#------------------------------------------------------------------------------
#$Date: 2019-09-17 18:21:18 +0300 (Tue, 17 Sep 2019) $
#$Revision: 218385 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/21/55/7215532.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7215532
loop_
_publ_author_name
'Kirchner, Michael T.'
'Bläser, Dieter'
'Boese, Roland'
'Desiraju, Gautam R.'
_publ_section_title
;
 Additive induced polymorphism. The pentafluorophenol--pentafluoroaniline
 system
;
_journal_coden_ASTM              CRECF4
_journal_issue                   2
_journal_name_full               CrystEngComm
_journal_page_first              229
_journal_page_last               231
_journal_paper_doi               10.1039/b810088h
_journal_volume                  11
_journal_year                    2009
_chemical_formula_moiety         'C6 H2 F5 N, 2(C6 H F5 O)'
_chemical_formula_sum            'C18 H4 F15 N O2'
_chemical_formula_weight         551.22
_chemical_name_common
'cocrystal pentafluorophenol * pentafluoroaniline 6:3'
_chemical_name_systematic
;
cocrystal pentafluorophenol * pentafluoroaniline 6:3
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.6340(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            12
_cell_length_a                   21.1790(5)
_cell_length_b                   17.0734(4)
_cell_length_c                   16.6258(4)
_cell_measurement_reflns_used    9847
_cell_measurement_temperature    140(2)
_cell_measurement_theta_max      35.728
_cell_measurement_theta_min      2.355
_cell_volume                     5464.7(2)
_computing_cell_refinement       'BRUKER AXS SMART APEX 2 Vers. 2.1-4'
_computing_data_collection       'BRUKER AXS SMART APEX 2 Vers. 2.1-4'
_computing_data_reduction        'BRUKER AXS SMART APEX 2 Vers. 2.1-4'
_computing_molecular_graphics    'BRUKER AXS SHELXTL (c) 2001 / Vers.6.12'
_computing_publication_material  'BRUKER AXS SHELXTL (c) 2001 / Vers.6.12'
_computing_structure_refinement  'BRUKER AXS SHELXTL (c) 2001 / Vers.6.12'
_computing_structure_solution    'BRUKER AXS SHELXTL (c) 2001 / Vers.6.12'
_diffrn_ambient_temperature      140(2)
_diffrn_detector_area_resol_mean 512
_diffrn_measured_fraction_theta_full 0.804
_diffrn_measured_fraction_theta_max 0.804
_diffrn_measurement_device_type
;
Siemens SMART three axis goniometer with APEX II area detector system
;
_diffrn_measurement_method
;
Data collection strategy APEX 2 / COSMO

with chi = 0
;
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0289
_diffrn_reflns_av_sigmaI/netI    0.0257
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            84547
_diffrn_reflns_theta_full        36.15
_diffrn_reflns_theta_max         36.15
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    0.234
_exptl_absorpt_correction_T_max  0.9770
_exptl_absorpt_correction_T_min  0.8506
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
BRUKER AXS SMART APEX 2 Vers. 2.1-4
R.H. Blessing, Acta Cryst. (1995) A51 33-38
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.010
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3240
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.462
_refine_diff_density_min         -0.373
_refine_diff_density_rms         0.056
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.5(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     974
_refine_ls_number_reflns         17115
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0826
_refine_ls_R_factor_gt           0.0446
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0794P)²+2.6132P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1293
_refine_ls_wR_factor_ref         0.1612
_reflns_number_gt                10484
_reflns_number_total             17115
_reflns_threshold_expression     >2sigma(I)
_cod_duplicate_entry             7200212
_cod_data_source_file            b810088h.txt
_cod_data_source_block           pfcoc_133_0m
_cod_depositor_comments
;
 Updated bibliographic information.

 Antanas Vaitkus,
 2019-09-17

 Marked entry as a duplicate of entry 7200212.

 Antanas Vaitkus,
 2019-09-17
;
_cod_original_sg_symbol_H-M      Cc
_cod_database_code               7215532
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O1_1 O 0.29067(10) -0.08826(14) 0.36189(15) 0.0273(5) Uani 1 1 d .
