#------------------------------------------------------------------------------
#$Date: 2016-03-26 20:56:05 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180456 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/25/7212595.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7212595
loop_
_publ_author_name
'Visinescu, Diana'
'Fabelo, Oscar'
'Ruiz-Pérez, Catalina'
'Lloret, Francesc'
'Julve, Miguel'
_publ_section_title
;
 [Fe(phen)(CN)4]−: a suitable metalloligand unit to build 3d--4f
 heterobimetallic complexes with mixed bpym-cyano bridges (phen =
 1,10-phenantroline, bpym = 2,2′-bipyrimidine)
;
_journal_issue                   8
_journal_name_full               CrystEngComm
_journal_page_first              2454
_journal_paper_doi               10.1039/c002305a
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C72 H66 Eu2 Fe4 N30 O20'
_chemical_formula_weight         2198.87
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.960(8)
_cell_angle_beta                 104.473(8)
_cell_angle_gamma                92.006(7)
_cell_formula_units_Z            1
_cell_length_a                   10.1400(6)
_cell_length_b                   15.0630(15)
_cell_length_c                   16.5770(18)
_cell_measurement_temperature    293(2)
_cell_volume                     2438.2(4)
_computing_cell_refinement       'EvalCCD (Duisenberg & Schreurs 1990-2000)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction        'EvalCCD (Duisenberg & Schreurs 1990-2000)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.959
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_sigmaI/netI    0.0471
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            25218
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         6.43
_diffrn_source                   'Enraf Nonius FR590'
_exptl_absorpt_coefficient_mu    1.922
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Brown
_exptl_crystal_density_diffrn    1.498
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1098
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.368
_refine_diff_density_min         -0.637
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     577
_refine_ls_number_reflns         10719
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0552
_refine_ls_R_factor_gt           0.0385
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0485P)²+2.8244P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0976
_refine_ls_wR_factor_ref         0.1075
_reflns_number_gt                8818
_reflns_number_total             10719
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c002305a.txt
_cod_data_source_block           compound
_cod_database_code               7212595
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.707962(17) 0.664650(12) 0.128855(12) 0.02887(7) Uani 1 1 d .
Fe1 Fe 1.12711(5) 0.45384(4) 0.27035(3) 0.03228(13) Uani 1 1 d .
Fe2 Fe 0.37264(6) 0.91797(4) 0.20856(4) 0.04037(15) Uani 1 1 d .
C1 C 0.7923(4) 0.4706(3) 0.0305(3) 0.0398(10) Uani 1 1 d .
H1 H 0.8786 0.4942 0.0598 0.048 Uiso 1 1 calc R
C2 C 0.7806(4) 0.3938(3) -0.0206(3) 0.0527(13) Uani 1 1 d .
H2 H 0.8576 0.3653 -0.0272 0.063 Uiso 1 1 calc R
C3 C 0.6525(4) 0.3595(3) -0.0620(3) 0.0469(12) Uani 1 1 d .
H3 H 0.6430 0.3068 -0.0971 0.056 Uiso 1 1 calc R
C4 C 0.5613(3) 0.4760(2) -0.0040(2) 0.0276(7) Uani 1 1 d .
C5 C 0.9841(4) 0.5317(3) 0.2326(3) 0.0340(8) Uani 1 1 d .
C6 C 0.4969(4) 0.8282(3) 0.1985(3) 0.0364(9) Uani 1 1 d .
C7 C 1.0990(4) 0.4057(3) 0.1572(3) 0.0409(10) Uani 1 1 d .
C8 C 1.2652(4) 0.5371(3) 0.2524(3) 0.0414(10) Uani 1 1 d .
C9 C 0.9863(5) 0.3693(3) 0.2834(3) 0.0497(11) Uani 1 1 d .
C10 C 0.3975(5) 0.8918(4) 0.3227(4) 0.0611(14) Uani 1 1 d .
C11 C 0.5229(5) 1.0072(3) 0.2427(4) 0.0560(13) Uani 1 1 d .
