#------------------------------------------------------------------------------
#$Date: 2016-03-26 20:48:18 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180449 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/18/7211817.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211817
loop_
_publ_author_name
'Qiu, Yongcai'
'Liu, Zhihui'
'Mou, Jixia'
'Deng, Hong'
'Zeller, Matthias'
_publ_section_title
;
 Rationally designed and controlled syntheses of different series of
 4d--4f heterometallic coordination frameworks based on lanthanide
 carboxylate and Ag(IN)2 substructures
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              277
_journal_paper_doi               10.1039/b915025k
_journal_volume                  12
_journal_year                    2010
_chemical_formula_moiety         'C37 H30 Ag3 Eu2 N7 O20, Cl O4, 2(H2 O)'
_chemical_formula_sum            'C37 H34 Ag3 Cl Eu2 N7 O26'
_chemical_formula_weight         1655.69
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.234(4)
_cell_angle_beta                 97.017(4)
_cell_angle_gamma                100.010(4)
_cell_formula_units_Z            2
_cell_length_a                   8.3624(5)
_cell_length_b                   16.903(1)
_cell_length_c                   17.3261(10)
_cell_measurement_reflns_used    6798
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.00
_cell_measurement_theta_min      1.26
_cell_volume                     2386.1(2)
_computing_cell_refinement       'Apex2 v2.1-4'
_computing_data_collection       'Apex2 v2.1-4 (Bruker, 2007)'
_computing_data_reduction        'Apex2 v2.1-4'
_computing_molecular_graphics    'SHELXTL 6.14'
_computing_publication_material  'SHELXTL 6.14'
_computing_structure_refinement  'SHELXTL 6.14'
_computing_structure_solution    'SHELXTL 6.14 (Bruker, 2000-2003)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II area-detector diffractometer'
_diffrn_measurement_method       'φ and ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0720
_diffrn_reflns_av_sigmaI/netI    0.0844
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            28848
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         1.19
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.955
_exptl_absorpt_correction_T_max  0.4827
_exptl_absorpt_correction_T_min  0.4196
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.304
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1594
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.950
_refine_diff_density_min         -1.413
_refine_diff_density_rms         0.340
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     667
_refine_ls_number_reflns         8501
_refine_ls_number_restraints     63
_refine_ls_restrained_S_all      1.130
_refine_ls_R_factor_all          0.1267
_refine_ls_R_factor_gt           0.1008
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0482P)²+31.9763P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2539
_refine_ls_wR_factor_ref         0.2664
_reflns_number_gt                6200
_reflns_number_total             8501
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b915025k.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7211817
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.32922(11) 0.01684(5) 0.11256(5) 0.0237(2) Uani 1 1 d .
Eu2 Eu 0.15437(11) 0.00246(6) 0.39749(5) 0.0239(2) Uani 1 1 d .
Ag1 Ag -0.2273(3) 0.48392(11) 0.40783(15) 0.0655(6) Uani 1 1 d .
Ag2 Ag 0.4402(3) 0.51553(12) 0.26425(16) 0.0792(8) Uani 1 1 d .
Ag3 Ag 0.8452(3) 0.49032(12) -0.08270(16) 0.0751(7) Uani 1 1 d .
C1 C -0.278(4) 0.3125(14) 0.4681(18) 0.075(9) Uani 1 1 d .
H1 H -0.3242 0.3397 0.5053 0.090 Uiso 1 1 calc R
C2 C -0.268(4) 0.2334(16) 0.477(2) 0.0791(15) Uani 1 1 d .
H2 H -0.3202 0.2055 0.5141 0.095 Uiso 1 1 calc R
C3 C -0.182(2) 0.1972(11) 0.4304(12) 0.030(4) Uani 1 1 d .
C4 C -0.118(3) 0.2400(12) 0.3702(14) 0.047(6) Uani 1 1 d .
H4 H -0.0581 0.2161 0.3366 0.057 Uiso 1 1 calc R
C5 C -0.144(3) 0.3175(13) 0.3619(14) 0.054(7) Uani 1 1 d .
