#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/20/7212053.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7212053
loop_
_publ_author_name
'Liu, Qing-Xiang'
'Yang, Xiao-Qiong'
'Zhao, Xiao-Jun'
'Ge, Shu-Sheng'
'Liu, Shu-Wen'
'Zang, Yan'
'Song, Hai-bin'
'Guo, Jian-Hua'
'Wang, Xiu-Guang'
_publ_section_title
;
 Macrocyclic dinuclear silver(i) complexes based on bis(N-heterocyclic
 carbene) ligands: synthesis and structural studies
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              2245
_journal_paper_doi               10.1039/b919007d
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C31.5 H30 Ag F6 N4 O0.5 P'
_chemical_formula_weight         725.43
_chemical_name_systematic
;
?
;
_space_group_IT_number           63
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.2792(17)
_cell_length_b                   26.712(3)
_cell_length_c                   17.4205(19)
_cell_measurement_reflns_used    4532
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      20.52
_cell_measurement_theta_min      2.34
_cell_volume                     7575.3(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0494
_diffrn_reflns_av_sigmaI/netI    0.0398
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            19180
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.46
_exptl_absorpt_coefficient_mu    0.629
_exptl_absorpt_correction_T_max  0.882
_exptl_absorpt_correction_T_min  0.871
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2920.0
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.355
_refine_diff_density_min         -0.488
_refine_diff_density_rms         0.195
_refine_ls_extinction_coef       0.0018(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.269
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     216
_refine_ls_number_reflns         3586
_refine_ls_number_restraints     86
_refine_ls_restrained_S_all      1.270
_refine_ls_R_factor_all          0.1288
_refine_ls_R_factor_gt           0.0939
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2807
_refine_ls_wR_factor_ref         0.3366
_reflns_number_gt                2308
_reflns_number_total             3588
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b919007d.txt
_cod_data_source_block           090313c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      Cmcm
_cod_original_formula_sum        'C31.50 H30 Ag F6 N4 O0.50 P'
_cod_database_code               7212053
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z-1/2'
'x, -y, z-1/2'
'-x, y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, -z-1/2'
'x+1/2, -y+1/2, z-1/2'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.80477(6) 0.18427(3) 0.2500 0.0792(5) Uani 1 2 d S . .
N1 N 0.7388(4) 0.1624(2) 0.0885(3) 0.0692(15) Uani 1 1 d . A .
N2 N 0.8495(4) 0.2069(2) 0.0808(4) 0.0727(16) Uani 1 1 d . . .
C1 C 0.7982(4) 0.1840(2) 0.1301(5) 0.0669(19) Uani 1 1 d . . .
C2 C 0.7514(5) 0.1713(3) 0.0101(4) 0.0725(19) Uani 1 1 d . . .
C3 C 0.8217(5) 0.1998(3) 0.0053(5) 0.079(2) Uani 1 1 d . . .
C4 C 0.8524(6) 0.2161(4) -0.0649(5) 0.091(2) Uani 1 1 d . . .
H4A H 0.8999 0.2353 -0.0687 0.109 Uiso 1 1 calc R . .
C5 C 0.8072(7) 0.2018(5) -0.1294(7) 0.111(4) Uani 1 1 d . . .
H5A H 0.8252 0.2116 -0.1778 0.133 Uiso 1 1 calc R . .
C6 C 0.7357(8) 0.1732(4) -0.1234(6) 0.103(3) Uani 1 1 d . . .
H6A H 0.7070 0.1652 -0.1679 0.124 Uiso 1 1 calc R . .
C7 C 0.7063(5) 0.1565(4) -0.0537(6) 0.092(3) Uani 1 1 d . . .
H7A H 0.6594 0.1368 -0.0498 0.110 Uiso 1 1 calc R . .
