#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:35:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180478 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/47/7214710.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7214710
loop_
_publ_author_name
'Jin, Feng'
'Yang, Xiao-Fei'
'Li, Sheng-Li'
'Zheng, Zheng'
'Yu, Zhi-Peng'
'Kong, Lin'
'Hao, Fu-Ying'
'Yang, Jia-Xiang'
'Wu, Jie-Ying'
'Tian, Yu-Peng'
'Zhou, Hong-Ping'
_publ_section_title
;
 Role of anions in preparing silver(i) complexes with a new multidentate
 ligand: polymorphs, structures and nonlinear optical properties
;
_journal_issue                   24
_journal_name_full               CrystEngComm
_journal_page_first              8409
_journal_paper_doi               10.1039/c2ce26145f
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C150 H108 Ag4 N28 O16'
_chemical_formula_weight         2990.12
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.276(5)
_cell_angle_beta                 93.521(5)
_cell_angle_gamma                114.371(5)
_cell_formula_units_Z            1
_cell_length_a                   12.745(5)
_cell_length_b                   13.971(5)
_cell_length_c                   21.091(5)
_cell_measurement_reflns_used    4263
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      20.91
_cell_measurement_theta_min      2.45
_cell_volume                     3312.1(19)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_sigmaI/netI    0.0695
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            23791
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.00
_exptl_absorpt_coefficient_mu    0.661
_exptl_absorpt_correction_T_max  0.8791
_exptl_absorpt_correction_T_min  0.8263
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.499
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.072
_refine_diff_density_min         -0.513
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     920
_refine_ls_number_reflns         11581
_refine_ls_number_restraints     90
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.1054
_refine_ls_R_factor_gt           0.0574
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1570
_refine_ls_wR_factor_ref         0.1886
_reflns_number_gt                6916
_reflns_number_total             11581
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce26145f.txt
_cod_data_source_block           jf_3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      'P-1 '
_cod_database_code               7214710
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.10635(4) 0.18982(4) 0.65896(2) 0.05873(18) Uani 1 1 d . . .
Ag2 Ag 0.65508(5) 0.38587(4) 0.79218(3) 0.0754(2) Uani 1 1 d . . .
C1 C -0.3075(5) 0.0639(6) 0.7327(3) 0.0658(18) Uani 1 1 d . . .
H1 H -0.3546 0.0655 0.6978 0.079 Uiso 1 1 calc R . .
C2 C -0.3594(5) -0.0007(6) 0.7738(3) 0.0670(19) Uani 1 1 d . . .
H2 H -0.4396 -0.0431 0.7666 0.080 Uiso 1 1 calc R . .
C3 C -0.2898(5) -0.0009(5) 0.8257(3) 0.0644(18) Uani 1 1 d . . .
H3 H -0.3227 -0.0438 0.8543 0.077 Uiso 1 1 calc R . .
C4 C -0.1723(5) 0.0617(5) 0.8356(3) 0.0552(15) Uani 1 1 d . . .
H4 H -0.1247 0.0625 0.8711 0.066 Uiso 1 1 calc R . .
C5 C -0.1241(4) 0.1248(4) 0.7914(3) 0.0424(13) Uani 1 1 d . . .
C6 C 0.0051(4) 0.1937(4) 0.7996(2) 0.0394(12) Uani 1 1 d . . .
C7 C 0.0811(4) 0.2011(4) 0.8511(3) 0.0421(13) Uani 1 1 d . . .
H7 H 0.0527 0.1640 0.8831 0.051 Uiso 1 1 calc R . .
C8 C 0.2015(5) 0.2641(4) 0.8561(2) 0.0411(12) Uani 1 1 d . . .
C9 C 0.2384(5) 0.3161(5) 0.8065(3) 0.0465(14) Uani 1 1 d . . .
H9 H 0.3176 0.3577 0.8075 0.056 Uiso 1 1 calc R . .
C10 C 0.1582(4) 0.3065(4) 0.7555(2) 0.0414(13) Uani 1 1 d . . .
C11 C 0.1975(5) 0.3622(4) 0.7021(3) 0.0462(14) Uani 1 1 d . . .
C12 C 0.2938(5) 0.3609(5) 0.6744(3) 0.0551(15) Uani 1 1 d . . .
H12 H 0.3333 0.3243 0.6891 0.066 Uiso 1 1 calc R . .
C13 C 0.3308(6) 0.4134(6) 0.6253(3) 0.0693(19) Uani 1 1 d . . .
H13 H 0.3942 0.4112 0.6066 0.083 Uiso 1 1 calc R . .
C14 C 0.2742(7) 0.4688(6) 0.6041(4) 0.081(2) Uani 1 1 d . . .
H14 H 0.3005 0.5053 0.5716 0.097 Uiso 1 1 calc R . .
C15 C 0.1793(7) 0.4709(6) 0.6304(4) 0.079(2) Uani 1 1 d . . .
H15 H 0.1409 0.5083 0.6155 0.094 Uiso 1 1 calc R . .
C16 C 0.1407(6) 0.4176(5) 0.6788(3) 0.0590(16) Uani 1 1 d . . .
H16 H 0.0758 0.4187 0.6962 0.071 Uiso 1 1 calc R . .
C17 C 0.2854(4) 0.2731(4) 0.9122(3) 0.0431(13) Uani 1 1 d . . .
C18 C 0.2556(5) 0.1940(5) 0.9479(3) 0.0495(14) Uani 1 1 d . . .
H18 H 0.1823 0.1354 0.9370 0.059 Uiso 1 1 calc R . .
C19 C 0.3330(5) 0.2013(5) 0.9992(3) 0.0508(15) Uani 1 1 d . . .
H19 H 0.3112 0.1478 1.0224 0.061 Uiso 1 1 calc R . .
C20 C 0.4417(4) 0.2865(4) 1.0164(3) 0.0439(13) Uani 1 1 d . . .
C21 C 0.4730(5) 0.3671(5) 0.9820(3) 0.0506(14) Uani 1 1 d . . .
H21 H 0.5459 0.4263 0.9940 0.061 Uiso 1 1 calc R . .
C22 C 0.3960(5) 0.3592(5) 0.9303(3) 0.0503(15) Uani 1 1 d . . .
H22 H 0.4185 0.4126 0.9069 0.060 Uiso 1 1 calc R . .
C23 C 0.5291(6) 0.2118(6) 1.0893(3) 0.073(2) Uani 1 1 d . . .
H23 H 0.4820 0.1384 1.0721 0.088 Uiso 1 1 calc R . .
