#------------------------------------------------------------------------------
#$Date: 2018-09-27 07:13:35 +0300 (Thu, 27 Sep 2018) $
#$Revision: 211196 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/21/02/7210258.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210258
loop_
_publ_author_name
'Luo, Yu-Hui'
'Yue, Feng-Xia'
'Yu, Xiao-Yang'
'Chen, Xin'
'Zhang, Hong'
_publ_section_title
;
 Coordination polymers of lanthanide complexes with benzene dicarboxylato
 ligands
;
_journal_issue                   32
_journal_name_full               CrystEngComm
_journal_page_first              6340
_journal_paper_doi               10.1039/c3ce40357b
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C33 H22 Eu O11, H2 O'
_chemical_formula_sum            'C33 H24 Eu O12'
_chemical_formula_weight         764.48
_chemical_melting_point          ?
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.635(5)
_cell_angle_beta                 111.321(5)
_cell_angle_gamma                100.381(5)
_cell_formula_units_Z            2
_cell_length_a                   10.3979(6)
_cell_length_b                   11.4388(6)
_cell_length_c                   14.1007(8)
_cell_measurement_reflns_used    3924
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1302
_cell_measurement_theta_min      2.7577
_cell_volume                     1460.95(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0349
_diffrn_reflns_av_sigmaI/netI    0.0669
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9693
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.76
_exptl_absorpt_coefficient_mu    2.216
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.99255
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrysAlis (Oxford Diffraction, 2006)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.738
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             762
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.19
_refine_diff_density_max         1.113
_refine_diff_density_min         -0.701
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         5710
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0467
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0243P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0658
_refine_ls_wR_factor_ref         0.0702
_reflns_number_gt                4947
_reflns_number_total             5710
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40357b.txt
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

'_symmetry_cell_setting' value
'Triclinic' changed to 'triclinic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1460.95(14)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7210258
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.61396(2) 0.563440(19) 0.658491(16) 0.01448(7) Uani 1 1 d .
C1 C 0.7982(5) 0.7874(4) 0.8196(3) 0.0220(10) Uani 1 1 d .
C2 C 0.9013(5) 0.8988(4) 0.9113(3) 0.0226(10) Uani 1 1 d .
C3 C 0.8924(5) 0.9212(4) 1.0095(3) 0.0247(10) Uani 1 1 d .
H3 H 0.8193 0.8676 1.0156 0.030 Uiso 1 1 calc R
C4 C 1.0119(5) 0.9802(4) 0.9024(3) 0.0211(10) Uani 1 1 d .
C5 C 1.0201(5) 0.9658(4) 0.7952(4) 0.0264(11) Uani 1 1 d .
C6 C 1.1365(5) 0.9153(4) 0.7788(4) 0.0288(11) Uani 1 1 d .
C7 C 1.2595(6) 0.9176(5) 0.8607(5) 0.0434(14) Uani 1 1 d .
H7 H 1.2691 0.9438 0.9308 0.052 Uiso 1 1 calc R
C8 C 1.3710(7) 0.8814(6) 0.8409(5) 0.0557(17) Uani 1 1 d .
H8 H 1.4559 0.8866 0.8973 0.067 Uiso 1 1 calc R
C9 C 1.3531(7) 0.8379(6) 0.7365(5) 0.0534(15) Uani 1 1 d U
H9 H 1.4265 0.8131 0.7226 0.064 Uiso 1 1 calc R
C10 C 1.2310(7) 0.8307(6) 0.6541(5) 0.0539(15) Uani 1 1 d U
H10 H 1.2194 0.7985 0.5840 0.065 Uiso 1 1 calc R
C11 C 1.1215(7) 0.8716(5) 0.6738(4) 0.0468(15) Uani 1 1 d .
H11 H 1.0389 0.8698 0.6170 0.056 Uiso 1 1 calc R
C12 C 0.7007(5) 0.4923(4) 0.4304(3) 0.0178(9) Uani 1 1 d .