H5 H -0.1024 0.3453 0.3218 0.065 Uiso 1 1 calc R
C6 C -0.138(2) 0.1133(11) 0.4457(10) 0.026(4) Uani 1 1 d .
C7 C -0.327(3) 0.6458(13) 0.4556(15) 0.052(4) Uani 1 1 d .
H7 H -0.3952 0.6123 0.4836 0.062 Uiso 1 1 calc R
C8 C -0.316(3) 0.7280(13) 0.4692(15) 0.052(4) Uani 1 1 d .
H8 H -0.3738 0.7494 0.5054 0.062 Uiso 1 1 calc R
C9 C -0.217(3) 0.7764(13) 0.4270(15) 0.052(4) Uani 1 1 d .
C10 C -0.143(4) 0.7424(15) 0.3734(17) 0.077(9) Uani 1 1 d .
H10 H -0.0775 0.7750 0.3438 0.092 Uiso 1 1 calc R
C11 C -0.162(4) 0.6607(16) 0.3613(19) 0.076(9) Uani 1 1 d .
H11 H -0.1143 0.6389 0.3213 0.092 Uiso 1 1 calc R
C12 C -0.192(2) 0.8683(12) 0.4472(12) 0.030(5) Uani 1 1 d .
C13 C 0.033(2) 0.1393(12) 0.1565(11) 0.031(5) Uani 1 1 d .
C14 C 0.053(2) 0.2263(12) 0.1360(13) 0.033(5) Uani 1 1 d .
C15 C -0.038(3) 0.2787(13) 0.1644(14) 0.046(6) Uani 1 1 d .
H15A H -0.1182 0.2601 0.1949 0.055 Uiso 1 1 calc R
C16 C -0.012(3) 0.3567(14) 0.1488(16) 0.054(7) Uani 1 1 d .
H16 H -0.0748 0.3910 0.1696 0.064 Uiso 1 1 calc R
C17 C 0.183(4) 0.3348(15) 0.0751(19) 0.070(8) Uani 1 1 d .
H17 H 0.2608 0.3547 0.0438 0.084 Uiso 1 1 calc R
C18 C 0.164(3) 0.2549(14) 0.0868(16) 0.052(7) Uani 1 1 d .
H18 H 0.2233 0.2212 0.0629 0.063 Uiso 1 1 calc R
C19 C 0.371(2) 0.1304(11) 0.2780(11) 0.027(4) Uani 1 1 d .
C20 C 0.403(2) 0.2212(10) 0.2770(11) 0.025(4) Uani 1 1 d .
C21 C 0.328(4) 0.2683(14) 0.3234(17) 0.068(5) Uani 1 1 d .
H21 H 0.2662 0.2446 0.3599 0.082 Uiso 1 1 calc R
C22 C 0.343(4) 0.3472(14) 0.3168(17) 0.068(5) Uani 1 1 d .
H22 H 0.2828 0.3764 0.3454 0.082 Uiso 1 1 calc R
C23 C 0.522(4) 0.3434(14) 0.2266(17) 0.068(5) Uani 1 1 d .
H23 H 0.5930 0.3694 0.1948 0.082 Uiso 1 1 calc R
C24 C 0.502(3) 0.2605(13) 0.2277(13) 0.041(5) Uani 1 1 d .
H24 H 0.5547 0.2313 0.1952 0.049 Uiso 1 1 calc R
C25 C 0.579(2) 0.1361(11) 0.0143(11) 0.027(4) Uani 1 1 d .
C26 C 0.648(2) 0.2197(11) -0.0055(12) 0.030(5) Uani 1 1 d .
C27 C 0.578(3) 0.2849(13) 0.0120(15) 0.045(6) Uani 1 1 d .
H27 H 0.4897 0.2788 0.0406 0.054 Uiso 1 1 calc R
C28 C 0.636(3) 0.3591(13) -0.0123(17) 0.057(7) Uani 1 1 d .
