#------------------------------------------------------------------------------
#$Date: 2016-03-26 20:46:48 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180448 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/17/7211794.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211794
loop_
_publ_author_name
'Farnum, Gregory A.'
'Nettleman, Joseph H.'
'LaDuca, Robert L.'
_publ_section_title
;
 Structure and physical properties of substituted malonate divalent metal
 coordination polymers with dipyridylamine co-ligands: acentric chain,
 herringbone layer, and novel binodal network topologies
;
_journal_issue                   3
_journal_name_full               CrystEngComm
_journal_page_first              888
_journal_paper_doi               10.1039/b914746b
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C40 H43 Cl2 Cu3 N9 O18'
_chemical_formula_weight         1199.36
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2009-06-09 # Formatted by publCIF
;
_cell_angle_alpha                90.00
_cell_angle_beta                 127.7640(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   29.090(4)
_cell_length_b                   9.1837(11)
_cell_length_c                   21.114(3)
_cell_measurement_temperature    173(2)
_cell_volume                     4459.2(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.931
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0367
_diffrn_reflns_av_sigmaI/netI    0.0328
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            24094
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.26
_diffrn_reflns_theta_min         1.77
_exptl_absorpt_coefficient_mu    1.627
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6590
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.781
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2428
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.35
_refine_diff_density_max         0.837
_refine_diff_density_min         -0.767
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         5143
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0531
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0462P)²+16.5218P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0961
_refine_ls_wR_factor_ref         0.1025
_reflns_number_gt                4206
_reflns_number_total             5143
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b914746b.txt
_cod_data_source_block           c2c
_cod_original_cell_volume        4459.1(10)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7211794
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.250188(14) -0.21747(4) 0.28985(2) 0.01180(10) Uani 1 1 d . . .
Cu2 Cu 0.2500 -0.2500 0.5000 0.01128(12) Uani 1 2 d S . .
C1 C -0.12349(14) -0.2353(4) -0.0857(2) 0.0251(7) Uani 1 1 d . . .
H1 H -0.1314 -0.1447 -0.1101 0.030 Uiso 1 1 calc R . .
C2 C -0.06698(14) -0.2644(4) -0.0201(2) 0.0266(7) Uani 1 1 d . . .
H2 H -0.0380 -0.1948 -0.0009 0.032 Uiso 1 1 calc R . .
C3 C -0.05410(12) -0.4003(3) 0.01684(17) 0.0165(6) Uani 1 1 d . . .
C4 C -0.10060(12) -0.4967(3) -0.01357(17) 0.0168(6) Uani 1 1 d . . .
H4 H -0.0944 -0.5871 0.0104 0.020 Uiso 1 1 calc R . .
C5 C -0.15502(12) -0.4573(3) -0.07857(17) 0.0167(6) Uani 1 1 d . . .
H5 H -0.1852 -0.5231 -0.0978 0.020 Uiso 1 1 calc R . .
C8 C 0.05526(12) -0.3949(3) 0.12231(17) 0.0152(6) Uani 1 1 d . . .
C7 C 0.07056(13) -0.2700(3) 0.1020(2) 0.0244(7) Uani 1 1 d . . .
H7 H 0.0423 -0.2144 0.0579 0.029 Uiso 1 1 calc R . .
C9 C 0.10062(13) -0.4759(3) 0.18794(18) 0.0193(6) Uani 1 1 d . . .
H9 H 0.0926 -0.5629 0.2019 0.023 Uiso 1 1 calc R . .
C6 C 0.12821(14) -0.2295(3) 0.14792(19) 0.0229(7) Uani 1 1 d . . .
H6 H 0.1379 -0.1465 0.1332 0.028 Uiso 1 1 calc R . .
C11 C 0.34346(12) -0.0346(3) 0.59363(17) 0.0157(6) Uani 1 1 d . . .
H11 H 0.3120 0.0289 0.5682 0.019 Uiso 1 1 calc R . .
C12 C 0.39807(13) 0.0212(3) 0.65109(17) 0.0170(6) Uani 1 1 d . . .
