#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:23:19 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180432 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/01/7210122.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210122
loop_
_publ_author_name
'Xu, Guohai'
'Lv, Jianyi'
'Guo, Peng'
'Zhou, Zhonggao'
'Du, Ziyi'
'Xie, Yongrong'
_publ_section_title
;
 Two ligand-length-tunable interpenetrating coordination networks with
 stable Zn2 unit as three-connected uninode and supramolecular topologies
;
_journal_issue                   22
_journal_name_full               CrystEngComm
_journal_page_first              4473
_journal_paper_doi               10.1039/c3ce40117k
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C36 H40 N2 O18 Zn4, 2(C H4 O)'
_chemical_formula_sum            'C38 H48 N2 O20 Zn4'
_chemical_formula_weight         1114.26
_chemical_melting_point          ?
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.608(5)
_cell_angle_beta                 101.952(5)
_cell_angle_gamma                98.351(5)
_cell_formula_units_Z            2
_cell_length_a                   11.302(5)
_cell_length_b                   11.733(5)
_cell_length_c                   19.506(5)
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.6
_cell_measurement_theta_min      1.9
_cell_volume                     2381.2(16)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1999)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97(Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0529
_diffrn_reflns_av_sigmaI/netI    0.1063
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            15868
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         26.57
_diffrn_reflns_theta_min         1.93
_exptl_absorpt_coefficient_mu    2.066
_exptl_absorpt_correction_T_max  0.524
_exptl_absorpt_correction_T_min  0.373
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.554
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1140
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.27
_refine_diff_density_max         1.103
_refine_diff_density_min         -0.750
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.907
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     569
_refine_ls_number_reflns         9618
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      0.913
_refine_ls_R_factor_all          0.0889
_refine_ls_R_factor_gt           0.0491
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0456P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1211
_refine_ls_wR_factor_ref         0.1375
_reflns_number_gt                5663
_reflns_number_total             9618
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40117k.txt
_cod_data_source_block           compound1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

'_symmetry_cell_setting' value
'Triclinic' changed to 'triclinic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        2381.2(2)
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7210122
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.8172(5) 0.3145(5) 0.3606(3) 0.0442(12) Uani 1 1 d .
C2 C 0.8538(4) 0.2154(4) 0.3098(3) 0.0376(11) Uani 1 1 d .
C3 C 0.9529(5) 0.2370(4) 0.2820(3) 0.0441(12) Uani 1 1 d .
H3 H 0.9980 0.3158 0.2945 0.053 Uiso 1 1 calc R
C4 C 0.9869(5) 0.1451(5) 0.2361(3) 0.0531(14) Uani 1 1 d .
H4 H 1.0558 0.1613 0.2184 0.064 Uiso 1 1 calc R
C5 C 0.9190(4) 0.0273(4) 0.2157(3) 0.0398(11) Uani 1 1 d .
C6 C 0.8192(5) 0.0053(4) 0.2447(3) 0.0477(13) Uani 1 1 d .
H6 H 0.7737 -0.0733 0.2323 0.057 Uiso 1 1 calc R
C7 C 0.7871(5) 0.0983(4) 0.2913(3) 0.0476(13) Uani 1 1 d .
H7 H 0.7201 0.0827 0.3106 0.057 Uiso 1 1 calc R
C8 C 0.9558(4) -0.0736(5) 0.1664(3) 0.0434(12) Uani 1 1 d .
C9 C 0.8247(4) -0.2928(5) -0.0367(3) 0.0409(11) Uani 1 1 d .
C10 C 0.7332(4) -0.3146(4) -0.1082(3) 0.0359(11) Uani 1 1 d .
C11 C 0.7475(5) -0.2388(5) -0.1500(3) 0.0503(13) Uani 1 1 d .
H11 H 0.8121 -0.1710 -0.1325 0.060 Uiso 1 1 calc R
C12 C 0.6663(5) -0.2632(5) -0.2173(3) 0.0524(14) Uani 1 1 d .
H12 H 0.6774 -0.2121 -0.2457 0.063 Uiso 1 1 calc R
C13 C 0.5690(4) -0.3613(4) -0.2438(3) 0.0386(11) Uani 1 1 d .
C14 C 0.5544(5) -0.4370(5) -0.2011(3) 0.0502(13) Uani 1 1 d .
H14 H 0.4886 -0.5037 -0.2181 0.060 Uiso 1 1 calc R
C15 C 0.6366(5) -0.4140(5) -0.1339(3) 0.0508(14) Uani 1 1 d .
H15 H 0.6269 -0.4657 -0.1058 0.061 Uiso 1 1 calc R
C16 C 0.4805(4) -0.3893(4) -0.3165(3) 0.0374(11) Uani 1 1 d .
C17 C 0.8928(5) 0.7466(4) 0.4540(3) 0.0442(12) Uani 1 1 d .
C18 C 0.9484(4) 0.8771(4) 0.4770(3) 0.0383(11) Uani 1 1 d .
C19 C 1.0299(5) 0.9315(4) 0.5447(3) 0.0501(14) Uani 1 1 d .
H19 H 1.0502 0.8855 0.5757 0.060 Uiso 1 1 calc R
C20 C 1.0820(5) 1.0524(5) 0.5674(3) 0.0498(13) Uani 1 1 d .
H20 H 1.1384 1.0874 0.6133 0.060 Uiso 1 1 calc R
C21 C 1.2979(7) -0.0751(6) 0.0575(5) 0.076(2) Uani 1 1 d .
C22 C 1.4033(5) -0.0357(6) 0.0284(4) 0.0713(19) Uani 1 1 d .
C23 C 1.3845(6) -0.0438(8) -0.0455(4) 0.092(2) Uani 1 1 d .
H23 H 1.3050 -0.0723 -0.0765 0.111 Uiso 1 1 calc R
C24 C 1.4790(6) -0.0113(8) -0.0734(4) 0.097(3) Uani 1 1 d .
H24 H 1.4643 -0.0207 -0.1235 0.116 Uiso 1 1 calc R
C25 C 0.7658(5) 0.5455(4) 0.5657(3) 0.0434(12) Uani 1 1 d .
