#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:26:27 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180429 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/98/7209829.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7209829
loop_
_publ_author_name
'Pettinari, Claudio'
'Marchetti, Fabio'
'Orbisaglia, Serena'
'Pettinari, Riccardo'
'Ngoune, Jean'
'Gómez, Margarita'
'Santos, Carina'
'Álvarez, Eleuterio'
_publ_section_title
;
 Group 11 complexes with the bidentate di(1H-indazol-1-yl)methane and
 di(2H-indazol-2-yl)methane) ligands
;
_journal_issue                   19
_journal_name_full               CrystEngComm
_journal_page_first              3892
_journal_paper_doi               10.1039/c3ce40355f
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C30 H24 Ag N8, C H3 O3 S'
_chemical_formula_sum            'C31 H27 Ag N8 O3 S'
_chemical_formula_weight         699.54
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.0110(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            12
_cell_length_a                   43.4103(9)
_cell_length_b                   12.3013(3)
_cell_length_c                   19.7415(4)
_cell_measurement_reflns_used    9930
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.14
_cell_measurement_theta_min      2.38
_cell_volume                     9773.6(4)
_computing_cell_refinement       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_collection       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_reduction        'APEX2 Software Suite (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL and publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2002 (Burla et al., 2003)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type
;
Bruker-Nonius X8kappa APEX II CCD area detector
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0385
_diffrn_reflns_av_sigmaI/netI    0.0290
_diffrn_reflns_limit_h_max       52
_diffrn_reflns_limit_h_min       -39
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            46746
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         2.07
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.727
_exptl_absorpt_correction_T_max  0.8864
_exptl_absorpt_correction_T_min  0.8743
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
APEX2 Software Suite; Bruker 2005.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.426
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4272
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.488
_refine_diff_density_min         -1.672
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     619
_refine_ls_number_reflns         8815
_refine_ls_number_restraints     127
_refine_ls_restrained_S_all      1.119
_refine_ls_R_factor_all          0.0989
_refine_ls_R_factor_gt           0.0643
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1627P)²+48.3179P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1459
_refine_ls_wR_factor_ref         0.2100
_reflns_number_gt                6585
_reflns_number_total             8815
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40355f.txt
_cod_data_source_block           15
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7209829
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.772572(14) 0.43832(5) 0.43938(3) 0.0487(2) Uani 1 1 d . . .
N1 N 0.73794(11) 0.4774(4) 0.2673(2) 0.0306(10) Uani 1 1 d . . .
N2 N 0.76703(13) 0.4452(4) 0.3215(3) 0.0369(12) Uani 1 1 d . . .
N3 N 0.69594(12) 0.4825(4) 0.3183(2) 0.0308(10) Uani 1 1 d . . .
N4 N 0.70956(13) 0.4594(4) 0.3917(3) 0.0346(11) Uani 1 1 d . . .
N5 N 0.81305(12) 0.3803(4) 0.6048(2) 0.0322(11) Uani 1 1 d . . .
N6 N 0.78290(12) 0.3625(4) 0.5499(3) 0.0320(10) Uani 1 1 d . . .
N7 N 0.83840(14) 0.5359(4) 0.5718(3) 0.0352(11) Uani 1 1 d . . .
N8 N 0.81764(15) 0.5727(4) 0.5057(3) 0.0436(13) Uani 1 1 d . . .
C1 C 0.78497(16) 0.3972(6) 0.2899(4) 0.0409(15) Uani 1 1 d . . .
H1 H 0.8063 0.3667 0.3152 0.049 Uiso 1 1 d R . .
C2 C 0.76850(15) 0.3967(5) 0.2136(3) 0.0346(13) Uani 1 1 d . . .
C3 C 0.77578(18) 0.3572(6) 0.1537(4) 0.0452(16) Uani 1 1 d . . .
H3 H 0.7961 0.3204 0.1615 0.054 Uiso 1 1 d R . .
C4 C 0.7525(2) 0.3738(6) 0.0846(4) 0.056(2) Uani 1 1 d . . .
H4 H 0.7571 0.3491 0.0438 0.067 Uiso 1 1 d R . .
C5 C 0.7225(2) 0.4278(6) 0.0739(4) 0.0477(17) Uani 1 1 d . . .
H5 H 0.7072 0.4379 0.0253 0.057 Uiso 1 1 d R . .
C6 C 0.71457(16) 0.4662(5) 0.1302(3) 0.0386(14) Uani 1 1 d . . .
H6 H 0.6940 0.5014 0.1220 0.046 Uiso 1 1 d R . .
C7 C 0.73801(15) 0.4497(5) 0.2005(3) 0.0309(12) Uani 1 1 d . . .
C8 C 0.68694(15) 0.4020(5) 0.4066(3) 0.0333(13) Uani 1 1 d . . .
