#------------------------------------------------------------------------------
#$Date: 2016-03-26 20:48:18 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180449 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/18/7211816.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211816
loop_
_publ_author_name
'Qiu, Yongcai'
'Liu, Zhihui'
'Mou, Jixia'
'Deng, Hong'
'Zeller, Matthias'
_publ_section_title
;
 Rationally designed and controlled syntheses of different series of
 4d--4f heterometallic coordination frameworks based on lanthanide
 carboxylate and Ag(IN)2 substructures
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              277
_journal_paper_doi               10.1039/b915025k
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C54 H56 Ag4 Cl2 Lu3 N8 O37'
_chemical_formula_weight         2436.36
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                86.038(1)
_cell_angle_beta                 83.144(1)
_cell_angle_gamma                84.315(1)
_cell_formula_units_Z            2
_cell_length_a                   14.3880(2)
_cell_length_b                   15.0923(2)
_cell_length_c                   17.3671(2)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.00
_cell_measurement_theta_min      1.36
_cell_volume                     3719.58(8)
_computing_cell_refinement       'Apex2 v2.1-4'
_computing_data_collection       'Apex2 v2.1-4 (Bruker, 2007)'
_computing_data_reduction        'Apex2 v2.1-4'
_computing_molecular_graphics    'SHELXTL 6.14'
_computing_publication_material  'SHELXTL 6.14'
_computing_structure_refinement  'SHELXTL 6.14'
_computing_structure_solution    'SHELXTL 6.14 (Bruker, 2000-2003)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker AXS SMART APEX CCD diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0664
_diffrn_reflns_av_sigmaI/netI    0.0885
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            42404
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         1.18
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.141
_exptl_absorpt_correction_T_max  0.5630
_exptl_absorpt_correction_T_min  0.4817
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Apex2 v2.1-4 (Bruker, 2007)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.175
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2334
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.501
_refine_diff_density_min         -1.259
_refine_diff_density_rms         0.342
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1018
_refine_ls_number_reflns         13315
_refine_ls_number_restraints     336
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.1124
_refine_ls_R_factor_gt           0.0796
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1582P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2356
_refine_ls_wR_factor_ref         0.2603
_reflns_number_gt                8812
_reflns_number_total             13315
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b915025k.txt
_cod_data_source_block           6b
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7211816
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Lu1 Lu 0.68221(5) 0.80546(4) 0.95025(4) 0.0297(2) Uani 1 1 d . A .
Lu2 Lu 0.73848(5) 1.13148(5) 0.94320(4) 0.0318(2) Uani 1 1 d . . .
Lu3 Lu 0.77613(5) 0.48720(4) 0.98356(4) 0.0312(2) Uani 1 1 d . A .
Ag1 Ag 0.84374(11) 1.11392(10) 0.42989(7) 0.0448(4) Uani 1 1 d . . .
Ag2 Ag 0.87195(12) 0.51586(10) 0.49558(7) 0.0472(4) Uani 1 1 d . . .
Ag3 Ag 0.41251(12) 0.89659(12) 0.53481(7) 0.0548(5) Uani 1 1 d . . .
Ag4 Ag 0.64294(12) 0.61465(12) 0.45809(7) 0.0584(5) Uani 1 1 d . . .
C1 C 0.8933(12) 0.9899(10) 0.5751(8) 0.030(3) Uani 1 1 d U . .
H1 H 0.9132 0.9476 0.5387 0.036 Uiso 1 1 calc R . .
C2 C 0.8992(12) 0.9657(10) 0.6515(8) 0.030(3) Uani 1 1 d U . .
H2 H 0.9194 0.9073 0.6667 0.036 Uiso 1 1 calc R . .
C3 C 0.8752(11) 1.0281(9) 0.7057(8) 0.022(2) Uani 1 1 d U . .
C4 C 0.8405(12) 1.1158(10) 0.6794(9) 0.032(3) Uani 1 1 d U . .
H4 H 0.8223 1.1603 0.7140 0.038 Uiso 1 1 calc R . .
C5 C 0.8353(13) 1.1315(10) 0.6024(9) 0.035(3) Uani 1 1 d U . .
H5 H 0.8123 1.1884 0.5857 0.042 Uiso 1 1 calc R . .
C6 C 0.8818(10) 1.0062(9) 0.7896(7) 0.020(2) Uani 1 1 d U . .
C7 C 0.7719(12) 0.2536(10) 1.3126(8) 0.031(3) Uani 1 1 d U . .
H7 H 0.7566 0.2847 1.3575 0.037 Uiso 1 1 calc R . .
C8 C 0.7471(11) 0.2946(10) 1.2436(8) 0.026(3) Uani 1 1 d U . .
H8 H 0.7161 0.3517 1.2421 0.032 Uiso 1 1 calc R . .
C9 C 0.7698(10) 0.2479(9) 1.1759(8) 0.019(2) Uani 1 1 d U . .
C10 C 0.8143(12) 0.1644(10) 1.1833(9) 0.033(3) Uani 1 1 d U . .
H10 H 0.8284 0.1302 1.1402 0.040 Uiso 1 1 calc R . .
C11 C 0.8382(13) 0.1308(11) 1.2535(9) 0.035(3) Uani 1 1 d U . .
H11 H 0.8721 0.0751 1.2557 0.042 Uiso 1 1 calc R . .
C12 C 0.7416(10) 0.2868(9) 1.0987(8) 0.019(2) Uani 1 1 d U . .
C13 C 0.6207(10) 0.6308(9) 1.0886(8) 0.018(2) Uani 1 1 d U . .
C14 C 0.6175(11) 0.6281(10) 1.1771(8) 0.025(2) Uani 1 1 d U . .
C15 C 0.6102(13) 0.5504(11) 1.2196(9) 0.035(3) Uani 1 1 d U . .
H15 H 0.6009 0.4992 1.1957 0.042 Uiso 1 1 calc R . .
C16 C 0.6165(13) 0.5468(12) 1.2977(9) 0.041(3) Uani 1 1 d U . .
H16 H 0.6140 0.4922 1.3257 0.049 Uiso 1 1 calc R . .
C17 C 0.6340(14) 0.6986(13) 1.2913(9) 0.044(3) Uani 1 1 d U . .
H17 H 0.6420 0.7501 1.3152 0.053 Uiso 1 1 calc R . .