H1_1 H 0.3171 -0.0426 0.4130 0.041 Uiso 1 1 d R
F2_1 F 0.22406(12) -0.21365(13) 0.26563(14) 0.0414(5) Uani 1 1 d .
F3_1 F 0.08576(12) -0.23260(14) 0.21280(14) 0.0487(6) Uani 1 1 d .
F4_1 F 0.01143(9) -0.12389(12) 0.25772(13) 0.0431(5) Uani 1 1 d .
F5_1 F 0.07685(9) 0.00536(13) 0.35276(13) 0.0386(5) Uani 1 1 d .
F6_1 F 0.21508(10) 0.02550(12) 0.40526(13) 0.0368(5) Uani 1 1 d .
C1_1 C 0.22172(14) -0.0950(2) 0.33670(19) 0.0235(7) Uani 1 1 d .
C2_1 C 0.18779(17) -0.1596(2) 0.2870(2) 0.0279(7) Uani 1 1 d .
C3_1 C 0.11740(17) -0.1691(2) 0.2606(2) 0.0299(7) Uani 1 1 d .
C4_1 C 0.07989(15) -0.1142(2) 0.2825(2) 0.0304(7) Uani 1 1 d .
C5_1 C 0.11224(14) -0.0494(2) 0.33016(19) 0.0276(7) Uani 1 1 d .
C6_1 C 0.18381(14) -0.0389(2) 0.35729(18) 0.0231(6) Uani 1 1 d .
F1_2 F 0.28576(11) 0.25557(14) 0.36123(15) 0.0424(5) Uani 1 1 d .
F2_2 F 0.22964(11) 0.12450(13) 0.26565(14) 0.0376(5) Uani 1 1 d .
F3_2 F 0.09341(12) 0.09327(14) 0.20836(14) 0.0433(5) Uani 1 1 d .
N4_2 N 0.00675(14) 0.1908(2) 0.25136(19) 0.0433(8) Uani 1 1 d .
H1_2 H -0.0250 0.2266 0.2350 0.065 Uiso 1 1 d R
H2_2 H -0.0056 0.1523 0.2071 0.065 Uiso 1 1 d R
F5_2 F 0.06469(12) 0.32573(16) 0.34213(17) 0.0521(7) Uani 1 1 d .
F6_2 F 0.20241(13) 0.35695(14) 0.39810(15) 0.0424(6) Uani 1 1 d .
C1_2 C 0.21832(16) 0.2408(2) 0.3334(2) 0.0257(7) Uani 1 1 d .
C2_2 C 0.18916(15) 0.17414(19) 0.2842(2) 0.0259(7) Uani 1 1 d .
C3_2 C 0.11927(17) 0.1589(2) 0.2559(2) 0.0288(7) Uani 1 1 d .
C4_2 C 0.07556(17) 0.2088(2) 0.2742(2) 0.0339(8) Uani 1 1 d .
C5_2 C 0.10477(18) 0.2753(2) 0.3221(2) 0.0333(8) Uani 1 1 d .
C6_2 C 0.17535(17) 0.2922(2) 0.3514(2) 0.0299(7) Uani 1 1 d .
O1_3 O 0.29098(11) 0.58251(15) 0.36095(16) 0.0327(5) Uani 1 1 d .
H1_3 H 0.3007 0.6228 0.3983 0.049 Uiso 1 1 d R
F2_3 F 0.22519(12) 0.45638(13) 0.26496(15) 0.0430(5) Uani 1 1 d .
F3_3 F 0.08803(13) 0.43490(15) 0.21217(15) 0.0511(6) Uani 1 1 d .
F4_3 F 0.01122(10) 0.53977(15) 0.25760(14) 0.0514(6) Uani 1 1 d .
F5_3 F 0.07511(11) 0.66925(14) 0.35477(14) 0.0468(6) Uani 1 1 d .
F6_3 F 0.21264(10) 0.69182(12) 0.40576(13) 0.0353(4) Uani 1 1 d .
C1_3 C 0.22200(15) 0.5743(2) 0.3364(2) 0.0256(6) Uani 1 1 d .
C2_3 C 0.18836(17) 0.5091(2) 0.2867(2) 0.0284(7) Uani 1 1 d .
