#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:14:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180418 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/87/7208773.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208773
loop_
_publ_author_name
'Kyprianidou, Eleni J.'
'Papaefstathiou, Giannis S.'
'Manos, Manolis J.'
'Tasiopoulos, Anastasios J.'
_publ_section_title
;
 A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected
 topology, unprecedented secondary building units and single crystal to
 single crystal solvent exchange properties
;
_journal_issue                   24
_journal_name_full               CrystEngComm
_journal_page_first              8368
_journal_paper_doi               10.1039/c2ce25913c
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C41 H33 Cd3 N5 O15, 4.5(C6 H6)'
_chemical_formula_sum            'C68 H60 Cd3 N5 O15'
_chemical_formula_weight         1524.41
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.172(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   35.319(3)
_cell_length_b                   18.2332(10)
_cell_length_c                   23.452(2)
_cell_measurement_reflns_used    9049
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.0063
_cell_measurement_theta_min      2.9532
_cell_volume                     13056(2)
_computing_cell_refinement       'CrysAlis RED'
_computing_data_collection       'CrysAlis CCD'
_computing_data_reduction        'CrysAlis RED'
_computing_molecular_graphics
;
DIAMOND (Brandenburg, 2006)
MERCURY (Bruno et al. 2002)
;
_computing_publication_material  'WINGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4223
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0403
_diffrn_reflns_av_sigmaI/netI    0.0434
_diffrn_reflns_limit_h_max       42
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            31147
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.96
_exptl_absorpt_coefficient_mu    1.038
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.71298
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Empirical absorption correction (CrysAlis RED, Oxford Diffraction)'
_exptl_crystal_colour            'light brown'
_exptl_crystal_density_diffrn    1.551
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedral
_exptl_crystal_F_000             6136
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.341
_refine_diff_density_min         -0.911
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     841
_refine_ls_number_reflns         11471
_refine_ls_number_restraints     307
_refine_ls_restrained_S_all      1.098
_refine_ls_R_factor_all          0.0829
_refine_ls_R_factor_gt           0.0694
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0926P)²+156.9655P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1849
_refine_ls_wR_factor_ref         0.1926
_reflns_number_gt                9476
_reflns_number_total             11471
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25913c.txt
_cod_data_source_block           UCY-3-benzene
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        13057(2)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7208773
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.4088(2) 0.8505(6) 0.5900(4) 0.061(2) Uani 1 1 d . . .
N2 N 0.6104(2) 0.6659(3) 0.6218(3) 0.0491(18) Uani 1 1 d . . .
N3 N 0.3781(5) 0.3297(8) 0.5432(8) 0.153(7) Uani 1 1 d . . .
N4 N 0.3989(3) 0.6724(5) 0.6549(4) 0.081(3) Uani 1 1 d . . .
N5 N 0.2596(3) 0.4710(5) 0.1645(4) 0.066(2) Uani 1 1 d . . .
O1 O 0.3554(3) 0.8450(5) 0.7563(5) 0.0440(19) Uani 0.70 1 d PU . .
O1A O 0.3549(7) 0.8743(15) 0.7933(14) 0.073(7) Uani 0.30 1 d PU . .
O2 O 0.3648(3) 0.9451(6) 0.7141(5) 0.059(2) Uani 0.75 1 d PU . .
O2A O 0.6405(9) 0.881(2) 0.7911(16) 0.080(10) Uani 0.25 1 d PU . .
O3 O 0.21884(17) 0.9107(3) 0.4905(3) 0.0431(12) Uani 1 1 d . . .
O4 O 0.27376(19) 0.9504(3) 0.5868(3) 0.0458(13) Uani 1 1 d . . .
O5 O 0.31287(15) 0.6610(3) 0.4207(2) 0.0375(12) Uani 1 1 d . A .
O6 O 0.24436(15) 0.7024(3) 0.3800(2) 0.0364(11) Uani 1 1 d . . .
O7 O 0.38167(17) 0.5356(3) 0.4537(3) 0.0495(15) Uani 1 1 d . . .
O8 O 0.38817(17) 0.6216(3) 0.3924(3) 0.0509(15) Uani 1 1 d . . .
O9 O 0.21847(16) 0.9694(3) 0.6452(2) 0.0367(11) Uani 1 1 d . . .
O10 O 0.28268(16) 1.0093(3) 0.7227(3) 0.0404(12) Uani 1 1 d . . .
O11 O 0.29669(16) 0.7315(3) 0.2897(3) 0.0517(15) Uani 1 1 d . . .
O12 O 0.26098(15) 0.8413(3) 0.7469(2) 0.0356(11) Uani 1 1 d . . .
O13 O 0.3320(3) 0.4301(3) 0.5014(4) 0.0670(18) Uani 1 1 d . . .
O14 O 0.3785(2) 0.5946(4) 0.5690(3) 0.0617(18) Uani 1 1 d . . .
O15 O 0.3079(2) 0.5490(3) 0.2446(3) 0.0504(14) Uani 1 1 d . . .
C1 C 0.6211(3) 0.8888(6) 0.7453(6) 0.064(3) Uani 1 1 d . . .
C2 C 0.5723(3) 0.8771(5) 0.7024(5) 0.069(3) Uani 1 1 d D A .
C3 C 0.5553(4) 0.8168(8) 0.6613(7) 0.121(5) Uani 1 1 d DU . .
H3 H 0.5758 0.7828 0.6641 0.145 Uiso 1 1 calc R . .