H28 H 0.5828 0.4016 -0.0014 0.068 Uiso 1 1 calc R
C29 C 0.836(3) 0.3092(14) -0.0664(14) 0.048(6) Uani 1 1 d .
H29 H 0.9276 0.3181 -0.0926 0.058 Uiso 1 1 calc R
C30 C 0.786(2) 0.2334(12) -0.0472(12) 0.034(5) Uani 1 1 d .
H30 H 0.8392 0.1917 -0.0607 0.041 Uiso 1 1 calc R
C31 C 0.279(2) -0.1229(12) 0.2569(12) 0.033(5) Uani 1 1 d .
C32 C 0.327(2) -0.2049(13) 0.2566(10) 0.038(5) Uani 1 1 d D
C37 C -0.046(2) -0.0320(11) 0.0267(12) 0.031(5) Uani 1 1 d .
Cl1 Cl 0.7518(10) 0.5550(5) 0.1362(5) 0.080(2) Uani 1 1 d .
N1 N -0.225(2) 0.3531(11) 0.4085(13) 0.049(5) Uani 1 1 d .
N2 N -0.247(3) 0.6113(12) 0.4054(13) 0.056(6) Uani 1 1 d .
N3 N 0.443(3) 0.3868(11) 0.2699(13) 0.056(6) Uani 1 1 d .
N4 N 0.101(3) 0.3863(10) 0.1040(13) 0.052(5) Uani 1 1 d .
N6 N 0.402(3) -0.3608(12) 0.2567(13) 0.070(7) Uani 1 1 d D
N5 N 0.765(3) 0.3728(10) -0.0510(12) 0.050(5) Uani 1 1 d .
N7 N 0.176(2) 0.5005(11) 0.3947(11) 0.066(4) Uani 1 1 d DU
O1 O -0.210(2) 0.0792(9) 0.4968(9) 0.045(4) Uani 1 1 d .
O2 O -0.0428(18) 0.0895(9) 0.4079(9) 0.043(4) Uani 1 1 d .
O3 O -0.2643(17) 0.8938(8) 0.4967(8) 0.035(3) Uani 1 1 d .
O4 O -0.0893(16) 0.9108(8) 0.4099(9) 0.037(4) Uani 1 1 d .
O5 O 0.1432(18) 0.1022(9) 0.1408(9) 0.041(4) Uani 1 1 d .
O6 O -0.0883(18) 0.1115(9) 0.1873(10) 0.047(4) Uani 1 1 d .
O7 O 0.4900(17) 0.1328(8) 0.0689(8) 0.034(3) Uani 1 1 d .
O8 O 0.617(2) 0.0777(10) -0.0211(9) 0.049(4) Uani 1 1 d .
O9 O 0.2731(18) 0.1032(9) 0.3213(9) 0.042(4) Uani 1 1 d .
O10 O 0.4417(17) 0.0914(8) 0.2321(8) 0.036(3) Uani 1 1 d .
O11 O 0.2192(18) -0.1014(8) 0.3166(8) 0.036(3) Uani 1 1 d .
O12 O 0.3005(18) -0.0864(8) 0.1982(8) 0.039(4) Uani 1 1 d .
O13 O 0.095(3) 0.5208(15) 0.4425(14) 0.102(6) Uani 1 1 d DU
O14 O 0.109(3) 0.4803(11) 0.3262(12) 0.083(5) Uani 1 1 d DU
O15 O 0.329(2) 0.5166(12) 0.4127(14) 0.081(5) Uani 1 1 d DU
O16 O 0.586(3) 0.5144(17) 0.1028(18) 0.129(11) Uani 1 1 d .
O17 O 0.794(7) 0.5170(16) 0.206(2) 0.22(2) Uani 1 1 d .
O18 O 0.840(4) 0.5309(16) 0.0817(18) 0.142(12) Uani 1 1 d .
O19 O 0.782(4) 0.6392(15) 0.140(3) 0.192(16) Uani 1 1 d .