H25A H 0.7158 0.5741 0.5989 0.052 Uiso 1 1 calc R
H25B H 0.8371 0.6100 0.5753 0.052 Uiso 1 1 calc R
C26 C 0.8086(4) 0.4356(5) 0.5796(3) 0.0452(12) Uani 1 1 d .
H26A H 0.8718 0.4172 0.5540 0.054 Uiso 1 1 calc R
H26B H 0.8450 0.4532 0.6319 0.054 Uiso 1 1 calc R
C27 C 0.4894(5) 0.2978(5) 0.5659(3) 0.0498(13) Uani 1 1 d .
H27A H 0.4676 0.2100 0.5478 0.060 Uiso 1 1 calc R
H27B H 0.4395 0.3256 0.5993 0.060 Uiso 1 1 calc R
C28 C 0.6242(5) 0.3396(5) 0.6056(3) 0.0506(13) Uani 1 1 d .
H28A H 0.6394 0.4231 0.6362 0.061 Uiso 1 1 calc R
H28B H 0.6451 0.2911 0.6377 0.061 Uiso 1 1 calc R
C29 C 0.6472(5) 0.1109(5) 0.4972(3) 0.0585(15) Uani 1 1 d D
H29A H 0.6799 0.0404 0.4780 0.070 Uiso 1 1 calc R
H29B H 0.5955 0.0918 0.5282 0.070 Uiso 1 1 calc R
C30 C 0.7516(5) 0.2160(5) 0.5415(3) 0.0520(14) Uani 1 1 d .
H30A H 0.7874 0.2050 0.5884 0.062 Uiso 1 1 calc R
H30B H 0.8155 0.2204 0.5154 0.062 Uiso 1 1 calc R
C31 C 1.1641(6) -0.3418(7) 0.1326(3) 0.0651(17) Uani 1 1 d .
H31A H 1.2411 -0.2841 0.1425 0.078 Uiso 1 1 calc R
H31B H 1.1791 -0.4226 0.1149 0.078 Uiso 1 1 calc R
C32 C 1.1227(5) -0.3279(6) 0.2029(3) 0.0630(16) Uani 1 1 d .
H32A H 1.1809 -0.3519 0.2375 0.076 Uiso 1 1 calc R
H32B H 1.1218 -0.2436 0.2251 0.076 Uiso 1 1 calc R
C33 C 0.7970(6) -0.4107(6) 0.2192(3) 0.0634(16) Uani 1 1 d .
H33A H 0.7772 -0.4942 0.2188 0.076 Uiso 1 1 calc R
H33B H 0.7558 -0.3634 0.2520 0.076 Uiso 1 1 calc R
C34 C 0.9343(5) -0.3630(6) 0.2462(3) 0.0635(16) Uani 1 1 d .
H34A H 0.9516 -0.2752 0.2634 0.076 Uiso 1 1 calc R
H34B H 0.9668 -0.3907 0.2874 0.076 Uiso 1 1 calc R
C35 C 0.9978(7) -0.5342(6) 0.1688(4) 0.0706(19) Uani 1 1 d .
H35A H 0.9947 -0.5602 0.2117 0.085 Uiso 1 1 calc R
H35B H 1.0751 -0.5462 0.1568 0.085 Uiso 1 1 calc R
C36 C 0.8935(7) -0.6109(6) 0.1062(3) 0.0696(19) Uani 1 1 d .
H36A H 0.9101 -0.6910 0.0883 0.084 Uiso 1 1 calc R
H36B H 0.8181 -0.6195 0.1224 0.084 Uiso 1 1 calc R
C37 C 0.4920(18) -0.3278(18) 0.0355(11) 0.264(9) Uiso 1 1 d .
H37A H 0.4091 -0.3195 0.0367 0.317 Uiso 1 1 calc R
H37B H 0.4901 -0.4071 0.0042 0.317 Uiso 1 1 calc R
H37C H 0.5288 -0.2678 0.0167 0.317 Uiso 1 1 calc R
C38 C 0.2489(14) 0.0662(14) 0.3642(8) 0.204(6) Uiso 1 1 d .
H38A H 0.1724 0.0071 0.3439 0.245 Uiso 1 1 calc R
H38B H 0.2556 0.1168 0.3333 0.245 Uiso 1 1 calc R
H38C H 0.2506 0.1152 0.4127 0.245 Uiso 1 1 calc R
N1 N 0.7053(3) 0.3302(3) 0.5544(2) 0.0400(9) Uani 1 1 d .
N2 N 0.9966(4) -0.4039(4) 0.1875(2) 0.0527(12) Uani 1 1 d .
O1 O 0.7477(4) 0.2873(3) 0.3973(2) 0.0559(10) Uani 1 1 d .
O2 O 0.8625(3) 0.4211(3) 0.3642(2) 0.0550(10) Uani 1 1 d .
O3 O 1.0441(3) -0.0427(3) 0.1402(2) 0.0620(11) Uani 1 1 d .
O4 O 0.8993(3) -0.1793(3) 0.1537(2) 0.0542(9) Uani 1 1 d .
O5 O 0.9216(3) -0.2162(3) -0.02111(19) 0.0500(9) Uani 1 1 d .
O6 O 0.7973(3) -0.3573(3) 0.00302(19) 0.0527(9) Uani 1 1 d .
O7 O 0.5054(3) -0.3251(3) -0.35610(19) 0.0526(9) Uani 1 1 d .
O8 O 0.3890(3) -0.4737(3) -0.33372(18) 0.0488(9) Uani 1 1 d .
O9 O 0.9364(4) 0.6820(3) 0.4902(2) 0.0601(10) Uani 1 1 d .
O10 O 0.8002(3) 0.7028(3) 0.3984(2) 0.0500(9) Uani 1 1 d .
O11 O 1.3163(5) -0.0791(6) 0.1201(3) 0.108(2) Uani 1 1 d .
O12 O 1.1931(4) -0.1075(4) 0.0147(3) 0.0729(13) Uani 1 1 d .
O13 O 0.6945(3) 0.5160(3) 0.49080(16) 0.0335(7) Uani 1 1 d .
O14 O 0.4661(3) 0.3462(4) 0.5054(2) 0.0533(10) Uani 1 1 d D
O15 O 0.5760(4) 0.1401(3) 0.4383(2) 0.0554(10) Uani 1 1 d D
O16 O 1.0722(3) -0.3221(3) 0.07721(18) 0.0431(8) Uani 1 1 d .