C24 C 0.6177(8) 0.2560(8) 1.1403(4) 0.093(3) Uani 1 1 d . . .
H24 H 0.6430 0.2196 1.1656 0.111 Uiso 1 1 calc R . .
C25 C 0.6620(6) 0.3653(8) 1.1468(4) 0.087(2) Uani 1 1 d . . .
H25 H 0.7260 0.4158 1.1775 0.104 Uiso 1 1 calc R . .
C26 C -0.1822(6) 0.2860(6) 0.5505(3) 0.0674(18) Uani 1 1 d . . .
H26 H -0.2312 0.2947 0.5797 0.081 Uiso 1 1 calc R . .
C27 C -0.1833(7) 0.3212(6) 0.4949(4) 0.082(2) Uani 1 1 d . . .
H27 H -0.2311 0.3542 0.4863 0.098 Uiso 1 1 calc R . .
C28 C -0.1107(8) 0.3063(7) 0.4511(4) 0.091(2) Uani 1 1 d . . .
H28 H -0.1084 0.3302 0.4128 0.110 Uiso 1 1 calc R . .
C29 C -0.0418(6) 0.2555(6) 0.4652(3) 0.075(2) Uani 1 1 d . . .
H29 H 0.0053 0.2432 0.4358 0.090 Uiso 1 1 calc R . .
C30 C -0.0437(5) 0.2238(5) 0.5226(3) 0.0483(14) Uani 1 1 d . . .
C31 C 0.0314(5) 0.1718(4) 0.5413(3) 0.0449(13) Uani 1 1 d . . .
C32 C 0.1285(5) 0.1817(5) 0.5114(3) 0.0523(15) Uani 1 1 d . . .
H32 H 0.1483 0.2222 0.4802 0.063 Uiso 1 1 calc R . .
C33 C 0.1966(5) 0.1306(5) 0.5285(3) 0.0471(14) Uani 1 1 d . . .
C34 C 0.1660(5) 0.0763(5) 0.5771(3) 0.0480(14) Uani 1 1 d . . .
H34 H 0.2106 0.0436 0.5908 0.058 Uiso 1 1 calc R . .
C35 C 0.0686(5) 0.0699(4) 0.6058(3) 0.0427(13) Uani 1 1 d . . .
C36 C 0.0320(5) 0.0096(5) 0.6578(3) 0.0486(14) Uani 1 1 d . . .
C37 C 0.1135(6) 0.0136(6) 0.7056(3) 0.0636(17) Uani 1 1 d . . .
H37 H 0.1925 0.0541 0.7054 0.076 Uiso 1 1 calc R . .
C38 C 0.0783(8) -0.0427(7) 0.7543(3) 0.081(2) Uani 1 1 d . . .
H38 H 0.1332 -0.0369 0.7877 0.098 Uiso 1 1 calc R . .
C39 C -0.0380(8) -0.1066(6) 0.7522(4) 0.082(2) Uani 1 1 d . . .
H39 H -0.0615 -0.1463 0.7836 0.099 Uiso 1 1 calc R . .
C40 C -0.1195(7) -0.1126(6) 0.7047(3) 0.0718(19) Uani 1 1 d . . .
H40 H -0.1982 -0.1560 0.7039 0.086 Uiso 1 1 calc R . .
C41 C -0.0855(6) -0.0543(5) 0.6580(3) 0.0581(16) Uani 1 1 d . . .
H41 H -0.1417 -0.0576 0.6262 0.070 Uiso 1 1 calc R . .
C42 C 0.2972(5) 0.1378(5) 0.4949(3) 0.0499(14) Uani 1 1 d . . .
C43 C 0.3272(5) 0.0529(5) 0.4804(3) 0.0545(15) Uani 1 1 d . . .
H43 H 0.2886 -0.0083 0.4961 0.065 Uiso 1 1 calc R . .
C44 C 0.4129(5) 0.0565(5) 0.4432(3) 0.0607(16) Uani 1 1 d . . .
H44 H 0.4302 -0.0028 0.4332 0.073 Uiso 1 1 calc R . .
C45 C 0.4733(5) 0.1464(5) 0.4208(3) 0.0561(16) Uani 1 1 d . . .
C46 C 0.4472(6) 0.2336(5) 0.4356(4) 0.072(2) Uani 1 1 d . . .
H46 H 0.4878 0.2952 0.4207 0.087 Uiso 1 1 calc R . .
C47 C 0.3615(6) 0.2297(5) 0.4723(3) 0.0680(19) Uani 1 1 d . . .
H47 H 0.3454 0.2895 0.4825 0.082 Uiso 1 1 calc R . .
C48 C 0.6012(6) 0.0772(7) 0.3602(4) 0.083(2) Uani 1 1 d . . .
H48 H 0.5829 0.0128 0.3729 0.099 Uiso 1 1 calc R . .
C49 C 0.6753(6) 0.1163(8) 0.3184(4) 0.095(3) Uani 1 1 d . . .
H49 H 0.7183 0.0838 0.2971 0.114 Uiso 1 1 calc R . .
C50 C 0.6754(6) 0.2125(8) 0.3133(4) 0.089(2) Uani 1 1 d . . .
H50 H 0.7187 0.2559 0.2873 0.107 Uiso 1 1 calc R . .
C51 C 0.8937(6) 0.4637(6) 0.7415(3) 0.0629(17) Uani 1 1 d . . .
H51 H 0.8376 0.3923 0.7272 0.076 Uiso 1 1 calc R . .
C52 C 0.9149(7) 0.5319(7) 0.6994(4) 0.080(2) Uani 1 1 d . . .
H52 H 0.8730 0.5062 0.6571 0.096 Uiso 1 1 calc R . .
C53 C 0.9995(7) 0.6399(7) 0.7205(4) 0.082(2) Uani 1 1 d . . .
H53 H 1.0134 0.6865 0.6927 0.098 Uiso 1 1 calc R . .
C54 C 1.0618(6) 0.6757(6) 0.7830(4) 0.0716(19) Uani 1 1 d . . .
H54 H 1.1184 0.7469 0.7973 0.086 Uiso 1 1 calc R . .
C55 C 1.0409(5) 0.6069(5) 0.8243(3) 0.0595(16) Uani 1 1 d . . .
H55 H 1.0850 0.6323 0.8659 0.071 Uiso 1 1 calc R . .
C56 C 0.9558(5) 0.5008(5) 0.8056(3) 0.0492(14) Uani 1 1 d . A .
C57 C 0.9264(5) 0.4301(5) 0.8513(3) 0.0475(14) Uani 1 1 d . . .
