#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:09:08 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180492 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/61/7216183.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7216183
loop_
_publ_author_name
'Gao, Yan-Qing'
'Zhang, Zhi-Ming'
'Shen, Jian-Qiang'
'Jia, Yue'
'Liu, Zhu-Jun'
'Wang, En-Bo'
_publ_section_title
;
 Self-assembly and thermotropic liquid crystal properties of a hexavacant
 germanomolybdate: [Ge2Mo16O58]12−
;
_journal_issue                   29
_journal_name_full               CrystEngComm
_journal_page_first              6784
_journal_paper_doi               10.1039/c4ce00536h
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'Ge2 H60 Mo16 Na12 O88'
_chemical_formula_weight         3424.58
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 103.62(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   21.051(4)
_cell_length_b                   15.483(3)
_cell_length_c                   13.472(3)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.482
_cell_measurement_theta_min      3.057
_cell_volume                     4267.5(16)
_computing_cell_refinement       auto
_computing_data_collection       auto
_computing_data_reduction        auto
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.01
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID IP'
_diffrn_measurement_method       Oscillation
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_unetI/netI     0.0306
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            20526
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.482
_diffrn_reflns_theta_min         3.057
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.142
_exptl_absorpt_correction_T_max  0.644
_exptl_absorpt_correction_T_min  0.556
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8 March, 1995'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3264
_exptl_crystal_size_max          0.190
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.140
_refine_diff_density_max         2.144
_refine_diff_density_min         -1.337
_refine_diff_density_rms         0.193
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     300
_refine_ls_number_reflns         5014
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0453
_refine_ls_R_factor_gt           0.0399
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0606P)²+66.5414P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1212
_refine_ls_wR_factor_ref         0.1237
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4582
_reflns_number_total             5014
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4ce00536h2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7216182--7216183.cif.'
_cod_original_cell_volume        4267.8(16)
_cod_database_code               7216183
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.587
_shelx_estimated_absorpt_t_max   0.667
_shelxl_version_number           2013-2
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mo1 Mo 0.5000 0.38345(4) 0.0000 0.01669(15) Uani 1 2 d S T P . .
Mo2 Mo 0.36244(3) 0.5000 -0.02650(5) 0.02409(17) Uani 1 2 d S T P . .
Mo3 Mo 0.37628(2) 0.37832(3) -0.26904(4) 0.02241(13) Uani 1 1 d . . . . .
Mo4 Mo 0.32988(3) 0.39430(3) 0.22146(4) 0.02313(14) Uani 1 1 d . . . . .
Mo5 Mo 0.48661(3) 0.27173(3) 0.25071(4) 0.02235(13) Uani 1 1 d . . . . .
Ge1 Ge 0.47831(4) 0.5000 0.21278(6) 0.01562(17) Uani 1 2 d S T P . .
O1 O 0.4675(3) 0.5000 0.0762(4) 0.0161(10) Uani 1 2 d S T P . .
O2 O 0.41683(19) 0.4120(3) -0.0870(3) 0.0201(8) Uani 1 1 d . . . . .
O3 O 0.4024(3) 0.5000 0.2432(4) 0.0203(11) Uani 1 2 d S T P . .
O4 O 0.2811(3) 0.5000 0.1835(5) 0.0257(12) Uani 1 2 d S T P . .
O5 O 0.3677(3) 0.5000 -0.2685(5) 0.0246(12) Uani 1 2 d S T P . .
O6 O 0.4745(2) 0.3153(3) 0.0839(3) 0.0220(8) Uani 1 1 d . . . . .
O7 O 0.3439(2) 0.4143(3) 0.0576(3) 0.0271(9) Uani 1 1 d . . . . .
O8 O 0.3294(3) 0.3938(3) 0.3491(4) 0.0366(11) Uani 1 1 d . . . . .
O9 O 0.3556(2) 0.3625(3) -0.3980(3) 0.0342(10) Uani 1 1 d . . . . .