C13 C 0.8570(5) 0.5014(4) 0.4669(3) 0.0190(9) Uani 1 1 d .
C14 C 0.9289(5) 0.4821(4) 0.5626(3) 0.0205(10) Uani 1 1 d .
H14 H 0.8805 0.4705 0.6053 0.025 Uiso 1 1 calc R
C15 C 0.9297(5) 0.5205(4) 0.4024(3) 0.0209(10) Uani 1 1 d .
C16 C 0.8629(5) 0.5426(4) 0.2961(4) 0.0264(11) Uani 1 1 d .
C17 C 0.7992(5) 0.6476(5) 0.2881(4) 0.0306(11) Uani 1 1 d .
C18 C 0.8174(6) 0.7367(5) 0.3785(5) 0.0458(14) Uani 1 1 d .
H18 H 0.8689 0.7310 0.4459 0.055 Uiso 1 1 calc R
C19 C 0.7562(8) 0.8390(6) 0.3682(6) 0.067(2) Uani 1 1 d .
H19 H 0.7664 0.9012 0.4275 0.080 Uiso 1 1 calc R
C20 C 0.6808(7) 0.8391(6) 0.2641(5) 0.0610(17) Uani 1 1 d U
H20 H 0.6397 0.9039 0.2548 0.073 Uiso 1 1 calc R
C21 C 0.6640(7) 0.7539(6) 0.1782(5) 0.0607(17) Uani 1 1 d U
H21 H 0.6117 0.7587 0.1106 0.073 Uiso 1 1 calc R
C22 C 0.7240(6) 0.6574(6) 0.1886(5) 0.0458(14) Uani 1 1 d .
H22 H 0.7138 0.5978 0.1276 0.055 Uiso 1 1 calc R
C23 C 0.4838(5) 0.7407(4) 0.4959(3) 0.0202(9) Uani 1 1 d .
C24 C 0.4873(5) 0.8754(4) 0.4980(3) 0.0180(9) Uani 1 1 d .
C25 C 0.6053(5) 0.9705(4) 0.5764(3) 0.0200(9) Uani 1 1 d .
H25 H 0.6759 0.9510 0.6284 0.024 Uiso 1 1 calc R
C26 C 0.3793(5) 0.9045(4) 0.4211(3) 0.0184(9) Uani 1 1 d .
C27 C 0.2428(5) 0.8080(4) 0.3416(3) 0.0221(10) Uani 1 1 d .
C28 C 0.2084(5) 0.7815(4) 0.2254(3) 0.0245(10) Uani 1 1 d .
C29 C 0.3134(6) 0.8238(5) 0.1919(4) 0.0401(13) Uani 1 1 d .
H29 H 0.4046 0.8737 0.2418 0.048 Uiso 1 1 calc R
C30 C 0.2807(7) 0.7907(6) 0.0832(5) 0.0557(17) Uani 1 1 d .
H30 H 0.3508 0.8179 0.0603 0.067 Uiso 1 1 calc R
C31 C 0.1467(8) 0.7189(6) 0.0099(4) 0.0551(17) Uani 1 1 d .
H31 H 0.1263 0.6971 -0.0626 0.066 Uiso 1 1 calc R
C32 C 0.0410(7) 0.6780(5) 0.0418(4) 0.0488(15) Uani 1 1 d .
H32 H -0.0505 0.6296 -0.0087 0.059 Uiso 1 1 calc R
C33 C 0.0728(6) 0.7099(4) 0.1501(4) 0.0331(12) Uani 1 1 d .
H33 H 0.0018 0.6828 0.1722 0.040 Uiso 1 1 calc R
O1 O 0.6846(3) 0.7308(3) 0.8237(2) 0.0283(7) Uani 1 1 d .
O2 O 0.8287(3) 0.7486(3) 0.7427(2) 0.0291(8) Uani 1 1 d .
O3 O 0.9402(4) 1.0001(3) 0.7284(3) 0.0404(9) Uani 1 1 d .