O21 O 0.0495(16) -0.0615(8) 0.0744(8) 0.034(3) Uani 1 1 d .
O22 O -0.1915(17) -0.0476(10) 0.0137(9) 0.045(4) Uani 1 1 d .
O1W O 0.6196(15) -0.0014(8) 0.1444(7) 0.031(3) Uani 1 1 d .
H1W H 0.6598 -0.0167 0.1065 0.046 Uiso 1 1 d R
H2W H 0.6948 0.0261 0.1761 0.046 Uiso 1 1 d R
O2W O 0.4476(14) 0.0129(10) 0.4217(9) 0.044(4) Uani 1 1 d .
H3W H 0.4679 -0.0170 0.3860 0.066 Uiso 1 1 d R
H4W H 0.3989 -0.0120 0.4528 0.066 Uiso 1 1 d R
O3W O -0.020(3) -0.0101(10) 0.2737(8) 0.078(7) Uani 1 1 d .
H6W H 0.0729 0.0204 0.2674 0.118 Uiso 1 1 d R
H5W H -0.0282 -0.0540 0.2469 0.118 Uiso 1 1 d R
O4W O 0.6256(19) 0.9644(12) 0.3146(9) 0.061(5) Uani 1 1 d .
H8W H 0.6358 1.0119 0.3013 0.092 Uiso 1 1 d R
H7W H 0.7194 0.9547 0.3269 0.092 Uiso 1 1 d R
O5W O 0.887(4) 0.8365(17) 0.1717(16) 0.126(11) Uani 1 1 d .
H9W H 0.8438 0.8597 0.1327 0.189 Uiso 1 1 d R
H10W H 0.8481 0.7872 0.1665 0.189 Uiso 1 1 d R
C33 C 0.204(5) -0.269(2) 0.2661(15) 0.053(9) Uani 0.50 1 d PDU
H33 H 0.0997 -0.2604 0.2739 0.064 Uiso 0.50 1 calc PR
C34 C 0.241(3) -0.346(3) 0.2635(19) 0.055(9) Uani 0.50 1 d PDU
H34 H 0.1581 -0.3892 0.2664 0.067 Uiso 0.50 1 calc PR
C35 C 0.505(3) -0.3007(14) 0.242(2) 0.030(6) Uani 0.50 1 d PDU
H35 H 0.6065 -0.3094 0.2312 0.036 Uiso 0.50 1 calc PR
C36 C 0.473(3) -0.2207(18) 0.2420(19) 0.029(6) Uani 0.50 1 d PDU
H36 H 0.5536 -0.1790 0.2316 0.035 Uiso 0.50 1 calc PR
C33' C 0.261(4) -0.261(2) 0.3050(19) 0.053(9) Uani 0.50 1 d PD
H33' H 0.1868 -0.2465 0.3368 0.064 Uiso 0.50 1 calc PR
C34' C 0.297(4) -0.335(3) 0.308(2) 0.055(9) Uani 0.50 1 d PD
H34' H 0.2543 -0.3693 0.3433 0.067 Uiso 0.50 1 calc PR
C35' C 0.471(4) -0.3070(16) 0.2173(19) 0.030(6) Uani 0.50 1 d PD
H35' H 0.5491 -0.3207 0.1878 0.036 Uiso 0.50 1 calc PR
C36' C 0.438(3) -0.2273(18) 0.2144(19) 0.029(6) Uani 0.50 1 d PD
H36' H 0.4926 -0.1913 0.1835 0.035 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O8 Eu1 O12 87.4(5) 2_655 .
O8 Eu1 O10 142.3(6) 2_655 .
O12 Eu1 O10 79.9(5) . .
O8 Eu1 O5 144.3(5) 2_655 .
O12 Eu1 O5 106.7(5) . .
O10 Eu1 O5 73.3(5) . .
O8 Eu1 O7 97.2(5) 2_655 .
O12 Eu1 O7 150.1(5) . .
