#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:46:17 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180482 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/51/7215188.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7215188
loop_
_publ_author_name
'Cui, Keyu'
'Li, Fengyan'
'Xu, Lin'
'Wang, Yuchao'
'Sun, Zhixia'
'Fu, Honggang'
_publ_section_title
;
 A 3D all-inorganic architecture based on the [H2W12O42]10−
 building block with different alkaline-earth metal linkers: crystal
 structures, surface photovoltage and photoluminescent properties
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              4721
_journal_paper_doi               10.1039/c3ce40222c
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'H62 Na2 O72 Sr4 W12'
_chemical_formula_weight         3817.16
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.5870(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.4169(12)
_cell_length_b                   23.762(3)
_cell_length_c                   12.4588(14)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.14
_cell_measurement_theta_min      3.09
_cell_volume                     3164.1(6)
_computing_cell_refinement       'SMART (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        'SAINT (Bruker, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0997
_diffrn_reflns_av_sigmaI/netI    0.0873
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            15631
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    25.196
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.579
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2002)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    4.007
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3400
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         3.413
_refine_diff_density_min         -2.773
_refine_diff_density_rms         0.458
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         5556
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0663
_refine_ls_R_factor_gt           0.0582
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0930P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1507
_refine_ls_wR_factor_ref         0.1574
_reflns_number_gt                4692
_reflns_number_total             5556
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40222c_3.cif
_cod_data_source_block           33
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7215188
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
O1 O 0.9056(9) 0.0504(5) 0.3163(9) 0.031(2) Uani 1 1 d
O2 O 0.5085(12) 0.1116(6) 0.3429(11) 0.045(3) Uani 1 1 d
O1W O 0.7392(11) 0.0058(5) 0.8625(10) 0.047(3) Uani 1 1 d
O3 O 0.8710(9) 0.0356(5) 0.6117(9) 0.033(2) Uani 1 1 d
O2W O 0.5679(11) 0.0905(6) 0.6915(11) 0.050(3) Uani 1 1 d
O4 O 0.8811(9) 0.1226(5) 0.4761(10) 0.036(3) Uani 1 1 d
O3W O 0.5478(13) 0.2004(7) 0.8216(15) 0.068(4) Uani 1 1 d
O5 O 0.8857(11) 0.1991(5) 0.6550(10) 0.041(3) Uani 1 1 d
