#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:17:49 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180472 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/41/7214189.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7214189
loop_
_publ_author_name
'Zheng, Sheng-Run'
'Chen, Rui-Ling'
'Liu, Zi-Meng'
'Wen, Xi-Ling'
'Xie, Tao'
'Fan, Jun'
'Zhang, Wei-Guang'
_publ_section_title
;
 Construction of terpyridine--Ln(iii) coordination polymers: structural
 diversity, visible and NIR luminescence properties and response to
 nerve-agent mimics
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2898
_journal_paper_doi               10.1039/c3ce42091d
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C25 H19 Dy N3 O10 S2'
_chemical_formula_weight         748.05
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.647(4)
_cell_angle_beta                 103.175(4)
_cell_angle_gamma                109.375(3)
_cell_formula_units_Z            2
_cell_length_a                   10.744(3)
_cell_length_b                   11.964(3)
_cell_length_c                   12.004(6)
_cell_measurement_reflns_used    2249
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.24
_cell_measurement_theta_min      2.30
_cell_volume                     1266.9(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_sigmaI/netI    0.0589
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            6367
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    3.181
_exptl_absorpt_correction_T_max  0.6826
_exptl_absorpt_correction_T_min  0.5687
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.961
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.987
_refine_diff_density_min         -1.748
_refine_diff_density_rms         0.186
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         4381
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0552
_refine_ls_R_factor_gt           0.0459
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0790P)²+0.9293P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1136
_refine_ls_wR_factor_ref         0.1222
_reflns_number_gt                3745
_reflns_number_total             4381
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce42091d.txt
_cod_data_source_block           19
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               7214189
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.03310(3) 0.46520(3) 0.18194(3) 0.02191(14) Uani 1 1 d .
S1 S 0.1954(2) 0.26722(19) 0.2514(2) 0.0354(5) Uani 1 1 d .
S2 S 0.1577(2) -0.21778(17) 0.14336(18) 0.0281(4) Uani 1 1 d .
O1 O 0.2099(8) 0.2215(6) 0.1303(6) 0.0559(18) Uani 1 1 d .
O2 O 0.0927(6) 0.3239(5) 0.2509(5) 0.0336(12) Uani 1 1 d .
O3 O 0.3277(6) 0.3525(6) 0.3617(7) 0.0562(18) Uani 1 1 d .
O4 O 0.3104(6) -0.1488(6) 0.1965(6) 0.0496(16) Uani 1 1 d .
O5 O 0.1005(6) -0.3230(5) 0.1783(5) 0.0365(13) Uani 1 1 d .
O6 O 0.0971(6) -0.2618(5) 0.0059(5) 0.0349(13) Uani 1 1 d .
O7 O -0.1848(6) 0.5339(5) -0.0789(5) 0.0344(12) Uani 1 1 d .
O8 O -0.1658(6) 0.4774(6) 0.0799(6) 0.0405(14) Uani 1 1 d .
N1 N 0.1731(7) 0.6455(6) 0.7607(6) 0.0300(14) Uani 1 1 d .
N2 N -0.0274(6) 0.3995(6) 0.6108(6) 0.0263(13) Uani 1 1 d .
N3 N -0.2740(7) 0.3665(6) 0.6367(6) 0.0294(14) Uani 1 1 d .
C1 C 0.2672(9) 0.7741(8) 0.8317(8) 0.039(2) Uani 1 1 d .
H1A H 0.2421 0.8297 0.8874 0.047 Uiso 1 1 calc R
C2 C 0.3988(10) 0.8271(9) 0.8255(9) 0.046(2) Uani 1 1 d .
H2A H 0.4610 0.9167 0.8758 0.055 Uiso 1 1 calc R
C3 C 0.4370(9) 0.7457(8) 0.7440(8) 0.042(2) Uani 1 1 d .
H3A H 0.5269 0.7785 0.7408 0.050 Uiso 1 1 calc R
C4 C 0.3404(9) 0.6145(9) 0.6668(8) 0.039(2) Uani 1 1 d .
