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#$Date: 2016-03-26 18:15:34 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180419 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/88/7208809.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208809
loop_
_publ_author_name
'Sun, Di'
'Liu, Fu-Jing'
'Huang, Rong-Bin'
'Zheng, Lan-Sun'
_publ_section_title
;
 Three guest-dependent nitrate--water aggregations encapsulated in
 silver(i)--bipyridine supramolecular frameworks
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              7872
_journal_paper_doi               10.1039/c2ce26161h
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         '2(C10 H8 Ag N2), C7 H6 N2, 2(N O3), H2 O '
_chemical_formula_sum            'C27 H24 Ag2 N8 O7'
_chemical_formula_weight         788.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.627(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.010(4)
_cell_length_b                   11.380(3)
_cell_length_c                   18.085(5)
_cell_measurement_temperature    173(2)
_cell_volume                     2824.2(13)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0606
_diffrn_reflns_av_sigmaI/netI    0.1193
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            13681
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.48
_exptl_absorpt_coefficient_mu    1.449
_exptl_absorpt_correction_T_max  0.7604
_exptl_absorpt_correction_T_min  0.5949
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.854
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1568
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.603
_refine_diff_density_min         -0.996
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.189
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         4950
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.194
_refine_ls_R_factor_all          0.0994
_refine_ls_R_factor_gt           0.0767
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+17.3495P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1979
_refine_ls_wR_factor_ref         0.2106
_reflns_number_gt                3755
_reflns_number_total             4950
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce26161h.txt
_cod_data_source_block           p3
_cod_original_sg_symbol_H-M      p2(1)/c
_cod_database_code               7208809
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.88953(6) 1.01668(6) 0.50371(4) 0.0368(3) Uani 1 1 d .
Ag2 Ag 0.62280(6) 1.31227(7) 0.48824(5) 0.0467(3) Uani 1 1 d .
C1 C 0.9099(7) 0.7694(8) 0.5746(5) 0.036(2) Uani 1 1 d .
H1 H 0.9343 0.8116 0.6198 0.043 Uiso 1 1 calc R
C2 C 0.9053(8) 0.6480(10) 0.5776(5) 0.042(3) Uani 1 1 d .
H2 H 0.9246 0.6101 0.6250 0.050 Uiso 1 1 calc R
C3 C 0.8741(7) 0.5811(8) 0.5154(6) 0.032(2) Uani 1 1 d .
C4 C 0.8428(7) 0.6451(8) 0.4468(5) 0.031(2) Uani 1 1 d U
H4 H 0.8183 0.6043 0.4011 0.038 Uiso 1 1 calc R
C5 C 0.8482(8) 0.7653(9) 0.4471(6) 0.042(3) Uani 1 1 d .
H5 H 0.8277 0.8057 0.4006 0.051 Uiso 1 1 calc R
C6 C 0.9057(8) 0.2634(10) 0.5736(6) 0.044(3) Uani 1 1 d U
H6 H 0.9274 0.2201 0.6188 0.053 Uiso 1 1 calc R
C7 C 0.9022(8) 0.3869(10) 0.5778(6) 0.046(3) Uani 1 1 d U
H7 H 0.9209 0.4253 0.6252 0.055 Uiso 1 1 calc R
C8 C 0.8718(6) 0.4513(9) 0.5136(5) 0.028(2) Uani 1 1 d .
C9 C 0.8429(9) 0.3856(10) 0.4480(5) 0.050(3) Uani 1 1 d .
H9 H 0.8185 0.4248 0.4017 0.060 Uiso 1 1 calc R
C10 C 0.8488(9) 0.2695(8) 0.4490(6) 0.045(3) Uani 1 1 d .
H10 H 0.8289 0.2290 0.4025 0.054 Uiso 1 1 calc R
C11 C 0.6222(9) 1.0652(10) 0.5548(7) 0.054(3) Uani 1 1 d .
H11 H 0.6205 1.1082 0.5995 0.065 Uiso 1 1 calc R
C12 C 0.6149(8) 0.9421(9) 0.5557(6) 0.042(3) Uani 1 1 d .
