#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:29:49 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180437 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/06/7210697.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210697
loop_
_publ_author_name
'He, Xiang'
'Lu, Xiao-Peng'
'Ju, Zhan-Feng'
'Li, Chun-Ju'
'Zhang, Qi-Kai'
'Li, Ming-Xing'
_publ_section_title
;
 Syntheses, structures, and photoluminescent properties of ten
 metal--organic frameworks constructed by a flexible tetracarboxylate
 ligand
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2731
_journal_paper_doi               10.1039/c3ce26864k
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C28 H33 N4 O5 Zn, 3(O)'
_chemical_formula_sum            'C56 H66 N8 O16 Zn2'
_chemical_formula_weight         1237.91
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.534(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.3898(7)
_cell_length_b                   19.8601(14)
_cell_length_c                   17.9499(11)
_cell_measurement_temperature    293(2)
_cell_volume                     3134.7(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0360
_diffrn_reflns_av_sigmaI/netI    0.0473
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            19472
_diffrn_reflns_theta_full        27.54
_diffrn_reflns_theta_max         27.54
_diffrn_reflns_theta_min         2.32
_exptl_absorpt_coefficient_mu    0.835
_exptl_absorpt_correction_T_max  0.9439
_exptl_absorpt_correction_T_min  0.8992
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick,1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.312
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1292
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.357
_refine_diff_density_min         -0.471
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         7181
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0933
_refine_ls_R_factor_gt           0.0733
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1256P)²+4.1524P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2195
_refine_ls_wR_factor_ref         0.2376
_reflns_number_gt                5403
_reflns_number_total             7181
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce26864k.txt
_cod_data_source_block           a10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7210697
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 1.3929(5) 0.1575(2) 0.1880(3) 0.0400(9) Uani 1 1 d .
C2 C 1.4402(5) 0.1671(2) 0.1172(2) 0.0356(9) Uani 1 1 d .
C3 C 1.3603(5) 0.2106(2) 0.0559(2) 0.0364(9) Uani 1 1 d .
H3 H 1.2748 0.2330 0.0581 0.044 Uiso 1 1 calc R
C4 C 1.4073(5) 0.2208(2) -0.0081(2) 0.0386(9) Uani 1 1 d .
C5 C 1.3203(5) 0.2685(2) -0.0727(3) 0.0448(10) Uani 1 1 d .
C6 C 1.5312(6) 0.1848(2) -0.0140(3) 0.0475(11) Uani 1 1 d .
H6 H 1.5613 0.1906 -0.0577 0.057 Uiso 1 1 calc R
C7 C 1.6082(6) 0.1406(3) 0.0464(3) 0.0495(12) Uani 1 1 d .
C8 C 1.5649(5) 0.1324(2) 0.1122(3) 0.0462(11) Uani 1 1 d .
H8 H 1.6195 0.1035 0.1530 0.055 Uiso 1 1 calc R
C9 C 1.7675(7) 0.1022(3) -0.0235(3) 0.0669(17) Uani 1 1 d .
H9A H 1.8062 0.1460 -0.0307 0.080 Uiso 1 1 calc R
H9B H 1.6786 0.0922 -0.0698 0.080 Uiso 1 1 calc R
C10 C 1.8876(6) 0.0490(3) -0.0126(3) 0.0561(13) Uani 1 1 d .
C11 C 2.0406(6) 0.0676(3) 0.0091(3) 0.0612(14) Uani 1 1 d .
H11 H 2.0684 0.1128 0.0151 0.073 Uiso 1 1 calc R
C12 C 1.8502(6) -0.0180(3) -0.0217(3) 0.0632(15) Uani 1 1 d .
H12 H 1.7485 -0.0305 -0.0366 0.076 Uiso 1 1 calc R
C13 C 0.9670(6) 0.2621(3) 0.1608(3) 0.0596(14) Uani 1 1 d .
H13 H 1.0062 0.2418 0.1254 0.071 Uiso 1 1 calc R
C14 C 0.8543(7) 0.3093(3) 0.1317(4) 0.0701(17) Uani 1 1 d .