C4 C 0.5119(4) 0.8002(11) 0.6165(9) 0.156(7) Uani 1 1 d DU A .
H4 H 0.5036 0.7621 0.5861 0.187 Uiso 1 1 calc R . .
C5 C 0.4824(4) 0.8458(7) 0.6215(6) 0.090(4) Uani 1 1 d D . .
C6 C 0.4961(3) 0.8996(7) 0.6693(5) 0.091(4) Uani 1 1 d D A 1
H6 H 0.4757 0.9248 0.6758 0.110 Uiso 1 1 calc R A 1
C8A C 0.4329(10) 0.8861(15) 0.6173(15) 0.031(6) Uani 0.25 1 d PU A 2
C7 C 0.5407(3) 0.9161(8) 0.7081(6) 0.109(5) Uani 1 1 d DU . .
H7 H 0.5493 0.9542 0.7384 0.131 Uiso 1 1 calc R A 1
C8 C 0.4342(5) 0.8320(9) 0.5792(7) 0.082(5) Uani 0.75 1 d PU A .
C9 C 0.2588(2) 0.9130(4) 0.5342(4) 0.0367(16) Uani 1 1 d . . .
C10 C 0.2897(2) 0.8669(4) 0.5232(3) 0.0322(15) Uani 1 1 d . A .
C11 C 0.2734(2) 0.8127(4) 0.4750(3) 0.0303(15) Uani 1 1 d . . .
H11 H 0.2434 0.8057 0.4491 0.036 Uiso 1 1 calc R . .
C12 C 0.3017(2) 0.7692(4) 0.4655(3) 0.0332(15) Uani 1 1 d . A .
C13 C 0.3467(2) 0.7809(4) 0.5025(4) 0.0375(16) Uani 1 1 d . . .
H13 H 0.3658 0.7521 0.4956 0.045 Uiso 1 1 calc R A .
C14 C 0.3630(2) 0.8367(4) 0.5503(4) 0.0406(18) Uani 1 1 d . A .
C15 C 0.3350(2) 0.8778(4) 0.5615(4) 0.0374(17) Uani 1 1 d . . .
H15 H 0.3460 0.9131 0.5946 0.045 Uiso 1 1 calc R A .
C16 C 0.2845(2) 0.7070(4) 0.4176(3) 0.0320(15) Uani 1 1 d . . .
C17 C 0.4033(2) 0.5813(5) 0.4428(4) 0.0433(19) Uani 1 1 d . . .
C18 C 0.4514(2) 0.5906(4) 0.4931(4) 0.0419(19) Uani 1 1 d . . .
C19 C 0.4722(3) 0.5446(5) 0.5451(4) 0.048(2) Uani 1 1 d . . .
H19 H 0.4565 0.5080 0.5518 0.057 Uiso 1 1 calc R . .
C20 C 0.5169(3) 0.5520(5) 0.5885(4) 0.048(2) Uani 1 1 d . . .
H20 H 0.5311 0.5188 0.6230 0.058 Uiso 1 1 calc R . .
C21 C 0.5403(3) 0.6075(4) 0.5811(4) 0.047(2) Uani 1 1 d . . .
C22 C 0.5183(3) 0.6546(6) 0.5297(6) 0.090(4) Uani 1 1 d . . .
H22 H 0.5331 0.6944 0.5254 0.108 Uiso 1 1 calc R . .
C23 C 0.4748(3) 0.6449(6) 0.4842(6) 0.082(4) Uani 1 1 d . . .
H23 H 0.4611 0.6752 0.4473 0.099 Uiso 1 1 calc R . .
C24 C 0.5880(3) 0.6125(4) 0.6246(4) 0.046(2) Uani 1 1 d D . .
C25 C 0.2431(2) 1.0199(4) 0.6856(4) 0.0356(16) Uani 1 1 d . . .
C26 C 0.2217(2) 1.0892(4) 0.6878(4) 0.0361(17) Uani 1 1 d . . .
C27 C 0.1763(2) 1.0947(4) 0.6552(4) 0.0393(18) Uani 1 1 d . . .
H27 H 0.1592 1.0545 0.6323 0.047 Uiso 1 1 calc R . .
C28 C 0.1563(2) 1.1596(4) 0.6567(4) 0.0396(18) Uani 1 1 d . . .
C29 C 0.1822(2) 1.2209(4) 0.6887(4) 0.0425(18) Uani 1 1 d . . .
H29 H 0.1691 1.2655 0.6878 0.051 Uiso 1 1 calc R . .
C30 C 0.2276(2) 1.2149(4) 0.7219(3) 0.0356(16) Uani 1 1 d . . .
C31 C 0.2475(2) 1.1495(4) 0.7213(3) 0.0338(15) Uani 1 1 d . . .
H31 H 0.2779 1.1460 0.7431 0.041 Uiso 1 1 calc R . .
C32 C 0.2564(2) 0.7214(4) 0.2578(4) 0.0372(17) Uani 1 1 d . . .
C33 C 0.3667(6) 0.3908(8) 0.5107(7) 0.104(5) Uani 1 1 d . . .
C34 C 0.3565(10) 0.3020(13) 0.5807(15) 0.245(18) Uani 1 1 d . . .
H34A H 0.3684 0.2549 0.5994 0.367 Uiso 1 1 calc R . .
H34B H 0.3255 0.2977 0.5512 0.367 Uiso 1 1 calc R . .
