#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:08:33 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180467 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/36/7213635.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7213635
loop_
_publ_author_name
'Li, Bo'
'Huang, Ren-Wu'
'Yao, Hong-Chang'
'Zang, Shuang-Quan'
'Mak, Thomas C. W.'
_publ_section_title
;
 Silver(i)--organic frameworks assembled with flexible supramolecular
 synthons with a pendant ethynide arm attached to the heteroaryl skeleton
;
_journal_issue                   4
_journal_name_full               CrystEngComm
_journal_page_first              723
_journal_paper_doi               10.1039/c3ce41752b
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C70 H58 Ag9 N9 O22 S7'
_chemical_formula_weight         2572.50
_chemical_name_systematic
;
?
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.46(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.346(3)
_cell_length_b                   24.558(5)
_cell_length_c                   22.739(5)
_cell_measurement_reflns_used    11874
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      29.0681
_cell_measurement_theta_min      1.9112
_cell_volume                     8080(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0463
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            18965
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.12
_exptl_absorpt_coefficient_mu    2.391
_exptl_absorpt_correction_T_max  0.6728
_exptl_absorpt_correction_T_min  0.6463
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS(2009)
_exptl_crystal_density_diffrn    2.115
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5008
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.167
_refine_diff_density_min         -1.359
_refine_diff_density_rms         0.179
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.0(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1046
_refine_ls_number_reflns         8356
_refine_ls_number_restraints     181
_refine_ls_restrained_S_all      1.084
_refine_ls_R_factor_all          0.0827
_refine_ls_R_factor_gt           0.0763
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1283P)²+110.0252P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2095
_refine_ls_wR_factor_ref         0.2161
_reflns_number_gt                7404
_reflns_number_total             8356
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41752b.txt
_cod_data_source_block           1a
_cod_original_sg_symbol_H-M      'C c'
_cod_database_code               7213635
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C4 C 0.3951(17) 0.9254(12) 0.7990(15) 0.089(10) Uani 1 1 d D . 4
Ag1 Ag 0.3590(4) 0.74533(8) 0.81536(16) 0.0551(4) Uani 1 1 d . . 4
Ag2 Ag 0.5269(4) 0.88856(8) 0.82803(17) 0.0586(5) Uani 1 1 d U . 4
Ag3 Ag 0.7216(4) 0.88488(8) 0.79523(16) 0.0584(5) Uani 1 1 d U . 4
Ag4 Ag 0.1359(4) 0.74187(10) 0.78966(17) 0.0697(6) Uani 1 1 d U . 4
Ag5 Ag 0.4834(5) 0.63848(9) 0.84874(17) 0.0682(6) Uani 1 1 d . . 4
Ag6 Ag 0.4116(4) 1.00338(8) 0.85958(16) 0.0643(5) Uani 1 1 d . . 4
Ag7 Ag 0.5564(4) 0.77332(9) 0.82933(17) 0.0707(6) Uani 1 1 d . . 4
Ag8 Ag 0.3666(5) 0.75596(13) 0.67627(18) 0.0904(8) Uani 1 1 d . . 4
Ag9 Ag 0.3607(5) 0.85805(10) 0.85866(19) 0.0882(7) Uani 1 1 d . . 4
O1 O 0.0838(10) 0.8452(6) 0.8825(6) 0.043(3) Uani 1 1 d . . 4
O2 O 0.1830(11) 0.9895(6) 0.7668(7) 0.051(4) Uani 1 1 d . . 4
O3 O 0.6282(12) 0.6419(6) 0.7505(7) 0.052(4) Uani 1 1 d . . 4
O4 O 0.8671(11) 0.7859(7) 0.8899(6) 0.052(4) Uani 1 1 d . . 4
O5 O 0.5598(18) 1.0088(11) 0.9359(10) 0.112(10) Uani 1 1 d . . 4
O6 O 0.634(3) 0.9663(16) 0.8011(16) 0.153(5) Uani 1 1 d U . 4
O7 O 0.5760(15) 0.7180(8) 0.9288(6) 0.071(6) Uani 1 1 d . . 4
O8 O 0.3425(18) 0.9145(11) 0.9448(11) 0.097(5) Uani 1 1 d U . 4
O9 O 0.429(2) 0.9198(16) 1.0467(10) 0.145(13) Uani 1 1 d . . 4
O10 O 0.455(3) 0.8743(15) 0.9828(16) 0.144(11) Uani 1 1 d U . 4
O11 O 0.371(2) 0.7016(13) 0.5869(12) 0.115(8) Uani 1 1 d U . 4
O12 O 0.317(2) 0.6223(16) 0.5513(15) 0.143(11) Uani 1 1 d U . 4
O13 O 0.3017(18) 0.6525(10) 0.6305(10) 0.095(7) Uani 1 1 d . . 4
O14 O 0.381(3) 0.6381(16) 0.9260(16) 0.153(11) Uani 1 1 d . A 4
O15 O 0.287(2) 0.6312(13) 0.8188(10) 0.138(13) Uani 1 1 d . A 4
O16 O 0.242(2) 0.609(3) 0.904(2) 0.29(4) Uani 1 1 d D A 4
O17 O 0.2596(19) 0.8289(12) 0.6716(12) 0.111(8) Uani 1 1 d U . 4
O18 O 0.1990(17) 0.7614(13) 0.6997(11) 0.103(7) Uani 1 1 d U . 4
O19 O 0.1386(19) 0.8327(16) 0.6906(14) 0.136(12) Uani 1 1 d U . 4
O20' O 0.637(5) 0.813(3) 0.712(3) 0.105(10) Uani 0.42(4) 1 d P . 4
O20 O 0.611(3) 0.8582(19) 0.697(2) 0.105(10) Uani 0.58(4) 1 d PDU . 2
O21 O 0.539(2) 0.7794(11) 0.6575(12) 0.112(6) Uani 1 1 d D . .
O22 O 0.486(2) 0.8341(15) 0.7050(14) 0.144(12) Uani 1 1 d DU . .
S1 S 0.0035(6) 0.8762(3) 0.7590(3) 0.0512(13) Uani 1 1 d . . .
S2 S 0.1829(6) 0.9874(3) 0.8850(3) 0.0517(13) Uani 1 1 d . . .
S3 S 0.7361(6) 0.6574(2) 0.8706(3) 0.0504(13) Uani 1 1 d . . .
S4 S 0.8225(6) 0.7560(2) 0.7664(3) 0.0482(13) Uani 1 1 d . . .
S6 S 0.6179(6) 0.9567(4) 0.9621(3) 0.096(3) Uani 1 1 d DU . .
S7 S 0.5381(7) 0.7502(4) 0.9703(4) 0.093(3) Uani 1 1 d D . .
N1 N -0.1566(14) 0.9017(8) 0.7618(10) 0.053(5) Uani 1 1 d . . .
N2 N 0.0518(16) 1.0561(7) 0.8761(8) 0.053(5) Uani 1 1 d . . .
N3 N 0.8578(12) 0.5861(7) 0.8764(9) 0.047(4) Uani 1 1 d . . .
N4 N 0.9879(14) 0.7257(8) 0.7670(9) 0.054(5) Uani 1 1 d . . .
N5 N 0.406(2) 0.9012(13) 0.9962(15) 0.097(5) Uani 1 1 d . . .
N6 N 0.3327(19) 0.6592(12) 0.5896(12) 0.078(6) Uani 1 1 d U . .
N7 N 0.305(3) 0.6204(18) 0.880(2) 0.153(11) Uani 1 1 d D . .
N8 N 0.197(2) 0.8116(18) 0.6807(14) 0.103(7) Uani 1 1 d U . .
N9 N 0.552(2) 0.8217(11) 0.6887(15) 0.112(6) Uani 1 1 d DU . .
C1 C 0.2711(15) 0.7820(9) 0.8560(11) 0.056(6) Uani 1 1 d D . .
C2 C 0.2150(19) 0.7983(10) 0.8788(14) 0.069(8) Uani 1 1 d D . .
C3 C 0.1592(16) 0.8238(14) 0.9177(12) 0.076(10) Uani 1 1 d . . .
H3A H 0.1453 0.7959 0.9434 0.092 Uiso 1 1 calc R . 4
H3B H 0.1965 0.8515 0.9452 0.092 Uiso 1 1 calc R . 4
C5 C 0.3199(15) 0.9459(9) 0.7746(9) 0.048(5) Uani 1 1 d D . .
C6 C 0.2312(17) 0.9643(12) 0.7334(10) 0.061(7) Uani 1 1 d . . .
H6A H 0.2401 0.9895 0.7031 0.073 Uiso 1 1 calc R B 4
H6B H 0.1961 0.9334 0.7110 0.073 Uiso 1 1 calc R B 4
C7 C 0.4569(18) 0.7132(9) 0.7766(12) 0.062(7) Uani 1 1 d D . .
C8 C 0.4930(15) 0.6865(10) 0.7468(9) 0.050(5) Uani 1 1 d D . .
C9 C 0.5475(17) 0.6623(9) 0.7128(12) 0.058(6) Uani 1 1 d . . .
H9A H 0.5121 0.6334 0.6866 0.070 Uiso 1 1 calc R . 4
H9B H 0.5601 0.6896 0.6859 0.070 Uiso 1 1 calc R . 4
C10 C 0.6486(17) 0.8412(12) 0.8588(12) 0.064(6) Uani 1 1 d DU . .
C11 C 0.7259(17) 0.8253(9) 0.8867(10) 0.058(6) Uani 1 1 d D . .
C12 C 0.8223(15) 0.8066(11) 0.9292(11) 0.055(6) Uani 1 1 d . . .
H12A H 0.8567 0.8370 0.9531 0.066 Uiso 1 1 calc R . 4
H12B H 0.8166 0.7787 0.9579 0.066 Uiso 1 1 calc R . 4
C13 C 0.0376(14) 0.8811(10) 0.9057(10) 0.056(6) Uani 1 1 d D . .
C14 C 0.0617(16) 0.8911(11) 0.9722(10) 0.052(6) Uani 1 1 d . . .
H14 H 0.1106 0.8716 0.9993 0.063 Uiso 1 1 calc R . .
C15 C 0.0187(17) 0.9260(9) 0.9962(10) 0.053(5) Uani 1 1 d . . .
H15 H 0.0374 0.9310 1.0391 0.063 Uiso 1 1 calc R . .
C16 C -0.0590(17) 0.9570(11) 0.9549(12) 0.064(7) Uani 1 1 d U . .