H12 H 0.6054 0.9031 0.6001 0.050 Uiso 1 1 calc R
C13 C 0.6214(7) 0.8772(8) 0.4917(5) 0.030(2) Uani 1 1 d .
C14 C 0.6331(9) 0.9408(10) 0.4306(7) 0.052(3) Uani 1 1 d .
H14 H 0.6377 0.9010 0.3853 0.063 Uiso 1 1 calc R
C15 C 0.6385(8) 1.0604(10) 0.4328(6) 0.045(3) Uani 1 1 d U
H15 H 0.6477 1.1011 0.3889 0.054 Uiso 1 1 calc R
C16 C 0.6459(7) 0.5586(9) 0.5532(6) 0.035(2) Uani 1 1 d U
H16 H 0.6682 0.5154 0.5984 0.042 Uiso 1 1 calc R
C17 C 0.6480(7) 0.6838(8) 0.5564(5) 0.034(2) Uani 1 1 d .
H17 H 0.6710 0.7218 0.6034 0.041 Uiso 1 1 calc R
C18 C 0.6169(7) 0.7518(8) 0.4914(5) 0.030(2) Uani 1 1 d .
C19 C 0.5828(7) 0.6846(8) 0.4241(6) 0.037(2) Uani 1 1 d .
H19 H 0.5602 0.7238 0.3774 0.045 Uiso 1 1 calc R
C20 C 0.5827(8) 0.5618(9) 0.4268(6) 0.043(3) Uani 1 1 d .
H20 H 0.5589 0.5202 0.3813 0.052 Uiso 1 1 calc R
C21 C 0.1189(8) 0.6143(11) 0.7444(6) 0.043(3) Uani 1 1 d .
C22 C 0.1649(8) 0.4999(8) 0.7476(5) 0.035(2) Uani 1 1 d .
C23 C 0.1092(7) 0.3982(8) 0.7453(5) 0.035(2) Uani 1 1 d .
H23 H 0.0412 0.4028 0.7438 0.042 Uiso 1 1 calc R
C24 C 0.1542(7) 0.2911(9) 0.7451(5) 0.035(2) Uani 1 1 d .
H24 H 0.1164 0.2216 0.7435 0.042 Uiso 1 1 calc R
C25 C 0.2557(7) 0.2815(9) 0.7472(5) 0.034(2) Uani 1 1 d .
C26 C 0.3097(7) 0.3850(9) 0.7490(5) 0.037(2) Uani 1 1 d .
H26 H 0.3778 0.3806 0.7505 0.045 Uiso 1 1 calc R
C27 C 0.2655(7) 0.4940(8) 0.7484(5) 0.034(2) Uani 1 1 d .
H27 H 0.3026 0.5639 0.7487 0.041 Uiso 1 1 calc R
N1 N 0.8812(5) 0.8297(6) 0.5101(4) 0.0265(16) Uani 1 1 d .
N2 N 0.8805(5) 0.2062(7) 0.5103(4) 0.0316(18) Uani 1 1 d .
N3 N 0.6315(6) 1.1222(8) 0.4934(5) 0.041(2) Uani 1 1 d .
N4 N 0.6137(6) 0.4998(7) 0.4892(4) 0.0351(19) Uani 1 1 d .
N5 N 0.0812(8) 0.7042(8) 0.7374(5) 0.052(2) Uani 1 1 d .
N6 N 0.2989(6) 0.1749(7) 0.7442(5) 0.039(2) Uani 1 1 d .
H6A H 0.3614 0.1708 0.7434 0.047 Uiso 1 1 calc R
H6B H 0.2643 0.1102 0.7432 0.047 Uiso 1 1 calc R
N7 N 0.8860(6) 0.4881(7) 0.8179(4) 0.0355(19) Uani 1 1 d .
N8 N 0.5610(7) 0.2981(8) 0.2973(6) 0.049(2) Uani 1 1 d .
O1 O 0.8175(6) 0.4706(7) 0.8502(4) 0.054(2) Uani 1 1 d .
O1W O 0.3044(7) 0.6673(9) 0.3328(5) 0.086(3) Uani 1 1 d .
