#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:49:02 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180483 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/52/7215268.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7215268
loop_
_publ_author_name
'Béziau, Antoine'
'Baudron, Stéphane A.'
'Rasoloarison, Dimby'
'Hosseini, Mir Wais'
_publ_section_title
;
 Rigid yet flexible heteroleptic Co(iii) dipyrrin complexes for the
 construction of heterometallic 1- and 2-D coordination polymers
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              4973
_journal_paper_doi               10.1039/c4ce00273c
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C68 H62 Cd Cl2 Co2 N12 O6'
_chemical_formula_weight         1444.46
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.5700(10)
_cell_angle_beta                 106.7170(10)
_cell_angle_gamma                98.3020(10)
_cell_formula_units_Z            1
_cell_length_a                   9.4261(2)
_cell_length_b                   13.4558(2)
_cell_length_c                   13.9409(2)
_cell_measurement_reflns_used    9936
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.95
_cell_measurement_theta_min      2.33
_cell_volume                     1573.00(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0194
_diffrn_reflns_av_sigmaI/netI    0.0235
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24944
_diffrn_reflns_theta_full        29.32
_diffrn_reflns_theta_max         29.32
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    1.005
_exptl_absorpt_correction_T_max  0.9515
_exptl_absorpt_correction_T_min  0.9062
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    1.525
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             738
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.527
_refine_diff_density_min         -0.625
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     416
_refine_ls_number_reflns         8347
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0389
_refine_ls_R_factor_gt           0.0322
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0417P)²+1.4189P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0841
_refine_ls_wR_factor_ref         0.0885
_reflns_number_gt                7260
_reflns_number_total             8347
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ce00273c1.cif
_cod_data_source_block           CP7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7215264--7215273.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               7215268
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.6761(2) 0.12626(17) 0.63325(16) 0.0237(4) Uani 1 1 d .
H1 H 0.7114 0.1309 0.7043 0.028 Uiso 1 1 calc R
C2 C 0.7020(2) 0.05145(18) 0.55011(17) 0.0274(4) Uani 1 1 d .
H2 H 0.7566 -0.0001 0.5560 0.033 Uiso 1 1 calc R
C3 C 0.6297(2) 0.07014(18) 0.45825(17) 0.0262(4) Uani 1 1 d .
H3 H 0.6256 0.0329 0.3897 0.031 Uiso 1 1 calc R
C4 C 0.5631(2) 0.15626(16) 0.48734(15) 0.0217(4) Uani 1 1 d .
C5 C 0.4788(2) 0.20407(17) 0.42117(15) 0.0230(4) Uani 1 1 d .
C6 C 0.4237(2) 0.29234(18) 0.45587(16) 0.0245(4) Uani 1 1 d .
C7 C 0.3409(3) 0.3463(2) 0.39222(18) 0.0333(5) Uani 1 1 d .
H7 H 0.3101 0.3267 0.3184 0.040 Uiso 1 1 calc R
C8 C 0.3159(3) 0.4312(2) 0.4597(2) 0.0379(6) Uani 1 1 d .
H8 H 0.2643 0.4806 0.4411 0.045 Uiso 1 1 calc R
C9 C 0.3835(3) 0.42993(19) 0.56383(19) 0.0308(5) Uani 1 1 d .
H9 H 0.3838 0.4804 0.6255 0.037 Uiso 1 1 calc R
C10 C 0.4478(2) 0.15595(18) 0.30442(15) 0.0244(4) Uani 1 1 d .
C11 C 0.5648(3) 0.1597(2) 0.26242(18) 0.0341(5) Uani 1 1 d .
H11 H 0.6658 0.1909 0.3072 0.041 Uiso 1 1 calc R
C12 C 0.5292(3) 0.1163(2) 0.15337(18) 0.0354(5) Uani 1 1 d .
H12 H 0.6058 0.1181 0.1237 0.042 Uiso 1 1 calc R
C13 C 0.3784(3) 0.07046(19) 0.08905(16) 0.0287(5) Uani 1 1 d .