H4A H 0.3629 0.5586 0.6085 0.047 Uiso 1 1 calc R
C5 C 0.2095(8) 0.5672(7) 0.6772(7) 0.0269(16) Uani 1 1 d .
C6 C 0.0971(8) 0.4251(8) 0.5926(7) 0.0311(17) Uani 1 1 d .
C7 C 0.1220(9) 0.3326(8) 0.5102(7) 0.0317(17) Uani 1 1 d .
H7A H 0.2123 0.3527 0.5075 0.038 Uiso 1 1 calc R
C8 C 0.0089(9) 0.2069(7) 0.4299(7) 0.0333(18) Uani 1 1 d .
C9 C -0.1231(9) 0.1814(8) 0.4390(7) 0.0344(18) Uani 1 1 d .
H9A H -0.2012 0.0997 0.3841 0.041 Uiso 1 1 calc R
C10 C -0.1385(9) 0.2791(7) 0.5310(7) 0.0311(17) Uani 1 1 d .
C11 C -0.2760(8) 0.2598(7) 0.5457(7) 0.0306(17) Uani 1 1 d .
C12 C -0.4011(9) 0.1437(8) 0.4679(8) 0.041(2) Uani 1 1 d .
H12A H -0.3993 0.0714 0.4081 0.049 Uiso 1 1 calc R
C13 C -0.5281(10) 0.1360(9) 0.4796(9) 0.049(2) Uani 1 1 d .
H13A H -0.6131 0.0592 0.4276 0.058 Uiso 1 1 calc R
C14 C -0.5257(9) 0.2446(9) 0.5699(9) 0.047(2) Uani 1 1 d .
H14A H -0.6099 0.2424 0.5792 0.056 Uiso 1 1 calc R
C15 C -0.3984(9) 0.3569(8) 0.6467(8) 0.0389(19) Uani 1 1 d .
H15A H -0.3989 0.4290 0.7081 0.047 Uiso 1 1 calc R
C16 C 0.0350(9) 0.1028(7) 0.3426(7) 0.0313(17) Uani 1 1 d .
C17 C 0.1172(8) 0.1196(7) 0.2695(7) 0.0291(17) Uani 1 1 d .
C18 C 0.1478(8) 0.0186(7) 0.2054(8) 0.0327(17) Uani 1 1 d .
H18A H 0.2026 0.0307 0.1568 0.039 Uiso 1 1 calc R
C19 C 0.0974(8) -0.1011(7) 0.2129(7) 0.0275(16) Uani 1 1 d .
C20 C 0.0094(10) -0.1223(8) 0.2771(8) 0.041(2) Uani 1 1 d .
H20A H -0.0280 -0.2037 0.2787 0.049 Uiso 1 1 calc R
C21 C -0.0245(10) -0.0238(8) 0.3397(8) 0.042(2) Uani 1 1 d .
H21A H -0.0873 -0.0405 0.3806 0.050 Uiso 1 1 calc R
C22 C -0.2285(8) 0.5064(7) 0.0009(7) 0.0262(16) Uani 1 1 d .
C23 C -0.3698(8) 0.5035(7) 0.0001(7) 0.0259(15) Uani 1 1 d .
C24 C -0.4235(8) 0.5722(8) -0.0508(8) 0.0362(19) Uani 1 1 d .
H24A H -0.3723 0.6216 -0.0847 0.043 Uiso 1 1 calc R
O1W O 0.4017(9) 0.1195(8) 0.7782(9) 0.101(3) Uani 1 1 d .
H1WA H 0.4135 0.1990 0.8164 0.152 Uiso 1 1 d R
H1WB H 0.4852 0.1237 0.7903 0.152 Uiso 1 1 d R
O2W O 0.2651(14) 0.0620(11) 0.9418(12) 0.144(5) Uani 1 1 d .
