#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/49/7214956.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7214956
loop_
_publ_author_name
'Gao, Jia-Zhen'
'Yang, Jin'
'Liu, Ying-Ying'
'Ma, Jian-Fang'
_publ_section_title
;
 Ten new coordination polymers based on
 3-carboxy-1-(4′-carboxybenzyl)-2-oxidopyridinium and different
 N-donor ligands: syntheses, structures, and photoluminescent properties
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              8173
_journal_paper_doi               10.1039/c2ce25953b
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C26 H19 N3 O6 Zn'
_chemical_formula_sum            'C26 H19 N3 O6 Zn'
_chemical_formula_weight         534.81
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.807(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.6011(3)
_cell_length_b                   16.3324(5)
_cell_length_c                   12.0354(4)
_cell_measurement_reflns_used    3938
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1175
_cell_measurement_theta_min      3.0105
_cell_volume                     2275.36(12)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_sigmaI/netI    0.0460
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            13667
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         3.02
_exptl_absorpt_coefficient_mu    1.129
_exptl_absorpt_correction_T_max  0.8858
_exptl_absorpt_correction_T_min  0.7812
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.561
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1096
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.390
_refine_diff_density_min         -0.362
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         4009
_refine_ls_number_restraints     13
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0575
_refine_ls_R_factor_gt           0.0390
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0370P)²+1.0589P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0834
_refine_ls_wR_factor_ref         0.0931
_reflns_number_gt                3104
_reflns_number_total             4009
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25953b.txt
_cod_data_source_block           Compound-5
_cod_original_sg_symbol_Hall     '-p 2yn'
_cod_original_sg_symbol_H-M      p21/n
_cod_database_code               7214956
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.78258(3) 0.10293(2) 0.15515(3) 0.03204(13) Uani 1 1 d .
C14 C 0.0927(3) 0.33284(19) 0.4998(3) 0.0373(7) Uani 1 1 d .
C12 C 0.1137(2) 0.24871(17) 0.5492(2) 0.0310(7) Uani 1 1 d .
C11 C 0.0298(3) 0.1901(2) 0.5325(3) 0.0421(8) Uani 1 1 d .
H11 H -0.0402 0.2041 0.4952 0.051 Uiso 1 1 calc R
C10 C 0.0468(3) 0.10992(19) 0.5698(3) 0.0464(8) Uani 1 1 d .
H10 H -0.0123 0.0716 0.5609 0.056 Uiso 1 1 calc R
C9 C 0.1503(3) 0.08900(19) 0.6189(3) 0.0408(8) Uani 1 1 d .
H9 H 0.1637 0.0350 0.6407 0.049 Uiso 1 1 calc R
C13 C 0.2209(2) 0.22711(17) 0.6074(2) 0.0295(6) Uani 1 1 d .
C8 C 0.3495(2) 0.12078(18) 0.6865(2) 0.0346(7) Uani 1 1 d .
H8B H 0.3435 0.0664 0.7180 0.042 Uiso 1 1 calc R
H8A H 0.3725 0.1580 0.7467 0.042 Uiso 1 1 calc R
C5 C 0.4415(2) 0.12020(17) 0.6039(2) 0.0313(7) Uani 1 1 d .
C6 C 0.4164(2) 0.10440(19) 0.4919(3) 0.0380(7) Uani 1 1 d .
H6 H 0.3400 0.0967 0.4657 0.046 Uiso 1 1 calc R
C7 C 0.5023(2) 0.09978(19) 0.4183(3) 0.0389(8) Uani 1 1 d .
H7 H 0.4833 0.0887 0.3435 0.047 Uiso 1 1 calc R
C2 C 0.6170(2) 0.11157(17) 0.4552(3) 0.0326(7) Uani 1 1 d .
C3 C 0.6425(2) 0.12663(19) 0.5670(3) 0.0379(8) Uani 1 1 d .
H3 H 0.7190 0.1337 0.5931 0.046 Uiso 1 1 calc R
C4 C 0.5565(2) 0.13140(19) 0.6406(3) 0.0367(7) Uani 1 1 d .
H4 H 0.5757 0.1422 0.7154 0.044 Uiso 1 1 calc R
C1 C 0.7106(3) 0.10912(18) 0.3759(3) 0.0391(7) Uani 1 1 d U
C15 C 0.7536(3) -0.0752(2) 0.0583(3) 0.0421(8) Uani 1 1 d .
