#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:49:02 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180483 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/52/7215271.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7215271
loop_
_publ_author_name
'Béziau, Antoine'
'Baudron, Stéphane A.'
'Rasoloarison, Dimby'
'Hosseini, Mir Wais'
_publ_section_title
;
 Rigid yet flexible heteroleptic Co(iii) dipyrrin complexes for the
 construction of heterometallic 1- and 2-D coordination polymers
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              4973
_journal_paper_doi               10.1039/c4ce00273c
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C66 H42 Cd Cl2 Co2 F12 N12 O4'
_chemical_formula_sum            'C66 H42 Cd Cl2 Co2 F12 N12 O4'
_chemical_formula_weight         1596.28
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.6850(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.1158(7)
_cell_length_b                   25.2786(8)
_cell_length_c                   15.2033(5)
_cell_measurement_reflns_used    9968
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.12
_cell_measurement_theta_min      2.41
_cell_volume                     8729.8(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0382
_diffrn_reflns_av_sigmaI/netI    0.0350
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            60417
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         1.21
_exptl_absorpt_coefficient_mu    0.748
_exptl_absorpt_correction_T_max  0.9707
_exptl_absorpt_correction_T_min  0.8961
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    1.215
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3192
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.04
_platon_squeeze_details
;
;
_refine_diff_density_max         1.407
_refine_diff_density_min         -0.638
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.129
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     448
_refine_ls_number_reflns         9862
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.129
_refine_ls_R_factor_all          0.0554
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0710P)²+0.0648P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1182
_refine_ls_wR_factor_ref         0.1231
_reflns_number_gt                7414
_reflns_number_total             9862
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ce00273c1.cif
_cod_data_source_block           CP10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7215264--7215273.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'C2/c  '
_cod_database_code               7215271
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.22165(13) 0.24543(13) 0.12253(19) 0.0458(8) Uani 1 1 d .
H1 H 0.1921 0.2694 0.1283 0.055 Uiso 1 1 calc R
C2 C 0.21620(14) 0.20509(13) 0.0582(2) 0.0493(8) Uani 1 1 d .
H2 H 0.1832 0.1974 0.0150 0.059 Uiso 1 1 calc R
C3 C 0.26910(13) 0.17920(12) 0.07186(19) 0.0450(7) Uani 1 1 d .
H3 H 0.2788 0.1508 0.0386 0.054 Uiso 1 1 calc R
C4 C 0.30590(12) 0.20294(11) 0.14436(17) 0.0348(6) Uani 1 1 d .
C5 C 0.36144(12) 0.18620(11) 0.18883(18) 0.0354(6) Uani 1 1 d .
C6 C 0.38906(12) 0.20415(11) 0.27230(19) 0.0391(7) Uani 1 1 d .
C7 C 0.44215(14) 0.18605(13) 0.3284(2) 0.0490(8) Uani 1 1 d .
H7 H 0.4679 0.1607 0.3137 0.059 Uiso 1 1 calc R
C8 C 0.44781(15) 0.21284(14) 0.4071(2) 0.0543(9) Uani 1 1 d .
H8 H 0.4773 0.2084 0.4571 0.065 Uiso 1 1 calc R
C9 C 0.40060(13) 0.24835(13) 0.39809(19) 0.0451(8) Uani 1 1 d .
H9 H 0.3948 0.2724 0.4419 0.054 Uiso 1 1 calc R
C10 C 0.39035(12) 0.14385(11) 0.14437(18) 0.0348(6) Uani 1 1 d .
C11 C 0.40037(12) 0.15053(10) 0.05735(18) 0.0350(6) Uani 1 1 d .
H11 H 0.3887 0.1815 0.0260 0.042 Uiso 1 1 calc R
C12 C 0.42796(11) 0.11060(10) 0.01779(18) 0.0332(6) Uani 1 1 d .
H12 H 0.4344 0.1154 -0.0403 0.040 Uiso 1 1 calc R
C13 C 0.43556(12) 0.05960(11) 0.14361(17) 0.0337(6) Uani 1 1 d .