C12 C 0.2239(4) 0.8261(3) 0.1721(3) 0.0418(10) Uani 1 1 d .
C13 C 1.3261(5) 0.3099(3) 0.2706(4) 0.0553(13) Uani 1 1 d .
H13 H 1.2953 0.3026 0.2125 0.066 Uiso 1 1 calc R
C14 C 1.4257(6) 0.2557(4) 0.3097(5) 0.0773(19) Uani 1 1 d .
H14 H 1.4588 0.2118 0.2782 0.093 Uiso 1 1 calc R
C15 C 1.4745(8) 0.2671(6) 0.3943(6) 0.103(3) Uani 1 1 d .
H15 H 1.5408 0.2308 0.4208 0.124 Uiso 1 1 calc R
C16 C 1.4248(7) 0.3342(6) 0.4423(4) 0.089(2) Uani 1 1 d .
C17 C 1.3215(5) 0.3848(4) 0.3981(3) 0.0585(14) Uani 1 1 d .
C18 C 1.4697(9) 0.3566(9) 0.5318(6) 0.135(4) Uani 1 1 d .
H18 H 1.5391 0.3257 0.5633 0.162 Uiso 1 1 calc R
C19 C 1.4132(10) 0.4209(9) 0.5702(5) 0.139(4) Uani 1 1 d .
H19 H 1.4431 0.4325 0.6281 0.167 Uiso 1 1 calc R
C20 C 1.3104(8) 0.4716(6) 0.5262(4) 0.097(2) Uani 1 1 d .
C21 C 1.2642(5) 0.4523(4) 0.4386(3) 0.0598(14) Uani 1 1 d .
C22 C 1.1121(6) 0.5637(4) 0.4266(3) 0.0630(14) Uani 1 1 d .
H22 H 1.0466 0.5961 0.3938 0.076 Uiso 1 1 calc R
C23 C 1.1507(9) 0.5856(6) 0.5135(4) 0.096(2) Uani 1 1 d .
H23 H 1.1095 0.6312 0.5378 0.115 Uiso 1 1 calc R
C24 C 1.2465(9) 0.5411(7) 0.5613(4) 0.114(3) Uani 1 1 d .
H24 H 1.2716 0.5562 0.6189 0.136 Uiso 1 1 calc R
C25 C 0.1929(6) 1.0430(4) 0.2781(5) 0.0746(18) Uani 1 1 d .
H25 H 0.2251 1.0210 0.3297 0.090 Uiso 1 1 calc R
C26 C 0.0965(7) 1.1086(5) 0.2692(6) 0.087(2) Uani 1 1 d .
H26 H 0.0665 1.1306 0.3153 0.105 Uiso 1 1 calc R
C27 C 0.0468(7) 1.1402(4) 0.1939(6) 0.086(2) Uani 1 1 d .
H27 H -0.0181 1.1829 0.1886 0.104 Uiso 1 1 calc R
C28 C 0.0927(5) 1.1090(3) 0.1241(5) 0.0684(17) Uani 1 1 d .
C29 C 0.1904(5) 1.0444(3) 0.1380(4) 0.0527(13) Uani 1 1 d .
C30 C 0.0489(6) 1.1362(4) 0.0425(6) 0.078(2) Uani 1 1 d .
H30 H -0.0159 1.1788 0.0327 0.094 Uiso 1 1 calc R
C31 C 0.0970(6) 1.1032(4) -0.0204(5) 0.0751(19) Uani 1 1 d .
H31 H 0.0658 1.1237 -0.0728 0.090 Uiso 1 1 calc R
C32 C 0.1968(5) 1.0363(3) -0.0098(4) 0.0586(14) Uani 1 1 d .
C33 C 0.2417(4) 1.0092(3) 0.0707(4) 0.0496(12) Uani 1 1 d .
C34 C 0.3852(5) 0.9112(3) 0.0276(4) 0.0515(12) Uani 1 1 d .
