#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:24:35 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180433 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/02/7210270.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210270
loop_
_publ_author_name
'Zhang, Jinhong'
'Cheng, Shaomin'
'Wang, Xiangfei'
'Yuan, Limin'
'Xue, Mingqiang'
'Wang, Yang'
'Liu, Wenlong'
_publ_section_title
;
 Heterometallic coordination polymers based on dipeptide schiff base
 Cu(ii) metalloligand: synthesis, structures, and magnetic properties
;
_journal_issue                   30
_journal_name_full               CrystEngComm
_journal_page_first              6074
_journal_paper_doi               10.1039/c3ce40596f
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C11 H12 Cu N2 O9 S Sr'
_chemical_formula_sum            'C11 H12 Cu N2 O9 S Sr'
_chemical_formula_weight         499.45
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.757(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.1109(11)
_cell_length_b                   11.7065(18)
_cell_length_c                   16.460(3)
_cell_measurement_reflns_used    3277
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.96
_cell_measurement_theta_min      2.51
_cell_volume                     1535.4(4)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Smart Aepex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0747
_diffrn_reflns_av_sigmaI/netI    0.1328
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            17039
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.15
_exptl_absorpt_coefficient_mu    5.048
_exptl_absorpt_correction_T_max  0.359
_exptl_absorpt_correction_T_min  0.268
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            'violet red '
_exptl_crystal_density_diffrn    2.161
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             988
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.829
_refine_diff_density_min         -0.817
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         3016
_refine_ls_number_restraints     207
_refine_ls_restrained_S_all      0.998
_refine_ls_R_factor_all          0.0962
_refine_ls_R_factor_gt           0.0618
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0379P)²+6.8000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1125
_refine_ls_wR_factor_ref         0.1170
_reflns_number_gt                1934
_reflns_number_total             3016
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40596f.txt
_cod_data_source_block           compound_2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7210270
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.33105(10) 0.41311(7) 0.45665(5) 0.0288(2) Uani 1 1 d U
Sr1 Sr 0.35140(8) 0.08282(6) 0.58536(4) 0.02622(19) Uani 1 1 d U
C1 C 0.1772(8) 0.5507(5) 0.5623(4) 0.0255(5) Uani 1 1 d U