H34C H 0.3620 0.3359 0.6154 0.367 Uiso 1 1 calc R . .
C35 C 0.4134(9) 0.2832(13) 0.5475(13) 0.214(14) Uani 1 1 d . . .
H35A H 0.4159 0.2398 0.5722 0.321 Uiso 1 1 calc R . .
H35B H 0.4405 0.3098 0.5691 0.321 Uiso 1 1 calc R . .
H35C H 0.4068 0.2698 0.5039 0.321 Uiso 1 1 calc R . .
C36 C 0.3696(3) 0.6395(5) 0.6001(4) 0.055(2) Uani 1 1 d . . .
C37 C 0.4459(4) 0.6590(9) 0.6814(7) 0.132(7) Uani 1 1 d . . .
H37A H 0.4625 0.6867 0.7212 0.197 Uiso 1 1 calc R . .
H37B H 0.4538 0.6738 0.6496 0.197 Uiso 1 1 calc R . .
H37C H 0.4519 0.6077 0.6907 0.197 Uiso 1 1 calc R . .
C38 C 0.3850(5) 0.7233(7) 0.6889(6) 0.100(5) Uani 1 1 d . . .
H38A H 0.4103 0.7417 0.7278 0.150 Uiso 1 1 calc R . .
H38B H 0.3663 0.6982 0.7012 0.150 Uiso 1 1 calc R . .
H38C H 0.3693 0.7634 0.6601 0.150 Uiso 1 1 calc R . .
C39 C 0.2697(3) 0.5316(5) 0.2018(4) 0.061(3) Uani 1 1 d . . .
C40 C 0.2927(3) 0.4242(6) 0.1676(5) 0.069(3) Uani 1 1 d . . .
H40A H 0.2793 0.3844 0.1371 0.103 Uiso 1 1 calc R . .
H40B H 0.3098 0.4050 0.2115 0.103 Uiso 1 1 calc R . .
H40C H 0.3113 0.4514 0.1563 0.103 Uiso 1 1 calc R . .
C41 C 0.2140(4) 0.4498(9) 0.1212(6) 0.101(5) Uani 1 1 d . . .
H41A H 0.2129 0.4058 0.0979 0.152 Uiso 1 1 calc R . .
H41B H 0.1989 0.4884 0.0901 0.152 Uiso 1 1 calc R . .
H41C H 0.2003 0.4413 0.1470 0.152 Uiso 1 1 calc R . .
C42 C 0.3288(6) 0.1406(10) 0.4314(8) 0.171(9) Uani 1 1 d DU . .
H42 H 0.3081 0.1715 0.3994 0.205 Uiso 1 1 calc R . .
C43 C 0.3228(7) 0.1194(10) 0.4834(8) 0.181(9) Uani 1 1 d DU . .
H43 H 0.2989 0.1352 0.4865 0.217 Uiso 1 1 calc R . .
C44 C 0.3545(7) 0.0732(9) 0.5304(9) 0.186(10) Uani 1 1 d DU . .
H44 H 0.3517 0.0578 0.5659 0.223 Uiso 1 1 calc R . .
C45 C 0.3902(7) 0.0495(9) 0.5255(10) 0.167(8) Uani 1 1 d DU . .
H45 H 0.4109 0.0185 0.5574 0.201 Uiso 1 1 calc R . .
C46 C 0.3947(6) 0.0725(9) 0.4729(9) 0.174(8) Uani 1 1 d DU . .
H46 H 0.4188 0.0569 0.4700 0.209 Uiso 1 1 calc R . .
C47 C 0.3640(6) 0.1183(9) 0.4246(10) 0.169(9) Uani 1 1 d DU . .
H47 H 0.3668 0.1335 0.3891 0.202 Uiso 1 1 calc R . .
C48 C 0.2848(7) 0.2623(10) 0.6289(9) 0.155(7) Uani 1 1 d DU . .
H48 H 0.2759 0.3108 0.6255 0.186 Uiso 1 1 calc R . .
C49 C 0.3260(7) 0.2436(13) 0.6809(10) 0.197(10) Uani 1 1 d DU . .
H49 H 0.3438 0.2790 0.7110 0.237 Uiso 1 1 calc R . .
C50 C 0.3404(7) 0.1714(12) 0.6875(9) 0.159(7) Uani 1 1 d DU . .
H50 H 0.3678 0.1578 0.7220 0.191 Uiso 1 1 calc R . .
C51 C 0.3131(5) 0.1200(11) 0.6417(7) 0.139(6) Uani 1 1 d DU . .
H51 H 0.3221 0.0715 0.6448 0.167 Uiso 1 1 calc R . .
C52 C 0.2722(5) 0.1415(8) 0.5909(7) 0.108(4) Uani 1 1 d DU . .
H52 H 0.2543 0.1059 0.5611 0.130 Uiso 1 1 calc R . .
C53 C 0.2563(6) 0.2128(8) 0.5818(8) 0.142(6) Uani 1 1 d DU . .
H53 H 0.2289 0.2262 0.5472 0.170 Uiso 1 1 calc R . .
C54 C 0.4111(5) 0.1876(10) 0.9041(9) 0.184(10) Uani 1 1 d DU . .
H54 H 0.4034 0.2355 0.9077 0.221 Uiso 1 1 calc R . .
C55 C 0.4533(6) 0.1609(10) 0.9417(10) 0.299(19) Uani 1 1 d DU . .
H55 H 0.4736 0.1942 0.9712 0.358 Uiso 1 1 calc R . .