H16 H -0.0873 0.9847 0.9700 0.077 Uiso 1 1 calc R . .
C17 C -0.0916(17) 0.9417(11) 0.8858(11) 0.062(6) Uani 1 1 d U . .
H17 H -0.1453 0.9569 0.8582 0.074 Uiso 1 1 calc R . .
C18 C -0.0413(14) 0.9059(9) 0.8653(10) 0.055(6) Uani 1 1 d D . .
C19 C -0.0740(13) 0.8961(8) 0.7991(9) 0.038(4) Uani 1 1 d . . .
C20 C -0.1679(17) 0.8951(9) 0.6997(10) 0.050(5) Uani 1 1 d . . .
C21 C -0.085(2) 0.8833(9) 0.6866(13) 0.064(7) Uani 1 1 d . . .
C22 C -0.078(2) 0.8749(12) 0.6267(12) 0.071(7) Uani 1 1 d U . .
H22 H -0.0240 0.8645 0.6191 0.085 Uiso 1 1 calc R . .
C23 C -0.166(2) 0.8850(11) 0.5795(13) 0.066(5) Uani 1 1 d U . .
H23 H -0.1689 0.8806 0.5382 0.079 Uiso 1 1 calc R . .
C24 C -0.237(2) 0.8989(12) 0.5884(12) 0.065(5) Uani 1 1 d U . .
H24 H -0.2888 0.9072 0.5542 0.078 Uiso 1 1 calc R . .
C25 C -0.2436(19) 0.9027(12) 0.6488(10) 0.064(7) Uani 1 1 d . . .
H25 H -0.3002 0.9105 0.6536 0.077 Uiso 1 1 calc R . .
C26 C 0.0895(15) 1.0075(8) 0.7344(10) 0.042(5) Uani 1 1 d . . .
C27 C 0.0503(16) 1.0034(9) 0.6769(10) 0.046(5) Uani 1 1 d . . .
H27 H 0.0831 0.9896 0.6524 0.056 Uiso 1 1 calc R . .
C28 C -0.043(2) 1.0193(10) 0.6481(13) 0.064(6) Uani 1 1 d . . .
H28 H -0.0713 1.0176 0.6051 0.077 Uiso 1 1 calc R . .
C29 C -0.092(2) 1.0383(14) 0.6882(14) 0.081(8) Uani 1 1 d U . .
H29 H -0.1518 1.0517 0.6712 0.097 Uiso 1 1 calc R . .
C30 C -0.0493(17) 1.0363(10) 0.7518(10) 0.057(6) Uani 1 1 d . . .
H30 H -0.0803 1.0434 0.7798 0.068 Uiso 1 1 calc R . .
C31 C 0.0458(15) 1.0226(9) 0.7710(13) 0.058(7) Uani 1 1 d . . .
C32 C 0.0895(16) 1.0260(9) 0.8435(9) 0.046(5) Uani 1 1 d . . .
C33 C 0.106(2) 1.0505(9) 0.9424(10) 0.058(6) Uani 1 1 d . . .
C34 C 0.1739(17) 1.0140(9) 0.9547(9) 0.047(5) Uani 1 1 d . . .
C35 C 0.2381(19) 1.0040(12) 1.0173(10) 0.061(7) Uani 1 1 d . . .
H35 H 0.2894 0.9814 1.0253 0.073 Uiso 1 1 calc R . .
C36 C 0.217(2) 1.0299(14) 1.0618(17) 0.099(10) Uani 1 1 d DU . .
H36 H 0.2524 1.0246 1.1034 0.118 Uiso 1 1 calc R . .
C37 C 0.142(2) 1.0652(14) 1.0458(10) 0.085(10) Uani 1 1 d D . .
H37 H 0.1300 1.0810 1.0795 0.102 Uiso 1 1 calc R . .
C38 C 0.0854(19) 1.0796(11) 0.9909(11) 0.063(6) Uani 1 1 d U . .
H38 H 0.0383 1.1051 0.9842 0.076 Uiso 1 1 calc R . .
C39 C 0.6999(17) 0.6240(8) 0.7271(11) 0.047(5) Uani 1 1 d . . .
C40 C 0.6814(18) 0.6237(10) 0.6624(10) 0.055(6) Uani 1 1 d . . .
H40 H 0.6248 0.6347 0.6344 0.065 Uiso 1 1 calc R . .
C41 C 0.7587(16) 0.6045(10) 0.6412(10) 0.060(6) Uani 1 1 d D . .
H41 H 0.7480 0.5977 0.5991 0.072 Uiso 1 1 calc R . .
C42 C 0.8466(16) 0.5967(11) 0.6845(11) 0.067(7) Uani 1 1 d D . .
H42 H 0.8992 0.5923 0.6733 0.081 Uiso 1 1 calc R . .
C43 C 0.848(2) 0.5963(9) 0.7457(10) 0.059(7) Uani 1 1 d . . .
H43 H 0.9042 0.5851 0.7745 0.071 Uiso 1 1 calc R . .
C44 C 0.7815(17) 0.6097(9) 0.7708(12) 0.052(6) Uani 1 1 d . . .
C45 C 0.7987(17) 0.6146(8) 0.8361(11) 0.049(5) Uani 1 1 d . . .
C46 C 0.7968(17) 0.6366(11) 0.9418(9) 0.051(6) Uani 1 1 d . . .
C47 C 0.8700(14) 0.5977(8) 0.9377(9) 0.045(5) Uani 1 1 d D . .
C48 C 0.9331(17) 0.5783(11) 0.9933(10) 0.065(6) Uani 1 1 d DU . .
H48 H 0.9765 0.5526 0.9910 0.079 Uiso 1 1 calc R . .
C49 C 0.935(3) 0.5947(18) 1.0499(18) 0.106(11) Uani 1 1 d U . .
H49 H 0.9770 0.5806 1.0861 0.128 Uiso 1 1 calc R . .
C50 C 0.8666(19) 0.6359(12) 1.0524(10) 0.064(7) Uani 1 1 d . . .
H50 H 0.8717 0.6492 1.0917 0.077 Uiso 1 1 calc R . .
C51 C 0.795(2) 0.6575(12) 1.0022(13) 0.075(8) Uani 1 1 d . . .
H51 H 0.7516 0.6821 1.0064 0.090 Uiso 1 1 calc R . .
C52 C 0.9380(15) 0.7540(9) 0.9144(9) 0.041(5) Uani 1 1 d . . .
C53 C 0.9822(17) 0.7392(12) 0.9786(9) 0.061(7) Uani 1 1 d . . .
H53 H 0.9584 0.7525 1.0085 0.073 Uiso 1 1 calc R . .
C54 C 1.057(2) 0.7066(11) 0.9968(10) 0.078(9) Uani 1 1 d . . .
H54 H 1.0885 0.7025 1.0393 0.094 Uiso 1 1 calc R . .
C55 C 1.0898(17) 0.6793(11) 0.9559(13) 0.065(7) Uani 1 1 d . . .
H55 H 1.1349 0.6525 0.9696 0.078 Uiso 1 1 calc R . .
C56 C 1.0531(16) 0.6930(10) 0.8935(10) 0.053(6) Uani 1 1 d . . .
H56 H 1.0806 0.6782 0.8663 0.064 Uiso 1 1 calc R . .
C57 C 0.9768(16) 0.7278(8) 0.8684(9) 0.040(5) Uani 1 1 d . . .
C58 C 0.9410(17) 0.7394(11) 0.8041(10) 0.058(7) Uani 1 1 d . . .
C59 C 0.836(2) 0.7468(10) 0.6928(12) 0.062(6) Uani 1 1 d U . .
C60 C 0.9226(19) 0.7296(11) 0.7005(11) 0.058(6) Uani 1 1 d U . .
C61 C 0.945(2) 0.7134(13) 0.6492(10) 0.073(9) Uani 1 1 d . . .
H61 H 1.0027 0.6978 0.6541 0.087 Uiso 1 1 calc R . .
C62 C 0.887(2) 0.7203(15) 0.5962(10) 0.088(10) Uani 1 1 d U . .
H62 H 0.9047 0.7118 0.5618 0.105 Uiso 1 1 calc R . .
C63 C 0.801(3) 0.7393(13) 0.5855(12) 0.080(8) Uani 1 1 d U . .
H63 H 0.7605 0.7456 0.5452 0.096 Uiso 1 1 calc R . .
C64 C 0.774(2) 0.7492(13) 0.6390(12) 0.073(8) Uani 1 1 d . . .
H64 H 0.7128 0.7572 0.6349 0.088 Uiso 1 1 calc R . .
C67 C 0.727(3) 0.9819(17) 0.9593(19) 0.112(12) Uani 1 1 d U . .
H67A H 0.7177 0.9978 0.9191 0.168 Uiso 1 1 calc R . .
H67B H 0.7699 0.9524 0.9661 0.168 Uiso 1 1 calc R . .
H67C H 0.7504 1.0089 0.9911 0.168 Uiso 1 1 calc R . .
C68 C 0.647(2) 0.950(2) 1.0412(4) 0.120(6) Uani 1 1 d DU . .
H68A H 0.5980 0.9649 1.0542 0.179 Uiso 1 1 calc R . .
H68B H 0.7028 0.9702 1.0614 0.179 Uiso 1 1 calc R . .
H68C H 0.6559 0.9127 1.0526 0.179 Uiso 1 1 calc R . .
C69 C 0.6298(16) 0.7873(13) 1.0164(13) 0.094(9) Uani 1 1 d DU . .
H69A H 0.6591 0.8056 0.9907 0.140 Uiso 1 1 calc R . .
H69B H 0.6734 0.7634 1.0448 0.140 Uiso 1 1 calc R . .
H69C H 0.6084 0.8137 1.0396 0.140 Uiso 1 1 calc R . .
C70 C 0.520(3) 0.709(2) 1.033(2) 0.140(16) Uani 1 1 d U . .
H70A H 0.5308 0.7309 1.0698 0.210 Uiso 1 1 d R . .
H70B H 0.5626 0.6790 1.0423 0.210 Uiso 1 1 d R . .
H70C H 0.4580 0.6956 1.0194 0.210 Uiso 1 1 d R . .
S5 S 0.5878(13) 1.0135(8) 0.7618(8) 0.157(5) Uani 1 1 d DU . .
