#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:26:27 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180429 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/98/7209861.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7209861
loop_
_publ_author_name
'Zhao, Lang'
'Wu, Jianfeng'
'Ke, Hongshan'
'Tang, Jinkui'
_publ_section_title
;
 Three dinuclear lanthanide(iii) compounds of a polydentate Schiff base
 ligand: Slow magnetic relaxation behaviour of the DyIII derivative
;
_journal_issue                   26
_journal_name_full               CrystEngComm
_journal_page_first              5301
_journal_paper_doi               10.1039/c3ce40153g
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C60 H66 Gd2 N8 O12'
_chemical_formula_weight         1405.71
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.5560(10)
_cell_angle_beta                 102.6370(10)
_cell_angle_gamma                101.9690(10)
_cell_formula_units_Z            1
_cell_length_a                   10.5471(5)
_cell_length_b                   11.3694(6)
_cell_length_c                   12.8451(7)
_cell_measurement_temperature    191(2)
_cell_volume                     1388.74(13)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      191(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0208
_diffrn_reflns_av_sigmaI/netI    0.0418
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            7716
_diffrn_reflns_theta_full        26.15
_diffrn_reflns_theta_max         26.15
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    2.439
_exptl_absorpt_correction_T_max  0.7111
_exptl_absorpt_correction_T_min  0.6411
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.681
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             706
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.744
_refine_diff_density_min         -0.832
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     502
_refine_ls_number_reflns         5416
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0336
_refine_ls_R_factor_gt           0.0288
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0380P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0667
_refine_ls_wR_factor_ref         0.0697
_reflns_number_gt                4855
_reflns_number_total             5416
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40153g.txt
_cod_data_source_block           1a
_cod_original_cell_volume        1388.74(12)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7209861
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
C1 C 0.1028(4) 0.4335(3) 0.1437(3) 0.0264(8) Uani 1 1 d
C2 C -0.0123(4) 0.3639(3) 0.0485(3) 0.0280(8) Uani 1 1 d
C3 C 0.0014(5) 0.3236(4) -0.0601(4) 0.0356(9) Uani 1 1 d
H3 H -0.076(4) 0.277(4) -0.118(3) 0.029(11) Uiso 1 1 d
C4 C 0.1244(5) 0.3449(4) -0.0795(4) 0.0413(11) Uani 1 1 d
H4 H 0.133(4) 0.318(4) -0.154(4) 0.046(13) Uiso 1 1 d
C5 C 0.2394(5) 0.4122(4) 0.0114(4) 0.0363(10) Uani 1 1 d
H5 H 0.327(5) 0.434(4) 0.012(4) 0.039(12) Uiso 1 1 d
C6 C 0.2295(4) 0.4559(4) 0.1199(3) 0.0308(9) Uani 1 1 d
C7 C 0.3691(5) 0.6495(5) 0.2543(5) 0.0449(11) Uani 1 1 d
H7A H 0.296(6) 0.671(5) 0.267(4) 0.063(17) Uiso 1 1 d
H7B H 0.399(5) 0.680(5) 0.201(4) 0.059(16) Uiso 1 1 d
H7C H 0.448(5) 0.684(5) 0.319(4) 0.060(16) Uiso 1 1 d
C8 C -0.1481(4) 0.3412(3) 0.0596(3) 0.0274(8) Uani 1 1 d
H8 H -0.222(4) 0.320(4) -0.009(3) 0.030(11) Uiso 1 1 d