C2 C 0.1161(8) 0.5716(6) 0.6385(4) 0.0253(6) Uani 1 1 d U
H2 H 0.1230 0.5132 0.6773 0.030 Uiso 1 1 calc R
C3 C 0.0489(8) 0.6743(6) 0.6552(4) 0.0253(6) Uani 1 1 d U
H3 H 0.0099 0.6836 0.7045 0.030 Uiso 1 1 calc R
C4 C 0.0382(8) 0.7623(6) 0.6012(4) 0.0248(6) Uani 1 1 d U
C5 C 0.0938(8) 0.7515(6) 0.5251(4) 0.0252(6) Uani 1 1 d U
H5 H 0.0854 0.8126 0.4885 0.030 Uiso 1 1 calc R
C6 C 0.1620(8) 0.6469(6) 0.5058(4) 0.0254(5) Uani 1 1 d U
C7 C 0.2183(8) 0.6394(6) 0.4293(4) 0.0258(5) Uani 1 1 d U
H7 H 0.1967 0.7023 0.3945 0.031 Uiso 1 1 calc R
C8 C 0.3527(8) 0.5652(6) 0.3242(4) 0.0269(5) Uani 1 1 d U
H8A H 0.4416 0.6215 0.3282 0.032 Uiso 1 1 calc R
H8B H 0.2616 0.5887 0.2805 0.032 Uiso 1 1 calc R
C9 C 0.4182(8) 0.4490(6) 0.3036(4) 0.0273(5) Uani 1 1 d U
C10 C 0.4788(8) 0.2595(6) 0.3575(4) 0.0270(5) Uani 1 1 d U
H10A H 0.5930 0.2624 0.3477 0.032 Uiso 1 1 calc R
H10B H 0.4115 0.2170 0.3126 0.032 Uiso 1 1 calc R
C11 C 0.4759(8) 0.1987(6) 0.4396(4) 0.0265(5) Uani 1 1 d U
N1 N 0.2926(7) 0.5588(5) 0.4036(3) 0.0267(5) Uani 1 1 d U
N2 N 0.4118(7) 0.3772(5) 0.3595(3) 0.0272(5) Uani 1 1 d U
S1 S -0.0284(2) 0.90197(14) 0.62642(10) 0.0273(3) Uani 1 1 d U
O5 O -0.1510(5) 0.9415(4) 0.5547(3) 0.0277(6) Uani 1 1 d U
O6 O 0.1208(5) 0.9750(4) 0.6386(3) 0.0274(6) Uani 1 1 d U
O7 O -0.0994(5) 0.8882(4) 0.7003(3) 0.0286(7) Uani 1 1 d U
O1 O 0.2425(5) 0.4524(4) 0.5503(3) 0.0255(6) Uani 1 1 d U
O2 O 0.4673(5) 0.4392(4) 0.2366(3) 0.0275(6) Uani 1 1 d U
O3 O 0.4011(5) 0.2581(4) 0.4911(3) 0.0265(6) Uani 1 1 d U
O4 O 0.5287(5) 0.1043(4) 0.4521(3) 0.0269(6) Uani 1 1 d U
O8 O 0.6718(5) 0.1136(4) 0.6390(3) 0.0259(9) Uani 1 1 d U
H8D H 0.7141 0.1246 0.5962 0.031 Uiso 1 1 d R
H8E H 0.7101 0.0499 0.6590 0.031 Uiso 1 1 d R
O9 O 0.2210(5) 0.2610(4) 0.6438(3) 0.0245(9) Uani 1 1 d U
H9Y H 0.2966 0.3114 0.6575 0.029 Uiso 1 1 d R
H9X H 0.1436 0.2878 0.6067 0.029 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 N2 177.4(2) . .
O1 Cu1 N1 95.8(2) . .
N2 Cu1 N1 82.2(2) . .
O1 Cu1 O3 97.13(18) . .
N2 Cu1 O3 84.9(2) . .
N1 Cu1 O3 166.8(2) . .
O2 Sr1 O4 93.62(14) 4_566 3_656
O2 Sr1 O6 76.73(14) 4_566 1_545
O4 Sr1 O6 89.72(14) 3_656 1_545
O2 Sr1 O5 159.22(14) 4_566 3_566
O4 Sr1 O5 83.85(14) 3_656 3_566
O6 Sr1 O5 82.63(14) 1_545 3_566
O2 Sr1 O9 79.52(14) 4_566 .
O4 Sr1 O9 171.56(14) 3_656 .
O6 Sr1 O9 83.95(14) 1_545 .
O5 Sr1 O9 100.80(13) 3_566 .
O2 Sr1 O8 60.80(14) 4_566 .
O4 Sr1 O8 78.31(14) 3_656 .
O6 Sr1 O8 134.58(14) 1_545 .
O5 Sr1 O8 137.76(14) 3_566 .
O9 Sr1 O8 102.23(14) . .
O2 Sr1 O3 126.29(14) 4_566 .
O4 Sr1 O3 114.99(14) 3_656 .
O6 Sr1 O3 142.03(14) 1_545 .
O5 Sr1 O3 72.61(14) 3_566 .
O9 Sr1 O3 73.28(13) . .
O8 Sr1 O3 80.81(13) . .
O2 Sr1 O4 128.64(14) 4_566 .
O4 Sr1 O4 67.37(16) 3_656 .
O6 Sr1 O4 144.89(13) 1_545 .
O5 Sr1 O4 69.25(13) 3_566 .
O9 Sr1 O4 120.80(13) . .
O8 Sr1 O4 68.57(13) . .
O3 Sr1 O4 47.69(13) . .