C65 C 0.572(9) 0.984(5) 0.687(3) 0.156(5) Uani 0.49(5) 1 d PDU . 1
H65A H 0.6302 0.9809 0.6808 0.234 Uiso 0.49(5) 1 d PR . 1
H65B H 0.5307 1.0060 0.6549 0.234 Uiso 0.49(5) 1 d PR . 1
H65C H 0.5455 0.9487 0.6871 0.234 Uiso 0.49(5) 1 d PR . 1
C66 C 0.664(6) 1.058(4) 0.741(5) 0.16(2) Uani 0.49(5) 1 d PDU . 1
H66A H 0.6375 1.0936 0.7324 0.237 Uiso 0.49(5) 1 d PR . 1
H66B H 0.6737 1.0438 0.7040 0.237 Uiso 0.49(5) 1 d PR . 1
H66C H 0.7226 1.0600 0.7740 0.237 Uiso 0.49(5) 1 d PR . 1
C66' C 0.580(8) 1.0824(16) 0.784(5) 0.16(2) Uani 0.51(5) 1 d PD . 2
H66D H 0.5167 1.0923 0.7748 0.237 Uiso 0.51(5) 1 d PR . 2
H66E H 0.6087 1.1055 0.7620 0.237 Uiso 0.51(5) 1 d PR . 2
H66F H 0.6119 1.0865 0.8285 0.237 Uiso 0.51(5) 1 d PR . 2
C65' C 0.518(7) 1.000(5) 0.683(2) 0.156(5) Uani 0.51(5) 1 d PD . 2
H65D H 0.4908 1.0338 0.6652 0.234 Uiso 0.51(5) 1 d PR . 2
H65E H 0.4706 0.9737 0.6801 0.234 Uiso 0.51(5) 1 d PR . 2
H65F H 0.5576 0.9867 0.6611 0.234 Uiso 0.51(5) 1 d PR . 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C5 C4 Ag2 171(3) . .
C5 C4 Ag9 101(2) . .
Ag2 C4 Ag9 83.8(10) . .
C5 C4 Ag6 80.1(17) . .
Ag2 C4 Ag6 105.3(13) . .
Ag9 C4 Ag6 104.1(13) . .
C1 Ag1 C7 175.3(10) . .
C1 Ag1 Ag9 51.4(6) . .
C7 Ag1 Ag9 124.0(7) . .
C1 Ag1 Ag7 129.2(7) . .
C7 Ag1 Ag7 46.1(8) . .
C1 Ag1 Ag5 132.7(6) . .
C7 Ag1 Ag5 49.0(6) . .
Ag9 Ag1 Ag5 139.41(10) . .
C1 Ag1 Ag8 130.1(6) . .
C7 Ag1 Ag8 50.3(7) . .
Ag9 Ag1 Ag8 104.73(10) . .
C1 Ag1 Ag4 45.2(7) . .
C7 Ag1 Ag4 139.1(8) . .
Ag7 Ag1 Ag4 167.72(10) . .
Ag5 Ag1 Ag4 121.95(9) . .
C4 Ag2 C10 171.5(12) . .
C4 Ag2 Ag7 123.9(9) . .
C10 Ag2 Ag7 48.2(8) . .
C4 Ag2 Ag9 51.0(9) . .
C10 Ag2 Ag9 121.3(8) . .
Ag7 Ag2 Ag9 83.85(9) . .
C4 Ag2 Ag3 141.6(9) . .
C10 Ag2 Ag3 45.2(8) . .
Ag9 Ag2 Ag3 163.73(10) . .
N1 Ag3 C10 153.7(7) 1_655 .
N1 Ag3 O6 113.5(10) 1_655 .
C10 Ag3 O6 87.5(11) . .
N1 Ag3 C11 125.5(7) 1_655 .
O6 Ag3 C11 107.1(10) . .
N1 Ag3 O20' 98.2(15) 1_655 .
C10 Ag3 O20' 85.3(16) . .
O6 Ag3 O20' 116.5(18) . .
C11 Ag3 O20' 94.6(16) . .
N1 Ag3 Ag2 166.4(5) 1_655 .
C10 Ag3 Ag2 39.4(6) . .
O6 Ag3 Ag2 53.8(9) . .
C11 Ag3 Ag2 66.9(5) . .
O20' Ag3 Ag2 85.2(15) . .
N4 Ag4 C1 148.8(7) 1_455 .
N4 Ag4 C2 119.4(7) 1_455 .
N4 Ag4 O18 118.7(8) 1_455 .
C1 Ag4 O18 86.9(8) . .
C2 Ag4 O18 109.9(8) . .
N4 Ag4 Ag1 170.4(5) 1_455 .
C1 Ag4 Ag1 39.1(5) . .
C2 Ag4 Ag1 68.5(5) . .
O18 Ag4 Ag1 59.4(6) . .
N2 Ag5 C7 145.6(6) 3_545 .
N2 Ag5 C8 118.8(6) 3_545 .
N2 Ag5 Ag1 170.4(5) 3_545 .
C7 Ag5 Ag1 42.0(5) . .
C8 Ag5 Ag1 68.2(5) . .
N3 Ag6 C4 149.6(7) 3_455 .
N3 Ag6 O5 98.1(7) 3_455 .
C4 Ag6 O5 111.7(8) . .
N3 Ag6 C5 120.4(7) 3_455 .
O5 Ag6 C5 141.2(7) . .
C10 Ag7 C7 165.8(9) . .
C10 Ag7 O7 105.3(8) . .
C7 Ag7 O7 88.9(7) . .
C10 Ag7 Ag2 47.2(7) . .
C7 Ag7 Ag2 125.9(6) . .
O7 Ag7 Ag2 120.2(4) . .
C10 Ag7 Ag1 138.1(7) . .
C7 Ag7 Ag1 44.9(5) . .
O7 Ag7 Ag1 78.0(5) . .
O17 Ag8 O11 125.1(9) . .
O17 Ag8 C7 121.4(7) . .
O11 Ag8 C7 111.8(8) . .
O17 Ag8 O22 82.7(10) . .
O11 Ag8 O22 113.8(10) . .
C7 Ag8 O22 87.1(9) . .
O17 Ag8 C8 147.9(7) . .
O11 Ag8 C8 86.3(8) . .
O22 Ag8 C8 90.6(9) . .
O17 Ag8 Ag1 81.7(6) . .
O11 Ag8 Ag1 142.3(7) . .
C7 Ag8 Ag1 41.5(4) . .
O22 Ag8 Ag1 93.8(7) . .
C8 Ag8 Ag1 67.4(4) . .
C4 Ag9 C1 144.6(10) . .
C4 Ag9 O8 99.8(9) . .
C1 Ag9 O8 104.4(8) . .
C4 Ag9 Ag1 117.2(7) . .
C1 Ag9 Ag1 44.7(5) . .
O8 Ag9 Ag1 143.0(6) . .
C4 Ag9 Ag2 45.2(5) . .
C1 Ag9 Ag2 138.8(5) . .
O8 Ag9 Ag2 112.1(6) . .
C3 O1 C13 120.6(16) . .
C6 O2 C26 118.9(16) . .
C9 O3 C39 122.2(18) . .
C52 O4 C12 117.8(16) . .
S6 O5 Ag6 121.5(15) . .
S5 O6 Ag3 140(2) . .
S7 O7 Ag7 108.8(11) . .
N5 O8 Ag9 109(2) . .
N6 O11 Ag8 106(2) . .
N8 O17 Ag8 109(3) . .
N8 O18 Ag4 117(2) . .
N9 O20' Ag3 113(4) . .
N9 O22 Ag8 109(2) . .
C21 S1 C19 90.6(10) . .
C32 S2 C34 89.4(11) . .
C46 S3 C45 92.1(11) . .
C59 S4 C58 90.0(13) . .
O5 S6 C68 113.0(19) . .
O5 S6 C67 97.1(19) . .
C68 S6 C67 99(2) . .
O7 S7 C69 104.8(16) . .
O7 S7 C70 112.9(19) . .
C69 S7 C70 97(2) . .
C19 N1 C20 115(2) . .
C19 N1 Ag3 120.1(15) . 1_455
C20 N1 Ag3 119.0(15) . 1_455
C32 N2 C33 108.7(18) . .
C32 N2 Ag5 126.9(12) . 3_455
C33 N2 Ag5 114.7(13) . 3_455
C45 N3 C47 116.3(17) . .
C45 N3 Ag6 125.9(15) . 3_545
C47 N3 Ag6 115.0(13) . 3_545
C58 N4 C60 107(2) . .
C58 N4 Ag4 123.1(15) . 1_655
C60 N4 Ag4 120.9(14) . 1_655
O10 N5 O9 119(4) . .
O10 N5 O8 106(3) . .
O9 N5 O8 132(4) . .
O13 N6 O11 119(3) . .
O13 N6 O12 115(3) . .
O11 N6 O12 126(3) . .
O16 N7 O15 124(4) . .
O16 N7 O14 109(4) . .
O15 N7 O14 124(4) . .
O19 N8 O17 130(5) . .
O19 N8 O18 108(4) . .
O17 N8 O18 119(4) . .
O20 N9 O21 132(4) . .
O20 N9 O22 114(4) . .
O21 N9 O22 113(3) . .
O20 N9 O20' 57(4) . .
O21 N9 O20' 93(4) . .
O22 N9 O20' 140(4) . .
C2 C1 Ag1 173(2) . .
C2 C1 Ag9 102.8(18) . .
Ag1 C1 Ag9 83.9(7) . .
C2 C1 Ag4 79.1(17) . .
Ag1 C1 Ag4 95.7(9) . .
Ag9 C1 Ag4 138.6(10) . .
C1 C2 C3 169(3) . .
C1 C2 Ag4 71.4(16) . .
C3 C2 Ag4 119.4(16) . .
O1 C3 C2 111(2) . .
O1 C3 H3A 109.4 . .
C2 C3 H3A 109.4 . .
O1 C3 H3B 109.4 . .
C2 C3 H3B 109.4 . .
H3A C3 H3B 108.0 . .
C4 C5 C6 167(2) . .
C4 C5 Ag6 70.5(17) . .
C6 C5 Ag6 120.4(16) . .
O2 C6 C5 110.4(17) . .
O2 C6 H6A 109.6 . .
C5 C6 H6A 109.6 . .
O2 C6 H6B 109.6 . .
C5 C6 H6B 109.6 . .
H6A C6 H6B 108.1 . .
C8 C7 Ag1 163(2) . .
C8 C7 Ag7 108.0(18) . .
Ag1 C7 Ag7 89.0(9) . .
C8 C7 Ag5 88.0(15) . .
Ag1 C7 Ag5 89.1(7) . .
Ag7 C7 Ag5 102.4(11) . .
