#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:35:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180478 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/47/7214738.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7214738
loop_
_publ_author_name
'Li, Zhao-Hao'
'Xue, Li-Ping'
'Zhao, Bang-Tun'
'Kan, Jian'
'Su, Wei-Ping'
_publ_section_title
;
 2D lanthanide--organic frameworks constructed from lanthanide acetate
 skeletons and benzotriazole-5-carboxylic acid connectors: synthesis,
 structure, luminescence and magnetic properties
;
_journal_issue                   24
_journal_name_full               CrystEngComm
_journal_page_first              8485
_journal_paper_doi               10.1039/c2ce25927c
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C16 H13 Eu N6 O7'
_chemical_formula_weight         553.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.630(12)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.537(3)
_cell_length_b                   14.403(2)
_cell_length_c                   7.9836(11)
_cell_measurement_reflns_used    5150
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4719
_cell_measurement_theta_min      2.4797
_cell_volume                     1888.8(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_molecular_graphics    'Diamond Version 2.1c(K.Brandenburg, 1999)'
_computing_publication_material  'enCIFer (Allen et al., 2004); PLATON'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0633
_diffrn_reflns_av_sigmaI/netI    0.0628
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            12536
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.83
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.375
_exptl_absorpt_correction_T_max  0.6681
_exptl_absorpt_correction_T_min  0.5375
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.946
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1080
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.336
_refine_diff_density_min         -1.831
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.170
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3507
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.170
_refine_ls_R_factor_all          0.0502
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0359P)²+2.8395P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1073
_refine_ls_wR_factor_ref         0.1112
_reflns_number_gt                3258
_reflns_number_total             3507
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25927c.txt
_cod_data_source_block           aa
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7214738
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.448813(9) 0.615929(11) 0.052477(19) 0.02473(5) Uani 1 1 d .
O4 O 0.36539(14) 0.49055(17) 0.1056(3) 0.0416(7) Uani 1 1 d .
O5 O 0.42521(15) 0.35653(18) 0.0496(3) 0.0424(7) Uani 1 1 d .
O6 O 0.34446(13) 0.67821(16) 0.2042(3) 0.0352(6) Uani 1 1 d .
O7 O 0.37602(13) 0.81585(17) 0.3182(3) 0.0343(6) Uani 1 1 d .
O3 O 0.45710(14) 0.50941(17) -0.1746(3) 0.0364(7) Uani 1 1 d .
O2 O 0.47576(16) 0.39198(16) -0.3373(3) 0.0359(7) Uani 1 1 d .
O1 O 0.48590(15) 0.77664(16) 0.0931(3) 0.0405(7) Uani 1 1 d .
H1W H 0.5165 0.8023 0.0407 0.061 Uiso 1 1 d R
H2W H 0.4627 0.7902 0.1853 0.061 Uiso 1 1 d R
C4 C 0.3010(2) 0.3508(2) 0.1695(4) 0.0307(9) Uani 1 1 d .
C5 C 0.3014(2) 0.2554(2) 0.1725(4) 0.0345(9) Uani 1 1 d .
H5 H 0.3430 0.2216 0.1324 0.041 Uiso 1 1 calc R
C6 C 0.2365(2) 0.2112(3) 0.2384(4) 0.0354(10) Uani 1 1 d .
C7 C 0.1752(2) 0.2634(3) 0.2993(4) 0.0349(10) Uani 1 1 d .
C8 C 0.1733(2) 0.3607(3) 0.2954(5) 0.0422(10) Uani 1 1 d .
H8 H 0.1317 0.3946 0.3352 0.051 Uiso 1 1 calc R
C9 C 0.2368(2) 0.4022(3) 0.2293(4) 0.0346(9) Uani 1 1 d .
H9 H 0.2381 0.4666 0.2231 0.042 Uiso 1 1 calc R
C3 C 0.3681(2) 0.4035(2) 0.1029(5) 0.0331(9) Uani 1 1 d .
C11 C 0.2415(2) 0.7616(2) 0.3239(4) 0.0303(9) Uani 1 1 d .
C12 C 0.1936(2) 0.6824(3) 0.3438(5) 0.0424(10) Uani 1 1 d .
H12 H 0.2143 0.6240 0.3235 0.051 Uiso 1 1 calc R
C13 C 0.1175(2) 0.6896(3) 0.3922(5) 0.0459(11) Uani 1 1 d .