C18 C 0.6302(13) 0.7012(11) 1.2150(9) 0.039(3) Uani 1 1 d U . .
H18 H 0.6364 0.7552 1.1865 0.046 Uiso 1 1 calc R . .
C19 C 0.6885(10) 0.6258(9) 0.8203(8) 0.017(2) Uani 1 1 d U . .
C20 C 0.6806(10) 0.6202(9) 0.7356(8) 0.020(2) Uani 1 1 d U . .
C21 C 0.7191(11) 0.6851(10) 0.6824(8) 0.027(3) Uani 1 1 d U . .
H21 H 0.7490 0.7313 0.6985 0.033 Uiso 1 1 calc R . .
C22 C 0.7102(11) 0.6761(11) 0.6045(9) 0.029(3) Uani 1 1 d U . .
H22 H 0.7393 0.7155 0.5680 0.035 Uiso 1 1 calc R . .
C23 C 0.6270(11) 0.5543(11) 0.6307(8) 0.029(3) Uani 1 1 d U . .
H23 H 0.5952 0.5100 0.6136 0.035 Uiso 1 1 calc R . .
C24 C 0.6359(10) 0.5557(10) 0.7091(8) 0.023(2) Uani 1 1 d U . .
H24 H 0.6111 0.5120 0.7437 0.028 Uiso 1 1 calc R . .
C25 C 0.4494(9) 0.8575(8) 0.9036(8) 0.015(2) Uani 1 1 d U . .
C26 C 0.4420(10) 0.8659(9) 0.8172(8) 0.018(2) Uani 1 1 d U . .
C27 C 0.3909(12) 0.9383(11) 0.7830(9) 0.035(3) Uani 1 1 d U . .
H27 H 0.3597 0.9825 0.8139 0.042 Uiso 1 1 calc R . .
C28 C 0.3863(13) 0.9448(12) 0.7070(9) 0.041(3) Uani 1 1 d U . .
H28 H 0.3520 0.9944 0.6863 0.049 Uiso 1 1 calc R . .
C29 C 0.4771(11) 0.8131(10) 0.6908(8) 0.028(3) Uani 1 1 d U . .
H29 H 0.5064 0.7687 0.6594 0.033 Uiso 1 1 calc R . .
C30 C 0.4857(11) 0.8035(9) 0.7677(8) 0.022(2) Uani 1 1 d U . .
H30 H 0.5214 0.7541 0.7873 0.027 Uiso 1 1 calc R . .
C31 C 0.6323(10) 1.0042(9) 0.8267(8) 0.018(2) Uani 1 1 d U . .
C32 C 0.6216(11) 1.0266(9) 0.7437(8) 0.021(2) Uani 1 1 d U . .
C33 C 0.5858(12) 1.1127(10) 0.7175(8) 0.029(3) Uani 1 1 d U . .
H33 H 0.5679 1.1561 0.7532 0.035 Uiso 1 1 calc R . .
C34 C 0.5774(13) 1.1325(11) 0.6440(9) 0.040(3) Uani 1 1 d U . .
H34 H 0.5551 1.1902 0.6287 0.048 Uiso 1 1 calc R . .
C35 C 0.6358(13) 0.9894(11) 0.6099(9) 0.040(3) Uani 1 1 d U . .
H35 H 0.6546 0.9478 0.5727 0.048 Uiso 1 1 calc R . .
C36 C 0.6446(12) 0.9662(10) 0.6875(8) 0.029(3) Uani 1 1 d U . .
H36 H 0.6667 0.9081 0.7018 0.035 Uiso 1 1 calc R . .
C37 C 0.8020(10) 0.3301(9) 0.8378(7) 0.016(2) Uani 1 1 d U . .
C38 C 0.8189(9) 0.3765(8) 0.7600(7) 0.014(2) Uani 1 1 d U . .
C39 C 0.8713(9) 0.4471(9) 0.7475(8) 0.017(2) Uani 1 1 d U . .
H39 H 0.8974 0.4681 0.7884 0.020 Uiso 1 1 calc R . .
C40 C 0.8862(10) 0.4885(10) 0.6727(8) 0.023(2) Uani 1 1 d U . .
H40 H 0.9221 0.5370 0.6646 0.028 Uiso 1 1 calc R A .
C41 C 0.8031(12) 0.3874(10) 0.6256(8) 0.029(3) Uani 1 1 d U . .
H41 H 0.7837 0.3627 0.5833 0.034 Uiso 1 1 calc R A .
C42 C 0.7821(11) 0.3476(9) 0.6954(8) 0.023(2) Uani 1 1 d U . .
H42 H 0.7434 0.3011 0.7015 0.027 Uiso 1 1 calc R . .
C43 C 0.8950(12) 0.6306(11) 1.3401(8) 0.033(3) Uani 1 1 d U . .
H43 H 0.9073 0.6756 1.3705 0.039 Uiso 1 1 calc R . .
C44 C 0.8972(12) 0.6472(10) 1.2616(8) 0.030(3) Uani 1 1 d U . .
H44 H 0.9105 0.7033 1.2399 0.036 Uiso 1 1 calc R . .
C45 C 0.8799(11) 0.5824(9) 1.2134(8) 0.023(2) Uani 1 1 d U . .
C46 C 0.8601(12) 0.4986(10) 1.2507(9) 0.030(3) Uani 1 1 d U . .
H46 H 0.8490 0.4524 1.2212 0.036 Uiso 1 1 calc R . .
C47 C 0.8572(13) 0.4852(11) 1.3281(9) 0.039(3) Uani 1 1 d U . .
H47 H 0.8424 0.4302 1.3511 0.046 Uiso 1 1 calc R . .
C48 C 0.8808(11) 0.5984(9) 1.1288(8) 0.020(2) Uani 1 1 d U . .
C49 C 0.7954(11) 0.9593(9) 1.0337(8) 0.022(2) Uani 1 1 d U . .