O17 O 0.7544(3) -0.4035(4) 0.1464(2) 0.0551(10) Uani 1 1 d D
O18 O 0.8774(4) -0.5568(3) 0.0475(2) 0.0653(11) Uani 1 1 d D
O19 O 0.5657(18) -0.3110(17) 0.1107(11) 0.346(8) Uiso 1 1 d D
H05 H 0.5223 -0.3411 0.1329 0.416 Uiso 1 1 calc RD
O20 O 0.3523(7) 0.0048(8) 0.3685(4) 0.178(3) Uiso 1 1 d D
H06 H 0.3529 -0.0343 0.3269 0.214 Uiso 1 1 calc RD
Zn1 Zn 0.60808(5) 0.33534(5) 0.45071(3) 0.03407(15) Uani 1 1 d .
Zn2 Zn 0.77381(5) 0.53596(4) 0.41287(3) 0.03451(15) Uani 1 1 d .
Zn3 Zn 1.07424(5) -0.16395(5) 0.06114(3) 0.04007(16) Uani 1 1 d .
Zn4 Zn 0.90033(5) -0.36291(5) 0.09446(3) 0.03894(16) Uani 1 1 d D
H01 H 0.400(3) 0.381(5) 0.499(3) 0.058 Uiso 1 1 d D
H02 H 0.512(3) 0.080(2) 0.4061(17) 0.058 Uiso 1 1 d D
H03 H 0.680(2) -0.446(4) 0.143(3) 0.058 Uiso 1 1 d D
H04 H 0.917(4) -0.5727(13) 0.012(2) 0.058 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O2 124.8(5) . .
O1 C1 C2 118.2(5) . .
O2 C1 C2 117.0(4) . .
C3 C2 C7 119.4(4) . .
C3 C2 C1 121.5(5) . .
C7 C2 C1 119.1(4) . .
C4 C3 C2 121.1(5) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.4 . .
C3 C4 C5 120.1(5) . .
C3 C4 H4 119.9 . .
C5 C4 H4 119.9 . .
C6 C5 C4 118.7(4) . .
C6 C5 C8 120.7(5) . .
C4 C5 C8 120.6(4) . .
C7 C6 C5 120.5(5) . .
C7 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C6 C7 C2 120.2(4) . .
C6 C7 H7 119.9 . .
C2 C7 H7 119.9 . .
O4 C8 O3 125.4(5) . .
O4 C8 C5 119.2(4) . .
O3 C8 C5 115.4(4) . .
O5 C9 O6 125.1(5) . .
O5 C9 C10 118.3(4) . .
O6 C9 C10 116.6(4) . .
C11 C10 C15 119.8(5) . .
C11 C10 C9 120.3(4) . .
C15 C10 C9 119.8(4) . .
C12 C11 C10 119.8(5) . .
C12 C11 H11 120.1 . .
C10 C11 H11 120.1 . .
C11 C12 C13 121.3(5) . .
C11 C12 H12 119.3 . .
C13 C12 H12 119.3 . .
C12 C13 C14 118.6(5) . .
C12 C13 C16 122.1(4) . .
C14 C13 C16 119.3(4) . .
C15 C14 C13 120.4(5) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C14 C15 C10 120.0(5) . .
C14 C15 H15 120.0 . .
C10 C15 H15 120.0 . .
O8 C16 O7 125.5(5) . .
O8 C16 C13 118.0(4) . .
O7 C16 C13 116.5(4) . .
O9 C17 O10 121.5(5) . .
O9 C17 C18 119.5(5) . .
O10 C17 C18 119.0(5) . .
O9 C17 Zn2 65.9(3) . .
O10 C17 Zn2 55.7(2) . .
C18 C17 Zn2 172.6(4) . .
C19 C18 C20 118.5(5) . 2_776
C19 C18 C17 120.0(4) . .
C20 C18 C17 121.5(5) 2_776 .
C20 C19 C18 121.1(5) . .
C20 C19 H19 119.5 . .
C18 C19 H19 119.5 . .
C19 C20 C18 120.5(5) . 2_776
C19 C20 H20 119.8 . .
C18 C20 H20 119.8 2_776 .
O11 C21 O12 122.0(6) . .
O11 C21 C22 120.2(7) . .
O12 C21 C22 117.7(7) . .
C24 C22 C23 117.8(6) 2_855 .
C24 C22 C21 121.7(7) 2_855 .
C23 C22 C21 120.5(6) . .
C24 C23 C22 121.5(6) . .
C24 C23 H23 119.2 . .
C22 C23 H23 119.2 . .
C23 C24 C22 120.6(7) . 2_855
C23 C24 H24 119.7 . .
C22 C24 H24 119.7 2_855 .
O13 C25 C26 110.4(4) . .
O13 C25 H25A 109.6 . .
C26 C25 H25A 109.6 . .
O13 C25 H25B 109.6 . .
C26 C25 H25B 109.6 . .
H25A C25 H25B 108.1 . .
N1 C26 C25 111.1(4) . .
N1 C26 H26A 109.4 . .
C25 C26 H26A 109.4 . .
N1 C26 H26B 109.4 . .
C25 C26 H26B 109.4 . .
H26A C26 H26B 108.0 . .
O14 C27 C28 108.7(4) . .
O14 C27 H27A 109.9 . .
C28 C27 H27A 109.9 . .
O14 C27 H27B 109.9 . .
C28 C27 H27B 109.9 . .
H27A C27 H27B 108.3 . .
N1 C28 C27 112.5(4) . .
N1 C28 H28A 109.1 . .
C27 C28 H28A 109.1 . .
N1 C28 H28B 109.1 . .
C27 C28 H28B 109.1 . .
H28A C28 H28B 107.8 . .
O15 C29 C30 109.6(4) . .
O15 C29 H29A 109.7 . .
C30 C29 H29A 109.7 . .
O15 C29 H29B 109.7 . .
C30 C29 H29B 109.7 . .
H29A C29 H29B 108.2 . .
N1 C30 C29 109.8(4) . .
N1 C30 H30A 109.7 . .
C29 C30 H30A 109.7 . .
