#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:25:06 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180428 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/97/7209792.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7209792
loop_
_publ_author_name
'Li, Bo'
'Huang, Ren-Wu'
'Zang, Shuang-Quan'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of silver(i)--organic frameworks from flexible supramolecular
 synthons with pendant ethynide arm attached to biphenyl and
 phenoxybenzene skeletons
;
_journal_issue                   20
_journal_name_full               CrystEngComm
_journal_page_first              4087
_journal_paper_doi               10.1039/c3ce40230d
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C60 H44 Ag6 N2 O10'
_chemical_formula_weight         1600.19
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.781(2)
_cell_angle_beta                 92.459(2)
_cell_angle_gamma                90.367(2)
_cell_formula_units_Z            2
_cell_length_a                   7.6485(2)
_cell_length_b                   11.1943(3)
_cell_length_c                   30.1822(7)
_cell_measurement_reflns_used    5000
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      29.2541
_cell_measurement_theta_min      3.0370
_cell_volume                     2572.70(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_sigmaI/netI    0.0539
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            17096
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.04
_exptl_absorpt_coefficient_mu    2.304
_exptl_absorpt_correction_T_max  0.6686
_exptl_absorpt_correction_T_min  0.6433
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS(2009)
_exptl_crystal_density_diffrn    2.066
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.19
_refine_diff_density_max         2.191
_refine_diff_density_min         -1.142
_refine_diff_density_rms         0.138
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     716
_refine_ls_number_reflns         9016
_refine_ls_number_restraints     57
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0709
_refine_ls_R_factor_gt           0.0542
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0511P)²+10.0785P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1253
_refine_ls_wR_factor_ref         0.1351
_reflns_number_gt                7145
_reflns_number_total             9016
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40230d.txt
_cod_data_source_block           3
_cod_database_code               7209792
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.31524(7) 0.75190(5) 0.028808(17) 0.03382(15) Uani 1 1 d . . .
Ag2 Ag 0.26800(11) 0.48801(6) -0.02775(3) 0.0729(3) Uani 1 1 d . . .
Ag3 Ag -0.04400(8) 0.78284(8) 0.06231(3) 0.0752(3) Uani 1 1 d . . .
Ag4 Ag 0.29062(12) 1.01068(7) 0.06948(4) 0.0891(3) Uani 1 1 d . . .
Ag5 Ag 0.30934(7) 1.24891(5) 0.016381(17) 0.03589(16) Uani 1 1 d . . .
Ag6 Ag -0.05588(8) 1.25111(8) 0.04806(3) 0.0675(2) Uani 1 1 d U . .
O1 O 0.2753(6) 0.5859(5) -0.14860(15) 0.0408(12) Uani 1 1 d . A .
O2 O 0.3102(8) 1.1679(5) -0.15568(17) 0.0491(14) Uani 1 1 d . A .
O3 O 0.2182(7) 1.1613(5) 0.18660(16) 0.0459(13) Uani 1 1 d . A .
O4 O 0.2075(7) 0.7372(5) 0.19517(16) 0.0460(13) Uani 1 1 d . . .
O5 O 0.1175(13) 0.5067(9) 0.1102(4) 0.120(3) Uani 1 1 d U . .
O6 O 0.0758(11) 0.5023(8) 0.0427(3) 0.100(3) Uani 1 1 d U . .
O7 O 0.3302(8) 0.5221(6) 0.0675(3) 0.076(2) Uani 1 1 d U . .
N1 N 0.1826(11) 0.5122(6) 0.0773(4) 0.070(2) Uani 1 1 d U . .
C1 C 0.3327(8) 0.6853(6) -0.0376(2) 0.0288(15) Uani 1 1 d . . .
C2 C 0.3610(8) 0.6648(6) -0.0766(2) 0.0293(15) Uani 1 1 d . . .
C3 C 0.4121(9) 0.6496(7) -0.1233(2) 0.0384(17) Uani 1 1 d . . .
H3A H 0.4301 0.7272 -0.1345 0.046 Uiso 1 1 calc R A .
H3B H 0.5203 0.6052 -0.1254 0.046 Uiso 1 1 calc R . .
C4 C 0.2918(9) 0.5738(6) -0.1937(2) 0.0314(15) Uani 1 1 d . . .
C5 C 0.1614(8) 0.5059(6) -0.2177(2) 0.0313(15) Uani 1 1 d . A .
H5 H 0.0726 0.4710 -0.2030 0.038 Uiso 1 1 calc R . .
C6 C 0.4219(9) 0.6247(7) -0.2166(2) 0.0391(18) Uani 1 1 d . A .
H6 H 0.5102 0.6703 -0.2010 0.047 Uiso 1 1 calc R . .
C7 C 0.4214(9) 0.6081(7) -0.2624(2) 0.0378(17) Uani 1 1 d . . .
H7 H 0.5113 0.6421 -0.2771 0.045 Uiso 1 1 calc R A .
C8 C 0.2919(8) 0.5426(6) -0.2872(2) 0.0284(14) Uani 1 1 d . A .
C9 C 0.1640(9) 0.4905(6) -0.2635(2) 0.0329(16) Uani 1 1 d . . .
H9 H 0.0771 0.4437 -0.2791 0.040 Uiso 1 1 calc R A .
C10 C 0.2865(8) 0.5317(6) -0.3366(2) 0.0299(15) Uani 1 1 d . . .
C11 C 0.2044(9) 0.4355(7) -0.3616(2) 0.0397(18) Uani 1 1 d . A .
H11 H 0.1530 0.3748 -0.3471 0.048 Uiso 1 1 calc R . .
C12 C 0.1985(10) 0.4291(7) -0.4074(2) 0.0443(19) Uani 1 1 d . . .
H12 H 0.1436 0.3638 -0.4234 0.053 Uiso 1 1 calc R A .
C13 C 0.2714(10) 0.5167(7) -0.4296(3) 0.0438(19) Uani 1 1 d . A .
H13 H 0.2654 0.5116 -0.4606 0.053 Uiso 1 1 calc R . .
C14 C 0.3536(10) 0.6123(7) -0.4059(3) 0.0437(19) Uani 1 1 d . . .
H14 H 0.4048 0.6723 -0.4207 0.052 Uiso 1 1 calc R A .
C15 C 0.3598(10) 0.6192(7) -0.3602(3) 0.0406(18) Uani 1 1 d . A .
H15 H 0.4152 0.6848 -0.3445 0.049 Uiso 1 1 calc R . .
C16 C 0.3204(9) 1.2930(6) -0.04990(19) 0.0328(16) Uani 1 1 d D . .
C17 C 0.3318(9) 1.2915(6) -0.0900(2) 0.0337(16) Uani 1 1 d D . .
C18 C 0.3625(10) 1.2862(7) -0.1378(2) 0.0391(17) Uani 1 1 d . . .
H18A H 0.2937 1.3462 -0.1518 0.047 Uiso 1 1 calc R A .
H18B H 0.4852 1.3004 -0.1426 0.047 Uiso 1 1 calc R . .
C19 C 0.3117(9) 1.1453(6) -0.2013(2) 0.0365(17) Uani 1 1 d . . .
C20 C 0.2589(10) 1.0301(7) -0.2177(3) 0.0438(19) Uani 1 1 d . A .
H20 H 0.2290 0.9739 -0.1982 0.053 Uiso 1 1 calc R . .
C21 C 0.2512(10) 0.9998(7) -0.2631(2) 0.0403(18) Uani 1 1 d . . .
H21 H 0.2155 0.9227 -0.2737 0.048 Uiso 1 1 calc R A .
C22 C 0.2950(8) 1.0808(6) -0.2932(2) 0.0288(15) Uani 1 1 d . A .
C23 C 0.3501(9) 1.1949(6) -0.2752(2) 0.0373(17) Uani 1 1 d . . .
H23 H 0.3820 1.2512 -0.2944 0.045 Uiso 1 1 calc R A .
C24 C 0.3586(10) 1.2265(7) -0.2302(2) 0.0396(18) Uani 1 1 d . A .