H13 H 0.0866 0.6370 0.4081 0.055 Uiso 1 1 calc R
C14 C 0.0877(2) 0.7782(3) 0.4171(5) 0.0406(10) Uani 1 1 d .
C15 C 0.1344(2) 0.8554(3) 0.3929(5) 0.0365(10) Uani 1 1 d .
C16 C 0.2130(2) 0.8495(3) 0.3492(4) 0.0338(9) Uani 1 1 d .
H16 H 0.2446 0.9020 0.3376 0.041 Uiso 1 1 calc R
C10 C 0.3266(2) 0.7497(2) 0.2795(4) 0.0294(8) Uani 1 1 d .
C2 C 0.4385(2) 0.4666(2) -0.3111(4) 0.0296(9) Uani 1 1 d .
C1 C 0.3729(2) 0.5011(3) -0.4385(5) 0.0450(11) Uani 1 1 d .
H1A H 0.3795 0.4747 -0.5465 0.067 Uiso 1 1 calc R
H1B H 0.3758 0.5675 -0.4451 0.067 Uiso 1 1 calc R
H1C H 0.3209 0.4833 -0.4063 0.067 Uiso 1 1 calc R
N1 N 0.2210(2) 0.1184(2) 0.2568(4) 0.0442(10) Uani 1 1 d .
N2 N 0.1532(2) 0.1116(2) 0.3287(5) 0.0478(10) Uani 1 1 d .
N3 N 0.12446(18) 0.1977(2) 0.3530(4) 0.0467(9) Uani 1 1 d .
H3 H 0.0803 0.2095 0.3962 0.056 Uiso 1 1 calc R
N4 N 0.0149(2) 0.8084(3) 0.4670(5) 0.0528(10) Uani 1 1 d .
N5 N 0.0158(2) 0.8984(2) 0.4720(5) 0.0570(11) Uani 1 1 d .
N6 N 0.08630(19) 0.9290(2) 0.4281(4) 0.0492(10) Uani 1 1 d .
H6 H 0.0998 0.9865 0.4225 0.059 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O4 102.17(8) 4_575 .
O7 Eu1 O5 92.69(8) 4_575 3_665
O4 Eu1 O5 139.07(9) . 3_665
O7 Eu1 O3 74.37(8) 4_575 .
O4 Eu1 O3 74.28(9) . .
O5 Eu1 O3 73.46(9) 3_665 .
O7 Eu1 O6 84.95(8) 4_575 .
O4 Eu1 O6 73.92(8) . .
O5 Eu1 O6 146.05(8) 3_665 .
O3 Eu1 O6 137.04(8) . .
O7 Eu1 O1 78.58(8) 4_575 .
O4 Eu1 O1 149.74(8) . .
O5 Eu1 O1 70.31(9) 3_665 .
O3 Eu1 O1 133.10(8) . .
O6 Eu1 O1 76.04(8) . .
O7 Eu1 O2 157.21(8) 4_575 3_665
O4 Eu1 O2 92.47(8) . 3_665
O5 Eu1 O2 87.34(9) 3_665 3_665
O3 Eu1 O2 127.03(8) . 3_665
O6 Eu1 O2 82.43(8) . 3_665
O1 Eu1 O2 79.99(8) . 3_665
O7 Eu1 O3 149.21(8) 4_575 3_665
O4 Eu1 O3 74.11(8) . 3_665
O5 Eu1 O3 73.85(8) 3_665 3_665
O3 Eu1 O3 75.26(8) . 3_665
O6 Eu1 O3 121.63(8) . 3_665
O1 Eu1 O3 120.21(8) . 3_665
O2 Eu1 O3 51.89(7) 3_665 3_665
O7 Eu1 C2 170.55(9) 4_575 3_665
O4 Eu1 C2 84.10(9) . 3_665
O5 Eu1 C2 78.02(9) 3_665 3_665
O3 Eu1 C2 100.95(9) . 3_665
O6 Eu1 C2 103.71(8) . 3_665
O1 Eu1 C2 99.62(9) . 3_665
O2 Eu1 C2 26.08(8) 3_665 3_665
O3 Eu1 C2 25.91(8) 3_665 3_665
O7 Eu1 Eu1 112.88(6) 4_575 3_665
O4 Eu1 Eu1 69.89(6) . 3_665
O5 Eu1 Eu1 69.20(6) 3_665 3_665
O3 Eu1 Eu1 38.67(5) . 3_665
O6 Eu1 Eu1 142.17(6) . 3_665
O1 Eu1 Eu1 138.27(6) . 3_665
O2 Eu1 Eu1 88.43(6) 3_665 3_665
O3 Eu1 Eu1 36.59(5) 3_665 3_665
C2 Eu1 Eu1 62.36(6) 3_665 3_665
O7 Eu1 H2W 86.3 4_575 .