O10 Eu1 O7 78.5(5) . .
O5 Eu1 O7 86.5(5) . .
O8 Eu1 O22 74.8(5) 2_655 2
O12 Eu1 O22 138.0(5) . 2
O10 Eu1 O22 135.3(5) . 2
O5 Eu1 O22 72.9(5) . 2
O7 Eu1 O22 71.1(5) . 2
O8 Eu1 O21 80.2(5) 2_655 .
O12 Eu1 O21 74.3(5) . .
O10 Eu1 O21 128.6(5) . .
O5 Eu1 O21 72.8(5) . .
O7 Eu1 O21 135.6(5) . .
O22 Eu1 O21 65.5(5) 2 .
O8 Eu1 O1W 71.2(5) 2_655 .
O12 Eu1 O1W 78.7(5) . .
O10 Eu1 O1W 71.5(5) . .
O5 Eu1 O1W 142.8(5) . .
O7 Eu1 O1W 75.0(5) . .
O22 Eu1 O1W 127.6(4) 2 .
O21 Eu1 O1W 141.3(5) . .
O8 Eu1 C37 81.1(5) 2_655 2
O12 Eu1 C37 122.5(5) . 2
O10 Eu1 C37 135.3(5) . 2
O5 Eu1 C37 63.5(5) . 2
O7 Eu1 C37 87.4(5) . 2
O22 Eu1 C37 18.8(5) 2 2
O21 Eu1 C37 48.3(5) . 2
O1W Eu1 C37 144.6(5) . 2
O11 Eu2 O9 92.0(5) . .
O11 Eu2 O4 86.2(5) . 1_545
O9 Eu2 O4 144.2(5) . 1_545
O11 Eu2 O1 85.8(5) . 2_556
O9 Eu2 O1 144.4(5) . 2_556
O4 Eu2 O1 71.2(5) 1_545 2_556
O11 Eu2 O2 142.8(5) . .
O9 Eu2 O2 83.3(5) . .
O4 Eu2 O2 77.0(5) 1_545 .
O1 Eu2 O2 118.5(5) 2_556 .
O11 Eu2 O2W 73.6(5) . .
O9 Eu2 O2W 72.3(5) . .
O4 Eu2 O2W 139.9(5) 1_545 .
O1 Eu2 O2W 73.1(5) 2_556 .
O2 Eu2 O2W 137.7(6) . .
O11 Eu2 O3W 71.3(5) . .
O9 Eu2 O3W 72.7(6) . .
O4 Eu2 O3W 72.9(6) 1_545 .
O1 Eu2 O3W 138.4(6) 2_556 .
O2 Eu2 O3W 72.1(6) . .
O2W Eu2 O3W 128.5(6) . .
O11 Eu2 O3 144.3(5) . 2_566
O9 Eu2 O3 82.2(5) . 2_566
O4 Eu2 O3 118.4(5) 1_545 2_566
O1 Eu2 O3 79.3(5) 2_556 2_566
O2 Eu2 O3 71.7(5) . 2_566
O2W Eu2 O3 71.1(5) . 2_566
O3W Eu2 O3 137.7(5) . 2_566
N2 Ag1 N1 176.2(8) . .
N6 Ag2 N3 172.5(8) 1_565 .
N5 Ag3 N4 171.3(8) . 2_665
N1 C1 C2 124(2) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 119(3) . .
C3 C2 H2 120.6 . .
C1 C2 H2 120.6 . .
C2 C3 C4 118(2) . .
C2 C3 C6 122(2) . .
C4 C3 C6 119.5(18) . .
C5 C4 C3 119(2) . .
C5 C4 H4 120.4 . .
C3 C4 H4 120.4 . .
N1 C5 C4 122(2) . .
N1 C5 H5 119.0 . .
C4 C5 H5 119.0 . .
O2 C6 O1 128.4(19) . .
O2 C6 C3 117.9(17) . .
O1 C6 C3 113.7(17) . .
N2 C7 C8 125(2) . .