C58 C 0.7790(5) 0.3007(4) 0.8899(3) 0.0483(14) Uani 1 1 d . . .
C59 C 0.6516(5) 0.2290(5) 0.8825(3) 0.0526(15) Uani 1 1 d . A .
C60 C 0.6092(5) 0.1548(5) 0.9195(3) 0.0663(18) Uani 1 1 d . . .
H60 H 0.6591 0.1527 0.9527 0.080 Uiso 1 1 calc R A .
C61 C 0.4928(6) 0.0835(6) 0.9074(4) 0.076(2) Uani 1 1 d . A .
H61 H 0.4639 0.0317 0.9315 0.092 Uiso 1 1 calc R . .
C62 C 0.4195(6) 0.0897(6) 0.8592(4) 0.080(2) Uani 1 1 d . . .
H62 H 0.3405 0.0426 0.8498 0.096 Uiso 1 1 calc R A .
C63 C 0.4681(6) 0.1685(6) 0.8252(4) 0.077(2) Uani 1 1 d . A .
H63 H 0.4194 0.1729 0.7923 0.092 Uiso 1 1 calc R . .
C64 C 1.0106(5) 0.4325(4) 0.8977(3) 0.0484(14) Uani 1 1 d . A .
H64 H 1.0889 0.4777 0.8990 0.058 Uiso 1 1 calc R . .
C65 C 0.8590(5) 0.3024(5) 0.9380(3) 0.0510(14) Uani 1 1 d . A .
H65 H 0.8335 0.2598 0.9677 0.061 Uiso 1 1 calc R . .
C66 C 0.9787(5) 0.3682(4) 0.9421(3) 0.0454(13) Uani 1 1 d . . .
C67 C 1.0640(5) 0.3670(4) 0.9937(3) 0.0430(13) Uani 1 1 d . A .
C68 C 1.1765(5) 0.4509(4) 1.0137(3) 0.0467(14) Uani 1 1 d . . .
H68 H 1.2018 0.5077 0.9931 0.056 Uiso 1 1 calc R A .
C69 C 1.0333(5) 0.2805(5) 1.0224(3) 0.0567(16) Uani 1 1 d . . .
H69 H 0.9611 0.2213 1.0071 0.068 Uiso 1 1 calc R A .
C70 C 1.2501(5) 0.4499(4) 1.0641(3) 0.0488(14) Uani 1 1 d . A .
H70 H 1.3243 0.5067 1.0771 0.059 Uiso 1 1 calc R . .
C71 C 1.1063(5) 0.2791(5) 1.0730(3) 0.0573(16) Uani 1 1 d . A .
H71 H 1.0823 0.2203 1.0919 0.069 Uiso 1 1 calc R . .
C72 C 1.2159(5) 0.3658(4) 1.0957(3) 0.0456(13) Uani 1 1 d . . .
C73 C 1.3000(6) 0.2806(6) 1.1638(3) 0.0649(18) Uani 1 1 d . . .
H73 H 1.2590 0.2087 1.1406 0.078 Uiso 1 1 calc R A .
C74 C 1.3798(6) 0.3169(7) 1.2186(4) 0.078(2) Uani 1 1 d . A .
H74 H 1.4045 0.2771 1.2412 0.093 Uiso 1 1 calc R . .
C75 C 1.4158(6) 0.4279(6) 1.2331(4) 0.076(2) Uani 1 1 d . . .
H75 H 1.4729 0.4759 1.2682 0.092 Uiso 1 1 calc R A .
N1 N 0.0009(4) 0.1165(4) 0.5874(2) 0.0421(11) Uani 1 1 d . . .
N2 N -0.1125(4) 0.2384(4) 0.5653(2) 0.0506(12) Uani 1 1 d . . .
N3 N 0.5591(4) 0.1507(5) 0.3798(3) 0.0631(14) Uani 1 1 d . . .
N4 N 0.6040(5) 0.2352(5) 0.3513(3) 0.0815(18) Uani 1 1 d . . .
N5 N 0.0428(4) 0.2471(3) 0.7521(2) 0.0417(10) Uani 1 1 d . . .
N6 N -0.1915(4) 0.1249(4) 0.7404(2) 0.0507(12) Uani 1 1 d . . .
N7 N 0.5219(4) 0.2931(4) 1.0682(2) 0.0520(12) Uani 1 1 d . . .
N8 N 0.6037(5) 0.3912(5) 1.1046(3) 0.0767(17) Uani 1 1 d . . .
N9 N 0.5803(4) 0.2386(4) 0.8367(3) 0.0602(14) Uani 1 1 d . A .
N10 N 0.8118(4) 0.3651(4) 0.8474(2) 0.0486(11) Uani 1 1 d . A .
N11 N 1.2896(4) 0.3656(4) 1.1483(2) 0.0501(12) Uani 1 1 d . A .
N12 N 1.3611(4) 0.4584(4) 1.1923(3) 0.0614(14) Uani 1 1 d . . .
N13 N 0.5351(7) 0.2355(7) 0.6535(4) 0.0896(18) Uani 1 1 d U . .
N14 N 0.8017(8) 0.0774(6) 0.0498(7) 0.108(3) Uani 1 1 d . . .
O1 O 0.6177(18) 0.3319(12) 0.6676(8) 0.104(4) Uani 0.49(2) 1 d PU A 1
O2 O 0.5429(17) 0.1806(14) 0.6015(9) 0.123(5) Uani 0.49(2) 1 d PU A 1
O3 O 0.460(2) 0.214(2) 0.6866(11) 0.136(6) Uani 0.49(2) 1 d PU A 1
O1' O 0.5594(16) 0.3334(12) 0.6750(7) 0.094(3) Uani 0.51(2) 1 d PU A 2
O2' O 0.5917(18) 0.1925(16) 0.6320(11) 0.128(5) Uani 0.51(2) 1 d PU A 2
O3' O 0.4316(15) 0.1694(15) 0.6606(10) 0.114(5) Uani 0.51(2) 1 d PU A 2
O4 O 0.7884(15) 0.0468(6) -0.0015(4) 0.308(13) Uani 1 1 d . . .
O5 O 0.8618(9) 0.0714(6) 0.0884(4) 0.169(5) Uani 1 1 d . . .
O6 O 0.7471(12) 0.1173(12) 0.0723(12) 0.378(14) Uani 1 1 d . . .
O7 O 0.6666(8) 0.4902(15) 0.5790(5) 0.319(10) Uani 1 1 d . . .
O8 O 0.9420(9) 0.9805(9) 0.9407(6) 0.217(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N6 151.59(17) . .
N2 Ag1 N5 133.98(16) . .