O10 O 0.4243(2) 0.2714(3) -0.2322(3) 0.0251(9) Uani 1 1 d . . . . .
O11 O 0.52181(19) 0.5926(3) 0.2629(3) 0.0210(8) Uani 1 1 d . . . . .
O12 O 0.5029(3) 0.2608(3) 0.3804(4) 0.0378(11) Uani 1 1 d . . . . .
O13 O 0.2942(3) 0.5000 -0.1210(5) 0.0283(13) Uani 1 2 d S T P . .
O14 O 0.4036(2) 0.3216(3) 0.2267(3) 0.0278(9) Uani 1 1 d . . . . .
O15 O 0.4671(3) 0.1689(3) 0.2061(4) 0.0355(11) Uani 1 1 d . . . . .
O16 O 0.2682(2) 0.3248(3) 0.1688(4) 0.0382(11) Uani 1 1 d . . . . .
O17 O 0.3079(2) 0.3461(3) -0.2304(4) 0.0334(10) Uani 1 1 d . . . . .
Na1 Na 0.2606(2) 0.3542(3) 0.4577(3) 0.0663(10) Uani 1 1 d . . . . .
Na2 Na 0.1666(3) 0.2571(4) 0.0072(5) 0.1066(19) Uani 1 1 d . . . . .
Na3 Na 0.08312(18) 0.5000 0.0610(3) 0.0338(8) Uani 1 2 d S T P . .
Na4 Na 0.5505(3) 0.3868(4) 0.5089(5) 0.0388(14) Uani 0.5 1 d . . P A 1
O11W O 0.5656(9) 0.4485(14) 0.5069(12) 0.099(6) Uani 0.5 1 d . U P B 2
O1W O 0.1853(3) 0.3648(4) -0.1570(6) 0.0619(18) Uani 1 1 d . . . . .
O2W O -0.0197(4) 0.5000 0.1148(6) 0.0385(16) Uani 1 2 d S T P . .
O3W O 0.0665(3) 0.3473(3) 0.0613(4) 0.0413(12) Uani 1 1 d . . . . .
O4W O 0.1574(4) 0.5000 0.2257(6) 0.0482(19) Uani 1 2 d S T P . .
O5W O 0.1800(4) 0.5000 -0.0059(7) 0.054(2) Uani 1 2 d S T P . .
O6W O 0.2036(10) 0.5000 0.6804(13) 0.140(7) Uani 1 2 d S T P . .
O7W O 0.2836(4) 0.2140(5) 0.4132(6) 0.075(2) Uani 1 1 d . . . . .
O8W O 0.1532(5) 0.3590(5) 0.3484(7) 0.094(3) Uani 1 1 d . U . . .
O9W O 0.2474(8) 0.5000 0.4980(13) 0.113(5) Uani 1 2 d S TU P . .
O10W O 0.4107(7) 0.1500(11) 0.4694(15) 0.085(5) Uani 0.5 1 d . U P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Mo1 O6 104.4(3) 2_655 .
O6 Mo1 O2 96.95(18) 2_655 .
O6 Mo1 O2 99.34(18) . .
O6 Mo1 O2 99.35(18) 2_655 2_655
O6 Mo1 O2 96.95(18) . 2_655
O2 Mo1 O2 153.3(2) . 2_655
O6 Mo1 O1 90.97(17) 2_655 5_665
O6 Mo1 O1 164.12(17) . 5_665
O2 Mo1 O1 82.44(18) . 5_665
O2 Mo1 O1 76.26(17) 2_655 5_665
O6 Mo1 O1 164.12(17) 2_655 .
O6 Mo1 O1 90.97(17) . .
O2 Mo1 O1 76.26(17) . .
O2 Mo1 O1 82.43(18) 2_655 .
O1 Mo1 O1 74.0(2) 5_665 .
O13 Mo2 O7 101.4(2) . .
O13 Mo2 O7 101.4(2) . 6_565
O7 Mo2 O7 91.9(3) . 6_565
O13 Mo2 O2 98.91(19) . 6_565
O7 Mo2 O2 158.96(18) . 6_565
O7 Mo2 O2 89.18(18) 6_565 6_565
O13 Mo2 O2 98.91(19) . .
