#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:23:19 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180432 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/01/7210184.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210184
loop_
_publ_author_name
'Wang, Xiuli'
'Zhao, Dan'
'Tian, Aixiang'
'Ying, Jun'
_publ_section_title
;
 A series of 3D PW12O403−-based AgI--bis(triazole) complexes
 containing different multinuclear loops: syntheses, structures and
 properties
;
_journal_issue                   22
_journal_name_full               CrystEngComm
_journal_page_first              4516
_journal_paper_doi               10.1039/c3ce40375k
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C40 H64 Ag5 N24 O40 P W12'
_chemical_formula_weight         4297.67
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.470(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.3672(11)
_cell_length_b                   24.450(2)
_cell_length_c                   12.1885(11)
_cell_measurement_temperature    298(2)
_cell_volume                     3940.1(6)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_av_sigmaI/netI    0.0441
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            20574
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    18.765
_exptl_absorpt_correction_T_max  0.013
_exptl_absorpt_correction_T_min  0.011
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Sheldrick, 1996'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.622
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3860
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.23
_refine_diff_density_max         2.983
_refine_diff_density_min         -2.488
_refine_diff_density_rms         0.383
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     385
_refine_ls_number_reflns         6927
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0769
_refine_ls_R_factor_gt           0.0641
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0431P)²+323.1530P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1416
_refine_ls_wR_factor_ref         0.1465
_reflns_number_gt                5894
_reflns_number_total             6931
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40375k.txt
_cod_data_source_block           4
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7210184
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.53141(13) 0.04765(8) 0.27816(17) 0.0413(5) Uani 1 1 d .
Ag2 Ag 0.98817(15) 0.25647(6) 0.14333(12) 0.0308(4) Uani 1 1 d .
Ag3 Ag 0.5000 -0.5000 0.5000 0.0335(6) Uani 1 2 d S
P1 P 1.0000 0.0000 0.0000 0.0088(12) Uani 1 2 d S
C1 C 0.6374(19) -0.0382(10) 0.4455(18) 0.0369(13) Uani 1 1 d .
H1 H 0.6991 -0.0200 0.4510 0.044 Uiso 1 1 calc R
C2 C 0.6934(19) -0.1113(9) 0.586(3) 0.045(7) Uani 1 1 d .
H2A H 0.7370 -0.0853 0.6305 0.054 Uiso 1 1 calc R
H2B H 0.6568 -0.1315 0.6363 0.054 Uiso 1 1 calc R
C3 C 0.9173(17) 0.3808(8) -0.0018(15) 0.024(5) Uani 1 1 d .
H3A H 0.9529 0.4132 -0.0212 0.029 Uiso 1 1 calc R
H3B H 0.9399 0.3728 0.0758 0.029 Uiso 1 1 calc R
C4 C 0.8034(19) 0.3922(9) -0.019(2) 0.036(6) Uani 1 1 d .
H4A H 0.7913 0.4221 0.0298 0.044 Uiso 1 1 calc R
H4B H 0.7843 0.4051 -0.0945 0.044 Uiso 1 1 calc R
C5 C 0.489(2) -0.0604(13) 0.405(3) 0.069(10) Uani 1 1 d .
H5 H 0.4211 -0.0578 0.3761 0.083 Uiso 1 1 calc R
C6 C 0.4557(19) -0.3806(10) 0.5692(18) 0.0369(13) Uani 1 1 d .
H6A H 0.3868 -0.3857 0.5469 0.044 Uiso 1 1 calc R
C7 C 0.613(2) -0.3953(10) 0.597(2) 0.0429(11) Uani 1 1 d .
H7A H 0.6759 -0.4114 0.5994 0.051 Uiso 1 1 calc R
C8 C 0.4506(18) 0.1632(10) 0.187(2) 0.043(6) Uani 1 1 d .