C56 C 0.4696(6) 0.0917(9) 0.9419(10) 0.199(12) Uani 1 1 d DU . .
H56 H 0.4987 0.0777 0.9689 0.239 Uiso 1 1 calc R . .
C57 C 0.4370(6) 0.0466(9) 0.8965(8) 0.135(6) Uani 1 1 d DU . .
H57 H 0.4447 -0.0011 0.8927 0.163 Uiso 1 1 calc R . .
C58 C 0.3937(6) 0.0666(9) 0.8561(8) 0.166(9) Uani 1 1 d DU . .
H58 H 0.3734 0.0333 0.8264 0.199 Uiso 1 1 calc R . .
C59 C 0.3813(5) 0.1372(9) 0.8608(8) 0.137(6) Uani 1 1 d DU . .
H59 H 0.3522 0.1511 0.8342 0.164 Uiso 1 1 calc R . .
C60 C 0.0149(12) 0.361(2) 0.3158(18) 0.236(14) Uani 1 1 d DU . .
H60 H 0.0256 0.3629 0.3610 0.283 Uiso 1 1 calc R . .
C61 C 0.0451(9) 0.3607(15) 0.2943(14) 0.187(10) Uani 1 1 d DU . .
H61 H 0.0749 0.3615 0.3255 0.224 Uiso 1 1 calc R . .
C62 C 0.0323(11) 0.359(2) 0.2277(15) 0.221(12) Uani 1 1 d DU . .
H62 H 0.0520 0.3569 0.2125 0.265 Uiso 1 1 calc R . .
C63 C 0.4240(7) 0.4613(13) 0.6815(11) 0.223(13) Uani 1 1 d DU . .
H63 H 0.4142 0.4938 0.6463 0.267 Uiso 1 1 calc R . .
C64 C 0.4634(8) 0.4242(16) 0.7042(17) 0.31(2) Uani 1 1 d DU . .
H64 H 0.4824 0.4279 0.6878 0.377 Uiso 1 1 calc R . .
C65 C 0.4688(15) 0.381(2) 0.7564(18) 0.36(2) Uani 1 1 d DU . .
H65 H 0.4949 0.3545 0.7734 0.426 Uiso 1 1 calc R . .
C66 C 0.4478(11) 0.3633(18) 0.7913(17) 0.48(3) Uani 1 1 d DU . .
H66 H 0.4578 0.3307 0.8265 0.581 Uiso 1 1 calc R . .
C67 C 0.4091(11) 0.4032(10) 0.7646(6) 0.290(15) Uani 1 1 d DU . .
H67 H 0.3904 0.3992 0.7814 0.348 Uiso 1 1 calc R . .
C68 C 0.399428(9) 0.449460(16) 0.711972(15) 0.201(11) Uani 1 1 d DU . .
H68 H 0.3734 0.4756 0.6951 0.242 Uiso 1 1 calc R . .
Cd1 Cd 0.291496(9) 0.896893(16) 0.686282(15) 0.03435(16) Uani 1 1 d R . .
Cd2 Cd 0.323243(9) 0.546608(16) 0.471055(15) 0.03699(17) Uani 1 1 d R . .
Cd3 Cd 0.317343(9) 0.619594(16) 0.329819(15) 0.03455(16) Uani 1 1 d R . .
H24 H 0.602(2) 0.567(3) 0.650(3) 0.041 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C8A N1 C8 79.4(18) . .
C8A N1 C14 148.4(18) . .
C8 N1 C14 125.8(10) . .
C24 N2 C28 118.2(7) . 3_545
C33 N3 C35 122.5(15) . .
C33 N3 C34 122.2(14) . .
C35 N3 C34 115.3(14) . .
C36 N4 C37 120.2(11) . .
C36 N4 C38 120.4(11) . .
C37 N4 C38 119.5(10) . .
C39 N5 C40 121.3(9) . .
C39 N5 C41 120.7(9) . .
C40 N5 C41 117.9(9) . .
O1A O1 C1 89.2(18) . 2_656
O1A O1 O2A 120(2) . 2_656
C1 O1 O2A 43.5(14) 2_656 2_656
O1A O1 Cd1 87.8(13) . .
C1 O1 Cd1 99.2(8) 2_656 .
O2A O1 Cd1 71.3(12) 2_656 .
O1 O1A C1 49.1(15) . 2_656
O1 O1A Cd1 67.1(13) . .
C1 O1A Cd1 81.8(12) 2_656 .
O2A O2 C1 44.3(15) 2_656 2_656
O2A O2 Cd1 62.2(15) 2_656 .
C1 O2 Cd1 83.0(6) 2_656 .
C1 O2A O2 75(3) . 2_656
C1 O2A O1 57(2) . 2_656
O2 O2A O1 118(3) 2_656 2_656
C1 O2A Cd1 109(2) . 2_656
O2 O2A Cd1 89.3(17) 2_656 2_656
O1 O2A Cd1 73.1(14) 2_656 2_656
C9 O3 Cd2 111.1(5) . 7_566
C9 O4 Cd1 121.6(5) . .
C16 O5 Cd2 122.2(5) . .
C16 O5 Cd3 124.7(4) . .
Cd2 O5 Cd3 96.15(17) . .
C16 O6 Cd1 125.3(4) . 7_566
C17 O7 Cd2 132.6(5) . .
C17 O8 Cd3 115.1(5) . .