O7 Mo2 O2 89.18(18) . .
O7 Mo2 O2 158.96(18) 6_565 .
O2 Mo2 O2 82.5(2) 6_565 .
O13 Mo2 O1 168.0(2) . .
O7 Mo2 O1 86.80(17) . .
O7 Mo2 O1 86.80(17) 6_565 .
O2 Mo2 O1 72.28(14) 6_565 .
O2 Mo2 O1 72.28(14) . .
O9 Mo3 O17 103.6(2) . .
O9 Mo3 O5 98.3(2) . .
O17 Mo3 O5 101.6(2) . .
O9 Mo3 O10 97.5(2) . .
O17 Mo3 O10 95.6(2) . .
O5 Mo3 O10 153.1(2) . .
O9 Mo3 O11 94.7(2) . 5_665
O17 Mo3 O11 159.91(19) . 5_665
O5 Mo3 O11 83.6(2) . 5_665
O10 Mo3 O11 73.54(16) . 5_665
O9 Mo3 O2 173.08(19) . .
O17 Mo3 O2 83.01(19) . .
O5 Mo3 O2 78.2(2) . .
O10 Mo3 O2 83.60(16) . .
O11 Mo3 O2 79.05(14) 5_665 .
O16 Mo4 O8 103.3(2) . .
O16 Mo4 O14 100.1(2) . .
O8 Mo4 O14 99.0(2) . .
O16 Mo4 O4 96.8(2) . .
O8 Mo4 O4 98.1(2) . .
O14 Mo4 O4 152.4(2) . .
O16 Mo4 O3 162.9(2) . .
O8 Mo4 O3 92.1(2) . .
O14 Mo4 O3 84.35(17) . .
O4 Mo4 O3 73.49(18) . .
O16 Mo4 O7 86.7(2) . .
O8 Mo4 O7 169.9(2) . .
O14 Mo4 O7 80.17(18) . .
O4 Mo4 O7 79.2(2) . .
O3 Mo4 O7 77.79(18) . .
O12 Mo5 O15 103.9(2) . .
O12 Mo5 O14 99.9(2) . .
O15 Mo5 O14 100.7(2) . .
O12 Mo5 O10 99.4(2) . 2_655
O15 Mo5 O10 96.3(2) . 2_655
O14 Mo5 O10 150.24(18) . 2_655
O12 Mo5 O11 92.0(2) . 6_565
O15 Mo5 O11 161.97(19) . 6_565
O14 Mo5 O11 84.51(17) . 6_565
O10 Mo5 O11 72.40(16) 2_655 6_565
O12 Mo5 O6 167.7(2) . .
O15 Mo5 O6 88.1(2) . .
O14 Mo5 O6 79.98(17) . .
O10 Mo5 O6 76.38(16) 2_655 .
O11 Mo5 O6 75.71(14) 6_565 .
O3 Ge1 O11 109.59(16) . .
O3 Ge1 O11 109.59(16) . 6_565
O11 Ge1 O11 110.1(3) . 6_565
O3 Ge1 O1 109.8(3) . .
O11 Ge1 O1 108.85(16) . .
O11 Ge1 O1 108.85(16) 6_565 .
Ge1 O1 Mo1 119.02(15) . .
Ge1 O1 Mo1 119.02(15) . 5_665
Mo1 O1 Mo1 106.0(2) . 5_665
Ge1 O1 Mo2 118.9(3) . .
Mo1 O1 Mo2 94.44(15) . .
Mo1 O1 Mo2 94.44(15) 5_665 .
Mo1 O2 Mo2 114.99(18) . .
Mo1 O2 Mo3 127.94(19) . .
Mo2 O2 Mo3 116.07(17) . .
Ge1 O3 Mo4 127.77(14) . .