O4 O 0.6536(3) 0.5284(3) 0.5009(2) 0.0215(7) Uani 1 1 d .
O5 O 0.6181(3) 0.4487(3) 0.3339(2) 0.0255(7) Uani 1 1 d .
O6 O 0.8698(4) 0.4772(4) 0.2190(3) 0.0448(10) Uani 1 1 d .
O7 O 0.5395(3) 0.7228(3) 0.5843(2) 0.0215(7) Uani 1 1 d .
O8 O 0.4289(3) 0.6589(3) 0.4055(2) 0.0234(7) Uani 1 1 d .
O9 O 0.1611(4) 0.7525(3) 0.3715(3) 0.0344(8) Uani 1 1 d .
O1W O 0.5954(4) 0.4624(3) 0.7967(3) 0.0379(9) Uani 1 1 d .
H1WA H 0.5532 0.3854 0.7812 0.045 Uiso 1 1 d R
H1WB H 0.5567 0.5042 0.8302 0.045 Uiso 1 1 d R
O2W O 0.8398(4) 0.5216(3) 0.7653(3) 0.0344(8) Uani 1 1 d .
H2WA H 0.9252 0.5372 0.7698 0.041 Uiso 1 1 d R
H2WB H 0.8191 0.4500 0.7732 0.041 Uiso 1 1 d R
O3W O 0.4990(6) 0.3613(4) 0.0865(4) 0.0823(15) Uani 1 1 d .
H3WA H 0.4232 0.3205 0.0878 0.099 Uiso 1 1 d R
H3WB H 0.5704 0.3610 0.1406 0.099 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Eu1 O7 75.65(9) . .
O4 Eu1 O8 75.16(9) . 2_666
O7 Eu1 O8 136.68(10) . 2_666
O4 Eu1 O5 125.72(10) . 2_666
O7 Eu1 O5 77.01(10) . 2_666
O8 Eu1 O5 95.18(10) 2_666 2_666
O4 Eu1 O1 139.00(10) . .
O7 Eu1 O1 80.61(10) . .
O8 Eu1 O1 140.50(10) 2_666 .
O5 Eu1 O1 79.27(10) 2_666 .
O4 Eu1 O2 88.10(10) . .
O7 Eu1 O2 73.96(10) . .
O8 Eu1 O2 135.58(10) 2_666 .
O5 Eu1 O2 127.03(10) 2_666 .
O1 Eu1 O2 53.08(9) . .
O4 Eu1 O2W 94.02(10) . .
O7 Eu1 O2W 138.96(11) . .
O8 Eu1 O2W 74.38(11) 2_666 .
O5 Eu1 O2W 135.38(10) 2_666 .
O1 Eu1 O2W 82.45(10) . .
O2 Eu1 O2W 65.97(11) . .
O4 Eu1 O1W 142.20(10) . .
O7 Eu1 O1W 140.35(9) . .
O8 Eu1 O1W 68.75(10) 2_666 .
O5 Eu1 O1W 69.67(10) 2_666 .
O1 Eu1 O1W 72.75(10) . .
O2 Eu1 O1W 109.90(11) . .
O2W Eu1 O1W 66.10(10) . .
O4 Eu1 O4 76.15(10) . 2_666
O7 Eu1 O4 68.97(9) . 2_666
O8 Eu1 O4 73.44(9) 2_666 2_666
O5 Eu1 O4 50.37(9) 2_666 2_666
O1 Eu1 O4 124.95(9) . 2_666
O2 Eu1 O4 142.23(9) . 2_666
O2W Eu1 O4 147.78(10) . 2_666
O1W Eu1 O4 103.20(10) . 2_666
O4 Eu1 C1 113.80(11) . .
O7 Eu1 C1 76.42(11) . .
O8 Eu1 C1 145.47(11) 2_666 .
O5 Eu1 C1 103.88(11) 2_666 .
O1 Eu1 C1 26.71(10) . .
O2 Eu1 C1 26.38(10) . .
O2W Eu1 C1 71.80(11) . .
