9928(6) .
Ag2 Cl1 2.3916(14) .
Ag2 Cl2 2.5217(15) .
Ag2 Cl2 2.6533(18) 2_656
C1 C2 1.380(5) .
C1 N1 1.400(5) .
C1 C6 1.400(6) .
C2 C3 1.391(5) .
C2 N2 1.395(4) .
C3 C4 1.376(6) .
C3 H3 0.9300 .
C4 C5 1.385(7) .
C4 H4 0.9300 .
C5 C6 1.376(7) .
C5 H5 0.9300 .
C6 H6 0.9300 .
C7 N1 1.352(5) .
C7 N2 1.357(5) .
C8 N1 1.476(9) .
C8 C9 1.504(10) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C8' N1 1.473(9) .
C8' C9' 1.497(10) .
C8' H8'1 0.9700 .
C8' H8'2 0.9700 .
C9' H9'1 0.9600 .
C9' H9'2 0.9600 .
C9' H9'3 0.9600 .
C10 N2 1.461(5) .
C10 C11 1.508(5) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C16 1.389(5) .
C11 C12 1.398(5) .
C12 O1 1.365(4) .
C12 C13 1.392(5) .
C13 C14 1.382(5) .
C13 H13 0.9300 .
C14 C15 1.376(6) .
C14 H14 0.9300 .
C15 C16 1.383(6) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 O1 1.426(4) .
C17 C18 1.497(5) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 O2 1.424(4) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 O2 1.372(4) .
C19 C24 1.386(5) .
C19 C20 1.394(5) .
C20 C21 1.384(5) .
C20 C25 1.508(5) .
C21 C22 1.380(6) .
C21 H21 0.9300 .
C22 C23 1.374(6) .
C22 H22 0.9300 .
C23 C24 1.382(5) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 N3 1.461(5) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 N3 1.350(5) .
C26 N4 1.350(5) .
C27 C32 1.385(6) .
C27 C28 1.388(5) .
C27 N3 1.396(4) .
C28 C29 1.385(6) .
C28 H28 0.9300 .
C29 C30 1.383(7) .
C29 H29 0.9300 .
C30 C31 1.379(7) .
C30 H30 0.9300 .
C31 C32 1.390(6) .
C31 H31 0.9300 .
C32 N4 1.397(5) .
C33 N4 1.455(5) .
C33 C34 1.503(7) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
Cl2 Ag2 2.6534(18) 2_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 Ag1 Ag2 Cl1 -70.02(12) . .
C26 Ag1 Ag2 Cl1 112.49(11) . .
C7 Ag1 Ag2 Cl2 148.10(12) . .
C26 Ag1 Ag2 Cl2 -29.40(12) . .
C7 Ag1 Ag2 Cl2 60.43(12) . 2_656
C26 Ag1 Ag2 Cl2 -117.06(11) . 2_656
N1 C1 C2 C3 -176.4(3) . .
C6 C1 C2 C3 3.0(6) . .
N1 C1 C2 N2 1.6(4) . .
C6 C1 C2 N2 -179.1(4) . .
C1 C2 C3 C4 -1.6(6) . .
N2 C2 C3 C4 -179.0(4) . .
C2 C3 C4 C5 -1.0(6) . .
C3 C4 C5 C6 2.3(7) . .
C4 C5 C6 C1 -1.0(7) . .
C2 C1 C6 C5 -1.6(6) . .
N1 C1 C6 C5 177.5(4) . .
C26 Ag1 C7 N1 59.7(11) . .
Ag2 Ag1 C7 N1 -103.6(3) . .
C26 Ag1 C7 N2 -121.6(9) . .
Ag2 Ag1 C7 N2 75.1(3) . .
N2 C10 C11 C16 116.8(3) . .
N2 C10 C11 C12 -67.3(4) . .
C16 C11 C12 O1 178.2(3) . .
C10 C11 C12 O1 2.1(4) . .
C16 C11 C12 C13 -0.9(5) . .
C10 C11 C12 C13 -177.0(3) . .
O1 C12 C13 C14 -177.4(3) . .
C11 C12 C13 C14 1.6(5) . .
C12 C13 C14 C15 -1.0(5) . .
C13 C14 C15 C16 -0.4(6) . .
C14 C15 C16 C11 1.1(6) . .
C12 C11 C16 C15 -0.4(5) . .
C10 C11 C16 C15 175.6(3) . .
O1 C17 C18 O2 -63.7(4) . .
O2 C19 C20 C21 -179.5(3) . .
C24 C19 C20 C21 -0.3(5) . .
O2 C19 C20 C25 -3.5(4) . .