H8A H 0.3826 0.1535 0.1782 0.051 Uiso 1 1 calc R
C9 C 0.610(2) 0.1584(10) 0.215(2) 0.0429(11) Uani 1 1 d .
H9A H 0.6768 0.1462 0.2309 0.051 Uiso 1 1 calc R
C10 C 0.668(2) -0.3058(11) 0.686(3) 0.055(8) Uani 1 1 d .
H10A H 0.7205 -0.3254 0.7332 0.066 Uiso 1 1 calc R
H10B H 0.6338 -0.2826 0.7337 0.066 Uiso 1 1 calc R
C11 C 0.7158(18) -0.2704(10) 0.611(2) 0.0429(11) Uani 1 1 d D
H11A H 0.7473 -0.2930 0.5607 0.051 Uiso 1 1 calc R
H11B H 0.7686 -0.2490 0.6548 0.051 Uiso 1 1 calc R
C12 C 0.656(3) 0.2772(16) 0.104(3) 0.094(14) Uani 1 1 d D
H12A H 0.5899 0.2893 0.0699 0.113 Uiso 1 1 calc R
H12B H 0.6796 0.2483 0.0592 0.113 Uiso 1 1 calc R
C13 C 0.756(3) -0.1494(14) 0.534(4) 0.091(13) Uani 1 1 d .
H13A H 0.7842 -0.1294 0.4769 0.109 Uiso 1 1 calc R
H13B H 0.8121 -0.1601 0.5893 0.109 Uiso 1 1 calc R
C14 C 0.6431(16) -0.2329(9) 0.546(2) 0.0429(11) Uani 1 1 d D
H14A H 0.6077 -0.2107 0.5944 0.051 Uiso 1 1 calc R
H14B H 0.5940 -0.2529 0.4949 0.051 Uiso 1 1 calc R
C15 C 0.656(3) 0.2588(16) 0.222(3) 0.098(14) Uani 1 1 d D
H15A H 0.6269 0.2858 0.2661 0.118 Uiso 1 1 calc R
H15B H 0.7221 0.2477 0.2582 0.118 Uiso 1 1 calc R
C16 C 0.734(2) 0.3467(13) 0.000(3) 0.065(9) Uani 1 1 d .
H16A H 0.7499 0.3158 -0.0446 0.078 Uiso 1 1 calc R
H16B H 0.6657 0.3581 -0.0293 0.078 Uiso 1 1 calc R
C17 C 0.733(3) 0.3260(12) 0.119(3) 0.071(10) Uani 1 1 d D
H17A H 0.7108 0.3544 0.1652 0.086 Uiso 1 1 calc R
H17B H 0.8000 0.3137 0.1519 0.086 Uiso 1 1 calc R
C18 C 0.7114(19) -0.1977(10) 0.485(2) 0.0429(11) Uani 1 1 d D
H18A H 0.7660 -0.2210 0.4680 0.051 Uiso 1 1 calc R
H18B H 0.6723 -0.1875 0.4144 0.051 Uiso 1 1 calc R
C19 C 0.9988(18) 0.2567(11) -0.1058(18) 0.0369(13) Uani 1 1 d .
H19A H 1.0270 0.2218 -0.0987 0.044 Uiso 1 1 calc R
C20 C 0.9411(19) 0.3305(10) -0.178(2) 0.0429(11) Uani 1 1 d .
H20A H 0.9210 0.3581 -0.2287 0.051 Uiso 1 1 calc R
N1 N 0.5562(18) -0.0251(10) 0.377(2) 0.062(8) Uani 1 1 d .
N2 N 0.6192(15) -0.0807(9) 0.5053(15) 0.0369(13) Uani 1 1 d .
N3 N 0.522(2) -0.0991(10) 0.476(2) 0.063(7) Uani 1 1 d .
N4 N 0.9802(16) 0.2869(8) -0.0191(18) 0.0429(11) Uani 1 1 d .
N5 N 0.9421(15) 0.3344(8) -0.0701(15) 0.0369(13) Uani 1 1 d .