O1W Eu1 C1 91.06(12) . .
O4 Eu1 C1 140.31(10) 2_666 .
O4 Eu1 C12 101.39(11) . 2_666
O7 Eu1 C12 69.86(10) . 2_666
O8 Eu1 C12 85.43(11) 2_666 2_666
O5 Eu1 C12 24.55(10) 2_666 2_666
O1 Eu1 C12 101.12(11) . 2_666
O2 Eu1 C12 138.70(10) . 2_666
O2W Eu1 C12 150.56(11) . 2_666
O1W Eu1 C12 86.84(11) . 2_666
O4 Eu1 C12 25.90(9) 2_666 2_666
C1 Eu1 C12 122.42(11) . 2_666
O4 Eu1 Eu1 40.97(7) . 2_666
O7 Eu1 Eu1 67.08(7) . 2_666
O8 Eu1 Eu1 69.85(7) 2_666 2_666
O5 Eu1 Eu1 85.17(7) 2_666 2_666
O1 Eu1 Eu1 146.58(8) . 2_666
O2 Eu1 Eu1 120.94(7) . 2_666
O2W Eu1 Eu1 127.80(7) . 2_666
O1W Eu1 Eu1 128.54(9) . 2_666
O4 Eu1 Eu1 35.18(5) 2_666 2_666
C1 Eu1 Eu1 139.39(9) . 2_666
C12 Eu1 Eu1 60.64(8) 2_666 2_666
O2 C1 O1 121.4(4) . .
O2 C1 C2 119.3(4) . .
O1 C1 C2 119.2(4) . .
O2 C1 Eu1 61.8(2) . .
O1 C1 Eu1 59.7(2) . .
C2 C1 Eu1 174.7(3) . .
C3 C2 C4 118.6(4) . .
C3 C2 C1 119.9(4) . .
C4 C2 C1 121.5(4) . .
C4 C3 C2 122.2(4) 2_777 .
C4 C3 H3 118.9 2_777 .
C2 C3 H3 118.9 . .
C3 C4 C2 119.1(4) 2_777 .
C3 C4 C5 119.9(4) 2_777 .
C2 C4 C5 120.8(4) . .
O3 C5 C6 121.5(4) . .
O3 C5 C4 120.5(4) . .
C6 C5 C4 117.9(4) . .
C7 C6 C11 118.8(4) . .
C7 C6 C5 123.7(4) . .
C11 C6 C5 117.3(5) . .
C6 C7 C8 121.1(5) . .
C6 C7 H7 119.4 . .
C8 C7 H7 119.4 . .
C9 C8 C7 118.9(6) . .
C9 C8 H8 120.6 . .
C7 C8 H8 120.6 . .
C10 C9 C8 121.1(5) . .
C10 C9 H9 119.4 . .
C8 C9 H9 119.4 . .
C9 C10 C11 120.1(5) . .
C9 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C6 C11 C10 119.9(6) . .
C6 C11 H11 120.1 . .
C10 C11 H11 120.1 . .
O5 C12 O4 121.0(4) . .
O5 C12 C13 120.3(3) . .
O4 C12 C13 118.7(4) . .
O5 C12 Eu1 54.6(2) . 2_666
O4 C12 Eu1 66.6(2) . 2_666
C13 C12 Eu1 171.7(3) . 2_666
C14 C13 C15 119.3(4) . .
C14 C13 C12 119.0(4) . .
C15 C13 C12 121.6(4) . .
C13 C14 C15 122.3(4) . 2_766
C13 C14 H14 118.9 . .
C15 C14 H14 118.9 2_766 .
C14 C15 C13 118.5(4) 2_766 .
C14 C15 C16 117.3(3) 2_766 .
C13 C15 C16 124.3(4) . .
O6 C16 C17 120.9(4) . .
O6 C16 C15 118.6(4) . .
C17 C16 C15 120.4(4) . .
C18 C17 C22 119.9(5) . .
C18 C17 C16 120.8(5) . .
C22 C17 C16 119.3(5) . .
