#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:10:59 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180469 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/38/7213869.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7213869
loop_
_publ_author_name
'Ding, Caixia'
'Rui, Xing'
'Wang, Cheng'
'Xie, Yongshu'
_publ_section_title
;
 Coordination polymers of a multipyridyl and pyrazolyl ligand with
 conformational flexibility: syntheses, structures and luminescence
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              1010
_journal_paper_doi               10.1039/c3ce42147c
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C32 H24 Cl2 N10 Zn'
_chemical_formula_weight         684.88
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           29
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2ac'
_symmetry_space_group_name_H-M   'P c a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.6653(18)
_cell_length_b                   11.3358(11)
_cell_length_c                   14.1097(12)
_cell_measurement_reflns_used    2353
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.896
_cell_measurement_theta_min      2.532
_cell_volume                     3145.4(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1117
_diffrn_reflns_av_sigmaI/netI    0.1299
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14473
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.53
_exptl_absorpt_coefficient_mu    0.991
_exptl_absorpt_correction_T_max  0.8903
_exptl_absorpt_correction_T_min  0.8189
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.446
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1400
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.651
_refine_diff_density_min         -1.319
_refine_diff_density_rms         0.102
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.02(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         4768
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.1508
_refine_ls_R_factor_gt           0.0639
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0319P)²+12.6529P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1382
_refine_ls_wR_factor_ref         0.1952
_reflns_number_gt                2466
_reflns_number_total             4768
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce42147c.txt
_cod_data_source_block           120303i
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      Pca2(1)
_cod_database_code               7213869
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y, z'
'-x+1/2, y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.86766(6) 0.80805(11) 0.36820(12) 0.0499(4) Uani 1 1 d .
Cl1 Cl 0.90873(16) 0.6272(3) 0.3579(3) 0.0720(9) Uani 1 1 d .
Cl2 Cl 0.85698(16) 0.9052(3) 0.5061(2) 0.0629(9) Uani 1 1 d .
N1 N 0.4225(5) 0.4331(8) 0.0631(8) 0.057(3) Uani 1 1 d .
N2 N 0.5687(4) 0.8122(9) 0.2205(7) 0.043(2) Uani 1 1 d .
N3 N 0.3334(5) 0.5318(9) 0.1335(8) 0.057(3) Uani 1 1 d .
N4 N 0.2504(6) 0.6399(11) 0.2130(11) 0.075(4) Uani 1 1 d .
N5 N 0.1881(8) 0.6900(16) 0.2225(15) 0.117(6) Uani 1 1 d .
N6 N 0.4036(5) 0.2300(8) 0.0550(7) 0.049(2) Uani 1 1 d .
N7 N 0.3791(5) 0.0313(7) 0.0502(7) 0.052(3) Uani 1 1 d .
N8 N 0.3957(6) -0.0804(9) 0.0282(8) 0.069(3) Uani 1 1 d .
N9 N 0.7723(5) 0.8119(8) 0.3153(6) 0.046(2) Uani 1 1 d .
N10 N 0.9282(5) 0.9188(9) 0.2924(7) 0.054(3) Uani 1 1 d .
C1 C 0.4689(6) 0.5226(10) 0.0985(10) 0.048(3) Uani 1 1 d .
C2 C 0.4729(6) 0.6270(10) 0.0505(8) 0.051(3) Uani 1 1 d .
H2 H 0.4512 0.6351 -0.0077 0.061 Uiso 1 1 calc R
C3 C 0.5090(6) 0.7207(10) 0.0880(8) 0.047(3) Uani 1 1 d .
H3 H 0.5124 0.7913 0.0547 0.057 Uiso 1 1 calc R
C4 C 0.5400(6) 0.7087(10) 0.1750(9) 0.040(3) Uani 1 1 d .
C5 C 0.5388(6) 0.6012(11) 0.2212(9) 0.053(3) Uani 1 1 d .
H5 H 0.5621 0.5916 0.2780 0.064 Uiso 1 1 calc R
C6 C 0.5027(8) 0.5081(11) 0.1827(10) 0.064(4) Uani 1 1 d .
H6 H 0.5014 0.4358 0.2138 0.077 Uiso 1 1 calc R
C7 C 0.3524(6) 0.4579(10) 0.0643(11) 0.060(3) Uani 1 1 d .
C8 C 0.3081(8) 0.4157(12) -0.0048(12) 0.080(5) Uani 1 1 d .
H8 H 0.3229 0.3642 -0.0518 0.096 Uiso 1 1 calc R
C9 C 0.2415(9) 0.4533(13) -0.0008(16) 0.095(6) Uani 1 1 d .