C50A C 0.843(2) 0.8731(16) 1.0773(14) 0.023(2) Uani 0.49(2) 1 d PDU A 1
H50A H 0.9112 0.8627 1.0623 0.028 Uiso 0.49(2) 1 calc PR A 1
C51A C 0.818(3) 0.886(2) 1.1603(15) 0.030(3) Uani 0.49(2) 1 d PDU A 1
H51A H 0.8402 0.9404 1.1730 0.045 Uiso 0.49(2) 1 calc PR A 1
H51B H 0.8468 0.8368 1.1901 0.045 Uiso 0.49(2) 1 calc PR A 1
H51C H 0.7511 0.8887 1.1723 0.045 Uiso 0.49(2) 1 calc PR A 1
C50B C 0.801(2) 0.8834(13) 1.0941(18) 0.023(2) Uani 0.51(2) 1 d PDU A 2
H50B H 0.7437 0.8930 1.1300 0.028 Uiso 0.51(2) 1 calc PR A 2
C51B C 0.878(2) 0.889(2) 1.1413(19) 0.030(3) Uani 0.51(2) 1 d PDU A 2
H51D H 0.9337 0.9017 1.1081 0.045 Uiso 0.51(2) 1 calc PR A 2
H51E H 0.8893 0.8328 1.1700 0.045 Uiso 0.51(2) 1 calc PR A 2
H51F H 0.8608 0.9351 1.1769 0.045 Uiso 0.51(2) 1 calc PR A 2
C52 C 0.8676(10) 0.6470(8) 0.9133(8) 0.017(2) Uani 1 1 d U . .
C53A C 0.9142(16) 0.7278(14) 0.8703(12) 0.024(2) Uani 0.638(13) 1 d PDU A 1
H53A H 0.9639 0.7445 0.8990 0.036 Uiso 0.638(13) 1 calc PR A 1
C54A C 0.9526(18) 0.7088(16) 0.7907(12) 0.030(3) Uani 0.638(13) 1 d PDU A 1
H54A H 1.0078 0.6676 0.7915 0.046 Uiso 0.638(13) 1 calc PR A 1
H54B H 0.9687 0.7632 0.7625 0.046 Uiso 0.638(13) 1 calc PR A 1
H54C H 0.9064 0.6832 0.7657 0.046 Uiso 0.638(13) 1 calc PR A 1
C53B C 0.894(2) 0.7185(17) 0.844(3) 0.024(2) Uani 0.362(13) 1 d PDU A 2
H53B H 0.8722 0.7012 0.7964 0.028 Uiso 0.362(13) 1 calc PR A 2
C54B C 0.995(2) 0.729(3) 0.830(3) 0.030(3) Uani 0.362(13) 1 d PDU A 2
H54D H 1.0167 0.7423 0.8780 0.046 Uiso 0.362(13) 1 calc PR A 2
H54E H 1.0056 0.7769 0.7921 0.046 Uiso 0.362(13) 1 calc PR A 2
H54F H 1.0279 0.6747 0.8122 0.046 Uiso 0.362(13) 1 calc PR A 2
Cl1 Cl 0.3859(4) 0.6499(4) 0.5144(3) 0.0535(13) Uani 1 1 d . . .
N1 N 0.8598(10) 1.0733(8) 0.5490(7) 0.033(3) Uani 1 1 d U . .
N2 N 0.8167(10) 0.1719(8) 1.3189(7) 0.032(3) Uani 1 1 d U . .
N3 N 0.6260(12) 0.6189(10) 1.3349(8) 0.045(3) Uani 1 1 d U . .
N4 N 0.6630(9) 0.6153(9) 0.5790(7) 0.031(2) Uani 1 1 d U . .
N5 N 0.4290(9) 0.8829(9) 0.6573(7) 0.031(3) Uani 1 1 d U . .
N6 N 0.6008(12) 1.0703(10) 0.5883(8) 0.044(3) Uani 1 1 d U . .
N7 N 0.8490(9) 0.4588(9) 0.6118(7) 0.029(2) Uani 1 1 d U A .
N8 N 0.8755(11) 0.5504(9) 1.3747(7) 0.037(3) Uani 1 1 d U . .
O1 O 0.4359(15) 0.6626(19) 0.5759(15) 0.144(10) Uani 1 1 d . . .
O2 O 0.3273(14) 0.7322(12) 0.4992(11) 0.103(7) Uani 1 1 d . . .
O3 O 0.3216(14) 0.5870(12) 0.5404(10) 0.091(6) Uani 1 1 d . . .
O4 O 0.4349(17) 0.6360(15) 0.4369(12) 0.125(9) Uani 1 1 d . . .
Cl2 Cl 1.0006(10) 0.7183(8) 0.5370(6) 0.038(2) Uani 0.638(13) 1 d PD A 1
O5 O 0.971(3) 0.6330(16) 0.5484(17) 0.122(12) Uani 0.638(13) 1 d PDU A 1
O6 O 0.991(2) 0.7530(16) 0.4624(11) 0.103(9) Uani 0.638(13) 1 d PDU A 1
O7 O 0.953(2) 0.773(2) 0.5918(14) 0.133(10) Uani 0.638(13) 1 d PDU A 1
O8 O 1.0977(15) 0.711(2) 0.5466(17) 0.091(7) Uani 0.638(13) 1 d PDU A 1
Cl2B Cl 1.000(2) 0.7081(17) 0.5646(11) 0.038(2) Uani 0.362(13) 1 d PD A 2
O5B O 0.956(5) 0.646(3) 0.530(3) 0.128(14) Uani 0.362(13) 1 d PDU A 2
O6B O 0.976(4) 0.794(3) 0.534(3) 0.122(10) Uani 0.362(13) 1 d PDU A 2
O7B O 0.975(4) 0.703(3) 0.6444(15) 0.139(14) Uani 0.362(13) 1 d PDU A 2
O8B O 1.098(2) 0.689(4) 0.549(3) 0.091(7) Uani 0.362(13) 1 d PDU A 2
O13 O 0.7277(7) 0.3709(6) 1.0917(5) 0.023(2) Uani 1 1 d U . .
O14 O 0.7326(8) 0.2361(6) 1.0508(6) 0.028(2) Uani 1 1 d U . .
O15 O 0.9296(7) 0.9369(6) 0.8084(5) 0.021(2) Uani 1 1 d U . .
O16 O 0.8358(8) 1.0601(7) 0.8363(5) 0.028(2) Uani 1 1 d U . .
O17 O 0.6382(7) 0.5604(6) 1.0559(5) 0.020(2) Uani 1 1 d U . .
O18 O 0.6101(7) 0.7091(6) 1.0534(5) 0.022(2) Uani 1 1 d U . .