H8 H 0.6898 0.3744 0.4535 0.040 Uiso 1 1 d R . .
C9 C 0.65813(14) 0.3867(5) 0.3428(3) 0.0304(12) Uani 1 1 d . . .
C10 C 0.62695(15) 0.3357(5) 0.3264(3) 0.0372(14) Uani 1 1 d . . .
H10 H 0.6218 0.3005 0.3637 0.045 Uiso 1 1 d R . .
C11 C 0.60474(15) 0.3394(6) 0.2573(4) 0.0414(15) Uani 1 1 d . . .
H11 H 0.5838 0.3047 0.2457 0.050 Uiso 1 1 d R . .
C12 C 0.61199(16) 0.3920(6) 0.2015(3) 0.0435(15) Uani 1 1 d . . .
H12 H 0.5956 0.3934 0.1534 0.052 Uiso 1 1 d R . .
C13 C 0.64194(15) 0.4423(5) 0.2149(3) 0.0335(13) Uani 1 1 d . . .
H13 H 0.6468 0.4773 0.1773 0.040 Uiso 1 1 d R . .
C14 C 0.66491(14) 0.4388(4) 0.2867(3) 0.0296(12) Uani 1 1 d . . .
C15 C 0.71480(15) 0.5435(5) 0.2851(3) 0.0334(13) Uani 1 1 d . . .
H15A H 0.6994 0.5787 0.2401 0.040 Uiso 1 1 d R . .
H15B H 0.7271 0.6017 0.3192 0.040 Uiso 1 1 d R . .
C16 C 0.76229(16) 0.3331(5) 0.5830(3) 0.0355(13) Uani 1 1 d . . .
H16 H 0.7395 0.3155 0.5580 0.043 Uiso 1 1 d R . .
C17 C 0.77872(16) 0.3309(5) 0.6586(3) 0.0356(13) Uani 1 1 d . . .
C18 C 0.7692(2) 0.3061(5) 0.7180(4) 0.0456(16) Uani 1 1 d . . .
H18 H 0.7471 0.2842 0.7100 0.055 Uiso 1 1 d R . .
C19 C 0.7927(2) 0.3157(6) 0.7862(4) 0.057(2) Uani 1 1 d . . .
H19 H 0.7871 0.2976 0.8270 0.069 Uiso 1 1 d R . .
C20 C 0.8249(2) 0.3493(6) 0.7985(4) 0.054(2) Uani 1 1 d . . .
H20 H 0.8401 0.3575 0.8476 0.065 Uiso 1 1 d R . .
C21 C 0.83581(19) 0.3741(5) 0.7422(3) 0.0456(16) Uani 1 1 d . . .
H21 H 0.8580 0.3958 0.7511 0.055 Uiso 1 1 d R . .
C22 C 0.81159(16) 0.3637(4) 0.6716(3) 0.0343(13) Uani 1 1 d . . .
C23 C 0.81776(18) 0.6799(6) 0.5108(4) 0.0466(16) Uani 1 1 d . . .
H23 H 0.8052 0.7272 0.4723 0.056 Uiso 1 1 d R . .
C24 C 0.83878(15) 0.7152(5) 0.5822(4) 0.0387(14) Uani 1 1 d . . .
C25 C 0.84888(18) 0.8160(6) 0.6166(4) 0.0495(17) Uani 1 1 d . . .
H25 H 0.8413 0.8824 0.5912 0.059 Uiso 1 1 d R . .
C26 C 0.87007(19) 0.8150(7) 0.6879(5) 0.058(2) Uani 1 1 d . . .
H26 H 0.8766 0.8821 0.7130 0.069 Uiso 1 1 d R . .
C27 C 0.8823(2) 0.7175(7) 0.7255(4) 0.0562(19) Uani 1 1 d . . .
H27 H 0.8970 0.7205 0.7752 0.067 Uiso 1 1 d R . .
C28 C 0.87355(19) 0.6175(6) 0.6918(4) 0.0494(17) Uani 1 1 d . . .
H28 H 0.8824 0.5517 0.7167 0.059 Uiso 1 1 d R . .
C29 C 0.85190(14) 0.6188(5) 0.6202(3) 0.0322(12) Uani 1 1 d . . .
C30 C 0.84033(17) 0.4204(5) 0.5864(4) 0.0384(14) Uani 1 1 d . . .
H30A H 0.8404 0.3811 0.5427 0.046 Uiso 1 1 d R . .
H30B H 0.8615 0.4042 0.6272 0.046 Uiso 1 1 d R . .
Ag2 Ag 0.5000 0.45777(9) 0.2500 0.0660(3) Uani 1 2 d S . .
N9 N 0.53771(12) 0.4015(4) 0.4158(3) 0.0321(11) Uani 1 1 d . . .
N10 N 0.50781(13) 0.3869(5) 0.3613(3) 0.0406(12) Uani 1 1 d . . .