H1WA H 0.2613 0.6278 0.3033 0.103 Uiso 1 1 d R
H1WB H 0.3417 0.6996 0.3071 0.103 Uiso 1 1 d R
O2 O 0.9691(6) 0.5066(7) 0.8557(4) 0.056(2) Uani 1 1 d .
O3 O 0.8707(6) 0.4933(6) 0.7477(4) 0.0458(19) Uani 1 1 d .
O4 O 0.5348(8) 0.3069(13) 0.2314(6) 0.110(5) Uani 1 1 d .
O5 O 0.5054(7) 0.3015(9) 0.3404(6) 0.078(3) Uani 1 1 d .
O6 O 0.6494(7) 0.2848(9) 0.3276(6) 0.085(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 170.1(3) . 1_565
N1 Ag1 O1 95.4(3) . 4_575
N2 Ag1 O1 89.4(3) 1_565 4_575
N1 Ag1 Ag1 86.95(19) . 3_776
N2 Ag1 Ag1 101.0(2) 1_565 3_776
O1 Ag1 Ag1 97.29(17) 4_575 3_776
N4 Ag2 N3 177.0(3) 1_565 .
N1 C1 C2 122.3(8) . .
N1 C1 H1 118.9 . .
C2 C1 H1 118.9 . .
C3 C2 C1 122.6(9) . .
C3 C2 H2 118.7 . .
C1 C2 H2 118.7 . .
C2 C3 C4 115.2(9) . .
C2 C3 C8 125.5(9) . .
C4 C3 C8 119.3(8) . .
C5 C4 C3 119.9(9) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
N1 C5 C4 123.5(9) . .
N1 C5 H5 118.2 . .
C4 C5 H5 118.2 . .
N2 C6 C7 122.6(10) . .
N2 C6 H6 118.7 . .
C7 C6 H6 118.7 . .
C8 C7 C6 119.8(10) . .
C8 C7 H7 120.1 . .
C6 C7 H7 120.1 . .
C7 C8 C9 115.1(10) . .
C7 C8 C3 121.1(9) . .
C9 C8 C3 123.8(9) . .
C10 C9 C8 121.2(10) . .
C10 C9 H9 119.4 . .
C8 C9 H9 119.4 . .
N2 C10 C9 124.4(10) . .
N2 C10 H10 117.8 . .
C9 C10 H10 117.8 . .
N3 C11 C12 121.5(11) . .
N3 C11 H11 119.2 . .
C12 C11 H11 119.2 . .
C13 C12 C11 120.1(10) . .
C13 C12 H12 119.9 . .
C11 C12 H12 119.9 . .
C14 C13 C12 115.6(9) . .
C14 C13 C18 122.9(9) . .
C12 C13 C18 121.5(8) . .
C13 C14 C15 121.6(11) . .
C13 C14 H14 119.2 . .
C15 C14 H14 119.2 . .
N3 C15 C14 122.8(10) . .
N3 C15 H15 118.6 . .
C14 C15 H15 118.6 . .
N4 C16 C17 122.4(9) . .
N4 C16 H16 118.8 . .
C17 C16 H16 118.8 . .
C18 C17 C16 121.2(9) . .
C18 C17 H17 119.4 . .
C16 C17 H17 119.4 . .
C17 C18 C13 122.9(9) . .
C17 C18 C19 114.3(9) . .
C13 C18 C19 122.8(8) . .
C20 C19 C18 120.3(9) . .
C20 C19 H19 119.9 . .
C18 C19 H19 119.9 . .
N4 C20 C19 124.0(10) . .
N4 C20 H20 118.0 . .
C19 C20 H20 118.0 . .
N5 C21 C22 176.0(11) . .
C23 C22 C27 121.0(9) . .
C23 C22 C21 120.2(10) . .
C27 C22 C21 118.7(9) . .
C24 C23 C22 118.9(9) . .
C24 C23 H23 120.6 . .
C22 C23 H23 120.6 . .
C23 C24 C25 121.8(9) . .
C23 C24 H24 119.1 . .
C25 C24 H24 119.1 . .
N6 C25 C26 120.6(9) . .
N6 C25 C24 121.2(9) . .