N6 N 0.5248(13) -0.4186(8) 0.5540(15) 0.030(4) Uani 1 1 d .
N7 N 0.5951(14) -0.3454(8) 0.6343(15) 0.033(4) Uani 1 1 d .
N8 N 0.4933(15) -0.3356(9) 0.6181(15) 0.0369(13) Uani 1 1 d .
N9 N 0.5293(12) 0.1283(8) 0.2142(14) 0.027(4) Uani 1 1 d .
N10 N 0.582(2) 0.2082(10) 0.189(3) 0.091(12) Uani 1 1 d .
N11 N 0.486(2) 0.2125(10) 0.177(3) 0.080(9) Uani 1 1 d .
N12 N 0.9731(16) 0.2815(8) -0.2022(18) 0.0429(11) Uani 1 1 d .
O1 O 0.902(3) 0.0281(13) 0.008(3) 0.0429(11) Uani 0.50 1 d P
O2 O 0.8200(12) 0.0942(7) 0.1009(12) 0.0369(13) Uani 1 1 d .
O3 O 0.8337(13) -0.0513(7) 0.1901(15) 0.0429(11) Uani 1 1 d .
O4 O 1.0881(13) 0.0888(7) 0.2307(15) 0.0429(11) Uani 1 1 d .
O5 O 0.8722(13) -0.1260(7) 0.0526(15) 0.0429(11) Uani 1 1 d .
O6 O 0.7757(12) 0.0787(7) -0.1126(12) 0.0369(13) Uani 1 1 d .
O7 O 0.9858(12) 0.1451(7) 0.0690(12) 0.0369(13) Uani 1 1 d .
O8 O 1.0938(11) 0.0296(6) 0.4268(11) 0.027(3) Uani 1 1 d .
O9 O 0.9247(13) 0.0395(7) 0.2658(15) 0.0429(11) Uani 1 1 d .
O10 O 0.7329(13) 0.0037(7) 0.0258(15) 0.0429(11) Uani 1 1 d .
O11 O 1.081(2) 0.0269(14) 0.094(2) 0.0369(13) Uani 0.50 1 d P
O12 O 1.1778(13) 0.1802(7) 0.1496(15) 0.0429(11) Uani 1 1 d .
O13 O 0.8018(12) 0.1834(7) -0.0353(12) 0.0369(13) Uani 1 1 d .
O14 O 1.1846(13) -0.0028(7) 0.2474(15) 0.0429(11) Uani 1 1 d .
O15 O 1.0240(13) -0.0534(7) 0.2814(15) 0.0429(11) Uani 1 1 d .
O16 O 1.2297(13) 0.0729(7) 0.1098(15) 0.0429(11) Uani 1 1 d .
O17 O 0.964(3) -0.0141(13) 0.108(3) 0.0429(11) Uani 0.50 1 d P
O18 O 0.9151(13) -0.1506(7) 0.2733(15) 0.0429(11) Uani 1 1 d .
O19 O 1.3765(12) -0.0049(7) 0.1840(12) 0.0369(13) Uani 1 1 d .
O20 O 1.0601(11) -0.1295(8) 0.1448(12) 0.040(4) Uani 1 1 d .
O21 O 0.7159(11) 0.0362(6) 0.2394(15) 0.039(4) Uani 1 1 d .
O22 O 0.994(3) -0.0581(14) 0.023(3) 0.0429(11) Uani 0.50 1 d P
W1 W 1.06261(8) 0.02012(4) 0.29070(7) 0.0295(2) Uani 1 1 d .
W2 W 0.80707(6) 0.02431(4) 0.16319(7) 0.0249(2) Uani 1 1 d .
W3 W 0.93989(6) -0.10106(3) 0.18711(6) 0.01803(19) Uani 1 1 d .
W4 W 0.86497(6) 0.12557(3) -0.02626(7) 0.0236(2) Uani 1 1 d .