O19 O 0.7089(7) 0.5548(6) 0.8597(5) 0.0173(19) Uani 1 1 d U . .
O20 O 0.6710(7) 0.7017(6) 0.8454(5) 0.022(2) Uani 1 1 d U . .
O21 O 0.5086(6) 0.8006(6) 0.9278(5) 0.0179(19) Uani 1 1 d U . .
O22 O 0.3937(6) 0.9069(6) 0.9464(5) 0.0165(19) Uani 1 1 d U . .
O23 O 0.6481(7) 0.9206(6) 0.8451(5) 0.024(2) Uani 1 1 d U . .
O24 O 0.6227(7) 1.0635(6) 0.8733(5) 0.022(2) Uani 1 1 d U . .
O25 O 0.7699(7) 0.2568(6) 0.8411(5) 0.021(2) Uani 1 1 d U . .
O26 O 0.8244(7) 0.3667(6) 0.8945(5) 0.020(2) Uani 1 1 d U . .
O27 O 0.8437(7) 0.5418(6) 1.0955(5) 0.026(2) Uani 1 1 d U . .
O28 O 0.9185(7) 0.6636(6) 1.0962(5) 0.024(2) Uani 1 1 d U . .
O29 O 0.8224(7) 1.0335(5) 1.0455(5) 0.0183(14) Uani 1 1 d U A .
O30 O 0.7490(7) 0.9491(5) 0.9772(5) 0.0183(14) Uani 1 1 d U A .
O31 O 0.7919(7) 0.8028(6) 1.0592(6) 0.025(2) Uani 1 1 d DU . .
H31A H 0.8299 0.7623 1.0730 0.038 Uiso 1 1 d R A .
O32 O 0.7948(6) 0.6632(5) 0.9582(5) 0.0137(17) Uani 1 1 d U A .
O33 O 0.9111(6) 0.5711(6) 0.9064(5) 0.0171(19) Uani 1 1 d U A .
O34 O 0.8408(7) 0.7987(6) 0.8687(6) 0.028(2) Uani 1 1 d DU . .
H34A H 0.8561 0.8465 0.8483 0.042 Uiso 1 1 d R A .
O1W O 0.5947(6) 1.2463(6) 0.9255(5) 0.021(2) Uani 1 1 d . . .
H1WA H 0.5723 1.2759 0.9623 0.032 Uiso 1 1 d R A .
H1WB H 0.5546 1.2392 0.8974 0.032 Uiso 1 1 d R . .
O2W O 0.5738(7) 0.9092(7) 1.0477(6) 0.028(2) Uani 1 1 d . . .
H2WA H 0.5806 0.9521 1.0724 0.042 Uiso 1 1 d R A .
H2WB H 0.5201 0.8944 1.0575 0.042 Uiso 1 1 d R . .
O3W O 0.6147(7) 0.4301(6) 0.9465(6) 0.024(2) Uani 1 1 d . . .
H3WA H 0.5652 0.4477 0.9713 0.037 Uiso 1 1 d R A .
H3WB H 0.6239 0.4600 0.9057 0.037 Uiso 1 1 d R . .
O4W O 0.9333(7) 0.3959(6) 1.0099(6) 0.023(2) Uani 1 1 d . . .
H4WA H 0.9070 0.3498 1.0165 0.035 Uiso 1 1 d R A .
H4WB H 0.9668 0.3970 0.9682 0.035 Uiso 1 1 d R . .
O5W O 0.4902(8) 0.6009(8) 0.9040(7) 0.045(3) Uani 1 1 d . . .
H5WA H 0.5089 0.6451 0.8791 0.068 Uiso 1 1 d R . .
H5WB H 0.4676 0.6133 0.9480 0.068 Uiso 1 1 d R . .
O6W O 0.9038(8) 1.1841(7) 0.9481(7) 0.042(3) Uani 1 1 d . . .
H6WA H 0.8866 1.1754 0.9945 0.063 Uiso 1 1 d R A .
H6WB H 0.9400 1.2232 0.9408 0.063 Uiso 1 1 d R . .
O7W O 0.9929(9) 0.9171(9) 0.9508(7) 0.052(4) Uani 1 1 d . . .
H7WB H 0.9592 0.9340 0.9166 0.077 Uiso 1 1 d R . .
H7WA H 1.0228 0.8694 0.9406 0.077 Uiso 0.49(2) 1 d PR A 1
H7WC H 0.9713 0.8753 0.9776 0.077 Uiso 0.51(2) 1 d PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Lu Lu -0.4720 5.8584 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O18 Lu1 O23 143.8(3) . .
O18 Lu1 O20 94.3(3) . .
O23 Lu1 O20 82.2(3) . .
O18 Lu1 O34 134.1(3) . .
O23 Lu1 O34 79.8(3) . .
O20 Lu1 O34 74.3(3) . .
O18 Lu1 O30 122.2(3) . .
O23 Lu1 O30 71.2(3) . .
O20 Lu1 O30 143.2(3) . .
O34 Lu1 O30 76.2(3) . .
O18 Lu1 O32 73.9(3) . .
O23 Lu1 O32 134.4(3) . .
O20 Lu1 O32 66.8(3) . .
O34 Lu1 O32 60.6(3) . .
O30 Lu1 O32 115.6(3) . .
O18 Lu1 O21 72.3(3) . .
O23 Lu1 O21 72.7(3) . .
O20 Lu1 O21 70.0(3) . .
O34 Lu1 O21 137.2(3) . .
O30 Lu1 O21 122.4(3) . .
O32 Lu1 O21 121.7(3) . .
O18 Lu1 O31 76.3(3) . .
O23 Lu1 O31 131.0(3) . .
O20 Lu1 O31 133.1(3) . .
O34 Lu1 O31 80.0(3) . .
O30 Lu1 O31 60.8(3) . .
O32 Lu1 O31 66.4(3) . .
O21 Lu1 O31 142.5(3) . .
O18 Lu1 O2W 72.6(3) . .
O23 Lu1 O2W 87.4(3) . .
O20 Lu1 O2W 140.7(3) . .
O34 Lu1 O2W 140.7(3) . .
O30 Lu1 O2W 64.4(3) . .
O32 Lu1 O2W 137.5(3) . .