O4 Eu1 H2W 131.7 . .
O5 Eu1 H2W 86.7 3_665 .
O3 Eu1 H2W 151.3 . .
O6 Eu1 H2W 59.4 . .
O1 Eu1 H2W 18.7 . .
O2 Eu1 H2W 70.9 3_665 .
O3 Eu1 H2W 119.5 3_665 .
C2 Eu1 H2W 94.8 3_665 .
Eu1 Eu1 H2W 149.1 3_665 .
C3 O4 Eu1 138.1(2) . .
C3 O5 Eu1 138.2(2) . 3_665
C10 O6 Eu1 141.2(2) . .
C10 O7 Eu1 140.6(2) . 4_576
C2 O3 Eu1 160.2(2) . .
C2 O3 Eu1 93.6(2) . 3_665
Eu1 O3 Eu1 104.74(8) . 3_665
C2 O2 Eu1 95.18(18) . 3_665
H2W O1 Eu1 101.2 . .
H2W O1 H1W 134.7 . .
Eu1 O1 H1W 123.4 . .
H2W O1 H2W 0.0 . .
Eu1 O1 H2W 101.2 . .
H1W O1 H2W 134.7 . .
C5 C4 C9 121.2(3) . .
C5 C4 C3 120.8(3) . .
C9 C4 C3 118.0(3) . .
C4 C5 C6 117.3(3) . .
C4 C5 H5 121.4 . .
C6 C5 H5 121.4 . .
N1 C6 C7 109.6(3) . .
N1 C6 C5 130.0(3) . .
C7 C6 C5 120.4(3) . .
N3 C7 C6 103.5(3) . .
N3 C7 C8 133.4(3) . .
C6 C7 C8 123.1(3) . .
C9 C8 C7 115.5(3) . .
C9 C8 H8 122.3 . .
C7 C8 H8 122.3 . .
C8 C9 C4 122.6(3) . .
C8 C9 H9 118.7 . .
C4 C9 H9 118.7 . .
O4 C3 O5 124.5(3) . .
O4 C3 C4 118.2(3) . .
O5 C3 C4 117.3(3) . .
C16 C11 C12 121.5(3) . .
C16 C11 C10 119.2(3) . .
C12 C11 C10 119.3(3) . .
C13 C12 C11 121.4(4) . .
C13 C12 H12 119.3 . .
C11 C12 H12 119.3 . .
C12 C13 C14 117.7(4) . .
C12 C13 H13 121.2 . .
C14 C13 H13 121.2 . .
N4 C14 C15 107.9(3) . .
N4 C14 C13 131.7(4) . .
C15 C14 C13 120.4(3) . .
N6 C15 C14 104.2(3) . .
N6 C15 C16 132.9(4) . .
C14 C15 C16 122.8(4) . .
C11 C16 C15 116.2(3) . .
C11 C16 H16 121.9 . .
C15 C16 H16 121.9 . .
O6 C10 O7 123.8(3) . .
O6 C10 C11 119.3(3) . .
O7 C10 C11 116.8(3) . .
O3 C2 O2 118.9(3) . .
O3 C2 C1 121.1(3) . .
O2 C2 C1 120.0(3) . .
O3 C2 Eu1 60.49(16) . 3_665
O2 C2 Eu1 58.74(16) . 3_665
C1 C2 Eu1 173.0(2) . 3_665
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
N2 N1 C6 107.3(3) . .
N1 N2 N3 109.0(3) . .
N2 N3 C7 110.6(3) . .
N2 N3 H3 124.7 . .
C7 N3 H3 124.7 . .
N5 N4 C14 108.4(3) . .
N4 N5 N6 109.2(3) . .
N5 N6 C15 110.2(3) . .
N5 N6 H6 124.9 . .