N6 Ag1 N5 71.90(15) . .
N2 Ag1 N1 71.49(16) . .
N6 Ag1 N1 126.65(16) . .
N5 Ag1 N1 91.86(14) . .
N12 Ag2 N9 133.50(19) 2_767 .
N12 Ag2 N10 123.83(17) 2_767 .
N9 Ag2 N10 70.43(17) . .
N12 Ag2 O1' 90.3(4) 2_767 .
N9 Ag2 O1' 109.3(4) . .
N10 Ag2 O1' 134.5(4) . .
N12 Ag2 O1 99.1(5) 2_767 .
N9 Ag2 O1 112.2(4) . .
N10 Ag2 O1 117.8(5) . .
O1' Ag2 O1 17.6(4) . .
N6 C1 C2 123.1(6) . .
N6 C1 H1 118.5 . .
C2 C1 H1 118.5 . .
C3 C2 C1 118.1(6) . .
C3 C2 H2 121.0 . .
C1 C2 H2 121.0 . .
C4 C3 C2 120.2(6) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 119.1(6) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
N6 C5 C4 121.1(5) . .
N6 C5 C6 117.8(5) . .
C4 C5 C6 121.1(5) . .
N5 C6 C7 121.7(5) . .
N5 C6 C5 116.0(4) . .
C7 C6 C5 122.2(5) . .
C6 C7 C8 120.5(5) . .
C6 C7 H7 119.8 . .
C8 C7 H7 119.8 . .
C9 C8 C7 117.0(5) . .
C9 C8 C17 122.0(5) . .
C7 C8 C17 121.0(5) . .
C8 C9 C10 120.4(5) . .
C8 C9 H9 119.8 . .
C10 C9 H9 119.8 . .
N5 C10 C9 121.9(5) . .
N5 C10 C11 117.5(5) . .
C9 C10 C11 120.6(5) . .
C16 C11 C12 118.1(5) . .
C16 C11 C10 121.3(5) . .
C12 C11 C10 120.5(5) . .
C13 C12 C11 120.4(6) . .
C13 C12 H12 119.8 . .
C11 C12 H12 119.8 . .
C14 C13 C12 120.1(7) . .
C14 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
C15 C14 C13 120.5(6) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C14 C15 C16 119.9(7) . .
C14 C15 H15 120.1 . .
C16 C15 H15 120.1 . .
C15 C16 C11 120.9(6) . .
C15 C16 H16 119.5 . .
C11 C16 H16 119.5 . .
C22 C17 C18 117.4(5) . .
C22 C17 C8 121.7(5) . .
C18 C17 C8 120.9(5) . .
C19 C18 C17 121.1(5) . .
C19 C18 H18 119.4 . .
C17 C18 H18 119.4 . .
C20 C19 C18 120.7(5) . .
C20 C19 H19 119.6 . .
C18 C19 H19 119.6 . .
C19 C20 C21 119.3(5) . .
C19 C20 N7 120.8(5) . .
C21 C20 N7 119.9(5) . .
C22 C21 C20 120.0(5) . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
C21 C22 C17 121.4(5) . .
C21 C22 H22 119.3 . .
C17 C22 H22 119.3 . .
N7 C23 C24 107.3(7) . .
N7 C23 H23 126.3 . .
C24 C23 H23 126.3 . .
C23 C24 C25 105.3(7) . .
C23 C24 H24 127.4 . .
C25 C24 H24 127.4 . .
N8 C25 C24 112.4(7) . .
N8 C25 H25 123.8 . .
C24 C25 H25 123.8 . .
C27 C26 N2 123.0(6) . .
C27 C26 H26 118.5 . .
N2 C26 H26 118.5 . .
C26 C27 C28 117.8(7) . .
C26 C27 H27 121.1 . .
C28 C27 H27 121.1 . .
C29 C28 C27 119.4(7) . .
C29 C28 H28 120.3 . .
C27 C28 H28 120.3 . .
C30 C29 C28 119.6(7) . .
C30 C29 H29 120.2 . .
C28 C29 H29 120.2 . .
N2 C30 C29 121.6(6) . .
N2 C30 C31 116.6(5) . .
C29 C30 C31 121.8(5) . .
N1 C31 C32 122.3(5) . .
N1 C31 C30 117.1(5) . .
C32 C31 C30 120.6(5) . .
C31 C32 C33 119.8(5) . .
C31 C32 H32 120.1 . .
C33 C32 H32 120.1 . .
C34 C33 C32 117.2(5) . .
C34 C33 C42 123.0(5) . .
C32 C33 C42 119.7(5) . .
C33 C34 C35 120.5(5) . .
C33 C34 H34 119.7 . .
C35 C34 H34 119.7 . .
N1 C35 C34 121.8(5) . .
N1 C35 C36 116.5(5) . .
C34 C35 C36 121.7(5) . .
C37 C36 C41 118.6(6) . .
C37 C36 C35 120.9(5) . .
C41 C36 C35 120.5(5) . .
C36 C37 C38 120.5(7) . .
C36 C37 H37 119.8 . .
C38 C37 H37 119.8 . .
C39 C38 C37 119.4(7) . .
C39 C38 H38 120.3 . .
C37 C38 H38 120.3 . .
C40 C39 C38 120.7(7) . .
C40 C39 H39 119.7 . .
C38 C39 H39 119.7 . .
C39 C40 C41 120.1(7) . .
C39 C40 H40 120.0 . .
C41 C40 H40 120.0 . .
C40 C41 C36 120.7(6) . .
C40 C41 H41 119.6 . .
C36 C41 H41 119.6 . .
C43 C42 C47 116.8(5) . .
C43 C42 C33 122.1(5) . .
C47 C42 C33 120.9(5) . .
C44 C43 C42 121.5(6) . .
C44 C43 H43 119.3 . .
C42 C43 H43 119.3 . .
C45 C44 C43 120.6(6) . .
C45 C44 H44 119.7 . .
C43 C44 H44 119.7 . .
C44 C45 C46 119.4(6) . .
C44 C45 N3 121.9(6) . .
C46 C45 N3 118.7(6) . .
C47 C46 C45 119.8(6) . .
C47 C46 H46 120.1 . .
C45 C46 H46 120.1 . .
C46 C47 C42 121.8(6) . .
C46 C47 H47 119.1 . .
C42 C47 H47 119.1 . .
N3 C48 C49 106.2(8) . .
N3 C48 H48 126.9 . .
C49 C48 H48 126.9 . .
C48 C49 C50 107.4(8) . .
C48 C49 H49 126.3 . .
C50 C49 H49 126.3 . .