N1 C30 H30B 109.7 . .
C29 C30 H30B 109.7 . .
H30A C30 H30B 108.2 . .
O16 C31 C32 110.7(4) . .
O16 C31 H31A 109.5 . .
C32 C31 H31A 109.5 . .
O16 C31 H31B 109.5 . .
C32 C31 H31B 109.5 . .
H31A C31 H31B 108.1 . .
N2 C32 C31 110.8(5) . .
N2 C32 H32A 109.5 . .
C31 C32 H32A 109.5 . .
N2 C32 H32B 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 108.1 . .
O17 C33 C34 109.5(4) . .
O17 C33 H33A 109.8 . .
C34 C33 H33A 109.8 . .
O17 C33 H33B 109.8 . .
C34 C33 H33B 109.8 . .
H33A C33 H33B 108.2 . .
N2 C34 C33 111.3(5) . .
N2 C34 H34A 109.4 . .
C33 C34 H34A 109.4 . .
N2 C34 H34B 109.4 . .
C33 C34 H34B 109.4 . .
H34A C34 H34B 108.0 . .
N2 C35 C36 113.4(5) . .
N2 C35 H35A 108.9 . .
C36 C35 H35A 108.9 . .
N2 C35 H35B 108.9 . .
C36 C35 H35B 108.9 . .
H35A C35 H35B 107.7 . .
O18 C36 C35 110.0(5) . .
O18 C36 H36A 109.7 . .
C35 C36 H36A 109.7 . .
O18 C36 H36B 109.7 . .
C35 C36 H36B 109.7 . .
H36A C36 H36B 108.2 . .
O19 C37 H37A 109.5 . .
O19 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
O19 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
O20 C38 H38A 109.5 . .
O20 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
O20 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C26 N1 C28 111.4(4) . .
C26 N1 C30 110.6(4) . .
C28 N1 C30 112.8(4) . .
C26 N1 Zn1 104.0(3) . .
C28 N1 Zn1 110.4(3) . .
C30 N1 Zn1 107.2(3) . .
C34 N2 C35 113.1(5) . .
C34 N2 C32 112.7(4) . .
C35 N2 C32 111.9(5) . .
C34 N2 Zn4 106.3(3) . .
C35 N2 Zn4 110.7(3) . .
C32 N2 Zn4 101.4(3) . .
C1 O1 Zn1 146.5(3) . .
C1 O2 Zn2 111.2(3) . .
C8 O3 Zn3 117.2(3) . .
C8 O4 Zn4 140.5(3) . .
C9 O5 Zn3 133.7(3) . .
C9 O6 Zn4 127.5(3) . .
C16 O7 Zn1 123.3(3) . 2_655
C16 O8 Zn2 136.6(3) . 2_655
C17 O9 Zn2 83.7(3) . .
C17 O10 Zn2 93.5(3) . .
C21 O12 Zn3 110.6(5) . .
C25 O13 Zn2 121.1(3) . .
C25 O13 Zn1 110.4(2) . .
Zn2 O13 Zn1 102.15(13) . .
C27 O14 Zn1 111.0(3) . .
C27 O14 H01 119(3) . .
Zn1 O14 H01 130(3) . .
C29 O15 Zn1 114.2(3) . .
C29 O15 H02 116.8(14) . .
Zn1 O15 H02 127.5(16) . .
C31 O16 Zn3 122.9(4) . .
C31 O16 Zn4 110.3(3) . .
Zn3 O16 Zn4 102.17(14) . .
C33 O17 Zn4 114.5(3) . .
C33 O17 H03 89(3) . .
Zn4 O17 H03 150(4) . .
C36 O18 Zn4 109.2(3) . .
C36 O18 H04 122(3) . .
Zn4 O18 H04 110.0(10) . .
C37 O19 H05 109.5 . .
C38 O20 H06 109.5 . .
O7 Zn1 O13 102.45(14) 2_655 .
O7 Zn1 O14 92.24(15) 2_655 .
O13 Zn1 O14 97.64(14) . .
O7 Zn1 N1 171.08(15) 2_655 .
O13 Zn1 N1 83.82(14) . .
O14 Zn1 N1 80.54(14) . .
O7 Zn1 O1 91.35(15) 2_655 .
O13 Zn1 O1 92.71(13) . .
O14 Zn1 O1 168.05(14) . .
N1 Zn1 O1 94.71(15) . .
O7 Zn1 O15 97.82(15) 2_655 .
O13 Zn1 O15 158.72(13) . .
O14 Zn1 O15 87.91(15) . .
N1 Zn1 O15 76.82(15) . .
O1 Zn1 O15 80.30(14) . .
O7 Zn1 Zn2 82.48(10) 2_655 .
O13 Zn1 Zn2 37.82(8) . .
O14 Zn1 Zn2 130.57(11) . .
N1 Zn1 Zn2 106.19(11) . .
O1 Zn1 Zn2 61.24(10) . .
O15 Zn1 Zn2 141.51(11) . .
O2 Zn2 O13 124.37(14) . .
O2 Zn2 O8 96.30(15) . 2_655
O13 Zn2 O8 92.72(13) . 2_655
O2 Zn2 O10 116.55(15) . .
O13 Zn2 O10 117.52(13) . .
O8 Zn2 O10 93.36(14) 2_655 .
O2 Zn2 O9 99.83(15) . .
O13 Zn2 O9 94.82(14) . .
O8 Zn2 O9 153.99(13) 2_655 .
O10 Zn2 O9 61.16(14) . .
O2 Zn2 C17 112.19(16) . .
O13 Zn2 C17 107.19(15) . .
O8 Zn2 C17 123.89(17) 2_655 .
O10 Zn2 C17 30.87(15) . .
O9 Zn2 C17 30.33(15) . .
O2 Zn2 Zn1 92.67(11) . .
O13 Zn2 Zn1 40.02(9) . .
O8 Zn2 Zn1 71.24(10) 2_655 .
O10 Zn2 Zn1 148.69(11) . .
O9 Zn2 Zn1 127.76(10) . .
C17 Zn2 Zn1 147.13(12) . .
O12 Zn3 O3 115.53(17) . .
O12 Zn3 O16 118.41(16) . .
O3 Zn3 O16 114.37(16) . .