H13 H 0.3554 0.0426 0.0156 0.034 Uiso 1 1 calc R
C14 C 0.2991(2) 0.10721(17) 0.23339(15) 0.0230(4) Uani 1 1 d .
H14 H 0.2203 0.1043 0.2609 0.028 Uiso 1 1 calc R
C15 C 0.8316(2) 0.37764(18) 0.65002(16) 0.0242(4) Uani 1 1 d .
H15 H 0.8081 0.3178 0.5894 0.029 Uiso 1 1 calc R
C16 C 0.9700(2) 0.45793(19) 0.69520(18) 0.0284(4) Uani 1 1 d .
H16 H 1.0510 0.4607 0.6698 0.034 Uiso 1 1 calc R
C17 C 0.9617(2) 0.53077(18) 0.78367(17) 0.0261(4) Uani 1 1 d .
H17 H 1.0368 0.5920 0.8305 0.031 Uiso 1 1 calc R
C18 C 0.8160(2) 0.49470(16) 0.79020(15) 0.0217(4) Uani 1 1 d .
C19 C 0.7516(2) 0.54705(16) 0.86172(15) 0.0211(4) Uani 1 1 d .
C20 C 0.6004(2) 0.51683(17) 0.85480(16) 0.0228(4) Uani 1 1 d .
C21 C 0.5222(3) 0.57602(19) 0.91420(18) 0.0305(5) Uani 1 1 d .
H21 H 0.5644 0.6411 0.9702 0.037 Uiso 1 1 calc R
C22 C 0.3735(3) 0.5195(2) 0.8736(2) 0.0345(5) Uani 1 1 d .
H22 H 0.2946 0.5391 0.8962 0.041 Uiso 1 1 calc R
C23 C 0.3617(2) 0.42661(19) 0.79172(19) 0.0301(5) Uani 1 1 d .
H23 H 0.2720 0.3735 0.7516 0.036 Uiso 1 1 calc R
C24 C -0.1509(2) -0.35514(17) -0.04605(15) 0.0222(4) Uani 1 1 d .
C25 C -0.0936(3) -0.36115(18) 0.05522(17) 0.0287(5) Uani 1 1 d .
H25 H -0.1088 -0.4269 0.0651 0.034 Uiso 1 1 calc R
C26 C -0.0141(3) -0.26893(19) 0.14102(17) 0.0309(5) Uani 1 1 d .
H26 H 0.0263 -0.2715 0.2092 0.037 Uiso 1 1 calc R
C27 C 0.0042(2) -0.17293(18) 0.12359(16) 0.0263(4) Uani 1 1 d .
H27 H 0.0530 -0.1103 0.1820 0.032 Uiso 1 1 calc R
C28 C -0.1200(2) -0.25621(17) -0.05661(16) 0.0250(4) Uani 1 1 d .
H28 H -0.1527 -0.2518 -0.1246 0.030 Uiso 1 1 calc R
C29 C 0.4244(3) 0.17021(19) 0.80858(18) 0.0322(5) Uani 1 1 d .
H29 H 0.3881 0.1328 0.8469 0.039 Uiso 1 1 calc R
C30 C 0.3223(3) 0.16608(17) 0.71203(18) 0.0272(4) Uani 1 1 d .
C31 C 0.1621(3) 0.0970(2) 0.6701(2) 0.0372(5) Uani 1 1 d .
H31A H 0.0909 0.1413 0.6683 0.056 Uiso 1 1 calc R
H31B H 0.1520 0.0570 0.7159 0.056 Uiso 1 1 calc R
H31C H 0.1411 0.0484 0.5993 0.056 Uiso 1 1 calc R
C32 C 0.5771(3) 0.22664(17) 0.85157(16) 0.0254(4) Uani 1 1 d .
C33 C 0.6766(3) 0.2241(2) 0.95639(18) 0.0351(5) Uani 1 1 d .
