#------------------------------------------------------------------------------
#$Date: 2016-03-26 20:42:49 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180445 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/14/7211416.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211416
loop_
_publ_author_name
'Ma, Qi'
'Feng, Xuenan'
'Cao, Wei'
'Wang, Hailong'
'Jiang, Jianzhuang'
_publ_section_title
;
 Mixed (phthalocyanine)(Schiff-base) terbium(iii)--alkali
 metal(i)/zinc(ii) complexes: synthesis, structures, and spectroscopic
 properties
;
_journal_issue                   47
_journal_name_full               CrystEngComm
_journal_page_first              10383
_journal_paper_doi               10.1039/c3ce41619d
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C55 H38 N10 Na O5 Tb'
_chemical_formula_weight         1100.86
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           57
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2c 2b'
_symmetry_space_group_name_H-M   'P b c m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.3000(7)
_cell_length_b                   28.4450(3)
_cell_length_c                   18.8690(6)
_cell_measurement_reflns_used    10884
_cell_measurement_temperature    149.95(10)
_cell_measurement_theta_max      28.5316
_cell_measurement_theta_min      2.8586
_cell_volume                     4454.8(4)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      149.95(10)
_diffrn_detector_area_resol_mean 16.2141
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0449
_diffrn_reflns_av_sigmaI/netI    0.0257
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            30918
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.86
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.664
_exptl_absorpt_correction_T_max  0.9068
_exptl_absorpt_correction_T_min  0.4351
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.  
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.641
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2216
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.986
_refine_diff_density_min         -0.620
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         4038
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.106
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0273
_refine_ls_shift/su_max          0.184
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0239P)²+8.4154P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0615
_refine_ls_wR_factor_ref         0.0651
_reflns_number_gt                3473
_reflns_number_total             4038
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41619d.txt
_cod_data_source_block           TbNa1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      Pbcm
_cod_database_code               7211416
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z-1/2'
'-x, y-1/2, z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.5562(4) -0.03608(12) -0.2128(2) 0.0288(8) Uani 1 1 d .
H1 H -0.6203 -0.0576 -0.1886 0.035 Uiso 1 1 calc R
C2 C -0.4629(4) -0.00481(11) -0.17493(19) 0.0243(7) Uani 1 1 d .
H2 H -0.4643 -0.0045 -0.1256 0.029 Uiso 1 1 calc R
C3 C -0.3666(4) 0.02628(11) -0.21275(17) 0.0199(7) Uani 1 1 d .
C4 C -0.2521(4) 0.06235(11) -0.19108(17) 0.0189(7) Uani 1 1 d .
C5 C -0.1297(3) 0.10897(11) -0.10339(17) 0.0176(7) Uani 1 1 d .
C6 C -0.1202(4) 0.12484(11) -0.02987(17) 0.0198(7) Uani 1 1 d .
C7 C -0.1951(4) 0.10955(12) 0.03171(17) 0.0236(7) Uani 1 1 d .
H7 H -0.2637 0.0837 0.0315 0.028 Uiso 1 1 calc R
C8 C -0.1639(4) 0.13417(13) 0.09348(18) 0.0289(8) Uani 1 1 d .
H8 H -0.2130 0.1247 0.1354 0.035 Uiso 1 1 calc R
C9 C -0.0603(4) 0.17298(13) 0.09423(18) 0.0295(8) Uani 1 1 d .
H9 H -0.0411 0.1887 0.1366 0.035 Uiso 1 1 calc R
C10 C 0.0138(4) 0.18816(12) 0.03256(17) 0.0244(7) Uani 1 1 d .
H10 H 0.0824 0.2140 0.0328 0.029 Uiso 1 1 calc R
C11 C -0.0170(4) 0.16378(11) -0.02959(17) 0.0198(7) Uani 1 1 d .
C12 C 0.0340(4) 0.17044(11) -0.10321(16) 0.0176(7) Uani 1 1 d .
C13 C 0.1643(4) 0.21515(11) -0.19119(17) 0.0184(7) Uani 1 1 d .
C14 C 0.2563(4) 0.25654(11) -0.21285(16) 0.0182(7) Uani 1 1 d .
C15 C 0.3316(4) 0.29224(11) -0.17490(18) 0.0220(7) Uani 1 1 d .
H15 H 0.3295 0.2927 -0.1256 0.026 Uiso 1 1 calc R
C16 C 0.4100(4) 0.32718(11) -0.21292(18) 0.0248(7) Uani 1 1 d .
H16 H 0.4634 0.3510 -0.1887 0.030 Uiso 1 1 calc R
C17 C 0.5562(5) 0.20710(13) -0.0667(2) 0.0472(12) Uani 1 1 d .