H15 H 0.6759 -0.0626 0.0437 0.051 Uiso 1 1 calc R
C16 C 0.7919(3) -0.1530(2) 0.0320(3) 0.0538(9) Uani 1 1 d .
H16 H 0.7398 -0.1917 0.0023 0.065 Uiso 1 1 calc R
C17 C 0.9053(3) -0.1722(2) 0.0496(3) 0.0556(10) Uani 1 1 d .
H17 H 0.9316 -0.2239 0.0309 0.067 Uiso 1 1 calc R
C18 C 0.9824(3) -0.11383(19) 0.0962(3) 0.0402(8) Uani 1 1 d .
C19 C 1.1042(3) -0.1275(2) 0.1176(3) 0.0526(9) Uani 1 1 d .
H19 H 1.1354 -0.1779 0.0995 0.063 Uiso 1 1 calc R
C20 C 1.1739(3) -0.0693(2) 0.1633(3) 0.0508(9) Uani 1 1 d .
H20 H 1.2524 -0.0800 0.1760 0.061 Uiso 1 1 calc R
C21 C 1.1298(2) 0.0086(2) 0.1926(3) 0.0397(8) Uani 1 1 d .
C22 C 1.1980(3) 0.0716(2) 0.2411(3) 0.0524(9) Uani 1 1 d .
H22 H 1.2770 0.0641 0.2554 0.063 Uiso 1 1 calc R
C23 C 1.1477(3) 0.1435(2) 0.2671(3) 0.0542(10) Uani 1 1 d .
H23 H 1.1923 0.1855 0.2998 0.065 Uiso 1 1 calc R
C24 C 1.0290(3) 0.1546(2) 0.2445(3) 0.0449(8) Uani 1 1 d .
H24 H 0.9958 0.2040 0.2634 0.054 Uiso 1 1 calc R
C25 C 1.0113(2) 0.02450(18) 0.1723(2) 0.0330(7) Uani 1 1 d .
C26 C 0.9371(2) -0.03768(18) 0.1227(2) 0.0319(7) Uani 1 1 d .
N1 N 0.23551(19) 0.14564(14) 0.63710(19) 0.0309(6) Uani 1 1 d .
N2 N 0.9623(2) 0.09703(15) 0.1970(2) 0.0348(6) Uani 1 1 d .
N3 N 0.82327(19) -0.01837(14) 0.10339(19) 0.0325(6) Uani 1 1 d .
O5 O 0.0158(2) 0.33982(15) 0.4242(2) 0.0634(7) Uani 1 1 d .
O4 O 0.15378(18) 0.39245(12) 0.53581(19) 0.0445(6) Uani 1 1 d .
O1W O 0.04666(19) 0.51505(16) 0.3519(2) 0.0630(7) Uani 1 1 d .
H1A H 0.0395 0.4668 0.3853 0.094 Uiso 1 1 d R
H1B H -0.0134 0.5457 0.3691 0.094 Uiso 1 1 d R
O3 O 0.30452(15) 0.27418(12) 0.63190(17) 0.0383(5) Uani 1 1 d .
O1 O 0.68139(18) 0.08923(14) 0.27661(18) 0.0478(6) Uani 1 1 d .
O2 O 0.8132(4) 0.1057(3) 0.4151(4) 0.0402(12) Uani 0.50 1 d PU
O2' O 0.8054(4) 0.1427(3) 0.4021(4) 0.0480(12) Uani 0.50 1 d PU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O4 94.84(9) . 4_665
O1 Zn1 O3 107.59(9) . 4_665
O4 Zn1 O3 87.63(8) 4_665 4_665
O1 Zn1 N2 116.74(9) . .
O4 Zn1 N2 148.10(10) 4_665 .
O3 Zn1 N2 87.00(8) 4_665 .
O1 Zn1 N3 105.53(9) . .
O4 Zn1 N3 89.69(8) 4_665 .
O3 Zn1 N3 146.87(9) 4_665 .
N2 Zn1 N3 78.11(9) . .
O5 C14 O4 122.8(3) . .
O5 C14 C12 117.6(3) . .
O4 C14 C12 119.6(2) . .
C11 C12 C13 119.0(3) . .