N2 C7 H7 117.7 . .
C8 C7 H7 117.7 . .
C9 C8 C7 117(2) . .
C9 C8 H8 121.5 . .
C7 C8 H8 121.5 . .
C10 C9 C8 119(2) . .
C10 C9 C12 124(2) . .
C8 C9 C12 117(2) . .
C9 C10 C11 121(2) . .
C9 C10 H10 119.4 . .
C11 C10 H10 119.4 . .
N2 C11 C10 122(3) . .
N2 C11 H11 119.2 . .
C10 C11 H11 119.2 . .
O3 C12 O4 125.9(18) . .
O3 C12 C9 119.3(18) . .
O4 C12 C9 114.8(18) . .
O6 C13 O5 125.7(19) . .
O6 C13 C14 118.3(18) . .
O5 C13 C14 115.9(18) . .
C15 C14 C18 117.7(19) . .
C15 C14 C13 122.0(18) . .
C18 C14 C13 120.3(19) . .
C16 C15 C14 121(2) . .
C16 C15 H15A 119.4 . .
C14 C15 H15A 119.4 . .
N4 C16 C15 122(2) . .
N4 C16 H16 119.2 . .
C15 C16 H16 119.2 . .
N4 C17 C18 126(3) . .
N4 C17 H17 117.0 . .
C18 C17 H17 117.0 . .
C17 C18 C14 117(2) . .
C17 C18 H18 121.6 . .
C14 C18 H18 121.6 . .
O9 C19 O10 127.8(18) . .
O9 C19 C20 115.1(17) . .
O10 C19 C20 117.1(16) . .
C21 C20 C24 116.8(18) . .
C21 C20 C19 121.2(18) . .
C24 C20 C19 122.0(17) . .
C22 C21 C20 121(2) . .
C22 C21 H21 119.5 . .
C20 C21 H21 119.5 . .
C21 C22 N3 123(2) . .
C21 C22 H22 118.7 . .
N3 C22 H22 118.7 . .
N3 C23 C24 122(2) . .
N3 C23 H23 119.2 . .
C24 C23 H23 119.2 . .
C20 C24 C23 120(2) . .
C20 C24 H24 120.0 . .
C23 C24 H24 120.0 . .
O8 C25 O7 126.1(17) . .
O8 C25 C26 118.4(17) . .
O7 C25 C26 115.4(17) . .
C27 C26 C30 117.1(18) . .
C27 C26 C25 122.0(18) . .
C30 C26 C25 120.8(18) . .
C28 C27 C26 121(2) . .
C28 C27 H27 119.7 . .
C26 C27 H27 119.7 . .
N5 C28 C27 123(2) . .
N5 C28 H28 118.6 . .
C27 C28 H28 118.6 . .
N5 C29 C30 126(2) . .
N5 C29 H29 117.2 . .
C30 C29 H29 117.2 . .
C29 C30 C26 118(2) . .
C29 C30 H30 121.2 . .
C26 C30 H30 121.2 . .
O12 C31 O11 128.9(19) . .
O12 C31 C32 115.5(18) . .
O11 C31 C32 115.6(18) . .
C36' C32 C33' 116(3) . .
C36 C32 C33' 109(3) . .
C36' C32 C33 113(3) . .
C36 C32 C33 119(3) . .
C36' C32 C31 124(2) . .
C36 C32 C31 125(2) . .
C33' C32 C31 120(3) . .
C33 C32 C31 116(3) . .
O22 C37 O21 129(2) . .
O22 C37 C37 117(2) . 2
O21 C37 C37 114(2) . 2
O21 C37 Eu1 161.6(13) . 2
C37 C37 Eu1 76.5(14) 2 2
O18 Cl1 O19 105.8(18) . .
O18 Cl1 O17 108(2) . .
O19 Cl1 O17 118(2) . .
O18 Cl1 O16 101(2) . .
O19 Cl1 O16 116(2) . .
O17 Cl1 O16 107(2) . .
C5 N1 C1 117.6(19) . .