H17A H 0.6084 0.2284 -0.0987 0.071 Uiso 1 1 calc R
H17B H 0.6320 0.1967 -0.0315 0.071 Uiso 1 1 calc R
H17C H 0.4679 0.2228 -0.0438 0.071 Uiso 1 1 calc R
C18 C 0.4189(4) 0.13346(12) -0.06652(18) 0.0260(8) Uani 1 1 d .
C19 C 0.4221(4) 0.12853(14) 0.00567(19) 0.0322(9) Uani 1 1 d .
H19 H 0.4751 0.1508 0.0332 0.039 Uiso 1 1 calc R
C20 C 0.3468(5) 0.09043(14) 0.03831(19) 0.0343(9) Uani 1 1 d .
H20 H 0.3496 0.0874 0.0874 0.041 Uiso 1 1 calc R
C21 C 0.2689(4) 0.05755(13) -0.00164(18) 0.0303(8) Uani 1 1 d .
H21 H 0.2253 0.0311 0.0202 0.036 Uiso 1 1 calc R
C22 C 0.2534(4) 0.06313(12) -0.07611(17) 0.0231(7) Uani 1 1 d .
C23 C 0.3292(4) 0.10200(11) -0.10970(17) 0.0200(7) Uani 1 1 d .
C24 C 0.1693(4) 0.02729(11) -0.11518(17) 0.0226(7) Uani 1 1 d .
H24 H 0.1531 -0.0013 -0.0923 0.027 Uiso 1 1 calc R
C25 C 0.0393(4) -0.00851(10) -0.21243(17) 0.0187(7) Uani 1 1 d .
C26 C -0.0341(4) -0.04550(11) -0.17685(19) 0.0249(7) Uani 1 1 d .
H26 H -0.0352 -0.0457 -0.1276 0.030 Uiso 1 1 calc R
C27 C -0.1052(4) -0.08188(12) -0.21353(19) 0.0293(8) Uani 1 1 d .
H27 H -0.1533 -0.1065 -0.1889 0.035 Uiso 1 1 calc R
C28 C 0.7655(10) 0.2444(3) -0.2500 0.091(3) Uani 1 2 d SDU
H28A H 0.6736 0.2625 -0.2352 0.136 Uiso 0.50 1 calc PR
H28B H 0.7966 0.2538 -0.2969 0.136 Uiso 0.50 1 calc PR
H28C H 0.8532 0.2498 -0.2179 0.136 Uiso 0.50 1 calc PR
N1 N -0.1823(5) 0.08253(13) -0.2500 0.0191(8) Uani 1 2 d S
N2 N -0.2269(3) 0.07364(9) -0.12321(14) 0.0197(6) Uani 1 1 d .
N3 N -0.0332(3) 0.13617(9) -0.14540(14) 0.0189(6) Uani 1 1 d .
N4 N 0.1287(3) 0.20609(9) -0.12318(13) 0.0184(6) Uani 1 1 d .
N5 N 0.1147(4) 0.19064(13) -0.2500 0.0180(8) Uani 1 2 d S
N6 N 0.1140(3) 0.03092(9) -0.17916(13) 0.0172(6) Uani 1 1 d .
O1 O 0.4975(3) 0.16759(8) -0.10505(13) 0.0311(6) Uani 1 1 d .
O2 O 0.3208(3) 0.10986(7) -0.17814(11) 0.0207(5) Uani 1 1 d .
O3 O 0.7259(6) 0.19647(17) -0.2500 0.0694(14) Uani 1 2 d SDU
H3A H 0.7947 0.1733 -0.2500 0.104 Uiso 1 2 d SRD
Na1 Na 0.5099(3) 0.14947(8) -0.2500 0.0446(6) Uani 1 2 d S
Tb1 Tb 0.10318(3) 0.104459(7) -0.2500 0.01580(8) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C1 121.2(2) . 6
C2 C1 H1 119.4 . .
C1 C1 H1 119.4 6 .
C1 C2 C3 117.9(3) . .
C1 C2 H2 121.1 . .
C3 C2 H2 121.1 . .
C2 C3 C3 120.9(2) . 6
C2 C3 C4 132.8(3) . .
C3 C3 C4 106.29(18) 6 .
N2 C4 N1 127.3(3) . .
N2 C4 C3 122.7(3) . .
N1 C4 C3 109.9(3) . .
N2 C5 N3 127.9(3) . .
N2 C5 C6 121.9(3) . .
N3 C5 C6 110.1(3) . .
C7 C6 C11 121.2(3) . .
C7 C6 C5 132.4(3) . .
C11 C6 C5 106.3(3) . .
C8 C7 C6 117.6(3) . .