C9 C -0.3230(4) 0.3437(4) 0.1453(3) 0.0273(8) Uani 1 1 d
H9A H -0.377(4) 0.339(3) 0.075(3) 0.018(9) Uiso 1 1 d
H9B H -0.355(4) 0.277(4) 0.167(3) 0.022(10) Uiso 1 1 d
C10 C -0.3297(4) 0.4640(4) 0.2269(3) 0.0263(8) Uani 1 1 d
H10A H -0.287(4) 0.532(4) 0.206(3) 0.022(10) Uiso 1 1 d
H10B H -0.424(4) 0.463(4) 0.222(3) 0.040(12) Uiso 1 1 d
C11 C -0.3496(4) 0.4046(4) 0.3939(3) 0.0289(8) Uani 1 1 d
H11A H -0.342(5) 0.327(5) 0.385(4) 0.048(14) Uiso 1 1 d
H11B H -0.454(4) 0.398(4) 0.350(3) 0.030(10) Uiso 1 1 d
C12 C -0.3104(4) 0.4817(4) 0.5190(3) 0.0256(8) Uani 1 1 d
H12A H -0.395(4) 0.491(3) 0.541(3) 0.021(9) Uiso 1 1 d
H12B H -0.267(4) 0.442(4) 0.561(4) 0.043(13) Uiso 1 1 d
C13 C -0.2385(4) 0.6120(3) 0.4148(3) 0.0210(7) Uani 1 1 d
H13 H -0.321(4) 0.633(3) 0.393(3) 0.018(9) Uiso 1 1 d
C14 C -0.1253(4) 0.7086(3) 0.4035(3) 0.0212(7) Uani 1 1 d
C15 C -0.1517(4) 0.8093(4) 0.3690(3) 0.0284(8) Uani 1 1 d
H15 H -0.235(4) 0.814(4) 0.349(3) 0.022(10) Uiso 1 1 d
C16 C -0.0496(4) 0.9004(4) 0.3620(3) 0.0345(9) Uani 1 1 d
H16 H -0.064(4) 0.966(4) 0.341(3) 0.036(12) Uiso 1 1 d
C17 C 0.0837(4) 0.8938(4) 0.3919(3) 0.0323(9) Uani 1 1 d
H17 H 0.155(4) 0.955(4) 0.392(3) 0.023(10) Uiso 1 1 d
C18 C 0.1115(4) 0.7945(3) 0.4273(3) 0.0258(8) Uani 1 1 d
C19 C 0.0075(3) 0.6989(3) 0.4339(3) 0.0210(7) Uani 1 1 d
C20 C 0.3494(5) 0.8920(5) 0.4903(5) 0.0456(12) Uani 1 1 d
H20A H 0.340(4) 0.973(5) 0.544(4) 0.050(13) Uiso 1 1 d
H20B H 0.352(4) 0.916(4) 0.423(4) 0.044(13) Uiso 1 1 d
H20C H 0.426(5) 0.866(4) 0.521(4) 0.042(13) Uiso 1 1 d
C21 C -0.2603(4) 0.7174(4) 0.5952(3) 0.0256(8) Uani 1 1 d
H21A H -0.219(3) 0.787(3) 0.574(3) 0.013(8) Uiso 1 1 d
H21B H -0.354(4) 0.702(4) 0.571(3) 0.024(10) Uiso 1 1 d
C22 C -0.2068(4) 0.7480(4) 0.7213(3) 0.0271(8) Uani 1 1 d
H22A H -0.236(3) 0.816(4) 0.755(3) 0.018(9) Uiso 1 1 d
H22B H -0.233(3) 0.676(3) 0.744(3) 0.011(8) Uiso 1 1 d
C23 C 0.0075(4) 0.8944(3) 0.8202(3) 0.0255(8) Uani 1 1 d
H23 H -0.043(3) 0.947(4) 0.858(3) 0.021(9) Uiso 1 1 d
C24 C 0.1526(4) 0.9530(3) 0.8530(3) 0.0274(8) Uani 1 1 d
C25 C 0.2071(4) 1.0685(4) 0.9438(3) 0.0344(9) Uani 1 1 d
H25 H 0.149(4) 1.096(4) 0.980(3) 0.021(10) Uiso 1 1 d
C26 C 0.3416(5) 1.1303(4) 0.9763(4) 0.0413(11) Uani 1 1 d
H26 H 0.376(5) 1.201(5) 1.033(4) 0.049(14) Uiso 1 1 d
C27 C 0.4257(4) 1.0828(4) 0.9169(4) 0.0364(10) Uani 1 1 d
H27 H 0.519(5) 1.118(4) 0.932(4) 0.048(13) Uiso 1 1 d
C28 C 0.3739(4) 0.9731(4) 0.8251(3) 0.0303(8) Uani 1 1 d
C29 C 0.2346(4) 0.9028(3) 0.7896(3) 0.0260(8) Uani 1 1 d
C30 C 0.5856(5) 0.9949(5) 0.7834(5) 0.0425(11) Uani 1 1 d
H30A H 0.581(4) 1.068(5) 0.777(4) 0.035(12) Uiso 1 1 d
H30B H 0.618(5) 0.947(5) 0.729(4) 0.054(14) Uiso 1 1 d
H30C H 0.641(4) 1.012(4) 0.865(4) 0.043(13) Uiso 1 1 d
N1 N -0.1810(3) 0.3548(3) 0.1519(2) 0.0250(7) Uani 1 1 d
N2 N -0.2592(3) 0.4789(3) 0.3453(2) 0.0215(6) Uani 1 1 d
N3 N -0.2199(3) 0.6087(3) 0.5321(2) 0.0204(6) Uani 1 1 d
N4 N -0.0581(3) 0.7836(3) 0.7504(2) 0.0245(7) Uani 1 1 d
O1 O 0.0958(2) 0.4745(2) 0.2470(2) 0.0246(5) Uani 1 1 d
O2 O 0.3477(3) 0.5161(3) 0.2090(2) 0.0358(6) Uani 1 1 d
O3 O 0.0357(2) 0.6038(2) 0.46869(19) 0.0189(5) Uani 1 1 d
O4 O 0.2401(2) 0.7815(2) 0.4590(2) 0.0328(6) Uani 1 1 d
O5 O 0.1900(2) 0.7985(2) 0.7027(2) 0.0268(6) Uani 1 1 d
O6 O 0.4508(3) 0.9208(3) 0.7607(2) 0.0370(7) Uani 1 1 d
Gd1 Gd -0.032274(16) 0.391020(15) 0.345621(13) 0.01928(7) Uani 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 C6 120.9(3) . .