W5 W 1.25503(6) -0.00255(4) 0.12666(8) 0.0300(2) Uani 1 1 d .
W6 W 1.12124(7) 0.12233(3) 0.10301(7) 0.0237(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N9 Ag1 N1 166.0(8) . .
N9 Ag1 O19 109.7(6) . 1_455
N1 Ag1 O19 83.3(7) . 1_455
N9 Ag1 O21 89.7(6) . .
N1 Ag1 O21 86.6(8) . .
O19 Ag1 O21 126.3(5) 1_455 .
N4 Ag2 N12 170.3(8) . 4_566
N6 Ag3 N6 180.000(1) 3_646 .
O22 P1 O22 180(3) . 3_755
O22 P1 O1 68.7(18) . 3_755
O22 P1 O1 111.3(18) 3_755 3_755
O22 P1 O1 111.3(18) . .
O22 P1 O1 68.7(18) 3_755 .
O1 P1 O1 180(3) 3_755 .
O22 P1 O17 115.3(18) . 3_755
O22 P1 O17 64.7(18) 3_755 3_755
O1 P1 O17 69.7(18) 3_755 3_755
O1 P1 O17 110.3(18) . 3_755
O22 P1 O17 64.7(18) . .
O22 P1 O17 115.3(18) 3_755 .
O1 P1 O17 110.3(18) 3_755 .
O1 P1 O17 69.7(18) . .
O17 P1 O17 180(3) 3_755 .
O22 P1 O11 108.2(18) . .
O22 P1 O11 71.8(18) 3_755 .
O1 P1 O11 74.4(18) 3_755 .
O1 P1 O11 105.6(18) . .
O17 P1 O11 105.5(17) 3_755 .
O17 P1 O11 74.5(17) . .
O22 P1 O11 71.8(18) . 3_755
O22 P1 O11 108.2(18) 3_755 3_755
O1 P1 O11 105.6(18) 3_755 3_755
O1 P1 O11 74.4(18) . 3_755
O17 P1 O11 74.5(17) 3_755 3_755
O17 P1 O11 105.5(17) . 3_755
O11 P1 O11 180(3) . 3_755
N1 C1 N2 110(2) . .
N1 C1 H1 124.9 . .
N2 C1 H1 124.9 . .
C13 C2 N2 113(3) . .
C13 C2 H2A 108.9 . .
N2 C2 H2A 108.9 . .
C13 C2 H2B 108.9 . .
N2 C2 H2B 108.9 . .
H2A C2 H2B 107.7 . .
N5 C3 C4 111.4(17) . .
N5 C3 H3A 109.3 . .
C4 C3 H3A 109.3 . .
N5 C3 H3B 109.3 . .
C4 C3 H3B 109.3 . .
H3A C3 H3B 108.0 . .
C16 C4 C3 118(2) . .
C16 C4 H4A 107.8 . .
C3 C4 H4A 107.8 . .
C16 C4 H4B 107.8 . .
C3 C4 H4B 107.8 . .
H4A C4 H4B 107.1 . .
N3 C5 N1 118(3) . .
N3 C5 H5 121.1 . .
N1 C5 H5 121.1 . .
N8 C6 N6 115(2) . .
N8 C6 H6A 122.7 . .
N6 C6 H6A 122.7 . .
N7 C7 N6 110(2) . .
N7 C7 H7A 125.2 . .
N6 C7 H7A 125.2 . .
N11 C8 N9 109(2) . .
N11 C8 H8A 125.4 . .
N9 C8 H8A 125.4 . .
N10 C9 N9 108(2) . .
N10 C9 H9A 125.8 . .
N9 C9 H9A 125.8 . .
N7 C10 C11 117(3) . .
N7 C10 H10A 108.1 . .
C11 C10 H10A 108.1 . .
N7 C10 H10B 108.1 . .
C11 C10 H10B 108.1 . .
H10A C10 H10B 107.3 . .