O12 Zn3 O5 101.05(18) . .
O3 Zn3 O5 107.17(16) . .
O16 Zn3 O5 96.46(15) . .
O12 Zn3 Zn4 154.36(13) . .
O3 Zn3 Zn4 89.66(12) . .
O16 Zn3 Zn4 39.94(9) . .
O5 Zn3 Zn4 74.09(10) . .
O6 Zn4 O16 100.07(14) . .
O6 Zn4 N2 169.29(18) . .
O16 Zn4 N2 84.70(15) . .
O6 Zn4 O4 93.45(16) . .
O16 Zn4 O4 95.29(14) . .
N2 Zn4 O4 95.67(16) . .
O6 Zn4 O18 89.87(16) . .
O16 Zn4 O18 94.67(15) . .
N2 Zn4 O18 80.13(17) . .
O4 Zn4 O18 168.78(15) . .
O6 Zn4 O17 98.15(15) . .
O16 Zn4 O17 161.73(14) . .
N2 Zn4 O17 77.59(16) . .
O4 Zn4 O17 82.16(14) . .
O18 Zn4 O17 86.77(15) . .
O6 Zn4 Zn3 79.51(10) . .
O16 Zn4 Zn3 37.89(9) . .
N2 Zn4 Zn3 109.47(14) . .
O4 Zn4 Zn3 65.21(10) . .
O18 Zn4 Zn3 125.98(11) . .
O17 Zn4 Zn3 146.94(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.231(6) .
C1 O2 1.258(6) .
C1 C2 1.481(6) .
C2 C3 1.362(6) .
C2 C7 1.381(7) .
C3 C4 1.361(7) .
C3 H3 0.9300 .
C4 C5 1.389(7) .
C4 H4 0.9300 .
C5 C6 1.384(6) .
C5 C8 1.483(6) .
C6 C7 1.366(6) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 O4 1.244(6) .
C8 O3 1.262(6) .
C9 O5 1.236(6) .
C9 O6 1.271(6) .
C9 C10 1.488(6) .
C10 C11 1.373(7) .
C10 C15 1.376(7) .
C11 C12 1.368(7) .
C11 H11 0.9300 .
C12 C13 1.371(7) .
C12 H12 0.9300 .
C13 C14 1.387(7) .
C13 C16 1.478(6) .
C14 C15 1.373(7) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 O8 1.242(5) .
C16 O7 1.259(6) .
C17 O9 1.253(6) .
C17 O10 1.268(6) .
C17 C18 1.475(7) .
C17 Zn2 2.466(5) .
C18 C19 1.367(7) .
C18 C20 1.378(7) 2_776
C19 C20 1.366(7) .
C19 H19 0.9300 .
C20 C18 1.378(7) 2_776
C20 H20 0.9300 .
C21 O11 1.211(8) .
C21 O12 1.238(8) .
C21 C22 1.488(8) .
C22 C24 1.374(9) 2_855
C22 C23 1.388(9) .
C23 C24 1.347(9) .
C23 H23 0.9300 .
C24 C22 1.374(9) 2_855
C24 H24 0.9300 .
C25 O13 1.436(5) .
C25 C26 1.513(7) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 N1 1.466(6) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 O14 1.435(6) .
C27 C28 1.500(7) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 N1 1.482(6) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 O15 1.412(6) .
C29 C30 1.497(8) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 N1 1.487(6) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 O16 1.427(6) .
C31 C32 1.515(8) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 N2 1.492(7) .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 O17 1.431(6) .
C33 C34 1.499(8) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 N2 1.475(6) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 N2 1.476(8) .
C35 C36 1.482(9) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 O18 1.443(6) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 O19 1.475(19) .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 O20 1.459(13) .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
N1 Zn1 2.114(4) .
N2 Zn4 2.124(4) .
O1 Zn1 2.125(3) .
O2 Zn2 1.955(3) .
O3 Zn3 1.923(3) .
O4 Zn4 2.156(3) .
O5 Zn3 1.986(3) .
O6 Zn4 1.941(3) .
O7 Zn1 1.980(3) 2_655
O8 Zn2 2.032(3) 2_655
O9 Zn2 2.266(4) .
O10 Zn2 2.040(3) .
O12 Zn3 1.906(4) .
O13 Zn2 1.966(3) .
O13 Zn1 2.062(3) .
O14 Zn1 2.103(3) .
O14 H01 0.904(10) .
O15 Zn1 2.205(4) .
O15 H02 0.912(9) .
O16 Zn3 1.961(3) .
O16 Zn4 2.051(3) .
O17 Zn4 2.168(4) .
O17 H03 0.898(10) .
O18 Zn4 2.166(4) .
O18 H04 0.890(10) .
O19 H05 0.8200 .
O20 H06 0.8200 .
Zn1 O7 1.980(3) 2_655
Zn1 Zn2 3.1338(11) .
Zn2 O8 2.032(3) 2_655
Zn3 Zn4 3.1222(11) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O14 H01 O13 0.904(10) 1.72(2) 2.599(4) 162(5) 2_666
O17 H03 O19 0.898(10) 2.32(5) 2.584(18) 97(4) .
O18 H04 O16 0.890(10) 1.885(16) 2.685(5) 149(3) 2_745
O15 H02 O20 0.912(9) 1.80(2) 2.648(8) 154(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 -162.9(5) . .
O2 C1 C2 C3 15.4(7) . .
O1 C1 C2 C7 16.0(7) . .
O2 C1 C2 C7 -165.7(5) . .
C7 C2 C3 C4 0.2(8) . .
C1 C2 C3 C4 179.1(5) . .
C2 C3 C4 C5 1.3(8) . .
C3 C4 C5 C6 -2.0(8) . .
C3 C4 C5 C8 -179.5(5) . .
C4 C5 C6 C7 1.2(8) . .
C8 C5 C6 C7 178.7(5) . .
C5 C6 C7 C2 0.2(8) . .
C3 C2 C7 C6 -0.9(8) . .
C1 C2 C7 C6 -179.9(5) . .
C6 C5 C8 O4 -3.1(8) . .
C4 C5 C8 O4 174.4(5) . .
C6 C5 C8 O3 176.6(5) . .
C4 C5 C8 O3 -5.9(7) . .