Ge1 O3 Mo4 127.77(14) . 6_565
Mo4 O3 Mo4 95.5(2) . 6_565
Mo4 O4 Mo4 115.4(3) . 6_565
Mo3 O5 Mo3 168.9(4) 6_565 .
Mo1 O6 Mo5 147.2(2) . .
Mo2 O7 Mo4 140.7(2) . .
Mo2 O7 Na2 120.4(2) . 7
Mo4 O7 Na2 98.8(2) . 7
Mo4 O8 Na1 140.0(3) . .
Mo4 O8 Na4 117.9(3) . 2_656
Na1 O8 Na4 98.8(2) . 2_656
Mo3 O9 Na1 141.5(3) . 1_554
Mo3 O9 Na4 119.1(3) . 2_655
Na1 O9 Na4 97.6(2) 1_554 2_655
Mo3 O10 Mo5 115.1(2) . 2_655
Ge1 O11 Mo3 127.3(2) . 5_665
Ge1 O11 Mo5 127.7(2) . 6_565
Mo3 O11 Mo5 96.68(16) 5_665 6_565
Mo5 O12 Na4 123.4(3) . .
Mo5 O12 Na4 117.4(3) . 2_656
Na4 O12 Na4 44.4(3) . 2_656
Mo5 O14 Mo4 166.3(3) . .
Mo4 O16 Na2 154.8(3) . .
O7W Na1 O9W 174.1(5) . .
O7W Na1 O8 83.6(3) . .
O9W Na1 O8 91.0(5) . .
O7W Na1 O8W 95.4(3) . .
O9W Na1 O8W 88.1(5) . .
O8 Na1 O8W 103.8(3) . .
O7W Na1 O7W 85.2(3) . 7_556
O9W Na1 O7W 99.6(5) . 7_556
O8 Na1 O7W 163.5(3) . 7_556
O8W Na1 O7W 89.3(3) . 7_556
O7W Na1 O9 94.2(3) . 1_556
O9W Na1 O9 83.4(4) . 1_556
O8 Na1 O9 88.5(2) . 1_556
O8W Na1 O9 165.2(3) . 1_556
O7W Na1 O9 80.3(2) 7_556 1_556
O7W Na1 Na1 43.4(2) . 7_556
O9W Na1 Na1 141.4(5) . 7_556
O8 Na1 Na1 125.9(3) . 7_556
O8W Na1 Na1 93.1(3) . 7_556
O7W Na1 Na1 41.8(2) 7_556 7_556
O9 Na1 Na1 86.1(2) 1_556 7_556
O7W Na1 Na4 83.3(2) . 2_656
O9W Na1 Na4 91.2(4) . 2_656
O8 Na1 Na4 44.60(18) . 2_656
O8W Na1 Na4 148.4(3) . 2_656
O7W Na1 Na4 121.9(3) 7_556 2_656
O9 Na1 Na4 44.36(16) 1_556 2_656
Na1 Na1 Na4 106.6(2) 7_556 2_656
O3W Na2 O7 123.7(3) . 7
O3W Na2 O16 95.4(2) . .
O7 Na2 O16 125.2(3) 7 .
O3W Na2 O1W 99.3(3) . .
O7 Na2 O1W 109.1(3) 7 .
O16 Na2 O1W 99.2(3) . .
O3W Na2 Na2 150.0(3) . 7
O7 Na2 Na2 86.0(2) 7 7
O16 Na2 Na2 59.75(19) . 7
O1W Na2 Na2 71.3(3) . 7
O3W Na3 O3W 163.1(3) 6_565 .
O3W Na3 O4W 93.58(17) 6_565 .
O3W Na3 O4W 93.58(17) . .
O3W Na3 O5W 97.92(16) 6_565 .
O3W Na3 O5W 97.92(16) . .
O4W Na3 O5W 85.5(3) . .
O3W Na3 O2W 87.39(17) 6_565 5_565
O3W Na3 O2W 87.39(17) . 5_565
O4W Na3 O2W 172.9(3) . 5_565
O5W Na3 O2W 87.4(3) . 5_565
O3W Na3 O2W 81.87(16) 6_565 .