N4 C50 C49 110.2(7) . .
N4 C50 H50 124.9 . .
C49 C50 H50 124.9 . .
C52 C51 C56 121.0(7) . .
C52 C51 H51 119.5 . .
C56 C51 H51 119.5 . .
C51 C52 C53 119.9(7) . .
C51 C52 H52 120.0 . .
C53 C52 H52 120.0 . .
C54 C53 C52 119.0(7) . .
C54 C53 H53 120.5 . .
C52 C53 H53 120.5 . .
C55 C54 C53 120.6(7) . .
C55 C54 H54 119.7 . .
C53 C54 H54 119.7 . .
C54 C55 C56 121.7(6) . .
C54 C55 H55 119.1 . .
C56 C55 H55 119.1 . .
C55 C56 C51 117.7(6) . .
C55 C56 C57 121.9(6) . .
C51 C56 C57 120.4(6) . .
N10 C57 C64 121.7(5) . .
N10 C57 C56 115.9(5) . .
C64 C57 C56 122.3(5) . .
N10 C58 C65 121.8(5) . .
N10 C58 C59 116.4(5) . .
C65 C58 C59 121.8(5) . .
N9 C59 C60 121.5(6) . .
N9 C59 C58 117.0(5) . .
C60 C59 C58 121.5(6) . .
C59 C60 C61 119.8(7) . .
C59 C60 H60 120.1 . .
C61 C60 H60 120.1 . .
C60 C61 C62 119.4(7) . .
C60 C61 H61 120.3 . .
C62 C61 H61 120.3 . .
C61 C62 C63 117.4(6) . .
C61 C62 H62 121.3 . .
C63 C62 H62 121.3 . .
N9 C63 C62 124.0(7) . .
N9 C63 H63 118.0 . .
C62 C63 H63 118.0 . .
C66 C64 C57 120.6(5) . .
C66 C64 H64 119.7 . .
C57 C64 H64 119.7 . .
C58 C65 C66 120.3(5) . .
C58 C65 H65 119.8 . .
C66 C65 H65 119.8 . .
C64 C66 C65 116.9(5) . .
C64 C66 C67 123.7(5) . .
C65 C66 C67 119.4(5) . .
C69 C67 C68 117.9(5) . .
C69 C67 C66 120.1(5) . .
C68 C67 C66 122.0(5) . .
C70 C68 C67 120.2(5) . .
C70 C68 H68 119.9 . .
C67 C68 H68 119.9 . .
C67 C69 C71 122.0(5) . .
C67 C69 H69 119.0 . .
C71 C69 H69 119.0 . .
C68 C70 C72 121.6(5) . .
C68 C70 H70 119.2 . .
C72 C70 H70 119.2 . .
C69 C71 C72 120.0(5) . .
C69 C71 H71 120.0 . .
C72 C71 H71 120.0 . .
C70 C72 C71 118.0(5) . .
C70 C72 N11 121.9(5) . .
C71 C72 N11 120.1(5) . .
N11 C73 C74 108.8(6) . .
N11 C73 H73 125.6 . .
C74 C73 H73 125.6 . .
C73 C74 C75 103.2(6) . .
C73 C74 H74 128.4 . .
C75 C74 H74 128.4 . .
N12 C75 C74 113.2(6) . .
N12 C75 H75 123.4 . .
C74 C75 H75 123.4 . .
C31 N1 C35 118.2(4) . .
C31 N1 Ag1 109.3(3) . .
C35 N1 Ag1 125.4(3) . .
C30 N2 C26 118.6(5) . .
C30 N2 Ag1 119.5(4) . .
C26 N2 Ag1 121.9(4) . .
C48 N3 N4 111.3(6) . .
C48 N3 C45 129.3(6) . .
N4 N3 C45 119.3(5) . .
C50 N4 N3 104.9(7) . .
C10 N5 C6 118.5(4) . .
C10 N5 Ag1 127.1(3) . .
C6 N5 Ag1 113.0(3) . .
C5 N6 C1 118.5(5) . .
C5 N6 Ag1 118.3(3) . .
C1 N6 Ag1 121.3(4) . .
C23 N7 N8 111.3(5) . .
C23 N7 C20 127.7(5) . .
N8 N7 C20 120.9(5) . .
C25 N8 N7 103.6(6) . .
C63 N9 C59 117.9(6) . .
C63 N9 Ag2 123.8(5) . .
C59 N9 Ag2 118.0(4) . .
C57 N10 C58 118.6(5) . .
C57 N10 Ag2 125.0(4) . .
C58 N10 Ag2 114.3(4) . .
C73 N11 N12 110.5(5) . .
C73 N11 C72 128.5(5) . .
N12 N11 C72 121.0(5) . .
C75 N12 N11 104.3(5) . .
C75 N12 Ag2 127.7(5) . 2_767
N11 N12 Ag2 125.4(4) . 2_767
O2' N13 O3 134.2(17) . .
O2' N13 O2 38.8(10) . .
O3 N13 O2 129.6(16) . .
O2' N13 O1' 131.5(14) . .
O3 N13 O1' 88.6(13) . .
O2 N13 O1' 134.8(15) . .
O2' N13 O1 95.9(14) . .
O3 N13 O1 119.0(14) . .
O2 N13 O1 111.1(13) . .
O1' N13 O1 35.7(8) . .
O2' N13 O3' 114.1(14) . .
O3 N13 O3' 31.6(11) . .
O2 N13 O3' 98.2(13) . .
O1' N13 O3' 114.2(12) . .
O1 N13 O3' 148.8(13) . .
O4 N14 O5 128.3(16) . .
O4 N14 O6 120(2) . .
O5 N14 O6 111.4(19) . .
N13 O1 Ag2 104.0(10) . .
N13 O1' Ag2 106.8(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.217(5) .
Ag1 N6 2.231(4) .
Ag1 N5 2.404(4) .
Ag1 N1 2.450(4) .
Ag2 N12 2.232(5) 2_767
Ag2 N9 2.297(5) .
Ag2 N10 2.399(5) .
Ag2 O1' 2.514(15) .
Ag2 O1 2.545(16) .
C1 N6 1.347(7) .
C1 C2 1.375(9) .
C1 H1 0.9300 .
C2 C3 1.366(9) .
C2 H2 0.9300 .
C3 C4 1.365(8) .
C3 H3 0.9300 .
C4 C5 1.401(8) .
C4 H4 0.9300 .
C5 N6 1.335(7) .
C5 C6 1.504(7) .
C6 N5 1.360(6) .
C6 C7 1.368(7) .
C7 C8 1.404(7) .