C5 N1 Ag1 121.3(16) . .
C1 N1 Ag1 119.7(16) . .
C7 N2 C11 116(2) . .
C7 N2 Ag1 121.2(17) . .
C11 N2 Ag1 122.0(18) . .
C23 N3 C22 118(2) . .
C23 N3 Ag2 125.7(17) . .
C22 N3 Ag2 116.2(16) . .
C17 N4 C16 116(2) . .
C17 N4 Ag3 120.3(17) . 2_665
C16 N4 Ag3 123.2(15) . 2_665
C35 N6 C34' 110(3) . .
C35' N6 C34' 116(2) . .
C35 N6 C34 115(2) . .
C35' N6 C34 108(3) . .
C35 N6 Ag2 127.4(18) . 1_545
C35' N6 Ag2 128.7(19) . 1_545
C34' N6 Ag2 115(2) . 1_545
C34 N6 Ag2 117(2) . 1_545
C28 N5 C29 116.3(18) . .
C28 N5 Ag3 118.9(15) . .
C29 N5 Ag3 124.8(16) . .
O13 N7 O14 119(2) . .
O13 N7 O15 117(2) . .
O14 N7 O15 122(2) . .
C6 O1 Eu2 138.9(14) . 2_556
C6 O2 Eu2 147.6(13) . .
C12 O3 Eu2 127.7(13) . 2_566
C12 O4 Eu2 155.2(13) . 1_565
C13 O5 Eu1 172.8(14) . .
C25 O7 Eu1 128.5(12) . .
C25 O8 Eu1 166.8(14) . 2_655
C19 O9 Eu2 153.2(14) . .
C19 O10 Eu1 128.5(12) . .
C31 O11 Eu2 149.3(13) . .
C31 O12 Eu1 161.9(14) . .
C37 O21 Eu1 117.3(12) . .
C37 O22 Eu1 119.1(14) . 2
H1W O1W H2W 108.2 . .
H3W O2W H4W 112.0 . .
H6W O3W H5W 108.0 . .
H8W O4W H7W 107.7 . .
H9W O5W H10W 109.2 . .
C34 C33 C32 118(3) . .
C34 C33 H33 121.2 . .
C32 C33 H33 121.2 . .
C33 C34 N6 123(3) . .
C33 C34 H34 118.5 . .
N6 C34 H34 118.5 . .
N6 C35 C36 124(3) . .
N6 C35 H35 118.0 . .
C36 C35 H35 118.0 . .
C32 C36 C35 121(3) . .
C32 C36 H36 119.7 . .
C35 C36 H36 119.7 . .
C34' C33' C32 123(4) . .
C34' C33' H33' 118.4 . .
C32 C33' H33' 118.4 . .
C33' C34' N6 120(3) . .
C33' C34' H34' 120.1 . .
N6 C34' H34' 120.1 . .
N6 C35' C36' 126(3) . .
N6 C35' H35' 117.2 . .
C36' C35' H35' 117.2 . .
C32 C36' C35' 119(3) . .
C32 C36' H36' 120.5 . .
C35' C36' H36' 120.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O8 2.324(15) 2_655
Eu1 O12 2.353(13) .
Eu1 O10 2.362(13) .
Eu1 O5 2.372(13) .
Eu1 O7 2.391(13) .
Eu1 O22 2.470(15) 2
Eu1 O21 2.472(12) .
Eu1 O1W 2.499(12) .
Eu1 C37 3.22(2) 2
Eu2 O11 2.362(13) .
Eu2 O9 2.369(13) .
Eu2 O4 2.376(13) 1_545
Eu2 O1 2.405(14) 2_556
Eu2 O2 2.409(14) .
Eu2 O2W 2.410(12) .
Eu2 O3W 2.417(15) .
Eu2 O3 2.438(13) 2_566
Ag1 N2 2.190(19) .
Ag1 N1 2.216(18) .
Ag2 N6 2.177(19) 1_565
Ag2 N3 2.188(18) .