C11 C12 C14 118.9(2) . .
C13 C12 C14 122.0(2) . .
C12 C11 C10 121.7(3) . .
C12 C11 H11 119.1 . .
C10 C11 H11 119.1 . .
C9 C10 C11 118.8(3) . .
C9 C10 H10 120.6 . .
C11 C10 H10 120.6 . .
C10 C9 N1 121.0(3) . .
C10 C9 H9 119.5 . .
N1 C9 H9 119.5 . .
O3 C13 N1 116.6(2) . .
O3 C13 C12 126.6(3) . .
N1 C13 C12 116.8(2) . .
N1 C8 C5 113.1(2) . .
N1 C8 H8B 109.0 . .
C5 C8 H8B 109.0 . .
N1 C8 H8A 109.0 . .
C5 C8 H8A 109.0 . .
H8B C8 H8A 107.8 . .
C6 C5 C4 118.0(3) . .
C6 C5 C8 122.1(3) . .
C4 C5 C8 119.8(3) . .
C7 C6 C5 121.4(3) . .
C7 C6 H6 119.3 . .
C5 C6 H6 119.3 . .
C6 C7 C2 120.4(3) . .
C6 C7 H7 119.8 . .
C2 C7 H7 119.8 . .
C3 C2 C7 118.4(3) . .
C3 C2 C1 120.7(3) . .
C7 C2 C1 121.0(3) . .
C4 C3 C2 121.3(3) . .
C4 C3 H3 119.4 . .
C2 C3 H3 119.4 . .
C3 C4 C5 120.5(3) . .
C3 C4 H4 119.7 . .
C5 C4 H4 119.7 . .
O2' C1 O2 29.1(3) . .
O2' C1 O1 121.9(4) . .
O2 C1 O1 122.3(4) . .
O2' C1 C2 119.5(4) . .
O2 C1 C2 118.3(3) . .
O1 C1 C2 116.8(3) . .
N3 C15 C16 122.6(3) . .
N3 C15 H15 118.7 . .
C16 C15 H15 118.7 . .
C17 C16 C15 119.9(3) . .
C17 C16 H16 120.0 . .
C15 C16 H16 120.0 . .
C16 C17 C18 119.5(3) . .
C16 C17 H17 120.3 . .
C18 C17 H17 120.3 . .
C26 C18 C17 117.4(3) . .
C26 C18 C19 118.6(3) . .
C17 C18 C19 124.1(3) . .
C20 C19 C18 121.4(3) . .
C20 C19 H19 119.3 . .
C18 C19 H19 119.3 . .
C19 C20 C21 121.2(3) . .
C19 C20 H20 119.4 . .
C21 C20 H20 119.4 . .
C22 C21 C25 117.1(3) . .
C22 C21 C20 123.8(3) . .
C25 C21 C20 119.1(3) . .
C23 C22 C21 119.5(3) . .
C23 C22 H22 120.3 . .
C21 C22 H22 120.3 . .
C22 C23 C24 119.9(3) . .
C22 C23 H23 120.0 . .
C24 C23 H23 120.0 . .
N2 C24 C23 122.2(3) . .
N2 C24 H24 118.9 . .
C23 C24 H24 118.9 . .
N2 C25 C21 122.9(3) . .
N2 C25 C26 117.4(2) . .
C21 C25 C26 119.6(3) . .
N3 C26 C18 122.8(3) . .
N3 C26 C25 117.1(3) . .
C18 C26 C25 120.1(3) . .
C9 N1 C13 122.4(2) . .
C9 N1 C8 120.1(2) . .
C13 N1 C8 117.5(2) . .
C24 N2 C25 118.3(3) . .
C24 N2 Zn1 127.6(2) . .
C25 N2 Zn1 114.13(18) . .
C15 N3 C26 117.8(3) . .
C15 N3 Zn1 128.9(2) . .
C26 N3 Zn1 113.25(18) . .
C14 O4 Zn1 130.50(19) . 4_566
H1A O1W H1B 107.1 . .
C13 O3 Zn1 122.08(17) . 4_566
C1 O1 Zn1 122.9(2) . .
O2' O2 C1 75.3(7) . .
O2 O2' C1 75.6(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.948(2) .