C7 H7 0.9300 .
C8 C9 1.383(7) .
C8 C17 1.494(7) .
C9 C10 1.384(7) .
C9 H9 0.9300 .
C10 N5 1.347(6) .
C10 C11 1.489(7) .
C11 C16 1.390(8) .
C11 C12 1.397(8) .
C12 C13 1.379(8) .
C12 H12 0.9300 .
C13 C14 1.370(10) .
C13 H13 0.9300 .
C14 C15 1.370(11) .
C14 H14 0.9300 .
C15 C16 1.378(9) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C22 1.391(7) .
C17 C18 1.397(7) .
C18 C19 1.376(7) .
C18 H18 0.9300 .
C19 C20 1.370(7) .
C19 H19 0.9300 .
C20 C21 1.392(7) .
C20 N7 1.411(7) .
C21 C22 1.378(7) .
C21 H21 0.9300 .
C22 H22 0.9300 .
C23 N7 1.333(8) .
C23 C24 1.352(10) .
C23 H23 0.9300 .
C24 C25 1.366(11) .
C24 H24 0.9300 .
C25 N8 1.320(8) .
C25 H25 0.9300 .
C26 C27 1.359(9) .
C26 N2 1.366(7) .
C26 H26 0.9300 .
C27 C28 1.393(10) .
C27 H27 0.9300 .
C28 C29 1.389(10) .
C28 H28 0.9300 .
C29 C30 1.367(8) .
C29 H29 0.9300 .
C30 N2 1.339(7) .
C30 C31 1.496(8) .
C31 N1 1.337(7) .
C31 C32 1.392(8) .
C32 C33 1.402(8) .
C32 H32 0.9300 .
C33 C34 1.373(7) .
C33 C42 1.480(8) .
C34 C35 1.392(7) .
C34 H34 0.9300 .
C35 N1 1.356(6) .
C35 C36 1.493(7) .
C36 C37 1.378(8) .
C36 C41 1.392(8) .
C37 C38 1.399(9) .
C37 H37 0.9300 .
C38 C39 1.371(10) .
C38 H38 0.9300 .
C39 C40 1.364(10) .
C39 H39 0.9300 .
C40 C41 1.377(8) .
C40 H40 0.9300 .
C41 H41 0.9300 .
C42 C43 1.377(8) .
C42 C47 1.402(8) .
C43 C44 1.372(8) .
C43 H43 0.9300 .
C44 C45 1.369(8) .
C44 H44 0.9300 .
C45 C46 1.375(9) .
C45 N3 1.425(7) .
C46 C47 1.365(8) .
C46 H46 0.9300 .
C47 H47 0.9300 .
C48 N3 1.351(9) .
C48 C49 1.355(10) .
C48 H48 0.9300 .
C49 C50 1.369(11) .
C49 H49 0.9300 .
C50 N4 1.341(9) .
C50 H50 0.9300 .
C51 C52 1.385(9) .
C51 C56 1.405(8) .
C51 H51 0.9300 .
C52 C53 1.405(11) .
C52 H52 0.9300 .
C53 C54 1.380(10) .
C53 H53 0.9300 .
C54 C55 1.379(9) .
C54 H54 0.9300 .
C55 C56 1.386(8) .
C55 H55 0.9300 .
C56 C57 1.469(8) .
C57 N10 1.352(7) .
C57 C64 1.393(8) .
C58 N10 1.355(7) .
C58 C65 1.384(8) .
C58 C59 1.494(8) .
C59 N9 1.347(8) .
C59 C60 1.372(9) .
C60 C61 1.376(9) .
C60 H60 0.9300 .
C61 C62 1.377(10) .
C61 H61 0.9300 .
C62 C63 1.382(10) .
C62 H62 0.9300 .
C63 N9 1.331(8) .
C63 H63 0.9300 .
C64 C66 1.387(7) .
C64 H64 0.9300 .
C65 C66 1.405(7) .
C65 H65 0.9300 .
C66 C67 1.498(8) .
C67 C69 1.380(8) .
C67 C68 1.397(7) .
C68 C70 1.379(8) .
C68 H68 0.9300 .
C69 C71 1.381(8) .
C69 H69 0.9300 .
C70 C72 1.391(7) .
C70 H70 0.9300 .
C71 C72 1.394(8) .
C71 H71 0.9300 .
C72 N11 1.412(7) .
C73 N11 1.345(7) .
C73 C74 1.353(9) .
C73 H73 0.9300 .
C74 C75 1.385(10) .
C74 H74 0.9300 .
C75 N12 1.313(8) .
C75 H75 0.9300 .
N3 N4 1.359(8) .
N7 N8 1.366(7) .
N11 N12 1.350(7) .
N12 Ag2 2.232(5) 2_767
N13 O2' 1.173(18) .
N13 O3 1.20(2) .
N13 O2 1.244(17) .
N13 O1' 1.250(15) .
N13 O1 1.282(16) .
N13 O3' 1.300(18) .
N14 O4 1.058(12) .
N14 O5 1.121(11) .
N14 O6 1.131(14) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N6 C1 C2 C3 1.4(11) . .
C1 C2 C3 C4 -0.1(10) . .
C2 C3 C4 C5 -0.8(10) . .
C3 C4 C5 N6 0.5(9) . .
C3 C4 C5 C6 -179.0(5) . .
N6 C5 C6 N5 -2.8(7) . .
C4 C5 C6 N5 176.7(5) . .
N6 C5 C6 C7 178.4(5) . .
C4 C5 C6 C7 -2.1(8) . .
N5 C6 C7 C8 -0.4(8) . .
C5 C6 C7 C8 178.3(5) . .
C6 C7 C8 C9 -0.8(8) . .
C6 C7 C8 C17 179.8(5) . .
C7 C8 C9 C10 1.0(8) . .
C17 C8 C9 C10 -179.6(5) . .
C8 C9 C10 N5 0.0(9) . .
C8 C9 C10 C11 -180.0(5) . .
N5 C10 C11 C16 44.3(8) . .
C9 C10 C11 C16 -135.7(6) . .
N5 C10 C11 C12 -136.3(5) . .
C9 C10 C11 C12 43.7(8) . .
C16 C11 C12 C13 0.1(9) . .
C10 C11 C12 C13 -179.4(5) . .
C11 C12 C13 C14 1.0(10) . .
C12 C13 C14 C15 -1.3(11) . .
C13 C14 C15 C16 0.5(11) . .
C14 C15 C16 C11 0.6(11) . .
C12 C11 C16 C15 -0.9(9) . .
C10 C11 C16 C15 178.6(6) . .