C10 C11 C14 113(2) . .
C10 C11 H11A 109.1 . .
C14 C11 H11A 109.1 . .
C10 C11 H11B 109.1 . .
C14 C11 H11B 109.1 . .
H11A C11 H11B 107.8 . .
C15 C12 C17 102(3) . .
C15 C12 H12A 111.3 . .
C17 C12 H12A 111.3 . .
C15 C12 H12B 111.3 . .
C17 C12 H12B 111.3 . .
H12A C12 H12B 109.2 . .
C18 C13 C2 119(3) . .
C18 C13 H13A 107.6 . .
C2 C13 H13A 107.6 . .
C18 C13 H13B 107.6 . .
C2 C13 H13B 107.6 . .
H13A C13 H13B 107.0 . .
C11 C14 C18 102.6(19) . .
C11 C14 H14A 111.3 . .
C18 C14 H14A 111.3 . .
C11 C14 H14B 111.3 . .
C18 C14 H14B 111.3 . .
H14A C14 H14B 109.2 . .
C12 C15 N10 95(3) . .
C12 C15 H15A 112.8 . .
N10 C15 H15A 112.8 . .
C12 C15 H15B 112.8 . .
N10 C15 H15B 112.8 . .
H15A C15 H15B 110.2 . .
C4 C16 C17 119(3) . .
C4 C16 H16A 107.6 . .
C17 C16 H16A 107.6 . .
C4 C16 H16B 107.6 . .
C17 C16 H16B 107.6 . .
H16A C16 H16B 107.1 . .
C16 C17 C12 104(3) . .
C16 C17 H17A 111.1 . .
C12 C17 H17A 111.1 . .
C16 C17 H17B 111.1 . .
C12 C17 H17B 111.1 . .
H17A C17 H17B 109.0 . .
C13 C18 C14 120(3) . .
C13 C18 H18A 107.2 . .
C14 C18 H18A 107.2 . .
C13 C18 H18B 107.2 . .
C14 C18 H18B 107.2 . .
H18A C18 H18B 106.9 . .
N12 C19 N4 113(2) . .
N12 C19 H19A 123.4 . .
N4 C19 H19A 123.4 . .
N5 C20 N12 110(2) . .
N5 C20 H20A 125.2 . .
N12 C20 H20A 125.2 . .
C1 N1 C5 102(2) . .
C1 N1 Ag1 127.3(17) . .
C5 N1 Ag1 129(2) . .
C1 N2 N3 111(2) . .
C1 N2 C2 127(2) . .
N3 N2 C2 121.2(19) . .
C5 N3 N2 99(2) . .
C19 N4 N5 102(2) . .
C19 N4 Ag2 123.8(17) . .
N5 N4 Ag2 133.3(16) . .
C20 N5 N4 110(2) . .
C20 N5 C3 131(2) . .
N4 N5 C3 119.6(18) . .
C7 N6 C6 104(2) . .
C7 N6 Ag3 127.7(16) . .
C6 N6 Ag3 128.1(15) . .
C7 N7 N8 109(2) . .
C7 N7 C10 128(2) . .
N8 N7 C10 122(2) . .
C6 N8 N7 103(2) . .
C9 N9 C8 105(2) . .
C9 N9 Ag1 123.7(15) . .
C8 N9 Ag1 129.8(15) . .
N11 N10 C9 111(2) . .
N11 N10 C15 123(3) . .
C9 N10 C15 121(3) . .
N10 N11 C8 106(2) . .
C19 N12 C20 105(2) . .
C19 N12 Ag2 122.6(17) . 4_565
C20 N12 Ag2 132.0(18) . 4_565
P1 O1 O22 54.3(16) . 3_755
P1 O1 O17 55.3(16) . .
O22 O1 O17 95(2) 3_755 .
P1 O1 W2 126.6(19) . .
O22 O1 W2 138(2) 3_755 .