O5 C9 C10 C11 -10.0(7) . .
O6 C9 C10 C11 171.5(5) . .
O5 C9 C10 C15 167.5(5) . .
O6 C9 C10 C15 -11.0(7) . .
C15 C10 C11 C12 -0.8(8) . .
C9 C10 C11 C12 176.8(5) . .
C10 C11 C12 C13 1.1(8) . .
C11 C12 C13 C14 -0.5(8) . .
C11 C12 C13 C16 -179.9(5) . .
C12 C13 C14 C15 -0.4(8) . .
C16 C13 C14 C15 178.9(5) . .
C13 C14 C15 C10 0.8(8) . .
C11 C10 C15 C14 -0.2(8) . .
C9 C10 C15 C14 -177.7(5) . .
C12 C13 C16 O8 -174.0(5) . .
C14 C13 C16 O8 6.7(7) . .
C12 C13 C16 O7 6.5(7) . .
C14 C13 C16 O7 -172.8(5) . .
O9 C17 C18 C19 -12.7(7) . .
O10 C17 C18 C19 166.1(5) . .
Zn2 C17 C18 C19 124(3) . .
O9 C17 C18 C20 168.9(5) . 2_776
O10 C17 C18 C20 -12.3(7) . 2_776
Zn2 C17 C18 C20 -54(3) . 2_776
C20 C18 C19 C20 -1.1(9) 2_776 .
C17 C18 C19 C20 -179.6(5) . .
C18 C19 C20 C18 1.1(9) . 2_776
O11 C21 C22 C24 -8.3(12) . 2_855
O12 C21 C22 C24 174.5(7) . 2_855
O11 C21 C22 C23 172.8(8) . .
O12 C21 C22 C23 -4.5(11) . .
C24 C22 C23 C24 2.5(14) 2_855 .
C21 C22 C23 C24 -178.5(8) . .
C22 C23 C24 C22 -2.6(15) . 2_855
O13 C25 C26 N1 -50.1(5) . .
O14 C27 C28 N1 -43.8(6) . .
O15 C29 C30 N1 44.7(6) . .
O16 C31 C32 N2 51.7(7) . .
O17 C33 C34 N2 -41.0(7) . .
N2 C35 C36 O18 44.6(7) . .
C25 C26 N1 C28 -75.2(5) . .
C25 C26 N1 C30 158.5(4) . .
C25 C26 N1 Zn1 43.7(4) . .
C27 C28 N1 C26 139.4(4) . .
C27 C28 N1 C30 -95.5(5) . .
C27 C28 N1 Zn1 24.4(5) . .
C29 C30 N1 C26 -164.7(4) . .
C29 C30 N1 C28 69.8(6) . .
C29 C30 N1 Zn1 -51.9(5) . .
C33 C34 N2 C35 -71.2(6) . .
C33 C34 N2 C32 160.7(5) . .
C33 C34 N2 Zn4 50.5(6) . .
C36 C35 N2 C34 94.2(6) . .
C36 C35 N2 C32 -137.3(5) . .
C36 C35 N2 Zn4 -25.0(6) . .
C31 C32 N2 C34 -159.7(5) . .
C31 C32 N2 C35 71.6(6) . .
C31 C32 N2 Zn4 -46.5(5) . .
O2 C1 O1 Zn1 31.0(10) . .
C2 C1 O1 Zn1 -150.9(5) . .
O1 C1 O2 Zn2 -16.4(7) . .
C2 C1 O2 Zn2 165.4(3) . .
O4 C8 O3 Zn3 11.9(7) . .
C5 C8 O3 Zn3 -167.7(3) . .
O3 C8 O4 Zn4 2.4(9) . .
C5 C8 O4 Zn4 -177.9(4) . .
O6 C9 O5 Zn3 3.9(8) . .
C10 C9 O5 Zn3 -174.4(3) . .
O5 C9 O6 Zn4 -4.2(8) . .
C10 C9 O6 Zn4 174.1(3) . .
O8 C16 O7 Zn1 6.9(7) . 2_655
C13 C16 O7 Zn1 -173.6(3) . 2_655
O7 C16 O8 Zn2 -13.5(8) . 2_655
C13 C16 O8 Zn2 167.0(3) . 2_655
O10 C17 O9 Zn2 -4.3(4) . .
C18 C17 O9 Zn2 174.5(4) . .
O9 C17 O10 Zn2 4.7(5) . .
C18 C17 O10 Zn2 -174.0(4) . .
O11 C21 O12 Zn3 -1.0(9) . .
C22 C21 O12 Zn3 176.2(5) . .
C26 C25 O13 Zn2 -90.9(4) . .
C26 C25 O13 Zn1 28.2(4) . .
C28 C27 O14 Zn1 41.8(5) . .
C30 C29 O15 Zn1 -16.4(5) . .
C32 C31 O16 Zn3 93.7(5) . .
C32 C31 O16 Zn4 -26.8(6) . .
C34 C33 O17 Zn4 11.4(6) . .
C35 C36 O18 Zn4 -41.0(6) . .
C25 O13 Zn1 O7 170.1(3) . 2_655
Zn2 O13 Zn1 O7 -59.80(16) . 2_655
C25 O13 Zn1 O14 76.1(3) . .
Zn2 O13 Zn1 O14 -153.82(14) . .
C25 O13 Zn1 N1 -3.4(3) . .
Zn2 O13 Zn1 N1 126.63(15) . .
C25 O13 Zn1 O1 -97.9(3) . .
Zn2 O13 Zn1 O1 32.18(15) . .
C25 O13 Zn1 O15 -27.9(5) . .
Zn2 O13 Zn1 O15 102.1(4) . .
C25 O13 Zn1 Zn2 -130.0(3) . .
C27 O14 Zn1 O7 151.9(4) . 2_655
C27 O14 Zn1 O13 -105.2(4) . .
C27 O14 Zn1 N1 -22.8(4) . .
C27 O14 Zn1 O1 44.5(9) . .
C27 O14 Zn1 O15 54.1(4) . .
C27 O14 Zn1 Zn2 -126.1(3) . .