Ag3 N5 2.108(17) .
Ag3 N4 2.119(17) 2_665
C1 N1 1.35(3) .
C1 C2 1.37(3) .
C1 H1 0.9300 .
C2 C3 1.33(3) .
C2 H2 0.9300 .
C3 C4 1.41(3) .
C3 C6 1.56(3) .
C4 C5 1.38(3) .
C4 H4 0.9300 .
C5 N1 1.30(3) .
C5 H5 0.9300 .
C6 O2 1.20(2) .
C6 O1 1.24(2) .
C7 N2 1.33(3) .
C7 C8 1.38(3) .
C7 H7 0.9300 .
C8 C9 1.37(3) .
C8 H8 0.9300 .
C9 C10 1.34(3) .
C9 C12 1.54(3) .
C10 C11 1.36(4) .
C10 H10 0.9300 .
C11 N2 1.34(3) .
C11 H11 0.9300 .
C12 O3 1.21(2) .
C12 O4 1.29(2) .
C13 O6 1.23(2) .
C13 O5 1.25(2) .
C13 C14 1.52(3) .
C14 C15 1.37(3) .
C14 C18 1.38(3) .
C15 C16 1.35(3) .
C15 H15A 0.9300 .
C16 N4 1.35(3) .
C16 H16 0.9300 .
C17 N4 1.31(3) .
C17 C18 1.36(3) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 O9 1.23(2) .
C19 O10 1.27(2) .
C19 C20 1.51(3) .
C20 C21 1.37(3) .
C20 C24 1.38(3) .
C21 C22 1.33(3) .
C21 H21 0.9300 .
C22 N3 1.36(3) .
C22 H22 0.9300 .
C23 N3 1.33(3) .
C23 C24 1.38(3) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 O8 1.24(2) .
C25 O7 1.27(2) .
C25 C26 1.51(2) .
C26 C27 1.37(3) .
C26 C30 1.43(3) .
C27 C28 1.37(3) .
C27 H27 0.9300 .
C28 N5 1.34(3) .
C28 H28 0.9300 .
C29 N5 1.34(3) .
C29 C30 1.35(3) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 O12 1.23(2) .
C31 O11 1.26(2) .
C31 C32 1.51(3) .
C32 C36' 1.34(3) .
C32 C36 1.34(3) .
C32 C33' 1.39(4) .
C32 C33 1.39(4) .
C37 O22 1.19(2) .
C37 O21 1.26(2) .
C37 C37 1.62(4) 2
C37 Eu1 3.22(2) 2
Cl1 O18 1.35(3) .
Cl1 O19 1.40(3) .
Cl1 O17 1.44(4) .
Cl1 O16 1.47(3) .
N4 Ag3 2.119(17) 2_665
N6 C35 1.27(3) .
N6 C35' 1.27(3) .
N6 C34' 1.43(3) .
N6 C34 1.43(3) .
N6 Ag2 2.177(19) 1_545
N7 O13 1.204(17) .
N7 O14 1.251(17) .
N7 O15 1.257(16) .
O1 Eu2 2.405(14) 2_556
O3 Eu2 2.438(13) 2_566
O4 Eu2 2.376(13) 1_565
O8 Eu1 2.324(15) 2_655
O22 Eu1 2.470(15) 2
O1W H1W 0.8223 .
O1W H2W 0.8358 .
O2W H3W 0.8294 .
O2W H4W 0.8101 .
O3W H6W 0.8749 .
O3W H5W 0.8403 .
O4W H8W 0.8412 .
O4W H7W 0.8335 .
O5W H9W 0.8711 .
O5W H10W 0.8360 .
C33 C34 1.39(6) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 C36 1.42(3) .
C35 H35 0.9300 .
C36 H36 0.9300 .
C33' C34' 1.34(6) .
C33' H33' 0.9300 .
C34' H34' 0.9300 .
C35' C36' 1.42(3) .
C35' H35' 0.9300 .
C36' H36' 0.9300 .