O17 O1 W2 71.3(17) . .
P1 O1 W4 126.0(19) . .
O22 O1 W4 71.8(16) 3_755 .
O17 O1 W4 140(2) . .
W2 O1 W4 93.2(12) . .
W2 O2 W4 138.6(10) . .
W3 O3 W2 138.7(10) . .
W6 O4 W1 142.5(10) . .
W3 O5 W6 140.6(10) . 3_755
W4 O6 W5 139.6(9) . 3_755
W6 O7 W4 139.7(10) . .
W1 O9 W2 138.9(10) . .
W2 O10 W5 140.2(10) . 3_755
P1 O11 O22 50.3(14) . 3_755
P1 O11 W6 123.9(17) . .
O22 O11 W6 73.5(16) 3_755 .
P1 O11 W5 121.8(18) . .
O22 O11 W5 131.9(19) 3_755 .
W6 O11 W5 94.3(11) . .
P1 O11 W1 121.6(16) . .
O22 O11 W1 133(2) 3_755 .
W6 O11 W1 94.4(11) . .
W5 O11 W1 93.0(11) . .
W5 O14 W1 141.8(10) . .
W1 O15 W3 139.9(10) . .
W6 O16 W5 139.5(10) . .
P1 O17 O22 56.0(17) . .
P1 O17 O1 55.0(16) . .
O22 O17 O1 95(3) . .
P1 O17 W3 129.8(19) . .
O22 O17 W3 73.8(17) . .
O1 O17 W3 138(2) . .
P1 O17 W2 122.8(18) . .
O22 O17 W2 138(2) . .
O1 O17 W2 67.8(16) . .
W3 O17 W2 93.3(12) . .
W5 O19 Ag1 147.3(9) . 1_655
W4 O20 W3 139.6(10) 3_755 .
W2 O21 Ag1 156.2(10) . .
P1 O22 O17 59.3(18) . .
P1 O22 O1 57.0(16) . 3_755
O17 O22 O1 99(3) . 3_755
P1 O22 O11 57.9(16) . 3_755
O17 O22 O11 94(2) . 3_755
O1 O22 O11 91(2) 3_755 3_755
P1 O22 W3 127(2) . .
O17 O22 W3 68.0(17) . .
O1 O22 W3 137(2) 3_755 .
O11 O22 W3 129(2) 3_755 .
P1 O22 W4 126.0(19) . 3_755
O17 O22 W4 134(2) . 3_755
O1 O22 W4 69.0(16) 3_755 3_755
O11 O22 W4 129(2) 3_755 3_755
W3 O22 W4 91.0(11) . 3_755
O8 W1 O15 102.8(7) . .
O8 W1 O14 102.8(8) . .
O15 W1 O14 86.5(7) . .
O8 W1 O4 103.2(7) . .
O15 W1 O4 154.0(8) . .
O14 W1 O4 86.7(7) . .
O8 W1 O9 102.7(8) . .
O15 W1 O9 88.7(7) . .
O14 W1 O9 154.4(8) . .
O4 W1 O9 86.7(7) . .
O8 W1 O11 156.7(9) . .
O15 W1 O11 94.1(9) . .
O14 W1 O11 61.9(9) . .
O4 W1 O11 60.7(9) . .
O9 W1 O11 93.5(9) . .
O21 W2 O10 102.2(8) . .
O21 W2 O2 100.6(8) . .
O10 W2 O2 87.3(7) . .
O21 W2 O9 101.6(8) . .
O10 W2 O9 156.2(8) . .
O2 W2 O9 88.4(7) . .
O21 W2 O3 102.0(8) . .
O10 W2 O3 87.3(7) . .
O2 W2 O3 157.4(7) . .
O9 W2 O3 87.7(7) . .
O21 W2 O1 159.6(10) . .
O10 W2 O1 65.4(10) . .
O2 W2 O1 64.1(9) . .
O9 W2 O1 91.7(10) . .
