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#$Date: 2016-03-26 18:21:14 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180423 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/92/7209230.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7209230
loop_
_publ_author_name
'Wang, Xiuli'
'Huang, Jingjing'
'Liu, Lianli'
'Liu, Guocheng'
'Lin, Hongyan'
'Zhang, Juwen'
'Chen, Naili'
'Qu, Yun'
_publ_section_title
;
 Assembly of Zn/Cd coordination polymers containing helixes or
 polycatenane structures tuned by the tri-pyridyl--bis-amide ligands with
 different spacer: syntheses, structures, photoluminescent and
 photocatalytic properties
;
_journal_issue                   10
_journal_name_full               CrystEngComm
_journal_page_first              1960
_journal_paper_doi               10.1039/c2ce26892b
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C25 H19 Cd N5 O7'
_chemical_formula_weight         613.86
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.546(4)
_cell_angle_beta                 91.307(5)
_cell_angle_gamma                90.209(5)
_cell_formula_units_Z            2
_cell_length_a                   9.064(3)
_cell_length_b                   9.558(3)
_cell_length_c                   13.644(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1176.2(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0225
_diffrn_reflns_av_sigmaI/netI    0.0448
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6242
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.14
_exptl_absorpt_coefficient_mu    0.987
_exptl_absorpt_correction_T_max  0.694
_exptl_absorpt_correction_T_min  0.648
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.733
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             616
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.41
_exptl_crystal_size_min          0.37
_refine_diff_density_max         0.780
_refine_diff_density_min         -0.622
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     343
_refine_ls_number_reflns         4125
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.0312
_refine_ls_R_factor_gt           0.0271
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0352P)²+0.0113P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0659
_refine_ls_wR_factor_ref         0.0678
_reflns_number_gt                3716
_reflns_number_total             4151
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce26892b.txt
_cod_data_source_block           2
_cod_database_code               7209230
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cd1 Cd 0.88039(2) 0.071471(19) 0.117362(12) 0.02445(8) Uani 1 1 d .
O1 O 0.7280(2) 0.1867(2) 0.02118(14) 0.0342(5) Uani 1 1 d .
N1 N 0.9664(2) 0.1270(2) 0.28054(16) 0.0297(5) Uani 1 1 d .
C1 C 0.9030(3) 0.2325(3) 0.33446(19) 0.0286(6) Uani 1 1 d .
H1A H 0.8309 0.2837 0.3042 0.034 Uiso 1 1 calc R
O1W O 0.8154(2) 0.5638(2) 0.30337(15) 0.0434(5) Uani 1 1 d .
H1WA H 0.8091 0.5183 0.2467 0.052 Uiso 1 1 d R
H1WB H 0.9008 0.6010 0.3096 0.052 Uiso 1 1 d R
O2 O 0.7708(2) 0.3314(2) 0.15493(14) 0.0390(5) Uani 1 1 d .
N2 N 0.8566(2) 0.3847(2) 0.47926(15) 0.0281(5) Uani 1 1 d .
H2B H 0.8227 0.4450 0.4418 0.034 Uiso 1 1 calc R
C2 C 1.0688(3) 0.0519(3) 0.3249(2) 0.0324(7) Uani 1 1 d .
H2A H 1.1116 -0.0247 0.2892 0.039 Uiso 1 1 calc R
O3 O 1.0876(2) 0.12949(19) 0.02452(14) 0.0330(5) Uani 1 1 d .
N3 N 0.6637(2) 0.5935(2) 0.52697(15) 0.0257(5) Uani 1 1 d .
C3 C 0.9375(3) 0.2711(3) 0.43311(18) 0.0258(6) Uani 1 1 d .
O4 O 0.9643(2) -0.1512(2) 0.13364(15) 0.0412(5) Uani 1 1 d .
N4 N 0.5784(2) 0.7612(3) 0.38333(16) 0.0320(5) Uani 1 1 d .
H4B H 0.6454 0.6976 0.3771 0.038 Uiso 1 1 calc R
C4 C 1.0473(3) 0.1961(3) 0.4778(2) 0.0331(7) Uani 1 1 d .
H4A H 1.0761 0.2199 0.5431 0.040 Uiso 1 1 calc R
N5 N 0.6576(3) -0.0217(2) 0.18353(16) 0.0319(5) Uani 1 1 d .
C5 C 1.1123(3) 0.0855(3) 0.4225(2) 0.0372(7) Uani 1 1 d .