H9 H 0.2109 0.4278 -0.0467 0.114 Uiso 1 1 calc R
C10 C 0.2185(8) 0.5296(15) 0.0716(16) 0.088(6) Uani 1 1 d .
H10 H 0.1737 0.5556 0.0756 0.106 Uiso 1 1 calc R
C11 C 0.2670(8) 0.5621(12) 0.1349(12) 0.067(4) Uani 1 1 d .
C12 C 0.1915(14) 0.749(2) 0.302(2) 0.148(11) Uani 1 1 d .
H12 H 0.1557 0.7946 0.3248 0.178 Uiso 1 1 calc R
C13 C 0.2535(13) 0.7389(16) 0.3490(19) 0.132(9) Uani 1 1 d .
H13 H 0.2672 0.7720 0.4062 0.158 Uiso 1 1 calc R
C14 C 0.2900(10) 0.6650(15) 0.2871(14) 0.096(6) Uani 1 1 d .
H14 H 0.3342 0.6381 0.2963 0.115 Uiso 1 1 calc R
C15 C 0.4482(7) 0.3199(11) 0.0455(11) 0.055(4) Uani 1 1 d .
C16 C 0.5154(7) 0.3029(12) 0.0181(10) 0.071(4) Uani 1 1 d .
H16 H 0.5450 0.3662 0.0111 0.085 Uiso 1 1 calc R
C17 C 0.5363(7) 0.1900(12) 0.0018(11) 0.078(5) Uani 1 1 d .
H17 H 0.5808 0.1765 -0.0174 0.093 Uiso 1 1 calc R
C18 C 0.4935(7) 0.0966(13) 0.0129(10) 0.062(4) Uani 1 1 d .
H18 H 0.5083 0.0192 0.0059 0.075 Uiso 1 1 calc R
C19 C 0.4269(6) 0.1231(10) 0.0351(8) 0.049(3) Uani 1 1 d .
C20 C 0.3402(7) -0.1431(12) 0.0528(11) 0.071(4) Uani 1 1 d .
H20 H 0.3367 -0.2245 0.0463 0.086 Uiso 1 1 calc R
C21 C 0.2883(7) -0.0711(12) 0.0893(10) 0.065(4) Uani 1 1 d .
H21 H 0.2459 -0.0938 0.1118 0.078 Uiso 1 1 calc R
C22 C 0.3144(7) 0.0388(12) 0.0841(10) 0.065(4) Uani 1 1 d .
H22 H 0.2919 0.1080 0.1008 0.078 Uiso 1 1 calc R
C23 C 0.7258(5) 0.8864(9) 0.3494(8) 0.048(3) Uani 1 1 d .
H23 H 0.7399 0.9402 0.3951 0.058 Uiso 1 1 calc R
C24 C 0.6592(5) 0.8896(11) 0.3221(8) 0.050(3) Uani 1 1 d .
H24 H 0.6292 0.9413 0.3517 0.060 Uiso 1 1 calc R
C25 C 0.6354(5) 0.8136(10) 0.2481(7) 0.038(2) Uani 1 1 d .
C26 C 0.6838(6) 0.7377(10) 0.2128(8) 0.046(3) Uani 1 1 d .
H26 H 0.6714 0.6851 0.1653 0.055 Uiso 1 1 calc R
C27 C 0.7497(5) 0.7367(9) 0.2450(9) 0.046(3) Uani 1 1 d .
H27 H 0.7802 0.6834 0.2185 0.055 Uiso 1 1 calc R
C28 C 0.9103(6) 1.0359(11) 0.2891(9) 0.056(3) Uani 1 1 d .
H28 H 0.8664 1.0569 0.3068 0.067 Uiso 1 1 calc R
C29 C 0.9547(6) 1.1243(10) 0.2608(9) 0.047(3) Uani 1 1 d .
H29 H 0.9394 1.2015 0.2546 0.056 Uiso 1 1 calc R
C30 C 1.0220(5) 1.0968(10) 0.2417(8) 0.039(3) Uani 1 1 d .
C31 C 1.0402(6) 0.9779(10) 0.2386(9) 0.051(3) Uani 1 1 d .
H31 H 1.0829 0.9546 0.2173 0.061 Uiso 1 1 calc R
C32 C 0.9923(6) 0.8950(10) 0.2683(8) 0.047(3) Uani 1 1 d .
H32 H 1.0062 0.8167 0.2716 0.057 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N9 Zn1 N10 109.6(4) . .