O21 Lu1 O2W 70.7(3) . .
O31 Lu1 O2W 80.8(3) . .
O16 Lu2 O24 76.3(3) . .
O16 Lu2 O14 145.9(4) . 1_565
O24 Lu2 O14 137.1(3) . 1_565
O16 Lu2 O25 75.0(3) . 1_565
O24 Lu2 O25 95.8(3) . 1_565
O14 Lu2 O25 91.3(3) 1_565 1_565
O16 Lu2 O29 92.4(3) . .
O24 Lu2 O29 118.3(3) . .
O14 Lu2 O29 78.1(3) 1_565 .
O25 Lu2 O29 140.0(3) 1_565 .
O16 Lu2 O6W 75.7(4) . .
O24 Lu2 O6W 150.9(4) . .
O14 Lu2 O6W 70.2(4) 1_565 .
O25 Lu2 O6W 69.3(3) 1_565 .
O29 Lu2 O6W 70.7(3) . .
O16 Lu2 O1W 123.9(3) . .
O24 Lu2 O1W 70.3(3) . .
O14 Lu2 O1W 74.6(3) 1_565 .
O25 Lu2 O1W 65.4(3) 1_565 .
O29 Lu2 O1W 143.1(3) . .
O6W Lu2 O1W 120.7(3) . .
O16 Lu2 O22 139.1(3) . 2_677
O24 Lu2 O22 76.5(3) . 2_677
O14 Lu2 O22 70.2(3) 1_565 2_677
O25 Lu2 O22 137.8(3) 1_565 2_677
O29 Lu2 O22 74.6(3) . 2_677
O6W Lu2 O22 131.4(3) . 2_677
O1W Lu2 O22 73.1(3) . 2_677
O16 Lu2 O30 72.2(3) . .
O24 Lu2 O30 70.3(3) . .
O14 Lu2 O30 119.9(3) 1_565 .
O25 Lu2 O30 146.6(3) 1_565 .
O29 Lu2 O30 48.9(3) . .
O6W Lu2 O30 108.1(3) . .
O1W Lu2 O30 130.8(3) . .
O22 Lu2 O30 70.1(3) 2_677 .
O17 Lu3 O26 141.8(3) . .
O17 Lu3 O27 77.9(3) . .
O26 Lu3 O27 134.3(3) . .
O17 Lu3 O13 75.9(3) . .
O26 Lu3 O13 89.6(3) . .
O27 Lu3 O13 78.9(3) . .
O17 Lu3 O19 87.0(3) . .
O26 Lu3 O19 79.0(3) . .
O27 Lu3 O19 137.4(3) . .
O13 Lu3 O19 135.6(3) . .
O17 Lu3 O4W 139.1(3) . .
O26 Lu3 O4W 66.3(3) . .
O27 Lu3 O4W 68.1(3) . .
O13 Lu3 O4W 75.8(3) . .
O19 Lu3 O4W 133.7(3) . .
O17 Lu3 O33 124.2(3) . .
O26 Lu3 O33 86.2(3) . .
O27 Lu3 O33 81.2(3) . .
O13 Lu3 O33 147.6(3) . .
O19 Lu3 O33 74.9(3) . .
O4W Lu3 O33 73.2(3) . .
O17 Lu3 O32 75.0(3) . .
O26 Lu3 O32 128.6(3) . .
O27 Lu3 O32 70.8(3) . .
O13 Lu3 O32 141.5(3) . .
O19 Lu3 O32 66.9(3) . .
O4W Lu3 O32 112.4(3) . .
O33 Lu3 O32 49.3(3) . .
O17 Lu3 O3W 68.3(3) . .
O26 Lu3 O3W 73.9(3) . .
O27 Lu3 O3W 140.8(3) . .
O13 Lu3 O3W 74.3(3) . .
O19 Lu3 O3W 61.3(3) . .
O4W Lu3 O3W 129.6(3) . .
O33 Lu3 O3W 134.3(3) . .
O32 Lu3 O3W 116.4(3) . .
O17 Lu3 C52 99.6(3) . .
O26 Lu3 C52 106.7(3) . .
O27 Lu3 C52 77.2(3) . .
O13 Lu3 C52 156.1(3) . .
O19 Lu3 C52 66.4(3) . .
O4W Lu3 C52 94.5(3) . .
O33 Lu3 C52 24.9(3) . .
O32 Lu3 C52 24.7(3) . .
O3W Lu3 C52 126.5(3) . .
N2 Ag1 N1 171.3(5) 1_564 .
N8 Ag2 N7 167.2(6) 1_554 .
N8 Ag2 O5B 97.1(13) 1_554 .
N7 Ag2 O5B 95.6(13) . .
N5 Ag3 N6 172.1(5) . 2_676
N4 Ag4 N3 177.6(6) . 1_554
C2 C1 N1 123.5(14) . .
C2 C1 H1 118.2 . .
N1 C1 H1 118.2 . .
C1 C2 C3 119.3(14) . .
C1 C2 H2 120.3 . .
C3 C2 H2 120.4 . .
C2 C3 C4 117.8(13) . .
C2 C3 C6 121.9(12) . .
C4 C3 C6 120.3(12) . .
C5 C4 C3 117.6(14) . .
C5 C4 H4 121.2 . .
C3 C4 H4 121.2 . .
N1 C5 C4 125.8(14) . .
N1 C5 H5 117.1 . .
C4 C5 H5 117.1 . .
O15 C6 O16 125.5(12) . .
O15 C6 C3 118.0(12) . .
O16 C6 C3 116.4(11) . .
N2 C7 C8 124.0(14) . .
N2 C7 H7 118.0 . .
C8 C7 H7 118.0 . .
C7 C8 C9 118.2(13) . .
C7 C8 H8 120.9 . .
C9 C8 H8 120.9 . .
C10 C9 C8 117.1(13) . .
C10 C9 C12 121.4(12) . .
C8 C9 C12 121.4(12) . .
C11 C10 C9 120.2(14) . .
C11 C10 H10 119.9 . .
C9 C10 H10 119.9 . .
N2 C11 C10 124.5(15) . .
N2 C11 H11 117.8 . .
C10 C11 H11 117.8 . .
O14 C12 O13 126.1(12) . .
O14 C12 C9 117.8(12) . .
O13 C12 C9 116.1(12) . .
