#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:25:06 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180428 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/97/7209794.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7209794
loop_
_publ_author_name
'Li, Bo'
'Huang, Ren-Wu'
'Zang, Shuang-Quan'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of silver(i)--organic frameworks from flexible supramolecular
 synthons with pendant ethynide arm attached to biphenyl and
 phenoxybenzene skeletons
;
_journal_issue                   20
_journal_name_full               CrystEngComm
_journal_page_first              4087
_journal_paper_doi               10.1039/c3ce40230d
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C36 H22 Ag5 F9 O10'
_chemical_formula_weight         1324.89
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 127.60(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   32.536(6)
_cell_length_b                   11.670(2)
_cell_length_c                   26.226(5)
_cell_measurement_temperature    293(2)
_cell_volume                     7890(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0993
_diffrn_reflns_av_sigmaI/netI    0.0753
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            38968
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.92
_exptl_absorpt_coefficient_mu    2.537
_exptl_absorpt_correction_T_max  0.6723
_exptl_absorpt_correction_T_min  0.6309
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    2.231
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5072
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_refine_diff_density_max         2.460
_refine_diff_density_min         -1.221
_refine_diff_density_rms         0.186
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     552
_refine_ls_number_reflns         6954
_refine_ls_number_restraints     96
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.1495
_refine_ls_R_factor_gt           0.1255
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.3573P)²+37.4474P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.4347
_refine_ls_wR_factor_ref         0.4614
_reflns_number_gt                5691
_reflns_number_total             6954
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40230d.txt
_cod_data_source_block           5
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7209794
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.24377(6) -0.08949(15) 0.20089(8) 0.0557(6) Uani 1 1 d . . .
Ag2 Ag 0.27768(9) -0.03868(17) 0.33774(11) 0.0735(7) Uani 1 1 d U . .
Ag3 Ag 0.34435(8) 0.03415(14) 0.26332(10) 0.0623(6) Uani 1 1 d . . .
Ag4 Ag 0.33494(7) 0.19810(16) 0.34962(9) 0.0591(6) Uani 1 1 d . . .
Ag5 Ag 0.23086(8) 0.17174(16) 0.23046(8) 0.0630(6) Uani 1 1 d . . .
C1 C 0.2628(10) 0.149(2) 0.3307(12) 0.064(7) Uani 1 1 d D . .
C2 C 0.2440(8) 0.1441(17) 0.3584(9) 0.051(5) Uani 1 1 d D . .
C3 C 0.2197(9) 0.160(2) 0.3901(12) 0.059(6) Uani 1 1 d . . .
H3A H 0.1918 0.1045 0.3730 0.070 Uiso 1 1 calc R . .
H3B H 0.2451 0.1452 0.4359 0.070 Uiso 1 1 calc R . .
C4 C 0.1531(8) 0.2954(17) 0.3214(9) 0.044(4) Uani 1 1 d U . .
C5 C 0.1200(8) 0.2222(17) 0.2679(10) 0.048(5) Uani 1 1 d . . .
H5 H 0.1301 0.1469 0.2694 0.058 Uiso 1 1 calc R . .
C6 C 0.0744(10) 0.260(2) 0.2152(13) 0.065(6) Uani 1 1 d . . .
H6 H 0.0526 0.2088 0.1819 0.078 Uiso 1 1 calc R . .
C7 C 0.0589(11) 0.374(2) 0.2091(13) 0.069(7) Uani 1 1 d . . .
C8 C 0.0895(9) 0.449(2) 0.2593(12) 0.055(5) Uani 1 1 d . . .
H8 H 0.0789 0.5248 0.2561 0.066 Uiso 1 1 calc R . .
C9 C 0.1367(9) 0.411(2) 0.3151(11) 0.064(7) Uani 1 1 d . . .
H9 H 0.1578 0.4619 0.3487 0.077 Uiso 1 1 calc R . .
C10 C -0.0084(8) 0.517(2) 0.1373(13) 0.074(8) Uani 1 1 d D . .
C11 C 0.0032(9) 0.589(3) 0.1076(11) 0.070(8) Uani 1 1 d . . .
H11 H 0.0235 0.5639 0.0960 0.084 Uiso 1 1 calc R . .
C12 C -0.0147(10) 0.697(2) 0.0947(11) 0.066(7) Uani 1 1 d . . .
H12 H -0.0054 0.7472 0.0759 0.079 Uiso 1 1 calc R . .
C24 C 0.3759(8) -0.0519(18) 0.4698(12) 0.056(6) Uani 1 1 d . . .
H13 H 0.3696 -0.1303 0.4630 0.067 Uiso 1 1 calc R . .
C14 C -0.0558(14) 0.665(3) 0.1398(19) 0.094(10) Uani 1 1 d . . .
H14 H -0.0752 0.6933 0.1523 0.112 Uiso 1 1 calc R . .
C15 C -0.0384(12) 0.553(3) 0.1551(14) 0.082(9) Uani 1 1 d D . .
H15 H -0.0465 0.5053 0.1761 0.099 Uiso 1 1 calc R . .
C16 C 0.3177(8) -0.1082(15) 0.2914(11) 0.048(5) Uani 1 1 d . . .
C17 C 0.3581(9) -0.1330(18) 0.3407(9) 0.056(6) Uani 1 1 d . . .
C18 C 0.4088(10) -0.159(2) 0.4030(11) 0.063(6) Uani 1 1 d . . .
H18A H 0.4036 -0.2135 0.4266 0.075 Uiso 1 1 calc R . .
H18B H 0.4312 -0.1952 0.3949 0.075 Uiso 1 1 calc R . .
C19 C 0.4069(6) 0.0029(18) 0.4585(7) 0.038(4) Uani 1 1 d . . .
C20 C 0.4181(9) 0.121(2) 0.4731(10) 0.066(7) Uani 1 1 d . . .
H20 H 0.4409 0.1565 0.4680 0.079 Uiso 1 1 calc R . .
C21 C 0.3965(8) 0.183(2) 0.4940(11) 0.054(5) Uani 1 1 d U . .
H21 H 0.4026 0.2609 0.5011 0.065 Uiso 1 1 calc R . .
C22 C 0.3656(8) 0.1284(19) 0.5048(10) 0.052(5) Uani 1 1 d . . .
C23 C 0.3556(9) 0.0097(19) 0.4905(11) 0.057(6) Uani 1 1 d . . .
H23 H 0.3331 -0.0260 0.4962 0.068 Uiso 1 1 calc R . .
C25 C 0.3603(12) 0.290(2) 0.5560(12) 0.073(8) Uani 1 1 d . . .
C26 C 0.321(2) 0.380(3) 0.514(2) 0.130(17) Uani 1 1 d . . .