C9 C8 C17 C22 22.2(8) . .
C7 C8 C17 C22 -158.5(5) . .
C9 C8 C17 C18 -157.0(5) . .
C7 C8 C17 C18 22.4(8) . .
C22 C17 C18 C19 0.1(9) . .
C8 C17 C18 C19 179.3(5) . .
C17 C18 C19 C20 -0.2(9) . .
C18 C19 C20 C21 1.0(9) . .
C18 C19 C20 N7 -178.9(5) . .
C19 C20 C21 C22 -1.7(9) . .
N7 C20 C21 C22 178.3(5) . .
C20 C21 C22 C17 1.6(9) . .
C18 C17 C22 C21 -0.8(9) . .
C8 C17 C22 C21 -180.0(5) . .
N7 C23 C24 C25 -1.1(9) . .
C23 C24 C25 N8 2.3(10) . .
N2 C26 C27 C28 0.8(12) . .
C26 C27 C28 C29 0.8(13) . .
C27 C28 C29 C30 -1.9(13) . .
C28 C29 C30 N2 1.4(11) . .
C28 C29 C30 C31 -178.1(7) . .
N2 C30 C31 N1 19.0(7) . .
C29 C30 C31 N1 -161.4(6) . .
N2 C30 C31 C32 -160.8(5) . .
C29 C30 C31 C32 18.7(9) . .
N1 C31 C32 C33 1.4(8) . .
C30 C31 C32 C33 -178.7(5) . .
C31 C32 C33 C34 -2.9(8) . .
C31 C32 C33 C42 177.7(5) . .
C32 C33 C34 C35 2.2(8) . .
C42 C33 C34 C35 -178.4(5) . .
C33 C34 C35 N1 0.0(8) . .
C33 C34 C35 C36 178.8(5) . .
N1 C35 C36 C37 -141.8(6) . .
C34 C35 C36 C37 39.3(8) . .
N1 C35 C36 C41 39.8(8) . .
C34 C35 C36 C41 -139.1(6) . .
C41 C36 C37 C38 -2.0(10) . .
C35 C36 C37 C38 179.6(6) . .
C36 C37 C38 C39 3.3(11) . .
C37 C38 C39 C40 -2.4(12) . .
C38 C39 C40 C41 0.1(12) . .
C39 C40 C41 C36 1.2(10) . .
C37 C36 C41 C40 -0.3(9) . .
C35 C36 C41 C40 178.1(6) . .
C34 C33 C42 C43 36.8(9) . .
C32 C33 C42 C43 -143.8(6) . .
C34 C33 C42 C47 -147.7(6) . .
C32 C33 C42 C47 31.6(8) . .
C47 C42 C43 C44 -2.5(9) . .
C33 C42 C43 C44 173.1(6) . .
C42 C43 C44 C45 1.6(10) . .
C43 C44 C45 C46 -0.2(10) . .
C43 C44 C45 N3 -177.2(6) . .
C44 C45 C46 C47 -0.2(11) . .
N3 C45 C46 C47 177.0(6) . .
C45 C46 C47 C42 -0.9(11) . .
C43 C42 C47 C46 2.2(10) . .
C33 C42 C47 C46 -173.5(6) . .
N3 C48 C49 C50 -0.5(9) . .
C48 C49 C50 N4 0.5(10) . .
C56 C51 C52 C53 0.1(10) . .
C51 C52 C53 C54 1.0(11) . .
C52 C53 C54 C55 -0.4(11) . .
C53 C54 C55 C56 -1.3(10) . .
C54 C55 C56 C51 2.4(9) . .
C54 C55 C56 C57 -174.7(6) . .
C52 C51 C56 C55 -1.8(9) . .
C52 C51 C56 C57 175.4(6) . .
C55 C56 C57 N10 140.0(6) . .
C51 C56 C57 N10 -37.1(7) . .
C55 C56 C57 C64 -37.5(8) . .
C51 C56 C57 C64 145.4(6) . .
N10 C58 C59 N9 -3.3(8) . .
C65 C58 C59 N9 175.9(5) . .
N10 C58 C59 C60 175.2(6) . .
C65 C58 C59 C60 -5.6(9) . .
N9 C59 C60 C61 4.1(10) . .
C58 C59 C60 C61 -174.2(6) . .
C59 C60 C61 C62 -1.7(10) . .
C60 C61 C62 C63 0.0(11) . .
C61 C62 C63 N9 -0.5(11) . .
N10 C57 C64 C66 -0.5(8) . .
C56 C57 C64 C66 176.9(5) . .
N10 C58 C65 C66 -3.0(9) . .
C59 C58 C65 C66 177.8(5) . .
C57 C64 C66 C65 -0.4(8) . .
C57 C64 C66 C67 -179.6(5) . .
C58 C65 C66 C64 2.1(8) . .
C58 C65 C66 C67 -178.7(5) . .
C64 C66 C67 C69 -160.2(6) . .
C65 C66 C67 C69 20.7(8) . .
C64 C66 C67 C68 18.9(8) . .
C65 C66 C67 C68 -160.3(5) . .
C69 C67 C68 C70 -4.8(8) . .
C66 C67 C68 C70 176.2(5) . .
C68 C67 C69 C71 5.1(9) . .
C66 C67 C69 C71 -175.8(5) . .
C67 C68 C70 C72 0.7(9) . .
C67 C69 C71 C72 -1.4(10) . .
C68 C70 C72 C71 3.1(8) . .
C68 C70 C72 N11 -178.4(5) . .
C69 C71 C72 C70 -2.7(9) . .
C69 C71 C72 N11 178.7(5) . .
N11 C73 C74 C75 -0.9(8) . .
C73 C74 C75 N12 1.8(9) . .
C32 C31 N1 C35 0.8(8) . .
C30 C31 N1 C35 -179.1(5) . .
C32 C31 N1 Ag1 153.1(4) . .
C30 C31 N1 Ag1 -26.8(5) . .
C34 C35 N1 C31 -1.5(7) . .
C36 C35 N1 C31 179.6(5) . .
C34 C35 N1 Ag1 -149.0(4) . .
C36 C35 N1 Ag1 32.2(6) . .
N2 Ag1 N1 C31 20.1(3) . .
N6 Ag1 N1 C31 175.2(3) . .
N5 Ag1 N1 C31 -116.1(3) . .
N2 Ag1 N1 C35 169.9(4) . .
N6 Ag1 N1 C35 -35.0(5) . .
N5 Ag1 N1 C35 33.7(4) . .
C29 C30 N2 C26 0.2(9) . .