O1 C1 C2 123.6(3) . .
C6 C1 C2 115.5(3) . .
C3 C2 C1 121.0(4) . .
C3 C2 C8 117.6(4) . .
C1 C2 C8 121.2(3) . .
C4 C3 C2 121.9(4) . .
C4 C3 H3 121(2) . .
C2 C3 H3 117(3) . .
C3 C4 C5 118.8(4) . .
C3 C4 H4 121(3) . .
C5 C4 H4 120(3) . .
C6 C5 C4 120.9(4) . .
C6 C5 H5 110(3) . .
C4 C5 H5 129(3) . .
C5 C6 O2 118.9(3) . .
C5 C6 C1 121.9(4) . .
O2 C6 C1 119.1(3) . .
O2 C7 H7A 113(4) . .
O2 C7 H7B 103(3) . .
H7A C7 H7B 114(5) . .
O2 C7 H7C 109(3) . .
H7A C7 H7C 114(5) . .
H7B C7 H7C 103(4) . .
N1 C8 C2 126.7(3) . .
N1 C8 H8 116(2) . .
C2 C8 H8 117(2) . .
N1 C9 C10 107.9(3) . .
N1 C9 H9A 114(2) . .
C10 C9 H9A 105(2) . .
N1 C9 H9B 108(2) . .
C10 C9 H9B 109(2) . .
H9A C9 H9B 113(3) . .
N2 C10 C9 111.2(3) . .
N2 C10 H10A 110(2) . .
C9 C10 H10A 106(2) . .
N2 C10 H10B 108(2) . .
C9 C10 H10B 111(2) . .
H10A C10 H10B 110(3) . .
N2 C11 C12 105.6(3) . .
N2 C11 H11A 114(3) . .
C12 C11 H11A 111(3) . .
N2 C11 H11B 107(2) . .
C12 C11 H11B 111(2) . .
H11A C11 H11B 109(4) . .
N3 C12 C11 105.7(3) . .
N3 C12 H12A 111(2) . .
C11 C12 H12A 109(2) . .
N3 C12 H12B 111(3) . .
C11 C12 H12B 110(3) . .
H12A C12 H12B 109(3) . .
N2 C13 N3 104.7(3) . .
N2 C13 C14 114.9(3) . .
N3 C13 C14 113.5(3) . .
N2 C13 H13 108(2) . .
N3 C13 H13 107(2) . .
C14 C13 H13 109(2) . .
C15 C14 C19 120.8(3) . .
C15 C14 C13 120.1(3) . .
C19 C14 C13 119.0(3) . .
C16 C15 C14 121.0(4) . .
C16 C15 H15 119(3) . .
C14 C15 H15 120(3) . .
C15 C16 C17 119.6(4) . .
C15 C16 H16 123(3) . .
C17 C16 H16 118(3) . .
C18 C17 C16 120.0(4) . .
C18 C17 H17 117(2) . .
C16 C17 H17 123(2) . .
O4 C18 C17 123.6(3) . .
O4 C18 C19 115.1(3) . .
C17 C18 C19 121.3(4) . .
O3 C19 C14 122.0(3) . .