C24 C19 C20 C25 175.7(3) . .
C19 C20 C21 C22 1.5(5) . .
C25 C20 C21 C22 -174.5(3) . .
C20 C21 C22 C23 -1.2(6) . .
C21 C22 C23 C24 -0.4(6) . .
C22 C23 C24 C19 1.5(5) . .
O2 C19 C24 C23 177.9(3) . .
C20 C19 C24 C23 -1.2(5) . .
C21 C20 C25 N3 -120.5(4) . .
C19 C20 C25 N3 63.6(4) . .
C7 Ag1 C26 N3 108.2(10) . .
Ag2 Ag1 C26 N3 -87.6(3) . .
C7 Ag1 C26 N4 -66.5(11) . .
Ag2 Ag1 C26 N4 97.7(3) . .
C32 C27 C28 C29 1.0(6) . .
N3 C27 C28 C29 179.7(4) . .
C27 C28 C29 C30 -0.2(6) . .
C28 C29 C30 C31 -0.7(7) . .
C29 C30 C31 C32 0.8(7) . .
C28 C27 C32 C31 -1.0(6) . .
N3 C27 C32 C31 -180.0(4) . .
C28 C27 C32 N4 178.6(4) . .
N3 C27 C32 N4 -0.4(4) . .
C30 C31 C32 C27 0.1(6) . .
C30 C31 C32 N4 -179.4(4) . .
Cl1 Ag2 Cl2 Ag2 167.53(6) . 2_656
Cl2 Ag2 Cl2 Ag2 0.0 2_656 2_656
Ag1 Ag2 Cl2 Ag2 -75.78(5) . 2_656
N2 C7 N1 C1 -0.6(4) . .
Ag1 C7 N1 C1 178.4(3) . .
N2 C7 N1 C8' -166.4(8) . .
Ag1 C7 N1 C8' 12.6(9) . .
N2 C7 N1 C8 171.9(8) . .
Ag1 C7 N1 C8 -9.1(10) . .
C2 C1 N1 C7 -0.7(5) . .
C6 C1 N1 C7 -179.9(4) . .
C2 C1 N1 C8' 163.6(8) . .
C6 C1 N1 C8' -15.6(10) . .
C2 C1 N1 C8 -173.9(7) . .
C6 C1 N1 C8 6.8(9) . .
C9' C8' N1 C7 -100.6(13) . .
C9' C8' N1 C1 96.3(14) . .
C9' C8' N1 C8 23(4) . .
C9 C8 N1 C7 112.8(13) . .
C9 C8 N1 C1 -75.2(15) . .
C9 C8 N1 C8' 44(4) . .
N1 C7 N2 C2 1.6(4) . .
Ag1 C7 N2 C2 -177.2(3) . .
N1 C7 N2 C10 179.0(3) . .
Ag1 C7 N2 C10 0.1(5) . .
C1 C2 N2 C7 -2.1(4) . .
C3 C2 N2 C7 175.6(4) . .
C1 C2 N2 C10 -179.5(3) . .
C3 C2 N2 C10 -1.8(6) . .
C11 C10 N2 C7 118.3(4) . .
C11 C10 N2 C2 -64.6(4) . .
N4 C26 N3 C27 0.1(4) . .
Ag1 C26 N3 C27 -175.5(3) . .
N4 C26 N3 C25 176.7(3) . .
Ag1 C26 N3 C25 1.2(5) . .
C32 C27 N3 C26 0.2(4) . .
C28 C27 N3 C26 -178.6(4) . .
C32 C27 N3 C25 -176.5(3) . .
C28 C27 N3 C25 4.7(6) . .
C20 C25 N3 C26 -110.5(4) . .
C20 C25 N3 C27 65.7(4) . .
N3 C26 N4 C32 -0.3(4) . .
Ag1 C26 N4 C32 175.3(3) . .
N3 C26 N4 C33 -176.3(3) . .
Ag1 C26 N4 C33 -0.6(5) . .
C27 C32 N4 C26 0.4(4) . .
C31 C32 N4 C26 180.0(4) . .
C27 C32 N4 C33 176.4(4) . .
C31 C32 N4 C33 -4.1(7) . .
C34 C33 N4 C26 96.8(5) . .
C34 C33 N4 C32 -78.6(6) . .
C13 C12 O1 C17 -0.2(5) . .
C11 C12 O1 C17 -179.2(3) . .
C18 C17 O1 C12 173.9(3) . .
C24 C19 O2 C18 -16.3(5) . .
C20 C19 O2 C18 162.9(3) . .
C17 C18 O2 C19 -63.8(4) . .