H24 H 0.3962 1.3030 -0.2195 0.048 Uiso 1 1 calc R . .
C25 C 0.2868(8) 1.0499(6) -0.3419(2) 0.0312(15) Uani 1 1 d . . .
C26 C 0.1881(9) 0.9520(6) -0.3624(3) 0.0415(18) Uani 1 1 d . A .
H26 H 0.1268 0.9037 -0.3447 0.050 Uiso 1 1 calc R . .
C27 C 0.1799(10) 0.9259(7) -0.4076(3) 0.0433(19) Uani 1 1 d . . .
H27 H 0.1135 0.8606 -0.4199 0.052 Uiso 1 1 calc R A .
C28 C 0.2680(10) 0.9948(7) -0.4348(3) 0.046(2) Uani 1 1 d . A .
H28 H 0.2620 0.9763 -0.4654 0.055 Uiso 1 1 calc R . .
C29 C 0.3656(10) 1.0915(7) -0.4164(3) 0.0433(19) Uani 1 1 d . . .
H29 H 0.4255 1.1390 -0.4347 0.052 Uiso 1 1 calc R A .
C30 C 0.3749(9) 1.1185(7) -0.3709(3) 0.0401(18) Uani 1 1 d . A .
H30 H 0.4417 1.1842 -0.3591 0.048 Uiso 1 1 calc R . .
C31 C 0.2112(8) 1.2081(6) 0.0773(2) 0.0350(16) Uani 1 1 d . A .
C32 C 0.1545(9) 1.2110(6) 0.1138(2) 0.0336(16) Uani 1 1 d . A .
C33 C 0.0988(10) 1.2254(8) 0.1598(2) 0.051(2) Uani 1 1 d . . .
H33A H 0.0993 1.3096 0.1704 0.061 Uiso 1 1 calc R A .
H33B H -0.0190 1.1938 0.1614 0.061 Uiso 1 1 calc R . .
C34 C 0.3301(9) 1.1209(7) 0.2565(2) 0.0374(17) Uani 1 1 d . A .
H34 H 0.4117 1.0725 0.2419 0.045 Uiso 1 1 calc R . .
C35 C 0.2059(9) 1.1791(6) 0.2320(2) 0.0328(16) Uani 1 1 d . . .
C36 C 0.0842(9) 1.2491(7) 0.2538(2) 0.0425(18) Uani 1 1 d . A .
H36 H -0.0023 1.2874 0.2378 0.051 Uiso 1 1 calc R . .
C37 C 0.0918(10) 1.2619(7) 0.3001(2) 0.0432(19) Uani 1 1 d . . .
H37 H 0.0095 1.3098 0.3146 0.052 Uiso 1 1 calc R A .
C38 C 0.2162(8) 1.2066(6) 0.3253(2) 0.0309(15) Uani 1 1 d . A .
C39 C 0.3348(9) 1.1338(6) 0.3024(2) 0.0370(17) Uani 1 1 d . . .
H39 H 0.4188 1.0931 0.3183 0.044 Uiso 1 1 calc R A .
C40 C 0.2228(9) 1.2219(6) 0.3752(2) 0.0338(16) Uani 1 1 d . . .
C41 C 0.1567(10) 1.3238(7) 0.3977(3) 0.0426(18) Uani 1 1 d . A .
H41 H 0.1076 1.3837 0.3817 0.051 Uiso 1 1 calc R . .
C42 C 0.1634(11) 1.3369(8) 0.4440(3) 0.051(2) Uani 1 1 d . . .
H42 H 0.1165 1.4048 0.4587 0.062 Uiso 1 1 calc R A .
C43 C 0.2378(11) 1.2514(8) 0.4680(3) 0.051(2) Uani 1 1 d . A .
H43 H 0.2441 1.2615 0.4990 0.061 Uiso 1 1 calc R . .
C44 C 0.3031(11) 1.1503(8) 0.4462(3) 0.055(2) Uani 1 1 d . . .
H44 H 0.3533 1.0914 0.4625 0.066 Uiso 1 1 calc R A .
C45 C 0.2953(10) 1.1350(7) 0.4002(2) 0.0433(19) Uani 1 1 d . A .
H45 H 0.3393 1.0654 0.3860 0.052 Uiso 1 1 calc R . .
C46 C 0.2249(8) 0.8248(6) 0.0896(2) 0.0321(16) Uani 1 1 d . A .
C47 C 0.1966(9) 0.8337(6) 0.1287(2) 0.0341(16) Uani 1 1 d . . .
C48 C 0.1746(11) 0.8478(8) 0.1770(3) 0.049(2) Uani 1 1 d . A .
H48A H 0.2551 0.9086 0.1907 0.058 Uiso 1 1 calc R . .
H48B H 0.0563 0.8733 0.1830 0.058 Uiso 1 1 calc R . .
C49 C 0.2044(9) 0.7389(7) 0.2410(2) 0.0370(17) Uani 1 1 d . . .
C50 C 0.1508(10) 0.8357(7) 0.2681(3) 0.0434(19) Uani 1 1 d . . .
H50 H 0.1102 0.9045 0.2559 0.052 Uiso 1 1 calc R . .
C51 C 0.1583(9) 0.8291(7) 0.3137(2) 0.0395(18) Uani 1 1 d . . .
H51 H 0.1251 0.8958 0.3317 0.047 Uiso 1 1 calc R . .
C52 C 0.2123(8) 0.7289(6) 0.3337(2) 0.0299(15) Uani 1 1 d . . .
C53 C 0.2620(9) 0.6309(6) 0.3054(2) 0.0387(17) Uani 1 1 d . . .
H53 H 0.2983 0.5608 0.3174 0.046 Uiso 1 1 calc R . .
C54 C 0.2579(10) 0.6369(7) 0.2595(3) 0.0415(19) Uani 1 1 d . . .
H54 H 0.2918 0.5710 0.2411 0.050 Uiso 1 1 calc R . .
C55 C 0.2182(8) 0.7265(6) 0.3830(2) 0.0304(15) Uani 1 1 d . . .
C56 C 0.1219(9) 0.8083(7) 0.4091(2) 0.0391(17) Uani 1 1 d . . .
H56 H 0.0506 0.8628 0.3955 0.047 Uiso 1 1 calc R . .
C57 C 0.1311(10) 0.8092(7) 0.4549(3) 0.0456(19) Uani 1 1 d . . .
H57 H 0.0657 0.8643 0.4718 0.055 Uiso 1 1 calc R . .
C58 C 0.2349(11) 0.7304(7) 0.4756(3) 0.049(2) Uani 1 1 d . . .
H58 H 0.2409 0.7321 0.5065 0.058 Uiso 1 1 calc R . .
C59 C 0.3296(11) 0.6491(8) 0.4508(3) 0.050(2) Uani 1 1 d . . .
H59 H 0.3991 0.5944 0.4649 0.060 Uiso 1 1 calc R . .
C60 C 0.3232(10) 0.6474(7) 0.4051(3) 0.0424(18) Uani 1 1 d . . .
H60 H 0.3903 0.5923 0.3886 0.051 Uiso 1 1 calc R . .
N2 N 0.6874(18) 1.0148(15) 0.0535(5) 0.082(4) Uani 0.614(8) 1 d PDU A 1
O8 O 0.5598(16) 0.9986(16) 0.0234(4) 0.119(5) Uani 0.614(8) 1 d PDU . 1
O9 O 0.8383(15) 1.0102(12) 0.0414(4) 0.098(3) Uani 0.614(8) 1 d PDU A 1
O10 O 0.6473(18) 1.046(3) 0.0923(5) 0.114(5) Uani 0.614(8) 1 d PDU A 1
N2' N 0.685(3) 1.038(4) 0.0903(8) 0.082(4) Uani 0.386(8) 1 d PD A 2
O8' O 0.613(3) 0.991(3) 0.0552(7) 0.119(5) Uani 0.386(8) 1 d PD A 2
O9' O 0.843(2) 1.0280(19) 0.0959(7) 0.098(3) Uani 0.386(8) 1 d PD A 2
O10' O 0.594(3) 1.068(2) 0.1215(7) 0.114(5) Uani 0.386(8) 1 d PD A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C46 164.0(3) . .