N9 Zn1 Cl1 109.6(3) . .
N10 Zn1 Cl1 108.9(3) . .
N9 Zn1 Cl2 102.9(3) . .
N10 Zn1 Cl2 102.0(3) . .
Cl1 Zn1 Cl2 123.13(16) . .
C15 N1 C7 122.6(10) . .
C15 N1 C1 118.3(10) . .
C7 N1 C1 118.1(10) . .
C25 N2 C30 123.6(9) . 3_475
C25 N2 C4 120.6(9) . .
C30 N2 C4 115.5(8) 3_475 .
C7 N3 C11 116.1(12) . .
C14 N4 N5 111.1(16) . .
C14 N4 C11 126.4(13) . .
N5 N4 C11 122.2(16) . .
C12 N5 N4 105(2) . .
C19 N6 C15 116.3(10) . .
N8 N7 C22 111.6(10) . .
N8 N7 C19 119.7(11) . .
C22 N7 C19 128.7(10) . .
N7 N8 C20 103.9(11) . .
C23 N9 C27 115.4(10) . .
C23 N9 Zn1 121.1(8) . .
C27 N9 Zn1 123.4(7) . .
C32 N10 C28 115.4(10) . .
C32 N10 Zn1 124.2(8) . .
C28 N10 Zn1 117.6(8) . .
C2 C1 C6 120.4(11) . .
C2 C1 N1 118.1(11) . .
C6 C1 N1 121.2(11) . .
C1 C2 C3 120.4(11) . .
C1 C2 H2 119.8 . .
C3 C2 H2 119.8 . .
C4 C3 C2 119.4(11) . .
C4 C3 H3 120.3 . .
C2 C3 H3 120.3 . .
C3 C4 C5 120.1(11) . .
C3 C4 N2 119.1(10) . .
C5 C4 N2 120.7(11) . .
C4 C5 C6 119.7(12) . .
C4 C5 H5 120.1 . .
C6 C5 H5 120.1 . .
C1 C6 C5 119.8(11) . .
C1 C6 H6 120.1 . .
C5 C6 H6 120.1 . .
N3 C7 C8 123.4(13) . .
N3 C7 N1 114.1(11) . .
C8 C7 N1 122.4(14) . .
C9 C8 C7 117.4(16) . .
C9 C8 H8 121.3 . .
C7 C8 H8 121.3 . .
C8 C9 C10 121.5(15) . .
C8 C9 H9 119.3 . .
C10 C9 H9 119.3 . .
C11 C10 C9 114.6(15) . .
C11 C10 H10 122.7 . .
C9 C10 H10 122.7 . .
N3 C11 C10 126.9(17) . .
N3 C11 N4 112.6(13) . .
C10 C11 N4 120.4(15) . .
N5 C12 C13 114(2) . .
N5 C12 H12 122.9 . .
C13 C12 H12 122.9 . .
C12 C13 C14 102(3) . .
C12 C13 H13 129.2 . .
C14 C13 H13 129.2 . .
N4 C14 C13 108(2) . .
N4 C14 H14 125.8 . .
C13 C14 H14 125.8 . .
N6 C15 C16 122.6(12) . .
N6 C15 N1 116.1(11) . .
C16 C15 N1 121.3(12) . .
C17 C16 C15 117.6(12) . .
C17 C16 H16 121.2 . .
C15 C16 H16 121.2 . .
C18 C17 C16 121.6(13) . .
C18 C17 H17 119.2 . .
C16 C17 H17 119.2 . .
C17 C18 C19 116.3(13) . .
C17 C18 H18 121.9 . .
C19 C18 H18 121.9 . .
N6 C19 C18 125.2(11) . .
N6 C19 N7 114.2(10) . .
C18 C19 N7 120.2(11) . .
N8 C20 C21 112.1(12) . .
N8 C20 H20 124.0 . .
C21 C20 H20 124.0 . .
C22 C21 C20 103.9(12) . .
C22 C21 H21 128.0 . .
C20 C21 H21 128.0 . .
C21 C22 N7 108.4(12) . .
C21 C22 H22 125.8 . .
N7 C22 H22 125.8 . .
N9 C23 C24 125.0(10) . .
N9 C23 H23 117.5 . .
C24 C23 H23 117.5 . .
C23 C24 C25 120.2(10) . .
C23 C24 H24 119.9 . .
C25 C24 H24 119.9 . .
N2 C25 C26 123.6(10) . .
N2 C25 C24 121.9(9) . .
C26 C25 C24 114.4(9) . .