O3 C19 C18 120.7(3) . .
C14 C19 C18 117.3(3) . .
O4 C20 H20A 116(3) . .
O4 C20 H20B 108(3) . .
H20A C20 H20B 102(4) . .
O4 C20 H20C 103(3) . .
H20A C20 H20C 113(4) . .
H20B C20 H20C 115(4) . .
N3 C21 C22 111.7(3) . .
N3 C21 H21A 104(2) . .
C22 C21 H21A 109(2) . .
N3 C21 H21B 110(2) . .
C22 C21 H21B 113(2) . .
H21A C21 H21B 108(3) . .
N4 C22 C21 107.3(3) . .
N4 C22 H22A 111(2) . .
C21 C22 H22A 107(2) . .
N4 C22 H22B 106(2) . .
C21 C22 H22B 112(2) . .
H22A C22 H22B 113(3) . .
N4 C23 C24 127.0(3) . .
N4 C23 H23 118(2) . .
C24 C23 H23 115(2) . .
C25 C24 C29 120.9(4) . .
C25 C24 C23 117.7(3) . .
C29 C24 C23 121.2(3) . .
C26 C25 C24 120.5(4) . .
C26 C25 H25 123(2) . .
C24 C25 H25 116(2) . .
C25 C26 C27 120.1(4) . .
C25 C26 H26 121(3) . .
C27 C26 H26 119(3) . .
C28 C27 C26 120.4(4) . .
C28 C27 H27 113(3) . .
C26 C27 H27 127(3) . .
C27 C28 O6 123.9(4) . .
C27 C28 C29 121.6(4) . .
O6 C28 C29 114.5(3) . .
O5 C29 C24 124.1(3) . .
O5 C29 C28 119.6(3) . .
C24 C29 C28 116.3(3) . .
O6 C30 H30A 107(3) . .
O6 C30 H30B 104(3) . .
H30A C30 H30B 114(4) . .
O6 C30 H30C 111(3) . .
H30A C30 H30C 107(4) . .
H30B C30 H30C 114(4) . .
C8 N1 C9 117.5(3) . .
C8 N1 Gd1 128.2(3) . .
C9 N1 Gd1 114.3(2) . .
C13 N2 C10 107.4(3) . .
C13 N2 C11 102.8(3) . .
C10 N2 C11 111.0(3) . .
C13 N2 Gd1 117.9(2) . .
C10 N2 Gd1 108.34(19) . .
C11 N2 Gd1 109.4(2) . .
C21 N3 C13 107.2(3) . .
C21 N3 C12 113.1(3) . .
C13 N3 C12 104.8(3) . .
C21 N3 Gd1 109.6(2) . 2_566
C13 N3 Gd1 118.61(19) . 2_566
C12 N3 Gd1 103.5(2) . 2_566
C23 N4 C22 117.8(3) . .
C23 N4 Gd1 128.8(2) . 2_566
C22 N4 Gd1 113.4(2) . 2_566
C1 O1 Gd1 133.4(2) . .
C6 O2 C7 113.0(3) . .
C19 O3 Gd1 122.2(2) . .
C19 O3 Gd1 118.38(19) . 2_566
Gd1 O3 Gd1 110.40(9) . 2_566
C18 O4 C20 116.8(3) . .
C29 O5 Gd1 135.2(2) . 2_566
C28 O6 C30 116.7(3) . .
O5 Gd1 O1 131.56(9) 2_566 .
O5 Gd1 O3 142.27(8) 2_566 .
O1 Gd1 O3 83.67(8) . .
O5 Gd1 O3 82.44(8) 2_566 2_566
O1 Gd1 O3 142.95(8) . 2_566
O3 Gd1 O3 69.60(9) . 2_566
O5 Gd1 N1 73.96(9) 2_566 .
O1 Gd1 N1 71.01(9) . .
O3 Gd1 N1 114.72(9) . .
O3 Gd1 N1 143.30(9) 2_566 .
O5 Gd1 N4 71.26(9) 2_566 2_566
O1 Gd1 N4 73.81(9) . 2_566
O3 Gd1 N4 142.71(9) . 2_566
O3 Gd1 N4 112.94(9) 2_566 2_566
N1 Gd1 N4 85.82(9) . 2_566
O5 Gd1 N3 112.16(9) 2_566 2_566
O1 Gd1 N3 81.32(8) . 2_566
O3 Gd1 N3 82.34(8) . 2_566
O3 Gd1 N3 70.39(8) 2_566 2_566
N1 Gd1 N3 144.79(9) . 2_566
N4 Gd1 N3 65.40(9) 2_566 2_566
O5 Gd1 N2 81.39(9) 2_566 .