C15 N6 H6 124.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.322(2) 4_575
Eu1 O4 2.341(2) .
Eu1 O5 2.357(3) 3_665
Eu1 O3 2.391(2) .
Eu1 O6 2.394(2) .
Eu1 O1 2.407(2) .
Eu1 O2 2.467(2) 3_665
Eu1 O3 2.506(2) 3_665
Eu1 C2 2.874(3) 3_665
Eu1 Eu1 3.8791(5) 3_665
Eu1 H2W 2.7238 .
O4 C3 1.255(4) .
O5 C3 1.274(4) .
O5 Eu1 2.357(3) 3_665
O6 C10 1.245(4) .
O7 C10 1.270(4) .
O7 Eu1 2.322(2) 4_576
O3 C2 1.258(4) .
O3 Eu1 2.506(2) 3_665
O2 C2 1.269(4) .
O2 Eu1 2.467(2) 3_665
O1 H2W 0.8901 .
O1 H1W 0.7849 .
O1 H2W 0.8901 .
C4 C5 1.374(5) .
C4 C9 1.421(5) .
C4 C3 1.493(5) .
C5 C6 1.401(5) .
C5 H5 0.9300 .
C6 N1 1.372(5) .
C6 C7 1.394(5) .
C7 N3 1.366(5) .
C7 C8 1.401(5) .
C8 C9 1.366(5) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C11 C16 1.373(5) .
C11 C12 1.409(5) .
C11 C10 1.500(5) .
C12 C13 1.362(5) .
C12 H12 0.9300 .
C13 C14 1.391(5) .
C13 H13 0.9300 .
C14 N4 1.381(5) .
C14 C15 1.381(5) .
C15 N6 1.374(5) .
C15 C16 1.386(5) .
C16 H16 0.9300 .
C2 C1 1.484(5) .
C2 Eu1 2.874(3) 3_665
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
N1 N2 1.321(5) .
N2 N3 1.349(4) .
N3 H3 0.8600 .
N4 N5 1.298(5) .
N5 N6 1.331(5) .
N6 H6 0.8600 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N3 H3 N5 0.86 2.54 3.161(5) 130.3 3_566
N3 H3 N4 0.86 2.03 2.855(5) 159.5 3_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O7 Eu1 O4 C3 114.2(3) 4_575 .
O5 Eu1 O4 C3 5.4(4) 3_665 .
O3 Eu1 O4 C3 44.5(3) . .
O6 Eu1 O4 C3 -164.7(4) . .
O1 Eu1 O4 C3 -157.6(3) . .
O2 Eu1 O4 C3 -83.3(4) 3_665 .
O3 Eu1 O4 C3 -34.2(3) 3_665 .
C2 Eu1 O4 C3 -58.6(4) 3_665 .
Eu1 Eu1 O4 C3 4.1(3) 3_665 .
O7 Eu1 O6 C10 -87.9(3) 4_575 .
O4 Eu1 O6 C10 167.9(3) . .
O5 Eu1 O6 C10 -0.6(4) 3_665 .
O3 Eu1 O6 C10 -148.5(3) . .
O1 Eu1 O6 C10 -8.4(3) . .
O2 Eu1 O6 C10 73.1(3) 3_665 .
O3 Eu1 O6 C10 108.7(3) 3_665 .
C2 Eu1 O6 C10 88.3(3) 3_665 .
Eu1 Eu1 O6 C10 150.6(3) 3_665 .
O7 Eu1 O3 C2 -27.7(7) 4_575 .
O4 Eu1 O3 C2 80.1(7) . .
O5 Eu1 O3 C2 -125.4(7) 3_665 .
O6 Eu1 O3 C2 36.6(7) . .
O1 Eu1 O3 C2 -84.8(7) . .
O2 Eu1 O3 C2 161.1(6) 3_665 .
O3 Eu1 O3 C2 157.4(7) 3_665 .
C2 Eu1 O3 C2 160.7(6) 3_665 .
Eu1 Eu1 O3 C2 157.4(7) 3_665 .