N11 N 0.56662(13) 0.5432(4) 0.3789(3) 0.0355(12) Uani 1 1 d . . .
N12 N 0.45464(13) 0.5801(5) 0.1877(3) 0.0404(13) Uani 1 1 d . . .
C31 C 0.48644(16) 0.3624(6) 0.3925(4) 0.0467(16) Uani 1 1 d . . .
H31 H 0.4635 0.3479 0.3669 0.056 Uiso 1 1 d R . .
C32 C 0.50227(15) 0.3605(6) 0.4690(3) 0.0393(14) Uani 1 1 d . . .
C33 C 0.49247(18) 0.3390(7) 0.5280(4) 0.0520(18) Uani 1 1 d . . .
H33 H 0.4702 0.3187 0.5195 0.062 Uiso 1 1 d R . .
C34 C 0.51575(19) 0.3485(6) 0.5974(4) 0.0511(18) Uani 1 1 d . . .
H34 H 0.5094 0.3355 0.6378 0.061 Uiso 1 1 d R . .
C35 C 0.54927(17) 0.3769(6) 0.6108(4) 0.0464(16) Uani 1 1 d . . .
H35 H 0.5648 0.3834 0.6596 0.056 Uiso 1 1 d R . .
C36 C 0.55965(15) 0.3946(5) 0.5532(3) 0.0358(13) Uani 1 1 d . . .
H36 H 0.5821 0.4122 0.5616 0.043 Uiso 1 1 d R . .
C37 C 0.53575(14) 0.3870(5) 0.4829(3) 0.0316(12) Uani 1 1 d . . .
C38 C 0.45342(17) 0.6871(6) 0.1842(4) 0.0450(16) Uani 1 1 d . . .
H38 H 0.4656 0.7338 0.2234 0.054 Uiso 1 1 d R . .
C39 C 0.56833(16) 0.7237(6) 0.3856(4) 0.0418(15) Uani 1 1 d . . .
C40 C 0.5787(2) 0.8232(6) 0.4191(5) 0.0556(19) Uani 1 1 d . . .
H40 H 0.5710 0.8894 0.3935 0.067 Uiso 1 1 d R . .
C41 C 0.6002(3) 0.8247(8) 0.4903(5) 0.076(3) Uani 1 1 d . . .
H41 H 0.6079 0.8919 0.5143 0.091 Uiso 1 1 d R . .
C42 C 0.6115(2) 0.7291(8) 0.5279(4) 0.076(3) Uani 1 1 d . . .
H42 H 0.6263 0.7330 0.5775 0.092 Uiso 1 1 d R . .
C43 C 0.60260(19) 0.6291(7) 0.4982(4) 0.054(2) Uani 1 1 d . . .
H43 H 0.6107 0.5641 0.5249 0.065 Uiso 1 1 d R . .
C44 C 0.58048(15) 0.6276(6) 0.4248(3) 0.0396(14) Uani 1 1 d . . .
C45 C 0.56617(14) 0.4285(5) 0.3966(3) 0.0348(13) Uani 1 1 d . . .
H45A H 0.5869 0.4107 0.4382 0.042 Uiso 1 1 d R . .
H45B H 0.5655 0.3839 0.3543 0.042 Uiso 1 1 d R . .
S1 S 0.84820(4) 0.20911(15) 0.43060(9) 0.0458(4) Uani 1 1 d U . .
O1 O 0.8345(2) 0.1835(6) 0.3512(4) 0.091(2) Uani 1 1 d U . .
O2 O 0.82083(13) 0.2497(5) 0.4449(4) 0.0664(15) Uani 1 1 d U . .
O3 O 0.86327(17) 0.1099(7) 0.4645(5) 0.110(3) Uani 1 1 d U . .
C46 C 0.8749(3) 0.3110(10) 0.4354(8) 0.105(4) Uani 1 1 d U . .
H46A H 0.8713 0.3381 0.3864 0.157 Uiso 1 1 d R . .
H46B H 0.8977 0.2836 0.4584 0.157 Uiso 1 1 d R . .
H46C H 0.8714 0.3702 0.4650 0.157 Uiso 1 1 d R . .
S2 S 0.55204(9) 0.1223(3) 0.3254(2) 0.0691(11) Uani 0.50 1 d PDU A -1
O6 O 0.58558(14) 0.1304(12) 0.3764(6) 0.093(2) Uani 0.50 1 d PDU A -1
O5 O 0.5505(4) 0.0170(7) 0.2935(8) 0.099(3) Uani 0.50 1 d PDU A -1
O4 O 0.5337(3) 0.1027(14) 0.3711(7) 0.097(2) Uani 0.50 1 d PDU A -1
C47 C 0.5214(3) 0.2158(12) 0.2765(9) 0.074(3) Uani 0.50 1 d PDU A -1
H47A H 0.5201 0.2870 0.2975 0.110 Uiso 0.50 1 d PR A -1
H47B H 0.4982 0.1909 0.2498 0.110 Uiso 0.50 1 d PR A -1
H47C H 0.5347 0.2218 0.2460 0.110 Uiso 0.50 1 d PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N6 157.03(18) . .