C9 C 0.6748(9) 0.0805(3) 0.1230(10) 0.109(3) Uani 0.561(15) 1 d PGDU A 1
C10 C 0.7387(12) 0.0554(5) 0.0868(11) 0.146(7) Uani 0.561(15) 1 d PGDU A 1
H10A H 0.7741 0.0731 0.0519 0.175 Uiso 0.561(15) 1 d PR A 1
C11 C 0.7515(16) 0.0048(5) 0.1009(16) 0.302(18) Uani 0.561(15) 1 d PGU A 1
H11A H 0.7957 -0.0125 0.0759 0.362 Uiso 0.561(15) 1 d PR A 1
C12 C 0.7003(18) -0.0207(4) 0.1514(17) 0.212(12) Uani 0.561(15) 1 d PGU A 1
H12A H 0.7092 -0.0557 0.1611 0.255 Uiso 0.561(15) 1 d PR A 1
C13 C 0.6364(16) 0.0043(5) 0.1876(15) 0.204(10) Uani 0.561(15) 1 d PGU A 1
H13A H 0.5996 -0.0133 0.2269 0.245 Uiso 0.561(15) 1 d PR A 1
C14 C 0.6236(12) 0.0550(5) 0.1735(13) 0.187(10) Uani 0.561(15) 1 d PGDU A 1
H14A H 0.5794 0.0723 0.1985 0.225 Uiso 0.561(15) 1 d PR A 1
C8 C 0.6702(5) 0.1360(3) 0.1190(6) 0.095(3) Uani 1 1 d DU . .
H8A H 0.6241 0.1448 0.0874 0.114 Uiso 0.561(15) 1 d PR A 1
H8B H 0.6592 0.1487 0.1695 0.114 Uiso 0.561(15) 1 d PR A 1
H8C H 0.6234 0.1415 0.0865 0.114 Uiso 0.439(15) 1 d PR A 2
H8D H 0.6572 0.1472 0.1699 0.114 Uiso 0.439(15) 1 d PR A 2
C9' C 0.6887(9) 0.0813(3) 0.1199(17) 0.109(3) Uani 0.439(15) 1 d PGDU A 2
C10' C 0.7695(10) 0.0646(6) 0.1221(18) 0.146(7) Uani 0.439(15) 1 d PGDU A 2
H10B H 0.8137 0.0883 0.1251 0.175 Uiso 0.439(15) 1 d PR A 2
C11' C 0.7863(17) 0.0136(7) 0.120(2) 0.302(18) Uani 0.439(15) 1 d PGU A 2
H11B H 0.8422 0.0021 0.1216 0.362 Uiso 0.439(15) 1 d PR A 2
C12' C 0.722(2) -0.0207(4) 0.116(2) 0.212(12) Uani 0.439(15) 1 d PGU A 2
H12B H 0.7339 -0.0559 0.1144 0.255 Uiso 0.439(15) 1 d PR A 2
C13' C 0.6415(19) -0.0040(4) 0.114(2) 0.204(10) Uani 0.439(15) 1 d PGU A 2
H13B H 0.5973 -0.0277 0.1106 0.245 Uiso 0.439(15) 1 d PR A 2
C14' C 0.6246(12) 0.0470(5) 0.1156(19) 0.187(10) Uani 0.439(15) 1 d PGDU A 2
H14B H 0.5688 0.0585 0.1141 0.225 Uiso 0.439(15) 1 d PR A 2
C15 C 0.9228(4) 0.2345(3) 0.1006(5) 0.079(2) Uani 1 1 d . . .
H15A H 0.9214 0.2430 0.1548 0.095 Uiso 1 1 calc R . .
H15B H 0.9243 0.2655 0.0716 0.095 Uiso 1 1 calc R . .
C16 C 1.0000 0.2041(4) 0.0836(7) 0.077(3) Uani 1 2 d S . .
H16A H 1.0000 0.1740 0.1147 0.092 Uiso 1 2 calc SR . .
H16B H 1.0000 0.1942 0.0300 0.092 Uiso 1 2 calc SR . .
C17 C 0.5000 0.3589(12) 0.7500 0.167(11) Uani 1 4 d S . .
O1 O 0.5000 0.4097(6) 0.7500 0.203(11) Uani 1 4 d S . .
P1 P 0.0000 0.28447(18) 0.7500 0.0869(13) Uani 1 4 d S . .
P2 P 0.5000 0.14147(19) 0.7500 0.116(2) Uani 1 4 d S . .
F1 F 0.0000 0.3440(4) 0.7500 0.119(4) Uani 1 4 d S . .
F2 F 0.0974(5) 0.2845(3) 0.7500 0.112(2) Uani 1 2 d S . .
F3 F 0.0000 0.2841(4) 0.6597(5) 0.137(3) Uani 1 2 d S . .