O4W O 0.4984(13) 0.0891(6) 0.9247(15) 0.063(4) Uani 1 1 d
O6 O 0.9156(9) -0.0456(6) 0.4563(10) 0.040(3) Uani 1 1 d
O5W O 0.9433(11) 0.1098(6) 1.0336(11) 0.047(3) Uani 1 1 d
O7 O 0.9693(11) 0.1629(5) 0.3031(11) 0.043(3) Uani 1 1 d
O6W O 0.7414(12) 0.1813(5) 1.0859(13) 0.051(3) Uani 1 1 d
O8 O 0.7056(10) 0.1134(4) 0.2563(10) 0.035(3) Uani 1 1 d
O7W O 1.1877(15) 0.1385(9) 1.2046(15) 0.080(5) Uani 1 1 d
O9 O 0.7459(11) 0.0493(5) 0.0876(11) 0.043(3) Uani 1 1 d
O8W O 1.1670(15) 0.2527(7) 1.3070(15) 0.072(4) Uani 1 1 d
O10 O 0.7047(10) 0.1187(5) 0.5518(10) 0.036(3) Uani 1 1 d
O9W O 1.1336(16) 0.2363(7) 1.0239(15) 0.071(4) Uani 1 1 d
O11 O 0.6864(10) -0.0778(5) 0.3994(10) 0.035(2) Uani 1 1 d
O10W O 0.8379(13) 0.2165(6) 0.9048(12) 0.055(3) Uani 1 1 d
O12 O 0.6711(11) 0.1994(5) 0.3853(11) 0.040(3) Uani 1 1 d
O11W O 0.3593(18) 0.1756(7) 0.4463(17) 0.081(5) Uani 1 1 d
O13 O 0.7622(10) -0.0420(5) 0.2309(10) 0.037(3) Uani 1 1 d
O12W O 1.1350(17) 0.0900(10) 0.9521(15) 0.089(6) Uani 1 1 d
O14 O 1.0563(9) 0.1130(4) 0.7072(9) 0.029(2) Uani 1 1 d
O13W O 1.373(2) 0.1422(17) 1.085(2) 0.167(15) Uani 1 1 d
O15 O 0.5524(11) 0.0253(5) 0.1588(10) 0.038(3) Uani 1 1 d
O14W O 0.552(3) 0.2547(12) 1.0999(19) 0.160(14) Uani 1 1 d
O16 O 0.8785(10) -0.1505(4) 0.4612(9) 0.030(2) Uani 1 1 d
O17 O 0.6370(11) -0.0136(4) 0.5676(11) 0.039(3) Uani 1 1 d
O18 O 0.8482(9) -0.0784(5) 0.6122(10) 0.034(2) Uani 1 1 d
O19 O 0.8478(11) 0.1117(5) 0.7755(10) 0.039(3) Uani 1 1 d
O20 O 0.7009(10) -0.1578(5) 0.2407(10) 0.038(3) Uani 1 1 d
O21 O 0.7091(10) 0.0327(5) 0.3886(9) 0.034(2) Uani 1 1 d
OW15 O 1.0254(13) 0.0089(7) 1.1492(12) 0.057(4) Uani 1 1 d
Sr1 Sr 0.70916(15) 0.11592(7) 0.90301(14) 0.0376(4) Uani 1 1 d
Sr2 Sr 0.98660(18) 0.20845(8) 1.12981(16) 0.0478(4) Uani 1 1 d
W1 W 0.99715(6) 0.10760(3) 0.40155(6) 0.03078(19) Uani 1 1 d
W2 W 0.76351(6) -0.01467(3) 0.52171(5) 0.03024(19) Uani 1 1 d
W3 W 0.87957(6) 0.12634(3) 0.65269(6) 0.0320(2) Uani 1 1 d
W4 W 0.66911(6) 0.12718(3) 0.39031(6) 0.0330(2) Uani 1 1 d
W5 W 0.79471(6) -0.10780(3) 0.33209(6) 0.03200(19) Uani 1 1 d
W6 W 0.71401(6) 0.03410(3) 0.21031(6) 0.03230(19) Uani 1 1 d
Na1 Na 0.4536(7) 0.0129(3) 0.2972(7) 0.0505(18) Uani 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
W1 O1 W6 138.2(6) . .
W4 O2 Na1 115.7(7) . .
Na1 O1W Sr1 101.0(5) 3_656 .
W2 O3 W3 139.3(6) . .
Na1 O2W Sr1 102.1(5) 3_656 .
W1 O4 W3 138.2(6) . .
W1 O4 W4 126.0(6) . .
W3 O4 W4 94.9(4) . .
W3 O5 Sr2 151.2(6) . 4_565
W5 O6 W1 96.1(5) . 3_756
W5 O6 W2 95.6(4) . .
W1 O6 W2 96.4(5) 3_756 .
Sr1 O5W Sr2 103.0(4) . .
W1 O7 Sr2 152.5(7) . 1_554
Sr1 O6W Sr2 97.6(4) . .
W4 O8 W6 117.9(5) . .
W6 O9 Sr1 149.0(6) . 1_554
W4 O10 W3 117.1(6) . .
W5 O11 W2 115.2(5) . .
Sr2 O10W Sr1 94.8(4) . .
W6 O13 W5 146.6(7) . .
W3 O14 W5 146.3(6) . 3_756
W6 O15 Na1 117.2(6) . .
W5 O16 W1 116.2(5) . 3_756
W2 O17 Na1 153.9(7) . 3_656
W2 O18 W1 120.5(6) . 3_756
W3 O19 Sr1 153.2(6) . .
W2 O21 W6 138.7(5) . .