Zn1 O4 2.004(2) 4_665
Zn1 O3 2.045(2) 4_665
Zn1 N2 2.115(2) .
Zn1 N3 2.139(2) .
C14 O5 1.236(3) .
C14 O4 1.264(3) .
C14 C12 1.511(4) .
C12 C11 1.371(4) .
C12 C13 1.430(4) .
C11 C10 1.393(4) .
C11 H11 0.9300 .
C10 C9 1.347(4) .
C10 H10 0.9300 .
C9 N1 1.361(4) .
C9 H9 0.9300 .
C13 O3 1.258(3) .
C13 N1 1.385(4) .
C8 N1 1.470(3) .
C8 C5 1.507(4) .
C8 H8B 0.9700 .
C8 H8A 0.9700 .
C5 C6 1.385(4) .
C5 C4 1.389(4) .
C6 C7 1.378(4) .
C6 H6 0.9300 .
C7 C2 1.388(4) .
C7 H7 0.9300 .
C2 C3 1.380(4) .
C2 C1 1.493(4) .
C3 C4 1.380(4) .
C3 H3 0.9300 .
C4 H4 0.9300 .
C1 O2' 1.250(6) .
C1 O2 1.252(5) .
C1 O1 1.263(4) .
C15 N3 1.324(4) .
C15 C16 1.388(5) .
C15 H15 0.9300 .
C16 C17 1.356(5) .
C16 H16 0.9300 .
C17 C18 1.399(5) .
C17 H17 0.9300 .
C18 C26 1.395(4) .
C18 C19 1.437(4) .
C19 C20 1.343(5) .
C19 H19 0.9300 .
C20 C21 1.424(5) .
C20 H20 0.9300 .
C21 C22 1.401(5) .
C21 C25 1.404(4) .
C22 C23 1.358(5) .
C22 H22 0.9300 .
C23 C24 1.397(4) .
C23 H23 0.9300 .
C24 N2 1.323(4) .
C24 H24 0.9300 .
C25 N2 1.356(4) .
C25 C26 1.435(4) .
C26 N3 1.363(3) .
O4 Zn1 2.004(2) 4_566
O1W H1A 0.8909 .
O1W H1B 0.8933 .
O3 Zn1 2.045(2) 4_566
O2 O2' 0.629(6) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1A O5 0.89 2.15 3.020(3) 165.8 .
O1W H1B O4 0.89 2.29 3.152(3) 162.9 3_566
C11 H11 O2 0.93 2.49 3.121(5) 125.5 1_455
C8 H8A O5 0.97 2.62 3.404(4) 138.3 4_666
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 C14 C12 C11 -17.9(4) . .
O4 C14 C12 C11 162.6(3) . .
O5 C14 C12 C13 158.4(3) . .
O4 C14 C12 C13 -21.0(4) . .
C13 C12 C11 C10 -0.6(5) . .
C14 C12 C11 C10 175.9(3) . .
C12 C11 C10 C9 -3.1(5) . .
C11 C10 C9 N1 3.2(5) . .
C11 C12 C13 O3 -177.9(3) . .
C14 C12 C13 O3 5.7(5) . .
C11 C12 C13 N1 4.1(4) . .
C14 C12 C13 N1 -172.3(3) . .
N1 C8 C5 C6 -29.8(4) . .
N1 C8 C5 C4 153.8(3) . .
C4 C5 C6 C7 0.0(4) . .
C8 C5 C6 C7 -176.5(3) . .
C5 C6 C7 C2 -0.5(5) . .
C6 C7 C2 C3 1.0(4) . .
C6 C7 C2 C1 -178.2(3) . .
C7 C2 C3 C4 -1.1(4) . .
C1 C2 C3 C4 178.1(3) . .
C2 C3 C4 C5 0.7(5) . .
C6 C5 C4 C3 -0.1(4) . .
C8 C5 C4 C3 176.5(3) . .
C3 C2 C1 O2' -20.3(5) . .
C7 C2 C1 O2' 159.0(4) . .
C3 C2 C1 O2 13.1(5) . .
C7 C2 C1 O2 -167.7(4) . .
C3 C2 C1 O1 175.1(3) . .
C7 C2 C1 O1 -5.7(4) . .
N3 C15 C16 C17 -1.8(5) . .
C15 C16 C17 C18 1.1(6) . .