H5A H 1.1855 0.0334 0.4508 0.045 Uiso 1 1 calc R
C6 C 0.8275(3) 0.4080(3) 0.57591(19) 0.0282(6) Uani 1 1 d .
C7 C 0.6683(4) 0.5457(3) 0.6963(2) 0.0416(8) Uani 1 1 d .
H7A H 0.7062 0.4938 0.7452 0.050 Uiso 1 1 calc R
C8 C 0.5099(3) 0.7241(3) 0.6437(2) 0.0408(8) Uani 1 1 d .
H8A H 0.4401 0.7942 0.6566 0.049 Uiso 1 1 calc R
O9 O 0.8831(2) 0.3429(2) 0.64072(14) 0.0424(5) Uani 1 1 d .
C9 C 0.5622(3) 0.6930(3) 0.54917(19) 0.0278(6) Uani 1 1 d .
O10 O 0.3981(2) 0.8551(2) 0.48308(15) 0.0468(6) Uani 1 1 d .
C10 C 0.7153(3) 0.5217(3) 0.60075(18) 0.0274(6) Uani 1 1 d .
C11 C 0.5637(4) 0.6488(4) 0.7180(2) 0.0491(9) Uani 1 1 d .
H11A H 0.5302 0.6669 0.7819 0.059 Uiso 1 1 calc R
C12 C 0.5040(3) 0.7771(3) 0.4685(2) 0.0304(6) Uani 1 1 d .
C13 C 0.5519(3) 0.8436(3) 0.30386(19) 0.0273(6) Uani 1 1 d .
C14 C 0.4102(3) 0.8722(3) 0.2694(2) 0.0339(7) Uani 1 1 d .
H14A H 0.3274 0.8367 0.2977 0.041 Uiso 1 1 calc R
C15 C 0.6708(3) -0.1026(3) 0.2581(2) 0.0316(6) Uani 1 1 d .
H15A H 0.7652 -0.1236 0.2803 0.038 Uiso 1 1 calc R
C16 C 0.5200(3) 0.0060(3) 0.1513(2) 0.0320(7) Uani 1 1 d .
H16A H 0.5086 0.0620 0.0996 0.038 Uiso 1 1 calc R
C17 C 0.3962(3) 0.9547(3) 0.1919(2) 0.0362(7) Uani 1 1 d .
H17A H 0.3030 0.9755 0.1674 0.043 Uiso 1 1 calc R
C18 C 1.0505(3) 0.2030(3) -0.0452(2) 0.0298(6) Uani 1 1 d .
C19 C 0.9515(3) 0.4332(3) -0.0898(2) 0.0311(6) Uani 1 1 d .
H19A H 0.9191 0.3885 -0.1501 0.037 Uiso 1 1 calc R
C20 C 0.7078(3) 0.3017(3) 0.07273(19) 0.0280(6) Uani 1 1 d .
C21 C 0.6014(3) 0.4056(3) 0.03484(18) 0.0262(6) Uani 1 1 d .
C22 C 0.5967(4) 0.5422(3) 0.0766(2) 0.0436(8) Uani 1 1 d .
H22A H 0.6612 0.5716 0.1286 0.052 Uiso 1 1 calc R
C23 C 0.5038(4) 0.3630(3) -0.0419(2) 0.0427(8) Uani 1 1 d .
H23A H 0.5052 0.2706 -0.0704 0.051 Uiso 1 1 calc R
C24 C 1.0732(3) 0.4250(3) 0.0681(2) 0.0303(6) Uani 1 1 d .
H24A H 1.1225 0.3746 0.1136 0.036 Uiso 1 1 calc R
C27 C 1.0243(3) 0.3567(3) -0.02208(19) 0.0258(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cd1 O4 140.31(8) . .
O1 Cd1 N1 131.30(7) . .
O4 Cd1 N1 86.11(7) . .
O1 Cd1 O3 91.12(7) . .
O4 Cd1 O3 92.93(7) . .
N1 Cd1 O3 102.31(8) . .
O1 Cd1 N5 85.93(8) . .
O4 Cd1 N5 82.32(8) . .
N1 Cd1 N5 87.98(8) . .
O3 Cd1 N5 168.40(7) . .
O1 Cd1 O3 90.75(7) . 2_755
O4 Cd1 O3 53.52(6) . 2_755
N1 Cd1 O3 137.95(7) . 2_755
O3 Cd1 O3 72.18(7) . 2_755
N5 Cd1 O3 96.61(7) . 2_755
C20 O1 Cd1 102.76(16) . .