N2 Ag1 N8 105.90(19) . .
N6 Ag1 N8 86.24(18) . .
N2 Ag1 N4 86.01(17) . .
N6 Ag1 N4 101.28(17) . .
N8 Ag1 N4 129.88(18) . .
C7 N1 N2 110.3(5) . .
C7 N1 C15 129.4(5) . .
N2 N1 C15 119.8(5) . .
C1 N2 N1 107.3(5) . .
C1 N2 Ag1 128.6(4) . .
N1 N2 Ag1 121.9(4) . .
C14 N3 N4 111.2(5) . .
C14 N3 C15 129.1(5) . .
N4 N3 C15 119.7(5) . .
C8 N4 N3 106.4(5) . .
C8 N4 Ag1 130.1(4) . .
N3 N4 Ag1 112.8(3) . .
C22 N5 N6 111.5(5) . .
C22 N5 C30 129.4(5) . .
N6 N5 C30 119.0(5) . .
C16 N6 N5 105.8(5) . .
C16 N6 Ag1 131.0(4) . .
N5 N6 Ag1 118.9(4) . .
N8 N7 C29 112.3(5) . .
N8 N7 C30 119.2(5) . .
C29 N7 C30 128.0(5) . .
C23 N8 N7 106.1(5) . .
C23 N8 Ag1 132.3(5) . .
N7 N8 Ag1 112.8(4) . .
N2 C1 C2 111.0(6) . .
N2 C1 H1 124.5 . .
C2 C1 H1 124.5 . .
C1 C2 C7 105.1(5) . .
C1 C2 C3 135.4(6) . .
C7 C2 C3 119.5(6) . .
C4 C3 C2 117.8(7) . .
C4 C3 H3 121.5 . .
C2 C3 H3 120.8 . .
C3 C4 C5 121.0(6) . .
C3 C4 H4 119.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 122.9(7) . .
C6 C5 H5 118.8 . .
C4 C5 H5 118.2 . .
C5 C6 C7 116.5(6) . .
C5 C6 H6 121.8 . .
C7 C6 H6 121.7 . .
N1 C7 C6 131.4(6) . .
N1 C7 C2 106.2(5) . .
C6 C7 C2 122.4(6) . .
N4 C8 C9 110.7(5) . .
N4 C8 H8 124.7 . .
C9 C8 H8 124.6 . .
C14 C9 C10 119.2(5) . .
C14 C9 C8 105.4(5) . .
C10 C9 C8 135.4(5) . .
C11 C10 C9 118.5(6) . .
C11 C10 H10 121.1 . .
C9 C10 H10 120.4 . .
C10 C11 C12 121.6(6) . .
C10 C11 H11 119.0 . .
C12 C11 H11 119.4 . .
C13 C12 C11 121.8(6) . .
C13 C12 H12 119.2 . .
C11 C12 H12 119.0 . .
C12 C13 C14 116.6(6) . .
C12 C13 H13 121.8 . .
C14 C13 H13 121.6 . .
N3 C14 C13 131.3(5) . .
N3 C14 C9 106.3(5) . .
C13 C14 C9 122.3(5) . .
N1 C15 N3 112.7(5) . .
N1 C15 H15A 109.1 . .
N3 C15 H15A 109.2 . .
N1 C15 H15B 109.1 . .
N3 C15 H15B 108.8 . .
H15A C15 H15B 107.8 . .
N6 C16 C17 111.2(6) . .
N6 C16 H16 124.3 . .
C17 C16 H16 124.5 . .
C16 C17 C22 105.4(5) . .
C16 C17 C18 134.6(7) . .
C22 C17 C18 120.0(6) . .
C19 C18 C17 117.4(7) . .
C19 C18 H18 121.7 . .
C17 C18 H18 120.8 . .
C18 C19 C20 122.2(7) . .
C18 C19 H19 119.1 . .
C20 C19 H19 118.7 . .
C19 C20 C21 123.0(7) . .
C19 C20 H20 118.5 . .
C21 C20 H20 118.5 . .
C20 C21 C22 114.9(7) . .
C20 C21 H21 122.5 . .
C22 C21 H21 122.7 . .
N5 C22 C21 131.3(6) . .
N5 C22 C17 106.2(5) . .
C21 C22 C17 122.5(6) . .
N8 C23 C24 111.1(6) . .
N8 C23 H23 124.4 . .
C24 C23 H23 124.4 . .
C25 C24 C29 119.8(6) . .