W2 O21 W4 124.9(5) . .
W6 O21 W4 94.0(4) . .
W2 O21 Na1 103.2(5) . .
W6 O21 Na1 89.1(4) . .
W4 O21 Na1 89.2(4) . .
O4W Sr1 O5W 135.1(5) . .
O4W Sr1 O19 146.9(5) . .
O5W Sr1 O19 70.6(4) . .
O4W Sr1 O2W 77.5(5) . .
O5W Sr1 O2W 138.4(4) . .
O19 Sr1 O2W 70.8(4) . .
O4W Sr1 O3W 71.5(4) . .
O5W Sr1 O3W 134.4(4) . .
O19 Sr1 O3W 106.4(5) . .
O2W Sr1 O3W 72.2(5) . .
O4W Sr1 O6W 84.8(5) . .
O5W Sr1 O6W 72.3(4) . .
O19 Sr1 O6W 127.6(4) . .
O2W Sr1 O6W 147.1(4) . .
O3W Sr1 O6W 76.0(5) . .
O4W Sr1 O9 68.8(4) . 1_556
O5W Sr1 O9 67.4(4) . 1_556
O19 Sr1 O9 123.4(4) . 1_556
O2W Sr1 O9 125.1(4) . 1_556
O3W Sr1 O9 130.1(5) . 1_556
O6W Sr1 O9 71.4(4) . 1_556
O4W Sr1 O1W 88.0(4) . .
O5W Sr1 O1W 83.9(4) . .
O19 Sr1 O1W 72.9(4) . .
O2W Sr1 O1W 70.4(4) . .
O3W Sr1 O1W 140.4(4) . .
O6W Sr1 O1W 137.0(4) . .
O9 Sr1 O1W 66.4(4) 1_556 .
O4W Sr1 O10W 135.4(4) . .
O5W Sr1 O10W 67.8(4) . .
O19 Sr1 O10W 67.0(4) . .
O2W Sr1 O10W 109.8(4) . .
O3W Sr1 O10W 69.6(4) . .
O6W Sr1 O10W 65.4(4) . .
O9 Sr1 O10W 124.7(4) 1_556 .
O1W Sr1 O10W 136.5(4) . .
O4W Sr1 Na1 68.3(4) . 3_656
O5W Sr1 Na1 120.1(3) . 3_656
O19 Sr1 Na1 80.7(3) . 3_656
O2W Sr1 Na1 37.6(3) . 3_656
O3W Sr1 Na1 103.4(3) . 3_656
O6W Sr1 Na1 151.2(3) . 3_656
O9 Sr1 Na1 88.9(3) 1_556 3_656
O1W Sr1 Na1 36.9(3) . 3_656
O10W Sr1 Na1 142.2(3) . 3_656
O4W Sr1 Sr2 125.8(4) . .
O5W Sr1 Sr2 38.5(3) . .
O19 Sr1 Sr2 87.3(3) . .
O2W Sr1 Sr2 150.8(3) . .
O3W Sr1 Sr2 97.0(3) . .
O6W Sr1 Sr2 41.8(3) . .
O9 Sr1 Sr2 82.9(3) 1_556 .
O1W Sr1 Sr2 122.2(3) . .
O10W Sr1 Sr2 41.9(3) . .
Na1 Sr1 Sr2 158.48(13) 3_656 .
O7 Sr2 O5 95.2(4) 1_556 4_566
O7 Sr2 O9W 145.8(5) 1_556 .
O5 Sr2 O9W 104.3(5) 4_566 .
O7 Sr2 O5W 87.0(4) 1_556 .
O5 Sr2 O5W 144.3(4) 4_566 .
O9W Sr2 O5W 92.8(5) . .
O7 Sr2 O8W 74.1(5) 1_556 .
O5 Sr2 O8W 79.0(5) 4_566 .
O9W Sr2 O8W 82.4(5) . .
O5W Sr2 O8W 135.0(5) . .
O7 Sr2 O7W 75.6(5) 1_556 .