C3_3 C 0.11806(18) 0.4976(2) 0.2603(2) 0.0352(8) Uani 1 1 d .
C4_3 C 0.07972(15) 0.5518(2) 0.2825(2) 0.0351(8) Uani 1 1 d .
C5_3 C 0.11120(16) 0.6163(2) 0.3311(2) 0.0312(7) Uani 1 1 d .
C6_3 C 0.18200(16) 0.6282(2) 0.3576(2) 0.0264(7) Uani 1 1 d .
O1_4 O 0.37030(11) 0.03082(14) 0.48252(13) 0.0293(5) Uani 1 1 d .
H1_4 H 0.3722 0.0274 0.5330 0.044 Uiso 1 1 d R
F2_4 F 0.44492(9) 0.14051(12) 0.61369(12) 0.0321(4) Uani 1 1 d .
F3_4 F 0.50125(10) 0.26765(13) 0.57087(14) 0.0375(5) Uani 1 1 d .
F4_4 F 0.48863(11) 0.28828(13) 0.40162(15) 0.0433(5) Uani 1 1 d .
F5_4 F 0.41761(10) 0.17970(13) 0.27618(12) 0.0364(5) Uani 1 1 d .
F6_4 F 0.36179(9) 0.05235(12) 0.31944(12) 0.0314(4) Uani 1 1 d .
C1_4 C 0.40150(13) 0.09437(18) 0.46694(17) 0.0206(6) Uani 1 1 d .
C2_4 C 0.43811(14) 0.1506(2) 0.53007(18) 0.0242(6) Uani 1 1 d .
C3_4 C 0.46760(15) 0.2144(2) 0.5098(2) 0.0260(6) Uani 1 1 d .
C4_4 C 0.46067(15) 0.2247(2) 0.4234(2) 0.0286(7) Uani 1 1 d .
C5_4 C 0.42494(15) 0.1705(2) 0.35993(19) 0.0267(7) Uani 1 1 d .
C6_4 C 0.39646(14) 0.1056(2) 0.38178(18) 0.0223(6) Uani 1 1 d .
F1_5 F 0.38020(13) 0.37303(15) 0.48337(17) 0.0495(6) Uani 1 1 d .
F2_5 F 0.45136(11) 0.47983(13) 0.61186(13) 0.0413(6) Uani 1 1 d .
F3_5 F 0.50629(11) 0.60822(13) 0.57077(14) 0.0379(5) Uani 1 1 d .
O4_5 O 0.49731(13) 0.62995(16) 0.40544(17) 0.0372(6) Uani 1 1 d .
H1_5 H 0.4972 0.6366 0.3607 0.056 Uiso 1 1 d R
F5_5 F 0.42486(11) 0.52165(14) 0.27518(13) 0.0390(5) Uani 1 1 d .
F6_5 F 0.36773(11) 0.39387(14) 0.31602(14) 0.0416(6) Uani 1 1 d .
C1_5 C 0.40867(17) 0.4347(2) 0.4648(2) 0.0325(8) Uani 1 1 d .
C2_5 C 0.44456(16) 0.4903(2) 0.5283(2) 0.0303(8) Uani 1 1 d .
C3_5 C 0.47295(15) 0.5548(2) 0.5079(2) 0.0310(8) Uani 1 1 d .
C4_5 C 0.46832(16) 0.5676(2) 0.4219(2) 0.0310(7) Uani 1 1 d .
C5_5 C 0.43187(16) 0.5113(2) 0.3586(2) 0.0304(7) Uani 1 1 d .
C6_5 C 0.40345(15) 0.4465(2) 0.3801(2) 0.0299(8) Uani 1 1 d .
O1_6 O 0.36999(10) 0.69694(14) 0.47983(14) 0.0283(5) Uani 1 1 d .
H1_6 H 0.3719 0.6994 0.5344 0.043 Uiso 1 1 d R
F2_6 F 0.44517(9) 0.80530(13) 0.61321(12) 0.0331(4) Uani 1 1 d .
F3_6 F 0.50201(10) 0.93329(13) 0.57398(15) 0.0387(5) Uani 1 1 d .