C27 C26 C25 122.6(10) . .
C27 C26 H26 118.7 . .
C25 C26 H26 118.7 . .
C26 C27 N9 122.4(10) . .
C26 C27 H27 118.8 . .
N9 C27 H27 118.8 . .
N10 C28 C29 123.1(11) . .
N10 C28 H28 118.5 . .
C29 C28 H28 118.5 . .
C30 C29 C28 119.6(11) . .
C30 C29 H29 120.2 . .
C28 C29 H29 120.2 . .
C29 C30 C31 117.9(11) . .
C29 C30 N2 119.8(10) . 3_575
C31 C30 N2 122.2(10) . 3_575
C30 C31 C32 117.9(11) . .
C30 C31 H31 121.0 . .
C32 C31 H31 121.0 . .
N10 C32 C31 125.3(11) . .
N10 C32 H32 117.3 . .
C31 C32 H32 117.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 N9 2.019(9) .
Zn1 N10 2.035(10) .
Zn1 Cl1 2.208(3) .
Zn1 Cl2 2.246(4) .
N1 C15 1.401(15) .
N1 C7 1.407(15) .
N1 C1 1.453(14) .
N2 C25 1.367(12) .
N2 C30 1.414(14) 3_475
N2 C4 1.452(14) .
N3 C7 1.339(16) .
N3 C11 1.349(16) .
N4 C14 1.33(2) .
N4 N5 1.358(17) .
N4 C11 1.45(2) .
N5 C12 1.31(3) .
N6 C19 1.325(14) .
N6 C15 1.351(14) .
N7 N8 1.343(13) .
N7 C22 1.363(15) .
N7 C19 1.419(13) .
N8 C20 1.348(16) .
N9 C23 1.333(13) .
N9 C27 1.382(13) .
N10 C32 1.332(13) .
N10 C28 1.373(14) .
C1 C2 1.365(16) .
C1 C6 1.372(16) .
C2 C3 1.384(14) .
C2 H2 0.9300 .
C3 C4 1.377(15) .
C3 H3 0.9300 .
C4 C5 1.382(16) .
C5 C6 1.383(16) .
C5 H5 0.9300 .
C6 H6 0.9300 .
C7 C8 1.393(18) .
C8 C9 1.38(2) .
C8 H8 0.9300 .
C9 C10 1.41(2) .
C9 H9 0.9300 .
C10 C11 1.36(2) .
C10 H10 0.9300 .
C12 C13 1.39(3) .
C12 H12 0.9300 .
C13 C14 1.41(2) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 C16 1.390(18) .
C16 C17 1.364(16) .
C16 H16 0.9300 .
C17 C18 1.361(17) .
C17 H17 0.9300 .
C18 C19 1.379(17) .
C18 H18 0.9300 .
C20 C21 1.406(18) .
C20 H20 0.9300 .
C21 C22 1.349(17) .
C21 H21 0.9300 .
C22 H22 0.9300 .
C23 C24 1.367(14) .
C23 H23 0.9300 .
C24 C25 1.432(15) .
C24 H24 0.9300 .
C25 C26 1.376(14) .
C26 C27 1.373(14) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.388(15) .
C28 H28 0.9300 .
C29 C30 1.387(14) .
C29 H29 0.9300 .
C30 C31 1.394(15) .
C30 N2 1.414(14) 3_575
C31 C32 1.395(15) .
C31 H31 0.9300 .
C32 H32 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C14 N4 N5 C12 2(2) . .
C11 N4 N5 C12 177.6(16) . .
C22 N7 N8 C20 -2.3(14) . .
C19 N7 N8 C20 178.9(11) . .
N10 Zn1 N9 C23 -91.8(9) . .
Cl1 Zn1 N9 C23 148.7(8) . .
Cl2 Zn1 N9 C23 16.1(8) . .
N10 Zn1 N9 C27 90.5(9) . .
Cl1 Zn1 N9 C27 -29.0(9) . .
Cl2 Zn1 N9 C27 -161.6(8) . .
N9 Zn1 N10 C32 -140.3(9) . .
Cl1 Zn1 N10 C32 -20.4(10) . .
Cl2 Zn1 N10 C32 111.1(9) . .
N9 Zn1 N10 C28 59.2(9) . .
Cl1 Zn1 N10 C28 179.2(8) . .
Cl2 Zn1 N10 C28 -49.3(9) . .
C15 N1 C1 C2 126.5(13) . .
C7 N1 C1 C2 -64.7(16) . .
C15 N1 C1 C6 -60.0(19) . .
C7 N1 C1 C6 108.9(15) . .