C17 C18 C19 119.6(6) . .
C17 C18 H18 120.2 . .
C19 C18 H18 120.2 . .
C20 C19 C18 115.9(6) . .
C20 C19 H19 122.0 . .
C18 C19 H19 122.0 . .
C21 C20 C19 124.2(6) . .
C21 C20 H20 117.9 . .
C19 C20 H20 117.9 . .
C20 C21 C22 119.6(7) . .
C20 C21 H21 120.2 . .
C22 C21 H21 120.2 . .
C21 C22 C17 120.8(6) . .
C21 C22 H22 119.6 . .
C17 C22 H22 119.6 . .
O7 C23 O8 126.0(4) . .
O7 C23 C24 116.7(4) . .
O8 C23 C24 117.2(4) . .
C25 C24 C26 119.5(4) . .
C25 C24 C23 118.2(4) . .
C26 C24 C23 122.2(4) . .
C24 C25 C26 121.4(4) . 2_676
C24 C25 H25 119.3 . .
C26 C25 H25 119.3 2_676 .
C24 C26 C25 119.1(4) . 2_676
C24 C26 C27 122.0(4) . .
C25 C26 C27 118.7(4) 2_676 .
O9 C27 C28 120.9(4) . .
O9 C27 C26 120.4(4) . .
C28 C27 C26 118.8(4) . .
C33 C28 C29 119.5(4) . .
C33 C28 C27 119.8(4) . .
C29 C28 C27 120.7(4) . .
C30 C29 C28 119.4(5) . .
C30 C29 H29 120.3 . .
C28 C29 H29 120.3 . .
C31 C30 C29 120.4(5) . .
C31 C30 H30 119.8 . .
C29 C30 H30 119.8 . .
C30 C31 C32 120.8(5) . .
C30 C31 H31 119.6 . .
C32 C31 H31 119.6 . .
C31 C32 C33 119.2(6) . .
C31 C32 H32 120.4 . .
C33 C32 H32 120.4 . .
C28 C33 C32 120.7(5) . .
C28 C33 H33 119.7 . .
C32 C33 H33 119.7 . .
C1 O1 Eu1 93.5(2) . .
C1 O2 Eu1 91.9(3) . .
C12 O4 Eu1 162.7(3) . .
C12 O4 Eu1 87.5(2) . 2_666
Eu1 O4 Eu1 103.85(10) . 2_666
C12 O5 Eu1 100.8(2) . 2_666
C23 O7 Eu1 140.6(3) . .
C23 O8 Eu1 135.6(3) . 2_666
Eu1 O1W H1WA 123.2 . .
Eu1 O1W H1WB 106.6 . .
H1WA O1W H1WB 107.4 . .
Eu1 O2W H2WA 135.6 . .
Eu1 O2W H2WB 109.0 . .
H2WA O2W H2WB 107.4 . .
H3WA O3W H3WB 107.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O4 2.367(2) .
Eu1 O7 2.403(3) .
Eu1 O8 2.403(3) 2_666
Eu1 O5 2.435(3) 2_666
Eu1 O1 2.435(3) .
Eu1 O2 2.480(3) .
Eu1 O2W 2.481(3) .
Eu1 O1W 2.519(3) .
Eu1 O4 2.695(3) 2_666
C1 O2 1.251(5) .
C1 O1 1.267(5) .
C1 C2 1.491(6) .
C2 C3 1.392(6) .
C2 C4 1.405(6) .
C3 C4 1.375(6) 2_777
C3 H3 0.9300 .
C4 C3 1.375(6) 2_777
C4 C5 1.520(6) .
C5 O3 1.200(5) .
C5 C6 1.500(6) .
C6 C7 1.367(7) .
C6 C11 1.395(6) .
C7 C8 1.397(7) .
C7 H7 0.9300 .
C8 C9 1.378(8) .
C8 H8 0.9300 .
C9 C10 1.348(8) .
C9 H9 0.9300 .
C10 C11 1.398(7) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 O5 1.240(5) .