F4 F 0.0000 0.2249(5) 0.7500 0.167(6) Uani 1 4 d S . .
F5 F 0.4348(12) 0.1826(7) 0.7500 0.250(10) Uani 1 2 d S . .
F6 F 0.5000 0.1472(7) 0.6603(10) 0.241(7) Uani 1 2 d S . .
F7 F 0.4261(13) 0.1110(10) 0.7500 0.353(15) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C1 174.1(4) . 10_556
C1 N1 C2 110.5(6) . .
C1 N1 C8 125.3(7) . .
C2 N1 C8 124.2(7) . .
C1 N2 C3 109.8(7) . .
C1 N2 C15 126.3(7) . .
C3 N2 C15 123.9(7) . .
N1 C1 N2 107.3(7) . .
N1 C1 Ag1 125.4(5) . .
N2 C1 Ag1 127.2(6) . .
C3 C2 C7 123.1(8) . .
C3 C2 N1 105.9(7) . .
C7 C2 N1 130.9(8) . .
C2 C3 C4 121.7(8) . .
C2 C3 N2 106.5(7) . .
C4 C3 N2 131.8(8) . .
C3 C4 C5 115.6(9) . .
C3 C4 H4A 122.2 . .
C5 C4 H4A 122.2 . .
C6 C5 C4 122.0(9) . .
C6 C5 H5A 119.0 . .
C4 C5 H5A 119.0 . .
C7 C6 C5 122.2(10) . .
C7 C6 H6A 118.9 . .
C5 C6 H6A 118.9 . .
C6 C7 C2 115.4(9) . .
C6 C7 H7A 122.3 . .
C2 C7 H7A 122.3 . .
C10 C9 C14 120.0 . .
C10 C9 C8 119.8(4) . .
C14 C9 C8 119.3(4) . .
C11 C10 C9 120.0 . .
C11 C10 H10A 120.0 . .
C9 C10 H10A 120.0 . .
C10 C11 C12 120.0 . .
C10 C11 H11A 120.0 . .
C12 C11 H11A 120.0 . .
C10 C11 H11B 103.5 . .
C12 C11 H11B 114.1 . .
H11A C11 H11B 50.1 . .
C11 C12 C13 120.0 . .
C11 C12 H12A 120.0 . .
C13 C12 H12A 120.0 . .
C11 C12 H12B 77.5 . .
C13 C12 H12B 156.1 . .
H12A C12 H12B 45.8 . .
C12 C13 C14 120.0 . .
C12 C13 H13A 121.3 . .
C14 C13 H13A 118.7 . .
C13 C14 C9 120.0 . .
C13 C14 H14A 120.0 . .
C9 C14 H14A 120.0 . .
C13 C14 H14B 107.4 . .
C9 C14 H14B 83.0 . .
H14A C14 H14B 79.8 . .
N1 C8 C9 118.2(7) . .
N1 C8 C9' 109.4(8) . .
C9 C8 C9' 9.0(9) . .
N1 C8 H8A 106.1 . .
C9 C8 H8A 108.1 . .
C9' C8 H8A 113.8 . .
N1 C8 H8B 108.3 . .
C9 C8 H8B 108.5 . .
C9' C8 H8B 111.9 . .
H8A C8 H8B 107.1 . .
N1 C8 H8C 109.1 . .
C9 C8 H8C 102.7 . .
C9' C8 H8C 108.4 . .
H8A C8 H8C 5.5 . .
H8B C8 H8C 109.8 . .
N1 C8 H8D 111.3 . .
C9 C8 H8D 106.2 . .
C9' C8 H8D 109.9 . .
H8A C8 H8D 106.3 . .
H8B C8 H8D 3.0 . .
H8C C8 H8D 108.8 . .
C10' C9' C14' 120.0 . .
C10' C9' C8 120.3(4) . .
C14' C9' C8 119.6(4) . .
C11' C10' C9' 120.0 . .
C11' C10' H10A 98.1 . .
C9' C10' H10A 88.4 . .
C11' C10' H10B 120.0 . .
C9' C10' H10B 120.0 . .
H10A C10' H10B 83.6 . .
C10' C11' C12' 120.0 . .
C10' C11' H11A 134.3 . .