H26 H 0.2899 0.3657 0.4734 0.156 Uiso 1 1 calc R . .
C27 C 0.336(2) 0.489(4) 0.545(2) 0.139(15) Uani 1 1 d U . .
H27 H 0.3143 0.5512 0.5236 0.167 Uiso 1 1 calc R . .
C28 C 0.3787(12) 0.502(3) 0.5992(16) 0.087(8) Uani 1 1 d U . .
H28 H 0.3849 0.5754 0.6157 0.104 Uiso 1 1 calc R . .
C29 C 0.420(2) 0.419(4) 0.642(3) 0.143(15) Uani 1 1 d U . .
H29 H 0.4523 0.4374 0.6800 0.171 Uiso 1 1 calc R . .
C30 C 0.4053(13) 0.306(3) 0.6160(16) 0.100(11) Uani 1 1 d . . .
H30 H 0.4262 0.2439 0.6402 0.121 Uiso 1 1 calc R . .
C31 C 0.1398(10) 0.010(2) 0.1104(14) 0.066(7) Uani 1 1 d . A .
C32 C 0.0803(12) 0.0092(15) 0.0491(15) 0.089(5) Uani 1 1 d DU . .
C33 C 0.2556(10) 0.2039(19) 0.1395(11) 0.058(6) Uani 1 1 d . A .
C34 C 0.2600(16) 0.250(3) 0.0876(17) 0.093(10) Uani 1 1 d . . .
C35 C 0.3873(8) 0.281(2) 0.2911(12) 0.056(6) Uani 1 1 d . . .
C36 C 0.4043(13) 0.383(3) 0.2718(16) 0.083(8) Uani 1 1 d U . .
C13 C -0.0464(13) 0.733(3) 0.1089(14) 0.085(9) Uani 1 1 d . . .
H36 H -0.0613 0.8055 0.0966 0.101 Uiso 1 1 calc R . .
F1 F 0.0501(9) 0.067(2) 0.0587(12) 0.089(5) Uani 0.689(19) 1 d PDU A 1
F2 F 0.0603(8) -0.0959(16) 0.0296(12) 0.094(9) Uani 0.689(19) 1 d PD A 1
F2' F 0.0685(17) -0.040(3) -0.0025(19) 0.094(9) Uani 0.311(19) 1 d PD A 2
F1' F 0.0533(19) 0.099(4) 0.017(2) 0.089(5) Uani 0.311(19) 1 d PDU A 2
F3 F 0.0800(15) 0.061(3) 0.0033(18) 0.166(13) Uani 0.82(4) 1 d PDU A 1
F3' F 0.049(5) -0.037(3) 0.057(6) 0.166(13) Uani 0.18(4) 1 d PD A 2
F4 F 0.2130(10) 0.253(2) 0.0307(9) 0.138(9) Uani 1 1 d . . .
F5 F 0.2715(13) 0.361(2) 0.0957(14) 0.149(9) Uani 1 1 d . . .
F6 F 0.2893(15) 0.196(2) 0.0822(17) 0.199(18) Uani 1 1 d . . .
F7 F 0.3645(9) 0.4471(19) 0.2341(15) 0.194(17) Uani 1 1 d . . .
F8 F 0.4272(12) 0.358(2) 0.2496(14) 0.151(10) Uani 1 1 d . . .
F9 F 0.4416(11) 0.4449(19) 0.3273(13) 0.143(9) Uani 1 1 d . . .
O1 O 0.4345(6) -0.0550(15) 0.4427(8) 0.062(4) Uani 1 1 d . . .
O2 O 0.3439(8) 0.1805(17) 0.5308(11) 0.091(6) Uani 1 1 d . . .
O3 O 0.1997(6) 0.2718(15) 0.3806(8) 0.061(4) Uani 1 1 d . . .
O4 O 0.0105(7) 0.4018(15) 0.1505(8) 0.080(6) Uani 1 1 d . . .
O5 O 0.1527(7) 0.0960(14) 0.1433(10) 0.097(8) Uani 1 1 d . . .
O6 O 0.1639(6) -0.0726(13) 0.1150(7) 0.056(4) Uani 1 1 d . . .
O7 O 0.2632(8) 0.0980(17) 0.1476(10) 0.083(6) Uani 1 1 d . . .
O8 O 0.2444(7) 0.2677(15) 0.1638(9) 0.067(4) Uani 1 1 d . . .
O9 O 0.3738(9) 0.1964(16) 0.2550(10) 0.081(5) Uani 1 1 d . . .
O10 O 0.3864(7) 0.2868(16) 0.3356(11) 0.080(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C16 Ag1 O6 172.5(7) . .
C16 Ag1 Ag3 47.3(5) . .
O6 Ag1 Ag3 137.9(4) . .
C16 Ag1 Ag2 50.6(6) . .
O6 Ag1 Ag2 122.5(4) . .
Ag3 Ag1 Ag2 77.07(7) . .
C16 Ag1 Ag5 63.0(5) . 4_545
O6 Ag1 Ag5 113.8(4) . 4_545
Ag3 Ag1 Ag5 107.29(7) . 4_545
Ag2 Ag1 Ag5 73.91(6) . 4_545
C16 Ag1 Ag4 117.1(5) . 4_545
O6 Ag1 Ag4 59.6(4) . 4_545
Ag3 Ag1 Ag4 158.35(8) . 4_545
Ag2 Ag1 Ag4 104.83(8) . 4_545
Ag5 Ag1 Ag4 54.31(6) 4_545 4_545
C16 Ag1 Ag5 93.1(5) . .
O6 Ag1 Ag5 85.1(4) . .
Ag3 Ag1 Ag5 70.90(6) . .
Ag2 Ag1 Ag5 63.19(6) . .
Ag5 Ag1 Ag5 136.49(6) 4_545 .
Ag4 Ag1 Ag5 129.67(7) 4_545 .
C1 Ag2 O8 152.9(7) . 4_545
C1 Ag2 C16 116.6(6) . .
O8 Ag2 C16 85.5(6) 4_545 .
O8 Ag2 C2 128.6(6) 4_545 .
C16 Ag2 C2 144.2(6) . .
C1 Ag2 Ag1 100.7(6) . .
O8 Ag2 Ag1 84.7(4) 4_545 .
C16 Ag2 Ag1 43.1(5) . .
C2 Ag2 Ag1 120.0(4) . .
C1 Ag2 Ag4 41.6(6) . .
O8 Ag2 Ag4 165.5(4) 4_545 .
C16 Ag2 Ag4 83.1(5) . .
C2 Ag2 Ag4 64.6(4) . .
Ag1 Ag2 Ag4 92.98(8) . .