C12 O4 1.282(4) .
C12 C13 1.491(6) .
C12 Eu1 2.932(4) 2_666
C13 C14 1.372(6) .
C13 C15 1.405(5) .
C14 C15 1.379(6) 2_766
C14 H14 0.9300 .
C15 C14 1.379(6) 2_766
C15 C16 1.504(6) .
C16 O6 1.212(5) .
C16 C17 1.479(6) .
C17 C18 1.374(7) .
C17 C22 1.377(7) .
C18 C19 1.438(8) .
C18 H18 0.9300 .
C19 C20 1.391(9) .
C19 H19 0.9300 .
C20 C21 1.310(8) .
C20 H20 0.9300 .
C21 C22 1.372(8) .
C21 H21 0.9300 .
C22 H22 0.9300 .
C23 O7 1.250(5) .
C23 O8 1.258(5) .
C23 C24 1.527(5) .
C24 C25 1.385(6) .
C24 C26 1.399(6) .
C25 C26 1.400(5) 2_676
C25 H25 0.9300 .
C26 C25 1.400(5) 2_676
C26 C27 1.492(6) .
C27 O9 1.219(5) .
C27 C28 1.490(6) .
C28 C33 1.379(7) .
C28 C29 1.390(6) .
C29 C30 1.389(7) .
C29 H29 0.9300 .
C30 C31 1.362(9) .
C30 H30 0.9300 .
C31 C32 1.376(8) .
C31 H31 0.9300 .
C32 C33 1.386(7) .
C32 H32 0.9300 .
C33 H33 0.9300 .
O4 Eu1 2.695(3) 2_666
O5 Eu1 2.435(3) 2_666
O8 Eu1 2.403(3) 2_666
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
O2W H2WA 0.8501 .
O2W H2WB 0.8510 .
O3W H3WA 0.8500 .
O3W H3WB 0.8501 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Eu1 C1 O2 -13.9(3) . .
O7 Eu1 C1 O2 -81.2(2) . .
O8 Eu1 C1 O2 84.6(3) 2_666 .
O5 Eu1 C1 O2 -153.9(2) 2_666 .
O1 Eu1 C1 O2 -177.3(4) . .
O2W Eu1 C1 O2 72.4(2) . .
O1W Eu1 C1 O2 136.8(2) . .
O4 Eu1 C1 O2 -110.9(2) 2_666 .
C12 Eu1 C1 O2 -136.3(2) 2_666 .
Eu1 Eu1 C1 O2 -55.0(3) 2_666 .
O4 Eu1 C1 O1 163.5(2) . .
O7 Eu1 C1 O1 96.1(2) . .
O8 Eu1 C1 O1 -98.1(3) 2_666 .
O5 Eu1 C1 O1 23.4(3) 2_666 .
O2 Eu1 C1 O1 177.3(4) . .
O2W Eu1 C1 O1 -110.2(3) . .
O1W Eu1 C1 O1 -45.9(2) . .
O4 Eu1 C1 O1 66.5(3) 2_666 .
C12 Eu1 C1 O1 41.1(3) 2_666 .
Eu1 Eu1 C1 O1 122.3(2) 2_666 .
O2 C1 C2 C3 -160.7(4) . .
O1 C1 C2 C3 16.1(6) . .
O2 C1 C2 C4 16.7(6) . .
O1 C1 C2 C4 -166.4(4) . .
C4 C2 C3 C4 -0.1(7) . 2_777
C1 C2 C3 C4 177.5(4) . 2_777
C3 C2 C4 C3 0.1(7) . 2_777
C1 C2 C4 C3 -177.5(4) . 2_777
C3 C2 C4 C5 -175.5(4) . .
C1 C2 C4 C5 6.9(6) . .
C3 C4 C5 O3 -99.2(6) 2_777 .
C2 C4 C5 O3 76.4(6) . .
C3 C4 C5 C6 77.0(5) 2_777 .
C2 C4 C5 C6 -107.4(5) . .