O3 W2 O1 93.8(9) . .
O21 W2 O17 159.4(10) . .
O10 W2 O17 90.7(10) . .
O2 W2 O17 95.9(9) . .
O9 W2 O17 66.5(10) . .
O3 W2 O17 62.2(9) . .
O1 W2 O17 40.9(11) . .
O18 W3 O5 101.6(8) . .
O18 W3 O3 103.7(8) . .
O5 W3 O3 87.6(8) . .
O18 W3 O15 102.7(8) . .
O5 W3 O15 155.6(7) . .
O3 W3 O15 88.4(8) . .
O18 W3 O20 99.2(8) . .
O5 W3 O20 87.8(7) . .
O3 W3 O20 157.0(8) . .
O15 W3 O20 86.5(7) . .
O18 W3 O17 163.1(11) . .
O5 W3 O17 90.8(10) . .
O3 W3 O17 64.9(10) . .
O15 W3 O17 65.8(10) . .
O20 W3 O17 92.7(10) . .
O18 W3 O22 158.7(10) . .
O5 W3 O22 65.6(10) . .
O3 W3 O22 93.1(9) . .
O15 W3 O22 90.6(10) . .
O20 W3 O22 64.6(10) . .
O17 W3 O22 38.2(11) . .
O13 W4 O6 102.2(8) . .
O13 W4 O20 103.4(8) . 3_755
O6 W4 O20 88.1(6) . 3_755
O13 W4 O2 100.4(7) . .
O6 W4 O2 87.7(7) . .
O20 W4 O2 156.2(8) 3_755 .
O13 W4 O7 101.9(8) . .
O6 W4 O7 155.8(7) . .
O20 W4 O7 87.5(6) 3_755 .
O2 W4 O7 86.9(6) . .
O13 W4 O1 159.1(10) . .
O6 W4 O1 66.1(10) . .
O20 W4 O1 93.7(10) 3_755 .
O2 W4 O1 63.3(10) . .
O7 W4 O1 90.5(10) . .
O13 W4 O22 161.5(9) . 3_755
O6 W4 O22 91.2(10) . 3_755
O20 W4 O22 63.9(10) 3_755 3_755
O2 W4 O22 92.8(9) . 3_755
O7 W4 O22 65.6(10) . 3_755
O1 W4 O22 39.3(11) . 3_755
O19 W5 O14 104.0(7) . .
O19 W5 O16 103.2(8) . .
O14 W5 O16 89.2(7) . .
O19 W5 O10 101.1(7) . 3_755
O14 W5 O10 154.8(8) . 3_755
O16 W5 O10 86.9(7) . 3_755
O19 W5 O6 100.8(7) . 3_755
O14 W5 O6 86.6(7) . 3_755
O16 W5 O6 156.0(7) . 3_755
O10 W5 O6 86.9(7) 3_755 3_755
O19 W5 O11 158.9(9) . .
O14 W5 O11 62.7(9) . .
O16 W5 O11 62.4(9) . .
O10 W5 O11 93.7(9) 3_755 .
O6 W5 O11 94.9(9) 3_755 .
O12 W6 O4 103.9(8) . .
O12 W6 O16 102.9(8) . .
O4 W6 O16 87.5(7) . .
O12 W6 O7 101.4(8) . .
O4 W6 O7 88.6(7) . .
O16 W6 O7 155.6(7) . .
O12 W6 O5 102.3(8) . 3_755
O4 W6 O5 153.8(7) . 3_755
O16 W6 O5 85.8(7) . 3_755
O7 W6 O5 87.2(7) . 3_755
O12 W6 O11 158.8(9) . .
O4 W6 O11 61.9(9) . .
O16 W6 O11 62.9(9) . .
O7 W6 O11 94.2(9) . .
O5 W6 O11 92.6(9) 3_755 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N9 2.120(18) .
Ag1 N1 2.15(2) .