H33A H 0.7039 0.1568 0.9454 0.053 Uiso 1 1 calc R
H33B H 0.6219 0.2329 1.0054 0.053 Uiso 1 1 calc R
H33C H 0.7677 0.2811 0.9852 0.053 Uiso 1 1 calc R
N1 N 0.59450(19) 0.18985(14) 0.59722(13) 0.0211(3) Uani 1 1 d .
N2 N 0.44669(19) 0.34754(14) 0.56253(13) 0.0226(3) Uani 1 1 d .
N3 N 0.26353(19) 0.06415(14) 0.12733(13) 0.0227(3) Uani 1 1 d .
N4 N 0.73857(18) 0.39887(14) 0.70584(13) 0.0201(3) Uani 1 1 d .
N5 N 0.49618(19) 0.42401(14) 0.77860(13) 0.0226(3) Uani 1 1 d .
N6 N -0.0448(2) -0.16589(14) 0.02690(13) 0.0234(3) Uani 1 1 d .
O1 O 0.64499(16) 0.28072(12) 0.80906(11) 0.0234(3) Uani 1 1 d .
O2 O 0.35114(16) 0.21755(12) 0.65336(12) 0.0252(3) Uani 1 1 d .
Cl1 Cl -0.09046(6) 0.08481(5) 0.15281(4) 0.03220(13) Uani 1 1 d .
Co1 Co 0.54463(3) 0.30941(2) 0.683645(19) 0.01867(7) Uani 1 1 d .
Cd1 Cd 0.0000 0.0000 0.0000 0.01876(6) Uani 1 2 d S
C34 C 1.0187(4) 0.2171(4) 0.4541(3) 0.0753(11) Uani 1 1 d .
H34A H 1.0759 0.1823 0.4139 0.113 Uiso 1 1 calc R
H34B H 0.9507 0.1645 0.4650 0.113 Uiso 1 1 calc R
H34C H 1.0878 0.2665 0.5219 0.113 Uiso 1 1 calc R
O3 O 0.9363(6) 0.2710(9) 0.3995(9) 0.261(4) Uani 1 1 d .
H3A H 0.9941 0.3142 0.3879 0.392 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 111.52(18) . .
N1 C1 H1 124.2 . .
C2 C1 H1 124.2 . .
C3 C2 C1 106.03(19) . .
C3 C2 H2 127.0 . .
C1 C2 H2 127.0 . .
C2 C3 C4 107.32(19) . .
C2 C3 H3 126.3 . .
C4 C3 H3 126.3 . .
N1 C4 C5 123.12(19) . .
N1 C4 C3 108.81(17) . .
C5 C4 C3 128.08(19) . .
C6 C5 C4 125.07(18) . .
C6 C5 C10 117.93(18) . .
C4 C5 C10 117.00(19) . .
C5 C6 N2 124.53(18) . .
C5 C6 C7 127.4(2) . .
N2 C6 C7 108.0(2) . .
C8 C7 C6 107.3(2) . .
C8 C7 H7 126.4 . .
C6 C7 H7 126.4 . .
C7 C8 C9 106.6(2) . .
C7 C8 H8 126.7 . .
C9 C8 H8 126.7 . .
N2 C9 C8 111.5(2) . .
N2 C9 H9 124.2 . .
C8 C9 H9 124.2 . .
C11 C10 C14 117.74(19) . .
C11 C10 C5 121.59(18) . .
C14 C10 C5 120.66(18) . .
C12 C11 C10 119.2(2) . .
C12 C11 H11 120.4 . .
C10 C11 H11 120.4 . .
C13 C12 C11 119.1(2) . .
C13 C12 H12 120.5 . .
C11 C12 H12 120.5 . .
N3 C13 C12 123.12(19) . .
N3 C13 H13 118.4 . .
C12 C13 H13 118.4 . .
N3 C14 C10 123.51(19) . .