C26 C25 C24 118.1(9) . .
C27 C26 C25 121.0(9) . .
C27 C26 H26 119.5 . .
C25 C26 H26 119.5 . .
C26 C27 C22 119.2(9) . .
C26 C27 H27 120.4 . .
C22 C27 H27 120.4 . .
C1 N1 C5 116.5(8) . .
C1 N1 Ag1 123.0(6) . .
C5 N1 Ag1 120.4(6) . .
C6 N2 C10 116.8(9) . .
C6 N2 Ag1 122.5(7) . 1_545
C10 N2 Ag1 120.7(7) . 1_545
C11 N3 C15 118.3(10) . .
C11 N3 Ag2 121.0(8) . .
C15 N3 Ag2 120.5(7) . .
C20 N4 C16 117.8(9) . .
C20 N4 Ag2 122.3(7) . 1_545
C16 N4 Ag2 119.8(6) . 1_545
C25 N6 H6A 120.0 . .
C25 N6 H6B 120.0 . .
H6A N6 H6B 120.0 . .
O1 N7 O2 119.8(8) . .
O1 N7 O3 119.9(9) . .
O2 N7 O3 120.2(9) . .
O4 N8 O5 122.7(12) . .
O4 N8 O6 121.9(11) . .
O5 N8 O6 115.4(11) . .
N7 O1 Ag1 107.8(6) . 4_576
H1WA O1W H1WB 108.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.136(7) .
Ag1 N2 2.166(8) 1_565
Ag1 O1 2.760(8) 4_575
Ag1 Ag1 3.1482(18) 3_776
Ag2 N4 2.138(8) 1_565
Ag2 N3 2.168(9) .
C1 N1 1.344(11) .
C1 C2 1.385(14) .
C1 H1 0.9500 .
C2 C3 1.356(13) .
C2 H2 0.9500 .
C3 C4 1.428(13) .
C3 C8 1.478(13) .
C4 C5 1.370(14) .
C4 H4 0.9500 .
C5 N1 1.355(12) .
C5 H5 0.9500 .
C6 N2 1.303(13) .
C6 C7 1.408(15) .
C6 H6 0.9500 .
C7 C8 1.366(14) .
C7 H7 0.9500 .
C8 C9 1.392(13) .
C9 C10 1.323(14) .
C9 H9 0.9500 .
C10 N2 1.321(12) .
C10 H10 0.9500 .
C11 N3 1.314(13) .
C11 C12 1.404(15) .
C11 H11 0.9500 .
C12 C13 1.392(13) .
C12 H12 0.9500 .
C13 C14 1.358(14) .
C13 C18 1.428(13) .
C14 C15 1.364(16) .
C14 H14 0.9500 .
C15 N3 1.322(13) .
C15 H15 0.9500 .
C16 N4 1.335(12) .
C16 C17 1.427(13) .
C16 H16 0.9500 .
C17 C18 1.401(13) .
C17 H17 0.9500 .
C18 C19 1.436(13) .
C19 C20 1.399(14) .
C19 H19 0.9500 .
C20 N4 1.327(13) .
C20 H20 0.9500 .
C21 N5 1.147(13) .
C21 C22 1.449(15) .
C22 C23 1.392(13) .
C22 C27 1.407(14) .
C23 C24 1.372(14) .
C23 H23 0.9500 .
C24 C25 1.419(14) .
C24 H24 0.9500 .
C25 N6 1.361(12) .
C25 C26 1.397(14) .
C26 C27 1.387(14) .
C26 H26 0.9500 .
C27 H27 0.9500 .
N2 Ag1 2.166(8) 1_545
N4 Ag2 2.138(8) 1_545
N6 H6A 0.8800 .
N6 H6B 0.8800 .
N7 O1 1.236(11) .
N7 O2 1.244(11) .
N7 O3 1.245(10) .
N8 O4 1.179(13) .
N8 O5 1.207(12) .
N8 O6 1.258(12) .
O1 Ag1 2.760(8) 4_576
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N6 H6A O5 0.88 2.41 3.072(13) 132.1 4_566
N6 H6B O3 0.88 2.34 3.174(11) 157.2 2_646
O1W H1WA O3 0.85 2.34 3.169(12) 164.5 3_666
O1W H1WB O4 0.85 2.34 3.162(15) 164.5 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 2.0(17) . .