C8 C7 Ag8 86.1(17) . .
Ag1 C7 Ag8 88.2(8) . .
Ag7 C7 Ag8 107.1(9) . .
Ag5 C7 Ag8 150.3(13) . .
C7 C8 C9 170(3) . .
C7 C8 Ag5 65.1(14) . .
C9 C8 Ag5 119.8(17) . .
C7 C8 Ag8 67.2(16) . .
C9 C8 Ag8 112.0(15) . .
Ag5 C8 Ag8 124.6(8) . .
O3 C9 C8 113(2) . .
O3 C9 H9A 109.0 . .
C8 C9 H9A 109.0 . .
O3 C9 H9B 109.0 . .
C8 C9 H9B 109.0 . .
H9A C9 H9B 107.8 . .
C11 C10 Ag2 163(2) . .
C11 C10 Ag7 110(2) . .
Ag2 C10 Ag7 84.6(9) . .
C11 C10 Ag3 83.3(17) . .
Ag2 C10 Ag3 95.4(10) . .
Ag7 C10 Ag3 124.0(12) . .
C10 C11 C12 173(2) . .
C10 C11 Ag3 68.3(16) . .
C12 C11 Ag3 116.4(14) . .
O4 C12 C11 106.4(18) . .
O4 C12 H12A 110.5 . .
C11 C12 H12A 110.5 . .
O4 C12 H12B 110.5 . .
C11 C12 H12B 110.5 . .
H12A C12 H12B 108.6 . .
O1 C13 C18 119.0(18) . .
O1 C13 C14 122.2(17) . .
C18 C13 C14 119(2) . .
C15 C14 C13 124(2) . .
C15 C14 H14 118.1 . .
C13 C14 H14 118.1 . .
C14 C15 C16 119(2) . .
C14 C15 H15 120.3 . .
C16 C15 H15 120.3 . .
C15 C16 C17 116.7(19) . .
C15 C16 H16 121.7 . .
C17 C16 H16 121.7 . .
C18 C17 C16 119(2) . .
C18 C17 H17 120.5 . .
C16 C17 H17 120.5 . .
C17 C18 C13 122(2) . .
C17 C18 C19 115.4(18) . .
C13 C18 C19 122.8(19) . .
N1 C19 C18 127(2) . .
N1 C19 S1 111.8(15) . .
C18 C19 S1 121.2(14) . .
C25 C20 N1 130(2) . .
C25 C20 C21 115(2) . .
N1 C20 C21 115(2) . .
C22 C21 C20 126(3) . .
C22 C21 S1 127(2) . .
C20 C21 S1 106.9(18) . .
C21 C22 C23 109(3) . .
C21 C22 H22 125.3 . .
C23 C22 H22 125.3 . .
C24 C23 C22 126(3) . .
C24 C23 H23 116.8 . .
C22 C23 H23 116.8 . .
C23 C24 C25 122(3) . .
C23 C24 H24 118.9 . .
C25 C24 H24 118.9 . .
C20 C25 C24 120(3) . .
C20 C25 H25 119.9 . .
C24 C25 H25 119.9 . .
C27 C26 C31 122(2) . .
C27 C26 O2 123.9(19) . .
C31 C26 O2 113.7(19) . .
C26 C27 C28 121(2) . .
C26 C27 H27 119.3 . .
C28 C27 H27 119.3 . .
C27 C28 C29 117(3) . .
C27 C28 H28 121.3 . .
C29 C28 H28 121.3 . .
C30 C29 C28 119(3) . .
C30 C29 H29 120.4 . .
C28 C29 H29 120.4 . .
C29 C30 C31 114(2) . .
C29 C30 H30 122.8 . .
C31 C30 H30 122.8 . .
C26 C31 C30 125(2) . .
C26 C31 C32 124(2) . .
C30 C31 C32 110(2) . .
N2 C32 C31 120.8(19) . .
N2 C32 S2 116.5(14) . .
C31 C32 S2 122.5(17) . .
C34 C33 C38 122(2) . .
C34 C33 N2 114.6(19) . .
C38 C33 N2 123(2) . .
C33 C34 C35 123(2) . .
C33 C34 S2 110.6(16) . .
C35 C34 S2 126.0(18) . .
C36 C35 C34 114(3) . .
C36 C35 H35 122.9 . .
C34 C35 H35 122.9 . .
C35 C36 C37 120(3) . .
C35 C36 H36 120.2 . .
C37 C36 H36 120.2 . .
C38 C37 C36 130(3) . .
C38 C37 H37 114.9 . .
C36 C37 H37 114.9 . .
C37 C38 C33 110(2) . .
C37 C38 H38 124.8 . .
C33 C38 H38 124.8 . .
C44 C39 C40 125(2) . .
C44 C39 O3 116.1(19) . .
C40 C39 O3 118(2) . .
C39 C40 C41 116(2) . .
C39 C40 H40 122.1 . .
C41 C40 H40 122.1 . .
C42 C41 C40 120.0(19) . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
C43 C42 C41 114(2) . .
C43 C42 H42 123.1 . .
C41 C42 H42 123.1 . .
C44 C43 C42 131(2) . .
C44 C43 H43 114.7 . .
C42 C43 H43 114.7 . .
C39 C44 C43 113(2) . .
C39 C44 C45 123(2) . .
C43 C44 C45 123(2) . .
N3 C45 C44 123(2) . .
N3 C45 S3 111.8(16) . .
C44 C45 S3 124.8(17) . .
C51 C46 C47 122(2) . .
C51 C46 S3 129(2) . .
C47 C46 S3 109.0(14) . .
N3 C47 C48 132(2) . .
N3 C47 C46 110.1(15) . .
C48 C47 C46 118(2) . .
C49 C48 C47 123(3) . .
C49 C48 H48 118.3 . .
C47 C48 H48 118.3 . .
C48 C49 C50 117(3) . .
C48 C49 H49 121.3 . .
C50 C49 H49 121.3 . .
C51 C50 C49 127(3) . .
C51 C50 H50 116.4 . .
C49 C50 H50 116.4 . .
C50 C51 C46 112(3) . .
C50 C51 H51 123.9 . .
C46 C51 H51 123.9 . .
O4 C52 C53 129(2) . .
O4 C52 C57 115.3(16) . .
C53 C52 C57 115.7(19) . .
C54 C53 C52 122(2) . .
C54 C53 H53 119.1 . .
C52 C53 H53 119.1 . .
C53 C54 C55 123(2) . .
C53 C54 H54 118.4 . .
C55 C54 H54 118.4 . .
C54 C55 C56 118(2) . .
C54 C55 H55 121.2 . .
C56 C55 H55 121.2 . .
C55 C56 C57 124(2) . .
C55 C56 H56 117.9 . .
C57 C56 H56 117.9 . .
C56 C57 C58 122(2) . .
C56 C57 C52 116.5(18) . .
C58 C57 C52 121.7(19) . .
N4 C58 C57 120(2) . .
N4 C58 S4 116.0(16) . .
C57 C58 S4 121.8(19) . .
C64 C59 C60 122(3) . .
C64 C59 S4 127(2) . .
C60 C59 S4 110(2) . .
C59 C60 C61 120(2) . .
C59 C60 N4 117(2) . .
C61 C60 N4 124(3) . .
C62 C61 C60 118(3) . .
C62 C61 H61 120.9 . .
C60 C61 H61 120.9 . .
C61 C62 C63 124(3) . .
C61 C62 H62 117.8 . .
C63 C62 H62 117.8 . .
C62 C63 C64 117(3) . .
C62 C63 H63 121.6 . .
C64 C63 H63 121.6 . .
C59 C64 C63 118(3) . .
C59 C64 H64 121.1 . .
C63 C64 H64 121.1 . .
S6 C67 H67A 109.5 . .
S6 C67 H67B 109.5 . .
H67A C67 H67B 109.5 . .
S6 C67 H67C 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
S6 C68 H68A 109.5 . .
S6 C68 H68B 109.5 . .
H68A C68 H68B 109.5 . .
S6 C68 H68C 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
S7 C69 H69A 109.5 . .
S7 C69 H69B 109.5 . .
H69A C69 H69B 109.5 . .
S7 C69 H69C 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
S7 C70 H70A 110.0 . .
S7 C70 H70B 109.2 . .
H70A C70 H70B 109.5 . .
S7 C70 H70C 109.2 . .
H70A C70 H70C 109.5 . .
H70B C70 H70C 109.5 . .
O6 S5 C65 98(4) . .
O6 S5 C66' 129(4) . .
C65 S5 C66' 131(5) . .
O6 S5 C66 114(4) . .
C65 S5 C66 83(6) . .
C66' S5 C66 67(5) . .
O6 S5 C65' 117(4) . .
C66' S5 C65' 113(5) . .
C66 S5 C65' 94(6) . .
S5 C65 H65A 110.1 . .
S5 C65 H65B 110.8 . .
H65A C65 H65B 109.5 . .
S5 C65 H65C 107.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
S5 C65 H65E 89.2 . .
H65A C65 H65E 159.3 . .
H65B C65 H65E 68.1 . .
H65C C65 H65E 55.7 . .
H65C C65 H65F 94.4 . .
H65E C65 H65F 83.3 . .
S5 C66 H66A 109.6 . .
S5 C66 H66B 108.5 . .
H66A C66 H66B 109.5 . .
S5 C66 H66C 110.3 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
S5 C66' H66D 109.5 . .
S5 C66' H66E 108.9 . .
H66D C66' H66E 109.5 . .
S5 C66' H66F 110.0 . .
H66D C66' H66F 109.5 . .
H66E C66' H66F 109.5 . .
S5 C65' H65B 126.1 . .
S5 C65' H65C 92.3 . .
H65B C65' H65C 94.9 . .
S5 C65' H65D 107.2 . .
H65B C65' H65D 70.1 . .
H65C C65' H65D 160.0 . .
S5 C65' H65E 112.7 . .
H65B C65' H65E 118.8 . .
H65C C65' H65E 65.3 . .
H65D C65' H65E 109.5 . .
S5 C65' H65F 108.5 . .
H65C C65' H65F 58.3 . .
H65D C65' H65F 109.5 . .
H65E C65' H65F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C4 C5 1.211(10) .
C4 Ag2 2.11(2) .
C4 Ag9 2.31(3) .
C4 Ag6 2.32(3) .
Ag1 C1 2.077(19) .
Ag1 C7 2.130(19) .
Ag1 Ag9 2.935(3) .
Ag1 Ag5 3.185(3) .
Ag1 Ag8 3.214(3) .