C1 Ag2 Ag5 40.4(6) . .
O8 Ag2 Ag5 135.6(5) 4_545 .
C16 Ag2 Ag5 86.1(5) . .
C2 Ag2 Ag5 62.4(4) . .
Ag1 Ag2 Ag5 60.38(6) . .
Ag4 Ag2 Ag5 52.46(6) . .
C16 Ag3 O9 166.3(8) . .
C16 Ag3 C17 26.3(8) . .
O9 Ag3 C17 146.4(8) . .
C16 Ag3 Ag1 45.2(6) . .
O9 Ag3 Ag1 139.6(6) . .
C17 Ag3 Ag1 71.4(5) . .
C16 Ag3 Ag4 89.3(6) . .
O9 Ag3 Ag4 77.6(5) . .
C17 Ag3 Ag4 86.6(5) . .
Ag1 Ag3 Ag4 97.72(7) . .
C1 Ag4 O10 157.8(8) . .
C1 Ag4 Ag5 48.2(6) . .
O10 Ag4 Ag5 112.3(6) . .
C1 Ag4 Ag3 104.1(7) . .
O10 Ag4 Ag3 75.2(6) . .
Ag5 Ag4 Ag3 73.74(7) . .
C1 Ag4 Ag1 68.3(6) . 4
O10 Ag4 Ag1 93.7(5) . 4
Ag5 Ag4 Ag1 61.61(6) . 4
Ag3 Ag4 Ag1 125.51(8) . 4
C1 Ag4 Ag2 43.0(6) . .
O10 Ag4 Ag2 147.6(5) . .
Ag5 Ag4 Ag2 65.23(6) . .
Ag3 Ag4 Ag2 73.27(6) . .
Ag1 Ag4 Ag2 110.58(7) 4 .
C1 Ag5 O8 142.7(9) . .
C1 Ag5 O5 124.9(10) . .
O8 Ag5 O5 92.3(8) . .
C1 Ag5 Ag4 47.8(7) . .
O8 Ag5 Ag4 97.2(5) . .
O5 Ag5 Ag4 163.6(4) . .
C1 Ag5 Ag1 69.7(7) . 4
O8 Ag5 Ag1 84.3(4) . 4
O5 Ag5 Ag1 130.5(4) . 4
Ag4 Ag5 Ag1 64.08(6) . 4
C1 Ag5 Ag1 97.8(6) . .
O8 Ag5 Ag1 99.3(4) . .
O5 Ag5 Ag1 68.3(4) . .
Ag4 Ag5 Ag1 96.96(7) . .
Ag1 Ag5 Ag1 161.03(7) 4 .
C1 Ag5 Ag2 41.4(6) . .
O8 Ag5 Ag2 142.2(4) . .
O5 Ag5 Ag2 102.3(5) . .
Ag4 Ag5 Ag2 62.31(7) . .
Ag1 Ag5 Ag2 110.23(7) 4 .
Ag1 Ag5 Ag2 56.43(6) . .
C2 C1 Ag4 139(2) . .
C2 C1 Ag5 134(2) . .
Ag4 C1 Ag5 84.0(6) . .
C2 C1 Ag2 94.1(16) . .
Ag4 C1 Ag2 95.4(7) . .
Ag5 C1 Ag2 98.2(10) . .
C1 C2 C3 170(2) . .
C1 C2 Ag2 58.3(14) . .
C3 C2 Ag2 131.4(14) . .
O3 C3 C2 111.3(16) . .
O3 C3 H3A 109.4 . .
C2 C3 H3A 109.4 . .
O3 C3 H3B 109.4 . .
C2 C3 H3B 109.4 . .
H3A C3 H3B 108.0 . .
C5 C4 O3 129.8(19) . .
C5 C4 C9 116.8(18) . .
O3 C4 C9 113.4(18) . .
C6 C5 C4 121(2) . .
C6 C5 H5 119.5 . .
C4 C5 H5 119.5 . .
C5 C6 C7 122(2) . .
C5 C6 H6 119.2 . .
C7 C6 H6 119.2 . .
C8 C7 C6 120(3) . .
C8 C7 O4 125(2) . .
C6 C7 O4 115(2) . .
C7 C8 C9 119(2) . .
C7 C8 H8 120.5 . .
C9 C8 H8 120.5 . .
C4 C9 C8 121(2) . .
C4 C9 H9 119.3 . .
C8 C9 H9 119.3 . .
C11 C10 C15 121(3) . .
C11 C10 O4 120(2) . .
C15 C10 O4 120(3) . .
C12 C11 C10 120(3) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C13 120(3) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C23 C24 C19 117(2) . .
C23 C24 H13 121.3 . .
C19 C24 H13 121.3 . .
C13 C14 C15 123(3) . .
C13 C14 H14 118.4 . .
C15 C14 H14 118.4 . .
C10 C15 C14 116(3) . .
C10 C15 H15 122.0 . .
C14 C15 H15 122.0 . .
C17 C16 Ag1 171.8(18) . .
C17 C16 Ag3 98.5(17) . .
Ag1 C16 Ag3 87.5(8) . .
C17 C16 Ag2 96.5(17) . .
Ag1 C16 Ag2 86.4(7) . .
Ag3 C16 Ag2 111.1(8) . .
C16 C17 C18 178(2) . .
C16 C17 Ag3 55.2(13) . .
C18 C17 Ag3 123.5(17) . .
O1 C18 C17 112.0(19) . .
O1 C18 H18A 109.2 . .
C17 C18 H18A 109.2 . .
O1 C18 H18B 109.2 . .
C17 C18 H18B 109.2 . .
H18A C18 H18B 107.9 . .
O1 C19 C24 122.6(19) . .
O1 C19 C20 116.9(17) . .
C24 C19 C20 120(2) . .
C21 C20 C19 121(2) . .
C21 C20 H20 119.3 . .
C19 C20 H20 119.3 . .
C20 C21 C22 119(2) . .
C20 C21 H21 120.7 . .
C22 C21 H21 120.7 . .
C21 C22 O2 124(2) . .
C21 C22 C23 119(2) . .
O2 C22 C23 117.2(19) . .
C24 C23 C22 124(2) . .
C24 C23 H23 117.9 . .
C22 C23 H23 117.9 . .
C30 C25 O2 121(3) . .
C30 C25 C26 126(3) . .
O2 C25 C26 113(3) . .
C27 C26 C25 111(4) . .
C27 C26 H26 124.3 . .
C25 C26 H26 124.3 . .
C28 C27 C26 121(5) . .
C28 C27 H27 119.5 . .
C26 C27 H27 119.5 . .
C29 C28 C27 130(4) . .
C29 C28 H28 114.8 . .