C1 N1 C2 117.8(2) . .
C1 N1 Cd1 118.34(16) . .
C2 N1 Cd1 123.71(18) . .
N1 C1 C3 124.1(2) . .
N1 C1 H1A 117.9 . .
C3 C1 H1A 117.9 . .
H1WA O1W H1WB 107.7 . .
C6 N2 C3 126.7(2) . .
C6 N2 H2B 116.7 . .
C3 N2 H2B 116.7 . .
N1 C2 C5 121.7(3) . .
N1 C2 H2A 119.1 . .
C5 C2 H2A 119.1 . .
C18 O3 Cd1 111.80(17) . .
C18 O3 Cd1 84.18(16) . 2_755
Cd1 O3 Cd1 107.82(7) . 2_755
C9 N3 C10 117.5(2) . .
C1 C3 C4 117.9(2) . .
C1 C3 N2 116.3(2) . .
C4 C3 N2 125.8(2) . .
C18 O4 Cd1 99.32(17) 2_755 .
C12 N4 C13 123.5(2) . .
C12 N4 H4B 118.2 . .
C13 N4 H4B 118.2 . .
C5 C4 C3 118.3(2) . .
C5 C4 H4A 120.9 . .
C3 C4 H4A 120.9 . .
C15 N5 C16 117.5(2) . .
C15 N5 Cd1 118.59(18) . .
C16 N5 Cd1 123.89(18) . .
C4 C5 C2 120.2(2) . .
C4 C5 H5A 119.9 . .
C2 C5 H5A 119.9 . .
O9 C6 N2 124.7(3) . .
O9 C6 C10 120.7(2) . .
N2 C6 C10 114.5(2) . .
C10 C7 C11 118.8(3) . .
C10 C7 H7A 120.6 . .
C11 C7 H7A 120.6 . .
C11 C8 C9 118.6(3) . .
C11 C8 H8A 120.7 . .
C9 C8 H8A 120.7 . .
N3 C9 C8 122.9(2) . .
N3 C9 C12 118.8(2) . .
C8 C9 C12 118.2(2) . .
N3 C10 C7 123.1(3) . .
N3 C10 C6 117.7(2) . .
C7 C10 C6 119.2(2) . .
C8 C11 C7 119.2(3) . .
C8 C11 H11A 120.4 . .
C7 C11 H11A 120.4 . .
O10 C12 N4 124.4(3) . .
O10 C12 C9 120.3(2) . .
N4 C12 C9 115.3(2) . .
C15 C13 C14 118.4(2) 1_565 .
C15 C13 N4 118.9(2) 1_565 .
C14 C13 N4 122.7(3) . .
C17 C14 C13 118.2(3) . .
C17 C14 H14A 120.9 . .
C13 C14 H14A 120.9 . .
N5 C15 C13 123.5(3) . 1_545
N5 C15 H15A 118.2 . .
C13 C15 H15A 118.2 1_545 .
N5 C16 C17 122.5(3) . 1_545
N5 C16 H16A 118.7 . .
C17 C16 H16A 118.7 1_545 .
C16 C17 C14 119.9(3) 1_565 .
C16 C17 H17A 120.1 1_565 .
C14 C17 H17A 120.1 . .
O4 C18 O3 122.6(3) 2_755 .
O4 C18 C27 118.4(2) 2_755 .
O3 C18 C27 119.0(2) . .
C24 C19 C27 120.4(3) 2_765 .
C24 C19 H19A 119.8 2_765 .
C27 C19 H19A 119.8 . .
O2 C20 O1 122.6(2) . .
O2 C20 C21 118.9(3) . .
O1 C20 C21 118.6(2) . .
C22 C21 C23 119.0(2) . .
C22 C21 C20 121.1(2) . .
C23 C21 C20 119.9(3) . .
C21 C22 C23 120.6(3) . 2_665
C21 C22 H22A 119.7 . .
C23 C22 H22A 119.7 2_665 .
C21 C23 C22 120.4(3) . 2_665
C21 C23 H23A 119.8 . .
C22 C23 H23A 119.8 2_665 .
C19 C24 C27 120.3(2) 2_765 .
C19 C24 H24A 119.9 2_765 .
C27 C24 H24A 119.9 . .
C19 C27 C24 119.3(2) . .
C19 C27 C18 120.5(2) . .