N3 C14 H14 118.2 . .
C10 C14 H14 118.2 . .
N4 C15 C16 111.26(19) . .
N4 C15 H15 124.4 . .
C16 C15 H15 124.4 . .
C17 C16 C15 106.71(19) . .
C17 C16 H16 126.6 . .
C15 C16 H16 126.6 . .
C16 C17 C18 106.87(18) . .
C16 C17 H17 126.6 . .
C18 C17 H17 126.6 . .
C19 C18 N4 123.46(18) . .
C19 C18 C17 127.62(19) . .
N4 C18 C17 108.75(18) . .
C18 C19 C20 125.37(18) . .
C18 C19 C24 118.80(18) . 1_666
C20 C19 C24 115.83(18) . 1_666
C19 C20 N5 123.69(19) . .
C19 C20 C21 127.6(2) . .
N5 C20 C21 108.44(18) . .
C22 C21 C20 106.9(2) . .
C22 C21 H21 126.5 . .
C20 C21 H21 126.5 . .
C21 C22 C23 107.1(2) . .
C21 C22 H22 126.5 . .
C23 C22 H22 126.5 . .
N5 C23 C22 111.2(2) . .
N5 C23 H23 124.4 . .
C22 C23 H23 124.4 . .
C28 C24 C25 117.78(19) . .
C28 C24 C19 122.12(18) . 1_444
C25 C24 C19 120.04(19) . 1_444
C26 C25 C24 119.5(2) . .
C26 C25 H25 120.3 . .
C24 C25 H25 120.3 . .
C27 C26 C25 118.61(19) . .
C27 C26 H26 120.7 . .
C25 C26 H26 120.7 . .
N6 C27 C26 122.81(19) . .
N6 C27 H27 118.6 . .
C26 C27 H27 118.6 . .
N6 C28 C24 122.92(18) . .
N6 C28 H28 118.5 . .
C24 C28 H28 118.5 . .
C32 C29 C30 124.4(2) . .
C32 C29 H29 117.8 . .
C30 C29 H29 117.8 . .
O2 C30 C29 125.6(2) . .
O2 C30 C31 114.7(2) . .
C29 C30 C31 119.7(2) . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
O1 C32 C29 125.81(19) . .
O1 C32 C33 114.8(2) . .
C29 C32 C33 119.4(2) . .
C32 C33 H33A 109.5 . .
C32 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C32 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C1 N1 C4 106.32(17) . .
C1 N1 Co1 125.81(14) . .
C4 N1 Co1 127.75(14) . .
C9 N2 C6 106.59(17) . .
C9 N2 Co1 126.63(15) . .
C6 N2 Co1 126.75(15) . .
C13 N3 C14 117.38(17) . .
C13 N3 Cd1 118.42(13) . .
C14 N3 Cd1 123.54(13) . .
C15 N4 C18 106.40(17) . .
C15 N4 Co1 127.32(15) . .
C18 N4 Co1 126.05(14) . .
C23 N5 C20 106.36(18) . .
C23 N5 Co1 127.59(15) . .
C20 N5 Co1 125.80(14) . .
C27 N6 C28 118.25(18) . .
C27 N6 Cd1 121.59(14) . .
C28 N6 Cd1 120.16(13) . .
C32 O1 Co1 124.17(14) . .
C30 O2 Co1 124.56(14) . .
O1 Co1 O2 95.00(6) . .
O1 Co1 N1 90.53(7) . .
O2 Co1 N1 88.34(7) . .
O1 Co1 N2 176.46(7) . .
O2 Co1 N2 86.86(7) . .
N1 Co1 N2 92.55(7) . .
O1 Co1 N4 87.30(7) . .
O2 Co1 N4 176.77(7) . .
N1 Co1 N4 89.37(7) . .
N2 Co1 N4 90.97(7) . .
O1 Co1 N5 85.37(7) . .
O2 Co1 N5 90.25(7) . .
N1 Co1 N5 175.53(7) . .