O2 Sr1 C11 134.53(16) 4_566 .
O4 Sr1 C11 89.70(16) 3_656 .
O6 Sr1 C11 148.69(16) 1_545 .
O5 Sr1 C11 66.19(16) 3_566 .
O9 Sr1 C11 98.60(15) . .
O8 Sr1 C11 75.68(16) . .
O3 Sr1 C11 25.33(15) . .
O4 Sr1 C11 22.67(14) . .
O2 Sr1 Sr1 115.69(10) 4_566 3_656
O4 Sr1 Sr1 36.03(10) 3_656 3_656
O6 Sr1 Sr1 121.24(10) 1_545 3_656
O5 Sr1 Sr1 73.37(10) 3_566 3_656
O9 Sr1 Sr1 152.09(10) . 3_656
O8 Sr1 Sr1 69.69(10) . 3_656
O3 Sr1 Sr1 78.99(9) . 3_656
O4 Sr1 Sr1 31.34(9) . 3_656
C11 Sr1 Sr1 53.77(12) . 3_656
O2 Sr1 H8D 76.8 4_566 .
O4 Sr1 H8D 74.5 3_656 .
O6 Sr1 H8D 148.1 1_545 .
O5 Sr1 H8D 121.8 3_566 .
O9 Sr1 H8D 108.3 . .
O8 Sr1 H8D 16.1 . .
O3 Sr1 H8D 69.4 . .
O4 Sr1 H8D 52.5 . .
C11 Sr1 H8D 60.5 . .
Sr1 Sr1 H8D 57.5 3_656 .
O2 Sr1 H8E 54.7 4_566 .
O4 Sr1 H8E 65.9 3_656 .
O6 Sr1 H8E 121.6 1_545 .
O5 Sr1 H8E 139.4 3_566 .
O9 Sr1 H8E 112.9 . .
O8 Sr1 H8E 16.0 . .
O3 Sr1 H8E 95.5 . .
O4 Sr1 H8E 74.2 . .
C11 Sr1 H8E 86.4 . .
Sr1 Sr1 H8E 66.2 3_656 .
H8D Sr1 H8E 26.6 . .
O1 C1 C2 119.7(6) . .
O1 C1 C6 125.4(6) . .
C2 C1 C6 114.9(6) . .
C3 C2 C1 122.3(6) . .
C3 C2 H2 118.9 . .
C1 C2 H2 118.9 . .
C4 C3 C2 121.1(6) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C3 C4 C5 121.4(6) . .
C3 C4 S1 121.8(5) . .
C5 C4 S1 116.5(5) . .
C6 C5 C4 118.8(6) . .
C6 C5 H5 120.6 . .
C4 C5 H5 120.6 . .
C5 C6 C7 117.4(6) . .
C5 C6 C1 121.5(6) . .
C7 C6 C1 121.1(6) . .
N1 C7 C6 127.5(6) . .
N1 C7 H7 116.3 . .
C6 C7 H7 116.3 . .
N1 C8 C9 109.8(5) . .
N1 C8 H8A 109.7 . .
C9 C8 H8A 109.7 . .
N1 C8 H8B 109.7 . .
C9 C8 H8B 109.7 . .
H8A C8 H8B 108.2 . .
O2 C9 N2 130.6(6) . .
O2 C9 C8 117.5(6) . .
N2 C9 C8 111.8(6) . .
N2 C10 C11 110.2(5) . .
N2 C10 H10A 109.6 . .
C11 C10 H10A 109.6 . .
N2 C10 H10B 109.6 . .
C11 C10 H10B 109.6 . .
H10A C10 H10B 108.1 . .
O4 C11 O3 124.7(6) . .
O4 C11 C10 121.3(6) . .
O3 C11 C10 113.9(5) . .
O4 C11 Sr1 67.5(4) . .
O3 C11 Sr1 58.6(3) . .
C10 C11 Sr1 162.1(4) . .