C25 O9 Cd3 124.5(5) . 7_566
C25 O9 Cd2 136.8(5) . 7_566
Cd3 O9 Cd2 95.86(17) 7_566 7_566
C25 O9 Cd1 85.2(4) . .
Cd3 O9 Cd1 96.66(17) 7_566 .
Cd2 O9 Cd1 106.79(19) 7_566 .
C25 O10 Cd1 101.3(4) . .
C32 O11 Cd3 98.8(4) . .
C32 O12 Cd1 131.9(5) 7_566 .
C32 O12 Cd3 83.4(4) 7_566 7_566
Cd1 O12 Cd3 96.65(17) . 7_566
C33 O13 Cd2 122.3(8) . .
C36 O14 Cd2 119.8(6) . .
C39 O15 Cd3 118.4(6) . .
O2A C1 O1 79(3) . 2_656
O2A C1 O2 61(3) . 2_656
O1 C1 O2 122.8(10) 2_656 2_656
O2A C1 C2 131(2) . .
O1 C1 C2 118.4(12) 2_656 .
O2 C1 C2 118.7(10) 2_656 .
O2A C1 O1A 110(3) . 2_656
O1 C1 O1A 41.7(11) 2_656 2_656
O2 C1 O1A 116.1(11) 2_656 2_656
C2 C1 O1A 111.4(12) . 2_656
O2A C1 Cd1 51.1(19) . 2_656
O1 C1 Cd1 55.3(6) 2_656 2_656
O2 C1 Cd1 67.7(6) 2_656 2_656
C2 C1 Cd1 173.6(9) . 2_656
O1A C1 Cd1 63.4(9) 2_656 2_656
C3 C2 C7 112.7(11) . .
C3 C2 C1 121.7(10) . .
C7 C2 C1 124.7(10) . .
C2 C3 C4 129.0(14) . .
C2 C3 H3 115.5 . .
C4 C3 H3 115.5 . .
C5 C4 C3 113.4(14) . .
C5 C4 H4 123.3 . .
C3 C4 H4 123.3 . .
C6 C5 C4 121.4(13) . .
C6 C5 C8 118.4(11) . .
C4 C5 C8 119.8(10) . .
C6 C5 C8A 72.5(11) . .
C4 C5 C8A 164.8(14) . .
C8 C5 C8A 46.0(11) . .
C5 C6 C7 120.2(11) . .
C5 C6 H6 119.9 . .
C7 C6 H6 119.9 . .
N1 C8A C8 53.5(15) . .
N1 C8A C5 105(2) . .
C8 C8A C5 53.0(11) . .
C2 C7 C6 121.7(11) . .
C2 C7 H7 119.2 . .
C6 C7 H7 119.2 . .
N1 C8 C8A 47.1(14) . .
N1 C8 C5 125.6(12) . .
C8A C8 C5 81.0(15) . .
O3 C9 O4 123.8(7) . .
O3 C9 C10 117.1(6) . .
O4 C9 C10 119.1(7) . .
C11 C10 C15 119.6(7) . .
C11 C10 C9 120.0(6) . .
C15 C10 C9 120.4(6) . .
C10 C11 C12 120.3(6) . .
C10 C11 H11 119.8 . .
C12 C11 H11 119.8 . .
C11 C12 C13 120.3(6) . .
C11 C12 C16 120.3(6) . .
C13 C12 C16 119.3(6) . .
C12 C13 C14 119.3(7) . .
C12 C13 H13 120.4 . .
C14 C13 H13 120.4 . .
C15 C14 C13 120.3(7) . .
C15 C14 N1 118.1(7) . .
C13 C14 N1 121.6(8) . .
C14 C15 C10 120.2(7) . .
C14 C15 H15 119.9 . .
C10 C15 H15 119.9 . .
O6 C16 O5 125.3(6) . .
O6 C16 C12 118.3(6) . .
O5 C16 C12 116.3(6) . .
O7 C17 O8 124.9(7) . .
O7 C17 C18 118.7(8) . .
O8 C17 C18 116.5(8) . .
C19 C18 C23 119.3(7) . .
C19 C18 C17 121.4(8) . .
C23 C18 C17 119.2(8) . .
C18 C19 C20 120.1(8) . .
C18 C19 H19 119.9 . .
C20 C19 H19 119.9 . .
C21 C20 C19 120.9(8) . .
C21 C20 H20 119.5 . .
C19 C20 H20 119.5 . .
C22 C21 C20 117.7(8) . .
C22 C21 C24 121.4(8) . .
C20 C21 C24 120.8(8) . .
C21 C22 C23 121.8(10) . .
C21 C22 H22 119.1 . .
C23 C22 H22 119.1 . .
C22 C23 C18 119.9(9) . .
C22 C23 H23 120.1 . .
C18 C23 H23 120.1 . .
N2 C24 C21 122.5(8) . .
N2 C24 H24 122(5) . .
C21 C24 H24 115(5) . .
O10 C25 O9 120.6(6) . .
O10 C25 C26 121.6(6) . .
O9 C25 C26 117.8(6) . .
C31 C26 C27 120.0(7) . .
C31 C26 C25 119.5(6) . .
C27 C26 C25 120.5(6) . .
C26 C27 C28 120.6(7) . .
C26 C27 H27 119.7 . .
C28 C27 H27 119.7 . .
C29 C28 C27 119.4(7) . .
C29 C28 N2 119.9(7) . 3_455
C27 C28 N2 120.5(6) . 3_455
C30 C29 C28 119.7(7) . .