C27 C28 H28 114.8 . .
C28 C29 C30 111(4) . .
C28 C29 H29 124.5 . .
C30 C29 H29 124.5 . .
C25 C30 C29 120(4) . .
C25 C30 H30 120.2 . .
C29 C30 H30 120.2 . .
O6 C31 O5 132(3) . .
O6 C31 C32 114(2) . .
O5 C31 C32 113.7(17) . .
F2' C32 F3' 103(4) . .
F2' C32 F1' 92(3) . .
F3' C32 F1' 98(5) . .
F2' C32 F1 130(4) . .
F3' C32 F1 55.0(9) . .
F1' C32 F1 54.8(9) . .
F2' C32 F3 55.1(9) . .
F3' C32 F3 140(8) . .
F1' C32 F3 55.0(9) . .
F1 C32 F3 109.7(17) . .
F2' C32 F2 55.1(9) . .
F3' C32 F2 55.0(9) . .
F1' C32 F2 121(4) . .
F1 C32 F2 107(2) . .
F3 C32 F2 109.7(19) . .
F2' C32 C31 118(3) . .
F3' C32 C31 116(7) . .
F1' C32 C31 125(3) . .
F1 C32 C31 113(2) . .
F3 C32 C31 104(3) . .
F2 C32 C31 114(2) . .
O8 C33 O7 129(2) . .
O8 C33 C34 119(2) . .
O7 C33 C34 112(2) . .
F6 C34 F5 111(4) . .
F6 C34 F4 109(3) . .
F5 C34 F4 100(3) . .
F6 C34 C33 115(3) . .
F5 C34 C33 112(2) . .
F4 C34 C33 109(3) . .
O10 C35 O9 126(2) . .
O10 C35 C36 121(3) . .
O9 C35 C36 113(2) . .
F8 C36 F7 113(4) . .
F8 C36 F9 103(3) . .
F7 C36 F9 109(3) . .
F8 C36 C35 115(3) . .
F7 C36 C35 108(3) . .
F9 C36 C35 109(3) . .
C14 C13 C12 119(3) . .
C14 C13 H36 120.3 . .
C12 C13 H36 120.3 . .
C19 O1 C18 114.9(17) . .
C22 O2 C25 118(2) . .
C4 O3 C3 117.0(18) . .
C7 O4 C10 120.5(18) . .
C31 O5 Ag5 135.1(17) . .
C31 O6 Ag1 118.2(17) . .
C33 O8 Ag5 111.4(16) . .
C33 O8 Ag2 142.1(17) . 4
Ag5 O8 Ag2 106.1(6) . 4
C35 O9 Ag3 125.4(15) . .
C35 O10 Ag4 128.2(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C16 2.12(2) .
Ag1 O6 2.173(15) .
Ag1 Ag3 2.989(3) .
Ag1 Ag2 3.101(3) .
Ag1 Ag5 3.142(3) 4_545
Ag1 Ag4 3.212(3) 4_545
Ag1 Ag5 3.236(3) .
Ag2 C1 2.22(2) .
Ag2 O8 2.364(17) 4_545
Ag2 C16 2.40(2) .
Ag2 C2 2.603(19) .
Ag2 Ag4 3.240(3) .
Ag2 Ag5 3.322(3) .
Ag3 C16 2.20(2) .
Ag3 O9 2.192(19) .
Ag3 C17 2.65(2) .
Ag3 Ag4 3.118(3) .
Ag4 C1 2.16(2) .
Ag4 O10 2.181(15) .
Ag4 Ag5 2.901(3) .
Ag4 Ag1 3.212(3) 4
Ag5 C1 2.17(2) .
Ag5 O8 2.334(17) .
Ag5 O5 2.320(16) .
Ag5 Ag1 3.142(3) 4
C1 C2 1.206(10) .
C2 C3 1.47(3) .
C3 O3 1.42(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.42(3) .
C4 O3 1.38(3) .
C4 C9 1.42(3) .
C5 C6 1.34(3) .
C5 H5 0.9300 .
C6 C7 1.40(4) .
C6 H6 0.9300 .
C7 C8 1.38(3) .
C7 O4 1.41(3) .
C8 C9 1.40(3) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 C11 1.34(4) .
C10 C15 1.3800(11) .
C10 O4 1.43(3) .
C11 C12 1.34(4) .
C11 H11 0.9300 .
C12 C13 1.36(4) .
C12 H12 0.9300 .
C24 C23 1.30(3) .
C24 C19 1.37(3) .
C24 H13 0.9300 .
C14 C13 1.29(4) .
C14 C15 1.38(4) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.19(3) .
C17 C18 1.48(3) .
C18 O1 1.49(3) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 O1 1.38(2) .
C19 C20 1.42(3) .
C20 C21 1.33(3) .
C20 H20 0.9300 .
C21 C22 1.36(3) .
C21 H21 0.9300 .
C22 O2 1.39(3) .
C22 C23 1.42(3) .
C23 H23 0.9300 .
C25 C30 1.36(4) .
C25 O2 1.38(3) .
C25 C26 1.50(5) .
C26 C27 1.42(6) .
C26 H26 0.9300 .
C27 C28 1.25(5) .
C27 H27 0.9300 .
C28 C29 1.47(6) .
C28 H28 0.9300 .
C29 C30 1.42(6) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 O6 1.20(3) .
C31 O5 1.22(3) .
C31 C32 1.59(4) .
C32 F2' 1.29(4) .
C32 F3' 1.29(4) .
C32 F1' 1.29(4) .
C32 F1 1.34(2) .
C32 F3 1.34(2) .
C32 F2 1.34(2) .
C33 O8 1.17(3) .
C33 O7 1.25(3) .
C33 C34 1.55(4) .
C34 F6 1.22(4) .
C34 F5 1.32(4) .
C34 F4 1.34(4) .
C35 O10 1.19(3) .
C35 O9 1.24(3) .
C35 C36 1.53(4) .
C36 F8 1.23(4) .
C36 F7 1.28(4) .
C36 F9 1.40(4) .
C13 H36 0.9300 .
O8 Ag2 2.364(17) 4
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C16 Ag1 Ag2 C1 117.7(9) . .
O6 Ag1 Ag2 C1 -66.0(8) . .
Ag3 Ag1 Ag2 C1 73.1(7) . .
Ag5 Ag1 Ag2 C1 -174.3(7) 4_545 .
Ag4 Ag1 Ag2 C1 -129.1(7) 4_545 .
Ag5 Ag1 Ag2 C1 -1.8(7) . .