C1 Ag1 Ag3 116.59(17) . .
C46 Ag1 Ag3 47.96(18) . .
C1 Ag1 Ag6 48.98(18) . 2_575
C46 Ag1 Ag6 115.16(19) . 2_575
Ag3 Ag1 Ag6 70.44(2) . 2_575
C1 Ag1 Ag4 130.01(19) . .
C46 Ag1 Ag4 48.01(19) . .
Ag3 Ag1 Ag4 72.87(3) . .
Ag6 Ag1 Ag4 101.91(3) 2_575 .
C1 Ag1 Ag5 60.67(17) . 2_675
C46 Ag1 Ag5 133.83(18) . 2_675
Ag3 Ag1 Ag5 171.45(3) . 2_675
Ag6 Ag1 Ag5 104.20(2) 2_575 2_675
Ag4 Ag1 Ag5 102.42(3) . 2_675
C1 Ag1 Ag2 43.99(18) . .
C46 Ag1 Ag2 133.63(19) . .
Ag3 Ag1 Ag2 99.93(3) . .
Ag6 Ag1 Ag2 66.13(3) 2_575 .
Ag4 Ag1 Ag2 167.84(3) . .
Ag5 Ag1 Ag2 83.40(2) 2_675 .
C16 Ag2 C1 145.8(2) 1_545 .
C16 Ag2 C2 121.3(2) 1_545 .
C1 Ag2 C2 26.8(2) . .
C16 Ag2 Ag5 42.77(16) 1_545 1_545
C1 Ag2 Ag5 155.07(17) . 1_545
C2 Ag2 Ag5 156.38(14) . 1_545
C16 Ag2 Ag1 158.98(17) 1_545 .
C1 Ag2 Ag1 38.99(16) . .
C2 Ag2 Ag1 65.78(14) . .
Ag5 Ag2 Ag1 122.64(3) 1_545 .
C46 Ag3 C16 164.3(3) . 2_575
C46 Ag3 C17 137.8(2) . 2_575
C16 Ag3 C17 28.50(18) 2_575 2_575
C46 Ag3 C47 26.3(2) . .
C16 Ag3 C47 140.8(2) 2_575 .
C17 Ag3 C47 112.4(2) 2_575 .
C46 Ag3 Ag1 44.55(17) . .
C16 Ag3 Ag1 140.74(15) 2_575 .
C17 Ag3 Ag1 154.22(15) 2_575 .
C47 Ag3 Ag1 69.70(14) . .
C46 Ag3 Ag5 150.55(18) . 2_575
C16 Ag3 Ag5 43.56(16) 2_575 2_575
C17 Ag3 Ag5 71.48(15) 2_575 2_575
C47 Ag3 Ag5 173.97(16) . 2_575
Ag1 Ag3 Ag5 108.96(3) . 2_575
C46 Ag4 C31 143.7(2) . .
C46 Ag4 O8' 101.6(7) . .
C31 Ag4 O8' 110.9(7) . .
C46 Ag4 O8 109.2(4) . .
C31 Ag4 O8 107.1(4) . .
O8' Ag4 O8 23.6(6) . .
C46 Ag4 Ag1 43.13(16) . .
C31 Ag4 Ag1 159.55(19) . .
O8' Ag4 Ag1 77.5(6) . .
O8 Ag4 Ag1 72.8(4) . .
C46 Ag4 Ag5 163.30(18) . .
C31 Ag4 Ag5 40.41(18) . .
O8' Ag4 Ag5 85.3(7) . .
O8 Ag4 Ag5 71.7(4) . .
Ag1 Ag4 Ag5 126.11(4) . .
C31 Ag5 C16 161.4(3) . .
C31 Ag5 Ag6 49.01(19) . .
C16 Ag5 Ag6 112.47(19) . .
C31 Ag5 Ag3 114.35(19) . 2_575
C16 Ag5 Ag3 48.19(18) . 2_575
Ag6 Ag5 Ag3 69.39(2) . 2_575
C31 Ag5 Ag2 126.85(19) . 1_565
C16 Ag5 Ag2 47.16(19) . 1_565
Ag6 Ag5 Ag2 93.92(3) . 1_565
Ag3 Ag5 Ag2 70.04(3) 2_575 1_565
C31 Ag5 Ag4 45.01(19) . .
C16 Ag5 Ag4 138.10(19) . .
Ag6 Ag5 Ag4 76.67(3) . .
Ag3 Ag5 Ag4 107.46(3) 2_575 .
Ag2 Ag5 Ag4 170.44(3) 1_565 .
C31 Ag5 Ag1 137.12(19) . 2_675
C16 Ag5 Ag1 61.33(18) . 2_675
Ag6 Ag5 Ag1 173.65(3) . 2_675
Ag3 Ag5 Ag1 104.36(2) 2_575 2_675
Ag2 Ag5 Ag1 82.63(2) 1_565 2_675
Ag4 Ag5 Ag1 106.89(3) . 2_675
C1 Ag6 C31 164.7(2) 2_575 .
C1 Ag6 C32 137.8(2) 2_575 .
C31 Ag6 C32 27.8(2) . .
C1 Ag6 C2 26.8(2) 2_575 2_575
C31 Ag6 C2 138.1(2) . 2_575
C32 Ag6 C2 111.0(2) . 2_575
C1 Ag6 Ag1 44.33(16) 2_575 2_575
C31 Ag6 Ag1 150.99(18) . 2_575
C32 Ag6 Ag1 169.15(16) . 2_575
C2 Ag6 Ag1 70.73(14) 2_575 2_575
C1 Ag6 Ag5 146.66(17) 2_575 .
C31 Ag6 Ag5 44.50(18) . .
C32 Ag6 Ag5 71.70(15) . .
C2 Ag6 Ag5 159.91(15) 2_575 .
Ag1 Ag6 Ag5 110.54(3) 2_575 .
C4 O1 C3 116.2(5) . .
C19 O2 C18 116.7(6) . .
C35 O3 C33 117.1(5) . .
C49 O4 C48 115.9(5) . .
O5 N1 O7 133.4(12) . .
O5 N1 O6 114.4(10) . .
O7 N1 O6 112.2(10) . .
C2 C1 Ag1 168.3(6) . .
C2 C1 Ag6 96.2(5) . 2_575
Ag1 C1 Ag6 86.7(2) . 2_575
C2 C1 Ag2 93.8(5) . .
Ag1 C1 Ag2 97.0(3) . .
Ag6 C1 Ag2 97.7(2) 2_575 .
C1 C2 C3 173.5(7) . .
C1 C2 Ag2 59.3(4) . .
C3 C2 Ag2 125.6(5) . .
C1 C2 Ag6 57.1(4) . 2_575
C3 C2 Ag6 126.2(5) . 2_575
Ag2 C2 Ag6 79.97(18) . 2_575
O1 C3 C2 107.9(5) . .
O1 C3 H3A 110.1 . .
C2 C3 H3A 110.1 . .
O1 C3 H3B 110.1 . .
C2 C3 H3B 110.1 . .
H3A C3 H3B 108.4 . .
O1 C4 C6 125.9(6) . .
O1 C4 C5 115.4(6) . .
C6 C4 C5 118.7(6) . .
C9 C5 C4 119.9(6) . .
C9 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C7 C6 C4 120.3(6) . .
C7 C6 H6 119.9 . .
C4 C6 H6 119.9 . .
C6 C7 C8 122.3(6) . .
C6 C7 H7 118.9 . .
C8 C7 H7 118.9 . .
C7 C8 C9 116.5(6) . .
C7 C8 C10 121.8(6) . .
C9 C8 C10 121.7(6) . .
C5 C9 C8 122.3(6) . .
C5 C9 H9 118.8 . .
C8 C9 H9 118.8 . .
C15 C10 C11 116.7(6) . .
C15 C10 C8 121.3(6) . .
C11 C10 C8 122.0(6) . .
C12 C11 C10 120.6(7) . .
C12 C11 H11 119.7 . .
C10 C11 H11 119.7 . .