H14 H 0.8180 0.3197 0.0778 0.084 Uiso 1 1 calc R
C15 C 0.7946(6) 0.3413(3) 0.1826(4) 0.0605(14) Uani 1 1 d .
C16 C 0.8487(8) 0.3213(3) 0.2601(4) 0.0736(18) Uani 1 1 d .
H16 H 0.8094 0.3400 0.2963 0.088 Uiso 1 1 calc R
C17 C 0.9621(7) 0.2732(3) 0.2851(4) 0.0665(16) Uani 1 1 d .
H17 H 0.9975 0.2606 0.3384 0.080 Uiso 1 1 calc R
C18 C 0.6813(7) 0.3967(3) 0.1539(5) 0.0752(18) Uani 1 1 d .
H18A H 0.7344 0.4388 0.1552 0.090 Uiso 1 1 calc R
H18B H 0.6178 0.3879 0.0991 0.090 Uiso 1 1 calc R
C19 C 0.5051(7) 0.4678(3) 0.1892(5) 0.0700(18) Uani 1 1 d .
H19A H 0.4433 0.4722 0.1334 0.084 Uiso 1 1 calc R
H19B H 0.5787 0.5042 0.2031 0.084 Uiso 1 1 calc R
C20 C 0.4064(6) 0.4725(3) 0.2385(4) 0.0623(15) Uani 1 1 d .
H20A H 0.4689 0.4690 0.2943 0.075 Uiso 1 1 calc R
H20B H 0.3562 0.5160 0.2301 0.075 Uiso 1 1 calc R
C21 C 0.3712(6) 0.3543(3) 0.2317(4) 0.0649(16) Uani 1 1 d .
H21A H 0.2967 0.3183 0.2170 0.078 Uiso 1 1 calc R
H21B H 0.4320 0.3492 0.2876 0.078 Uiso 1 1 calc R
C22 C 0.4724(7) 0.3497(3) 0.1822(4) 0.0663(16) Uani 1 1 d .
H22A H 0.5237 0.3065 0.1912 0.080 Uiso 1 1 calc R
H22B H 0.4106 0.3528 0.1262 0.080 Uiso 1 1 calc R
C23 C 0.1960(6) 0.4227(3) 0.2654(4) 0.0656(16) Uani 1 1 d .
H23A H 0.2596 0.4235 0.3213 0.079 Uiso 1 1 calc R
H23B H 0.1357 0.3819 0.2562 0.079 Uiso 1 1 calc R
C24 C 0.0901(6) 0.4821(2) 0.2489(3) 0.0486(11) Uani 1 1 d .
C25 C 0.0509(7) 0.5199(3) 0.1804(4) 0.0696(17) Uani 1 1 d .
H25 H 0.0914 0.5093 0.1414 0.084 Uiso 1 1 calc R
C26 C -0.0481(7) 0.5736(3) 0.1691(3) 0.0648(16) Uani 1 1 d .
H26 H -0.0726 0.5982 0.1223 0.078 Uiso 1 1 calc R
C27 C -0.0761(7) 0.5540(3) 0.2871(3) 0.0615(15) Uani 1 1 d .
H27 H -0.1205 0.5651 0.3243 0.074 Uiso 1 1 calc R
C28 C 0.0206(8) 0.4997(3) 0.3027(3) 0.0684(17) Uani 1 1 d .
H28 H 0.0394 0.4749 0.3492 0.082 Uiso 1 1 calc R
N1 N 1.0231(4) 0.2440(2) 0.2366(2) 0.0472(9) Uani 1 1 d .
N2 N 0.5842(5) 0.4031(2) 0.2027(3) 0.0603(12) Uani 1 1 d .
N3 N 0.2931(4) 0.4198(2) 0.2186(3) 0.0523(11) Uani 1 1 d .
N4 N -0.1097(4) 0.59137(19) 0.2223(2) 0.0411(8) Uani 1 1 d .
O1 O 1.2683(4) 0.18502(15) 0.18361(19) 0.0441(7) Uani 1 1 d .
O2 O 1.4719(5) 0.1250(2) 0.2457(2) 0.0692(12) Uani 1 1 d .
O3 O 1.2149(5) 0.3021(2) -0.0662(3) 0.0745(13) Uani 1 1 d .