O17 C13 O18 124.9(12) . .
O17 C13 C14 118.6(12) . .
O18 C13 C14 116.4(12) . .
C15 C14 C18 117.5(14) . .
C15 C14 C13 120.3(13) . .
C18 C14 C13 121.9(13) . .
C14 C15 C16 120.1(16) . .
C14 C15 H15 120.0 . .
C16 C15 H15 120.0 . .
N3 C16 C15 122.2(16) . .
N3 C16 H16 118.9 . .
C15 C16 H16 118.9 . .
C18 C17 N3 119.8(16) . .
C18 C17 H17 120.1 . .
N3 C17 H17 120.1 . .
C17 C18 C14 122.7(17) . .
C17 C18 H18 118.7 . .
C14 C18 H18 118.7 . .
O20 C19 O19 126.2(12) . .
O20 C19 C20 115.3(11) . .
O19 C19 C20 118.4(12) . .
C24 C20 C21 119.2(13) . .
C24 C20 C19 121.8(13) . .
C21 C20 C19 118.9(13) . .
C22 C21 C20 116.3(15) . .
C22 C21 H21 121.8 . .
C20 C21 H21 121.8 . .
N4 C22 C21 124.3(15) . .
N4 C22 H22 117.8 . .
C21 C22 H22 117.8 . .
N4 C23 C24 121.5(15) . .
N4 C23 H23 119.3 . .
C24 C23 H23 119.3 . .
C20 C24 C23 120.4(15) . .
C20 C24 H24 119.8 . .
C23 C24 H24 119.8 . .
O21 C25 O22 124.0(12) . .
O21 C25 C26 117.9(12) . .
O22 C25 C26 118.0(11) . .
C30 C26 C27 116.1(13) . .
C30 C26 C25 122.3(12) . .
C27 C26 C25 121.6(13) . .
C28 C27 C26 120.6(15) . .
C28 C27 H27 119.7 . .
C26 C27 H27 119.7 . .
C27 C28 N5 123.8(15) . .
C27 C28 H28 118.1 . .
N5 C28 H28 118.1 . .
N5 C29 C30 123.8(14) . .
N5 C29 H29 118.1 . .
C30 C29 H29 118.1 . .
C29 C30 C26 120.6(13) . .
C29 C30 H30 119.7 . .
C26 C30 H30 119.7 . .
O24 C31 O23 124.5(12) . .
O24 C31 C32 120.3(11) . .
O23 C31 C32 115.2(12) . .
C36 C32 C33 115.6(13) . .
C36 C32 C31 122.9(12) . .
C33 C32 C31 121.5(13) . .
C34 C33 C32 121.3(15) . .
C34 C33 H33 119.4 . .
C32 C33 H33 119.4 . .
C33 C34 N6 122.1(15) . .
C33 C34 H34 119.0 . .
N6 C34 H34 119.0 . .
N6 C35 C36 120.4(16) . .
N6 C35 H35 119.8 . .
C36 C35 H35 119.8 . .
C32 C36 C35 121.8(14) . .
C32 C36 H36 119.1 . .
C35 C36 H36 119.1 . .
O25 C37 O26 125.2(12) . .
O25 C37 C38 117.3(12) . .
O26 C37 C38 117.5(12) . .
C39 C38 C42 117.1(13) . .
C39 C38 C37 121.9(12) . .
C42 C38 C37 121.0(12) . .
C38 C39 C40 120.0(13) . .
C38 C39 H39 120.0 . .
C40 C39 H39 120.0 . .
N7 C40 C39 121.1(14) . .
N7 C40 H40 119.5 . .
C39 C40 H40 119.5 . .
N7 C41 C42 125.1(15) . .
N7 C41 H41 117.4 . .
C42 C41 H41 117.4 . .
C41 C42 C38 119.4(14) . .
C41 C42 H42 120.3 . .
C38 C42 H42 120.3 . .
N8 C43 C44 121.6(15) . .
N8 C43 H43 119.2 . .
C44 C43 H43 119.2 . .
C43 C44 C45 121.6(15) . .
C43 C44 H44 119.2 . .
C45 C44 H44 119.2 . .
C44 C45 C46 116.0(13) . .
C44 C45 C48 122.9(13) . .
C46 C45 C48 121.1(13) . .
C47 C46 C45 120.7(15) . .
C47 C46 H46 119.6 . .
C45 C46 H46 119.6 . .
C46 C47 N8 122.2(15) . .
C46 C47 H47 118.9 . .
N8 C47 H47 118.9 . .
O28 C48 O27 125.6(12) . .
O28 C48 C45 119.1(12) . .
O27 C48 C45 115.3(13) . .
O29 C49 O30 122.1(11) . .
O29 C49 C50B 120.4(12) . .
O30 C49 C50B 116.6(13) . .
O29 C49 C50A 117.1(12) . .
O30 C49 C50A 119.0(12) . .
O31 C50A C51A 106(2) . .
O31 C50A C49 103.6(17) . .
C51A C50A C49 105(2) . .
O31 C50A H50A 113.5 . .
C51A C50A H50A 113.5 . .
C49 C50A H50A 113.5 . .
O31 C50B C51B 120(2) . .
O31 C50B C49 108.8(18) . .
C51B C50B C49 112(2) . .
O31 C50B H50B 104.8 . .
C51B C50B H50B 104.8 . .
C49 C50B H50B 104.8 . .
C50B C51B H51D 109.5 . .
C50B C51B H51E 109.5 . .
H51D C51B H51E 109.5 . .
C50B C51B H51F 109.5 . .
H51D C51B H51F 109.5 . .
H51E C51B H51F 109.5 . .
O32 C52 O33 124.5(12) . .
O32 C52 C53A 117.4(12) . .
O33 C52 C53A 117.7(13) . .
O32 C52 C53B 118.6(12) . .
O33 C52 C53B 114.8(13) . .
O32 C52 Lu3 64.8(7) . .
O33 C52 Lu3 60.8(7) . .
C53A C52 Lu3 175.5(11) . .
C53B C52 Lu3 153.7(15) . .
O34 C53A C54A 109.3(16) . .
O34 C53A C52 105.6(15) . .
C54A C53A C52 111.7(19) . .
O34 C53A H53A 110.1 . .
C54A C53A H53A 110.1 . .
C52 C53A H53A 110.1 . .