O7 Eu1 O3 Eu1 174.88(11) 4_575 3_665
O4 Eu1 O3 Eu1 -77.29(10) . 3_665
O5 Eu1 O3 Eu1 77.18(10) 3_665 3_665
O6 Eu1 O3 Eu1 -120.87(10) . 3_665
O1 Eu1 O3 Eu1 117.80(11) . 3_665
O2 Eu1 O3 Eu1 3.72(14) 3_665 3_665
O3 Eu1 O3 Eu1 0.0 3_665 3_665
C2 Eu1 O3 Eu1 3.32(11) 3_665 3_665
O7 Eu1 O1 H2W 113.2 4_575 .
O4 Eu1 O1 H2W 18.5 . .
O5 Eu1 O1 H2W -149.8 3_665 .
O3 Eu1 O1 H2W 168.7 . .
O6 Eu1 O1 H2W 25.6 . .
O2 Eu1 O1 H2W -59.0 3_665 .
O3 Eu1 O1 H2W -93.1 3_665 .
C2 Eu1 O1 H2W -76.3 3_665 .
Eu1 Eu1 O1 H2W -135.1 3_665 .
C9 C4 C5 C6 -0.7(5) . .
C3 C4 C5 C6 179.5(3) . .
C4 C5 C6 N1 179.9(3) . .
C4 C5 C6 C7 -0.6(5) . .
N1 C6 C7 N3 0.0(4) . .
C5 C6 C7 N3 -179.5(3) . .
N1 C6 C7 C8 -179.0(3) . .
C5 C6 C7 C8 1.5(5) . .
N3 C7 C8 C9 -179.6(4) . .
C6 C7 C8 C9 -0.9(5) . .
C7 C8 C9 C4 -0.5(5) . .
C5 C4 C9 C8 1.3(5) . .
C3 C4 C9 C8 -178.8(3) . .
Eu1 O4 C3 O5 -6.1(6) . .
Eu1 O4 C3 C4 172.5(2) . .
Eu1 O5 C3 O4 3.8(6) 3_665 .
Eu1 O5 C3 C4 -174.9(2) 3_665 .
C5 C4 C3 O4 -178.9(3) . .
C9 C4 C3 O4 1.3(5) . .
C5 C4 C3 O5 -0.1(5) . .
C9 C4 C3 O5 -180.0(3) . .
C16 C11 C12 C13 -1.3(5) . .
C10 C11 C12 C13 176.7(3) . .
C11 C12 C13 C14 1.7(6) . .
C12 C13 C14 N4 -179.2(4) . .
C12 C13 C14 C15 0.0(6) . .
N4 C14 C15 N6 -0.7(4) . .
C13 C14 C15 N6 179.9(3) . .
N4 C14 C15 C16 177.1(3) . .
C13 C14 C15 C16 -2.3(6) . .
C12 C11 C16 C15 -0.8(5) . .
C10 C11 C16 C15 -178.9(3) . .
N6 C15 C16 C11 179.7(4) . .
C14 C15 C16 C11 2.6(5) . .
Eu1 O6 C10 O7 -11.7(5) . .
Eu1 O6 C10 C11 166.4(2) . .
Eu1 O7 C10 O6 -109.8(4) 4_576 .
Eu1 O7 C10 C11 72.0(4) 4_576 .
C16 C11 C10 O6 -156.7(3) . .
C12 C11 C10 O6 25.3(4) . .
C16 C11 C10 O7 21.5(4) . .
C12 C11 C10 O7 -156.5(3) . .
Eu1 O3 C2 O2 -164.6(5) . .
Eu1 O3 C2 O2 -6.5(3) 3_665 .
Eu1 O3 C2 C1 13.9(9) . .
Eu1 O3 C2 C1 172.1(3) 3_665 .
Eu1 O3 C2 Eu1 -158.2(7) . 3_665
Eu1 O2 C2 O3 6.6(3) 3_665 .
Eu1 O2 C2 C1 -172.0(3) 3_665 .
C7 C6 N1 N2 -0.8(4) . .
C5 C6 N1 N2 178.6(4) . .
C6 N1 N2 N3 1.3(4) . .
N1 N2 N3 C7 -1.3(4) . .
C6 C7 N3 N2 0.8(4) . .
C8 C7 N3 N2 179.7(4) . .
C15 C14 N4 N5 0.6(5) . .
C13 C14 N4 N5 179.9(4) . .
C14 N4 N5 N6 -0.2(5) . .
N4 N5 N6 C15 -0.2(5) . .
C14 C15 N6 N5 0.6(4) . .
C16 C15 N6 N5 -176.9(4) . .