C16 Ag1 Ag2 O8 -89.1(8) . 4_545
O6 Ag1 Ag2 O8 87.2(7) . 4_545
Ag3 Ag1 Ag2 O8 -133.7(4) . 4_545
Ag5 Ag1 Ag2 O8 -21.1(4) 4_545 4_545
Ag4 Ag1 Ag2 O8 24.1(4) 4_545 4_545
Ag5 Ag1 Ag2 O8 151.4(4) . 4_545
O6 Ag1 Ag2 C16 176.3(8) . .
Ag3 Ag1 Ag2 C16 -44.6(6) . .
Ag5 Ag1 Ag2 C16 67.9(6) 4_545 .
Ag4 Ag1 Ag2 C16 113.2(6) 4_545 .
Ag5 Ag1 Ag2 C16 -119.5(6) . .
C16 Ag1 Ag2 C2 138.8(8) . .
O6 Ag1 Ag2 C2 -44.9(7) . .
Ag3 Ag1 Ag2 C2 94.2(5) . .
Ag5 Ag1 Ag2 C2 -153.2(5) 4_545 .
Ag4 Ag1 Ag2 C2 -108.0(5) 4_545 .
Ag5 Ag1 Ag2 C2 19.3(5) . .
C16 Ag1 Ag2 Ag4 76.5(6) . .
O6 Ag1 Ag2 Ag4 -107.2(5) . .
Ag3 Ag1 Ag2 Ag4 31.93(6) . .
Ag5 Ag1 Ag2 Ag4 144.49(8) 4_545 .
Ag4 Ag1 Ag2 Ag4 -170.29(6) 4_545 .
Ag5 Ag1 Ag2 Ag4 -42.98(6) . .
C16 Ag1 Ag2 Ag5 119.5(6) . .
O6 Ag1 Ag2 Ag5 -64.2(5) . .
Ag3 Ag1 Ag2 Ag5 74.92(7) . .
Ag5 Ag1 Ag2 Ag5 -172.53(5) 4_545 .
Ag4 Ag1 Ag2 Ag5 -127.31(8) 4_545 .
O6 Ag1 Ag3 C16 172.2(10) . .
Ag2 Ag1 Ag3 C16 47.6(8) . .
Ag5 Ag1 Ag3 C16 -20.8(8) 4_545 .
Ag4 Ag1 Ag3 C16 -50.1(8) 4_545 .
Ag5 Ag1 Ag3 C16 113.4(8) . .
C16 Ag1 Ag3 O9 -161.1(11) . .
O6 Ag1 Ag3 O9 11.1(11) . .
Ag2 Ag1 Ag3 O9 -113.5(8) . .
Ag5 Ag1 Ag3 O9 178.2(8) 4_545 .
Ag4 Ag1 Ag3 O9 148.8(8) 4_545 .
Ag5 Ag1 Ag3 O9 -47.7(8) . .
C16 Ag1 Ag3 C17 2.6(9) . .
O6 Ag1 Ag3 C17 174.8(8) . .
Ag2 Ag1 Ag3 C17 50.2(5) . .
Ag5 Ag1 Ag3 C17 -18.2(5) 4_545 .
Ag4 Ag1 Ag3 C17 -47.5(6) 4_545 .
Ag5 Ag1 Ag3 C17 115.9(5) . .
C16 Ag1 Ag3 Ag4 -81.2(8) . .
O6 Ag1 Ag3 Ag4 91.0(6) . .
Ag2 Ag1 Ag3 Ag4 -33.63(7) . .
Ag5 Ag1 Ag3 Ag4 -101.96(8) 4_545 .
Ag4 Ag1 Ag3 Ag4 -131.3(2) 4_545 .
Ag5 Ag1 Ag3 Ag4 32.15(6) . .
C16 Ag3 Ag4 C1 -42.3(8) . .
O9 Ag3 Ag4 C1 141.4(8) . .
C17 Ag3 Ag4 C1 -68.5(8) . .
Ag1 Ag3 Ag4 C1 2.2(6) . .
C16 Ag3 Ag4 O10 160.6(8) . .
O9 Ag3 Ag4 O10 -15.7(8) . .
C17 Ag3 Ag4 O10 134.4(8) . .
Ag1 Ag3 Ag4 O10 -154.9(5) . .
C16 Ag3 Ag4 Ag5 -80.3(6) . .
O9 Ag3 Ag4 Ag5 103.4(6) . .
C17 Ag3 Ag4 Ag5 -106.5(5) . .
Ag1 Ag3 Ag4 Ag5 -35.75(7) . .
C16 Ag3 Ag4 Ag1 -115.5(6) . 4
O9 Ag3 Ag4 Ag1 68.2(6) . 4
C17 Ag3 Ag4 Ag1 -141.7(5) . 4
Ag1 Ag3 Ag4 Ag1 -71.02(9) . 4
C16 Ag3 Ag4 Ag2 -11.9(6) . .
O9 Ag3 Ag4 Ag2 171.8(6) . .
C17 Ag3 Ag4 Ag2 -38.1(5) . .
Ag1 Ag3 Ag4 Ag2 32.66(7) . .
O8 Ag2 Ag4 C1 -177(2) 4_545 .
C16 Ag2 Ag4 C1 144.8(10) . .
C2 Ag2 Ag4 C1 -19.2(10) . .
Ag1 Ag2 Ag4 C1 102.8(9) . .
Ag5 Ag2 Ag4 C1 54.4(9) . .
C1 Ag2 Ag4 O10 -147.5(14) . .
O8 Ag2 Ag4 O10 36(2) 4_545 .
C16 Ag2 Ag4 O10 -2.7(12) . .
C2 Ag2 Ag4 O10 -166.7(11) . .
Ag1 Ag2 Ag4 O10 -44.7(10) . .
Ag5 Ag2 Ag4 O10 -93.1(10) . .
C1 Ag2 Ag4 Ag5 -54.4(9) . .
O8 Ag2 Ag4 Ag5 128.8(18) 4_545 .
C16 Ag2 Ag4 Ag5 90.4(5) . .
C2 Ag2 Ag4 Ag5 -73.6(5) . .
Ag1 Ag2 Ag4 Ag5 48.38(7) . .
C1 Ag2 Ag4 Ag3 -133.9(9) . .
O8 Ag2 Ag4 Ag3 49.3(18) 4_545 .
C16 Ag2 Ag4 Ag3 10.9(5) . .
C2 Ag2 Ag4 Ag3 -153.1(5) . .
Ag1 Ag2 Ag4 Ag3 -31.06(6) . .
Ag5 Ag2 Ag4 Ag3 -79.44(7) . .