H34 H 0.4488 0.8680 0.0391 0.062 Uiso 1 1 calc R
C35 C 0.3461(6) 0.9352(4) -0.0528(4) 0.0623(14) Uani 1 1 d .
H35 H 0.3845 0.9092 -0.0939 0.075 Uiso 1 1 calc R
C36 C 0.2503(6) 0.9976(4) -0.0724(4) 0.0660(15) Uani 1 1 d .
H36 H 0.2220 1.0135 -0.1267 0.079 Uiso 1 1 calc R
O1A O 0.6358(4) 0.7821(3) 0.0352(2) 0.0605(9) Uani 1 1 d .
O1W O 0.8948(3) 0.6787(2) 0.06845(18) 0.0398(7) Uani 1 1 d .
O2A O 0.6301(4) 0.6653(3) -0.0468(3) 0.0698(11) Uani 1 1 d .
O2W O 0.6184(3) 0.5809(2) 0.2215(2) 0.0529(8) Uani 1 1 d .
O3A O 0.5777(6) 0.7903(3) -0.0974(3) 0.0900(15) Uani 1 1 d .
O3W O 0.8594(3) 0.7694(2) 0.2262(2) 0.0629(10) Uani 1 1 d .
O4W O 0.6213(6) 0.3986(4) 0.2036(4) 0.1141(19) Uani 1 1 d .
O5W O 0.1065(6) 0.7451(5) 0.3340(5) 0.141(3) Uani 1 1 d .
O6W O 0.8105(9) 1.1815(5) 0.3712(4) 0.150(3) Uani 1 1 d .
O7W O 0.8468(9) 0.9336(6) 0.2972(7) 0.214(5) Uani 1 1 d .
N1 N 0.6818(3) 0.5135(2) 0.0397(2) 0.0309(7) Uani 1 1 d .
N1A N 0.6123(4) 0.7460(3) -0.0393(3) 0.0564(11) Uani 1 1 d .
N2 N 0.5406(3) 0.3996(2) -0.0532(2) 0.0347(7) Uani 1 1 d .
N3 N 0.8956(3) 0.5750(3) 0.2082(2) 0.0416(8) Uani 1 1 d .
N4 N 0.5672(4) 0.7726(2) 0.1886(2) 0.0417(8) Uani 1 1 d .
N5 N 1.0850(4) 0.3738(3) 0.0893(3) 0.0608(12) Uani 1 1 d .
N6 N 1.3525(4) 0.5821(3) 0.2424(3) 0.0621(12) Uani 1 1 d .
N7 N 0.9016(6) 0.3217(4) 0.2898(4) 0.0901(19) Uani 1 1 d .
N8 N 0.4109(7) 0.8768(5) 0.3893(4) 0.100(2) Uani 1 1 d .
N9 N 0.6120(6) 1.0593(4) 0.2625(4) 0.0871(17) Uani 1 1 d .
N10 N 0.1375(4) 0.7734(3) 0.1477(3) 0.0532(10) Uani 1 1 d .
N11 N 1.2735(4) 0.3718(3) 0.3133(2) 0.0433(9) Uani 1 1 d .
N12 N 1.1663(4) 0.4983(3) 0.3903(2) 0.0454(9) Uani 1 1 d .
N13 N 0.2387(4) 1.0119(3) 0.2127(3) 0.0537(11) Uani 1 1 d .
N14 N 0.3366(3) 0.9467(2) 0.0897(3) 0.0427(9) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1W Eu1 O3W 77.22(12) . .
O1W Eu1 O2W 143.11(10) . .
O3W Eu1 O2W 100.63(14) . .
O1W Eu1 O1A 78.48(11) . .
O3W Eu1 O1A 90.39(14) . .
O2W Eu1 O1A 138.30(11) . .
O1W Eu1 N4 134.60(11) . .
O3W Eu1 N4 72.33(12) . .
O2W Eu1 N4 76.28(12) . .
O1A Eu1 N4 69.01(13) . .