C30 C29 H29 120.1 . .
C28 C29 H29 120.1 . .
C29 C30 C31 120.6(6) . .
C29 C30 C32 121.4(7) . 6_576
C31 C30 C32 118.0(6) . 6_576
C26 C31 C30 119.6(6) . .
C26 C31 H31 120.2 . .
C30 C31 H31 120.2 . .
O11 C32 O12 122.5(6) . 7_566
O11 C32 C30 118.3(6) . 6_575
O12 C32 C30 119.2(6) 7_566 6_575
O11 C32 Cd3 54.0(3) . .
O12 C32 Cd3 68.6(4) 7_566 .
C30 C32 Cd3 172.2(5) 6_575 .
N3 C33 O13 123.0(15) . .
N3 C34 H34A 109.5 . .
N3 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
N3 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
N3 C35 H35A 109.5 . .
N3 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
N3 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
O14 C36 N4 124.4(10) . .
N4 C37 H37A 109.5 . .
N4 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
N4 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
N4 C38 H38A 109.5 . .
N4 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
N4 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
O15 C39 N5 124.0(9) . .
N5 C40 H40A 109.5 . .
N5 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
N5 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
N5 C41 H41A 109.5 . .
N5 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
N5 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C47 C42 C43 123.8(19) . .
C47 C42 H42 118.1 . .
C43 C42 H42 118.1 . .
C44 C43 C42 116.5(19) . .
C44 C43 H43 121.8 . .
C42 C43 H43 121.8 . .
C45 C44 C43 122(2) . .
C45 C44 H44 119.2 . .
C43 C44 H44 119.2 . .
C46 C45 C44 120(2) . .
C46 C45 H45 120.2 . .
C44 C45 H45 120.2 . .
C47 C46 C45 121(2) . .
C47 C46 H46 119.5 . .
C45 C46 H46 119.5 . .
C46 C47 C42 117.4(19) . .
C46 C47 H47 121.3 . .
C42 C47 H47 121.3 . .
C53 C48 C49 124(2) . .
C53 C48 H48 118.0 . .
C49 C48 H48 118.0 . .
C50 C49 C48 119(2) . .
C50 C49 H49 120.3 . .
C48 C49 H49 120.3 . .
C51 C50 C49 119(2) . .
C51 C50 H50 120.6 . .
C49 C50 H50 120.6 . .
C50 C51 C52 119.4(19) . .
C50 C51 H51 120.3 . .
C52 C51 H51 120.3 . .
C51 C52 C53 124.3(17) . .
C51 C52 H52 117.9 . .
C53 C52 H52 117.9 . .
C52 C53 C48 114.1(17) . .
C52 C53 H53 122.9 . .
C48 C53 H53 122.9 . .
C59 C54 C55 114.4(16) . .
C59 C54 H54 122.8 . .
C55 C54 H54 122.8 . .
C54 C55 C56 129.5(19) . .
C54 C55 H55 115.2 . .
C56 C55 H55 115.2 . .
C57 C56 C55 110.7(17) . .
C57 C56 H56 124.6 . .
C55 C56 H56 124.6 . .
C56 C57 C58 125.4(16) . .
C56 C57 H57 117.3 . .
C58 C57 H57 117.3 . .
C59 C58 C57 118.5(16) . .
C59 C58 H58 120.8 . .
C57 C58 H58 120.8 . .
C58 C59 C54 121.5(16) . .
C58 C59 H59 119.2 . .
C54 C59 H59 119.2 . .
C61 C60 C62 124(3) . 2
C61 C60 H60 117.8 . .
C62 C60 H60 117.8 2 .
C60 C61 C62 122(3) . .
C60 C61 H61 119.0 . .
C62 C61 H61 119.0 . .
C61 C62 C60 113(3) . 2
C61 C62 H62 123.3 . .
C60 C62 H62 123.3 2 .
C68 C63 C64 119(2) . .
C68 C63 H63 120.3 . .
C64 C63 H63 120.3 . .
C65 C64 C63 106(4) . .
C65 C64 H64 126.8 . .
C63 C64 H64 126.8 . .
C66 C65 C64 140(4) . .
C66 C65 H65 109.8 . .
C64 C65 H65 109.8 . .
C67 C66 C65 108(4) . .
C67 C66 H66 126.0 . .
C65 C66 H66 126.0 . .
C66 C67 C68 118(3) . .
C66 C67 H67 121.0 . .
C68 C67 H67 121.0 . .
C67 C68 C63 127.8(19) . .
C67 C68 H68 116.1 . .
C63 C68 H68 116.1 . .
O2A Cd1 O1 35.6(11) 2_656 .
O2A Cd1 O10 111.4(11) 2_656 .
O1 Cd1 O10 112.4(3) . .
O2A Cd1 O6 102.7(10) 2_656 7_566
O1 Cd1 O6 100.0(3) . 7_566
O10 Cd1 O6 144.92(17) . 7_566
O2A Cd1 O4 90.6(10) 2_656 .
O1 Cd1 O4 125.8(3) . .
O10 Cd1 O4 88.84(19) . .
O6 Cd1 O4 82.69(19) 7_566 .
O2A Cd1 O12 124.1(11) 2_656 .
O1 Cd1 O12 88.5(3) . .
O10 Cd1 O12 88.37(18) . .
O6 Cd1 O12 79.00(18) 7_566 .
O4 Cd1 O12 143.52(19) . .