O5 Sr2 O7W 147.9(5) 4_566 .
O9W Sr2 O7W 73.0(5) . .
O5W Sr2 O7W 66.9(5) . .
O8W Sr2 O7W 69.0(6) . .
O7 Sr2 O10W 135.5(4) 1_556 .
O5 Sr2 O10W 85.5(4) 4_566 .
O9W Sr2 O10W 74.7(5) . .
O5W Sr2 O10W 69.0(4) . .
O8W Sr2 O10W 148.1(5) . .
O7W Sr2 O10W 122.7(5) . .
O7 Sr2 O6W 71.5(4) 1_556 .
O5 Sr2 O6W 75.7(4) 4_566 .
O9W Sr2 O6W 140.2(5) . .
O5W Sr2 O6W 71.3(4) . .
O8W Sr2 O6W 134.6(5) . .
O7W Sr2 O6W 127.3(5) . .
O10W Sr2 O6W 65.6(4) . .
O7 Sr2 Sr1 95.0(3) 1_556 .
O5 Sr2 Sr1 106.0(3) 4_566 .
O9W Sr2 Sr1 105.8(4) . .
O5W Sr2 Sr1 38.5(3) . .
O8W Sr2 Sr1 168.5(4) . .
O7W Sr2 Sr1 105.4(4) . .
O10W Sr2 Sr1 43.3(3) . .
O6W Sr2 Sr1 40.6(3) . .
O7 W1 O1 103.1(5) . .
O7 W1 O4 102.5(5) . .
O1 W1 O4 94.0(5) . .
O7 W1 O18 98.7(5) . 3_756
O1 W1 O18 92.0(5) . 3_756
O4 W1 O18 156.0(5) . 3_756
O7 W1 O16 96.5(5) . 3_756
O1 W1 O16 160.3(4) . 3_756
O4 W1 O16 84.1(5) . 3_756
O18 W1 O16 82.5(4) 3_756 3_756
O7 W1 O6 164.9(5) . 3_756
O1 W1 O6 88.5(5) . 3_756
O4 W1 O6 86.0(4) . 3_756
O18 W1 O6 71.0(4) 3_756 3_756
O16 W1 O6 71.7(4) 3_756 3_756
O17 W2 O3 104.5(5) . .
O17 W2 O21 102.9(5) . .
O3 W2 O21 95.3(5) . .
O17 W2 O18 97.0(5) . .
O3 W2 O18 93.8(5) . .
O21 W2 O18 155.2(5) . .
O17 W2 O11 93.7(5) . .
O3 W2 O11 161.7(4) . .
O21 W2 O11 82.3(5) . .
O18 W2 O11 81.9(5) . .
O17 W2 O6 161.8(5) . .
O3 W2 O6 89.9(4) . .
O21 W2 O6 86.3(5) . .
O18 W2 O6 70.7(4) . .
O11 W2 O6 71.8(4) . .
O17 W2 Na1 64.0(4) . .
O3 W2 Na1 127.8(4) . .
O21 W2 Na1 46.6(4) . .
O18 W2 Na1 136.5(3) . .
O11 W2 Na1 62.2(3) . .
O6 W2 Na1 115.5(3) . .
O19 W3 O5 101.9(6) . .
O19 W3 O14 100.1(5) . .
O5 W3 O14 97.4(5) . .
O19 W3 O10 93.8(5) . .
O5 W3 O10 97.4(5) . .
O14 W3 O10 157.2(5) . .
O19 W3 O4 162.2(5) . .
O5 W3 O4 92.5(5) . .
O14 W3 O4 88.3(4) . .
O10 W3 O4 73.8(4) . .
O19 W3 O3 90.1(5) . .
O5 W3 O3 167.7(5) . .
O14 W3 O3 82.9(4) . .
O10 W3 O3 79.0(4) . .
O4 W3 O3 75.2(4) . .
O12 W4 O2 103.0(6) . .
O12 W4 O8 97.5(5) . .
O2 W4 O8 101.2(5) . .