Ag2 C10 2.11(2) .
Ag2 Ag7 2.864(3) .
Ag3 N1 2.277(19) 1_655
Ag3 C10 2.36(3) .
Ag3 O6 2.44(4) .
Ag3 C11 2.52(2) .
Ag3 O20' 2.60(7) .
Ag4 N4 2.19(2) 1_455
Ag4 C1 2.34(2) .
Ag4 C2 2.42(3) .
Ag4 O18 2.58(2) .
Ag5 N2 2.269(17) 3_545
Ag5 C7 2.40(2) .
Ag5 C8 2.65(2) .
Ag6 N3 2.273(15) 3_455
Ag6 O5 2.36(2) .
Ag6 C5 2.43(2) .
Ag7 C10 2.14(3) .
Ag7 C7 2.18(3) .
Ag7 O7 2.569(14) .
Ag8 O17 2.41(3) .
Ag8 O11 2.45(3) .
Ag8 C7 2.47(3) .
Ag8 O22 2.58(4) .
Ag8 C8 2.68(2) .
Ag9 C1 2.31(2) .
Ag9 O8 2.49(2) .
O1 C3 1.28(3) .
O1 C13 1.34(3) .
O2 C6 1.37(3) .
O2 C26 1.45(3) .
O3 C9 1.35(3) .
O3 C39 1.44(2) .
O4 C52 1.31(2) .
O4 C12 1.39(3) .
O5 S6 1.56(2) .
O6 S5 1.49(4) .
O7 S7 1.49(2) .
O8 N5 1.29(3) .
O9 N5 1.18(4) .
O10 N5 1.11(4) .
O11 N6 1.21(4) .
O12 N6 1.22(4) .
O13 N6 1.19(3) .
O14 N7 1.35(5) .
O15 N7 1.36(4) .
O16 N7 1.285(11) .
O17 N8 1.14(4) .
O18 N8 1.30(4) .
O19 N8 1.11(4) .
O20' N9 1.25(7) .
O20 N9 1.24(2) .
O21 N9 1.24(2) .
O22 N9 1.24(2) .
S1 C21 1.76(3) .
S1 C19 1.79(2) .
S2 C32 1.72(2) .
S2 C34 1.76(2) .
S3 C46 1.66(2) .
S3 C45 1.77(2) .
S4 C59 1.77(3) .
S4 C58 1.78(2) .
S6 C68 1.7102(12) .
S6 C67 1.80(4) .
S7 C69 1.7100(12) .
S7 C70 1.84(5) .
N1 C19 1.28(3) .
N1 C20 1.37(3) .
N1 Ag3 2.277(19) 1_455
N2 C32 1.31(3) .
N2 C33 1.47(3) .
N2 Ag5 2.269(17) 3_455
N3 C45 1.26(3) .
N3 C47 1.37(3) .
N3 Ag6 2.273(15) 3_545
N4 C58 1.32(3) .
N4 C60 1.51(3) .
N4 Ag4 2.19(2) 1_655
C1 C2 1.212(10) .
C2 C3 1.55(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C5 C6 1.44(3) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 C8 1.202(10) .
C8 C9 1.44(3) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.208(10) .
C11 C12 1.54(3) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C18 1.391(10) .
C13 C14 1.45(3) .
C14 C15 1.31(3) .
C14 H14 0.9300 .
C15 C16 1.46(4) .
C15 H15 0.9300 .
C16 C17 1.53(3) .
C16 H16 0.9300 .
C17 C18 1.35(3) .
C17 H17 0.9300 .
C18 C19 1.44(3) .
C20 C25 1.35(3) .
C20 C21 1.43(4) .
C21 C22 1.42(4) .
C22 C23 1.44(4) .
C22 H22 0.9300 .
C23 C24 1.23(4) .
C23 H23 0.9300 .
C24 C25 1.41(4) .
C24 H24 0.9300 .
C25 H25 0.9300 .
C26 C27 1.25(3) .
C26 C31 1.28(3) .
C27 C28 1.42(3) .
C27 H27 0.9300 .
C28 C29 1.44(4) .
C28 H28 0.9300 .
C29 C30 1.38(4) .
C29 H29 0.9300 .
C30 C31 1.42(3) .
C30 H30 0.9300 .
C31 C32 1.56(3) .
C33 C34 1.33(3) .
C33 C38 1.44(3) .
C34 C35 1.46(3) .
C35 C36 1.32(4) .
C35 H35 0.9300 .
C36 C37 1.390(10) .
C36 H36 0.9300 .
C37 C38 1.31(3) .
C37 H37 0.9300 .
C38 H38 0.9300 .
C39 C44 1.36(3) .
C39 C40 1.40(3) .
C40 C41 1.50(3) .
C40 H40 0.9300 .
C41 C42 1.393(10) .
C41 H41 0.9300 .
C42 C43 1.38(3) .
C42 H42 0.9300 .
C43 C44 1.37(3) .
C43 H43 0.9300 .
C44 C45 1.42(3) .
C46 C51 1.47(3) .
C46 C47 1.50(3) .
C47 C48 1.395(10) .
C48 C49 1.34(4) .
C48 H48 0.9300 .
C49 C50 1.47(5) .
C49 H49 0.9300 .
C50 C51 1.40(4) .
C50 H50 0.9300 .
C51 H51 0.9300 .
C52 C53 1.44(3) .
C52 C57 1.51(3) .
C53 C54 1.35(3) .
C53 H53 0.9300 .
C54 C55 1.37(4) .
C54 H54 0.9300 .
C55 C56 1.38(3) .
C55 H55 0.9300 .
C56 C57 1.41(3) .
C56 H56 0.9300 .
C57 C58 1.41(3) .
C59 C64 1.28(4) .
C59 C60 1.34(4) .
C60 C61 1.38(3) .
C61 C62 1.25(3) .
C61 H61 0.9300 .
C62 C63 1.35(5) .
C62 H62 0.9300 .
C63 C64 1.43(4) .
C63 H63 0.9300 .
C64 H64 0.9300 .
C67 H67A 0.9600 .
C67 H67B 0.9600 .
C67 H67C 0.9600 .
C68 H68A 0.9600 .
C68 H68B 0.9600 .
C68 H68C 0.9600 .
C69 H69A 0.9600 .
C69 H69B 0.9600 .
C69 H69C 0.9600 .
C70 H70A 0.9600 .
C70 H70B 0.9600 .
C70 H70C 0.9600 .
S5 C65 1.777(11) .
S5 C66' 1.782(11) .
S5 C66 1.779(11) .
S5 C65' 1.783(11) .
C65 H65A 0.9600 .
C65 H65B 0.9600 .
C65 H65C 0.9600 .
C65 H65F 0.5694 .
C66 H66A 0.9600 .
C66 H66B 0.9600 .
C66 H66C 0.9600 .
C66' H66D 0.9600 .
C66' H66E 0.9600 .
C66' H66F 0.9600 .
C65' H65B 0.7432 .
C65' H65D 0.9600 .
C65' H65E 0.9600 .
C65' H65F 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ag9 C4 Ag2 Ag7 44.6(12) . .
Ag6 C4 Ag2 Ag7 147.5(7) . .
Ag6 C4 Ag2 Ag9 102.9(14) . .
Ag9 C4 Ag2 Ag3 165.1(5) . .
Ag6 C4 Ag2 Ag3 -92.0(15) . .
C4 Ag2 Ag3 N1 21(3) . 1_655
C10 Ag2 Ag3 N1 -166(2) . 1_655
Ag7 Ag2 Ag3 N1 155(2) . 1_655
Ag9 Ag2 Ag3 N1 156(2) . 1_655
C4 Ag2 Ag3 C10 -172.4(18) . .
Ag7 Ag2 Ag3 C10 -39.0(10) . .
Ag9 Ag2 Ag3 C10 -37.9(11) . .
C4 Ag2 Ag3 O6 44.0(18) . .
C10 Ag2 Ag3 O6 -143.6(14) . .
Ag7 Ag2 Ag3 O6 177.4(10) . .
Ag9 Ag2 Ag3 O6 178.5(11) . .
C4 Ag2 Ag3 C11 179.0(15) . .
C10 Ag2 Ag3 C11 -8.6(12) . .
Ag7 Ag2 Ag3 C11 -47.6(6) . .
Ag9 Ag2 Ag3 C11 -46.6(7) . .
C4 Ag2 Ag3 O20' -84(2) . .
C10 Ag2 Ag3 O20' 88.4(18) . .
Ag7 Ag2 Ag3 O20' 49.4(15) . .
Ag9 Ag2 Ag3 O20' 50.4(15) . .
C7 Ag1 Ag4 C1 -177.1(13) . .
Ag9 Ag1 Ag4 C1 -31.3(8) . .
Ag7 Ag1 Ag4 C1 -68.3(9) . .
Ag5 Ag1 Ag4 C1 120.4(8) . .
Ag8 Ag1 Ag4 C1 -136.0(8) . .
C1 Ag1 Ag4 C2 -2.3(11) . .
C7 Ag1 Ag4 C2 -179.3(12) . .
Ag9 Ag1 Ag4 C2 -33.5(8) . .
Ag7 Ag1 Ag4 C2 -70.6(9) . .
Ag5 Ag1 Ag4 C2 118.2(8) . .
Ag8 Ag1 Ag4 C2 -138.3(8) . .
C1 Ag1 Ag4 O18 128.9(12) . .
C7 Ag1 Ag4 O18 -48.1(12) . .
Ag9 Ag1 Ag4 O18 97.7(8) . .
Ag7 Ag1 Ag4 O18 60.6(9) . .
Ag5 Ag1 Ag4 O18 -110.6(8) . .
Ag8 Ag1 Ag4 O18 -7.1(8) . .
C1 Ag1 Ag5 C7 -174.0(14) . .
Ag9 Ag1 Ag5 C7 -97.1(10) . .
Ag7 Ag1 Ag5 C7 -48.4(10) . .
Ag8 Ag1 Ag5 C7 22.4(10) . .
Ag4 Ag1 Ag5 C7 129.6(10) . .
C1 Ag1 Ag5 C8 177.9(10) . .
C7 Ag1 Ag5 C8 -8.1(11) . .
Ag9 Ag1 Ag5 C8 -105.3(5) . .
Ag7 Ag1 Ag5 C8 -56.5(5) . .
Ag8 Ag1 Ag5 C8 14.3(5) . .
Ag4 Ag1 Ag5 C8 121.5(5) . .