H13 H 0.4478 0.0283 0.1736 0.040 Uiso 1 1 calc R
C14 C 0.40813(12) 0.09716(11) 0.18726(18) 0.0369(7) Uani 1 1 d .
H14 H 0.4017 0.0910 0.2450 0.044 Uiso 1 1 calc R
C15 C 0.24921(14) 0.21655(12) 0.3703(2) 0.0452(8) Uani 1 1 d .
H15 H 0.2744 0.1892 0.3614 0.054 Uiso 1 1 calc R
C16 C 0.20471(15) 0.21230(13) 0.4212(2) 0.0519(8) Uani 1 1 d .
H16 H 0.1952 0.1823 0.4510 0.062 Uiso 1 1 calc R
C17 C 0.17765(14) 0.26123(13) 0.4186(2) 0.0476(8) Uani 1 1 d .
H17 H 0.1466 0.2705 0.4467 0.057 Uiso 1 1 calc R
C18 C 0.20598(13) 0.29459(11) 0.36512(18) 0.0374(7) Uani 1 1 d .
C19 C 0.18766(12) 0.34408(11) 0.33181(17) 0.0358(6) Uani 1 1 d .
C20 C 0.20734(13) 0.36842(11) 0.26025(19) 0.0390(7) Uani 1 1 d .
C21 C 0.18534(14) 0.41435(13) 0.2121(2) 0.0496(8) Uani 1 1 d .
H21 H 0.1575 0.4377 0.2267 0.060 Uiso 1 1 calc R
C22 C 0.21281(15) 0.41796(14) 0.1401(2) 0.0557(9) Uani 1 1 d .
H22 H 0.2060 0.4435 0.0953 0.067 Uiso 1 1 calc R
C23 C 0.25252(14) 0.37671(12) 0.14613(19) 0.0461(8) Uani 1 1 d .
H23 H 0.2777 0.3708 0.1060 0.055 Uiso 1 1 calc R
C24 C 0.14275(12) 0.37248(11) 0.37299(18) 0.0371(7) Uani 1 1 d .
C25 C 0.08631(13) 0.38214(12) 0.32570(19) 0.0438(8) Uani 1 1 d .
H25 H 0.0745 0.3688 0.2681 0.053 Uiso 1 1 calc R
C26 C 0.04801(12) 0.41178(11) 0.36541(19) 0.0373(7) Uani 1 1 d .
H26 H 0.0101 0.4173 0.3334 0.045 Uiso 1 1 calc R
C27 C 0.11612(13) 0.42234(13) 0.4930(2) 0.0447(8) Uani 1 1 d .
H27 H 0.1266 0.4358 0.5507 0.054 Uiso 1 1 calc R
C28 C 0.15706(13) 0.39219(13) 0.45816(19) 0.0466(8) Uani 1 1 d .
H28 H 0.1939 0.3855 0.4926 0.056 Uiso 1 1 calc R
C29 C 0.4269(2) 0.3707(2) 0.1427(3) 0.0940(16) Uani 1 1 d .
C30 C 0.39104(15) 0.35699(17) 0.2137(2) 0.0596(9) Uani 1 1 d .
C31 C 0.39661(18) 0.38981(18) 0.2892(3) 0.0738(11) Uani 1 1 d .
H31 H 0.4205 0.4196 0.2929 0.089 Uiso 1 1 calc R
C32 C 0.36705(16) 0.37846(15) 0.3588(2) 0.0573(9) Uani 1 1 d .
C33 C 0.3795(2) 0.41187(18) 0.4408(3) 0.0817(13) Uani 1 1 d .
N1 N 0.27496(10) 0.24468(9) 0.17419(14) 0.0369(6) Uani 1 1 d .
N2 N 0.36502(10) 0.24339(10) 0.31895(15) 0.0409(6) Uani 1 1 d .