C25 C24 C23 135.6(6) . .
C29 C24 C23 104.6(5) . .
C26 C25 C24 117.4(7) . .
C26 C25 H25 121.2 . .
C24 C25 H25 121.4 . .
C25 C26 C27 121.9(7) . .
C25 C26 H26 119.1 . .
C27 C26 H26 119.1 . .
C28 C27 C26 121.6(7) . .
C28 C27 H27 119.3 . .
C26 C27 H27 119.1 . .
C29 C28 C27 116.3(7) . .
C29 C28 H28 122.0 . .
C27 C28 H28 121.7 . .
N7 C29 C28 131.2(6) . .
N7 C29 C24 105.9(5) . .
C28 C29 C24 123.0(6) . .
N7 C30 N5 113.1(5) . .
N7 C30 H30A 109.0 . .
N5 C30 H30A 108.8 . .
N7 C30 H30B 109.1 . .
N5 C30 H30B 108.9 . .
H30A C30 H30B 107.8 . .
N10 Ag2 N10 134.8(3) 2_655 .
N10 Ag2 N12 122.02(19) 2_655 2_655
N10 Ag2 N12 87.06(18) . 2_655
N10 Ag2 N12 87.06(18) 2_655 .
N10 Ag2 N12 122.02(19) . .
N12 Ag2 N12 103.0(3) 2_655 .
N10 N9 C37 111.3(5) . .
N10 N9 C45 118.5(5) . .
C37 N9 C45 130.2(5) . .
C31 N10 N9 106.9(5) . .
C31 N10 Ag2 131.3(4) . .
N9 N10 Ag2 118.0(4) . .
C44 N11 N12 110.9(5) . 2_655
C44 N11 C45 128.5(5) . .
N12 N11 C45 119.2(5) 2_655 .
C38 N12 N11 106.4(5) . 2_655
C38 N12 Ag2 131.1(5) . .
N11 N12 Ag2 114.2(4) 2_655 .
N10 C31 C32 110.9(6) . .
N10 C31 H31 124.9 . .
C32 C31 H31 124.1 . .
C33 C32 C31 135.6(6) . .
C33 C32 C37 119.4(6) . .
C31 C32 C37 104.9(5) . .
C34 C33 C32 118.3(6) . .
C34 C33 H33 121.2 . .
C32 C33 H33 120.5 . .
C33 C34 C35 121.8(6) . .
C33 C34 H34 119.3 . .
C35 C34 H34 118.9 . .
C36 C35 C34 120.6(6) . .
C36 C35 H35 119.4 . .
C34 C35 H35 120.0 . .
C35 C36 C37 117.2(6) . .
C35 C36 H36 121.3 . .
C37 C36 H36 121.5 . .
N9 C37 C36 131.5(5) . .
N9 C37 C32 105.9(5) . .
C36 C37 C32 122.6(5) . .
N12 C38 C39 111.5(6) . 2_655
N12 C38 H38 124.2 . .
C39 C38 H38 124.3 2_655 .
C40 C39 C44 119.6(6) . .
C40 C39 C38 136.3(7) . 2_655
C44 C39 C38 104.1(6) . 2_655
C41 C40 C39 118.5(8) . .
C41 C40 H40 120.3 . .
C39 C40 H40 121.2 . .
C40 C41 C42 120.7(8) . .
C40 C41 H41 120.1 . .
C42 C41 H41 119.1 . .
C43 C42 C41 123.7(8) . .
C43 C42 H42 117.7 . .
C41 C42 H42 118.6 . .
C42 C43 C44 115.5(8) . .
C42 C43 H43 122.6 . .
C44 C43 H43 122.0 . .
N11 C44 C39 107.2(5) . .
N11 C44 C43 131.0(7) . .
C39 C44 C43 121.9(7) . .
N11 C45 N9 111.9(5) . .
N11 C45 H45A 108.9 . .
N9 C45 H45A 109.3 . .
N11 C45 H45B 109.5 . .
N9 C45 H45B 109.4 . .
H45A C45 H45B 107.8 . .
O2 S1 O3 118.7(5) . .
O2 S1 O1 104.5(4) . .
O3 S1 O1 104.2(5) . .
O2 S1 C46 109.8(5) . .
O3 S1 C46 115.1(5) . .
O1 S1 C46 102.3(6) . .
S1 C46 H46A 110.2 . .
S1 C46 H46B 108.9 . .
H46A C46 H46B 109.5 . .
S1 C46 H46C 109.3 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
O6 S2 O5 104.0(8) . .
O6 S2 O4 103.2(9) . .
O5 S2 O4 100.3(10) . .
O6 S2 C47 134.9(9) . .
O5 S2 C47 116.8(9) . .
O4 S2 C47 88.3(10) . .
S2 C47 H47A 120.3 . .
S2 C47 H47B 120.0 . .