C13 C12 C11 121.3(7) . .
C13 C12 H12 119.3 . .
C11 C12 H12 119.3 . .
C12 C13 C14 119.3(7) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
C13 C14 C15 119.6(7) . .
C13 C14 H14 120.2 . .
C15 C14 H14 120.2 . .
C14 C15 C10 122.4(7) . .
C14 C15 H15 118.8 . .
C10 C15 H15 118.8 . .
C17 C16 Ag5 165.6(6) . .
C17 C16 Ag2 104.3(5) . 1_565
Ag5 C16 Ag2 90.1(2) . 1_565
C17 C16 Ag3 88.2(5) . 2_575
Ag5 C16 Ag3 88.3(2) . 2_575
Ag2 C16 Ag3 101.8(3) 1_565 2_575
C16 C17 C18 174.7(7) . .
C16 C17 Ag3 63.3(4) . 2_575
C18 C17 Ag3 120.8(5) . 2_575
O2 C18 C17 106.1(6) . .
O2 C18 H18A 110.5 . .
C17 C18 H18A 110.5 . .
O2 C18 H18B 110.5 . .
C17 C18 H18B 110.5 . .
H18A C18 H18B 108.7 . .
C24 C19 O2 125.1(6) . .
C24 C19 C20 119.6(7) . .
O2 C19 C20 115.4(7) . .
C21 C20 C19 119.7(7) . .
C21 C20 H20 120.1 . .
C19 C20 H20 120.1 . .
C20 C21 C22 122.0(7) . .
C20 C21 H21 119.0 . .
C22 C21 H21 119.0 . .
C21 C22 C23 116.4(6) . .
C21 C22 C25 122.7(6) . .
C23 C22 C25 120.9(6) . .
C24 C23 C22 122.4(7) . .
C24 C23 H23 118.8 . .
C22 C23 H23 118.8 . .
C23 C24 C19 120.0(7) . .
C23 C24 H24 120.0 . .
C19 C24 H24 120.0 . .
C30 C25 C26 115.5(7) . .
C30 C25 C22 121.7(6) . .
C26 C25 C22 122.8(6) . .
C27 C26 C25 122.0(7) . .
C27 C26 H26 119.0 . .
C25 C26 H26 119.0 . .
C28 C27 C26 120.8(7) . .
C28 C27 H27 119.6 . .
C26 C27 H27 119.6 . .
C27 C28 C29 119.4(7) . .
C27 C28 H28 120.3 . .
C29 C28 H28 120.3 . .
C28 C29 C30 120.2(7) . .
C28 C29 H29 119.9 . .
C30 C29 H29 119.9 . .
C29 C30 C25 122.1(7) . .
C29 C30 H30 118.9 . .
C25 C30 H30 118.9 . .
C32 C31 Ag5 165.9(6) . .
C32 C31 Ag6 90.6(5) . .
Ag5 C31 Ag6 86.5(3) . .
C32 C31 Ag4 99.1(5) . .
Ag5 C31 Ag4 94.6(3) . .
Ag6 C31 Ag4 116.1(3) . .
C31 C32 C33 173.7(8) . .
C31 C32 Ag6 61.6(5) . .
C33 C32 Ag6 121.3(5) . .
O3 C33 C32 108.0(6) . .
O3 C33 H33A 110.1 . .
C32 C33 H33A 110.1 . .
O3 C33 H33B 110.1 . .
C32 C33 H33B 110.1 . .
H33A C33 H33B 108.4 . .
C35 C34 C39 120.7(6) . .
C35 C34 H34 119.7 . .
C39 C34 H34 119.7 . .
C36 C35 O3 125.7(6) . .
C36 C35 C34 119.3(6) . .
O3 C35 C34 115.0(6) . .
C35 C36 C37 119.2(7) . .
C35 C36 H36 120.4 . .
C37 C36 H36 120.4 . .
C38 C37 C36 122.7(6) . .
C38 C37 H37 118.6 . .
C36 C37 H37 118.6 . .
C37 C38 C39 116.9(6) . .
C37 C38 C40 121.9(6) . .
C39 C38 C40 121.2(6) . .
C34 C39 C38 121.2(7) . .
C34 C39 H39 119.4 . .
C38 C39 H39 119.4 . .
C45 C40 C41 118.1(7) . .
C45 C40 C38 121.0(6) . .
C41 C40 C38 120.9(7) . .
C42 C41 C40 120.3(8) . .
C42 C41 H41 119.8 . .
C40 C41 H41 119.8 . .
C43 C42 C41 120.8(7) . .
C43 C42 H42 119.6 . .
C41 C42 H42 119.6 . .
C42 C43 C44 119.3(8) . .
C42 C43 H43 120.4 . .
C44 C43 H43 120.4 . .
C43 C44 C45 120.7(9) . .
C43 C44 H44 119.6 . .
C45 C44 H44 119.6 . .
C40 C45 C44 120.8(7) . .
C40 C45 H45 119.6 . .
C44 C45 H45 119.6 . .
C47 C46 Ag1 159.1(6) . .
C47 C46 Ag3 99.2(5) . .
Ag1 C46 Ag3 87.5(2) . .
C47 C46 Ag4 108.0(5) . .
Ag1 C46 Ag4 88.9(3) . .
Ag3 C46 Ag4 106.1(3) . .
C46 C47 C48 176.0(8) . .
C46 C47 Ag3 54.6(4) . .
C48 C47 Ag3 129.4(5) . .
O4 C48 C47 109.4(6) . .
O4 C48 H48A 109.8 . .
C47 C48 H48A 109.8 . .
O4 C48 H48B 109.8 . .
C47 C48 H48B 109.8 . .
H48A C48 H48B 108.2 . .
C54 C49 C50 119.6(7) . .
C54 C49 O4 116.6(6) . .
C50 C49 O4 123.8(7) . .
C49 C50 C51 119.0(7) . .
C49 C50 H50 120.5 . .
C51 C50 H50 120.5 . .
C52 C51 C50 123.4(7) . .
C52 C51 H51 118.3 . .
C50 C51 H51 118.3 . .
C51 C52 C53 116.5(6) . .
C51 C52 C55 121.2(6) . .
C53 C52 C55 122.3(7) . .
C52 C53 C54 120.8(7) . .
C52 C53 H53 119.6 . .
C54 C53 H53 119.6 . .
C49 C54 C53 120.7(6) . .
C49 C54 H54 119.7 . .
C53 C54 H54 119.7 . .
C56 C55 C60 117.3(7) . .
C56 C55 C52 120.3(7) . .
C60 C55 C52 122.4(6) . .
C57 C56 C55 120.6(7) . .
C57 C56 H56 119.7 . .
C55 C56 H56 119.7 . .
C58 C57 C56 120.8(7) . .
C58 C57 H57 119.6 . .
C56 C57 H57 119.6 . .
C59 C58 C57 119.6(8) . .
C59 C58 H58 120.2 . .
C57 C58 H58 120.2 . .
C58 C59 C60 120.4(8) . .
C58 C59 H59 119.8 . .
C60 C59 H59 119.8 . .
C59 C60 C55 121.2(7) . .
C59 C60 H60 119.4 . .
C55 C60 H60 119.4 . .
O10 N2 O9 123.7(11) . .
O10 N2 O8 117.2(10) . .
O9 N2 O8 118.7(10) . .
N2 O8 O8 162.2(18) . 2_675
N2 O8 Ag4 102.8(8) . .
O8 O8 Ag4 91.9(9) 2_675 .
O9' N2' O10' 120.8(14) . .
O9' N2' O8' 118.7(14) . .
O10' N2' O8' 118.4(14) . .
N2' O8' Ag4 103.4(12) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.089(6) .
Ag1 C46 2.093(6) .
Ag1 Ag3 2.9807(8) .
Ag1 Ag6 2.9851(9) 2_575
Ag1 Ag4 3.0607(9) .
Ag1 Ag5 3.2310(7) 2_675
Ag1 Ag2 3.2960(8) .
Ag2 C16 2.273(7) 1_545
Ag2 C1 2.306(7) .