C7 N1 C8 121.7(6) . .
C7 N1 Cu1 124.9(5) . .
C8 N1 Cu1 113.3(4) . .
C9 N2 C10 122.8(6) . .
C9 N2 Cu1 122.7(5) . .
C10 N2 Cu1 114.4(4) . .
O7 S1 O6 113.4(3) . .
O7 S1 O5 113.2(3) . .
O6 S1 O5 110.1(3) . .
O7 S1 C4 106.1(3) . .
O6 S1 C4 106.7(3) . .
O5 S1 C4 106.8(3) . .
S1 O5 Sr1 154.6(3) . 3_566
S1 O6 Sr1 152.2(3) . 1_565
C1 O1 Cu1 124.9(4) . .
C9 O2 Sr1 140.0(4) . 4_565
C11 O3 Cu1 116.3(4) . .
C11 O3 Sr1 96.1(4) . .
Cu1 O3 Sr1 145.3(2) . .
C11 O4 Sr1 155.3(4) . 3_656
C11 O4 Sr1 89.9(4) . .
Sr1 O4 Sr1 112.63(16) 3_656 .
Sr1 O8 H8D 105.7 . .
Sr1 O8 H8E 106.2 . .
H8D O8 H8E 106.3 . .
Sr1 O9 H9Y 109.3 . .
Sr1 O9 H9X 109.1 . .
H9Y O9 H9X 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O1 1.876(4) .
Cu1 N2 1.885(5) .
Cu1 N1 1.915(5) .
Cu1 O3 1.954(4) .
Sr1 O2 2.504(4) 4_566
Sr1 O4 2.520(4) 3_656
Sr1 O6 2.543(5) 1_545
Sr1 O5 2.576(4) 3_566
Sr1 O9 2.602(4) .
Sr1 O8 2.609(4) .
Sr1 O3 2.648(4) .
Sr1 O4 2.850(4) .
Sr1 C11 3.086(7) .
Sr1 H8D 2.9546 .
Sr1 H8E 2.9612 .
C1 O1 1.297(8) .
C1 C2 1.453(9) .
C1 C6 1.451(9) .
C2 C3 1.369(9) .
C2 H2 0.9300 .
C3 C4 1.354(9) .
C3 H3 0.9300 .
C4 C5 1.414(9) .
C4 S1 1.794(7) .
C5 C6 1.404(9) .
C5 H5 0.9300 .
C6 C7 1.421(9) .
C7 N1 1.235(8) .
C7 H7 0.9300 .
C8 N1 1.480(8) .
C8 C9 1.521(9) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 O2 1.247(8) .
C9 N2 1.255(8) .
C10 N2 1.484(8) .
C10 C11 1.531(9) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 O4 1.189(8) .
C11 O3 1.328(7) .
S1 O7 1.448(5) .
S1 O6 1.465(5) .
S1 O5 1.469(5) .
O5 Sr1 2.577(4) 3_566
O6 Sr1 2.543(5) 1_565
O2 Sr1 2.504(4) 4_565
O4 Sr1 2.520(4) 3_656
O8 H8D 0.8500 .
O8 H8E 0.8500 .
O9 H9Y 0.8500 .
O9 H9X 0.8500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O8 H8D O4 0.85 2.58 3.085(5) 120 .
O8 H8D O5 0.85 2.56 2.965(5) 111 1_645
O8 H8E O7 0.85 2.45 3.272(5) 162 1_645
O8 H8D O5 0.85 2.56 2.965(5) 111 1_645
O8 H8E S1 0.85 2.87 3.505(4) 134 1_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 178.8(6) . .
C6 C1 C2 C3 0.3(9) . .
C1 C2 C3 C4 -0.9(10) . .
C2 C3 C4 C5 0.8(10) . .
C2 C3 C4 S1 -173.2(5) . .
C3 C4 C5 C6 -0.2(10) . .
S1 C4 C5 C6 174.1(5) . .
C4 C5 C6 C7 -179.3(6) . .