C26 N1 Zn1 O7 -157.2(9) . 2_655
C28 N1 Zn1 O7 -37.5(11) . 2_655
C30 N1 Zn1 O7 85.6(10) . 2_655
C26 N1 Zn1 O13 -22.0(3) . .
C28 N1 Zn1 O13 97.6(3) . .
C30 N1 Zn1 O13 -139.2(3) . .
C26 N1 Zn1 O14 -120.9(3) . .
C28 N1 Zn1 O14 -1.3(3) . .
C30 N1 Zn1 O14 121.9(3) . .
C26 N1 Zn1 O1 70.2(3) . .
C28 N1 Zn1 O1 -170.2(3) . .
C30 N1 Zn1 O1 -47.0(3) . .
C26 N1 Zn1 O15 149.1(3) . .
C28 N1 Zn1 O15 -91.3(3) . .
C30 N1 Zn1 O15 31.9(3) . .
C26 N1 Zn1 Zn2 8.8(3) . .
C28 N1 Zn1 Zn2 128.4(3) . .
C30 N1 Zn1 Zn2 -108.4(3) . .
C1 O1 Zn1 O7 61.5(7) . 2_655
C1 O1 Zn1 O13 -41.1(7) . .
C1 O1 Zn1 O14 168.9(7) . .
C1 O1 Zn1 N1 -125.1(7) . .
C1 O1 Zn1 O15 159.2(7) . .
C1 O1 Zn1 Zn2 -19.2(6) . .
C29 O15 Zn1 O7 178.3(3) . 2_655
C29 O15 Zn1 O13 16.1(6) . .
C29 O15 Zn1 O14 -89.7(3) . .
C29 O15 Zn1 N1 -8.9(3) . .
C29 O15 Zn1 O1 88.3(3) . .
C29 O15 Zn1 Zn2 90.6(4) . .
C1 O2 Zn2 O13 31.4(4) . .
C1 O2 Zn2 O8 -66.3(4) . 2_655
C1 O2 Zn2 O10 -163.2(3) . .
C1 O2 Zn2 O9 134.2(4) . .
C1 O2 Zn2 C17 163.1(4) . .
C1 O2 Zn2 Zn1 5.1(4) . .
C25 O13 Zn2 O2 79.8(3) . .
Zn1 O13 Zn2 O2 -43.4(2) . .
C25 O13 Zn2 O8 179.3(3) . 2_655
Zn1 O13 Zn2 O8 56.14(14) . 2_655
C25 O13 Zn2 O10 -85.5(3) . .
Zn1 O13 Zn2 O10 151.36(14) . .
C25 O13 Zn2 O9 -25.6(3) . .
Zn1 O13 Zn2 O9 -148.78(13) . .
C25 O13 Zn2 C17 -53.9(3) . .
Zn1 O13 Zn2 C17 -177.06(15) . .
C25 O13 Zn2 Zn1 123.1(3) . .
C17 O10 Zn2 O2 -89.3(3) . .
C17 O10 Zn2 O13 77.2(3) . .
C17 O10 Zn2 O8 172.0(3) . 2_655
C17 O10 Zn2 O9 -2.5(3) . .
C17 O10 Zn2 Zn1 113.6(3) . .
C17 O9 Zn2 O2 117.6(3) . .
C17 O9 Zn2 O13 -116.3(3) . .
C17 O9 Zn2 O8 -10.0(5) . 2_655
C17 O9 Zn2 O10 2.6(3) . .
C17 O9 Zn2 Zn1 -141.2(2) . .
O9 C17 Zn2 O2 -70.6(3) . .
O10 C17 Zn2 O2 105.0(3) . .
C18 C17 Zn2 O2 150(3) . .
O9 C17 Zn2 O13 69.2(3) . .
O10 C17 Zn2 O13 -115.2(3) . .
C18 C17 Zn2 O13 -70(3) . .
O9 C17 Zn2 O8 174.8(3) . 2_655
O10 C17 Zn2 O8 -9.6(3) . 2_655
C18 C17 Zn2 O8 35(3) . 2_655
O9 C17 Zn2 O10 -175.6(5) . .
C18 C17 Zn2 O10 45(3) . .
O10 C17 Zn2 O9 175.6(5) . .
C18 C17 Zn2 O9 -139(3) . .
O9 C17 Zn2 Zn1 65.8(4) . .
O10 C17 Zn2 Zn1 -118.6(3) . .
C18 C17 Zn2 Zn1 -74(3) . .
O7 Zn1 Zn2 O2 -92.94(17) 2_655 .
O13 Zn1 Zn2 O2 145.41(18) . .
O14 Zn1 Zn2 O2 -179.43(18) . .
N1 Zn1 Zn2 O2 89.24(16) . .
O1 Zn1 Zn2 O2 2.77(16) . .
O15 Zn1 Zn2 O2 0.2(2) . .
O7 Zn1 Zn2 O13 121.65(18) 2_655 .
O14 Zn1 Zn2 O13 35.15(19) . .
N1 Zn1 Zn2 O13 -56.18(17) . .
O1 Zn1 Zn2 O13 -142.64(18) . .
O15 Zn1 Zn2 O13 -145.2(2) . .
O7 Zn1 Zn2 O8 2.81(16) 2_655 2_655
O13 Zn1 Zn2 O8 -118.83(17) . 2_655
O14 Zn1 Zn2 O8 -83.68(18) . 2_655
N1 Zn1 Zn2 O8 -175.01(15) . 2_655
O1 Zn1 Zn2 O8 98.52(16) . 2_655
O15 Zn1 Zn2 O8 95.9(2) . 2_655
O7 Zn1 Zn2 O10 66.7(2) 2_655 .
O13 Zn1 Zn2 O10 -54.9(2) . .
O14 Zn1 Zn2 O10 -19.7(2) . .
N1 Zn1 Zn2 O10 -111.1(2) . .
O1 Zn1 Zn2 O10 162.5(2) . .
O15 Zn1 Zn2 O10 159.9(3) . .
O7 Zn1 Zn2 O9 162.44(17) 2_655 .
O13 Zn1 Zn2 O9 40.80(18) . .
O14 Zn1 Zn2 O9 75.95(19) . .
N1 Zn1 Zn2 O9 -15.38(16) . .
O1 Zn1 Zn2 O9 -101.85(18) . .
O15 Zn1 Zn2 O9 -104.4(2) . .