F4_6 F 0.49001(11) 0.95655(13) 0.40508(15) 0.0418(5) Uani 1 1 d .
F5_6 F 0.41828(10) 0.85091(13) 0.27667(13) 0.0364(5) Uani 1 1 d .
F6_6 F 0.36211(10) 0.72241(13) 0.31685(12) 0.0331(4) Uani 1 1 d .
C1_6 C 0.40152(13) 0.76200(19) 0.46535(18) 0.0221(6) Uani 1 1 d .
C2_6 C 0.43837(13) 0.8163(2) 0.52940(18) 0.0241(6) Uani 1 1 d .
C3_6 C 0.46801(15) 0.8814(2) 0.5108(2) 0.0289(7) Uani 1 1 d .
C4_6 C 0.46180(15) 0.8935(2) 0.4249(2) 0.0287(7) Uani 1 1 d .
C5_6 C 0.42551(15) 0.8394(2) 0.3603(2) 0.0268(7) Uani 1 1 d .
C6_6 C 0.39643(14) 0.7748(2) 0.38000(19) 0.0227(6) Uani 1 1 d .
N1_7 N 0.36415(12) -0.01515(17) 0.63848(16) 0.0293(5) Uani 1 1 d .
H1_7 H 0.3760 0.0183 0.6777 0.044 Uiso 1 1 d R
H2_7 H 0.3864 -0.0595 0.6519 0.044 Uiso 1 1 d R
F2_7 F 0.30619(10) -0.15392(12) 0.54891(13) 0.0364(5) Uani 1 1 d .
F3_7 F 0.17032(10) -0.18729(12) 0.49268(13) 0.0348(4) Uani 1 1 d .
F4_7 F 0.08427(9) -0.08743(13) 0.52613(14) 0.0351(5) Uani 1 1 d .
F5_7 F 0.13719(10) 0.04593(13) 0.62035(14) 0.0378(5) Uani 1 1 d .
F6_7 F 0.27409(10) 0.07948(12) 0.67673(13) 0.0339(4) Uani 1 1 d .
C1_7 C 0.29385(14) -0.0363(2) 0.61391(17) 0.0233(6) Uani 1 1 d .
C2_7 C 0.26534(15) -0.1034(2) 0.56795(19) 0.0248(6) Uani 1 1 d .
C3_7 C 0.19590(16) -0.12206(19) 0.5387(2) 0.0247(6) Uani 1 1 d .
C4_7 C 0.15205(15) -0.0708(2) 0.5560(2) 0.0264(7) Uani 1 1 d .
C5_7 C 0.17888(15) -0.0032(2) 0.6025(2) 0.0257(6) Uani 1 1 d .
C6_7 C 0.24905(15) 0.0140(2) 0.63164(19) 0.0239(6) Uani 1 1 d .
O1_8 O 0.35922(12) 0.2982(2) 0.62914(19) 0.0548(9) Uani 1 1 d .
H1_8 H 0.3810 0.2569 0.6518 0.082 Uiso 1 1 calc R
F2_8 F 0.29546(12) 0.16771(15) 0.53720(16) 0.0511(7) Uani 1 1 d .
F3_8 F 0.15797(13) 0.14420(14) 0.48575(15) 0.0450(6) Uani 1 1 d .
F4_8 F 0.08074(10) 0.25315(14) 0.52800(15) 0.0427(6) Uani 1 1 d .
F5_8 F 0.14319(13) 0.38169(14) 0.62052(15) 0.0447(6) Uani 1 1 d .
F6_8 F 0.28166(14) 0.40583(14) 0.67215(16) 0.0538(7) Uani 1 1 d .
C1_8 C 0.29086(18) 0.2869(3) 0.6059(2) 0.0376(9) Uani 1 1 d .
C2_8 C 0.25873(18) 0.2212(2) 0.5589(2) 0.0346(8) Uani 1 1 d .
C3_8 C 0.18859(16) 0.2082(2) 0.5328(2) 0.0263(7) Uani 1 1 d .
C4_8 C 0.14916(16) 0.2632(2) 0.5537(2) 0.0254(7) Uani 1 1 d .