O1W Eu1 N3 72.62(11) . .
O3W Eu1 N3 74.33(13) . .
O2W Eu1 N3 71.44(11) . .
O1A Eu1 N3 149.58(12) . .
N4 Eu1 N3 127.52(12) . .
O1W Eu1 N1 79.45(10) . .
O3W Eu1 N1 146.08(10) . .
O2W Eu1 N1 83.80(12) . .
O1A Eu1 N1 108.68(12) . .
N4 Eu1 N1 140.25(11) . .
N3 Eu1 N1 75.40(11) . .
O1W Eu1 N2 127.02(10) . 2_665
O3W Eu1 N2 150.75(11) . 2_665
O2W Eu1 N2 70.30(11) . 2_665
O1A Eu1 N2 80.53(12) . 2_665
N4 Eu1 N2 78.46(11) . 2_665
N3 Eu1 N2 124.87(11) . 2_665
N1 Eu1 N2 62.42(9) . 2_665
O1W Eu1 O2A 66.48(11) . .
O3W Eu1 O2A 127.04(14) . .
O2W Eu1 O2A 131.55(12) . .
O1A Eu1 O2A 46.64(12) . .
N4 Eu1 O2A 107.58(12) . .
N3 Eu1 O2A 124.83(11) . .
N1 Eu1 O2A 62.30(11) . .
N2 Eu1 O2A 63.73(11) 2_665 .
O1W Eu1 N1A 71.05(10) . .
O3W Eu1 N1A 109.15(14) . .
O2W Eu1 N1A 140.19(11) . .
O1A Eu1 N1A 23.05(12) . .
N4 Eu1 N1A 88.02(12) . .
N3 Eu1 N1A 141.47(11) . .
N1 Eu1 N1A 85.76(12) . .
N2 Eu1 N1A 70.80(12) 2_665 .
O2A Eu1 N1A 23.60(11) . .
C7 Fe1 C5 87.82(17) . .
C7 Fe1 C8 88.20(19) . .
C5 Fe1 C8 92.45(17) . .
C7 Fe1 C9 89.5(2) . .
C5 Fe1 C9 86.90(19) . .
C8 Fe1 C9 177.7(2) . .
C7 Fe1 N12 176.11(17) . .
C5 Fe1 N12 96.07(17) . .
C8 Fe1 N12 91.61(18) . .
C9 Fe1 N12 90.67(19) . .
C7 Fe1 N11 93.71(17) . .
C5 Fe1 N11 177.91(16) . .
C8 Fe1 N11 89.03(17) . .
C9 Fe1 N11 91.68(19) . .
N12 Fe1 N11 82.40(16) . .
C6 Fe2 C10 87.0(2) . .
C6 Fe2 C11 90.13(19) . .
C10 Fe2 C11 90.3(3) . .
C6 Fe2 C12 88.47(17) . .
C10 Fe2 C12 90.5(2) . .
C11 Fe2 C12 178.3(2) . .
C6 Fe2 N14 95.60(17) . .
C10 Fe2 N14 176.97(19) . .
C11 Fe2 N14 91.3(2) . .
C12 Fe2 N14 88.00(18) . .
C6 Fe2 N13 177.06(19) . .
C10 Fe2 N13 95.8(2) . .
C11 Fe2 N13 90.78(18) . .
C12 Fe2 N13 90.58(16) . .
N14 Fe2 N13 81.59(18) . .
N1 C1 C2 121.6(4) . .
N1 C1 H1 119.2 . .
C2 C1 H1 119.2 . .
C1 C2 C3 118.2(4) . .
C1 C2 H2 120.9 . .
C3 C2 H2 120.9 . .
N2 C3 C2 121.8(4) . .
N2 C3 H3 119.1 . .
C2 C3 H3 119.1 . .
N2 C4 N1 126.1(3) . .
N2 C4 C4 117.3(4) . 2_665
N1 C4 C4 116.6(4) . 2_665
N3 C5 Fe1 177.0(4) . .