C6 C1 C2 C3 -2(2) . .
N1 C1 C2 C3 171.2(11) . .
C1 C2 C3 C4 -1.2(18) . .
C2 C3 C4 C5 4.4(18) . .
C2 C3 C4 N2 -170.6(10) . .
C25 N2 C4 C3 -124.7(11) . .
C30 N2 C4 C3 61.2(15) 3_475 .
C25 N2 C4 C5 60.3(15) . .
C30 N2 C4 C5 -113.8(12) 3_475 .
C3 C4 C5 C6 -4.2(19) . .
N2 C4 C5 C6 170.8(11) . .
C2 C1 C6 C5 3(2) . .
N1 C1 C6 C5 -170.8(11) . .
C4 C5 C6 C1 1(2) . .
C11 N3 C7 C8 1.7(18) . .
C11 N3 C7 N1 177.3(11) . .
C15 N1 C7 N3 139.2(13) . .
C1 N1 C7 N3 -29.1(16) . .
C15 N1 C7 C8 -45(2) . .
C1 N1 C7 C8 146.5(13) . .
N3 C7 C8 C9 0(2) . .
N1 C7 C8 C9 -174.9(13) . .
C7 C8 C9 C10 -1(2) . .
C8 C9 C10 C11 0(2) . .
C7 N3 C11 C10 -3(2) . .
C7 N3 C11 N4 178.7(11) . .
C9 C10 C11 N3 2(2) . .
C9 C10 C11 N4 -179.8(13) . .
C14 N4 C11 N3 -12(2) . .
N5 N4 C11 N3 173.6(13) . .
C14 N4 C11 C10 169.6(15) . .
N5 N4 C11 C10 -5(2) . .
N4 N5 C12 C13 -2(3) . .
N5 C12 C13 C14 1(3) . .
N5 N4 C14 C13 -2(2) . .
C11 N4 C14 C13 -176.9(13) . .
C12 C13 C14 N4 1(2) . .
C19 N6 C15 C16 -1(2) . .
C19 N6 C15 N1 177.7(11) . .
C7 N1 C15 N6 -17(2) . .
C1 N1 C15 N6 151.0(12) . .
C7 N1 C15 C16 161.5(14) . .
C1 N1 C15 C16 -30(2) . .
N6 C15 C16 C17 -1(2) . .
N1 C15 C16 C17 -179.6(15) . .
C15 C16 C17 C18 -1(2) . .
C16 C17 C18 C19 4(2) . .
C15 N6 C19 C18 5.2(19) . .
C15 N6 C19 N7 177.3(10) . .
C17 C18 C19 N6 -7(2) . .
C17 C18 C19 N7 -178.5(13) . .
N8 N7 C19 N6 176.7(10) . .
C22 N7 C19 N6 -1.8(18) . .
N8 N7 C19 C18 -10.7(17) . .
C22 N7 C19 C18 170.8(13) . .
N7 N8 C20 C21 0.7(16) . .
N8 C20 C21 C22 1.1(18) . .
C20 C21 C22 N7 -2.5(16) . .
N8 N7 C22 C21 3.1(15) . .
C19 N7 C22 C21 -178.2(12) . .
C27 N9 C23 C24 2.3(16) . .
Zn1 N9 C23 C24 -175.5(9) . .
N9 C23 C24 C25 -3.6(18) . .
C30 N2 C25 C26 -167.0(11) 3_475 .
C4 N2 C25 C26 19.4(17) . .
C30 N2 C25 C24 17.8(17) 3_475 .
C4 N2 C25 C24 -155.8(11) . .
C23 C24 C25 N2 178.3(10) . .
C23 C24 C25 C26 2.7(16) . .
N2 C25 C26 C27 -176.6(11) . .
C24 C25 C26 C27 -1.1(17) . .
C25 C26 C27 N9 0.0(18) . .
C23 N9 C27 C26 -0.5(15) . .
Zn1 N9 C27 C26 177.3(9) . .
C32 N10 C28 C29 1.5(18) . .
Zn1 N10 C28 C29 163.6(10) . .
N10 C28 C29 C30 -5.3(19) . .
C28 C29 C30 C31 9.1(18) . .
C28 C29 C30 N2 -174.7(11) . 3_575
C29 C30 C31 C32 -9.2(18) . .
N2 C30 C31 C32 174.7(10) 3_575 .
C28 N10 C32 C31 -1.8(18) . .
Zn1 N10 C32 C31 -162.6(10) . .
C30 C31 C32 N10 5.9(19) . .