O12 W4 O10 98.2(5) . .
O2 W4 O10 98.1(5) . .
O8 W4 O10 151.6(5) . .
O12 W4 O4 92.3(5) . .
O2 W4 O4 163.4(5) . .
O8 W4 O4 83.0(5) . .
O10 W4 O4 72.9(4) . .
O12 W4 O21 166.6(5) . .
O2 W4 O21 88.7(5) . .
O8 W4 O21 73.5(4) . .
O10 W4 O21 86.4(4) . .
O4 W4 O21 77.0(4) . .
O12 W4 Na1 139.8(4) . .
O2 W4 Na1 38.0(5) . .
O8 W4 Na1 85.5(4) . .
O10 W4 Na1 97.4(4) . .
O4 W4 Na1 127.7(3) . .
O21 W4 Na1 50.9(3) . .
O20 W5 O16 101.9(5) . .
O20 W5 O11 101.8(5) . .
O16 W5 O11 92.3(5) . .
O20 W5 O14 100.7(5) . 3_756
O16 W5 O14 87.3(5) . 3_756
O11 W5 O14 157.1(4) . 3_756
O20 W5 O13 101.0(5) . .
O16 W5 O13 156.4(5) . .
O11 W5 O13 88.8(5) . .
O14 W5 O13 82.7(5) 3_756 .
O20 W5 O6 177.5(5) . .
O16 W5 O6 75.9(5) . .
O11 W5 O6 77.3(4) . .
O14 W5 O6 80.4(4) 3_756 .
O13 W5 O6 81.3(5) . .
O9 W6 O15 103.0(5) . .
O9 W6 O13 100.3(5) . .
O15 W6 O13 99.0(5) . .
O9 W6 O8 96.0(5) . .
O15 W6 O8 93.9(5) . .
O13 W6 O8 156.4(5) . .
O9 W6 O1 91.1(5) . .
O15 W6 O1 164.5(5) . .
O13 W6 O1 84.5(4) . .
O8 W6 O1 78.1(4) . .
O9 W6 O21 164.8(5) . .
O15 W6 O21 88.3(5) . .
O13 W6 O21 87.6(5) . .
O8 W6 O21 73.0(4) . .
O1 W6 O21 76.7(4) . .
O9 W6 Na1 139.5(4) . .
O15 W6 Na1 36.9(4) . .
O13 W6 Na1 93.3(4) . .
O8 W6 Na1 85.2(3) . .
O1 W6 Na1 128.2(3) . .
O21 W6 Na1 51.6(3) . .
O17 Na1 O15 172.4(5) 3_656 .
O17 Na1 O1W 95.2(5) 3_656 3_656
O15 Na1 O1W 87.3(5) . 3_656
O17 Na1 O2 88.1(5) 3_656 .
O15 Na1 O2 84.4(5) . .
O1W Na1 O2 116.8(5) 3_656 .
O17 Na1 O2W 83.4(5) 3_656 3_656
O15 Na1 O2W 104.2(5) . 3_656
O1W Na1 O2W 77.6(5) 3_656 3_656
O2 Na1 O2W 164.0(6) . 3_656
O17 Na1 O21 112.5(5) 3_656 .
O15 Na1 O21 65.1(4) . .
O1W Na1 O21 152.2(5) 3_656 .
O2 Na1 O21 66.1(4) . .
O2W Na1 O21 104.8(5) 3_656 .
O17 Na1 W6 151.5(4) 3_656 .
O15 Na1 W6 25.9(3) . .
O1W Na1 W6 113.0(4) 3_656 .
O2 Na1 W6 76.1(3) . .
O2W Na1 W6 105.6(4) 3_656 .
O21 Na1 W6 39.3(2) . .
O17 Na1 W4 101.3(4) 3_656 .
O15 Na1 W4 72.2(3) . .
O1W Na1 W4 136.5(4) 3_656 .
O2 Na1 W4 26.3(3) . .
O2W Na1 W4 143.7(4) 3_656 .
O21 Na1 W4 39.9(2) . .