H47A C47 H47B 107.1 . .
S2 C47 H47C 83.6 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 114.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.250(5) .
Ag1 N6 2.258(5) .
Ag1 N8 2.521(6) .
Ag1 N4 2.551(5) .
N1 C7 1.363(7) .
N1 N2 1.372(7) .
N1 C15 1.435(8) .
N2 C1 1.307(9) .
N3 C14 1.365(8) .
N3 N4 1.374(7) .
N3 C15 1.437(8) .
N4 C8 1.329(8) .
N5 C22 1.359(7) .
N5 N6 1.369(7) .
N5 C30 1.449(8) .
N6 C16 1.340(8) .
N7 N8 1.355(7) .
N7 C29 1.370(8) .
N7 C30 1.446(8) .
N8 C23 1.322(9) .
C1 C2 1.404(9) .
C1 H1 0.9500 .
C2 C7 1.410(9) .
C2 C3 1.419(9) .
C3 C4 1.375(11) .
C3 H3 0.9500 .
C4 C5 1.405(12) .
C4 H4 0.9500 .
C5 C6 1.366(10) .
C5 H5 0.9500 .
C6 C7 1.394(8) .
C6 H6 0.9500 .
C8 C9 1.416(8) .
C8 H8 0.9500 .
C9 C14 1.403(8) .
C9 C10 1.415(9) .
C10 C11 1.345(9) .
C10 H10 0.9500 .
C11 C12 1.411(10) .
C11 H11 0.9500 .
C12 C13 1.373(9) .
C12 H12 0.9500 .
C13 C14 1.394(8) .
C13 H13 0.9500 .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 C17 1.394(9) .
C16 H16 0.9500 .
C17 C22 1.411(9) .
C17 C18 1.414(9) .
C18 C19 1.354(11) .
C18 H18 0.9500 .
C19 C20 1.390(12) .
C19 H19 0.9500 .
C20 C21 1.396(11) .
C20 H20 0.9500 .
C21 C22 1.402(9) .
C21 H21 0.9500 .
C23 C24 1.429(9) .
C23 H23 0.9500 .
C24 C25 1.402(9) .
C24 C29 1.405(9) .
C25 C26 1.364(12) .
C25 H25 0.9500 .
C26 C27 1.405(12) .
C26 H26 0.9500 .
C27 C28 1.382(10) .
C27 H27 0.9500 .
C28 C29 1.373(10) .
C28 H28 0.9500 .
C30 H30A 0.9900 .
C30 H30B 0.9900 .
Ag2 N10 2.268(5) 2_655
Ag2 N10 2.268(5) .
Ag2 N12 2.416(6) 2_655
Ag2 N12 2.416(6) .
N9 N10 1.352(7) .
N9 C37 1.371(7) .
N9 C45 1.460(7) .
N10 C31 1.326(9) .
N11 C44 1.362(9) .
N11 N12 1.369(7) 2_655
N11 C45 1.455(8) .
N12 C38 1.318(9) .
N12 N11 1.369(7) 2_655
C31 C32 1.406(9) .
C31 H31 0.9500 .
C32 C33 1.406(9) .
C32 C37 1.412(9) .
C33 C34 1.369(11) .
C33 H33 0.9499 .
C34 C35 1.422(10) .
C34 H34 0.9500 .
C35 C36 1.389(9) .
C35 H35 0.9500 .
C36 C37 1.390(8) .
C36 H36 0.9500 .
C38 C39 1.420(10) 2_655
C38 H38 0.9500 .
C39 C40 1.384(11) .
C39 C44 1.402(10) .
C39 C38 1.420(10) 2_655
C40 C41 1.365(12) .
C40 H40 0.9500 .
C41 C42 1.378(15) .
C41 H41 0.9500 .
C42 C43 1.356(12) .
C42 H42 0.9500 .
C43 C44 1.407(9) .
C43 H43 0.9500 .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
S1 O2 1.412(5) .
S1 O3 1.427(8) .
S1 O1 1.487(7) .
S1 C46 1.685(11) .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
S2 O6 1.4300(2) .
S2 O5 1.4300(2) .
S2 O4 1.4300(2) .
S2 C47 1.7501(2) .
C47 H47A 0.9800 .
C47 H47B 0.9921 .
C47 H47C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 N1 N2 C1 -0.7(7) . .
C15 N1 N2 C1 -173.0(5) . .
C7 N1 N2 Ag1 -165.2(4) . .
C15 N1 N2 Ag1 22.6(7) . .
N6 Ag1 N2 C1 -38.4(8) . .
N8 Ag1 N2 C1 81.4(6) . .
N4 Ag1 N2 C1 -148.1(6) . .
N6 Ag1 N2 N1 122.5(5) . .
N8 Ag1 N2 N1 -117.7(4) . .