H12 H 0.4029 0.1200 0.6631 0.020 Uiso 1 1 calc R . .
C13 C 0.44632(12) -0.0721(3) 0.69129(17) 0.0154(6) Uani 1 1 d . . .
C14 C 0.43638(13) -0.2174(3) 0.66673(18) 0.0174(6) Uani 1 1 d . . .
H14 H 0.4672 -0.2825 0.6894 0.021 Uiso 1 1 calc R . .
C15 C 0.37995(13) -0.2631(3) 0.60807(18) 0.0175(6) Uani 1 1 d . . .
H15 H 0.3741 -0.3603 0.5925 0.021 Uiso 1 1 calc R . .
C10 C 0.15647(13) -0.4265(3) 0.23107(18) 0.0189(6) Uani 1 1 d . . .
H10 H 0.1857 -0.4804 0.2751 0.023 Uiso 1 1 calc R . .
C51 C 0.21803(11) -0.0630(3) 0.38242(16) 0.0114(5) Uani 1 1 d . . .
C52 C 0.19441(12) 0.0769(3) 0.33197(17) 0.0144(6) Uani 1 1 d . . .
C53 C 0.21667(11) 0.1060(3) 0.28258(16) 0.0128(5) Uani 1 1 d . . .
C54 C 0.20642(19) 0.2068(3) 0.3852(2) 0.0310(8) Uani 1 1 d . . .
H54A H 0.1915 0.2938 0.3533 0.046 Uiso 1 1 calc R . .
H54B H 0.2476 0.2165 0.4262 0.046 Uiso 1 1 calc R . .
H54C H 0.1877 0.1919 0.4095 0.046 Uiso 1 1 calc R . .
C55 C 0.12753(13) 0.0531(4) 0.2695(2) 0.0268(7) Uani 1 1 d . . .
H55A H 0.1101 0.1375 0.2359 0.040 Uiso 1 1 calc R . .
H55B H 0.1112 0.0376 0.2970 0.040 Uiso 1 1 calc R . .
H55C H 0.1201 -0.0305 0.2372 0.040 Uiso 1 1 calc R . .
O1W O 0.2929(3) 0.4956(7) 0.4142(4) 0.138(2) Uani 1 1 d . . .
O1 O 0.22686(9) 0.2391(2) 0.27825(12) 0.0162(4) Uani 1 1 d . . .
O4 O 0.22954(8) -0.1778(2) 0.36231(12) 0.0146(4) Uani 1 1 d . . .
O3 O 0.22313(8) -0.0600(2) 0.44660(11) 0.0141(4) Uani 1 1 d . . .
O2 O 0.22074(9) 0.0063(2) 0.24648(12) 0.0154(4) Uani 1 1 d . . .
N1 N -0.16759(10) -0.3286(3) -0.11648(14) 0.0152(5) Uani 1 1 d . . .
N2 N -0.00010(11) -0.4512(3) 0.08190(16) 0.0209(5) Uani 1 1 d D . .
H2N H -0.0015(15) -0.538(3) 0.098(2) 0.025 Uiso 1 1 d D . .
N4 N 0.33304(10) -0.1761(3) 0.57211(14) 0.0139(5) Uani 1 1 d . . .
N5 N 0.5000 -0.0105(4) 0.7500 0.0185(7) Uani 1 2 d SD . .
H5N H 0.5000 0.085(2) 0.7500 0.022 Uiso 1 2 d SD . .
N3 N 0.17114(10) -0.3033(3) 0.21270(14) 0.0149(5) Uani 1 1 d . . .
Cl1 Cl 0.03492(4) 0.12941(9) 0.39273(5) 0.0303(2) Uani 1 1 d . . .