O7 Zn1 Zn2 C17 126.8(3) 2_655 .
O13 Zn1 Zn2 C17 5.2(3) . .
O14 Zn1 Zn2 C17 40.3(3) . .
N1 Zn1 Zn2 C17 -51.0(3) . .
O1 Zn1 Zn2 C17 -137.5(3) . .
O15 Zn1 Zn2 C17 -140.1(3) . .
C21 O12 Zn3 O3 67.6(5) . .
C21 O12 Zn3 O16 -73.5(5) . .
C21 O12 Zn3 O5 -177.1(4) . .
C21 O12 Zn3 Zn4 -100.9(5) . .
C8 O3 Zn3 O12 171.8(4) . .
C8 O3 Zn3 O16 -45.6(4) . .
C8 O3 Zn3 O5 60.0(4) . .
C8 O3 Zn3 Zn4 -13.2(4) . .
C31 O16 Zn3 O12 73.9(4) . .
Zn4 O16 Zn3 O12 -161.90(18) . .
C31 O16 Zn3 O3 -67.6(3) . .
Zn4 O16 Zn3 O3 56.56(19) . .
C31 O16 Zn3 O5 -179.8(3) . .
Zn4 O16 Zn3 O5 -55.62(16) . .
C31 O16 Zn3 Zn4 -124.2(4) . .
C9 O5 Zn3 O12 152.5(5) . .
C9 O5 Zn3 O3 -86.2(5) . .
C9 O5 Zn3 O16 31.8(5) . .
C9 O5 Zn3 Zn4 -1.6(4) . .
C9 O6 Zn4 O16 -29.7(4) . .
C9 O6 Zn4 N2 -145.4(8) . .
C9 O6 Zn4 O4 66.2(4) . .
C9 O6 Zn4 O18 -124.5(4) . .
C9 O6 Zn4 O17 148.8(4) . .
C9 O6 Zn4 Zn3 2.2(4) . .
C31 O16 Zn4 O6 -169.7(4) . .
Zn3 O16 Zn4 O6 58.05(17) . .
C31 O16 Zn4 N2 0.6(4) . .
Zn3 O16 Zn4 N2 -131.64(18) . .
C31 O16 Zn4 O4 95.8(4) . .
Zn3 O16 Zn4 O4 -36.41(16) . .
C31 O16 Zn4 O18 -79.0(4) . .
Zn3 O16 Zn4 O18 148.75(16) . .
C31 O16 Zn4 O17 14.8(6) . .
Zn3 O16 Zn4 O17 -117.4(4) . .
C31 O16 Zn4 Zn3 132.2(4) . .
C34 N2 Zn4 O6 -100.2(9) . .
C35 N2 Zn4 O6 23.0(11) . .
C32 N2 Zn4 O6 141.9(8) . .
C34 N2 Zn4 O16 142.8(4) . .
C35 N2 Zn4 O16 -94.0(4) . .
C32 N2 Zn4 O16 24.9(3) . .
C34 N2 Zn4 O4 48.0(4) . .
C35 N2 Zn4 O4 171.2(4) . .
C32 N2 Zn4 O4 -69.9(3) . .
C34 N2 Zn4 O18 -121.5(4) . .
C35 N2 Zn4 O18 1.7(4) . .
C32 N2 Zn4 O18 120.6(3) . .
C34 N2 Zn4 O17 -32.6(4) . .
C35 N2 Zn4 O17 90.6(4) . .
C32 N2 Zn4 O17 -150.6(3) . .
C34 N2 Zn4 Zn3 113.7(4) . .
C35 N2 Zn4 Zn3 -123.1(4) . .
C32 N2 Zn4 Zn3 -4.2(3) . .
C8 O4 Zn4 O6 -86.3(6) . .
C8 O4 Zn4 O16 14.1(6) . .
C8 O4 Zn4 N2 99.3(6) . .
C8 O4 Zn4 O18 166.7(7) . .
C8 O4 Zn4 O17 175.9(6) . .
C8 O4 Zn4 Zn3 -9.5(5) . .
C36 O18 Zn4 O6 -154.5(4) . .
C36 O18 Zn4 O16 105.4(4) . .
C36 O18 Zn4 N2 21.7(4) . .
C36 O18 Zn4 O4 -47.1(10) . .
C36 O18 Zn4 O17 -56.3(4) . .
C36 O18 Zn4 Zn3 128.6(4) . .
C33 O17 Zn4 O6 -177.9(4) . .
C33 O17 Zn4 O16 -2.4(7) . .
C33 O17 Zn4 N2 12.1(4) . .
C33 O17 Zn4 O4 -85.5(4) . .
C33 O17 Zn4 O18 92.7(4) . .
C33 O17 Zn4 Zn3 -94.6(4) . .
O12 Zn3 Zn4 O6 -82.7(4) . .
O3 Zn3 Zn4 O6 107.64(17) . .
O16 Zn3 Zn4 O6 -121.83(19) . .
O5 Zn3 Zn4 O6 -0.33(16) . .
O12 Zn3 Zn4 O16 39.2(4) . .
O3 Zn3 Zn4 O16 -130.5(2) . .
O5 Zn3 Zn4 O16 121.50(19) . .
O12 Zn3 Zn4 N2 91.3(4) . .
O3 Zn3 Zn4 N2 -78.40(18) . .
O16 Zn3 Zn4 N2 52.12(19) . .
O5 Zn3 Zn4 N2 173.62(17) . .
O12 Zn3 Zn4 O4 178.5(4) . .
O3 Zn3 Zn4 O4 8.85(17) . .
O16 Zn3 Zn4 O4 139.38(19) . .
O5 Zn3 Zn4 O4 -99.13(16) . .
O12 Zn3 Zn4 O18 -0.6(4) . .
O3 Zn3 Zn4 O18 -170.24(19) . .
O16 Zn3 Zn4 O18 -39.7(2) . .
O5 Zn3 Zn4 O18 81.78(18) . .
O12 Zn3 Zn4 O17 -171.5(4) . .
O3 Zn3 Zn4 O17 18.8(2) . .
O16 Zn3 Zn4 O17 149.3(2) . .
O5 Zn3 Zn4 O17 -89.2(2) . .