N4 C6 Fe2 176.5(4) . .
N5 C7 Fe1 177.4(4) . .
N6 C8 Fe1 175.7(4) . .
N7 C9 Fe1 178.0(6) . .
N8 C10 Fe2 179.4(6) . .
N9 C11 Fe2 179.5(6) . .
N10 C12 Fe2 177.2(5) . .
N11 C13 C14 122.2(6) . .
N11 C13 H13 118.9 . .
C14 C13 H13 118.9 . .
C15 C14 C13 119.6(6) . .
C15 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
C14 C15 C16 120.3(5) . .
C14 C15 H15 119.8 . .
C16 C15 H15 119.8 . .
C17 C16 C15 116.6(6) . .
C17 C16 C18 116.7(7) . .
C15 C16 C18 126.8(7) . .
N11 C17 C21 116.1(4) . .
N11 C17 C16 122.1(5) . .
C21 C17 C16 121.8(6) . .
C19 C18 C16 121.1(7) . .
C19 C18 H18 119.4 . .
C16 C18 H18 119.4 . .
C18 C19 C20 122.3(7) . .
C18 C19 H19 118.8 . .
C20 C19 H19 118.8 . .
C19 C20 C24 126.2(7) . .
C19 C20 C21 118.4(7) . .
C24 C20 C21 115.5(7) . .
N12 C21 C17 117.5(4) . .
N12 C21 C20 122.8(6) . .
C17 C21 C20 119.7(5) . .
N12 C22 C23 121.7(6) . .
N12 C22 H22 119.2 . .
C23 C22 H22 119.2 . .
C24 C23 C22 119.9(7) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C20 121.2(6) . .
C23 C24 H24 119.4 . .
C20 C24 H24 119.4 . .
N13 C25 C26 120.4(7) . .
N13 C25 H25 119.8 . .
C26 C25 H25 119.8 . .
C27 C26 C25 120.5(7) . .
C27 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C26 C27 C28 120.5(6) . .
C26 C27 H27 119.7 . .
C28 C27 H27 119.7 . .
C27 C28 C29 115.8(7) . .
C27 C28 C30 126.0(6) . .
C29 C28 C30 118.2(6) . .
N13 C29 C28 123.8(5) . .
N13 C29 C33 116.9(4) . .
C28 C29 C33 119.3(6) . .
C31 C30 C28 122.4(5) . .
C31 C30 H30 118.8 . .
C28 C30 H30 118.8 . .
C30 C31 C32 121.6(6) . .
C30 C31 H31 119.2 . .
C32 C31 H31 119.2 . .
C36 C32 C33 118.3(5) . .
C36 C32 C31 125.2(6) . .
C33 C32 C31 116.6(6) . .
N14 C33 C32 122.6(5) . .
N14 C33 C29 115.5(5) . .
C32 C33 C29 121.9(4) . .
N14 C34 C35 123.2(5) . .
N14 C34 H34 118.4 . .
C35 C34 H34 118.4 . .
C36 C35 C34 119.9(6) . .
C36 C35 H35 120.0 . .
C34 C35 H35 120.0 . .
C35 C36 C32 118.8(6) . .
C35 C36 H36 120.6 . .
C32 C36 H36 120.6 . .
N1A O1A Eu1 107.3(3) . .
N1A O2A Eu1 90.4(3) . .
C4 N1 C1 116.1(3) . .
C4 N1 Eu1 122.9(2) . .
C1 N1 Eu1 120.8(2) . .
O3A N1A O2A 124.1(5) . .
O3A N1A O1A 120.2(5) . .
O2A N1A O1A 115.6(4) . .
O3A N1A Eu1 169.8(4) . .
O2A N1A Eu1 66.0(3) . .
O1A N1A Eu1 49.6(2) . .
C4 N2 C3 116.2(3) . .
C4 N2 Eu1 120.7(2) . 2_665
C3 N2 Eu1 123.2(3) . 2_665
C5 N3 Eu1 169.7(3) . .