O5A O 0.0071(4) 0.2687(10) 0.3547(4) 0.0312(15) Uani 0.70 1 d P A 1
O6A O 0.0240(4) 0.0305(7) 0.3358(4) 0.066(2) Uani 0.70 1 d P A 1
O7A O 0.0103(3) 0.0753(7) 0.4302(4) 0.0633(16) Uani 0.70 1 d P A 1
O8A O 0.0942(3) 0.1554(8) 0.4544(4) 0.070(2) Uani 0.70 1 d P A 1
O5B O 0.0931(8) 0.1352(19) 0.4126(17) 0.113(10) Uani 0.30 1 d P A 2
O6B O 0.0064(7) -0.0014(15) 0.3530(12) 0.074(6) Uani 0.30 1 d P A 2
O7B O 0.0016(14) 0.251(3) 0.358(2) 0.100(12) Uani 0.30 1 d P A 2
O8B O 0.0485(13) 0.115(3) 0.4670(10) 0.129(10) Uani 0.30 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 O4 177.79(8) 4_545 .
O1 Cu1 N3 93.48(9) 4_545 .
O4 Cu1 N3 87.73(9) . .
O1 Cu1 N1 91.72(9) 4_545 8_546
O4 Cu1 N1 86.70(9) . 8_546
N3 Cu1 N1 166.41(10) . 8_546
O1 Cu1 O2 96.06(8) 4_545 .
O4 Cu1 O2 85.69(8) . .
N3 Cu1 O2 93.95(9) . .
N1 Cu1 O2 97.98(9) 8_546 .
O3 Cu2 O3 180.0 7_546 .
O3 Cu2 N4 89.68(9) 7_546 .
O3 Cu2 N4 90.33(9) . .
O3 Cu2 N4 90.32(9) 7_546 7_546
O3 Cu2 N4 89.67(9) . 7_546
N4 Cu2 N4 179.997(1) . 7_546
N1 C1 C2 124.3(3) . .
C1 C2 C3 118.7(3) . .
N2 C3 C2 127.4(3) . .
N2 C3 C4 115.5(3) . .
C2 C3 C4 117.1(3) . .
C5 C4 C3 119.5(3) . .
N1 C5 C4 123.8(3) . .
N2 C8 C7 126.2(3) . .
N2 C8 C9 116.5(3) . .
C7 C8 C9 117.2(3) . .
C6 C7 C8 119.1(3) . .
C10 C9 C8 119.8(3) . .
N3 C6 C7 123.7(3) . .
N4 C11 C12 123.7(3) . .
C11 C12 C13 119.5(3) . .
N5 C13 C14 125.9(3) . .
N5 C13 C12 116.9(3) . .
C14 C13 C12 117.2(3) . .
C15 C14 C13 119.0(3) . .
N4 C15 C14 124.2(3) . .
N3 C10 C9 123.0(3) . .
O4 C51 O3 119.9(2) . .
O4 C51 C52 124.5(2) . .
O3 C51 C52 115.6(2) . .
C54 C52 C51 109.9(2) . .
C54 C52 C53 111.0(2) . .
C51 C52 C53 114.6(2) . .
C54 C52 C55 109.7(3) . .
C51 C52 C55 105.4(2) . .
C53 C52 C55 105.9(2) . .
O2 C53 O1 123.3(3) . .
O2 C53 C52 121.4(2) . .
O1 C53 C52 115.2(2) . .
C53 O1 Cu1 116.51(18) . 4
C51 O4 Cu1 133.01(18) . .
C51 O3 Cu2 109.80(17) . .
C53 O2 Cu1 126.34(18) . .
C1 N1 C5 116.4(3) . .
C1 N1 Cu1 123.7(2) . 8_445
C5 N1 Cu1 119.83(19) . 8_445
C8 N2 C3 132.1(3) . .
C15 N4 C11 116.2(2) . .
C15 N4 Cu2 123.7(2) . .
C11 N4 Cu2 119.64(19) . .
C13 N5 C13 131.8(4) . 2_656
C6 N3 C10 117.2(3) . .
C6 N3 Cu1 121.5(2) . .
C10 N3 Cu1 120.5(2) . .
O7B Cl1 O8B 107.7(17) . .
O7B Cl1 O6A 111.5(14) . .
O8B Cl1 O6A 133.1(10) . .
O7B Cl1 O8A 115.1(14) . .
O8B Cl1 O8A 68.1(13) . .
O6A Cl1 O8A 114.6(4) . .