C4 C5 C6 C1 -0.4(10) . .
O1 C1 C6 C5 -178.1(6) . .
C2 C1 C6 C5 0.3(9) . .
O1 C1 C6 C7 0.9(10) . .
C2 C1 C6 C7 179.3(6) . .
C5 C6 C7 N1 174.2(7) . .
C1 C6 C7 N1 -4.7(11) . .
N1 C8 C9 O2 177.2(6) . .
N1 C8 C9 N2 -2.5(8) . .
N2 C10 C11 O4 -177.9(6) . .
N2 C10 C11 O3 6.1(8) . .
N2 C10 C11 Sr1 67.1(16) . .
O2 Sr1 C11 O4 85.2(4) 4_566 .
O4 Sr1 C11 O4 -9.5(4) 3_656 .
O6 Sr1 C11 O4 -98.5(5) 1_545 .
O5 Sr1 C11 O4 -92.9(4) 3_566 .
O9 Sr1 C11 O4 169.0(4) . .
O8 Sr1 C11 O4 68.5(4) . .
O3 Sr1 C11 O4 167.3(7) . .
Sr1 Sr1 C11 O4 -6.6(3) 3_656 .
O2 Sr1 C11 O3 -82.1(4) 4_566 .
O4 Sr1 C11 O3 -176.9(4) 3_656 .
O6 Sr1 C11 O3 94.1(4) 1_545 .
O5 Sr1 C11 O3 99.7(4) 3_566 .
O9 Sr1 C11 O3 1.6(4) . .
O8 Sr1 C11 O3 -98.9(4) . .
O4 Sr1 C11 O3 -167.3(7) . .
Sr1 Sr1 C11 O3 -174.0(4) 3_656 .
O2 Sr1 C11 C10 -151.7(13) 4_566 .
O4 Sr1 C11 C10 113.5(14) 3_656 .
O6 Sr1 C11 C10 24.5(16) 1_545 .
O5 Sr1 C11 C10 30.1(14) 3_566 .
O9 Sr1 C11 C10 -68.0(14) . .
O8 Sr1 C11 C10 -168.5(14) . .
O3 Sr1 C11 C10 -69.7(14) . .
O4 Sr1 C11 C10 123.0(16) . .
Sr1 Sr1 C11 C10 116.4(15) 3_656 .
C6 C7 N1 C8 -176.4(6) . .
C6 C7 N1 Cu1 7.2(10) . .
C9 C8 N1 C7 -172.6(6) . .
C9 C8 N1 Cu1 4.2(6) . .
O1 Cu1 N1 C7 -5.1(6) . .
N2 Cu1 N1 C7 173.2(6) . .
O3 Cu1 N1 C7 -173.5(7) . .
O1 Cu1 N1 C8 178.3(4) . .
N2 Cu1 N1 C8 -3.5(4) . .
O3 Cu1 N1 C8 9.9(12) . .
O2 C9 N2 C10 4.7(12) . .
C8 C9 N2 C10 -175.7(6) . .
O2 C9 N2 Cu1 -180.0(6) . .
C8 C9 N2 Cu1 -0.3(8) . .
C11 C10 N2 C9 171.7(6) . .
C11 C10 N2 Cu1 -4.0(7) . .
N1 Cu1 N2 C9 2.3(6) . .
O3 Cu1 N2 C9 -174.7(6) . .
N1 Cu1 N2 C10 178.0(5) . .
O3 Cu1 N2 C10 1.0(4) . .
C3 C4 S1 O7 -13.1(6) . .
C5 C4 S1 O7 172.6(5) . .
C3 C4 S1 O6 108.2(6) . .
C5 C4 S1 O6 -66.1(6) . .
C3 C4 S1 O5 -134.1(6) . .
C5 C4 S1 O5 51.6(6) . .