O3 C5 C6 C7 155.1(5) . .
C4 C5 C6 C7 -21.0(7) . .
O3 C5 C6 C11 -20.3(7) . .
C4 C5 C6 C11 163.6(4) . .
C11 C6 C7 C8 2.2(8) . .
C5 C6 C7 C8 -173.1(5) . .
C6 C7 C8 C9 -2.7(9) . .
C7 C8 C9 C10 0.4(9) . .
C8 C9 C10 C11 2.2(9) . .
C7 C6 C11 C10 0.4(8) . .
C5 C6 C11 C10 176.0(5) . .
C9 C10 C11 C6 -2.6(9) . .
O5 C12 C13 C14 -144.5(4) . .
O4 C12 C13 C14 34.3(6) . .
O5 C12 C13 C15 31.0(6) . .
O4 C12 C13 C15 -150.2(4) . .
C15 C13 C14 C15 -0.7(7) . 2_766
C12 C13 C14 C15 174.9(4) . 2_766
C14 C13 C15 C14 0.6(7) . 2_766
C12 C13 C15 C14 -174.8(4) . 2_766
C14 C13 C15 C16 -180.0(4) . .
C12 C13 C15 C16 4.6(6) . .
C14 C15 C16 O6 52.2(6) 2_766 .
C13 C15 C16 O6 -127.2(5) . .
C14 C15 C16 C17 -123.7(4) 2_766 .
C13 C15 C16 C17 57.0(6) . .
O6 C16 C17 C18 -166.6(5) . .
C15 C16 C17 C18 9.2(7) . .
O6 C16 C17 C22 11.8(7) . .
C15 C16 C17 C22 -172.5(4) . .
C22 C17 C18 C19 0.6(8) . .
C16 C17 C18 C19 179.0(5) . .
C17 C18 C19 C20 0.2(8) . .
C18 C19 C20 C21 -0.2(10) . .
C19 C20 C21 C22 -0.5(10) . .
C20 C21 C22 C17 1.4(9) . .
C18 C17 C22 C21 -1.4(8) . .
C16 C17 C22 C21 -179.8(5) . .
O7 C23 C24 C25 34.2(5) . .
O8 C23 C24 C25 -144.0(4) . .
O7 C23 C24 C26 -148.8(4) . .
O8 C23 C24 C26 33.0(5) . .
C26 C24 C25 C26 -1.5(6) . 2_676
C23 C24 C25 C26 175.6(3) . 2_676
C25 C24 C26 C25 1.5(6) . 2_676
C23 C24 C26 C25 -175.5(3) . 2_676
C25 C24 C26 C27 -173.7(4) . .
C23 C24 C26 C27 9.3(5) . .
C24 C26 C27 O9 61.6(5) . .
C25 C26 C27 O9 -113.6(4) 2_676 .
C24 C26 C27 C28 -118.6(4) . .
C25 C26 C27 C28 66.2(5) 2_676 .
O9 C27 C28 C33 11.3(6) . .
C26 C27 C28 C33 -168.5(4) . .
O9 C27 C28 C29 -166.1(4) . .
C26 C27 C28 C29 14.1(6) . .
C33 C28 C29 C30 -1.5(7) . .
C27 C28 C29 C30 175.9(4) . .
C28 C29 C30 C31 0.8(8) . .
C29 C30 C31 C32 0.3(9) . .
C30 C31 C32 C33 -0.6(9) . .
C29 C28 C33 C32 1.2(7) . .
C27 C28 C33 C32 -176.2(4) . .
C31 C32 C33 C28 -0.1(8) . .
O2 C1 O1 Eu1 2.8(4) . .
C2 C1 O1 Eu1 -174.0(3) . .
O4 Eu1 O1 C1 -23.4(3) . .
O7 Eu1 O1 C1 -78.4(3) . .
O8 Eu1 O1 C1 118.1(3) 2_666 .
O5 Eu1 O1 C1 -156.8(3) 2_666 .
O2 Eu1 O1 C1 -1.5(2) . .