N3 N 0.44546(9) 0.06581(8) 0.06026(14) 0.0279(5) Uani 1 1 d .
N4 N 0.25049(10) 0.26556(9) 0.33615(14) 0.0383(6) Uani 1 1 d .
N5 N 0.24989(10) 0.34636(9) 0.21764(14) 0.0382(6) Uani 1 1 d .
N6 N 0.56209(9) 0.06724(8) -0.05358(14) 0.0283(5) Uani 1 1 d .
O1 O 0.35941(9) 0.31752(9) 0.19491(13) 0.0481(5) Uani 1 1 d .
O2 O 0.33093(9) 0.34093(8) 0.36308(13) 0.0434(5) Uani 1 1 d .
F1 F 0.46373(17) 0.33339(17) 0.1342(3) 0.1666(17) Uani 1 1 d .
F2 F 0.39225(14) 0.37915(16) 0.0646(2) 0.1326(13) Uani 1 1 d .
F3 F 0.45829(14) 0.41534(15) 0.1586(2) 0.1320(12) Uani 1 1 d .
F4 F 0.33039(16) 0.42495(13) 0.4691(2) 0.1328(12) Uani 1 1 d .
F5 F 0.40755(18) 0.38458(13) 0.5099(2) 0.1364(13) Uani 1 1 d .
F6 F 0.4079(2) 0.45518(14) 0.4350(2) 0.1588(16) Uani 1 1 d .
Cl1 Cl 0.43073(3) 0.00306(2) -0.14980(4) 0.02688(14) Uani 1 1 d .
Co2 Co 0.304224(16) 0.291986(15) 0.26734(2) 0.03667(12) Uani 1 1 d .
Cd1 Cd 0.5000 0.0000 0.0000 0.01866(8) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 110.7(2) . .
N1 C1 H1 124.6 . .
C2 C1 H1 124.6 . .
C3 C2 C1 106.3(3) . .
C3 C2 H2 126.9 . .
C1 C2 H2 126.9 . .
C2 C3 C4 108.1(3) . .
C2 C3 H3 126.0 . .
C4 C3 H3 126.0 . .
N1 C4 C3 107.9(2) . .
N1 C4 C5 123.4(2) . .
C3 C4 C5 128.4(2) . .
C6 C5 C4 124.6(2) . .
C6 C5 C10 118.8(2) . .
C4 C5 C10 116.5(2) . .
C5 C6 N2 122.6(2) . .
C5 C6 C7 129.6(2) . .
N2 C6 C7 107.6(2) . .
C8 C7 C6 107.2(3) . .
C8 C7 H7 126.4 . .
C6 C7 H7 126.4 . .
C7 C8 C9 106.7(3) . .
C7 C8 H8 126.6 . .
C9 C8 H8 126.6 . .
N2 C9 C8 111.6(3) . .
N2 C9 H9 124.2 . .
C8 C9 H9 124.2 . .
C14 C10 C11 117.8(2) . .
C14 C10 C5 121.5(2) . .
C11 C10 C5 120.7(2) . .
C12 C11 C10 119.5(2) . .
C12 C11 H11 120.2 . .
C10 C11 H11 120.2 . .
N3 C12 C11 122.1(2) . .
N3 C12 H12 118.9 . .
C11 C12 H12 118.9 . .
N3 C13 C14 123.3(2) . .
N3 C13 H13 118.3 . .
C14 C13 H13 118.3 . .
C10 C14 C13 119.2(2) . .
C10 C14 H14 120.4 . .
C13 C14 H14 120.4 . .
N4 C15 C16 110.8(3) . .
N4 C15 H15 124.6 . .
C16 C15 H15 124.6 . .
C17 C16 C15 106.8(3) . .
C17 C16 H16 126.6 . .
C15 C16 H16 126.6 . .
C16 C17 C18 107.2(3) . .
C16 C17 H17 126.4 . .
C18 C17 H17 126.4 . .
C19 C18 N4 123.4(3) . .
C19 C18 C17 127.3(3) . .