O7B Cl1 O6B 114.5(15) . .
O8B Cl1 O6B 104.3(14) . .
O6A Cl1 O6B 35.2(7) . .
O8A Cl1 O6B 129.7(7) . .
O7B Cl1 O7A 98.2(14) . .
O8B Cl1 O7A 39.5(12) . .
O6A Cl1 O7A 109.0(4) . .
O8A Cl1 O7A 106.8(4) . .
O6B Cl1 O7A 73.9(8) . .
O7B Cl1 O5A 10.3(17) . .
O8B Cl1 O5A 113.0(10) . .
O6A Cl1 O5A 110.0(4) . .
O8A Cl1 O5A 108.2(5) . .
O6B Cl1 O5A 119.5(8) . .
O7A Cl1 O5A 108.0(4) . .
O7B Cl1 O5B 116.2(15) . .
O8B Cl1 O5B 101.7(16) . .
O6A Cl1 O5B 83.3(10) . .
O8A Cl1 O5B 35.6(10) . .
O6B Cl1 O5B 110.9(11) . .
O7A Cl1 O5B 136.5(10) . .
O5A Cl1 O5B 106.1(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O1 1.962(2) 4_545
Cu1 O4 1.9900(19) .
Cu1 N3 1.993(2) .
Cu1 N1 2.004(2) 8_546
Cu1 O2 2.199(2) .
Cu2 O3 1.9617(19) 7_546
Cu2 O3 1.9617(19) .
Cu2 N4 2.027(2) .
Cu2 N4 2.027(2) 7_546
C1 N1 1.334(4) .
C1 C2 1.379(4) .
C2 C3 1.396(4) .
C3 N2 1.389(4) .
C3 C4 1.401(4) .
C4 C5 1.364(4) .
C5 N1 1.346(4) .
C8 N2 1.380(4) .
C8 C7 1.390(4) .
C8 C9 1.405(4) .
C7 C6 1.378(4) .
C9 C10 1.364(4) .
C6 N3 1.340(4) .
C11 N4 1.348(4) .
C11 C12 1.377(4) .
C12 C13 1.402(4) .
C13 N5 1.387(3) .
C13 C14 1.396(4) .
C14 C15 1.384(4) .
C15 N4 1.345(4) .
C10 N3 1.348(4) .
C51 O4 1.256(3) .
C51 O3 1.270(3) .
C51 C52 1.537(4) .
C52 C54 1.525(4) .
C52 C53 1.551(4) .
C52 C55 1.559(4) .
C53 O2 1.243(3) .
C53 O1 1.274(3) .
O1 Cu1 1.961(2) 4
N1 Cu1 2.004(2) 8_445
N5 C13 1.387(3) 2_656
Cl1 O7B 1.36(3) .
Cl1 O8B 1.370(17) .
Cl1 O6A 1.380(6) .
Cl1 O8A 1.406(6) .
Cl1 O6B 1.409(13) .
Cl1 O7A 1.443(6) .
Cl1 O5A 1.463(9) .
Cl1 O5B 1.473(14) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2N O5A 0.876(18) 2.09(2) 2.964(9) 173(3) 2_545
N2 H2N O7B 0.876(18) 2.15(4) 3.02(3) 178(4) 2_545
N5 H5N O5A 0.88(2) 2.484(13) 3.049(9) 122.7(4) 8_556
N5 H5N O5A 0.88(2) 2.484(13) 3.049(9) 122.7(4) 7_556
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 0.6(6) . .
C1 C2 C3 N2 178.5(3) . .
C1 C2 C3 C4 -2.7(5) . .
N2 C3 C4 C5 -178.5(3) . .
C2 C3 C4 C5 2.5(4) . .
C3 C4 C5 N1 -0.2(5) . .
N2 C8 C7 C6 -178.9(3) . .
C9 C8 C7 C6 -2.1(5) . .
N2 C8 C9 C10 -179.6(3) . .
C7 C8 C9 C10 3.4(4) . .
C8 C7 C6 N3 -0.9(5) . .
N4 C11 C12 C13 -0.9(4) . .