C1 Ag2 Ag4 Ag1 -11.5(9) . 4
O8 Ag2 Ag4 Ag1 171.7(18) 4_545 4
C16 Ag2 Ag4 Ag1 133.3(5) . 4
C2 Ag2 Ag4 Ag1 -30.7(5) . 4
Ag1 Ag2 Ag4 Ag1 91.28(9) . 4
Ag5 Ag2 Ag4 Ag1 42.90(7) . 4
O10 Ag4 Ag5 C1 -167.2(10) . .
Ag3 Ag4 Ag5 C1 126.9(8) . .
Ag1 Ag4 Ag5 C1 -85.4(8) 4 .
Ag2 Ag4 Ag5 C1 48.2(8) . .
C1 Ag4 Ag5 O8 165.4(9) . .
O10 Ag4 Ag5 O8 -1.8(7) . .
Ag3 Ag4 Ag5 O8 -67.7(4) . .
Ag1 Ag4 Ag5 O8 80.0(4) 4 .
Ag2 Ag4 Ag5 O8 -146.4(4) . .
C1 Ag4 Ag5 O5 -70(3) . .
O10 Ag4 Ag5 O5 123(2) . .
Ag3 Ag4 Ag5 O5 57(2) . .
Ag1 Ag4 Ag5 O5 -155(2) 4 .
Ag2 Ag4 Ag5 O5 -21(2) . .
C1 Ag4 Ag5 Ag1 85.4(8) . 4
O10 Ag4 Ag5 Ag1 -81.8(6) . 4
Ag3 Ag4 Ag5 Ag1 -147.71(7) . 4
Ag2 Ag4 Ag5 Ag1 133.58(8) . 4
C1 Ag4 Ag5 Ag1 -94.3(8) . .
O10 Ag4 Ag5 Ag1 98.5(6) . .
Ag3 Ag4 Ag5 Ag1 32.60(6) . .
Ag1 Ag4 Ag5 Ag1 -179.70(7) 4 .
Ag2 Ag4 Ag5 Ag1 -46.12(6) . .
C1 Ag4 Ag5 Ag2 -48.2(8) . .
O10 Ag4 Ag5 Ag2 144.6(6) . .
Ag3 Ag4 Ag5 Ag2 78.72(6) . .
Ag1 Ag4 Ag5 Ag2 -133.58(8) 4 .
C16 Ag1 Ag5 C1 -40.5(9) . .
O6 Ag1 Ag5 C1 132.2(8) . .
Ag3 Ag1 Ag5 C1 -83.0(7) . .
Ag2 Ag1 Ag5 C1 1.8(7) . .
Ag5 Ag1 Ag5 C1 12.3(7) 4_545 .
Ag4 Ag1 Ag5 C1 89.2(7) 4_545 .
C16 Ag1 Ag5 O8 106.2(7) . .
O6 Ag1 Ag5 O8 -81.1(6) . .
Ag3 Ag1 Ag5 O8 63.7(5) . .
Ag2 Ag1 Ag5 O8 148.5(5) . .
Ag5 Ag1 Ag5 O8 159.0(5) 4_545 .
Ag4 Ag1 Ag5 O8 -124.1(5) 4_545 .
C16 Ag1 Ag5 O5 -165.0(9) . .
O6 Ag1 Ag5 O5 7.7(8) . .
Ag3 Ag1 Ag5 O5 152.5(7) . .
Ag2 Ag1 Ag5 O5 -122.7(7) . .
Ag5 Ag1 Ag5 O5 -112.2(7) 4_545 .
Ag4 Ag1 Ag5 O5 -35.4(7) 4_545 .
C16 Ag1 Ag5 Ag4 7.7(6) . .
O6 Ag1 Ag5 Ag4 -179.6(4) . .
Ag3 Ag1 Ag5 Ag4 -34.82(7) . .
Ag2 Ag1 Ag5 Ag4 50.00(7) . .
Ag5 Ag1 Ag5 Ag4 60.46(10) 4_545 .
Ag4 Ag1 Ag5 Ag4 137.33(8) 4_545 .
C16 Ag1 Ag5 Ag1 6.9(6) . 4
O6 Ag1 Ag5 Ag1 179.5(5) . 4
Ag3 Ag1 Ag5 Ag1 -35.7(2) . 4
Ag2 Ag1 Ag5 Ag1 49.2(2) . 4
Ag5 Ag1 Ag5 Ag1 59.6(2) 4_545 4
Ag4 Ag1 Ag5 Ag1 136.5(2) 4_545 4
C16 Ag1 Ag5 Ag2 -42.3(6) . .
O6 Ag1 Ag5 Ag2 130.4(4) . .
Ag3 Ag1 Ag5 Ag2 -84.82(8) . .
Ag5 Ag1 Ag5 Ag2 10.46(8) 4_545 .
Ag4 Ag1 Ag5 Ag2 87.33(11) 4_545 .
O8 Ag2 Ag5 C1 139.8(12) 4_545 .
C16 Ag2 Ag5 C1 -140.7(11) . .
C2 Ag2 Ag5 C1 21.6(10) . .
Ag1 Ag2 Ag5 C1 -177.3(10) . .
Ag4 Ag2 Ag5 C1 -56.4(10) . .
C1 Ag2 Ag5 O8 120.0(12) . .
O8 Ag2 Ag5 O8 -100.2(10) 4_545 .
C16 Ag2 Ag5 O8 -20.7(9) . .
C2 Ag2 Ag5 O8 141.6(9) . .
Ag1 Ag2 Ag5 O8 -57.3(7) . .
Ag4 Ag2 Ag5 O8 63.6(7) . .
C1 Ag2 Ag5 O5 -129.6(12) . .
O8 Ag2 Ag5 O5 10.2(9) 4_545 .
C16 Ag2 Ag5 O5 89.7(8) . .
C2 Ag2 Ag5 O5 -108.0(8) . .
Ag1 Ag2 Ag5 O5 53.1(6) . .
Ag4 Ag2 Ag5 O5 174.0(6) . .
C1 Ag2 Ag5 Ag4 56.4(10) . .
O8 Ag2 Ag5 Ag4 -163.8(6) 4_545 .
C16 Ag2 Ag5 Ag4 -84.3(5) . .
C2 Ag2 Ag5 Ag4 78.0(5) . .
Ag1 Ag2 Ag5 Ag4 -120.83(8) . .
C1 Ag2 Ag5 Ag1 12.5(10) . 4
O8 Ag2 Ag5 Ag1 152.3(6) 4_545 4
C16 Ag2 Ag5 Ag1 -128.3(5) . 4
C2 Ag2 Ag5 Ag1 34.0(5) . 4
Ag1 Ag2 Ag5 Ag1 -164.81(8) . 4
Ag4 Ag2 Ag5 Ag1 -43.98(7) . 4
C1 Ag2 Ag5 Ag1 177.3(10) . .