N4 C18 C17 108.3(2) . .
C18 C19 C20 124.1(2) . .
C18 C19 C24 118.1(3) . .
C20 C19 C24 117.8(2) . .
N5 C20 C19 123.1(2) . .
N5 C20 C21 107.8(3) . .
C19 C20 C21 128.8(3) . .
C22 C21 C20 107.1(3) . .
C22 C21 H21 126.5 . .
C20 C21 H21 126.5 . .
C21 C22 C23 107.3(3) . .
C21 C22 H22 126.3 . .
C23 C22 H22 126.3 . .
N5 C23 C22 110.9(3) . .
N5 C23 H23 124.6 . .
C22 C23 H23 124.6 . .
C28 C24 C25 117.7(2) . .
C28 C24 C19 120.5(2) . .
C25 C24 C19 121.8(2) . .
C26 C25 C24 119.0(3) . .
C26 C25 H25 120.5 . .
C24 C25 H25 120.5 . .
N6 C26 C25 123.8(3) 8_456 .
N6 C26 H26 118.1 8_456 .
C25 C26 H26 118.1 . .
N6 C27 C28 122.5(3) 8_456 .
N6 C27 H27 118.7 8_456 .
C28 C27 H27 118.7 . .
C24 C28 C27 119.7(3) . .
C24 C28 H28 120.1 . .
C27 C28 H28 120.1 . .
F1 C29 F2 109.2(5) . .
F1 C29 F3 106.8(4) . .
F2 C29 F3 104.1(5) . .
F1 C29 C30 111.2(5) . .
F2 C29 C30 110.8(4) . .
F3 C29 C30 114.4(4) . .
O1 C30 C31 128.8(3) . .
O1 C30 C29 113.3(4) . .
C31 C30 C29 117.9(4) . .
C32 C31 C30 121.1(4) . .
C32 C31 H31 119.5 . .
C30 C31 H31 119.5 . .
O2 C32 C31 127.7(3) . .
O2 C32 C33 114.0(4) . .
C31 C32 C33 118.2(4) . .
F6 C33 F5 108.5(4) . .
F6 C33 F4 106.7(4) . .
F5 C33 F4 101.2(5) . .
F6 C33 C32 116.5(4) . .
F5 C33 C32 111.1(4) . .
F4 C33 C32 111.6(4) . .
C1 N1 C4 107.0(2) . .
C1 N1 Co2 126.77(18) . .
C4 N1 Co2 126.19(18) . .
C9 N2 C6 106.8(2) . .
C9 N2 Co2 126.26(19) . .
C6 N2 Co2 125.29(18) . .
C12 N3 C13 118.0(2) . .
C12 N3 Cd1 123.08(16) . .
C13 N3 Cd1 118.68(16) . .
C15 N4 C18 106.9(2) . .
C15 N4 Co2 127.11(19) . .
C18 N4 Co2 125.9(2) . .
C23 N5 C20 106.9(2) . .
C23 N5 Co2 127.14(19) . .
C20 N5 Co2 124.84(19) . .
C26 N6 C27 117.1(2) 8 8
C26 N6 Cd1 121.78(17) 8 .
C27 N6 Cd1 120.26(17) 8 .
C30 O1 Co2 123.9(2) . .
C32 O2 Co2 124.2(2) . .
N1 Co2 N4 90.61(10) . .
N1 Co2 N5 92.36(9) . .
N4 Co2 N5 91.25(10) . .
N1 Co2 N2 91.99(10) . .
N4 Co2 N2 93.10(10) . .
N5 Co2 N2 173.82(11) . .
N1 Co2 O2 177.70(9) . .
N4 Co2 O2 87.71(10) . .
N5 Co2 O2 86.10(9) . .
N2 Co2 O2 89.68(9) . .
N1 Co2 O1 88.09(10) . .
N4 Co2 O1 178.57(10) . .
N5 Co2 O1 89.40(10) . .
N2 Co2 O1 86.36(10) . .