C11 C12 C13 N5 -178.4(2) . .
C11 C12 C13 C14 3.9(4) . .
N5 C13 C14 C15 178.9(2) . .
C12 C13 C14 C15 -3.5(4) . .
C13 C14 C15 N4 0.2(5) . .
C8 C9 C10 N3 -1.7(5) . .
O4 C51 C52 C54 -159.2(3) . .
O3 C51 C52 C54 24.1(3) . .
O4 C51 C52 C53 -33.4(4) . .
O3 C51 C52 C53 149.9(2) . .
O4 C51 C52 C55 82.7(3) . .
O3 C51 C52 C55 -94.0(3) . .
C54 C52 C53 O2 167.0(3) . .
C51 C52 C53 O2 41.8(4) . .
C55 C52 C53 O2 -74.0(3) . .
C54 C52 C53 O1 -16.9(3) . .
C51 C52 C53 O1 -142.2(2) . .
C55 C52 C53 O1 102.1(3) . .
O2 C53 O1 Cu1 0.1(3) . 4
C52 C53 O1 Cu1 -175.82(17) . 4
O3 C51 O4 Cu1 -158.91(19) . .
C52 C51 O4 Cu1 24.5(4) . .
O1 Cu1 O4 C51 129(2) 4_545 .
N3 Cu1 O4 C51 -107.7(3) . .
N1 Cu1 O4 C51 84.7(3) 8_546 .
O2 Cu1 O4 C51 -13.6(2) . .
O4 C51 O3 Cu2 0.3(3) . .
C52 C51 O3 Cu2 177.19(17) . .
O3 Cu2 O3 C51 -152(4) 7_546 .
N4 Cu2 O3 C51 96.94(18) . .
N4 Cu2 O3 C51 -83.06(18) 7_546 .
O1 C53 O2 Cu1 145.2(2) . .
C52 C53 O2 Cu1 -39.1(3) . .
O1 Cu1 O2 C53 -157.5(2) 4_545 .
O4 Cu1 O2 C53 21.2(2) . .
N3 Cu1 O2 C53 108.6(2) . .
N1 Cu1 O2 C53 -64.9(2) 8_546 .
C2 C1 N1 C5 1.7(5) . .
C2 C1 N1 Cu1 178.4(3) . 8_445
C4 C5 N1 C1 -1.9(4) . .
C4 C5 N1 Cu1 -178.8(2) . 8_445
C7 C8 N2 C3 -4.7(5) . .
C9 C8 N2 C3 178.6(3) . .
C2 C3 N2 C8 -8.1(6) . .
C4 C3 N2 C8 173.0(3) . .
C14 C15 N4 C11 2.8(4) . .
C14 C15 N4 Cu2 -169.6(2) . .
C12 C11 N4 C15 -2.5(4) . .
C12 C11 N4 Cu2 170.3(2) . .
O3 Cu2 N4 C15 24.0(2) 7_546 .
O3 Cu2 N4 C15 -156.0(2) . .
N4 Cu2 N4 C15 120(4) 7_546 .
O3 Cu2 N4 C11 -148.1(2) 7_546 .
O3 Cu2 N4 C11 31.9(2) . .
N4 Cu2 N4 C11 -52(4) 7_546 .
C14 C13 N5 C13 -14.4(2) . 2_656
C12 C13 N5 C13 168.1(3) . 2_656
C7 C6 N3 C10 2.6(5) . .
C7 C6 N3 Cu1 -166.4(3) . .
C9 C10 N3 C6 -1.3(4) . .
C9 C10 N3 Cu1 167.8(2) . .
O1 Cu1 N3 C6 -79.6(2) 4_545 .
O4 Cu1 N3 C6 102.3(2) . .
N1 Cu1 N3 C6 168.1(4) 8_546 .
O2 Cu1 N3 C6 16.8(2) . .
O1 Cu1 N3 C10 111.8(2) 4_545 .
O4 Cu1 N3 C10 -66.4(2) . .
N1 Cu1 N3 C10 -0.5(6) 8_546 .
O2 Cu1 N3 C10 -151.9(2) . .