O2A Cd1 O1A 53.0(11) 2_656 .
O1 Cd1 O1A 25.1(7) . .
O10 Cd1 O1A 89.7(8) . .
O6 Cd1 O1A 118.3(7) 7_566 .
O4 Cd1 O1A 139.6(7) . .
O12 Cd1 O1A 76.7(7) . .
O2A Cd1 O2 28.5(11) 2_656 .
O1 Cd1 O2 54.7(3) . .
O10 Cd1 O2 84.6(3) . .
O6 Cd1 O2 126.9(3) 7_566 .
O4 Cd1 O2 80.4(3) . .
O12 Cd1 O2 135.4(2) . .
O1A Cd1 O2 59.3(7) . .
O2A Cd1 O9 155.7(12) 2_656 .
O1 Cd1 O9 159.0(3) . .
O10 Cd1 O9 52.68(16) . .
O6 Cd1 O9 92.43(16) 7_566 .
O4 Cd1 O9 72.34(19) . .
O12 Cd1 O9 77.19(16) . .
O1A Cd1 O9 134.2(8) . .
O2 Cd1 O9 128.4(3) . .
O2A Cd1 C1 19.6(8) 2_656 2_656
O1 Cd1 C1 25.5(4) . 2_656
O10 Cd1 C1 99.1(2) . 2_656
O6 Cd1 C1 116.0(2) 7_566 2_656
O4 Cd1 C1 106.0(3) . 2_656
O12 Cd1 C1 110.4(3) . 2_656
O1A Cd1 C1 34.8(8) . 2_656
O2 Cd1 C1 29.3(4) . 2_656
O9 Cd1 C1 151.3(2) . 2_656
O13 Cd2 O3 102.6(2) . 7_566
O13 Cd2 O7 88.9(2) . .
O3 Cd2 O7 160.01(19) 7_566 .
O13 Cd2 O14 97.6(3) . .
O3 Cd2 O14 82.4(2) 7_566 .
O7 Cd2 O14 79.8(2) . .
O13 Cd2 O5 169.2(2) . .
O3 Cd2 O5 85.74(19) 7_566 .
O7 Cd2 O5 85.16(19) . .
O14 Cd2 O5 90.2(2) . .
O13 Cd2 O9 99.0(2) . 7_566
O3 Cd2 O9 110.59(19) 7_566 7_566
O7 Cd2 O9 83.17(19) . 7_566
O14 Cd2 O9 155.9(2) . 7_566
O5 Cd2 O9 71.35(16) . 7_566
O13 Cd2 Cd3 127.27(18) . .
O3 Cd2 Cd3 121.23(14) 7_566 .
O7 Cd2 Cd3 59.72(15) . .
O14 Cd2 Cd3 114.67(19) . .
O5 Cd2 Cd3 41.99(12) . .
O9 Cd2 Cd3 41.30(12) 7_566 .
O8 Cd3 O11 107.1(2) . .
O8 Cd3 O15 102.4(2) . .
O11 Cd3 O15 106.2(2) . .
O8 Cd3 O9 115.6(2) . 7_566
O11 Cd3 O9 130.65(19) . 7_566
O15 Cd3 O9 88.2(2) . 7_566
O8 Cd3 O5 87.8(2) . .
O11 Cd3 O5 86.1(2) . .
O15 Cd3 O5 160.6(2) . .
O9 Cd3 O5 72.47(17) 7_566 .
O8 Cd3 O12 162.2(2) . 7_566
O11 Cd3 O12 55.10(17) . 7_566
O15 Cd3 O12 84.79(19) . 7_566
O9 Cd3 O12 80.55(16) 7_566 7_566
O5 Cd3 O12 90.37(16) . 7_566
O8 Cd3 C32 134.2(2) . .
O11 Cd3 C32 27.1(2) . .
O15 Cd3 C32 97.0(2) . .
O9 Cd3 C32 106.0(2) 7_566 .
O5 Cd3 C32 87.2(2) . .
O12 Cd3 C32 28.00(19) 7_566 .
O8 Cd3 Cd2 82.28(17) . .
O11 Cd3 Cd2 127.43(18) . .
O15 Cd3 Cd2 122.48(15) . .
O9 Cd3 Cd2 42.84(12) 7_566 .
O5 Cd3 Cd2 41.85(12) . .
O12 Cd3 Cd2 107.83(12) 7_566 .
C32 Cd3 Cd2 120.44(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N1 C8A 1.00(3) .
N1 C8 1.102(16) .
N1 C14 1.425(10) .
N2 C24 1.277(11) .
N2 C28 1.406(9) 3_545
N3 C33 1.296(17) .
N3 C35 1.47(2) .
N3 C34 1.51(2) .
N4 C36 1.321(11) .
N4 C37 1.470(18) .
N4 C38 1.461(16) .
N5 C39 1.342(12) .
N5 C40 1.419(12) .
N5 C41 1.459(15) .
O1 O1A 1.03(3) .
O1 C1 1.165(14) 2_656
O1 O2A 1.36(4) 2_656
O1 Cd1 2.227(8) .
O1A C1 1.54(3) 2_656
O1A Cd1 2.42(2) .
O2 O2A 1.19(4) 2_656
O2 C1 1.317(16) 2_656
O2 Cd1 2.492(9) .
O2A C1 0.95(3) .
O2A O2 1.19(4) 2_656
O2A O1 1.36(4) 2_656
O2A Cd1 2.20(3) 2_656
O3 C9 1.261(9) .