H2WA H 0.1837 0.0099 0.8851 0.216 Uiso 1 1 d R
H2WB H 0.2603 0.1256 0.9967 0.216 Uiso 1 1 d R
C25 C -0.4449(8) 0.4320(8) 0.0519(8) 0.0360(19) Uani 1 1 d .
H25A H -0.4078 0.3864 0.0877 0.043 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Dy1 O8 114.3(2) 2_565 .
O7 Dy1 O2 89.11(18) 2_565 .
O8 Dy1 O2 139.26(19) . .
O7 Dy1 O6 76.53(19) 2_565 2
O8 Dy1 O6 75.4(2) . 2
O2 Dy1 O6 78.68(19) . 2
O7 Dy1 O5 77.68(19) 2_565 1_565
O8 Dy1 O5 70.3(2) . 1_565
O2 Dy1 O5 150.2(2) . 1_565
O6 Dy1 O5 122.70(19) 2 1_565
O7 Dy1 N2 139.8(2) 2_565 2_566
O8 Dy1 N2 87.9(2) . 2_566
O2 Dy1 N2 94.77(19) . 2_566
O6 Dy1 N2 143.40(19) 2 2_566
O5 Dy1 N2 79.46(18) 1_565 2_566
O7 Dy1 N1 154.2(2) 2_565 2_566
O8 Dy1 N1 69.9(2) . 2_566
O2 Dy1 N1 75.22(19) . 2_566
O6 Dy1 N1 80.37(19) 2 2_566
O5 Dy1 N1 125.29(19) 1_565 2_566
N2 Dy1 N1 63.24(19) 2_566 2_566
O7 Dy1 N3 78.0(2) 2_565 2_566
O8 Dy1 N3 134.6(2) . 2_566
O2 Dy1 N3 80.8(2) . 2_566
O6 Dy1 N3 147.3(2) 2 2_566
O5 Dy1 N3 70.4(2) 1_565 2_566
N2 Dy1 N3 63.34(19) 2_566 2_566
N1 Dy1 N3 118.3(2) 2_566 2_566
O1 S1 O3 115.4(4) . .
O1 S1 O2 112.3(4) . .
O3 S1 O2 112.0(4) . .
O1 S1 C17 104.6(4) . .
O3 S1 C17 105.6(4) . .
O2 S1 C17 106.0(3) . .
O4 S2 O5 113.9(4) . .
O4 S2 O6 112.8(4) . .
O5 S2 O6 112.3(3) . .
O4 S2 C19 106.3(4) . .
O5 S2 C19 104.9(3) . .
O6 S2 C19 105.8(3) . .
S1 O2 Dy1 139.6(3) . .
S2 O5 Dy1 160.1(3) . 1_545
S2 O6 Dy1 137.4(3) . 2
C22 O7 Dy1 148.3(5) . 2_565
C22 O8 Dy1 149.9(5) . .
C1 N1 C5 117.7(7) . .
C1 N1 Dy1 122.1(5) . 2_566
C5 N1 Dy1 118.2(5) . 2_566
C10 N2 C6 117.4(6) . .
C10 N2 Dy1 119.1(5) . 2_566
C6 N2 Dy1 120.9(5) . 2_566
C15 N3 C11 117.6(7) . .
C15 N3 Dy1 122.6(5) . 2_566
C11 N3 Dy1 116.7(5) . 2_566
N1 C1 C2 123.0(8) . .
N1 C1 H1A 118.5 . .
C2 C1 H1A 118.5 . .
C3 C2 C1 118.9(8) . .
C3 C2 H2A 120.5 . .
C1 C2 H2A 120.5 . .
C2 C3 C4 119.2(8) . .
C2 C3 H3A 120.4 . .
C4 C3 H3A 120.4 . .
C3 C4 C5 119.1(8) . .
C3 C4 H4A 120.5 . .
C5 C4 H4A 120.5 . .
N1 C5 C4 122.1(7) . .
N1 C5 C6 116.2(6) . .
C4 C5 C6 121.7(7) . .
N2 C6 C7 124.0(7) . .