Ag2 C2 2.676(7) .
Ag2 Ag5 3.0996(10) 1_545
Ag3 C46 2.216(7) .
Ag3 C16 2.277(7) 2_575
Ag3 C17 2.547(6) 2_575
Ag3 C47 2.685(7) .
Ag3 Ag5 3.0532(9) 2_575
Ag4 C46 2.275(7) .
Ag4 C31 2.291(7) .
Ag4 O8' 2.53(2) .
Ag4 O8 2.531(13) .
Ag4 Ag5 3.2292(10) .
Ag5 C31 2.100(7) .
Ag5 C16 2.105(6) .
Ag5 Ag6 2.9907(8) .
Ag5 Ag3 3.0532(9) 2_575
Ag5 Ag2 3.0996(10) 1_565
Ag5 Ag1 3.2310(7) 2_675
Ag6 C1 2.256(7) 2_575
Ag6 C31 2.262(7) .
Ag6 C32 2.571(7) .
Ag6 C2 2.673(6) 2_575
Ag6 Ag1 2.9851(9) 2_575
O1 C4 1.367(8) .
O1 C3 1.421(8) .
O2 C19 1.379(8) .
O2 C18 1.436(8) .
O3 C35 1.377(8) .
O3 C33 1.430(9) .
O4 C49 1.383(8) .
O4 C48 1.415(10) .
O5 N1 1.136(12) .
O6 N1 1.294(12) .
O7 N1 1.186(9) .
C1 C2 1.211(9) .
C1 Ag6 2.256(6) 2_575
C2 C3 1.473(9) .
C2 Ag6 2.673(6) 2_575
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C6 1.382(9) .
C4 C5 1.392(9) .
C5 C9 1.380(9) .
C5 H5 0.9300 .
C6 C7 1.380(10) .
C6 H6 0.9300 .
C7 C8 1.384(9) .
C7 H7 0.9300 .
C8 C9 1.390(9) .
C8 C10 1.484(9) .
C9 H9 0.9300 .
C10 C15 1.386(10) .
C10 C11 1.392(9) .
C11 C12 1.377(10) .
C11 H11 0.9300 .
C12 C13 1.363(11) .
C12 H12 0.9300 .
C13 C14 1.370(11) .
C13 H13 0.9300 .
C14 C15 1.375(10) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.216(7) .
C16 Ag2 2.273(7) 1_565
C16 Ag3 2.277(7) 2_575
C17 C18 1.467(9) .
C17 Ag3 2.547(6) 2_575
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C24 1.369(10) .
C19 C20 1.393(10) .
C20 C21 1.381(10) .
C20 H20 0.9300 .
C21 C22 1.386(10) .
C21 H21 0.9300 .
C22 C23 1.401(9) .
C22 C25 1.480(9) .
C23 C24 1.371(10) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C30 1.401(10) .
C25 C26 1.411(9) .
C26 C27 1.369(11) .
C26 H26 0.9300 .
C27 C28 1.367(11) .
C27 H27 0.9300 .
C28 C29 1.375(10) .
C28 H28 0.9300 .
C29 C30 1.381(10) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 C32 1.198(9) .
C32 C33 1.466(10) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 C35 1.378(10) .
C34 C39 1.379(10) .
C34 H34 0.9300 .
C35 C36 1.375(9) .
C36 C37 1.390(10) .
C36 H36 0.9300 .
C37 C38 1.375(10) .
C37 H37 0.9300 .
C38 C39 1.391(9) .
C38 C40 1.501(9) .
C39 H39 0.9300 .
C40 C45 1.385(11) .
C40 C41 1.387(10) .
C41 C42 1.393(11) .
C41 H41 0.9300 .
C42 C43 1.362(12) .
C42 H42 0.9300 .
C43 C44 1.369(11) .
C43 H43 0.9300 .
C44 C45 1.382(11) .
C44 H44 0.9300 .
C45 H45 0.9300 .
C46 C47 1.204(9) .
C47 C48 1.470(10) .
C48 H48A 0.9700 .
C48 H48B 0.9700 .
C49 C54 1.369(11) .
C49 C50 1.378(10) .
C50 C51 1.383(10) .
C50 H50 0.9300 .
C51 C52 1.375(10) .
C51 H51 0.9300 .
C52 C53 1.398(9) .
C52 C55 1.490(9) .
C53 C54 1.393(10) .
C53 H53 0.9300 .
C54 H54 0.9300 .
C55 C56 1.392(9) .
C55 C60 1.390(10) .
C56 C57 1.381(10) .
C56 H56 0.9300 .
C57 C58 1.363(11) .
C57 H57 0.9300 .
C58 C59 1.362(11) .
C58 H58 0.9300 .
C59 C60 1.378(11) .
C59 H59 0.9300 .
C60 H60 0.9300 .
N2 O10 1.245(15) .
N2 O9 1.225(14) .
N2 O8 1.305(15) .
O8 O8 1.65(2) 2_675
N2' O9' 1.218(18) .
N2' O10' 1.222(19) .
N2' O8' 1.246(19) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ag1 Ag2 C16 116.7(5) . 1_545
C46 Ag1 Ag2 C16 -85.6(5) . 1_545
Ag3 Ag1 Ag2 C16 -125.0(5) . 1_545
Ag6 Ag1 Ag2 C16 171.7(5) 2_575 1_545
Ag4 Ag1 Ag2 C16 -177.7(5) . 1_545
Ag5 Ag1 Ag2 C16 62.9(5) 2_675 1_545
C46 Ag1 Ag2 C1 157.6(4) . .
Ag3 Ag1 Ag2 C1 118.2(3) . .
Ag6 Ag1 Ag2 C1 54.9(3) 2_575 .
Ag4 Ag1 Ag2 C1 65.6(3) . .
Ag5 Ag1 Ag2 C1 -53.8(3) 2_675 .
C1 Ag1 Ag2 C2 2.2(3) . .
C46 Ag1 Ag2 C2 159.8(3) . .
Ag3 Ag1 Ag2 C2 120.37(15) . .
Ag6 Ag1 Ag2 C2 57.07(15) 2_575 .
Ag4 Ag1 Ag2 C2 67.7(2) . .
Ag5 Ag1 Ag2 C2 -51.67(15) 2_675 .
C1 Ag1 Ag2 Ag5 157.0(3) . 1_545
C46 Ag1 Ag2 Ag5 -45.4(3) . 1_545
Ag3 Ag1 Ag2 Ag5 -84.81(4) . 1_545
Ag6 Ag1 Ag2 Ag5 -148.12(4) 2_575 1_545
Ag4 Ag1 Ag2 Ag5 -137.45(13) . 1_545
Ag5 Ag1 Ag2 Ag5 103.14(3) 2_675 1_545
C1 Ag1 Ag3 C46 -175.1(3) . .
Ag6 Ag1 Ag3 C46 -158.1(3) 2_575 .
Ag4 Ag1 Ag3 C46 -48.3(3) . .
Ag2 Ag1 Ag3 C46 141.8(3) . .
C1 Ag1 Ag3 C16 27.2(4) . 2_575
C46 Ag1 Ag3 C16 -157.8(4) . 2_575
Ag6 Ag1 Ag3 C16 44.1(3) 2_575 2_575
Ag4 Ag1 Ag3 C16 153.9(3) . 2_575
Ag2 Ag1 Ag3 C16 -16.0(3) . 2_575
C1 Ag1 Ag3 C17 75.9(4) . 2_575
C46 Ag1 Ag3 C17 -109.0(4) . 2_575
Ag6 Ag1 Ag3 C17 92.8(4) 2_575 2_575
Ag4 Ag1 Ag3 C17 -157.4(4) . 2_575
Ag2 Ag1 Ag3 C17 32.7(4) . 2_575
C1 Ag1 Ag3 C47 175.7(3) . .
C46 Ag1 Ag3 C47 -9.3(3) . .
Ag6 Ag1 Ag3 C47 -167.41(17) 2_575 .
Ag4 Ag1 Ag3 C47 -57.61(17) . .
Ag2 Ag1 Ag3 C47 132.48(17) . .