O3 Cd2 2.231(5) 7_566
O4 C9 1.271(9) .
O4 Cd1 2.306(5) .
O5 C16 1.281(8) .
O5 Cd2 2.334(5) .
O5 Cd3 2.340(5) .
O6 C16 1.239(8) .
O6 Cd1 2.305(5) 7_566
O7 C17 1.241(10) .
O7 Cd2 2.304(6) .
O8 C17 1.260(10) .
O8 Cd3 2.173(5) .
O9 C25 1.294(9) .
O9 Cd3 2.307(5) 7_566
O9 Cd2 2.377(5) 7_566
O9 Cd1 2.613(5) .
O10 C25 1.237(8) .
O10 Cd1 2.301(5) .
O11 C32 1.245(9) .
O11 Cd3 2.211(5) .
O12 C32 1.276(9) 7_566
O12 Cd1 2.398(5) .
O12 Cd3 2.529(5) 7_566
O13 C33 1.339(18) .
O13 Cd2 2.212(6) .
O14 C36 1.240(12) .
O14 Cd2 2.312(6) .
O15 C39 1.253(11) .
O15 Cd3 2.256(6) .
C1 O1 1.165(14) 2_656
C1 O2 1.317(16) 2_656
C1 C2 1.511(13) .
C1 O1A 1.54(3) 2_656
C1 Cd1 2.674(10) 2_656
C2 C3 1.384(5) .
C2 C7 1.386(5) .
C3 C4 1.387(5) .
C3 H3 0.9300 .
C4 C5 1.385(5) .
C4 H4 0.9300 .
C5 C6 1.382(5) .
C5 C8 1.497(18) .
C5 C8A 1.85(3) .
C6 C7 1.397(5) .
C6 H6 0.9300 .
C8A C8 1.35(3) .
C7 H7 0.9300 .
C9 C10 1.498(11) .
C10 C11 1.389(10) .
C10 C15 1.401(10) .
C11 C12 1.377(10) .
C11 H11 0.9300 .
C12 C13 1.394(10) .
C12 C16 1.494(9) .
C13 C14 1.405(10) .
C13 H13 0.9300 .
C14 C15 1.368(11) .
C15 H15 0.9300 .
C17 C18 1.514(10) .
C18 C19 1.352(12) .
C18 C23 1.372(13) .
C19 C20 1.391(11) .
C19 H19 0.9300 .
C20 C21 1.371(12) .
C20 H20 0.9300 .
C21 C22 1.361(13) .
C21 C24 1.469(11) .
C22 C23 1.372(13) .
C22 H22 0.9300 .
C23 H23 0.9300 .
C24 H24 1.00(2) .
C25 C26 1.484(10) .
C26 C31 1.392(10) .
C26 C27 1.391(10) .
C27 C28 1.387(11) .
C27 H27 0.9300 .
C28 C29 1.400(10) .
C28 N2 1.406(9) 3_455
C29 C30 1.390(10) .
C29 H29 0.9300 .
C30 C31 1.389(10) .
C30 C32 1.492(9) 6_576
C31 H31 0.9300 .
C32 O12 1.275(9) 7_566
C32 C30 1.492(9) 6_575
C32 Cd3 2.699(7) .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 C47 1.390(5) .
C42 C43 1.393(5) .
C42 H42 0.9300 .
C43 C44 1.391(5) .
C43 H43 0.9300 .
C44 C45 1.389(5) .
C44 H44 0.9300 .
C45 C46 1.387(5) .
C45 H45 0.9300 .
C46 C47 1.387(5) .
C46 H46 0.9300 .
C47 H47 0.9300 .
C48 C53 1.390(5) .
C48 C49 1.392(5) .
C48 H48 0.9300 .
C49 C50 1.392(5) .
C49 H49 0.9300 .
C50 C51 1.386(5) .
C50 H50 0.9300 .
C51 C52 1.389(5) .
C51 H51 0.9300 .
C52 C53 1.389(5) .
C52 H52 0.9300 .
C53 H53 0.9300 .
C54 C59 1.382(5) .
C54 C55 1.384(5) .
C54 H54 0.9300 .
C55 C56 1.385(5) .
C55 H55 0.9300 .
C56 C57 1.381(5) .
C56 H56 0.9300 .
C57 C58 1.383(5) .
C57 H57 0.9300 .
C58 C59 1.381(5) .
C58 H58 0.9300 .
C59 H59 0.9300 .
C60 C61 1.390(5) .
C60 C62 1.45(4) 2
C60 H60 0.9300 .
C61 C62 1.391(5) .
C61 H61 0.9300 .
C62 C60 1.45(4) 2
C62 H62 0.9300 .
C63 C68 1.389(5) .
C63 C64 1.390(5) .
C63 H63 0.9300 .
C64 C65 1.390(5) .
C64 H64 0.9300 .
C65 C66 1.390(5) .
C65 H65 0.9300 .
C66 C67 1.387(5) .
C66 H66 0.9300 .
C67 C68 1.387(5) .
C67 H67 0.9300 .
C68 H68 0.9300 .
Cd1 O2A 2.20(3) 2_656
Cd1 O6 2.305(5) 7_566
Cd1 C1 2.674(10) 2_656
Cd2 O3 2.231(5) 7_566
Cd2 O9 2.377(5) 7_566
Cd2 Cd3 3.4774 .
Cd3 O9 2.307(5) 7_566
Cd3 O12 2.529(5) 7_566