C5_8 C 0.18075(17) 0.3290(2) 0.6004(2) 0.0298(7) Uani 1 1 d .
C6_8 C 0.25171(18) 0.3411(2) 0.6271(2) 0.0321(8) Uani 1 1 d .
N1_9 N 0.36525(12) 0.65241(18) 0.63639(17) 0.0326(6) Uani 1 1 d .
H1_9 H 0.3755 0.6875 0.6764 0.049 Uiso 1 1 d R
H2_9 H 0.3894 0.6063 0.6480 0.049 Uiso 1 1 d R
F2_9 F 0.30830(10) 0.51286(13) 0.54798(14) 0.0394(5) Uani 1 1 d .
F3_9 F 0.17234(10) 0.47785(12) 0.49209(13) 0.0353(5) Uani 1 1 d .
F4_9 F 0.08591(9) 0.57725(13) 0.52715(14) 0.0377(5) Uani 1 1 d .
F5_9 F 0.13806(10) 0.71096(14) 0.61960(14) 0.0387(5) Uani 1 1 d .
F6_9 F 0.27467(10) 0.74651(12) 0.67526(13) 0.0352(4) Uani 1 1 d .
C1_9 C 0.29501(15) 0.6307(2) 0.61277(18) 0.0242(6) Uani 1 1 d .
C2_9 C 0.26732(15) 0.5625(2) 0.5672(2) 0.0270(6) Uani 1 1 d .
C3_9 C 0.19767(16) 0.5436(2) 0.53867(19) 0.0260(6) Uani 1 1 d .
C4_9 C 0.15378(15) 0.5942(2) 0.5560(2) 0.0267(7) Uani 1 1 d .
C5_9 C 0.17961(16) 0.6620(2) 0.6019(2) 0.0271(7) Uani 1 1 d .
C6_9 C 0.24995(15) 0.6795(2) 0.63070(19) 0.0246(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1_1 O1_1 H1_1 115.5
O1_1 C1_1 C6_1 122.1(3)
O1_1 C1_1 C2_1 118.6(3)
C6_1 C1_1 C2_1 119.3(3)
F2_1 C2_1 C3_1 119.9(3)
F2_1 C2_1 C1_1 119.6(3)
C3_1 C2_1 C1_1 120.5(3)
F3_1 C3_1 C4_1 120.4(3)
F3_1 C3_1 C2_1 119.3(3)
C4_1 C3_1 C2_1 120.3(3)
F4_1 C4_1 C5_1 119.6(3)
F4_1 C4_1 C3_1 120.3(3)
C5_1 C4_1 C3_1 120.1(3)
F5_1 C5_1 C4_1 121.4(3)
F5_1 C5_1 C6_1 118.4(3)
C4_1 C5_1 C6_1 120.2(3)
F6_1 C6_1 C1_1 121.0(3)
F6_1 C6_1 C5_1 119.3(3)
C1_1 C6_1 C5_1 119.6(3)
C4_2 N4_2 H1_2 121.5
C4_2 N4_2 H2_2 106.7
H1_2 N4_2 H2_2 108.8
F1_2 C1_2 C6_2 120.8(3)
F1_2 C1_2 C2_2 120.7(3)
C6_2 C1_2 C2_2 118.4(3)
F2_2 C2_2 C3_2 120.3(3)
F2_2 C2_2 C1_2 119.2(3)
C3_2 C2_2 C1_2 120.5(3)
F3_2 C3_2 C2_2 118.2(3)
F3_2 C3_2 C4_2 119.7(3)
C2_2 C3_2 C4_2 122.1(3)
N4_2 C4_2 C5_2 120.8(3)
N4_2 C4_2 C3_2 122.0(4)
C5_2 C4_2 C3_2 117.1(3)
F5_2 C5_2 C4_2 119.6(3)
F5_2 C5_2 C6_2 118.5(4)