C1 Ag1 Ag3 Ag5 -10.6(2) . 2_575
C46 Ag1 Ag3 Ag5 164.5(3) . 2_575
Ag6 Ag1 Ag3 Ag5 6.35(3) 2_575 2_575
Ag4 Ag1 Ag3 Ag5 116.15(4) . 2_575
Ag2 Ag1 Ag3 Ag5 -53.77(4) . 2_575
C1 Ag1 Ag4 C46 158.9(3) . .
Ag3 Ag1 Ag4 C46 48.3(2) . .
Ag6 Ag1 Ag4 C46 113.3(2) 2_575 .
Ag5 Ag1 Ag4 C46 -139.1(2) 2_675 .
Ag2 Ag1 Ag4 C46 103.3(3) . .
C1 Ag1 Ag4 C31 38.3(5) . .
C46 Ag1 Ag4 C31 -120.7(6) . .
Ag3 Ag1 Ag4 C31 -72.4(5) . .
Ag6 Ag1 Ag4 C31 -7.4(5) 2_575 .
Ag5 Ag1 Ag4 C31 100.2(5) 2_675 .
Ag2 Ag1 Ag4 C31 -17.4(5) . .
C1 Ag1 Ag4 O8' -78.6(6) . .
C46 Ag1 Ag4 O8' 122.5(6) . .
Ag3 Ag1 Ag4 O8' 170.8(6) . .
Ag6 Ag1 Ag4 O8' -124.2(6) 2_575 .
Ag5 Ag1 Ag4 O8' -16.6(6) 2_675 .
Ag2 Ag1 Ag4 O8' -134.2(6) . .
C1 Ag1 Ag4 O8 -54.6(4) . .
C46 Ag1 Ag4 O8 146.5(4) . .
Ag3 Ag1 Ag4 O8 -165.3(3) . .
Ag6 Ag1 Ag4 O8 -100.3(3) 2_575 .
Ag5 Ag1 Ag4 O8 7.4(3) 2_675 .
Ag2 Ag1 Ag4 O8 -110.2(3) . .
C1 Ag1 Ag4 Ag5 -3.9(2) . .
C46 Ag1 Ag4 Ag5 -162.8(3) . .
Ag3 Ag1 Ag4 Ag5 -114.56(4) . .
Ag6 Ag1 Ag4 Ag5 -49.58(4) 2_575 .
Ag5 Ag1 Ag4 Ag5 58.07(4) 2_675 .
Ag2 Ag1 Ag4 Ag5 -59.54(16) . .
C46 Ag4 Ag5 C31 114.2(6) . .
O8' Ag4 Ag5 C31 -130.3(5) . .
O8 Ag4 Ag5 C31 -150.1(4) . .
Ag1 Ag4 Ag5 C31 158.8(3) . .
C46 Ag4 Ag5 C16 -39.0(6) . .
C31 Ag4 Ag5 C16 -153.2(4) . .
O8' Ag4 Ag5 C16 76.5(5) . .
O8 Ag4 Ag5 C16 56.8(4) . .
Ag1 Ag4 Ag5 C16 5.6(3) . .
C46 Ag4 Ag5 Ag6 69.9(6) . .
C31 Ag4 Ag5 Ag6 -44.3(3) . .
O8' Ag4 Ag5 Ag6 -174.6(4) . .
O8 Ag4 Ag5 Ag6 165.7(3) . .
Ag1 Ag4 Ag5 Ag6 114.54(4) . .
C46 Ag4 Ag5 Ag3 6.9(6) . 2_575
C31 Ag4 Ag5 Ag3 -107.3(3) . 2_575
O8' Ag4 Ag5 Ag3 122.4(4) . 2_575
O8 Ag4 Ag5 Ag3 102.7(3) . 2_575
Ag1 Ag4 Ag5 Ag3 51.53(5) . 2_575
C46 Ag4 Ag5 Ag1 -104.6(6) . 2_675
C31 Ag4 Ag5 Ag1 141.2(3) . 2_675
O8' Ag4 Ag5 Ag1 10.8(4) . 2_675
O8 Ag4 Ag5 Ag1 -8.9(3) . 2_675
Ag1 Ag4 Ag5 Ag1 -60.02(4) . 2_675
C31 Ag5 Ag6 C1 163.1(4) . 2_575
C16 Ag5 Ag6 C1 -19.2(4) . 2_575
Ag3 Ag5 Ag6 C1 -41.3(3) 2_575 2_575
Ag2 Ag5 Ag6 C1 25.6(3) 1_565 2_575
Ag4 Ag5 Ag6 C1 -156.1(3) . 2_575
C16 Ag5 Ag6 C31 177.7(3) . .
Ag3 Ag5 Ag6 C31 155.6(3) 2_575 .
Ag2 Ag5 Ag6 C31 -137.5(3) 1_565 .
Ag4 Ag5 Ag6 C31 40.8(3) . .
C31 Ag5 Ag6 C32 6.7(3) . .
C16 Ag5 Ag6 C32 -175.6(3) . .
Ag3 Ag5 Ag6 C32 162.30(17) 2_575 .
Ag2 Ag5 Ag6 C32 -130.73(17) 1_565 .
Ag4 Ag5 Ag6 C32 47.56(17) . .
C31 Ag5 Ag6 C2 108.1(5) . 2_575
C16 Ag5 Ag6 C2 -74.2(5) . 2_575
Ag3 Ag5 Ag6 C2 -96.3(4) 2_575 2_575
Ag2 Ag5 Ag6 C2 -29.4(4) 1_565 2_575
Ag4 Ag5 Ag6 C2 148.9(4) . 2_575
C31 Ag5 Ag6 Ag1 -162.0(3) . 2_575
C16 Ag5 Ag6 Ag1 15.7(2) . 2_575
Ag3 Ag5 Ag6 Ag1 -6.43(3) 2_575 2_575
Ag2 Ag5 Ag6 Ag1 60.53(3) 1_565 2_575
Ag4 Ag5 Ag6 Ag1 -121.18(3) . 2_575
C46 Ag1 C1 C2 112(3) . .
Ag3 Ag1 C1 C2 126(3) . .
Ag6 Ag1 C1 C2 105(3) 2_575 .
Ag4 Ag1 C1 C2 36(3) . .
Ag5 Ag1 C1 C2 -45(3) 2_675 .
Ag2 Ag1 C1 C2 -158(3) . .
C46 Ag1 C1 Ag6 7.9(10) . 2_575
Ag3 Ag1 C1 Ag6 21.3(2) . 2_575
Ag4 Ag1 C1 Ag6 -68.1(2) . 2_575
Ag5 Ag1 C1 Ag6 -149.5(3) 2_675 2_575
Ag2 Ag1 C1 Ag6 97.4(2) . 2_575
C46 Ag1 C1 Ag2 -89.5(10) . .
Ag3 Ag1 C1 Ag2 -76.1(2) . .
Ag6 Ag1 C1 Ag2 -97.4(2) 2_575 .
Ag4 Ag1 C1 Ag2 -165.50(7) . .
Ag5 Ag1 C1 Ag2 113.1(3) 2_675 .
C16 Ag2 C1 C2 30.4(7) 1_545 .
Ag5 Ag2 C1 C2 124.2(5) 1_545 .
Ag1 Ag2 C1 C2 175.6(6) . .
C16 Ag2 C1 Ag1 -145.3(3) 1_545 .
C2 Ag2 C1 Ag1 -175.6(6) . .
Ag5 Ag2 C1 Ag1 -51.4(5) 1_545 .
C16 Ag2 C1 Ag6 127.1(4) 1_545 2_575
C2 Ag2 C1 Ag6 96.8(5) . 2_575
Ag5 Ag2 C1 Ag6 -139.0(2) 1_545 2_575
Ag1 Ag2 C1 Ag6 -87.6(2) . 2_575
Ag1 C1 C2 Ag2 158(3) . .
Ag6 C1 C2 Ag2 -98.2(3) 2_575 .
Ag1 C1 C2 Ag6 -104(3) . 2_575
Ag2 C1 C2 Ag6 98.2(3) . 2_575
C16 Ag2 C2 C1 -160.6(5) 1_545 .