C5 C4 Ag6 N3 -10(3) . 3_455
Ag2 C4 Ag6 N3 163.1(11) . 3_455
Ag9 C4 Ag6 N3 -109.5(17) . 3_455
C5 C4 Ag6 O5 -178.8(18) . .
Ag2 C4 Ag6 O5 -5.6(17) . .
Ag9 C4 Ag6 O5 81.7(12) . .
Ag2 C4 Ag6 C5 173(3) . .
Ag9 C4 Ag6 C5 -99(2) . .
C4 Ag2 Ag7 C10 -176.1(15) . .
Ag9 Ag2 Ag7 C10 -142.9(10) . .
Ag3 Ag2 Ag7 C10 36.8(10) . .
C4 Ag2 Ag7 C7 20.0(13) . .
C10 Ag2 Ag7 C7 -163.9(12) . .
Ag9 Ag2 Ag7 C7 53.3(7) . .
Ag3 Ag2 Ag7 C7 -127.0(7) . .
C4 Ag2 Ag7 O7 -93.2(12) . .
C10 Ag2 Ag7 O7 82.9(11) . .
Ag9 Ag2 Ag7 O7 -59.9(6) . .
Ag3 Ag2 Ag7 O7 119.8(5) . .
C4 Ag2 Ag7 Ag1 -14.7(11) . .
C10 Ag2 Ag7 Ag1 161.5(10) . .
Ag9 Ag2 Ag7 Ag1 18.61(9) . .
Ag3 Ag2 Ag7 Ag1 -161.69(8) . .
C1 Ag1 Ag7 C10 -19.3(13) . .
C7 Ag1 Ag7 C10 159.7(13) . .
Ag9 Ag1 Ag7 C10 1.6(10) . .
Ag5 Ag1 Ag7 C10 -148.8(10) . .
Ag8 Ag1 Ag7 C10 109.7(10) . .
Ag4 Ag1 Ag7 C10 39.1(11) . .
C1 Ag1 Ag7 C7 -179.0(12) . .
Ag9 Ag1 Ag7 C7 -158.1(9) . .
Ag5 Ag1 Ag7 C7 51.6(9) . .
Ag8 Ag1 Ag7 C7 -50.0(9) . .
Ag4 Ag1 Ag7 C7 -120.6(10) . .
C1 Ag1 Ag7 O7 80.3(9) . .
C7 Ag1 Ag7 O7 -100.8(10) . .
Ag9 Ag1 Ag7 O7 101.1(4) . .
Ag5 Ag1 Ag7 O7 -49.2(4) . .
Ag8 Ag1 Ag7 O7 -150.7(4) . .
Ag4 Ag1 Ag7 O7 138.6(6) . .
C1 Ag1 Ag7 Ag2 -39.7(8) . .
C7 Ag1 Ag7 Ag2 139.2(9) . .
Ag9 Ag1 Ag7 Ag2 -18.84(9) . .
Ag5 Ag1 Ag7 Ag2 -169.21(9) . .
Ag8 Ag1 Ag7 Ag2 89.27(9) . .
Ag4 Ag1 Ag7 Ag2 18.7(4) . .
C1 Ag1 Ag8 O17 10.4(11) . .
C7 Ag1 Ag8 O17 -163.4(11) . .
Ag9 Ag1 Ag8 O17 -41.2(7) . .
Ag7 Ag1 Ag8 O17 -117.6(7) . .
Ag5 Ag1 Ag8 O17 174.7(7) . .
Ag4 Ag1 Ag8 O17 50.6(7) . .
C1 Ag1 Ag8 O11 -129.2(13) . .
C7 Ag1 Ag8 O11 56.9(14) . .
Ag9 Ag1 Ag8 O11 179.2(11) . .
Ag7 Ag1 Ag8 O11 102.7(11) . .
Ag5 Ag1 Ag8 O11 35.0(11) . .
Ag4 Ag1 Ag8 O11 -89.1(11) . .
C1 Ag1 Ag8 C7 173.8(12) . .
Ag9 Ag1 Ag8 C7 122.2(9) . .
Ag7 Ag1 Ag8 C7 45.8(9) . .
Ag5 Ag1 Ag8 C7 -21.9(9) . .
Ag4 Ag1 Ag8 C7 -146.0(9) . .
C1 Ag1 Ag8 O22 92.5(11) . .
C7 Ag1 Ag8 O22 -81.4(12) . .
Ag9 Ag1 Ag8 O22 40.9(8) . .
Ag7 Ag1 Ag8 O22 -35.6(8) . .
Ag5 Ag1 Ag8 O22 -103.3(8) . .
Ag4 Ag1 Ag8 O22 132.6(8) . .
C1 Ag1 Ag8 C8 -178.4(10) . .
C7 Ag1 Ag8 C8 7.7(10) . .
Ag9 Ag1 Ag8 C8 130.0(5) . .
Ag7 Ag1 Ag8 C8 53.5(5) . .
Ag5 Ag1 Ag8 C8 -14.2(5) . .
Ag4 Ag1 Ag8 C8 -138.3(5) . .
C5 C4 Ag9 C1 58(3) . .
Ag2 C4 Ag9 C1 -115.7(11) . .
Ag6 C4 Ag9 C1 140.1(11) . .
C5 C4 Ag9 O8 -75(2) . .
Ag2 C4 Ag9 O8 111.5(9) . .
Ag6 C4 Ag9 O8 7.2(10) . .
C5 C4 Ag9 Ag1 106.5(18) . .
Ag2 C4 Ag9 Ag1 -66.7(10) . .
Ag6 C4 Ag9 Ag1 -171.0(4) . .
C5 C4 Ag9 Ag2 173(3) . .
Ag6 C4 Ag9 Ag2 -104.3(13) . .
C1 Ag1 Ag9 C4 -141.6(11) . .
C7 Ag1 Ag9 C4 40.1(11) . .
Ag7 Ag1 Ag9 C4 59.1(7) . .
Ag5 Ag1 Ag9 C4 104.7(7) . .
Ag8 Ag1 Ag9 C4 -11.6(7) . .
Ag4 Ag1 Ag9 C4 -113.5(7) . .
C7 Ag1 Ag9 C1 -178.3(12) . .
Ag7 Ag1 Ag9 C1 -159.3(8) . .
Ag5 Ag1 Ag9 C1 -113.7(8) . .
Ag8 Ag1 Ag9 C1 130.0(8) . .
Ag4 Ag1 Ag9 C1 28.1(8) . .
C1 Ag1 Ag9 O8 41.4(13) . .
C7 Ag1 Ag9 O8 -136.9(13) . .
Ag7 Ag1 Ag9 O8 -118.0(10) . .
Ag5 Ag1 Ag9 O8 -72.3(10) . .
Ag8 Ag1 Ag9 O8 171.4(10) . .
Ag4 Ag1 Ag9 O8 69.5(10) . .
C1 Ag1 Ag9 Ag2 177.6(8) . .
C7 Ag1 Ag9 Ag2 -0.7(9) . .
Ag7 Ag1 Ag9 Ag2 18.24(9) . .
Ag5 Ag1 Ag9 Ag2 63.87(16) . .
Ag8 Ag1 Ag9 Ag2 -52.45(11) . .
Ag4 Ag1 Ag9 Ag2 -154.32(9) . .
C10 Ag2 Ag9 C4 -175.9(15) . .
Ag7 Ag2 Ag9 C4 -144.1(12) . .
Ag3 Ag2 Ag9 C4 -145.2(12) . .
C4 Ag2 Ag9 C1 127.6(14) . .
C10 Ag2 Ag9 C1 -48.3(12) . .
Ag7 Ag2 Ag9 C1 -16.5(9) . .
Ag3 Ag2 Ag9 C1 -17.6(10) . .
C4 Ag2 Ag9 O8 -81.8(13) . .
C10 Ag2 Ag9 O8 102.3(10) . .
Ag7 Ag2 Ag9 O8 134.1(6) . .
Ag3 Ag2 Ag9 O8 133.1(7) . .
C4 Ag2 Ag9 Ag1 125.0(11) . .
C10 Ag2 Ag9 Ag1 -50.9(9) . .
Ag7 Ag2 Ag9 Ag1 -19.15(9) . .
Ag3 Ag2 Ag9 Ag1 -20.2(4) . .
N3 Ag6 O5 S6 159.1(17) 3_455 .
C4 Ag6 O5 S6 -27(2) . .
C5 Ag6 O5 S6 -28(3) . .
N1 Ag3 O6 S5 51(4) 1_655 .
C10 Ag3 O6 S5 -145(4) . .
C11 Ag3 O6 S5 -166(3) . .
O20' Ag3 O6 S5 -62(4) . .
Ag2 Ag3 O6 S5 -123(4) . .
C10 Ag7 O7 S7 68.2(13) . .
C7 Ag7 O7 S7 -112.7(12) . .
Ag2 Ag7 O7 S7 19.1(13) . .
Ag1 Ag7 O7 S7 -68.8(10) . .
C4 Ag9 O8 N5 -116(2) . .
C1 Ag9 O8 N5 90(2) . .
Ag1 Ag9 O8 N5 61(2) . .
Ag2 Ag9 O8 N5 -70(2) . .
O17 Ag8 O11 N6 -101(2) . .
C7 Ag8 O11 N6 64(2) . .
O22 Ag8 O11 N6 161(2) . .
C8 Ag8 O11 N6 72(2) . .
Ag1 Ag8 O11 N6 28(3) . .
O11 Ag8 O17 N8 91(3) . .
C7 Ag8 O17 N8 -72(3) . .
O22 Ag8 O17 N8 -155(3) . .
C8 Ag8 O17 N8 -75(3) . .
Ag1 Ag8 O17 N8 -60(2) . .
N4 Ag4 O18 N8 87(3) 1_455 .
C1 Ag4 O18 N8 -74(3) . .
C2 Ag4 O18 N8 -56(3) . .
Ag1 Ag4 O18 N8 -104(3) . .
N1 Ag3 O20' N9 -134(4) 1_655 .
C10 Ag3 O20' N9 72(4) . .
O6 Ag3 O20' N9 -12(5) . .
C11 Ag3 O20' N9 99(4) . .
Ag2 Ag3 O20' N9 33(4) . .
O17 Ag8 O22 N9 -153(3) . .
O11 Ag8 O22 N9 -27(3) . .
C7 Ag8 O22 N9 85(3) . .
C8 Ag8 O22 N9 59(3) . .
Ag1 Ag8 O22 N9 126(3) . .
Ag6 O5 S6 C68 -122(2) . .