C4_2 C5_2 C6_2 122.0(3)
F6_2 C6_2 C1_2 119.3(3)
F6_2 C6_2 C5_2 120.8(3)
C1_2 C6_2 C5_2 119.9(3)
C1_3 O1_3 H1_3 101.3
O1_3 C1_3 C6_3 123.5(3)
O1_3 C1_3 C2_3 118.9(3)
C6_3 C1_3 C2_3 117.7(3)
F2_3 C2_3 C3_3 119.6(3)
F2_3 C2_3 C1_3 119.2(3)
C3_3 C2_3 C1_3 121.3(3)
F3_3 C3_3 C4_3 120.9(3)
F3_3 C3_3 C2_3 119.2(4)
C4_3 C3_3 C2_3 119.9(3)
F4_3 C4_3 C5_3 120.2(3)
F4_3 C4_3 C3_3 119.6(3)
C5_3 C4_3 C3_3 120.2(3)
F5_3 C5_3 C4_3 121.3(3)
F5_3 C5_3 C6_3 118.6(3)
C4_3 C5_3 C6_3 120.1(3)
F6_3 C6_3 C5_3 119.7(3)
F6_3 C6_3 C1_3 119.4(3)
C5_3 C6_3 C1_3 120.9(3)
C1_4 O1_4 H1_4 115.5
O1_4 C1_4 C6_4 118.1(3)
O1_4 C1_4 C2_4 124.9(2)
C6_4 C1_4 C2_4 117.1(3)
F2_4 C2_4 C3_4 119.5(3)
F2_4 C2_4 C1_4 118.4(3)
C3_4 C2_4 C1_4 122.1(3)
F3_4 C3_4 C2_4 120.9(3)
F3_4 C3_4 C4_4 119.6(3)
C2_4 C3_4 C4_4 119.5(3)
F4_4 C4_4 C5_4 119.8(3)
F4_4 C4_4 C3_4 120.5(3)
C5_4 C4_4 C3_4 119.7(3)
F5_4 C5_4 C4_4 120.5(3)
F5_4 C5_4 C6_4 119.4(3)
C4_4 C5_4 C6_4 120.1(3)
F6_4 C6_4 C5_4 119.9(3)
F6_4 C6_4 C1_4 118.6(3)
C5_4 C6_4 C1_4 121.5(3)
C4_5 O4_5 H1_5 121.3
F1_5 C1_5 C6_5 120.6(3)
F1_5 C1_5 C2_5 122.0(3)
C6_5 C1_5 C2_5 117.5(3)
F2_5 C2_5 C3_5 119.7(3)
F2_5 C2_5 C1_5 118.8(3)
C3_5 C2_5 C1_5 121.5(3)
F3_5 C3_5 C2_5 119.8(3)
F3_5 C3_5 C4_5 118.4(3)
C2_5 C3_5 C4_5 121.8(3)
O4_5 C4_5 C5_5 124.1(3)
O4_5 C4_5 C3_5 119.8(3)
C5_5 C4_5 C3_5 116.1(3)
F5_5 C5_5 C6_5 120.1(3)
F5_5 C5_5 C4_5 118.4(3)
C6_5 C5_5 C4_5 121.5(3)
F6_5 C6_5 C5_5 119.3(3)
F6_5 C6_5 C1_5 119.0(3)
C5_5 C6_5 C1_5 121.7(3)
C1_6 O1_6 H1_6 108.7
O1_6 C1_6 C2_6 124.7(3)
O1_6 C1_6 C6_6 118.1(3)
C2_6 C1_6 C6_6 117.2(3)
F2_6 C2_6 C3_6 118.8(3)
F2_6 C2_6 C1_6 119.0(3)
C3_6 C2_6 C1_6 122.3(3)
F3_6 C3_6 C2_6 120.6(3)
F3_6 C3_6 C4_6 119.9(3)
C2_6 C3_6 C4_6 119.5(3)
F4_6 C4_6 C5_6 120.5(3)
F4_6 C4_6 C3_6 120.7(3)
C5_6 C4_6 C3_6 118.8(3)
F5_6 C5_6 C6_6 119.7(3)
F5_6 C5_6 C4_6 119.5(3)
C6_6 C5_6 C4_6 120.8(3)
F6_6 C6_6 C5_6 120.1(3)
F6_6 C6_6 C1_6 118.6(3)