Ag1 O19 2.561(16) 1_455
Ag1 O21 2.594(14) .
Ag2 N4 2.10(2) .
Ag2 N12 2.13(2) 4_566
Ag3 N6 2.11(2) 3_646
Ag3 N6 2.11(2) .
P1 O22 1.45(3) .
P1 O22 1.45(3) 3_755
P1 O1 1.50(3) 3_755
P1 O1 1.50(3) .
P1 O17 1.51(4) 3_755
P1 O17 1.51(4) .
P1 O11 1.60(3) .
P1 O11 1.60(3) 3_755
C1 N1 1.31(3) .
C1 N2 1.31(3) .
C1 H1 0.9300 .
C2 C13 1.46(4) .
C2 N2 1.49(3) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 N5 1.47(3) .
C3 C4 1.53(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C16 1.49(4) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 N3 1.31(4) .
C5 N1 1.33(4) .
C5 H5 0.9300 .
C6 N8 1.32(3) .
C6 N6 1.34(3) .
C6 H6A 0.9300 .
C7 N7 1.34(3) .
C7 N6 1.34(3) .
C7 H7A 0.9300 .
C8 N11 1.31(4) .
C8 N9 1.36(3) .
C8 H8A 0.9300 .
C9 N10 1.30(3) .
C9 N9 1.31(3) .
C9 H9A 0.9300 .
C10 N7 1.45(3) .
C10 C11 1.47(4) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C14 1.479(18) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C15 1.507(19) .
C12 C17 1.566(19) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C18 1.42(4) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 C18 1.529(18) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 N10 1.59(4) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 C17 1.54(4) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 N12 1.32(3) .
C19 N4 1.34(3) .
C19 H19A 0.9300 .
C20 N5 1.31(3) .
C20 N12 1.32(3) .
C20 H20A 0.9300 .
N2 N3 1.37(3) .
N4 N5 1.38(3) .
N7 N8 1.37(3) .
N10 N11 1.28(4) .
N12 Ag2 2.13(2) 4_565
O1 O22 1.67(5) 3_755
O1 O17 1.72(5) .
O1 W2 2.43(4) .
O1 W4 2.46(3) .
O2 W2 1.889(16) .
O2 W4 1.904(15) .
O3 W3 1.873(17) .
O3 W2 1.903(16) .
O4 W6 1.870(17) .
O4 W1 1.881(16) .
O5 W3 1.855(18) .
O5 W6 1.914(18) 3_755
O6 W4 1.863(16) .
O6 W5 1.909(17) 3_755
O7 W6 1.881(16) .
O7 W4 1.906(15) .
O8 W1 1.667(13) .
O9 W1 1.885(17) .
O9 W2 1.896(18) .
O10 W2 1.885(18) .
O10 W5 1.889(18) 3_755
O11 O22 1.79(5) 3_755
O11 W6 2.40(3) .
O11 W5 2.42(3) .
O11 W1 2.45(3) .
O12 W6 1.664(17) .
O13 W4 1.642(17) .
O14 W5 1.860(17) .
O14 W1 1.872(17) .
O15 W1 1.870(17) .
O15 W3 1.887(18) .
O16 W6 1.879(17) .
O16 W5 1.882(16) .
O17 O22 1.58(5) .
O17 W3 2.38(3) .
O17 W2 2.48(3) .
O18 W3 1.668(17) .
O19 W5 1.671(16) .
O19 Ag1 2.561(16) 1_655
O20 W4 1.878(15) 3_755
O20 W3 1.891(15) .
O21 W2 1.663(14) .
O22 O1 1.67(5) 3_755
O22 O11 1.79(5) 3_755
O22 W3 2.46(3) .
O22 W4 2.50(3) 3_755
W4 O20 1.878(15) 3_755
W4 O22 2.50(3) 3_755
W5 O10 1.889(18) 3_755
W5 O6 1.909(17) 3_755
W6 O5 1.914(18) 3_755