O8 Ag2 Ag5 Ag1 -42.9(6) 4_545 .
C16 Ag2 Ag5 Ag1 36.5(5) . .
C2 Ag2 Ag5 Ag1 -161.2(5) . .
Ag4 Ag2 Ag5 Ag1 120.83(8) . .
O10 Ag4 C1 C2 -127(3) . .
Ag5 Ag4 C1 C2 -160(3) . .
Ag3 Ag4 C1 C2 148(3) . .
Ag1 Ag4 C1 C2 -89(3) 4 .
Ag2 Ag4 C1 C2 103(3) . .
O10 Ag4 C1 Ag5 33(3) . .
Ag3 Ag4 C1 Ag5 -52.3(6) . .
Ag1 Ag4 C1 Ag5 70.7(5) 4 .
Ag2 Ag4 C1 Ag5 -97.7(10) . .
O10 Ag4 C1 Ag2 130.4(19) . .
Ag5 Ag4 C1 Ag2 97.7(10) . .
Ag3 Ag4 C1 Ag2 45.4(8) . .
Ag1 Ag4 C1 Ag2 168.4(9) 4 .
O8 Ag5 C1 C2 137(3) . .
O5 Ag5 C1 C2 -37(3) . .
Ag4 Ag5 C1 C2 162(3) . .
Ag1 Ag5 C1 C2 89(3) 4 .
Ag1 Ag5 C1 C2 -106(3) . .
Ag2 Ag5 C1 C2 -104(3) . .
O8 Ag5 C1 Ag4 -24.4(14) . .
O5 Ag5 C1 Ag4 161.2(6) . .
Ag1 Ag5 C1 Ag4 -72.9(6) 4 .
Ag1 Ag5 C1 Ag4 92.3(6) . .
Ag2 Ag5 C1 Ag4 94.6(7) . .
O8 Ag5 C1 Ag2 -119.0(11) . .
O5 Ag5 C1 Ag2 66.6(10) . .
Ag4 Ag5 C1 Ag2 -94.6(7) . .
Ag1 Ag5 C1 Ag2 -167.5(10) 4 .
Ag1 Ag5 C1 Ag2 -2.3(8) . .
O8 Ag2 C1 C2 38(3) 4_545 .
C16 Ag2 C1 C2 -179.8(16) . .
Ag1 Ag2 C1 C2 137.6(17) . .
Ag4 Ag2 C1 C2 -140(2) . .
Ag5 Ag2 C1 C2 135(2) . .
O8 Ag2 C1 Ag4 178.2(11) 4_545 .
C16 Ag2 C1 Ag4 -39.8(12) . .
C2 Ag2 C1 Ag4 140(2) . .
Ag1 Ag2 C1 Ag4 -82.3(8) . .
Ag5 Ag2 C1 Ag4 -84.7(6) . .
O8 Ag2 C1 Ag5 -97.0(14) 4_545 .
C16 Ag2 C1 Ag5 45.0(12) . .
C2 Ag2 C1 Ag5 -135(2) . .
Ag1 Ag2 C1 Ag5 2.4(9) . .
Ag4 Ag2 C1 Ag5 84.7(6) . .
Ag4 C1 C2 C3 79(15) . .
Ag5 C1 C2 C3 -72(16) . .
Ag2 C1 C2 C3 -178(14) . .
Ag4 C1 C2 Ag2 -103(2) . .
Ag5 C1 C2 Ag2 105(3) . .
O8 Ag2 C2 C1 -158.9(18) 4_545 .
C16 Ag2 C2 C1 0(2) . .
Ag1 Ag2 C2 C1 -50(2) . .
Ag4 Ag2 C2 C1 28.1(18) . .
Ag5 Ag2 C2 C1 -31.0(18) . .
C1 Ag2 C2 C3 180(3) . .
O8 Ag2 C2 C3 21(2) 4_545 .
C16 Ag2 C2 C3 179.8(19) . .
Ag1 Ag2 C2 C3 130(2) . .
Ag4 Ag2 C2 C3 -152(2) . .
Ag5 Ag2 C2 C3 149(2) . .
C1 C2 C3 O3 8(16) . .
Ag2 C2 C3 O3 -170.0(14) . .
O3 C4 C5 C6 176(2) . .
C9 C4 C5 C6 -3(3) . .
C4 C5 C6 C7 4(4) . .
C5 C6 C7 C8 -3(4) . .
C5 C6 C7 O4 179(2) . .
C6 C7 C8 C9 2(3) . .
O4 C7 C8 C9 180(2) . .
C5 C4 C9 C8 2(3) . .
O3 C4 C9 C8 -177.7(18) . .
C7 C8 C9 C4 -1(3) . .
C15 C10 C11 C12 0(4) . .
O4 C10 C11 C12 179(2) . .
C10 C11 C12 C13 -3(3) . .
C11 C10 C15 C14 1(4) . .
O4 C10 C15 C14 -179(3) . .
C13 C14 C15 C10 2(6) . .
Ag2 Ag1 C16 Ag3 -111.4(7) . .
Ag5 Ag1 C16 Ag3 157.7(8) 4_545 .
Ag4 Ag1 C16 Ag3 161.5(3) 4_545 .
Ag5 Ag1 C16 Ag3 -60.3(5) . .
Ag3 Ag1 C16 Ag2 111.4(7) . .
Ag5 Ag1 C16 Ag2 -91.0(5) 4_545 .
Ag4 Ag1 C16 Ag2 -87.2(5) 4_545 .
Ag5 Ag1 C16 Ag2 51.0(4) . .
O9 Ag3 C16 C17 -68(4) . .
Ag1 Ag3 C16 C17 174.4(19) . .
Ag4 Ag3 C16 C17 -83.9(15) . .
O9 Ag3 C16 Ag1 117(3) . .
C17 Ag3 C16 Ag1 -174.4(19) . .
Ag4 Ag3 C16 Ag1 101.7(5) . .
O9 Ag3 C16 Ag2 32(4) . .
C17 Ag3 C16 Ag2 100.4(19) . .
Ag1 Ag3 C16 Ag2 -85.1(9) . .
Ag4 Ag3 C16 Ag2 16.5(8) . .
C1 Ag2 C16 C17 111.1(17) . .
O8 Ag2 C16 C17 -85.3(16) 4_545 .
C2 Ag2 C16 C17 110.9(17) . .
Ag1 Ag2 C16 C17 -172.3(18) . .
Ag4 Ag2 C16 C17 85.7(15) . .
Ag5 Ag2 C16 C17 138.4(15) . .
C1 Ag2 C16 Ag1 -76.6(10) . .
O8 Ag2 C16 Ag1 87.1(7) 4_545 .