C8 C7 H7 121.2 . .
C6 C7 H7 121.2 . .
C7 C8 C9 121.5(3) . .
C7 C8 H8 119.3 . .
C9 C8 H8 119.3 . .
C10 C9 C8 120.7(3) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 118.2(3) . .
C9 C10 H10 120.9 . .
C11 C10 H10 120.9 . .
C10 C11 C6 120.8(3) . .
C10 C11 C12 133.2(3) . .
C6 C11 C12 106.0(3) . .
N4 C12 N3 127.7(3) . .
N4 C12 C11 122.4(3) . .
N3 C12 C11 109.9(3) . .
N4 C13 N5 127.5(3) . .
N4 C13 C14 122.5(3) . .
N5 C13 C14 109.8(3) . .
C15 C14 C14 120.99(19) . 6
C15 C14 C13 132.8(3) . .
C14 C14 C13 106.24(17) 6 .
C16 C15 C14 117.9(3) . .
C16 C15 H15 121.1 . .
C14 C15 H15 121.1 . .
C15 C16 C16 121.14(19) . 6
C15 C16 H16 119.4 . .
C16 C16 H16 119.4 6 .
O1 C17 H17A 109.5 . .
O1 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
O1 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 O1 126.0(3) . .
C19 C18 C23 121.1(3) . .
O1 C18 C23 112.9(3) . .
C18 C19 C20 120.7(3) . .
C18 C19 H19 119.7 . .
C20 C19 H19 119.7 . .
C21 C20 C19 120.1(3) . .
C21 C20 H20 120.0 . .
C19 C20 H20 120.0 . .
C20 C21 C22 120.9(4) . .
C20 C21 H21 119.6 . .
C22 C21 H21 119.6 . .
C21 C22 C23 119.2(3) . .
C21 C22 C24 118.1(3) . .
C23 C22 C24 122.5(3) . .
O2 C23 C18 119.0(3) . .
O2 C23 C22 123.2(3) . .
C18 C23 C22 117.8(3) . .
N6 C24 C22 126.4(3) . .
N6 C24 H24 116.8 . .
C22 C24 H24 116.8 . .
C26 C25 C25 118.9(2) . 6
C26 C25 N6 125.0(3) . .
C25 C25 N6 116.10(16) 6 .
C27 C26 C25 120.9(3) . .
C27 C26 H26 119.5 . .
C25 C26 H26 119.5 . .
C27 C27 C26 120.2(2) 6 .
C27 C27 H27 119.9 6 .
C26 C27 H27 119.9 . .
O3 C28 H28A 109.5 . .
O3 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
O3 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C4 N1 C4 107.5(4) 6 .
C4 N1 Tb1 120.8(2) 6 .
C4 N1 Tb1 120.8(2) . .
C4 N2 C5 122.8(3) . .
C5 N3 C12 107.6(3) . .
C5 N3 Tb1 122.01(19) . .
C12 N3 Tb1 122.7(2) . .
C12 N4 C13 123.0(3) . .
C13 N5 C13 107.8(4) 6 .
C13 N5 Tb1 121.24(19) 6 .
C13 N5 Tb1 121.24(19) . .
C24 N6 C25 120.1(3) . .
C24 N6 Tb1 125.5(2) . .
C25 N6 Tb1 114.16(18) . .
C18 O1 C17 116.8(3) . .
C18 O1 Na1 113.91(19) . .
C17 O1 Na1 129.3(2) . .
C23 O2 Tb1 128.3(2) . .
C23 O2 Na1 127.7(2) . .
Tb1 O2 Na1 102.64(9) . .
C28 O3 Na1 140.3(5) . .
C28 O3 H3A 125.5 . .
Na1 O3 H3A 94.2 . .
O3 Na1 O2 144.93(6) . .
O3 Na1 O2 144.93(6) . 6
O2 Na1 O2 70.12(12) . 6
O3 Na1 O1 85.35(7) . 6
O2 Na1 O1 128.89(11) . 6
O2 Na1 O1 59.98(7) 6 6
O3 Na1 O1 85.35(7) . .
O2 Na1 O1 59.98(7) . .
O2 Na1 O1 128.89(11) 6 .
O1 Na1 O1 158.23(14) 6 .
O3 Na1 Tb1 164.05(16) . .
O2 Na1 Tb1 37.72(6) . .
O2 Na1 Tb1 37.72(6) 6 .
O1 Na1 Tb1 91.78(7) 6 .
O1 Na1 Tb1 91.78(7) . .
O3 Na1 H3A 20.7 . .
O2 Na1 H3A 140.4 . .
O2 Na1 H3A 140.4 6 .
O1 Na1 H3A 89.1 6 .