O1 Gd1 N2 112.38(9) . .
O3 Gd1 N2 70.87(8) . .
O3 Gd1 N2 83.20(8) 2_566 .
N1 Gd1 N2 65.99(9) . .
N4 Gd1 N2 145.32(9) 2_566 .
N3 Gd1 N2 147.64(8) 2_566 .
O5 Gd1 Gd1 113.58(6) 2_566 2_566
O1 Gd1 Gd1 114.85(6) . 2_566
O3 Gd1 Gd1 34.90(5) . 2_566
O3 Gd1 Gd1 34.70(5) 2_566 2_566
N1 Gd1 Gd1 138.03(7) . 2_566
N4 Gd1 Gd1 136.15(7) 2_566 2_566
N3 Gd1 Gd1 73.39(6) 2_566 2_566
N2 Gd1 Gd1 74.26(6) . 2_566
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.308(4) .
C1 C6 1.423(5) .
C1 C2 1.424(5) .
C2 C3 1.396(5) .
C2 C8 1.447(5) .
C3 C4 1.358(6) .
C3 H3 0.92(4) .
C4 C5 1.392(7) .
C4 H4 0.95(4) .
C5 C6 1.384(5) .
C5 H5 0.90(4) .
C6 O2 1.391(5) .
C7 O2 1.420(6) .
C7 H7A 0.89(5) .
C7 H7B 0.93(5) .
C7 H7C 0.96(5) .
C8 N1 1.286(5) .
C8 H8 0.97(4) .
C9 N1 1.458(5) .
C9 C10 1.510(5) .
C9 H9A 0.94(4) .
C9 H9B 0.90(4) .
C10 N2 1.487(5) .
C10 H10A 0.95(4) .
C10 H10B 0.98(4) .
C11 N2 1.490(5) .
C11 C12 1.525(5) .
C11 H11A 0.88(5) .
C11 H11B 1.10(4) .
C12 N3 1.501(4) .
C12 H12A 1.01(4) .
C12 H12B 0.90(5) .
C13 N2 1.479(4) .
C13 N3 1.488(4) .
C13 C14 1.506(5) .
C13 H13 0.95(4) .
C14 C15 1.391(5) .
C14 C19 1.405(5) .
C15 C16 1.367(6) .
C15 H15 0.87(4) .
C16 C17 1.398(6) .
C16 H16 0.89(4) .
C17 C18 1.386(5) .
C17 H17 0.91(4) .
C18 O4 1.379(4) .
C18 C19 1.410(5) .
C19 O3 1.338(4) .
C20 O4 1.412(5) .
C20 H20A 1.03(5) .
C20 H20B 0.98(5) .
C20 H20C 0.95(5) .
C21 N3 1.483(4) .
C21 C22 1.509(5) .
C21 H21A 0.96(4) .
C21 H21B 0.93(4) .
C22 N4 1.470(5) .
C22 H22A 0.92(4) .
C22 H22B 0.95(4) .
C23 N4 1.277(5) .
C23 C24 1.452(5) .
C23 H23 0.98(4) .
C24 C25 1.409(5) .
C24 C29 1.414(5) .
C25 C26 1.360(6) .
C25 H25 0.91(4) .
C26 C27 1.391(6) .
C26 H26 0.87(5) .
C27 C28 1.376(5) .
C27 H27 0.94(5) .
C28 O6 1.387(5) .
C28 C29 1.425(5) .
C29 O5 1.304(4) .
C30 O6 1.417(5) .
C30 H30A 0.87(5) .
C30 H30B 0.93(5) .
C30 H30C 1.03(5) .
N1 Gd1 2.510(3) .
N2 Gd1 2.777(3) .
N3 Gd1 2.777(3) 2_566
N4 Gd1 2.521(3) 2_566
O1 Gd1 2.278(2) .
O3 Gd1 2.366(2) .
O3 Gd1 2.379(2) 2_566
O5 Gd1 2.267(2) 2_566
Gd1 O5 2.267(2) 2_566
Gd1 O3 2.379(2) 2_566
Gd1 N4 2.521(3) 2_566
Gd1 N3 2.777(3) 2_566
Gd1 Gd1 3.8963(4) 2_566