C2 Ag2 C16 Ag1 -76.7(13) . .
Ag4 Ag2 C16 Ag1 -101.9(5) . .
Ag5 Ag2 C16 Ag1 -49.3(5) . .
C1 Ag2 C16 Ag3 9.3(14) . .
O8 Ag2 C16 Ag3 173.0(10) 4_545 .
C2 Ag2 C16 Ag3 9.2(18) . .
Ag1 Ag2 C16 Ag3 85.9(9) . .
Ag4 Ag2 C16 Ag3 -16.0(8) . .
Ag5 Ag2 C16 Ag3 36.6(8) . .
Ag2 C16 C17 Ag3 -112.6(10) . .
O9 Ag3 C17 C16 156.6(16) . .
Ag1 Ag3 C17 C16 -4.2(15) . .
Ag4 Ag3 C17 C16 95.2(16) . .
C16 Ag3 C17 C18 -178(3) . .
O9 Ag3 C17 C18 -21(2) . .
Ag1 Ag3 C17 C18 177.9(18) . .
Ag4 Ag3 C17 C18 -82.8(17) . .
Ag3 C17 C18 O1 48(2) . .
C23 C24 C19 O1 173.4(19) . .
C23 C24 C19 C20 4(3) . .
O1 C19 C20 C21 -174.5(19) . .
C24 C19 C20 C21 -4(3) . .
C19 C20 C21 C22 4(3) . .
C20 C21 C22 O2 175(2) . .
C20 C21 C22 C23 -3(3) . .
C19 C24 C23 C22 -3(4) . .
C21 C22 C23 C24 3(4) . .
O2 C22 C23 C24 -175(2) . .
C30 C25 C26 C27 1(6) . .
O2 C25 C26 C27 173(3) . .
C25 C26 C27 C28 1(6) . .
C26 C27 C28 C29 2(7) . .
C27 C28 C29 C30 -6(7) . .
O2 C25 C30 C29 -178(3) . .
C26 C25 C30 C29 -6(6) . .
C28 C29 C30 C25 8(6) . .
O6 C31 C32 F2' -32(3) . .
O5 C31 C32 F2' 146(2) . .
O6 C31 C32 F3' 90(2) . .
O5 C31 C32 F3' -91(3) . .
O6 C31 C32 F1' -147(2) . .
O5 C31 C32 F1' 32(3) . .
O6 C31 C32 F1 151(2) . .
O5 C31 C32 F1 -30(3) . .
O6 C31 C32 F3 -90(2) . .
O5 C31 C32 F3 89(3) . .
O6 C31 C32 F2 29(3) . .
O5 C31 C32 F2 -152(2) . .
O8 C33 C34 F6 154(4) . .
O7 C33 C34 F6 -29(5) . .
O8 C33 C34 F5 26(4) . .
O7 C33 C34 F5 -156(3) . .
O8 C33 C34 F4 -84(3) . .
O7 C33 C34 F4 94(3) . .
O10 C35 C36 F8 147(3) . .
O9 C35 C36 F8 -35(4) . .
O10 C35 C36 F7 -86(4) . .
O9 C35 C36 F7 92(3) . .
O10 C35 C36 F9 32(4) . .
O9 C35 C36 F9 -150(3) . .
C15 C14 C13 C12 -5(6) . .
C11 C12 C13 C14 6(4) . .
C24 C19 O1 C18 34(3) . .
C20 C19 O1 C18 -155.9(18) . .
C17 C18 O1 C19 60(2) . .
C21 C22 O2 C25 -10(4) . .
C23 C22 O2 C25 168(2) . .
C30 C25 O2 C22 -81(4) . .
C26 C25 O2 C22 107(3) . .
C5 C4 O3 C3 3(3) . .
C9 C4 O3 C3 -177.9(17) . .
C2 C3 O3 C4 78(3) . .
C8 C7 O4 C10 5(4) . .
C6 C7 O4 C10 -177(2) . .
C11 C10 O4 C7 90(3) . .
C15 C10 O4 C7 -90(3) . .
O6 C31 O5 Ag5 7(5) . .
C32 C31 O5 Ag5 -171.6(19) . .
C1 Ag5 O5 C31 -95(3) . .
O8 Ag5 O5 C31 88(3) . .
Ag4 Ag5 O5 C31 -38(5) . .
Ag1 Ag5 O5 C31 173(3) 4 .
Ag1 Ag5 O5 C31 -11(3) . .
Ag2 Ag5 O5 C31 -57(3) . .
O5 C31 O6 Ag1 7(4) . .
C32 C31 O6 Ag1 -174.8(14) . .
Ag3 Ag1 O6 C31 -64.7(19) . .
Ag2 Ag1 O6 C31 43.3(19) . .
Ag5 Ag1 O6 C31 128.9(17) 4_545 .
Ag4 Ag1 O6 C31 132.1(18) 4_545 .
Ag5 Ag1 O6 C31 -10.4(17) . .
O7 C33 O8 Ag5 -4(4) . .
C34 C33 O8 Ag5 173(2) . .
O7 C33 O8 Ag2 -175.6(19) . 4
C34 C33 O8 Ag2 2(4) . 4
C1 Ag5 O8 C33 111.8(19) . .
O5 Ag5 O8 C33 -72.8(18) . .
Ag4 Ag5 O8 C33 93.9(18) . .
Ag1 Ag5 O8 C33 156.8(18) 4 .
Ag1 Ag5 O8 C33 -4.4(18) . .
Ag2 Ag5 O8 C33 41(2) . .
C1 Ag5 O8 Ag2 -73.6(13) . 4
O5 Ag5 O8 Ag2 101.8(8) . 4
Ag4 Ag5 O8 Ag2 -91.5(6) . 4
Ag1 Ag5 O8 Ag2 -28.6(6) 4 4
Ag1 Ag5 O8 Ag2 170.2(5) . 4
Ag2 Ag5 O8 Ag2 -144.6(4) . 4
O10 C35 O9 Ag3 0(4) . .
C36 C35 O9 Ag3 -177.8(17) . .
C16 Ag3 O9 C35 0(5) . .
C17 Ag3 O9 C35 -48(3) . .
Ag1 Ag3 O9 C35 103(2) . .
Ag4 Ag3 O9 C35 16(2) . .
O9 C35 O10 Ag4 -28(4) . .
C36 C35 O10 Ag4 149.5(19) . .
C1 Ag4 O10 C35 -62(3) . .
Ag5 Ag4 O10 C35 -36(2) . .
Ag3 Ag4 O10 C35 29(2) . .
Ag1 Ag4 O10 C35 -97(2) 4 .
Ag2 Ag4 O10 C35 42(3) . .