O1 Na1 H3A 89.1 . .
Tb1 Na1 H3A 175.2 . .
O2 Tb1 O2 73.59(11) . 6
O2 Tb1 N3 145.79(8) . 6
O2 Tb1 N3 82.01(8) 6 6
O2 Tb1 N3 82.01(8) . .
O2 Tb1 N3 145.79(8) 6 .
N3 Tb1 N3 107.51(12) 6 .
O2 Tb1 N1 142.08(6) . .
O2 Tb1 N1 142.08(6) 6 .
N3 Tb1 N1 69.31(7) 6 .
N3 Tb1 N1 69.31(7) . .
O2 Tb1 N5 84.33(9) . .
O2 Tb1 N5 84.33(9) 6 .
N3 Tb1 N5 69.49(7) 6 .
N3 Tb1 N5 69.49(7) . .
N1 Tb1 N5 106.98(12) . .
O2 Tb1 N6 110.52(8) . 6
O2 Tb1 N6 72.90(8) 6 6
N3 Tb1 N6 83.87(8) 6 6
N3 Tb1 N6 139.56(8) . 6
N1 Tb1 N6 79.67(9) . 6
N5 Tb1 N6 147.15(6) . 6
O2 Tb1 N6 72.90(8) . .
O2 Tb1 N6 110.52(8) 6 .
N3 Tb1 N6 139.56(8) 6 .
N3 Tb1 N6 83.87(8) . .
N1 Tb1 N6 79.67(9) . .
N5 Tb1 N6 147.15(6) . .
N6 Tb1 N6 65.11(11) 6 .
O2 Tb1 Na1 39.64(6) . .
O2 Tb1 Na1 39.64(6) 6 .
N3 Tb1 Na1 107.56(6) 6 .
N3 Tb1 Na1 107.56(6) . .
N1 Tb1 Na1 173.98(9) . .
N5 Tb1 Na1 67.01(9) . .
N6 Tb1 Na1 105.35(7) 6 .
N6 Tb1 Na1 105.35(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.379(5) .
C1 C1 1.405(7) 6
C1 H1 0.9300 .
C2 C3 1.389(4) .
C2 H2 0.9300 .
C3 C3 1.406(7) 6
C3 C4 1.457(4) .
C4 N2 1.337(4) .
C4 N1 1.379(4) .
C5 N2 1.342(4) .
C5 N3 1.367(4) .
C5 C6 1.461(4) .
C6 C7 1.388(4) .
C6 C11 1.400(5) .
C7 C8 1.384(5) .
C7 H7 0.9300 .
C8 C9 1.399(5) .
C8 H8 0.9300 .
C9 C10 1.385(5) .
C9 H9 0.9300 .
C10 C11 1.386(4) .
C10 H10 0.9300 .
C11 C12 1.465(4) .
C12 N4 1.337(4) .
C12 N3 1.376(4) .
C13 N4 1.342(4) .
C13 N5 1.374(4) .
C13 C14 1.462(4) .
C14 C15 1.391(4) .
C14 C14 1.402(6) 6
C15 C16 1.388(5) .
C15 H15 0.9300 .
C16 C16 1.399(7) 6
C16 H16 0.9300 .
C17 O1 1.423(4) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.370(5) .
C18 O1 1.377(4) .
C18 C23 1.421(5) .
C19 C20 1.395(6) .
C19 H19 0.9300 .
C20 C21 1.364(5) .
C20 H20 0.9300 .
C21 C22 1.420(5) .
C21 H21 0.9300 .
C22 C23 1.421(5) .
C22 C24 1.439(5) .
C23 O2 1.312(4) .
C24 N6 1.296(4) .
C24 H24 0.9300 .
C25 C26 1.389(4) .
C25 C25 1.418(6) 6
C25 N6 1.427(4) .
C26 C27 1.378(5) .
C26 H26 0.9300 .
C27 C27 1.376(7) 6
C27 H27 0.9300 .
C28 O3 1.403(9) .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
N1 C4 1.379(4) 6
N1 Tb1 2.450(4) .
N3 Tb1 2.447(3) .
N5 C13 1.374(4) 6
N5 Tb1 2.453(4) .
N6 Tb1 2.484(2) .
O1 Na1 2.785(3) .
O2 Tb1 2.264(2) .
O2 Na1 2.360(3) .
O3 Na1 2.236(5) .
O3 H3A 0.8718 .
Na1 O2 2.360(3) 6
Na1 O1 2.785(3) 6
Na1 Tb1 3.611(2) .
Na1 H3A 2.4595 .
Tb1 O2 2.264(2) 6
Tb1 N3 2.447(3) 6
Tb1 N6 2.484(2) 6