C5_6 C6_6 C1_6 121.3(3)
C1_7 N1_7 H1_7 110.1
C1_7 N1_7 H2_7 104.2
H1_7 N1_7 H2_7 116.5
C2_7 C1_7 C6_7 116.8(3)
C2_7 C1_7 N1_7 122.7(3)
C6_7 C1_7 N1_7 120.4(3)
F2_7 C2_7 C1_7 119.3(3)
F2_7 C2_7 C3_7 117.6(3)
C1_7 C2_7 C3_7 123.1(3)
F3_7 C3_7 C2_7 120.9(3)
F3_7 C3_7 C4_7 119.9(3)
C2_7 C3_7 C4_7 119.2(3)
F4_7 C4_7 C5_7 121.0(3)
F4_7 C4_7 C3_7 119.7(3)
C5_7 C4_7 C3_7 119.3(3)
F5_7 C5_7 C4_7 119.7(3)
F5_7 C5_7 C6_7 119.9(3)
C4_7 C5_7 C6_7 120.4(3)
F6_7 C6_7 C5_7 119.6(3)
F6_7 C6_7 C1_7 119.3(3)
C5_7 C6_7 C1_7 121.1(3)
C1_8 O1_8 H1_8 109.5
O1_8 C1_8 C2_8 119.8(4)
O1_8 C1_8 C6_8 121.2(4)
C2_8 C1_8 C6_8 118.9(3)
F2_8 C2_8 C1_8 120.2(3)
F2_8 C2_8 C3_8 118.3(4)
C1_8 C2_8 C3_8 121.5(3)
F3_8 C3_8 C2_8 120.6(3)
F3_8 C3_8 C4_8 120.0(3)
C2_8 C3_8 C4_8 119.4(3)
F4_8 C4_8 C5_8 119.5(3)
F4_8 C4_8 C3_8 121.0(3)
C5_8 C4_8 C3_8 119.5(3)
F5_8 C5_8 C4_8 119.6(3)
F5_8 C5_8 C6_8 119.9(3)
C4_8 C5_8 C6_8 120.5(3)
F6_8 C6_8 C1_8 120.1(3)
F6_8 C6_8 C5_8 119.8(3)
C1_8 C6_8 C5_8 120.1(3)
C1_9 N1_9 H1_9 107.2
C1_9 N1_9 H2_9 105.3
H1_9 N1_9 H2_9 120.1
C2_9 C1_9 C6_9 116.8(3)
C2_9 C1_9 N1_9 121.9(3)
C6_9 C1_9 N1_9 121.3(3)
F2_9 C2_9 C1_9 119.6(3)
F2_9 C2_9 C3_9 118.1(3)
C1_9 C2_9 C3_9 122.2(3)
F3_9 C3_9 C4_9 120.0(3)
F3_9 C3_9 C2_9 120.4(3)
C4_9 C3_9 C2_9 119.6(3)
F4_9 C4_9 C5_9 120.1(3)
F4_9 C4_9 C3_9 120.1(3)
C5_9 C4_9 C3_9 119.8(3)
F5_9 C5_9 C4_9 120.4(3)
F5_9 C5_9 C6_9 120.0(3)
C4_9 C5_9 C6_9 119.6(3)
F6_9 C6_9 C1_9 118.9(3)
F6_9 C6_9 C5_9 119.1(3)
C1_9 C6_9 C5_9 122.0(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O1_1 C1_1 1.346(3)
O1_1 H1_1 1.1162
F2_1 C2_1 1.340(4)
F3_1 C3_1 1.346(4)
F4_1 C4_1 1.342(3)
F5_1 C5_1 1.346(4)
F6_1 C6_1 1.358(4)
C1_1 C6_1 1.381(4)
C1_1 C2_1 1.387(5)
C2_1 C3_1 1.377(4)
C3_1 C4_1 1.373(5)
C4_1 C5_1 1.367(5)
C5_1 C6_1 1.401(4)
F1_2 C1_2 1.329(4)
F2_2 C2_2 1.330(4)
F3_2 C3_2 1.349(4)
N4_2 C4_2 1.379(4)
N4_2 H1_2 0.8635
N4_2 H2_2 0.9399
F5_2 C5_2 1.345(4)