O34 C53B C54B 112(3) . .
O34 C53B C52 103(2) . .
C54B C53B C52 113(3) . .
O34 C53B H53B 109.5 . .
C54B C53B H53B 109.5 . .
C52 C53B H53B 109.5 . .
C53B C54B H54D 109.5 . .
C53B C54B H54E 109.5 . .
H54D C54B H54E 109.5 . .
C53B C54B H54F 109.5 . .
H54D C54B H54F 109.5 . .
H54E C54B H54F 109.5 . .
O1 Cl1 O3 107.7(15) . .
O1 Cl1 O2 107.8(14) . .
O3 Cl1 O2 104.5(12) . .
O1 Cl1 O4 120.4(14) . .
O3 Cl1 O4 114.2(11) . .
O2 Cl1 O4 100.6(13) . .
C5 N1 C1 115.9(13) . .
C5 N1 Ag1 118.9(10) . .
C1 N1 Ag1 125.2(10) . .
C11 N2 C7 115.9(13) . .
C11 N2 Ag1 124.1(10) . 1_546
C7 N2 Ag1 120.0(10) . 1_546
C16 N3 C17 117.7(14) . .
C16 N3 Ag4 123.2(12) . 1_556
C17 N3 Ag4 118.9(11) . 1_556
C22 N4 C23 118.1(13) . .
C22 N4 Ag4 121.3(11) . .
C23 N4 Ag4 120.6(11) . .
C29 N5 C28 115.1(13) . .
C29 N5 Ag3 123.8(10) . .
C28 N5 Ag3 121.1(10) . .
C35 N6 C34 118.8(14) . .
C35 N6 Ag3 119.0(12) . 2_676
C34 N6 Ag3 122.1(10) . 2_676
C41 N7 C40 116.9(13) . .
C41 N7 Ag2 119.6(10) . .
C40 N7 Ag2 123.3(10) . .
C43 N8 C47 117.9(13) . .
C43 N8 Ag2 125.2(11) . 1_556
C47 N8 Ag2 117.0(10) . 1_556
O7 Cl2 O6 111.8(11) . .
O7 Cl2 O5 110.4(11) . .
O6 Cl2 O5 111.1(11) . .
O7 Cl2 O8 108.6(11) . .
O6 Cl2 O8 107.6(11) . .
O5 Cl2 O8 107.2(11) . .
O5B Cl2B O6B 110.5(12) . .
O5B Cl2B O7B 109.7(12) . .
O6B Cl2B O7B 109.9(12) . .
O5B Cl2B O8B 108.9(12) . .
O6B Cl2B O8B 108.8(12) . .
O7B Cl2B O8B 109.0(12) . .
Cl2B O5B Ag2 168(3) . .
C12 O13 Lu3 133.3(9) . .
C12 O14 Lu2 171.6(11) . 1_545
C6 O16 Lu2 166.6(10) . .
C13 O17 Lu3 135.0(9) . .
C13 O18 Lu1 142.7(9) . .
C19 O19 Lu3 145.4(8) . .
C19 O20 Lu1 148.6(8) . .
C25 O21 Lu1 132.6(8) . .
C25 O22 Lu2 130.9(8) . 2_677
C31 O23 Lu1 146.2(9) . .
C31 O24 Lu2 132.1(9) . .
C37 O25 Lu2 137.0(8) . 1_545
C37 O26 Lu3 143.8(9) . .
C48 O27 Lu3 153.5(9) . .
C49 O29 Lu2 99.2(7) . .
C49 O30 Lu1 125.6(8) . .
C49 O30 Lu2 89.4(7) . .
Lu1 O30 Lu2 143.8(3) . .
C50B O31 Lu1 119.2(10) . .
C50A O31 Lu1 127.4(12) . .
C50B O31 H31A 111.6 . .
C50A O31 H31A 95.4 . .
Lu1 O31 H31A 128.5 . .
C52 O32 Lu1 125.1(8) . .
C52 O32 Lu3 90.5(7) . .
Lu1 O32 Lu3 135.7(4) . .
C52 O33 Lu3 94.4(8) . .
C53A O34 Lu1 126.6(10) . .
C53B O34 Lu1 124.8(15) . .
C53A O34 H34A 116.0 . .
C53B O34 H34A 118.7 . .
Lu1 O34 H34A 115.3 . .
Lu2 O1W H1WA 118.6 . .
Lu2 O1W H1WB 123.3 . .
H1WA O1W H1WB 111.0 . .
Lu1 O2W H2WA 136.0 . .
Lu1 O2W H2WB 113.3 . .
H2WA O2W H2WB 110.6 . .
Lu3 O3W H3WA 118.1 . .
Lu3 O3W H3WB 86.2 . .
H3WA O3W H3WB 111.1 . .
Lu3 O4W H4WA 90.7 . .
Lu3 O4W H4WB 105.6 . .
H4WA O4W H4WB 110.7 . .
H5WA O5W H5WB 110.8 . .
Lu2 O6W H6WA 79.0 . .
Lu2 O6W H6WB 150.2 . .
H6WA O6W H6WB 111.2 . .
H7WB O7W H7WA 110.4 . .
H7WB O7W H7WC 110.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Lu1 O18 2.429(10) .
Lu1 O23 2.490(9) .
Lu1 O20 2.512(9) .
Lu1 O34 2.535(10) .
Lu1 O30 2.550(9) .
Lu1 O32 2.564(8) .
Lu1 O21 2.583(9) .
Lu1 O31 2.600(9) .
Lu1 O2W 2.647(10) .
Lu2 O16 2.434(10) .
Lu2 O24 2.509(10) .
Lu2 O14 2.516(10) 1_565
Lu2 O25 2.538(9) 1_565
Lu2 O29 2.568(8) .
Lu2 O6W 2.594(10) .
Lu2 O1W 2.597(9) .
Lu2 O22 2.612(9) 2_677
Lu2 O30 2.768(8) .
Lu3 O17 2.429(9) .
Lu3 O26 2.462(9) .
Lu3 O27 2.498(9) .
Lu3 O13 2.563(9) .
Lu3 O19 2.569(8) .
Lu3 O4W 2.601(9) .
Lu3 O33 2.608(9) .
Lu3 O32 2.697(8) .
Lu3 O3W 2.717(10) .