O4 O 1.3578(4) 0.27085(18) -0.13423(19) 0.0527(8) Uani 1 1 d .
O5 O 1.7293(5) 0.1017(2) 0.0459(2) 0.0699(12) Uani 1 1 d .
O6 O 0.1152(9) 0.4034(5) 0.0465(4) 0.166(3) Uani 1 1 d .
O7 O 0.1854(13) 0.5482(6) 0.0084(6) 0.223(5) Uani 1 1 d .
O9 O 0.0487(9) 0.7361(6) 0.0265(4) 0.175(4) Uani 1 1 d .
Zn1 Zn 1.21103(5) 0.18130(2) 0.27810(3) 0.03643(19) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 123.5(4) . .
O2 C1 C2 120.8(4) . .
O1 C1 C2 115.7(4) . .
C8 C2 C3 119.4(4) . .
C8 C2 C1 120.0(4) . .
C3 C2 C1 120.7(4) . .
C4 C3 C2 120.4(4) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C6 120.3(4) . .
C3 C4 C5 119.3(4) . .
C6 C4 C5 120.4(4) . .
O3 C5 O4 122.6(4) . .
O3 C5 C4 120.5(4) . .
O4 C5 C4 117.0(4) . .
C7 C6 C4 119.0(4) . .
C7 C6 H6 120.5 . .
C4 C6 H6 120.5 . .
O5 C7 C6 123.8(4) . .
O5 C7 C8 115.4(4) . .
C6 C7 C8 120.8(4) . .
C7 C8 C2 120.2(4) . .
C7 C8 H8 119.9 . .
C2 C8 H8 119.9 . .
O5 C9 C10 107.0(4) . .
O5 C9 H9A 110.3 . .
C10 C9 H9A 110.3 . .
O5 C9 H9B 110.3 . .
C10 C9 H9B 110.3 . .
H9A C9 H9B 108.6 . .
C12 C10 C11 118.9(5) . .
C12 C10 C9 121.0(5) . .
C11 C10 C9 120.0(6) . .
C12 C11 C10 119.2(6) 3_955 .
C12 C11 H11 120.4 3_955 .
C10 C11 H11 120.4 . .
C10 C12 C11 121.8(5) . 3_955
C10 C12 H12 119.1 . .
C11 C12 H12 119.1 3_955 .
N1 C13 C14 123.5(5) . .
N1 C13 H13 118.3 . .
C14 C13 H13 118.3 . .
C13 C14 C15 120.0(6) . .
C13 C14 H14 120.0 . .
C15 C14 H14 120.0 . .
C16 C15 C14 116.6(5) . .
C16 C15 C18 122.3(6) . .
C14 C15 C18 121.1(6) . .
C15 C16 C17 120.1(5) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
N1 C17 C16 123.2(6) . .
N1 C17 H17 118.4 . .
C16 C17 H17 118.4 . .
N2 C18 C15 111.9(5) . .
N2 C18 H18A 109.2 . .
C15 C18 H18A 109.2 . .
N2 C18 H18B 109.2 . .
C15 C18 H18B 109.2 . .
H18A C18 H18B 107.9 . .
N2 C19 C20 110.0(5) . .
N2 C19 H19A 109.7 . .
C20 C19 H19A 109.7 . .
N2 C19 H19B 109.7 . .
C20 C19 H19B 109.7 . .
H19A C19 H19B 108.2 . .
N3 C20 C19 111.4(5) . .
N3 C20 H20A 109.4 . .
C19 C20 H20A 109.4 . .
N3 C20 H20B 109.4 . .
C19 C20 H20B 109.4 . .
H20A C20 H20B 108.0 . .
N3 C21 C22 109.9(5) . .
N3 C21 H21A 109.7 . .
C22 C21 H21A 109.7 . .
N3 C21 H21B 109.7 . .
C22 C21 H21B 109.7 . .
H21A C21 H21B 108.2 . .
N2 C22 C21 110.9(5) . .
N2 C22 H22A 109.5 . .
C21 C22 H22A 109.5 . .
N2 C22 H22B 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 108.1 . .
N3 C23 C24 115.3(4) . .