C12' C11' H11A 68.3 . .
C10' C11' H11B 120.0 . .
C12' C11' H11B 120.0 . .
H11A C11' H11B 70.8 . .
C13' C12' C11' 120.0 . .
C13' C12' H11A 138.1 . .
C11' C12' H11A 44.3 . .
C13' C12' H12A 95.5 . .
C11' C12' H12A 126.2 . .
H11A C12' H12A 125.5 . .
C13' C12' H12B 120.0 . .
C11' C12' H12B 120.0 . .
H11A C12' H12B 88.4 . .
H12A C12' H12B 46.6 . .
C12' C13' C14' 120.0 . .
C12' C13' H13B 120.0 . .
C14' C13' H13B 120.0 . .
C13' C14' C9' 120.0 . .
C13' C14' H14B 120.0 . .
C9' C14' H14B 120.0 . .
N2 C15 C16 111.2(7) . .
N2 C15 H15A 109.4 . .
C16 C15 H15A 109.4 . .
N2 C15 H15B 109.4 . .
C16 C15 H15B 109.4 . .
H15A C15 H15B 108.0 . .
C15 C16 C15 110.9(9) 12_755 .
C15 C16 H16A 109.5 12_755 .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 12_755 .
C15 C16 H16B 109.5 . .
H16A C16 H16B 108.0 . .
F3 P1 F3 179.4(9) . 10_557
F3 P1 F2 90.002(4) . 3_556
F3 P1 F2 89.999(4) 10_557 3_556
F3 P1 F2 90.000(4) . .
F3 P1 F2 90.000(4) 10_557 .
F2 P1 F2 179.9(7) 3_556 .
F3 P1 F1 90.3(5) . .
F3 P1 F1 90.3(5) 10_557 .
F2 P1 F1 89.9(4) 3_556 .
F2 P1 F1 89.9(4) . .
F3 P1 F4 89.7(5) . .
F3 P1 F4 89.7(5) 10_557 .
F2 P1 F4 90.1(4) 3_556 .
F2 P1 F4 90.1(4) . .
F1 P1 F4 180.000(3) . .
F7 P2 F7 112(3) . 3_656
F7 P2 F5 80.0(14) . .
F7 P2 F5 168.1(18) 3_656 .
F7 P2 F5 168.1(17) . 3_656
F7 P2 F5 80.0(14) 3_656 3_656
F5 P2 F5 88.0(18) . 3_656
F7 P2 F6 93.1(4) . .
F7 P2 F6 93.1(4) 3_656 .
F5 P2 F6 86.0(5) . .
F5 P2 F6 86.0(5) 3_656 .
F7 P2 F6 93.1(4) . 10_557
F7 P2 F6 93.1(4) 3_656 10_557
F5 P2 F6 86.0(5) . 10_557
F5 P2 F6 86.0(5) 3_656 10_557
F6 P2 F6 168.8(13) . 10_557
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.091(9) .
Ag1 C1 2.091(9) 10_556
N1 C1 1.340(10) .
N1 C2 1.401(10) .
N1 C8 1.423(10) .
N2 C1 1.345(10) .
N2 C3 1.404(11) .
N2 C15 1.445(9) .
C2 C3 1.379(12) .
C2 C7 1.390(12) .
C3 C4 1.391(12) .
C4 C5 1.398(16) .
C4 H4A 0.9300 .
C5 C6 1.395(16) .
C5 H5A 0.9300 .
C6 C7 1.379(14) .
C6 H6A 0.9300 .
C7 H7A 0.9300 .
C9 C10 1.3900 .
C9 C14 1.3900 .
C9 C8 1.486(7) .
C10 C11 1.3900 .
C10 H10A 0.9600 .
C11 C12 1.3900 .
C11 H11A 0.9599 .
C11 H11B 1.5208 .
C12 C13 1.3900 .
C12 H12A 0.9600 .
C12 H12B 1.2637 .
C13 C14 1.3900 .
C13 H13A 1.0245 .
C14 H14A 0.9600 .
C14 H14B 1.3696 .
C8 C9' 1.491(7) .
C8 H8A 0.9600 .
C8 H8B 0.9599 .
C8 H8C 0.9599 .
C8 H8D 0.9600 .
C9' C10' 1.3900 .