W6 Na1 W4 55.57(11) . .
O17 Na1 W2 90.3(4) 3_656 .
O15 Na1 W2 89.9(4) . .
O1W Na1 W2 158.6(4) 3_656 .
O2 Na1 W2 84.0(4) . .
O2W Na1 W2 82.5(3) 3_656 .
O21 Na1 W2 30.2(2) . .
W6 Na1 W2 64.88(13) . .
W4 Na1 W2 61.64(12) . .
O17 Na1 Sr1 103.7(4) 3_656 3_656
O15 Na1 Sr1 82.9(3) . 3_656
O1W Na1 Sr1 42.0(3) 3_656 3_656
O2 Na1 Sr1 155.7(4) . 3_656
O2W Na1 Sr1 40.4(3) 3_656 3_656
O21 Na1 Sr1 125.5(3) . 3_656
W6 Na1 Sr1 100.10(18) . 3_656
W4 Na1 Sr1 155.0(2) . 3_656
W2 Na1 Sr1 116.6(2) . 3_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O1 W1 1.813(10) .
O1 W6 2.156(10) .
O2 W4 1.757(13) .
O2 Na1 2.442(15) .
O1W Na1 2.433(15) 3_656
O1W Sr1 2.709(13) .
O3 W2 1.796(11) .
O3 W3 2.209(11) .
O2W Na1 2.478(17) 3_656
O2W Sr1 2.631(13) .
O4 W1 1.899(11) .
O4 W3 2.209(12) .
O4 W4 2.279(10) .
O3W Sr1 2.671(16) .
O5 W3 1.730(12) .
O5 Sr2 2.551(13) 4_565
O4W Sr1 2.594(14) .
O6 W5 2.232(12) .
O6 W1 2.249(12) 3_756
O6 W2 2.284(11) .
O5W Sr1 2.599(12) .
O5W Sr2 2.600(13) .
O7 W1 1.748(12) .
O7 Sr2 2.484(13) 1_554
O6W Sr1 2.674(14) .
O6W Sr2 2.735(13) .
O8 W4 1.886(12) .
O8 W6 1.982(11) .
O7W Sr2 2.719(18) .
O9 W6 1.729(13) .
O9 Sr1 2.701(13) 1_554
O8W Sr2 2.650(17) .
O10 W4 1.918(12) .
O10 W3 1.958(11) .
O9W Sr2 2.560(16) .
O11 W5 1.863(11) .
O11 W2 2.098(11) .
O10W Sr2 2.725(14) .
O10W Sr1 2.803(14) .
O12 W4 1.717(11) .
O13 W6 1.882(11) .
O13 W5 1.960(11) .
O14 W3 1.915(10) .
O14 W5 1.933(10) 3_756
O15 W6 1.740(12) .
O15 Na1 2.388(13) .
O16 W5 1.858(10) .
O16 W1 2.067(10) 3_756
O17 W2 1.730(12) .
O17 Na1 2.266(14) 3_656
O18 W2 1.932(11) .
O18 W1 1.960(10) 3_756
O19 W3 1.726(12) .
O19 Sr1 2.610(12) .
O20 W5 1.731(11) .
O21 W2 1.919(11) .
O21 W6 2.241(11) .
O21 W4 2.292(11) .
O21 Na1 2.773(13) .
Sr1 O9 2.701(13) 1_556
Sr1 Na1 3.973(8) 3_656
Sr1 Sr2 4.069(3) .
Sr2 O7 2.484(13) 1_556
Sr2 O5 2.551(13) 4_566
W1 O18 1.960(10) 3_756
W1 O16 2.067(10) 3_756
W1 O6 2.249(12) 3_756
W2 Na1 3.716(8) .
W4 Na1 3.573(7) .
W5 O14 1.933(10) 3_756
W6 Na1 3.540(7) .
Na1 O17 2.266(14) 3_656
Na1 O1W 2.433(15) 3_656
Na1 O2W 2.478(17) 3_656
Na1 Sr1 3.973(8) 3_656