N3 C23 H23A 108.5 . .
C24 C23 H23A 108.5 . .
N3 C23 H23B 108.5 . .
C24 C23 H23B 108.5 . .
H23A C23 H23B 107.5 . .
C25 C24 C28 116.1(4) . .
C25 C24 C23 123.8(5) . .
C28 C24 C23 120.1(5) . .
C24 C25 C26 120.5(5) . .
C24 C25 H25 119.8 . .
C26 C25 H25 119.8 . .
N4 C26 C25 122.8(5) . .
N4 C26 H26 118.6 . .
C25 C26 H26 118.6 . .
N4 C27 C28 123.9(5) . .
N4 C27 H27 118.1 . .
C28 C27 H27 118.1 . .
C27 C28 C24 119.7(5) . .
C27 C28 H28 120.2 . .
C24 C28 H28 120.2 . .
C13 N1 C17 116.5(5) . .
C13 N1 Zn1 120.9(3) . .
C17 N1 Zn1 122.3(4) . .
C22 N2 C19 108.7(4) . .
C22 N2 C18 109.3(5) . .
C19 N2 C18 111.3(5) . .
C20 N3 C23 112.7(5) . .
C20 N3 C21 108.6(4) . .
C23 N3 C21 108.9(4) . .
C27 N4 C26 117.0(4) . .
C27 N4 Zn1 117.8(3) . 2_655
C26 N4 Zn1 123.8(3) . 2_655
C1 O1 Zn1 117.3(3) . .
C5 O4 Zn1 112.8(3) . 4_565
C7 O5 C9 117.9(4) . .
O4 Zn1 O1 110.66(14) 4_566 .
O4 Zn1 N4 129.47(15) 4_566 2_645
O1 Zn1 N4 107.62(14) . 2_645
O4 Zn1 N1 105.70(16) 4_566 .
O1 Zn1 N1 97.13(14) . .
N4 Zn1 N1 100.89(16) 2_645 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.224(5) .
C1 O1 1.269(5) .
C1 C2 1.500(6) .
C2 C8 1.388(6) .
C2 C3 1.393(6) .
C3 C4 1.384(6) .
C3 H3 0.9300 .
C4 C6 1.400(6) .
C4 C5 1.499(6) .
C5 O3 1.233(6) .
C5 O4 1.272(5) .
C6 C7 1.385(6) .
C6 H6 0.9300 .
C7 O5 1.376(5) .
C7 C8 1.387(6) .
C8 H8 0.9300 .
C9 O5 1.411(6) .
C9 C10 1.507(7) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C12 1.373(9) .
C10 C11 1.400(8) .
C11 C12 1.382(7) 3_955
C11 H11 0.9300 .
C12 C11 1.382(7) 3_955
C12 H12 0.9300 .
C13 N1 1.325(6) .
C13 C14 1.372(7) .
C13 H13 0.9300 .
C14 C15 1.384(8) .
C14 H14 0.9300 .
C15 C16 1.362(9) .
C15 C18 1.491(8) .
C16 C17 1.383(8) .
C16 H16 0.9300 .
C17 N1 1.331(6) .
C17 H17 0.9300 .
C18 N2 1.475(7) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 N2 1.460(6) .
C19 C20 1.492(8) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 N3 1.445(7) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 N3 1.470(6) .
C21 C22 1.513(8) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 N2 1.447(7) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 N3 1.443(7) .
C23 C24 1.503(7) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C25 1.377(7) .
C24 C28 1.387(7) .
C25 C26 1.381(7) .
C25 H25 0.9300 .
C26 N4 1.326(6) .
C26 H26 0.9300 .
C27 N4 1.320(6) .
C27 C28 1.374(7) .
C27 H27 0.9300 .
C28 H28 0.9300 .
N1 Zn1 2.073(4) .
N4 Zn1 2.023(4) 2_655
O1 Zn1 1.952(3) .
O4 Zn1 1.938(3) 4_565
Zn1 O4 1.938(3) 4_566
Zn1 N4 2.022(4) 2_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O2 C1 C2 C8 7.9(7) .
O1 C1 C2 C8 -172.3(4) .
O2 C1 C2 C3 -172.1(5) .