Ag6 O5 S6 C67 135.7(19) . .
Ag7 O7 S7 C69 -90.4(15) . .
Ag7 O7 S7 C70 165.1(17) . .
Ag9 O8 N5 O10 10(4) . .
Ag9 O8 N5 O9 173(4) . .
Ag8 O11 N6 O13 1(3) . .
Ag8 O11 N6 O12 176(3) . .
Ag8 O17 N8 O19 168(4) . .
Ag8 O17 N8 O18 10(4) . .
Ag4 O18 N8 O19 -27(4) . .
Ag4 O18 N8 O17 136(3) . .
Ag8 O22 N9 O20 176(3) . .
Ag8 O22 N9 O21 8(4) . .
Ag8 O22 N9 O20' -118(7) . .
Ag3 O20' N9 O20 44(4) . .
Ag3 O20' N9 O21 -175(3) . .
Ag3 O20' N9 O22 -44(8) . .
Ag7 Ag1 C1 Ag9 26.8(10) . .
Ag5 Ag1 C1 Ag9 125.9(5) . .
Ag8 Ag1 C1 Ag9 -75.7(9) . .
Ag4 Ag1 C1 Ag9 -138.4(10) . .
Ag9 Ag1 C1 Ag4 138.4(10) . .
Ag7 Ag1 C1 Ag4 165.2(2) . .
Ag5 Ag1 C1 Ag4 -95.7(8) . .
Ag8 Ag1 C1 Ag4 62.7(9) . .
C4 Ag9 C1 C2 -107(2) . .
O8 Ag9 C1 C2 25(2) . .
Ag1 Ag9 C1 C2 -180(2) . .
Ag2 Ag9 C1 C2 176.6(17) . .
C4 Ag9 C1 Ag1 72.5(14) . .
O8 Ag9 C1 Ag1 -155.7(7) . .
Ag2 Ag9 C1 Ag1 -3.7(13) . .
C4 Ag9 C1 Ag4 -19(2) . .
O8 Ag9 C1 Ag4 112.7(14) . .
Ag1 Ag9 C1 Ag4 -91.6(15) . .
Ag2 Ag9 C1 Ag4 -95.3(14) . .
N4 Ag4 C1 C2 -5(2) 1_455 .
O18 Ag4 C1 C2 142.2(18) . .
Ag1 Ag4 C1 C2 -176(2) . .
N4 Ag4 C1 Ag1 170.7(11) 1_455 .
C2 Ag4 C1 Ag1 176(2) . .
O18 Ag4 C1 Ag1 -42.1(9) . .
N4 Ag4 C1 Ag9 -102.2(17) 1_455 .
C2 Ag4 C1 Ag9 -97(2) . .
O18 Ag4 C1 Ag9 45.0(14) . .
Ag1 Ag4 C1 Ag9 87.1(14) . .
Ag9 C1 C2 C3 -48(16) . .
Ag4 C1 C2 C3 175(16) . .
Ag9 C1 C2 Ag4 137.7(11) . .
N4 Ag4 C2 C1 177.0(15) 1_455 .
O18 Ag4 C2 C1 -40.6(19) . .
Ag1 Ag4 C2 C1 2.9(14) . .
N4 Ag4 C2 C3 -2(3) 1_455 .
C1 Ag4 C2 C3 -179(4) . .
O18 Ag4 C2 C3 141(2) . .
Ag1 Ag4 C2 C3 -176(3) . .
C13 O1 C3 C2 -163(2) . .
C1 C2 C3 O1 140(15) . .
Ag4 C2 C3 O1 -46(3) . .
Ag9 C4 C5 C6 -106(13) . .
Ag6 C4 C5 C6 151(13) . .
Ag9 C4 C5 Ag6 102.5(14) . .
N3 Ag6 C5 C4 174.1(19) 3_455 .
O5 Ag6 C5 C4 2(3) . .
N3 Ag6 C5 C6 1(2) 3_455 .
C4 Ag6 C5 C6 -173(3) . .
O5 Ag6 C5 C6 -171.3(18) . .
C26 O2 C6 C5 -175.8(18) . .
C4 C5 C6 O2 170(12) . .
Ag6 C5 C6 O2 -42(3) . .
Ag9 Ag1 C7 C8 -151(7) . .
Ag7 Ag1 C7 C8 -178(8) . .
Ag5 Ag1 C7 C8 80(7) . .
Ag8 Ag1 C7 C8 -71(7) . .
Ag4 Ag1 C7 C8 -14(8) . .
Ag9 Ag1 C7 Ag7 26.5(11) . .
Ag5 Ag1 C7 Ag7 -102.4(11) . .
Ag8 Ag1 C7 Ag7 107.2(9) . .
Ag4 Ag1 C7 Ag7 163.8(3) . .
Ag9 Ag1 C7 Ag5 128.8(5) . .
Ag7 Ag1 C7 Ag5 102.4(11) . .
Ag8 Ag1 C7 Ag5 -150.5(12) . .
Ag4 Ag1 C7 Ag5 -93.9(10) . .
Ag9 Ag1 C7 Ag8 -80.7(9) . .
Ag7 Ag1 C7 Ag8 -107.2(9) . .
Ag5 Ag1 C7 Ag8 150.5(12) . .
Ag4 Ag1 C7 Ag8 56.6(11) . .
C10 Ag7 C7 C8 70(4) . .
O7 Ag7 C7 C8 -106.8(19) . .
Ag2 Ag7 C7 C8 125.9(16) . .
Ag1 Ag7 C7 C8 179(2) . .
C10 Ag7 C7 Ag1 -109(3) . .
O7 Ag7 C7 Ag1 73.9(8) . .
Ag2 Ag7 C7 Ag1 -53.5(9) . .
C10 Ag7 C7 Ag5 162(3) . .
O7 Ag7 C7 Ag5 -14.9(7) . .
Ag2 Ag7 C7 Ag5 -142.3(4) . .
Ag1 Ag7 C7 Ag5 -88.8(8) . .
C10 Ag7 C7 Ag8 -22(4) . .
O7 Ag7 C7 Ag8 161.7(8) . .
Ag2 Ag7 C7 Ag8 34.4(10) . .
Ag1 Ag7 C7 Ag8 87.8(9) . .
N2 Ag5 C7 C8 7(3) 3_545 .
Ag1 Ag5 C7 C8 -163(2) . .
N2 Ag5 C7 Ag1 170.5(10) 3_545 .
C8 Ag5 C7 Ag1 163(2) . .
N2 Ag5 C7 Ag7 -100.7(15) 3_545 .
C8 Ag5 C7 Ag7 -108.0(19) . .
Ag1 Ag5 C7 Ag7 88.8(9) . .
N2 Ag5 C7 Ag8 86(2) 3_545 .
C8 Ag5 C7 Ag8 79(2) . .
Ag1 Ag5 C7 Ag8 -84.7(18) . .
O17 Ag8 C7 C8 -176.8(16) . .
O11 Ag8 C7 C8 17.4(19) . .
O22 Ag8 C7 C8 -97.1(18) . .
Ag1 Ag8 C7 C8 164(2) . .
O17 Ag8 C7 Ag1 19.3(13) . .
O11 Ag8 C7 Ag1 -146.5(9) . .
O22 Ag8 C7 Ag1 99.0(10) . .
C8 Ag8 C7 Ag1 -164(2) . .
O17 Ag8 C7 Ag7 -69.1(12) . .
O11 Ag8 C7 Ag7 125.1(10) . .
O22 Ag8 C7 Ag7 10.6(10) . .
C8 Ag8 C7 Ag7 107.7(19) . .
Ag1 Ag8 C7 Ag7 -88.4(9) . .
O17 Ag8 C7 Ag5 104.2(19) . .
O11 Ag8 C7 Ag5 -61.6(19) . .
O22 Ag8 C7 Ag5 -176.1(19) . .
C8 Ag8 C7 Ag5 -79(2) . .
Ag1 Ag8 C7 Ag5 84.9(18) . .
Ag1 C7 C8 C9 159(10) . .
Ag7 C7 C8 C9 -19(15) . .
Ag5 C7 C8 C9 -121(14) . .
Ag8 C7 C8 C9 88(15) . .
Ag1 C7 C8 Ag5 -80(7) . .
Ag7 C7 C8 Ag5 102.3(14) . .
Ag8 C7 C8 Ag5 -150.9(11) . .
Ag1 C7 C8 Ag8 71(7) . .
Ag7 C7 C8 Ag8 -106.8(12) . .
Ag5 C7 C8 Ag8 150.9(11) . .
N2 Ag5 C8 C7 -175.3(18) 3_545 .
Ag1 Ag5 C8 C7 12.0(17) . .
N2 Ag5 C8 C9 -5(2) 3_545 .
C7 Ag5 C8 C9 170(3) . .
Ag1 Ag5 C8 C9 -177.8(19) . .
N2 Ag5 C8 Ag8 151.7(9) 3_545 .
C7 Ag5 C8 Ag8 -33.0(16) . .
Ag1 Ag5 C8 Ag8 -21.0(7) . .
O17 Ag8 C8 C7 5(3) . .
O11 Ag8 C8 C7 -163.9(18) . .
O22 Ag8 C8 C7 82.4(18) . .
Ag1 Ag8 C8 C7 -11.5(15) . .
O17 Ag8 C8 C9 -164.1(17) . .
O11 Ag8 C8 C9 26.9(17) . .
C7 Ag8 C8 C9 -169(3) . .
O22 Ag8 C8 C9 -86.9(18) . .
Ag1 Ag8 C8 C9 179.3(18) . .
O17 Ag8 C8 Ag5 38(2) . .
O11 Ag8 C8 Ag5 -131.5(12) . .
C7 Ag8 C8 Ag5 32.4(14) . .
O22 Ag8 C8 Ag5 114.7(12) . .
Ag1 Ag8 C8 Ag5 20.9(7) . .
C39 O3 C9 C8 -169.6(19) . .
C7 C8 C9 O3 76(15) . .
Ag5 C8 C9 O3 -41(3) . .
Ag8 C8 C9 O3 159.9(15) . .
Ag7 Ag2 C10 C11 -151(9) . .
Ag9 Ag2 C10 C11 -107(8) . .
Ag3 Ag2 C10 C11 85(8) . .
Ag9 Ag2 C10 Ag7 44.6(10) . .
Ag3 Ag2 C10 Ag7 -123.8(12) . .
Ag7 Ag2 C10 Ag3 123.8(12) . .
Ag9 Ag2 C10 Ag3 168.4(3) . .