C24 C27 C18 120.2(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cd1 O1 2.2476(18) .
Cd1 O4 2.292(2) .
Cd1 N1 2.353(2) .
Cd1 O3 2.382(2) .
Cd1 N5 2.431(2) .
Cd1 O3 2.614(2) 2_755
O1 C20 1.263(3) .
N1 C1 1.330(3) .
N1 C2 1.344(3) .
C1 C3 1.389(4) .
C1 H1A 0.9300 .
O1W H1WA 0.8500 .
O1W H1WB 0.8500 .
O2 C20 1.254(3) .
N2 C6 1.348(3) .
N2 C3 1.417(3) .
N2 H2B 0.8600 .
C2 C5 1.388(4) .
C2 H2A 0.9300 .
O3 C18 1.276(3) .
O3 Cd1 2.614(2) 2_755
N3 C9 1.344(3) .
N3 C10 1.348(3) .
C3 C4 1.392(3) .
O4 C18 1.263(3) 2_755
N4 C12 1.353(3) .
N4 C13 1.418(3) .
N4 H4B 0.8600 .
C4 C5 1.379(4) .
C4 H4A 0.9300 .
N5 C15 1.340(3) .
N5 C16 1.348(3) .
C5 H5A 0.9300 .
C6 O9 1.229(3) .
C6 C10 1.511(4) .
C7 C10 1.379(4) .
C7 C11 1.386(4) .
C7 H7A 0.9300 .
C8 C11 1.381(4) .
C8 C9 1.389(4) .
C8 H8A 0.9300 .
C9 C12 1.511(4) .
O10 C12 1.225(3) .
C11 H11A 0.9300 .
C13 C15 1.380(4) 1_565
C13 C14 1.395(4) .
C14 C17 1.382(4) .
C14 H14A 0.9300 .
C15 C13 1.380(4) 1_545
C15 H15A 0.9300 .
C16 C17 1.373(4) 1_545
C16 H16A 0.9300 .
C17 C16 1.373(4) 1_565
C17 H17A 0.9300 .
C18 O4 1.263(3) 2_755
C18 C27 1.493(4) .
C19 C24 1.380(4) 2_765
C19 C27 1.389(4) .
C19 H19A 0.9300 .
C20 C21 1.506(3) .
C21 C22 1.374(4) .
C21 C23 1.384(4) .
C22 C23 1.395(4) 2_665
C22 H22A 0.9300 .
C23 C22 1.395(4) 2_665
C23 H23A 0.9300 .
C24 C19 1.380(4) 2_765
C24 C27 1.398(4) .
C24 H24A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Cd1 O1 C20 163.11(16) . .
N1 Cd1 O1 C20 6.6(2) . .
O3 Cd1 O1 C20 -100.94(17) . .
N5 Cd1 O1 C20 90.29(18) . .
O3 Cd1 O1 C20 -173.13(17) 2_755 .
O1 Cd1 N1 C1 11.2(2) . .
O4 Cd1 N1 C1 -154.0(2) . .
O3 Cd1 N1 C1 113.9(2) . .
N5 Cd1 N1 C1 -71.6(2) . .
O3 Cd1 N1 C1 -169.19(18) 2_755 .
O1 Cd1 N1 C2 -173.8(2) . .
O4 Cd1 N1 C2 21.0(2) . .
O3 Cd1 N1 C2 -71.2(2) . .
N5 Cd1 N1 C2 103.4(2) . .
O3 Cd1 N1 C2 5.8(3) 2_755 .
C2 N1 C1 C3 1.0(4) . .
Cd1 N1 C1 C3 176.3(2) . .
C1 N1 C2 C5 -2.6(4) . .
Cd1 N1 C2 C5 -177.6(2) . .
O1 Cd1 O3 C18 0.37(19) . .
O4 Cd1 O3 C18 140.88(19) . .
N1 Cd1 O3 C18 -132.47(19) . .
N5 Cd1 O3 C18 75.4(4) . .
O3 Cd1 O3 C18 90.80(19) 2_755 .
O1 Cd1 O3 Cd1 -90.43(8) . 2_755
O4 Cd1 O3 Cd1 50.08(8) . 2_755
N1 Cd1 O3 Cd1 136.73(7) . 2_755
N5 Cd1 O3 Cd1 -15.3(3) . 2_755
O3 Cd1 O3 Cd1 0.0 2_755 2_755
N1 C1 C3 C4 1.2(4) . .