O1 C1 C2 C3 7.7(6) .
C8 C2 C3 C4 -2.0(7) .
C1 C2 C3 C4 178.1(4) .
C2 C3 C4 C6 3.2(7) .
C2 C3 C4 C5 -179.3(4) .
C3 C4 C5 O3 5.2(7) .
C6 C4 C5 O3 -177.2(5) .
C3 C4 C5 O4 -172.8(4) .
C6 C4 C5 O4 4.8(7) .
C3 C4 C6 C7 -1.9(8) .
C5 C4 C6 C7 -179.4(5) .
C4 C6 C7 O5 178.5(5) .
C4 C6 C7 C8 -0.7(8) .
O5 C7 C8 C2 -177.4(5) .
C6 C7 C8 C2 1.9(8) .
C3 C2 C8 C7 -0.6(7) .
C1 C2 C8 C7 179.4(5) .
O5 C9 C10 C12 76.8(7) .
O5 C9 C10 C11 -101.3(6) .
C12 C10 C11 C12 -0.6(9) 3_955
C9 C10 C11 C12 177.7(5) 3_955
C11 C10 C12 C11 0.6(9) 3_955
C9 C10 C12 C11 -177.6(5) 3_955
N1 C13 C14 C15 0.9(10) .
C13 C14 C15 C16 -2.8(10) .
C13 C14 C15 C18 175.0(6) .
C14 C15 C16 C17 2.6(10) .
C18 C15 C16 C17 -175.2(6) .
C15 C16 C17 N1 -0.4(11) .
C16 C15 C18 N2 -27.8(9) .
C14 C15 C18 N2 154.6(6) .
N2 C19 C20 N3 -60.3(7) .
N3 C21 C22 N2 59.0(6) .
N3 C23 C24 C25 19.2(9) .
N3 C23 C24 C28 -163.6(6) .
C28 C24 C25 C26 2.2(10) .
C23 C24 C25 C26 179.5(6) .
C24 C25 C26 N4 0.0(11) .
N4 C27 C28 C24 0.6(10) .
C25 C24 C28 C27 -2.5(9) .
C23 C24 C28 C27 -179.9(6) .
C14 C13 N1 C17 1.3(9) .
C14 C13 N1 Zn1 -172.3(5) .
C16 C17 N1 C13 -1.6(9) .
C16 C17 N1 Zn1 172.0(5) .
C21 C22 N2 C19 -58.9(7) .
C21 C22 N2 C18 179.5(5) .
C20 C19 N2 C22 58.9(7) .
C20 C19 N2 C18 179.2(5) .
C15 C18 N2 C22 -76.1(7) .
C15 C18 N2 C19 163.8(5) .
C19 C20 N3 C23 179.8(5) .
C19 C20 N3 C21 59.0(6) .
C24 C23 N3 C20 68.5(7) .
C24 C23 N3 C21 -170.9(5) .
C22 C21 N3 C20 -57.6(6) .
C22 C21 N3 C23 179.3(5) .
C28 C27 N4 C26 1.7(9) .
C28 C27 N4 Zn1 -165.3(5) 2_655
C25 C26 N4 C27 -2.0(9) .
C25 C26 N4 Zn1 164.1(5) 2_655
O2 C1 O1 Zn1 5.5(6) .
C2 C1 O1 Zn1 -174.3(3) .
O3 C5 O4 Zn1 -10.6(7) 4_565
C4 C5 O4 Zn1 167.4(3) 4_565
C6 C7 O5 C9 -6.4(9) .
C8 C7 O5 C9 172.9(5) .
C10 C9 O5 C7 -172.4(5) .
C1 O1 Zn1 O4 62.9(3) 4_566
C1 O1 Zn1 N4 -83.4(3) 2_645
C1 O1 Zn1 N1 172.7(3) .
C13 N1 Zn1 O4 125.1(4) 4_566
C17 N1 Zn1 O4 -48.2(5) 4_566
C13 N1 Zn1 O1 11.2(4) .
C17 N1 Zn1 O1 -162.1(5) .
C13 N1 Zn1 N4 -98.3(4) 2_645
C17 N1 Zn1 N4 88.4(5) 2_645