N2 Co1 N5 91.61(8) . .
N4 Co1 N5 92.20(7) . .
N6 Cd1 N6 180.00(13) . 2
N6 Cd1 N3 94.65(6) . .
N6 Cd1 N3 85.35(6) 2 .
N6 Cd1 N3 85.35(6) . 2
N6 Cd1 N3 94.65(6) 2 2
N3 Cd1 N3 180.00(8) . 2
N6 Cd1 Cl1 89.92(5) . 2
N6 Cd1 Cl1 90.08(5) 2 2
N3 Cd1 Cl1 91.43(4) . 2
N3 Cd1 Cl1 88.57(4) 2 2
N6 Cd1 Cl1 90.08(5) . .
N6 Cd1 Cl1 89.92(5) 2 .
N3 Cd1 Cl1 88.57(4) . .
N3 Cd1 Cl1 91.43(4) 2 .
Cl1 Cd1 Cl1 180.00(2) 2 .
O3 C34 H34A 109.5 . .
O3 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
O3 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C34 O3 H3A 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.338(3) .
C1 C2 1.408(3) .
C1 H1 0.9300 .
C2 C3 1.378(3) .
C2 H2 0.9300 .
C3 C4 1.411(3) .
C3 H3 0.9300 .
C4 N1 1.394(2) .
C4 C5 1.400(3) .
C5 C6 1.382(3) .
C5 C10 1.492(3) .
C6 N2 1.396(3) .
C6 C7 1.434(3) .
C7 C8 1.355(4) .
C7 H7 0.9300 .
C8 C9 1.414(3) .
C8 H8 0.9300 .
C9 N2 1.330(3) .
C9 H9 0.9300 .
C10 C11 1.390(3) .
C10 C14 1.393(3) .
C11 C12 1.381(3) .
C11 H11 0.9300 .
C12 C13 1.380(3) .
C12 H12 0.9300 .
C13 N3 1.340(3) .
C13 H13 0.9300 .
C14 N3 1.343(2) .
C14 H14 0.9300 .
C15 N4 1.339(3) .
C15 C16 1.414(3) .
C15 H15 0.9300 .
C16 C17 1.370(3) .
C16 H16 0.9300 .
C17 C18 1.426(3) .
C17 H17 0.9300 .
C18 C19 1.390(3) .
C18 N4 1.396(3) .
C19 C20 1.391(3) .
C19 C24 1.495(3) 1_666
C20 N5 1.394(3) .
C20 C21 1.417(3) .
C21 C22 1.361(3) .
C21 H21 0.9300 .
C22 C23 1.397(3) .
C22 H22 0.9300 .
C23 N5 1.335(3) .
C23 H23 0.9300 .
C24 C28 1.379(3) .
C24 C25 1.389(3) .
C24 C19 1.495(3) 1_444
C25 C26 1.379(3) .
C25 H25 0.9300 .
C26 C27 1.377(3) .
C26 H26 0.9300 .
C27 N6 1.329(3) .
C27 H27 0.9300 .
C28 N6 1.343(3) .
C28 H28 0.9300 .
C29 C32 1.392(3) .
C29 C30 1.392(3) .
C29 H29 0.9300 .
C30 O2 1.273(3) .
C30 C31 1.504(3) .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C32 O1 1.273(3) .
C32 C33 1.505(3) .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
N1 Co1 1.9234(18) .
N2 Co1 1.9237(16) .
N3 Cd1 2.4570(16) .
N4 Co1 1.9271(16) .
N5 Co1 1.9302(18) .
N6 Cd1 2.3660(17) .
O1 Co1 1.9078(14) .
O2 Co1 1.9080(14) .
Cl1 Cd1 2.5509(5) .
Cd1 N6 2.3660(17) 2
Cd1 N3 2.4570(16) 2
Cd1 Cl1 2.5509(5) 2
C34 O3 1.359(8) .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
O3 H3A 0.8200 .