Ag5 Ag2 C2 C1 -119.6(5) 1_545 .
Ag1 Ag2 C2 C1 -3.0(4) . .
C16 Ag2 C2 C3 14.3(6) 1_545 .
C1 Ag2 C2 C3 174.9(8) . .
Ag5 Ag2 C2 C3 55.3(7) 1_545 .
Ag1 Ag2 C2 C3 171.9(6) . .
C16 Ag2 C2 Ag6 141.9(2) 1_545 2_575
C1 Ag2 C2 Ag6 -57.5(4) . 2_575
Ag5 Ag2 C2 Ag6 -177.1(2) 1_545 2_575
Ag1 Ag2 C2 Ag6 -60.51(10) . 2_575
C4 O1 C3 C2 173.7(6) . .
Ag2 C2 C3 O1 54.8(7) . .
Ag6 C2 C3 O1 -50.1(8) 2_575 .
C3 O1 C4 C6 -4.8(10) . .
C3 O1 C4 C5 176.8(6) . .
O1 C4 C5 C9 178.6(6) . .
C6 C4 C5 C9 0.1(10) . .
O1 C4 C6 C7 -178.3(7) . .
C5 C4 C6 C7 0.0(11) . .
C4 C6 C7 C8 1.0(12) . .
C6 C7 C8 C9 -2.0(11) . .
C6 C7 C8 C10 176.1(7) . .
C4 C5 C9 C8 -1.2(11) . .
C7 C8 C9 C5 2.1(10) . .
C10 C8 C9 C5 -176.0(6) . .
C7 C8 C10 C15 -26.2(10) . .
C9 C8 C10 C15 151.8(7) . .
C7 C8 C10 C11 155.4(7) . .
C9 C8 C10 C11 -26.6(10) . .
C15 C10 C11 C12 0.2(11) . .
C8 C10 C11 C12 178.6(7) . .
C10 C11 C12 C13 -0.4(12) . .
C11 C12 C13 C14 0.6(12) . .
C12 C13 C14 C15 -0.6(12) . .
C13 C14 C15 C10 0.5(12) . .
C11 C10 C15 C14 -0.3(11) . .
C8 C10 C15 C14 -178.7(7) . .
C31 Ag5 C16 C17 -99(2) . .
Ag6 Ag5 C16 C17 -104(2) . .
Ag3 Ag5 C16 C17 -76(2) 2_575 .
Ag2 Ag5 C16 C17 -178(3) 1_565 .
Ag4 Ag5 C16 C17 -9(3) . .
Ag1 Ag5 C16 C17 74(2) 2_675 .
C31 Ag5 C16 Ag2 79.0(8) . 1_565
Ag6 Ag5 C16 Ag2 73.6(2) . 1_565
Ag3 Ag5 C16 Ag2 101.8(3) 2_575 1_565
Ag4 Ag5 C16 Ag2 168.60(7) . 1_565
Ag1 Ag5 C16 Ag2 -107.9(2) 2_675 1_565
C31 Ag5 C16 Ag3 -22.8(9) . 2_575
Ag6 Ag5 C16 Ag3 -28.2(2) . 2_575
Ag2 Ag5 C16 Ag3 -101.8(3) 1_565 2_575
Ag4 Ag5 C16 Ag3 66.8(3) . 2_575
Ag1 Ag5 C16 Ag3 150.3(3) 2_675 2_575
Ag5 C16 C17 Ag3 76(2) . 2_575
Ag2 C16 C17 Ag3 -101.7(3) 1_565 2_575
C19 O2 C18 C17 174.0(6) . .
Ag3 C17 C18 O2 -47.3(7) 2_575 .
C18 O2 C19 C24 -0.1(10) . .
C18 O2 C19 C20 -179.5(6) . .
C24 C19 C20 C21 -1.2(11) . .
O2 C19 C20 C21 178.2(7) . .
C19 C20 C21 C22 0.1(12) . .
C20 C21 C22 C23 0.9(11) . .
C20 C21 C22 C25 -179.7(6) . .
C21 C22 C23 C24 -0.8(10) . .
C25 C22 C23 C24 179.8(7) . .
C22 C23 C24 C19 -0.2(11) . .
O2 C19 C24 C23 -178.1(7) . .
C20 C19 C24 C23 1.3(11) . .
C21 C22 C25 C30 -162.1(7) . .
C23 C22 C25 C30 17.3(10) . .
C21 C22 C25 C26 19.2(10) . .
C23 C22 C25 C26 -161.4(7) . .
C30 C25 C26 C27 0.2(10) . .
C22 C25 C26 C27 179.0(7) . .
C25 C26 C27 C28 -0.1(12) . .
C26 C27 C28 C29 -0.2(12) . .
C27 C28 C29 C30 0.3(12) . .
C28 C29 C30 C25 -0.1(12) . .
C26 C25 C30 C29 -0.1(10) . .
C22 C25 C30 C29 -178.9(7) . .
C16 Ag5 C31 C32 -85(3) . .
Ag6 Ag5 C31 C32 -79(2) . .
Ag3 Ag5 C31 C32 -104(2) 2_575 .
Ag2 Ag5 C31 C32 -21(3) 1_565 .
Ag4 Ag5 C31 C32 166(3) . .
Ag1 Ag5 C31 C32 104(2) 2_675 .
C16 Ag5 C31 Ag6 -6.7(9) . .
Ag3 Ag5 C31 Ag6 -25.1(3) 2_575 .
Ag2 Ag5 C31 Ag6 57.4(3) 1_565 .
Ag4 Ag5 C31 Ag6 -115.9(3) . .
Ag1 Ag5 C31 Ag6 -177.69(6) 2_675 .
C16 Ag5 C31 Ag4 109.2(8) . .
Ag6 Ag5 C31 Ag4 115.9(3) . .
Ag3 Ag5 C31 Ag4 90.8(2) 2_575 .
Ag2 Ag5 C31 Ag4 173.35(6) 1_565 .
Ag1 Ag5 C31 Ag4 -61.8(3) 2_675 .
C1 Ag6 C31 C32 23.4(12) 2_575 .
C2 Ag6 C31 C32 15.5(7) 2_575 .
Ag1 Ag6 C31 C32 -157.2(4) 2_575 .
Ag5 Ag6 C31 C32 166.2(6) . .
C1 Ag6 C31 Ag5 -142.8(8) 2_575 .
C32 Ag6 C31 Ag5 -166.2(6) . .
C2 Ag6 C31 Ag5 -150.7(2) 2_575 .
Ag1 Ag6 C31 Ag5 36.6(5) 2_575 .
C1 Ag6 C31 Ag4 123.8(8) 2_575 .
C32 Ag6 C31 Ag4 100.4(6) . .
C2 Ag6 C31 Ag4 115.9(3) 2_575 .
Ag1 Ag6 C31 Ag4 -56.8(5) 2_575 .
Ag5 Ag6 C31 Ag4 -93.4(3) . .
C46 Ag4 C31 C32 29.8(7) . .
O8' Ag4 C31 C32 -122.1(7) . .
O8 Ag4 C31 C32 -146.8(5) . .
Ag1 Ag4 C31 C32 126.7(5) . .
Ag5 Ag4 C31 C32 -176.5(7) . .
C46 Ag4 C31 Ag5 -153.7(3) . .
O8' Ag4 C31 Ag5 54.4(6) . .
O8 Ag4 C31 Ag5 29.7(4) . .
Ag1 Ag4 C31 Ag5 -56.8(6) . .
C46 Ag4 C31 Ag6 -65.4(6) . .
O8' Ag4 C31 Ag6 142.7(6) . .
O8 Ag4 C31 Ag6 118.0(4) . .
Ag1 Ag4 C31 Ag6 31.5(7) . .
Ag5 Ag4 C31 Ag6 88.3(4) . .
Ag5 C31 C32 Ag6 78(2) . .
Ag4 C31 C32 Ag6 -116.5(3) . .
C1 Ag6 C32 C31 -171.0(5) 2_575 .