C1 C2 C3 C4 -2.3(15) . .
C1 C2 C3 C8 176.8(10) . .
C2 C3 C4 C5 1.7(14) . .
C8 C3 C4 C5 -177.5(9) . .
C3 C4 C5 N1 -0.8(16) . .
N2 C6 C7 C8 -0.3(17) . .
C6 C7 C8 C9 2.2(15) . .
C6 C7 C8 C3 -175.5(9) . .
C2 C3 C8 C7 0.1(15) . .
C4 C3 C8 C7 179.2(9) . .
C2 C3 C8 C9 -177.3(10) . .
C4 C3 C8 C9 1.8(14) . .
C7 C8 C9 C10 -2.5(16) . .
C3 C8 C9 C10 175.1(11) . .
C8 C9 C10 N2 1(2) . .
N3 C11 C12 C13 2.7(18) . .
C11 C12 C13 C14 -1.2(16) . .
C11 C12 C13 C18 178.2(10) . .
C12 C13 C14 C15 0.3(16) . .
C18 C13 C14 C15 -179.1(10) . .
C13 C14 C15 N3 -0.9(19) . .
N4 C16 C17 C18 -0.6(14) . .
C16 C17 C18 C13 -177.5(9) . .
C16 C17 C18 C19 0.7(13) . .
C14 C13 C18 C17 150.5(10) . .
C12 C13 C18 C17 -28.9(14) . .
C14 C13 C18 C19 -27.6(15) . .
C12 C13 C18 C19 153.0(10) . .
C17 C18 C19 C20 -0.1(14) . .
C13 C18 C19 C20 178.2(9) . .
C18 C19 C20 N4 -0.7(16) . .
N5 C21 C22 C23 -83(17) . .
N5 C21 C22 C27 93(17) . .
C27 C22 C23 C24 1.1(14) . .
C21 C22 C23 C24 177.3(9) . .
C22 C23 C24 C25 0.0(14) . .
C23 C24 C25 N6 -177.6(9) . .
C23 C24 C25 C26 -0.4(14) . .
N6 C25 C26 C27 177.0(9) . .
C24 C25 C26 C27 -0.2(13) . .
C25 C26 C27 C22 1.2(13) . .
C23 C22 C27 C26 -1.7(13) . .
C21 C22 C27 C26 -177.9(9) . .
C2 C1 N1 C5 -0.8(14) . .
C2 C1 N1 Ag1 -179.1(8) . .
C4 C5 N1 C1 0.2(15) . .
C4 C5 N1 Ag1 178.6(8) . .
N2 Ag1 N1 C1 -62.6(19) 1_565 .
O1 Ag1 N1 C1 178.8(7) 4_575 .
Ag1 Ag1 N1 C1 81.7(7) 3_776 .
N2 Ag1 N1 C5 119.1(16) 1_565 .
O1 Ag1 N1 C5 0.5(7) 4_575 .
Ag1 Ag1 N1 C5 -96.5(7) 3_776 .
C7 C6 N2 C10 -1.4(16) . .
C7 C6 N2 Ag1 178.4(8) . 1_545
C9 C10 N2 C6 1.2(17) . .
C9 C10 N2 Ag1 -178.6(10) . 1_545
C12 C11 N3 C15 -3.2(17) . .
C12 C11 N3 Ag2 171.5(9) . .
C14 C15 N3 C11 2.4(17) . .
C14 C15 N3 Ag2 -172.4(9) . .
N4 Ag2 N3 C11 4(6) 1_565 .
N4 Ag2 N3 C15 179(100) 1_565 .
C19 C20 N4 C16 0.8(15) . .
C19 C20 N4 Ag2 -174.8(8) . 1_545
C17 C16 N4 C20 -0.2(14) . .
C17 C16 N4 Ag2 175.6(7) . 1_545
O2 N7 O1 Ag1 0.1(10) . 4_576
O3 N7 O1 Ag1 -176.0(6) . 4_576