C9' C14' 1.3900 .
C10' C11' 1.3900 .
C10' H10A 1.2460 .
C10' H10B 0.9599 .
C11' C12' 1.3900 .
C11' H11A 1.0507 .
C11' H11B 0.9599 .
C12' C13' 1.3900 .
C12' H11A 1.3994 .
C12' H12A 1.2428 .
C12' H12B 0.9600 .
C13' C14' 1.3900 .
C13' H13B 0.9601 .
C14' H14B 0.9600 .
C15 C16 1.525(10) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 C15 1.525(10) 12_755
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 O1 1.36(3) .
P1 F3 1.573(9) .
P1 F3 1.573(9) 10_557
P1 F2 1.586(7) 3_556
P1 F2 1.586(7) .
P1 F1 1.589(13) .
P1 F4 1.591(14) .
P2 F7 1.452(15) .
P2 F7 1.452(15) 3_656
P2 F5 1.528(13) .
P2 F5 1.528(13) 3_656
P2 F6 1.571(17) .
P2 F6 1.571(17) 10_557
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 N1 C1 N2 0.1(7) . .
C8 N1 C1 N2 -177.4(7) . .
C2 N1 C1 Ag1 177.3(5) . .
C8 N1 C1 Ag1 -0.2(10) . .
C3 N2 C1 N1 0.2(8) . .
C15 N2 C1 N1 -179.4(6) . .
C3 N2 C1 Ag1 -176.9(5) . .
C15 N2 C1 Ag1 3.4(10) . .
C1 Ag1 C1 N1 -27(4) 10_556 .
C1 Ag1 C1 N2 149(3) 10_556 .
C1 N1 C2 C3 -0.4(8) . .
C8 N1 C2 C3 177.1(7) . .
C1 N1 C2 C7 -179.9(8) . .
C8 N1 C2 C7 -2.4(12) . .
C7 C2 C3 C4 0.2(13) . .
N1 C2 C3 C4 -179.4(7) . .
C7 C2 C3 N2 -179.9(7) . .
N1 C2 C3 N2 0.5(8) . .
C1 N2 C3 C2 -0.5(9) . .
C15 N2 C3 C2 179.2(7) . .
C1 N2 C3 C4 179.4(9) . .
C15 N2 C3 C4 -0.9(14) . .
C2 C3 C4 C5 0.2(13) . .
N2 C3 C4 C5 -179.6(10) . .
C3 C4 C5 C6 0.4(16) . .
C4 C5 C6 C7 -1.4(18) . .
C5 C6 C7 C2 1.7(14) . .
C3 C2 C7 C6 -1.1(13) . .
N1 C2 C7 C6 178.3(8) . .
C14 C9 C10 C11 0.0 . .
C8 C9 C10 C11 169.1(18) . .
C9 C10 C11 C12 0.0 . .
C10 C11 C12 C13 0.0 . .
C11 C12 C13 C14 0.0 . .
C12 C13 C14 C9 0.0 . .
C10 C9 C14 C13 0.0 . .
C8 C9 C14 C13 -169.1(18) . .
C1 N1 C8 C9 -97.5(12) . .
C2 N1 C8 C9 85.4(13) . .
C1 N1 C8 C9' -95.8(14) . .
C2 N1 C8 C9' 87.0(14) . .
C10 C9 C8 N1 -10(2) . .
C14 C9 C8 N1 159.1(11) . .
C10 C9 C8 C9' -20(10) . .
C14 C9 C8 C9' 149(11) . .
N1 C8 C9' C10' 25(2) . .
C9 C8 C9' C10' -165(12) . .
N1 C8 C9' C14' -153.0(15) . .
C9 C8 C9' C14' 18(9) . .
C14' C9' C10' C11' 0.0 . .
C8 C9' C10' C11' -178(3) . .
C9' C10' C11' C12' 0.0 . .
C10' C11' C12' C13' 0.0 . .
C11' C12' C13' C14' 0.0 . .
C12' C13' C14' C9' 0.0 . .
C10' C9' C14' C13' 0.0 . .
C8 C9' C14' C13' 178(3) . .
C1 N2 C15 C16 103.8(9) . .
C3 N2 C15 C16 -75.8(10) . .
N2 C15 C16 C15 177.0(6) . 12_755