O7 S1 O5 Sr1 -104.7(6) . 3_566
O6 S1 O5 Sr1 127.2(6) . 3_566
C4 S1 O5 Sr1 11.7(7) . 3_566
O7 S1 O6 Sr1 -173.7(5) . 1_565
O5 S1 O6 Sr1 -45.7(6) . 1_565
C4 S1 O6 Sr1 69.8(6) . 1_565
C2 C1 O1 Cu1 -178.6(4) . .
C6 C1 O1 Cu1 -0.3(9) . .
N1 Cu1 O1 C1 1.7(5) . .
O3 Cu1 O1 C1 179.1(5) . .
N2 C9 O2 Sr1 102.0(8) . 4_565
C8 C9 O2 Sr1 -77.6(8) . 4_565
O4 C11 O3 Cu1 178.6(5) . .
C10 C11 O3 Cu1 -5.6(7) . .
Sr1 C11 O3 Cu1 -167.2(4) . .
O4 C11 O3 Sr1 -14.3(7) . .
C10 C11 O3 Sr1 161.6(5) . .
O1 Cu1 O3 C11 -179.0(4) . .
N2 Cu1 O3 C11 2.7(5) . .
N1 Cu1 O3 C11 -10.6(11) . .
O1 Cu1 O3 Sr1 23.8(4) . .
N2 Cu1 O3 Sr1 -154.5(4) . .
N1 Cu1 O3 Sr1 -167.8(7) . .
O2 Sr1 O3 C11 118.8(4) 4_566 .
O4 Sr1 O3 C11 3.4(4) 3_656 .
O6 Sr1 O3 C11 -122.6(4) 1_545 .
O5 Sr1 O3 C11 -70.9(4) 3_566 .
O9 Sr1 O3 C11 -178.3(4) . .
O8 Sr1 O3 C11 75.9(4) . .
O4 Sr1 O3 C11 6.6(3) . .
Sr1 Sr1 O3 C11 4.9(3) 3_656 .
O2 Sr1 O3 Cu1 -81.6(4) 4_566 .
O4 Sr1 O3 Cu1 163.0(3) 3_656 .
O6 Sr1 O3 Cu1 37.0(5) 1_545 .
O5 Sr1 O3 Cu1 88.7(4) 3_566 .
O9 Sr1 O3 Cu1 -18.7(3) . .
O8 Sr1 O3 Cu1 -124.5(4) . .
O4 Sr1 O3 Cu1 166.1(5) . .
C11 Sr1 O3 Cu1 159.6(6) . .
Sr1 Sr1 O3 Cu1 164.5(4) 3_656 .
O3 C11 O4 Sr1 169.7(6) . 3_656
C10 C11 O4 Sr1 -5.8(15) . 3_656
Sr1 C11 O4 Sr1 156.6(11) . 3_656
O3 C11 O4 Sr1 13.1(7) . .
C10 C11 O4 Sr1 -162.4(6) . .
O2 Sr1 O4 C11 -114.6(4) 4_566 .
O4 Sr1 O4 C11 169.7(5) 3_656 .
O6 Sr1 O4 C11 116.7(4) 1_545 .
O5 Sr1 O4 C11 77.7(4) 3_566 .
O9 Sr1 O4 C11 -12.7(4) . .
O8 Sr1 O4 C11 -104.5(4) . .
O3 Sr1 O4 C11 -7.3(4) . .
Sr1 Sr1 O4 C11 169.7(5) 3_656 .
O2 Sr1 O4 Sr1 75.8(2) 4_566 3_656
O4 Sr1 O4 Sr1 0.0 3_656 3_656
O6 Sr1 O4 Sr1 -53.0(3) 1_545 3_656
O5 Sr1 O4 Sr1 -91.94(18) 3_566 3_656
O9 Sr1 O4 Sr1 177.63(15) . 3_656
O8 Sr1 O4 Sr1 85.86(18) . 3_656
O3 Sr1 O4 Sr1 -176.9(3) . 3_656
C11 Sr1 O4 Sr1 -169.7(5) . 3_656