C16 C17 C18 C26 0.2(5) . .
C16 C17 C18 C19 -179.5(3) . .
C26 C18 C19 C20 0.8(5) . .
C17 C18 C19 C20 -179.5(4) . .
C18 C19 C20 C21 0.1(5) . .
C19 C20 C21 C22 179.5(3) . .
C19 C20 C21 C25 -0.5(5) . .
C25 C21 C22 C23 0.6(5) . .
C20 C21 C22 C23 -179.4(3) . .
C21 C22 C23 C24 -0.5(6) . .
C22 C23 C24 N2 -0.6(6) . .
C22 C21 C25 N2 0.3(5) . .
C20 C21 C25 N2 -179.7(3) . .
C22 C21 C25 C26 -180.0(3) . .
C20 C21 C25 C26 0.0(4) . .
C17 C18 C26 N3 -1.1(5) . .
C19 C18 C26 N3 178.6(3) . .
C17 C18 C26 C25 179.1(3) . .
C19 C18 C26 C25 -1.2(4) . .
N2 C25 C26 N3 0.7(4) . .
C21 C25 C26 N3 -179.0(3) . .
N2 C25 C26 C18 -179.4(3) . .
C21 C25 C26 C18 0.8(4) . .
C10 C9 N1 C13 0.5(5) . .
C10 C9 N1 C8 -177.4(3) . .
O3 C13 N1 C9 177.7(3) . .
C12 C13 N1 C9 -4.1(4) . .
O3 C13 N1 C8 -4.4(4) . .
C12 C13 N1 C8 173.8(2) . .
C5 C8 N1 C9 106.9(3) . .
C5 C8 N1 C13 -71.0(3) . .
C23 C24 N2 C25 1.6(5) . .
C23 C24 N2 Zn1 -179.3(3) . .
C21 C25 N2 C24 -1.4(4) . .
C26 C25 N2 C24 178.9(3) . .
C21 C25 N2 Zn1 179.4(2) . .
C26 C25 N2 Zn1 -0.3(3) . .
O1 Zn1 N2 C24 -77.6(3) . .
O4 Zn1 N2 C24 111.3(3) 4_665 .
O3 Zn1 N2 C24 30.6(3) 4_665 .
N3 Zn1 N2 C24 -179.1(3) . .
O1 Zn1 N2 C25 101.5(2) . .
O4 Zn1 N2 C25 -69.6(3) 4_665 .
O3 Zn1 N2 C25 -150.2(2) 4_665 .
N3 Zn1 N2 C25 0.0(2) . .
C16 C15 N3 C26 0.9(5) . .
C16 C15 N3 Zn1 -177.8(2) . .
C18 C26 N3 C15 0.5(4) . .
C25 C26 N3 C15 -179.6(3) . .
C18 C26 N3 Zn1 179.5(2) . .
C25 C26 N3 Zn1 -0.7(3) . .
O1 Zn1 N3 C15 64.4(3) . .
O4 Zn1 N3 C15 -30.5(3) 4_665 .
O3 Zn1 N3 C15 -115.7(3) 4_665 .
N2 Zn1 N3 C15 179.2(3) . .
O1 Zn1 N3 C26 -114.38(19) . .
O4 Zn1 N3 C26 150.7(2) 4_665 .
O3 Zn1 N3 C26 65.5(2) 4_665 .
N2 Zn1 N3 C26 0.37(19) . .
O5 C14 O4 Zn1 -179.6(2) . 4_566
C12 C14 O4 Zn1 -0.2(4) . 4_566
N1 C13 O3 Zn1 -154.54(19) . 4_566
C12 C13 O3 Zn1 27.4(4) . 4_566
O2' C1 O1 Zn1 3.4(5) . .
O2 C1 O1 Zn1 -31.1(5) . .
C2 C1 O1 Zn1 167.63(19) . .
O4 Zn1 O1 C1 -155.8(2) 4_665 .
O3 Zn1 O1 C1 -66.8(3) 4_665 .
N2 Zn1 O1 C1 28.8(3) . .
N3 Zn1 O1 C1 113.1(2) . .
O1 C1 O2 O2' 98.6(8) . .
C2 C1 O2 O2' -100.5(8) . .
O1 C1 O2' O2 -100.1(8) . .
C2 C1 O2' O2 96.0(8) . .