N4 Ag1 N2 N1 12.7(4) . .
C14 N3 N4 C8 -0.7(6) . .
C15 N3 N4 C8 -179.3(5) . .
C14 N3 N4 Ag1 147.7(4) . .
C15 N3 N4 Ag1 -30.9(6) . .
N2 Ag1 N4 C8 130.1(5) . .
N6 Ag1 N4 C8 -27.9(5) . .
N8 Ag1 N4 C8 -122.4(5) . .
N2 Ag1 N4 N3 -8.8(4) . .
N6 Ag1 N4 N3 -166.8(4) . .
N8 Ag1 N4 N3 98.7(4) . .
C22 N5 N6 C16 -0.7(6) . .
C30 N5 N6 C16 -176.1(5) . .
C22 N5 N6 Ag1 158.5(4) . .
C30 N5 N6 Ag1 -16.9(6) . .
N2 Ag1 N6 C16 -105.5(6) . .
N8 Ag1 N6 C16 131.2(5) . .
N4 Ag1 N6 C16 1.3(5) . .
N2 Ag1 N6 N5 101.4(6) . .
N8 Ag1 N6 N5 -21.9(4) . .
N4 Ag1 N6 N5 -151.8(4) . .
C29 N7 N8 C23 0.4(8) . .
C30 N7 N8 C23 172.3(6) . .
C29 N7 N8 Ag1 -151.5(4) . .
C30 N7 N8 Ag1 20.4(7) . .
N2 Ag1 N8 C23 78.0(7) . .
N6 Ag1 N8 C23 -121.8(7) . .
N4 Ag1 N8 C23 -20.2(8) . .
N2 Ag1 N8 N7 -139.7(4) . .
N6 Ag1 N8 N7 20.4(4) . .
N4 Ag1 N8 N7 122.0(4) . .
N1 N2 C1 C2 0.5(7) . .
Ag1 N2 C1 C2 163.6(4) . .
N2 C1 C2 C7 -0.1(7) . .
N2 C1 C2 C3 180.0(7) . .
C1 C2 C3 C4 -179.5(7) . .
C7 C2 C3 C4 0.6(9) . .
C2 C3 C4 C5 -0.2(10) . .
C3 C4 C5 C6 -0.3(11) . .
C4 C5 C6 C7 0.3(10) . .
N2 N1 C7 C6 -179.1(6) . .
C15 N1 C7 C6 -7.8(10) . .
N2 N1 C7 C2 0.6(6) . .
C15 N1 C7 C2 171.9(6) . .
C5 C6 C7 N1 179.9(6) . .
C5 C6 C7 C2 0.2(9) . .
C1 C2 C7 N1 -0.3(6) . .
C3 C2 C7 N1 179.6(5) . .
C1 C2 C7 C6 179.5(6) . .
C3 C2 C7 C6 -0.7(9) . .
N3 N4 C8 C9 0.0(6) . .
Ag1 N4 C8 C9 -140.8(4) . .
N4 C8 C9 C14 0.6(7) . .
N4 C8 C9 C10 -178.6(6) . .
C14 C9 C10 C11 -0.3(8) . .
C8 C9 C10 C11 178.8(6) . .
C9 C10 C11 C12 0.4(10) . .
C10 C11 C12 C13 -0.3(11) . .
C11 C12 C13 C14 0.0(10) . .
N4 N3 C14 C13 179.1(6) . .
C15 N3 C14 C13 -2.4(10) . .
N4 N3 C14 C9 1.1(6) . .
C15 N3 C14 C9 179.5(5) . .
C12 C13 C14 N3 -177.8(6) . .
C12 C13 C14 C9 0.1(9) . .
C10 C9 C14 N3 178.4(5) . .
C8 C9 C14 N3 -1.0(6) . .
C10 C9 C14 C13 0.1(8) . .
C8 C9 C14 C13 -179.3(5) . .
C7 N1 C15 N3 112.6(6) . .
N2 N1 C15 N3 -76.8(7) . .
C14 N3 C15 N1 -96.6(7) . .
N4 N3 C15 N1 81.8(6) . .
N5 N6 C16 C17 -0.4(6) . .
Ag1 N6 C16 C17 -156.1(4) . .
N6 C16 C17 C22 1.2(7) . .
N6 C16 C17 C18 -179.9(6) . .
C16 C17 C18 C19 -178.5(7) . .
C22 C17 C18 C19 0.2(9) . .
C17 C18 C19 C20 0.6(10) . .
C18 C19 C20 C21 -1.1(11) . .
C19 C20 C21 C22 0.7(10) . .
N6 N5 C22 C21 -178.6(6) . .
C30 N5 C22 C21 -3.8(10) . .
N6 N5 C22 C17 1.4(6) . .
C30 N5 C22 C17 176.2(5) . .
C20 C21 C22 N5 -179.8(6) . .