N2 C6 C5 113.2(7) . .
C7 C6 C5 122.8(7) . .
C6 C7 C8 118.5(7) . .
C6 C7 H7A 120.7 . .
C8 C7 H7A 120.7 . .
C9 C8 C7 118.4(7) . .
C9 C8 C16 122.1(7) . .
C7 C8 C16 119.4(7) . .
C8 C9 C10 119.8(7) . .
C8 C9 H9A 120.1 . .
C10 C9 H9A 120.1 . .
N2 C10 C9 121.4(7) . .
N2 C10 C11 115.7(6) . .
C9 C10 C11 122.9(7) . .
N3 C11 C12 121.6(7) . .
N3 C11 C10 115.6(7) . .
C12 C11 C10 122.7(7) . .
C13 C12 C11 119.8(8) . .
C13 C12 H12A 120.1 . .
C11 C12 H12A 120.1 . .
C14 C13 C12 118.2(8) . .
C14 C13 H13A 120.9 . .
C12 C13 H13A 120.9 . .
C13 C14 C15 119.9(8) . .
C13 C14 H14A 120.0 . .
C15 C14 H14A 120.0 . .
N3 C15 C14 122.8(8) . .
N3 C15 H15A 118.6 . .
C14 C15 H15A 118.6 . .
C17 C16 C21 117.6(7) . .
C17 C16 C8 126.4(7) . .
C21 C16 C8 115.9(7) . .
C18 C17 C16 120.2(7) . .
C18 C17 S1 114.1(6) . .
C16 C17 S1 125.7(5) . .
C17 C18 C19 120.8(7) . .
C17 C18 H18A 119.6 . .
C19 C18 H18A 119.6 . .
C20 C19 C18 119.8(7) . .
C20 C19 S2 122.3(6) . .
C18 C19 S2 117.9(6) . .
C19 C20 C21 120.3(7) . .
C19 C20 H20A 119.9 . .
C21 C20 H20A 119.9 . .
C20 C21 C16 121.0(7) . .
C20 C21 H21A 119.5 . .
C16 C21 H21A 119.5 . .
O8 C22 O7 125.2(7) . .
O8 C22 C23 116.8(6) . .
O7 C22 C23 118.0(7) . .
C24 C23 C25 119.9(7) . .
C24 C23 C22 120.4(7) . .
C25 C23 C22 119.7(7) . .
C23 C24 C25 119.9(7) . 2_465
C23 C24 H24A 120.0 . .
C25 C24 H24A 120.0 2_465 .
H1WA O1W H1WB 106.6 . .
H2WA O2W H2WB 109.1 . .
C23 C25 C24 120.1(7) . 2_465
C23 C25 H25A 119.9 . .
C24 C25 H25A 119.9 2_465 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O7 2.259(5) 2_565
Dy1 O8 2.285(5) .
Dy1 O2 2.318(5) .
Dy1 O6 2.362(5) 2
Dy1 O5 2.413(5) 1_565
Dy1 N2 2.498(6) 2_566
Dy1 N1 2.549(6) 2_566
Dy1 N3 2.553(6) 2_566
S1 O1 1.436(6) .
S1 O3 1.444(7) .
S1 O2 1.474(5) .
S1 C17 1.796(7) .
S2 O4 1.431(6) .
S2 O5 1.448(5) .
S2 O6 1.457(6) .
S2 C19 1.769(7) .
O5 Dy1 2.413(5) 1_545
O6 Dy1 2.362(5) 2
O7 C22 1.249(9) .
O7 Dy1 2.259(5) 2_565
O8 C22 1.249(9) .
N1 C1 1.345(10) .
N1 C5 1.351(9) .
N1 Dy1 2.549(6) 2_566
N2 C10 1.352(10) .
N2 C6 1.355(9) .
N2 Dy1 2.498(6) 2_566
N3 C15 1.340(10) .
N3 C11 1.362(9) .
N3 Dy1 2.553(6) 2_566
C1 C2 1.376(12) .