C7 Ag7 C10 C11 -122(3) . .
O7 Ag7 C10 C11 54(2) . .
Ag2 Ag7 C10 C11 172(3) . .
Ag1 Ag7 C10 C11 143.2(16) . .
C7 Ag7 C10 Ag2 66(4) . .
O7 Ag7 C10 Ag2 -117.2(8) . .
Ag1 Ag7 C10 Ag2 -28.3(14) . .
C7 Ag7 C10 Ag3 -27(4) . .
O7 Ag7 C10 Ag3 149.9(11) . .
Ag2 Ag7 C10 Ag3 -92.9(13) . .
Ag1 Ag7 C10 Ag3 -121.2(11) . .
N1 Ag3 C10 C11 10(3) 1_655 .
O6 Ag3 C10 C11 -134(2) . .
O20' Ag3 C10 C11 109(2) . .
Ag2 Ag3 C10 C11 -163(2) . .
N1 Ag3 C10 Ag2 172.8(13) 1_655 .
O6 Ag3 C10 Ag2 28.7(11) . .
C11 Ag3 C10 Ag2 163(2) . .
O20' Ag3 C10 Ag2 -88.2(17) . .
N1 Ag3 C10 Ag7 -100.1(19) 1_655 .
O6 Ag3 C10 Ag7 115.8(15) . .
C11 Ag3 C10 Ag7 -110(2) . .
O20' Ag3 C10 Ag7 -1.1(19) . .
Ag2 Ag3 C10 Ag7 87.1(13) . .
Ag2 C10 C11 Ag3 -87(8) . .
Ag7 C10 C11 Ag3 123.9(16) . .
N1 Ag3 C11 C10 -174.7(17) 1_655 .
O6 Ag3 C11 C10 48(2) . .
O20' Ag3 C11 C10 -71(2) . .
Ag2 Ag3 C11 C10 11.6(17) . .
N1 Ag3 C11 C12 10(2) 1_655 .
C10 Ag3 C11 C12 -175(3) . .
O6 Ag3 C11 C12 -126.7(18) . .
O20' Ag3 C11 C12 114(2) . .
Ag2 Ag3 C11 C12 -163.4(18) . .
C52 O4 C12 C11 -161.3(19) . .
Ag3 C11 C12 O4 -49(2) . .
C3 O1 C13 C18 176(2) . .
C3 O1 C13 C14 -10(4) . .
O1 C13 C14 C15 180(2) . .
C18 C13 C14 C15 -7(4) . .
C13 C14 C15 C16 1(4) . .
C14 C15 C16 C17 6(4) . .
C15 C16 C17 C18 -8(4) . .
C16 C17 C18 C13 2(4) . .
C16 C17 C18 C19 -177(2) . .
O1 C13 C18 C17 179(2) . .
C14 C13 C18 C17 5(4) . .
O1 C13 C18 C19 -2(4) . .
C14 C13 C18 C19 -176(2) . .
C20 N1 C19 C18 174(2) . .
Ag3 N1 C19 C18 -33(3) 1_455 .
C20 N1 C19 S1 -4(2) . .
Ag3 N1 C19 S1 149.5(11) 1_455 .
C17 C18 C19 N1 -25(4) . .
C13 C18 C19 N1 156(2) . .
C17 C18 C19 S1 152.2(19) . .
C13 C18 C19 S1 -27(3) . .
C21 S1 C19 N1 5.7(18) . .
C21 S1 C19 C18 -172.1(19) . .
C19 N1 C20 C25 -174(3) . .
Ag3 N1 C20 C25 32(3) 1_455 .
C19 N1 C20 C21 -1(3) . .
Ag3 N1 C20 C21 -154.3(16) 1_455 .
C25 C20 C21 C22 -5(4) . .
N1 C20 C21 C22 -180(2) . .
C25 C20 C21 S1 179.1(19) . .
N1 C20 C21 S1 5(2) . .
C19 S1 C21 C22 179(2) . .
C19 S1 C21 C20 -5.6(17) . .
C20 C21 C22 C23 5(4) . .
S1 C21 C22 C23 -180.0(19) . .
C21 C22 C23 C24 0(4) . .
C22 C23 C24 C25 -5(5) . .
N1 C20 C25 C24 173(2) . .
C21 C20 C25 C24 0(4) . .
C23 C24 C25 C20 5(5) . .
C6 O2 C26 C27 -3(3) . .
C6 O2 C26 C31 170(2) . .
C31 C26 C27 C28 5(4) . .
O2 C26 C27 C28 177(2) . .
C26 C27 C28 C29 -3(4) . .
C27 C28 C29 C30 -5(4) . .
C28 C29 C30 C31 9(4) . .
C27 C26 C31 C30 0(4) . .
O2 C26 C31 C30 -173(2) . .
C27 C26 C31 C32 177(2) . .
O2 C26 C31 C32 5(3) . .
C29 C30 C31 C26 -7(4) . .
C29 C30 C31 C32 175(2) . .
C33 N2 C32 C31 178.9(19) . .
Ag5 N2 C32 C31 -37(3) 3_455 .
C33 N2 C32 S2 3(3) . .
Ag5 N2 C32 S2 147.1(13) 3_455 .
C26 C31 C32 N2 159(2) . .
C30 C31 C32 N2 -23(3) . .
C26 C31 C32 S2 -25(3) . .
C30 C31 C32 S2 152.3(18) . .
C34 S2 C32 N2 -0.6(19) . .
C34 S2 C32 C31 -176.0(18) . .
C32 N2 C33 C34 -6(3) . .
Ag5 N2 C33 C34 -154.1(18) 3_455 .
C32 N2 C33 C38 178(2) . .
Ag5 N2 C33 C38 29(3) 3_455 .
C38 C33 C34 C35 -6(4) . .
N2 C33 C34 C35 177(2) . .
C38 C33 C34 S2 -178(2) . .
N2 C33 C34 S2 5(3) . .
C32 S2 C34 C33 -3(2) . .
C32 S2 C34 C35 -175(2) . .
C33 C34 C35 C36 7(4) . .
S2 C34 C35 C36 178(2) . .
C34 C35 C36 C37 -3(5) . .
C35 C36 C37 C38 -2(6) . .
C36 C37 C38 C33 3(5) . .
C34 C33 C38 C37 1(4) . .
N2 C33 C38 C37 177(3) . .
C9 O3 C39 C44 173(2) . .
C9 O3 C39 C40 -6(3) . .
C44 C39 C40 C41 2(3) . .
O3 C39 C40 C41 -179.8(19) . .
C39 C40 C41 C42 -10(3) . .
C40 C41 C42 C43 14(4) . .
C41 C42 C43 C44 -10(4) . .
C40 C39 C44 C43 2(3) . .
O3 C39 C44 C43 -176.2(18) . .
C40 C39 C44 C45 175(2) . .
O3 C39 C44 C45 -3(3) . .
C42 C43 C44 C39 2(4) . .
C42 C43 C44 C45 -171(3) . .
C47 N3 C45 C44 176(2) . .
Ag6 N3 C45 C44 -24(3) 3_545 .
C47 N3 C45 S3 -7(3) . .
Ag6 N3 C45 S3 152.6(12) 3_545 .
C39 C44 C45 N3 155(2) . .
C43 C44 C45 N3 -33(4) . .
C39 C44 C45 S3 -20(3) . .
C43 C44 C45 S3 152(2) . .
C46 S3 C45 N3 2(2) . .
C46 S3 C45 C44 178(2) . .
C45 S3 C46 C51 173(3) . .
C45 S3 C46 C47 2.9(18) . .
C45 N3 C47 C48 -174(3) . .
Ag6 N3 C47 C48 24(3) 3_545 .
C45 N3 C47 C46 9(3) . .
Ag6 N3 C47 C46 -152.6(15) 3_545 .
C51 C46 C47 N3 -178(2) . .
S3 C46 C47 N3 -7(2) . .
C51 C46 C47 C48 5(3) . .
S3 C46 C47 C48 175.5(19) . .
N3 C47 C48 C49 180(3) . .
C46 C47 C48 C49 -4(4) . .
C47 C48 C49 C50 -1(5) . .
C48 C49 C50 C51 5(6) . .
C49 C50 C51 C46 -4(5) . .
C47 C46 C51 C50 -1(4) . .
S3 C46 C51 C50 -170(2) . .
C12 O4 C52 C53 -4(4) . .
C12 O4 C52 C57 173.3(19) . .
O4 C52 C53 C54 -178(3) . .
C57 C52 C53 C54 4(4) . .
C52 C53 C54 C55 -9(5) . .
C53 C54 C55 C56 11(5) . .
C54 C55 C56 C57 -9(4) . .
C55 C56 C57 C58 -179(3) . .
C55 C56 C57 C52 4(3) . .
O4 C52 C57 C56 -179.6(19) . .
C53 C52 C57 C56 -2(3) . .
O4 C52 C57 C58 3(3) . .
C53 C52 C57 C58 -179(2) . .
C60 N4 C58 C57 165(2) . .
Ag4 N4 C58 C57 -47(3) 1_655 .
C60 N4 C58 S4 1(3) . .
Ag4 N4 C58 S4 148.9(14) 1_655 .
C56 C57 C58 N4 -12(4) . .
C52 C57 C58 N4 165(2) . .
C56 C57 C58 S4 151.4(19) . .
C52 C57 C58 S4 -31(3) . .
C59 S4 C58 N4 -3(2) . .
C59 S4 C58 C57 -167(2) . .
C58 S4 C59 C64 176(3) . .
C58 S4 C59 C60 4(2) . .
C64 C59 C60 C61 0(4) . .
S4 C59 C60 C61 172(2) . .
C64 C59 C60 N4 -177(2) . .
S4 C59 C60 N4 -4(3) . .
C58 N4 C60 C59 2(3) . .
Ag4 N4 C60 C59 -146.8(17) 1_655 .
C58 N4 C60 C61 -174(3) . .
Ag4 N4 C60 C61 37(3) 1_655 .
C59 C60 C61 C62 7(4) . .
N4 C60 C61 C62 -177(3) . .
C60 C61 C62 C63 -5(5) . .
C61 C62 C63 C64 -3(5) . .
C60 C59 C64 C63 -7(4) . .
S4 C59 C64 C63 -179(2) . .
C62 C63 C64 C59 9(4) . .
Ag3 O6 S5 C65 22(6) . .
Ag3 O6 S5 C66' -143(5) . .
Ag3 O6 S5 C66 -64(6) . .
Ag3 O6 S5 C65' 45(6) . .