F6_2 C6_2 1.335(4)
C1_2 C6_2 1.384(4)
C1_2 C2_2 1.387(5)
C2_2 C3_2 1.378(4)
C3_2 C4_2 1.382(5)
C4_2 C5_2 1.377(6)
C5_2 C6_2 1.396(5)
O1_3 C1_3 1.351(4)
O1_3 H1_3 0.8920
F2_3 C2_3 1.335(4)
F3_3 C3_3 1.330(4)
F4_3 C4_3 1.348(3)
F5_3 C5_3 1.345(4)
F6_3 C6_3 1.345(4)
C1_3 C6_3 1.391(5)
C1_3 C2_3 1.393(5)
C2_3 C3_3 1.380(5)
C3_3 C4_3 1.378(5)
C4_3 C5_3 1.364(5)
C5_3 C6_3 1.390(4)
O1_4 C1_4 1.350(3)
O1_4 H1_4 0.8260
F2_4 C2_4 1.348(3)
F3_4 C3_4 1.327(4)
F4_4 C4_4 1.356(4)
F5_4 C5_4 1.344(3)
F6_4 C6_4 1.343(3)
C1_4 C6_4 1.388(4)
C1_4 C2_4 1.395(4)
C2_4 C3_4 1.365(4)
C3_4 C4_4 1.393(4)
C4_4 C5_4 1.370(5)
C5_4 C6_4 1.382(4)
F1_5 C1_5 1.312(4)
F2_5 C2_5 1.348(4)
F3_5 C3_5 1.345(4)
O4_5 C4_5 1.313(5)
O4_5 H1_5 0.7512
F5_5 C5_5 1.343(4)
F6_5 C6_5 1.358(4)
C1_5 C6_5 1.380(5)
C1_5 C2_5 1.388(5)
C2_5 C3_5 1.363(5)
C3_5 C4_5 1.409(5)
C4_5 C5_5 1.396(5)
C5_5 C6_5 1.376(5)
O1_6 C1_6 1.368(4)
O1_6 H1_6 0.8915
F2_6 C2_6 1.353(3)
F3_6 C3_6 1.333(4)
F4_6 C4_6 1.338(4)
F5_6 C5_6 1.348(3)
F6_6 C6_6 1.340(3)
C1_6 C2_6 1.382(4)
C1_6 C6_6 1.395(4)
C2_6 C3_6 1.373(5)
C3_6 C4_6 1.395(4)
C4_6 C5_6 1.381(5)
C5_6 C6_6 1.368(4)
N1_7 C1_7 1.417(3)
N1_7 H1_7 0.8235
N1_7 H2_7 0.8702
F2_7 C2_7 1.349(3)
F3_7 C3_7 1.332(4)
F4_7 C4_7 1.339(3)
F5_7 C5_7 1.339(3)
F6_7 C6_7 1.327(4)
C1_7 C2_7 1.370(4)
C1_7 C6_7 1.399(4)
C2_7 C3_7 1.380(4)
C3_7 C4_7 1.390(4)
C4_7 C5_7 1.373(5)
C5_7 C6_7 1.389(4)
O1_8 C1_8 1.348(4)
O1_8 H1_8 0.8400
F2_8 C2_8 1.343(4)
F3_8 C3_8 1.343(4)
F4_8 C4_8 1.340(4)
F5_8 C5_8 1.332(4)
F6_8 C6_8 1.338(4)
C1_8 C2_8 1.374(6)
C1_8 C6_8 1.382(5)
C2_8 C3_8 1.381(5)
C3_8 C4_8 1.393(4)
C4_8 C5_8 1.371(5)
C5_8 C6_8 1.394(5)
N1_9 C1_9 1.420(4)
N1_9 H1_9 0.8528
N1_9 H2_9 0.9152
F2_9 C2_9 1.344(4)
F3_9 C3_9 1.342(4)
F4_9 C4_9 1.344(3)
F5_9 C5_9 1.333(3)
F6_9 C6_9 1.345(4)
C1_9 C2_9 1.380(5)
C1_9 C6_9 1.389(4)
C2_9 C3_9 1.386(4)
C3_9 C4_9 1.385(4)
C4_9 C5_9 1.368(5)
C5_9 C6_9 1.394(4)