C1 H1A 0.9300 .
C2 C3 1.371(12) .
C2 H2A 0.9300 .
C3 C4 1.379(12) .
C3 H3A 0.9300 .
C4 C5 1.383(10) .
C4 H4A 0.9300 .
C5 C6 1.515(11) .
C6 C7 1.363(11) .
C7 C8 1.394(11) .
C7 H7A 0.9300 .
C8 C9 1.388(11) .
C8 C16 1.488(10) .
C9 C10 1.398(10) .
C9 H9A 0.9300 .
C10 C11 1.479(11) .
C11 C12 1.387(11) .
C12 C13 1.379(13) .
C12 H12A 0.9300 .
C13 C14 1.371(13) .
C13 H13A 0.9300 .
C14 C15 1.378(12) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C16 C17 1.395(10) .
C16 C21 1.420(11) .
C17 C18 1.383(10) .
C18 C19 1.396(10) .
C18 H18A 0.9300 .
C19 C20 1.363(11) .
C20 C21 1.379(11) .
C20 H20A 0.9300 .
C21 H21A 0.9300 .
C22 C23 1.505(10) .
C23 C24 1.369(10) .
C23 C25 1.378(10) .
C24 C25 1.395(10) 2_465
C24 H24A 0.9300 .
O1W H1WA 0.8555 .
O1W H1WB 0.8565 .
O2W H2WA 0.8361 .
O2W H2WB 0.8493 .
C25 C24 1.395(10) 2_465
C25 H25A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 S1 O2 Dy1 -44.2(6) . .
O3 S1 O2 Dy1 87.6(6) . .
C17 S1 O2 Dy1 -157.8(5) . .
O7 Dy1 O2 S1 8.2(5) 2_565 .
O8 Dy1 O2 S1 135.9(5) . .
O6 Dy1 O2 S1 84.6(5) 2 .
O5 Dy1 O2 S1 -54.7(7) 1_565 .
N2 Dy1 O2 S1 -131.8(5) 2_566 .
N1 Dy1 O2 S1 167.5(6) 2_566 .
N3 Dy1 O2 S1 -69.8(5) 2_566 .
O4 S2 O5 Dy1 -75.9(11) . 1_545
O6 S2 O5 Dy1 53.9(12) . 1_545
C19 S2 O5 Dy1 168.3(10) . 1_545
O4 S2 O6 Dy1 114.5(5) . 2
O5 S2 O6 Dy1 -15.8(6) . 2
C19 S2 O6 Dy1 -129.7(5) . 2
O7 Dy1 O8 C22 -20.4(11) 2_565 .
O2 Dy1 O8 C22 -140.2(10) . .
O6 Dy1 O8 C22 -87.9(11) 2 .
O5 Dy1 O8 C22 45.4(11) 1_565 .
N2 Dy1 O8 C22 125.0(11) 2_566 .
N1 Dy1 O8 C22 -172.8(11) 2_566 .
N3 Dy1 O8 C22 76.8(11) 2_566 .
C5 N1 C1 C2 -2.2(12) . .
Dy1 N1 C1 C2 161.4(7) 2_566 .
N1 C1 C2 C3 -0.3(14) . .
C1 C2 C3 C4 2.7(14) . .
C2 C3 C4 C5 -2.5(13) . .
C1 N1 C5 C4 2.3(11) . .
Dy1 N1 C5 C4 -161.9(6) 2_566 .
C1 N1 C5 C6 -176.1(7) . .
Dy1 N1 C5 C6 19.7(8) 2_566 .
C3 C4 C5 N1 0.0(12) . .
C3 C4 C5 C6 178.3(7) . .
C10 N2 C6 C7 -8.3(11) . .
Dy1 N2 C6 C7 153.1(6) 2_566 .
C10 N2 C6 C5 173.7(6) . .
Dy1 N2 C6 C5 -24.9(8) 2_566 .
N1 C5 C6 N2 2.6(9) . .
C4 C5 C6 N2 -175.8(7) . .