O2 Co2 O1 93.60(10) . .
N3 Cd1 N3 180.00(12) . 5_655
N3 Cd1 N6 91.59(8) . .
N3 Cd1 N6 88.41(8) 5_655 .
N3 Cd1 N6 88.41(8) . 5_655
N3 Cd1 N6 91.59(8) 5_655 5_655
N6 Cd1 N6 180.00(12) . 5_655
N3 Cd1 Cl1 91.90(5) . .
N3 Cd1 Cl1 88.10(5) 5_655 .
N6 Cd1 Cl1 89.51(5) . .
N6 Cd1 Cl1 90.49(5) 5_655 .
N3 Cd1 Cl1 88.10(5) . 5_655
N3 Cd1 Cl1 91.90(5) 5_655 5_655
N6 Cd1 Cl1 90.49(5) . 5_655
N6 Cd1 Cl1 89.51(5) 5_655 5_655
Cl1 Cd1 Cl1 180.00(4) . 5_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.333(4) .
C1 C2 1.402(4) .
C1 H1 0.9300 .
C2 C3 1.368(4) .
C2 H2 0.9300 .
C3 C4 1.397(4) .
C3 H3 0.9300 .
C4 N1 1.397(3) .
C4 C5 1.401(4) .
C5 C6 1.387(4) .
C5 C10 1.489(3) .
C6 N2 1.394(3) .
C6 C7 1.433(4) .
C7 C8 1.360(4) .
C7 H7 0.9300 .
C8 C9 1.400(4) .
C8 H8 0.9300 .
C9 N2 1.332(4) .
C9 H9 0.9300 .
C10 C14 1.374(4) .
C10 C11 1.395(4) .
C11 C12 1.389(3) .
C11 H11 0.9300 .
C12 N3 1.329(3) .
C12 H12 0.9300 .
C13 N3 1.338(3) .
C13 C14 1.378(3) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 N4 1.346(4) .
C15 C16 1.402(4) .
C15 H15 0.9300 .
C16 C17 1.383(4) .
C16 H16 0.9300 .
C17 C18 1.414(4) .
C17 H17 0.9300 .
C18 C19 1.386(4) .
C18 N4 1.400(3) .
C19 C20 1.397(4) .
C19 C24 1.492(3) .
C20 N5 1.391(3) .
C20 C21 1.416(4) .
C21 C22 1.366(4) .
C21 H21 0.9300 .
C22 C23 1.381(4) .
C22 H22 0.9300 .
C23 N5 1.341(4) .
C23 H23 0.9300 .
C24 C28 1.370(4) .
C24 C25 1.390(4) .
C25 C26 1.381(4) .
C25 H25 0.9300 .
C26 N6 1.325(3) 8_456
C26 H26 0.9300 .
C27 N6 1.343(3) 8_456
C27 C28 1.394(4) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 F1 1.292(6) .
C29 F2 1.322(5) .
C29 F3 1.339(6) .
C29 C30 1.519(6) .
C30 O1 1.239(4) .
C30 C31 1.403(5) .
C31 C32 1.391(5) .
C31 H31 0.9300 .
C32 O2 1.274(4) .
C32 C33 1.489(5) .
C33 F6 1.288(5) .
C33 F5 1.322(5) .
C33 F4 1.329(5) .
N1 Co2 1.881(2) .
N2 Co2 1.921(2) .
N3 Cd1 2.3717(19) .
N4 Co2 1.888(2) .
N5 Co2 1.920(2) .
N6 C26 1.325(3) 8
N6 C27 1.343(3) 8
N6 Cd1 2.4589(19) .
O1 Co2 1.944(2) .
O2 Co2 1.923(2) .
Cl1 Cd1 2.5307(6) .
Cd1 N3 2.3717(19) 5_655
Cd1 N6 2.4589(19) 5_655
Cd1 Cl1 2.5307(6) 5_655
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.057 1533 485 ' '
2 0.500 0.500 0.022 1533 485 ' '