C31 C30 N2 C26 179.7(5) . .
C29 C30 N2 Ag1 -177.9(5) . .
C31 C30 N2 Ag1 1.6(7) . .
C27 C26 N2 C30 -1.4(10) . .
C27 C26 N2 Ag1 176.7(6) . .
N6 Ag1 N2 C30 -146.0(4) . .
N5 Ag1 N2 C30 62.7(5) . .
N1 Ag1 N2 C30 -11.3(4) . .
N6 Ag1 N2 C26 35.9(7) . .
N5 Ag1 N2 C26 -115.3(5) . .
N1 Ag1 N2 C26 170.6(5) . .
C49 C48 N3 N4 0.3(8) . .
C49 C48 N3 C45 176.1(6) . .
C44 C45 N3 C48 -4.9(11) . .
C46 C45 N3 C48 178.0(7) . .
C44 C45 N3 N4 170.5(6) . .
C46 C45 N3 N4 -6.6(9) . .
C49 C50 N4 N3 -0.3(9) . .
C48 N3 N4 C50 0.0(8) . .
C45 N3 N4 C50 -176.2(6) . .
C9 C10 N5 C6 -1.3(8) . .
C11 C10 N5 C6 178.7(5) . .
C9 C10 N5 Ag1 -166.5(4) . .
C11 C10 N5 Ag1 13.5(7) . .
C7 C6 N5 C10 1.5(8) . .
C5 C6 N5 C10 -177.3(5) . .
C7 C6 N5 Ag1 168.7(4) . .
C5 C6 N5 Ag1 -10.2(5) . .
N2 Ag1 N5 C10 -14.9(5) . .
N6 Ag1 N5 C10 179.1(5) . .
N1 Ag1 N5 C10 50.9(4) . .
N2 Ag1 N5 C6 179.3(3) . .
N6 Ag1 N5 C6 13.2(3) . .
N1 Ag1 N5 C6 -114.9(4) . .
C4 C5 N6 C1 0.8(9) . .
C6 C5 N6 C1 -179.7(5) . .
C4 C5 N6 Ag1 -163.7(4) . .
C6 C5 N6 Ag1 15.8(6) . .
C2 C1 N6 C5 -1.7(10) . .
C2 C1 N6 Ag1 162.2(5) . .
N2 Ag1 N6 C5 -174.0(4) . .
N5 Ag1 N6 C5 -15.4(4) . .
N1 Ag1 N6 C5 63.1(5) . .
N2 Ag1 N6 C1 22.0(7) . .
N5 Ag1 N6 C1 -179.3(5) . .
N1 Ag1 N6 C1 -100.9(5) . .
C24 C23 N7 N8 -0.5(8) . .
C24 C23 N7 C20 -179.3(6) . .
C19 C20 N7 C23 28.1(9) . .
C21 C20 N7 C23 -151.8(6) . .
C19 C20 N7 N8 -150.6(6) . .
C21 C20 N7 N8 29.5(8) . .
C24 C25 N8 N7 -2.5(9) . .
C23 N7 N8 C25 1.8(8) . .
C20 N7 N8 C25 -179.3(6) . .
C62 C63 N9 C59 2.8(10) . .
C62 C63 N9 Ag2 -169.8(6) . .
C60 C59 N9 C63 -4.6(9) . .
C58 C59 N9 C63 173.9(6) . .
C60 C59 N9 Ag2 168.5(5) . .
C58 C59 N9 Ag2 -13.1(7) . .
N12 Ag2 N9 C63 69.9(6) 2_767 .
N10 Ag2 N9 C63 -171.6(6) . .
O1' Ag2 N9 C63 -40.0(7) . .
O1 Ag2 N9 C63 -58.7(8) . .
N12 Ag2 N9 C59 -102.7(5) 2_767 .
N10 Ag2 N9 C59 15.8(4) . .
O1' Ag2 N9 C59 147.4(6) . .
O1 Ag2 N9 C59 128.7(7) . .
C64 C57 N10 C58 -0.2(8) . .
C56 C57 N10 C58 -177.8(5) . .
C64 C57 N10 Ag2 162.3(4) . .
C56 C57 N10 Ag2 -15.2(7) . .
C65 C58 N10 C57 2.0(8) . .
C59 C58 N10 C57 -178.8(5) . .
C65 C58 N10 Ag2 -162.4(4) . .
C59 C58 N10 Ag2 16.8(6) . .
N12 Ag2 N10 C57 -50.4(5) 2_767 .
N9 Ag2 N10 C57 179.7(5) . .
O1' Ag2 N10 C57 81.5(7) . .
O1 Ag2 N10 C57 74.3(6) . .
N12 Ag2 N10 C58 112.8(4) 2_767 .
N9 Ag2 N10 C58 -17.1(4) . .
O1' Ag2 N10 C58 -115.3(6) . .
O1 Ag2 N10 C58 -122.5(5) . .
C74 C73 N11 N12 -0.3(7) . .
C74 C73 N11 C72 -179.1(6) . .
C70 C72 N11 C73 -145.4(6) . .
C71 C72 N11 C73 33.2(9) . .
C70 C72 N11 N12 35.8(8) . .
C71 C72 N11 N12 -145.6(6) . .
C74 C75 N12 N11 -2.0(8) . .
C74 C75 N12 Ag2 160.5(5) . 2_767
C73 N11 N12 C75 1.4(7) . .
C72 N11 N12 C75 -179.7(5) . .
C73 N11 N12 Ag2 -161.6(4) . 2_767
C72 N11 N12 Ag2 17.3(7) . 2_767
O2' N13 O1 Ag2 -111.6(17) . .
O3 N13 O1 Ag2 37(2) . .
O2 N13 O1 Ag2 -148.5(15) . .
O1' N13 O1 Ag2 72.4(19) . .
O3' N13 O1 Ag2 53(3) . .
N12 Ag2 O1 N13 -126.7(12) 2_767 .
N9 Ag2 O1 N13 18.2(15) . .
N10 Ag2 O1 N13 97.0(13) . .
O1' Ag2 O1 N13 -65.8(18) . .
O2' N13 O1' Ag2 -83(2) . .
O3 N13 O1' Ag2 71.9(15) . .
O2 N13 O1' Ag2 -137.3(18) . .
O1 N13 O1' Ag2 -78(2) . .
O3' N13 O1' Ag2 91.0(15) . .
N12 Ag2 O1' N13 -168.2(11) 2_767 .
N9 Ag2 O1' N13 -31.2(13) . .
N10 Ag2 O1' N13 50.0(14) . .
O1 Ag2 O1' N13 71.5(19) . .