N1 C5 C6 C7 -175.4(7) . .
C4 C5 C6 C7 6.2(11) . .
N2 C6 C7 C8 6.7(12) . .
C5 C6 C7 C8 -175.6(7) . .
C6 C7 C8 C9 -0.9(11) . .
C6 C7 C8 C16 -177.7(7) . .
C7 C8 C9 C10 -2.7(12) . .
C16 C8 C9 C10 174.0(7) . .
C6 N2 C10 C9 4.3(11) . .
Dy1 N2 C10 C9 -157.5(6) 2_566 .
C6 N2 C10 C11 -174.2(6) . .
Dy1 N2 C10 C11 24.0(8) 2_566 .
C8 C9 C10 N2 1.0(12) . .
C8 C9 C10 C11 179.4(7) . .
C15 N3 C11 C12 -1.7(11) . .
Dy1 N3 C11 C12 159.1(6) 2_566 .
C15 N3 C11 C10 175.1(7) . .
Dy1 N3 C11 C10 -24.2(8) 2_566 .
N2 C10 C11 N3 0.8(10) . .
C9 C10 C11 N3 -177.7(7) . .
N2 C10 C11 C12 177.5(7) . .
C9 C10 C11 C12 -1.0(12) . .
N3 C11 C12 C13 1.8(13) . .
C10 C11 C12 C13 -174.6(8) . .
C11 C12 C13 C14 -0.6(14) . .
C12 C13 C14 C15 -0.7(14) . .
C11 N3 C15 C14 0.3(12) . .
Dy1 N3 C15 C14 -159.2(7) 2_566 .
C13 C14 C15 N3 0.8(14) . .
C9 C8 C16 C17 140.6(9) . .
C7 C8 C16 C17 -42.8(12) . .
C9 C8 C16 C21 -42.8(11) . .
C7 C8 C16 C21 133.8(8) . .
C21 C16 C17 C18 -5.1(12) . .
C8 C16 C17 C18 171.5(8) . .
C21 C16 C17 S1 176.6(6) . .
C8 C16 C17 S1 -6.9(12) . .
O1 S1 C17 C18 27.2(7) . .
O3 S1 C17 C18 -95.0(7) . .
O2 S1 C17 C18 146.0(6) . .
O1 S1 C17 C16 -154.4(7) . .
O3 S1 C17 C16 83.4(8) . .
O2 S1 C17 C16 -35.5(8) . .
C16 C17 C18 C19 -0.1(12) . .
S1 C17 C18 C19 178.5(6) . .
C17 C18 C19 C20 4.3(12) . .
C17 C18 C19 S2 -173.0(6) . .
O4 S2 C19 C20 -124.2(7) . .
O5 S2 C19 C20 -3.2(8) . .
O6 S2 C19 C20 115.7(7) . .
O4 S2 C19 C18 53.0(7) . .
O5 S2 C19 C18 174.0(6) . .
O6 S2 C19 C18 -67.1(7) . .
C18 C19 C20 C21 -3.1(13) . .
S2 C19 C20 C21 174.1(7) . .
C19 C20 C21 C16 -2.2(14) . .
C17 C16 C21 C20 6.3(13) . .
C8 C16 C21 C20 -170.6(9) . .
Dy1 O8 C22 O7 11.4(16) . .
Dy1 O8 C22 C23 -170.5(7) . .
Dy1 O7 C22 O8 13.6(15) 2_565 .
Dy1 O7 C22 C23 -164.5(6) 2_565 .
O8 C22 C23 C24 159.0(7) . .
O7 C22 C23 C24 -22.8(11) . .
O8 C22 C23 C25 -20.5(11) . .
O7 C22 C23 C25 157.7(7) . .
C25 C23 C24 C25 -1.0(14) . 2_465
C22 C23 C24 C25 179.5(7) . 2_465
C24 C23 C25 C24 1.0(14) . 2_465
C22 C23 C25 C24 -179.5(7) . 2_465