C20 C21 C22 C17 0.1(9) . .
C16 C17 C22 N5 -1.6(6) . .
C18 C17 C22 N5 179.4(5) . .
C16 C17 C22 C21 178.5(5) . .
C18 C17 C22 C21 -0.6(9) . .
N7 N8 C23 C24 -0.7(8) . .
Ag1 N8 C23 C24 143.3(5) . .
N8 C23 C24 C25 177.4(8) . .
N8 C23 C24 C29 0.7(8) . .
C29 C24 C25 C26 -3.4(10) . .
C23 C24 C25 C26 -179.7(8) . .
C24 C25 C26 C27 2.0(12) . .
C25 C26 C27 C28 0.2(13) . .
C26 C27 C28 C29 -1.0(12) . .
N8 N7 C29 C28 179.5(7) . .
C30 N7 C29 C28 8.5(11) . .
N8 N7 C29 C24 0.0(7) . .
C30 N7 C29 C24 -171.0(6) . .
C27 C28 C29 N7 -179.9(7) . .
C27 C28 C29 C24 -0.5(11) . .
C25 C24 C29 N7 -177.7(6) . .
C23 C24 C29 N7 -0.4(7) . .
C25 C24 C29 C28 2.7(10) . .
C23 C24 C29 C28 -179.9(7) . .
N8 N7 C30 N5 -79.4(7) . .
C29 N7 C30 N5 91.0(7) . .
C22 N5 C30 N7 -95.7(7) . .
N6 N5 C30 N7 78.7(7) . .
C37 N9 N10 C31 -0.4(7) . .
C45 N9 N10 C31 179.4(6) . .
C37 N9 N10 Ag2 160.4(4) . .
C45 N9 N10 Ag2 -19.8(7) . .
N10 Ag2 N10 C31 -92.2(7) 2_655 .
N12 Ag2 N10 C31 133.6(7) 2_655 .
N12 Ag2 N10 C31 30.1(7) . .
N10 Ag2 N10 N9 112.6(5) 2_655 .
N12 Ag2 N10 N9 -21.5(5) 2_655 .
N12 Ag2 N10 N9 -125.0(4) . .
N10 Ag2 N12 C38 -120.2(6) 2_655 .
N10 Ag2 N12 C38 96.7(6) . .
N12 Ag2 N12 C38 2.0(5) 2_655 .
N10 Ag2 N12 N11 23.1(4) 2_655 2_655
N10 Ag2 N12 N11 -120.0(4) . 2_655
N12 Ag2 N12 N11 145.3(5) 2_655 2_655
N9 N10 C31 C32 0.0(8) . .
Ag2 N10 C31 C32 -157.2(5) . .
N10 C31 C32 C33 -179.1(8) . .
N10 C31 C32 C37 0.4(8) . .
C31 C32 C33 C34 -178.3(8) . .
C37 C32 C33 C34 2.3(11) . .
C32 C33 C34 C35 -1.3(12) . .
C33 C34 C35 C36 -1.0(12) . .
C34 C35 C36 C37 2.2(10) . .
N10 N9 C37 C36 -179.3(6) . .
C45 N9 C37 C36 0.9(11) . .
N10 N9 C37 C32 0.6(7) . .
C45 N9 C37 C32 -179.2(6) . .
C35 C36 C37 N9 178.7(6) . .
C35 C36 C37 C32 -1.2(10) . .
C33 C32 C37 N9 179.0(6) . .
C31 C32 C37 N9 -0.5(7) . .
C33 C32 C37 C36 -1.1(10) . .
C31 C32 C37 C36 179.4(6) . .
N11 N12 C38 C39 -1.1(7) 2_655 2_655
Ag2 N12 C38 C39 144.3(5) . 2_655
C44 C39 C40 C41 -1.1(10) . .
C38 C39 C40 C41 178.7(8) 2_655 .
C39 C40 C41 C42 0.2(13) . .
C40 C41 C42 C43 0.5(15) . .
C41 C42 C43 C44 -0.3(13) . .
N12 N11 C44 C39 -1.6(7) 2_655 .
C45 N11 C44 C39 -167.2(6) . .
N12 N11 C44 C43 177.7(7) 2_655 .
C45 N11 C44 C43 12.1(11) . .
C40 C39 C44 N11 -179.3(6) . .
C38 C39 C44 N11 0.9(7) 2_655 .
C40 C39 C44 C43 1.3(10) . .
C38 C39 C44 C43 -178.5(6) 2_655 .
C42 C43 C44 N11 -179.8(7) . .
C42 C43 C44 C39 -0.5(11) . .
C44 N11 C45 N9 88.0(7) . .
N12 N11 C45 N9 -76.5(7) 2_655 .
N10 N9 C45 N11 79.8(7) . .
C37 N9 C45 N11 -100.5(7) . .