C6 N4 Eu1 164.8(4) . .
C13 N11 C17 119.2(4) . .
C13 N11 Fe1 128.8(3) . .
C17 N11 Fe1 112.0(3) . .
C22 N12 C21 118.9(4) . .
C22 N12 Fe1 129.2(4) . .
C21 N12 Fe1 112.0(3) . .
C25 N13 C29 119.0(5) . .
C25 N13 Fe2 128.1(4) . .
C29 N13 Fe2 112.9(3) . .
C34 N14 C33 117.1(4) . .
C34 N14 Fe2 129.7(3) . .
C33 N14 Fe2 113.1(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1W 2.365(3) .
Eu1 O3W 2.367(3) .
Eu1 O2W 2.393(3) .
Eu1 O1A 2.464(4) .
Eu1 N4 2.501(3) .
Eu1 N3 2.532(4) .
Eu1 N1 2.573(3) .
Eu1 N2 2.627(3) 2_665
Eu1 O2A 2.821(5) .
Eu1 N1A 3.088(5) .
Fe1 C7 1.899(5) .
Fe1 C5 1.914(4) .
Fe1 C8 1.942(5) .
Fe1 C9 1.944(5) .
Fe1 N12 1.979(4) .
Fe1 N11 1.998(3) .
Fe2 C6 1.905(4) .
Fe2 C10 1.923(7) .
Fe2 C11 1.934(5) .
Fe2 C12 1.952(5) .
Fe2 N14 2.001(4) .
Fe2 N13 2.004(4) .
C1 N1 1.346(4) .
C1 C2 1.356(6) .
C1 H1 0.9300 .
C2 C3 1.368(6) .
C2 H2 0.9300 .
C3 N2 1.337(5) .
C3 H3 0.9300 .
C4 N2 1.330(5) .
C4 N1 1.333(5) .
C4 C4 1.488(6) 2_665
C5 N3 1.140(5) .
C6 N4 1.146(5) .
C7 N5 1.158(6) .
C8 N6 1.150(6) .
C9 N7 1.131(7) .
C10 N8 1.122(8) .
C11 N9 1.139(7) .
C12 N10 1.131(6) .
C13 N11 1.328(6) .
C13 C14 1.389(7) .
C13 H13 0.9300 .
C14 C15 1.358(11) .
C14 H14 0.9300 .
C15 C16 1.417(11) .
C15 H15 0.9300 .
C16 C17 1.408(7) .
C16 C18 1.444(12) .
C17 N11 1.363(6) .
C17 C21 1.393(8) .
C18 C19 1.336(13) .
C18 H18 0.9300 .
C19 C20 1.405(12) .
C19 H19 0.9300 .
C20 C24 1.409(11) .
C20 C21 1.412(8) .
C21 N12 1.361(6) .
C22 N12 1.318(6) .
C22 C23 1.402(8) .
C22 H22 0.9300 .
C23 C24 1.331(11) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 N13 1.336(7) .
C25 C26 1.406(8) .
C25 H25 0.9300 .
C26 C27 1.357(11) .
C26 H26 0.9300 .
C27 C28 1.402(10) .
C27 H27 0.9300 .
C28 C29 1.405(6) .
C28 C30 1.415(10) .
C29 N13 1.354(7) .
C29 C33 1.415(8) .
C30 C31 1.325(10) .
C30 H30 0.9300 .
C31 C32 1.444(7) .
C31 H31 0.9300 .
C32 C36 1.382(9) .
C32 C33 1.398(8) .
C33 N14 1.369(5) .
C34 N14 1.328(6) .
C34 C35 1.377(8) .
C34 H34 0.9300 .
C35 C36 1.375(8) .
C35 H35 0.9300 .
C36 H36 0.9300 .
O1A N1A 1.266(6) .
O2A N1A 1.236(5) .
O3A N1A 1.206(6) .
N2 Eu1 2.627(3) 2_665