O2W Eu1 O1 C1 64.1(3) . .
O1W Eu1 O1 C1 131.3(3) . .
O4 Eu1 O1 C1 -134.4(2) 2_666 .
C12 Eu1 O1 C1 -145.6(2) 2_666 .
Eu1 Eu1 O1 C1 -93.1(3) 2_666 .
O1 C1 O2 Eu1 -2.7(4) . .
C2 C1 O2 Eu1 174.0(3) . .
O4 Eu1 O2 C1 167.3(2) . .
O7 Eu1 O2 C1 91.7(2) . .
O8 Eu1 O2 C1 -126.3(2) 2_666 .
O5 Eu1 O2 C1 32.4(3) 2_666 .
O1 Eu1 O2 C1 1.5(2) . .
O2W Eu1 O2 C1 -97.4(3) . .
O1W Eu1 O2 C1 -46.7(3) . .
O4 Eu1 O2 C1 103.0(3) 2_666 .
C12 Eu1 O2 C1 62.2(3) 2_666 .
Eu1 Eu1 O2 C1 141.6(2) 2_666 .
O5 C12 O4 Eu1 137.3(8) . .
C13 C12 O4 Eu1 -41.5(11) . .
Eu1 C12 O4 Eu1 131.4(9) 2_666 .
O5 C12 O4 Eu1 5.9(4) . 2_666
C13 C12 O4 Eu1 -172.9(3) . 2_666
O7 Eu1 O4 C12 159.1(9) . .
O8 Eu1 O4 C12 -53.3(9) 2_666 .
O5 Eu1 O4 C12 -139.0(9) 2_666 .
O1 Eu1 O4 C12 102.5(9) . .
O2 Eu1 O4 C12 85.1(9) . .
O2W Eu1 O4 C12 19.4(9) . .
O1W Eu1 O4 C12 -35.7(10) . .
O4 Eu1 O4 C12 -129.5(9) 2_666 .
C1 Eu1 O4 C12 91.2(9) . .
C12 Eu1 O4 C12 -135.4(9) 2_666 .
Eu1 Eu1 O4 C12 -129.5(9) 2_666 .
O7 Eu1 O4 Eu1 -71.43(10) . 2_666
O8 Eu1 O4 Eu1 76.21(10) 2_666 2_666
O5 Eu1 O4 Eu1 -9.45(15) 2_666 2_666
O1 Eu1 O4 Eu1 -128.00(14) . 2_666
O2 Eu1 O4 Eu1 -145.36(10) . 2_666
O2W Eu1 O4 Eu1 148.89(11) . 2_666
O1W Eu1 O4 Eu1 93.78(17) . 2_666
O4 Eu1 O4 Eu1 0.0 2_666 2_666
C1 Eu1 O4 Eu1 -139.25(11) . 2_666
C12 Eu1 O4 Eu1 -5.89(11) 2_666 2_666
O4 C12 O5 Eu1 -6.7(4) . 2_666
C13 C12 O5 Eu1 172.1(3) . 2_666
O8 C23 O7 Eu1 9.6(7) . .
C24 C23 O7 Eu1 -168.4(3) . .
O4 Eu1 O7 C23 32.5(4) . .
O8 Eu1 O7 C23 -16.5(5) 2_666 .
O5 Eu1 O7 C23 -100.2(4) 2_666 .
O1 Eu1 O7 C23 178.8(4) . .
O2 Eu1 O7 C23 124.6(4) . .
O2W Eu1 O7 C23 111.9(4) . .
O1W Eu1 O7 C23 -133.3(4) . .
O4 Eu1 O7 C23 -48.0(4) 2_666 .
C1 Eu1 O7 C23 151.8(4) . .
C12 Eu1 O7 C23 -75.6(4) 2_666 .
Eu1 Eu1 O7 C23 -10.0(4) 2_666 .
O7 C23 O8 Eu1 2.5(7) . 2_666
C24 C23 O8 Eu1 -179.5(2) . 2_666