Lu3 C52 2.980(13) .
Ag1 N2 2.124(12) 1_564
Ag1 N1 2.149(12) .
Ag2 N8 2.125(12) 1_554
Ag2 N7 2.140(12) .
Ag2 O5B 2.55(3) .
Ag3 N5 2.162(12) .
Ag3 N6 2.189(13) 2_676
Ag4 N4 2.154(12) .
Ag4 N3 2.177(13) 1_554
C1 C2 1.36(2) .
C1 N1 1.369(19) .
C1 H1 0.9300 .
C2 C3 1.369(19) .
C2 H2 0.9300 .
C3 C4 1.432(19) .
C3 C6 1.483(18) .
C4 C5 1.35(2) .
C4 H4 0.9300 .
C5 N1 1.315(19) .
C5 H5 0.9300 .
C6 O15 1.239(15) .
C6 O16 1.271(16) .
C7 N2 1.337(19) .
C7 C8 1.38(2) .
C7 H7 0.9300 .
C8 C9 1.402(19) .
C8 H8 0.9300 .
C9 C10 1.362(19) .
C9 C12 1.509(17) .
C10 C11 1.36(2) .
C10 H10 0.9300 .
C11 N2 1.320(19) .
C11 H11 0.9300 .
C12 O14 1.195(16) .
C12 O13 1.266(15) .
C13 O17 1.229(16) .
C13 O18 1.296(16) .
C13 C14 1.530(18) .
C14 C15 1.35(2) .
C14 C18 1.36(2) .
C15 C16 1.37(2) .
C15 H15 0.9300 .
C16 N3 1.33(2) .
C16 H16 0.9300 .
C17 C18 1.33(2) .
C17 N3 1.38(2) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 O20 1.245(16) .
C19 O19 1.260(15) .
C19 C20 1.498(18) .
C20 C24 1.35(2) .
C20 C21 1.41(2) .
C21 C22 1.39(2) .
C21 H21 0.9300 .
C22 N4 1.32(2) .
C22 H22 0.9300 .
C23 N4 1.34(2) .
C23 C24 1.38(2) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 O21 1.238(15) .
C25 O22 1.252(16) .
C25 C26 1.513(18) .
C26 C30 1.373(19) .
C26 C27 1.394(18) .
C27 C28 1.33(2) .
C27 H27 0.9300 .
C28 N5 1.37(2) .
C28 H28 0.9300 .
C29 N5 1.341(18) .
C29 C30 1.352(19) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 O24 1.235(16) .
C31 O23 1.285(15) .
C31 C32 1.479(18) .
C32 C36 1.37(2) .
C32 C33 1.415(18) .
C33 C34 1.31(2) .
C33 H33 0.9300 .
C34 N6 1.38(2) .
C34 H34 0.9300 .
C35 N6 1.32(2) .
C35 C36 1.39(2) .
C35 H35 0.9300 .
C36 H36 0.9300 .
C37 O25 1.236(16) .
C37 O26 1.251(16) .
C37 C38 1.483(18) .
C38 C39 1.357(19) .
C38 C42 1.409(18) .
C39 C40 1.404(18) .
C39 H39 0.9300 .
C40 N7 1.360(19) .
C40 H40 0.9300 .
C41 N7 1.31(2) .
C41 C42 1.33(2) .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 N8 1.35(2) .
C43 C44 1.37(2) .
C43 H43 0.9300 .
C44 C45 1.390(19) .
C44 H44 0.9300 .
C45 C46 1.42(2) .
C45 C48 1.471(18) .
C46 C47 1.34(2) .
C46 H46 0.9300 .
C47 N8 1.38(2) .
C47 H47 0.9300 .
C48 O28 1.239(17) .
C48 O27 1.258(16) .
C49 O29 1.258(16) .
C49 O30 1.276(16) .
C49 C50B 1.50(3) .
C49 C50A 1.60(3) .
C50A O31 1.424(19) .
C50A C51A 1.466(19) .
C50A H50A 0.9800 .
C51A H51A 0.9600 .
C51A H51B 0.9600 .
C51A H51C 0.9600 .
C50B O31 1.420(19) .
C50B C51B 1.462(18) .
C50B H50B 0.9800 .
C51B H51D 0.9600 .
C51B H51E 0.9600 .
C51B H51F 0.9600 .
C52 O32 1.244(16) .
C52 O33 1.256(15) .
C52 C53A 1.55(3) .
C52 C53B 1.59(4) .
C53A O34 1.428(19) .
C53A C54A 1.464(18) .
C53A H53A 0.9800 .
C54A H54A 0.9600 .
C54A H54B 0.9600 .
C54A H54C 0.9600 .
C53B O34 1.43(2) .
C53B C54B 1.465(19) .
C53B H53B 0.9800 .
C54B H54D 0.9600 .
C54B H54E 0.9600 .
C54B H54F 0.9600 .
Cl1 O1 1.39(2) .
Cl1 O3 1.406(18) .
Cl1 O2 1.457(16) .
Cl1 O4 1.461(19) .
N2 Ag1 2.124(12) 1_546
N3 Ag4 2.177(13) 1_556
N6 Ag3 2.189(13) 2_676
N8 Ag2 2.125(12) 1_556
Cl2 O7 1.377(17) .
Cl2 O6 1.381(15) .
Cl2 O5 1.392(15) .
Cl2 O8 1.419(16) .
Cl2B O5B 1.388(17) .
Cl2B O6B 1.388(17) .
Cl2B O7B 1.389(17) .
Cl2B O8B 1.402(17) .
O14 Lu2 2.516(10) 1_545
O22 Lu2 2.612(9) 2_677
O25 Lu2 2.538(9) 1_545
O31 H31A 0.8212 .
O34 H34A 0.8193 .
O1W H1WA 0.8197 .
O1W H1WB 0.8180 .
O2W H2WA 0.8207 .
O2W H2WB 0.8200 .
O3W H3WA 0.8175 .
O3W H3WB 0.8178 .
O4W H4WA 0.8186 .
O4W H4WB 0.8203 .
O5W H5WA 0.8204 .
O5W H5WB 0.8194 .
O6W H6WA 0.8196 .
O6W H6WB 0.8182 .
O7W H7WB 0.8221 .
O7W H7WA 0.8208 .
O7W H7WC 0.8210 .