C2 Ag6 C32 C31 -169.0(5) 2_575 .
Ag1 Ag6 C32 C31 93.6(9) 2_575 .
Ag5 Ag6 C32 C31 -10.2(5) . .
C1 Ag6 C32 C33 2.6(8) 2_575 .
C31 Ag6 C32 C33 173.6(9) . .
C2 Ag6 C32 C33 4.6(7) 2_575 .
Ag1 Ag6 C32 C33 -92.8(10) 2_575 .
Ag5 Ag6 C32 C33 163.4(6) . .
C35 O3 C33 C32 169.8(6) . .
Ag6 C32 C33 O3 161.4(5) . .
C33 O3 C35 C36 2.9(11) . .
C33 O3 C35 C34 -176.4(7) . .
C39 C34 C35 C36 -1.0(11) . .
C39 C34 C35 O3 178.4(6) . .
O3 C35 C36 C37 -177.8(7) . .
C34 C35 C36 C37 1.5(11) . .
C35 C36 C37 C38 -0.4(12) . .
C36 C37 C38 C39 -1.2(11) . .
C36 C37 C38 C40 179.7(7) . .
C35 C34 C39 C38 -0.7(11) . .
C37 C38 C39 C34 1.8(10) . .
C40 C38 C39 C34 -179.1(6) . .
C37 C38 C40 C45 154.0(7) . .
C39 C38 C40 C45 -25.0(10) . .
C37 C38 C40 C41 -26.0(10) . .
C39 C38 C40 C41 154.9(7) . .
C45 C40 C41 C42 -0.2(11) . .
C38 C40 C41 C42 179.9(7) . .
C40 C41 C42 C43 1.3(12) . .
C41 C42 C43 C44 -1.4(13) . .
C42 C43 C44 C45 0.5(13) . .
C41 C40 C45 C44 -0.8(11) . .
C38 C40 C45 C44 179.2(7) . .
C43 C44 C45 C40 0.6(13) . .
C1 Ag1 C46 C47 125.6(16) . .
Ag3 Ag1 C46 C47 109.3(17) . .
Ag6 Ag1 C46 C47 132.2(16) 2_575 .
Ag4 Ag1 C46 C47 -144.5(18) . .
Ag5 Ag1 C46 C47 -82.1(17) 2_675 .
Ag2 Ag1 C46 C47 51.9(17) . .
C1 Ag1 C46 Ag3 16.2(11) . .
Ag6 Ag1 C46 Ag3 22.8(3) 2_575 .
Ag4 Ag1 C46 Ag3 106.2(3) . .
Ag5 Ag1 C46 Ag3 168.57(5) 2_675 .
Ag2 Ag1 C46 Ag3 -57.4(3) . .
C1 Ag1 C46 Ag4 -89.9(9) . .
Ag3 Ag1 C46 Ag4 -106.2(3) . .
Ag6 Ag1 C46 Ag4 -83.34(19) 2_575 .
Ag5 Ag1 C46 Ag4 62.4(3) 2_675 .
Ag2 Ag1 C46 Ag4 -163.55(7) . .
C16 Ag3 C46 C47 -42.3(11) 2_575 .
C17 Ag3 C46 C47 -17.8(7) 2_575 .
Ag1 Ag3 C46 C47 -160.0(7) . .
Ag5 Ag3 C46 C47 169.0(4) 2_575 .
C16 Ag3 C46 Ag1 117.7(8) 2_575 .
C17 Ag3 C46 Ag1 142.2(3) 2_575 .
C47 Ag3 C46 Ag1 160.0(7) . .
Ag5 Ag3 C46 Ag1 -31.0(5) 2_575 .
C16 Ag3 C46 Ag4 -154.2(7) 2_575 .
C17 Ag3 C46 Ag4 -129.7(3) 2_575 .
C47 Ag3 C46 Ag4 -111.9(6) . .
Ag1 Ag3 C46 Ag4 88.1(3) . .
Ag5 Ag3 C46 Ag4 57.1(5) 2_575 .
C31 Ag4 C46 C47 -43.1(8) . .
O8' Ag4 C46 C47 110.2(7) . .
O8 Ag4 C46 C47 133.4(6) . .
Ag1 Ag4 C46 C47 167.4(7) . .
Ag5 Ag4 C46 C47 -136.5(5) . .
C31 Ag4 C46 Ag1 149.5(3) . .
O8' Ag4 C46 Ag1 -57.2(5) . .
O8 Ag4 C46 Ag1 -34.0(4) . .
Ag5 Ag4 C46 Ag1 56.1(7) . .
C31 Ag4 C46 Ag3 62.5(5) . .
O8' Ag4 C46 Ag3 -144.3(5) . .
O8 Ag4 C46 Ag3 -121.0(3) . .
Ag1 Ag4 C46 Ag3 -87.1(3) . .
Ag5 Ag4 C46 Ag3 -31.0(7) . .
Ag1 C46 C47 Ag3 -107.3(17) . .
Ag4 C46 C47 Ag3 110.3(4) . .
C16 Ag3 C47 C46 163.3(5) 2_575 .
C17 Ag3 C47 C46 167.2(5) 2_575 .
Ag1 Ag3 C47 C46 14.8(5) . .
C46 Ag3 C47 C48 179.1(10) . .
C16 Ag3 C47 C48 -17.6(8) 2_575 .
C17 Ag3 C47 C48 -13.7(7) 2_575 .
Ag1 Ag3 C47 C48 -166.1(7) . .
C49 O4 C48 C47 175.4(6) . .
Ag3 C47 C48 O4 93.9(7) . .
C48 O4 C49 C54 -171.9(6) . .
C48 O4 C49 C50 8.4(10) . .
C54 C49 C50 C51 2.3(11) . .
O4 C49 C50 C51 -177.9(7) . .
C49 C50 C51 C52 -1.9(12) . .
C50 C51 C52 C53 0.4(11) . .
C50 C51 C52 C55 179.9(7) . .
C51 C52 C53 C54 0.7(10) . .
C55 C52 C53 C54 -178.8(6) . .
C50 C49 C54 C53 -1.3(11) . .
O4 C49 C54 C53 178.9(6) . .
C52 C53 C54 C49 -0.2(11) . .
C51 C52 C55 C56 19.7(10) . .
C53 C52 C55 C56 -160.8(6) . .
C51 C52 C55 C60 -157.8(7) . .
C53 C52 C55 C60 21.7(10) . .
C60 C55 C56 C57 -0.3(10) . .
C52 C55 C56 C57 -177.9(6) . .
C55 C56 C57 C58 0.1(12) . .
C56 C57 C58 C59 -0.5(12) . .
C57 C58 C59 C60 1.0(13) . .
C58 C59 C60 C55 -1.1(13) . .
C56 C55 C60 C59 0.8(11) . .
C52 C55 C60 C59 178.3(7) . .
O10 N2 O8 O8 136(6) . 2_675
O9 N2 O8 O8 -37(7) . 2_675
O10 N2 O8 Ag4 -9(2) . .
O9 N2 O8 Ag4 177.9(14) . .
C46 Ag4 O8 N2 -88.8(12) . .
C31 Ag4 O8 N2 89.0(12) . .
O8' Ag4 O8 N2 -14(2) . .
Ag1 Ag4 O8 N2 -112.4(12) . .
Ag5 Ag4 O8 N2 108.8(12) . .
C46 Ag4 O8 O8 101.2(12) . 2_675
C31 Ag4 O8 O8 -80.9(12) . 2_675
O8' Ag4 O8 O8 176(3) . 2_675
Ag1 Ag4 O8 O8 77.7(12) . 2_675
Ag5 Ag4 O8 O8 -61.2(12) . 2_675
O9' N2' O8' Ag4 170(3) . .
O10' N2' O8' Ag4 6(4) . .
C46 Ag4 O8' N2' -99(3) . .
C31 Ag4 O8' N2' 65(3) . .
O8 Ag4 O8' N2' 150(4) . .
Ag1 Ag4 O8' N2' -135(3) . .
Ag5 Ag4 O8' N2' 96(3) . .