N1 C1 C3 N2 -178.9(2) . .
C6 N2 C3 C1 153.1(3) . .
C6 N2 C3 C4 -27.0(4) . .
O1 Cd1 O4 C18 26.7(2) . 2_755
N1 Cd1 O4 C18 -170.79(18) . 2_755
O3 Cd1 O4 C18 -68.64(18) . 2_755
N5 Cd1 O4 C18 100.73(18) . 2_755
O3 Cd1 O4 C18 -3.40(16) 2_755 2_755
C1 C3 C4 C5 -1.9(4) . .
N2 C3 C4 C5 178.2(3) . .
O1 Cd1 N5 C15 -175.7(2) . .
O4 Cd1 N5 C15 42.3(2) . .
N1 Cd1 N5 C15 -44.1(2) . .
O3 Cd1 N5 C15 108.7(3) . .
O3 Cd1 N5 C15 94.0(2) 2_755 .
O1 Cd1 N5 C16 2.5(2) . .
O4 Cd1 N5 C16 -139.5(2) . .
N1 Cd1 N5 C16 134.2(2) . .
O3 Cd1 N5 C16 -73.1(4) . .
O3 Cd1 N5 C16 -87.8(2) 2_755 .
C3 C4 C5 C2 0.4(4) . .
N1 C2 C5 C4 1.9(5) . .
C3 N2 C6 O9 9.8(5) . .
C3 N2 C6 C10 -169.1(2) . .
C10 N3 C9 C8 0.2(4) . .
C10 N3 C9 C12 179.0(2) . .
C11 C8 C9 N3 -0.5(5) . .
C11 C8 C9 C12 -179.3(3) . .
C9 N3 C10 C7 0.2(4) . .
C9 N3 C10 C6 178.9(2) . .
C11 C7 C10 N3 -0.3(5) . .
C11 C7 C10 C6 -179.0(3) . .
O9 C6 C10 N3 177.0(3) . .
N2 C6 C10 N3 -4.2(4) . .
O9 C6 C10 C7 -4.3(4) . .
N2 C6 C10 C7 174.6(3) . .
C9 C8 C11 C7 0.4(5) . .
C10 C7 C11 C8 -0.1(5) . .
C13 N4 C12 O10 6.6(5) . .
C13 N4 C12 C9 -172.1(2) . .
N3 C9 C12 O10 170.4(3) . .
C8 C9 C12 O10 -10.8(4) . .
N3 C9 C12 N4 -10.9(4) . .
C8 C9 C12 N4 167.9(3) . .
C12 N4 C13 C15 134.9(3) . 1_565
C12 N4 C13 C14 -45.5(4) . .
C15 C13 C14 C17 -0.9(4) 1_565 .
N4 C13 C14 C17 179.5(3) . .
C16 N5 C15 C13 -1.0(4) . 1_545
Cd1 N5 C15 C13 177.4(2) . 1_545
C15 N5 C16 C17 0.0(4) . 1_545
Cd1 N5 C16 C17 -178.3(2) . 1_545
C13 C14 C17 C16 0.0(4) . 1_565
Cd1 O3 C18 O4 -101.1(3) . 2_755
Cd1 O3 C18 O4 5.8(3) 2_755 2_755
Cd1 O3 C18 C27 79.2(3) . .
Cd1 O3 C18 C27 -173.9(2) 2_755 .
Cd1 O1 C20 O2 2.6(3) . .
Cd1 O1 C20 C21 -176.03(19) . .
O2 C20 C21 C22 14.6(4) . .
O1 C20 C21 C22 -166.7(3) . .
O2 C20 C21 C23 -163.8(3) . .
O1 C20 C21 C23 14.8(4) . .
C23 C21 C22 C23 -0.6(6) . 2_665
C20 C21 C22 C23 -179.1(3) . 2_665
C22 C21 C23 C22 0.6(6) . 2_665
C20 C21 C23 C22 179.1(3) . 2_665
C24 C19 C27 C24 -0.4(5) 2_765 .
C24 C19 C27 C18 179.7(3) 2_765 .
C19 C24 C27 C19 0.4(5) 2_765 .
C19 C24 C27 C18 -179.7(3) 2_765 .
O4 C18 C27 C19 15.5(4) 2_755 .
O3 C18 C27 C19 -164.8(2) . .
O4 C18 C27 C24 -164.4(3) 2_755 .
O3 C18 C27 C24 15.3(4) . .