O3W Na3 O2W 81.87(16) . .
O4W Na3 O2W 99.0(3) . .
O5W Na3 O2W 175.5(3) . .
O2W Na3 O2W 88.1(3) 5_565 .
O3W Na3 Na3 82.52(16) 6_565 5_565
O3W Na3 Na3 82.52(16) . 5_565
O4W Na3 Na3 142.9(3) . 5_565
O5W Na3 Na3 131.6(3) . 5_565
O2W Na3 Na3 44.2(2) 5_565 5_565
O2W Na3 Na3 44.0(2) . 5_565
Na4 Na4 O12 72.9(3) 2_656 .
Na4 Na4 O9 140.9(5) 2_656 2_655
O12 Na4 O9 75.8(2) . 2_655
Na4 Na4 O8 144.6(5) 2_656 2_656
O12 Na4 O8 128.3(3) . 2_656
O9 Na4 O8 74.2(2) 2_655 2_656
Na4 Na4 O12 62.8(3) 2_656 2_656
O12 Na4 O12 72.6(2) . 2_656
O9 Na4 O12 127.6(3) 2_655 2_656
O8 Na4 O12 94.2(2) 2_656 2_656
Na4 Na4 Na4 90.000(1) 2_656 6_565
O12 Na4 Na4 137.55(18) . 6_565
O9 Na4 Na4 97.81(17) 2_655 6_565
O8 Na4 Na4 87.76(18) 2_656 6_565
O12 Na4 Na4 133.36(17) 2_656 6_565
Na4 Na4 Na1 172.62(12) 2_656 2_656
O12 Na4 Na1 101.4(2) . 2_656
O9 Na4 Na1 38.04(14) 2_655 2_656
O8 Na4 Na1 36.58(14) 2_656 2_656
O12 Na4 Na1 111.5(2) 2_656 2_656
Na4 Na4 Na1 97.38(12) 6_565 2_656
Na4 Na4 Na4 59.31(17) 2_656 5_666
O12 Na4 Na4 119.0(3) . 5_666
O9 Na4 Na4 120.9(3) 2_655 5_666
O8 Na4 Na4 112.5(3) 2_656 5_666
O12 Na4 Na4 110.9(3) 2_656 5_666
Na4 Na4 Na4 30.69(17) 6_565 5_666
Na1 Na4 Na4 128.1(2) 2_656 5_666
Na3 O2W Na3 91.9(3) 5_565 .
Na3 O3W Na2 112.2(2) . .
Na1 O7W Na1 94.8(3) . 7_556
Na1 O9W Na1 147.1(9) 6_565 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mo1 O6 1.721(4) 2_655
Mo1 O6 1.721(4) .
Mo1 O2 1.916(4) .
Mo1 O2 1.916(4) 2_655
Mo1 O1 2.260(3) 5_665
Mo1 O1 2.260(3) .
Mo2 O13 1.680(6) .
Mo2 O7 1.845(4) .
Mo2 O7 1.845(4) 6_565
Mo2 O2 2.066(4) 6_565
Mo2 O2 2.066(4) .
Mo2 O1 2.316(5) .
Mo3 O9 1.706(5) .
Mo3 O17 1.716(5) .
Mo3 O5 1.8930(9) .
Mo3 O10 1.943(4) .
Mo3 O11 2.174(4) 5_665
Mo3 O2 2.456(4) .
Mo4 O16 1.706(5) .
Mo4 O8 1.721(5) .
Mo4 O14 1.904(4) .
Mo4 O4 1.936(3) .
Mo4 O3 2.210(4) .
Mo4 O7 2.316(4) .
Mo5 O12 1.708(5) .
Mo5 O15 1.718(5) .
Mo5 O14 1.868(4) .
Mo5 O10 1.948(4) 2_655
Mo5 O11 2.220(4) 6_565
Mo5 O6 2.303(4) .
Ge1 O3 1.741(5) .
Ge1 O11 1.749(4) .
Ge1 O11 1.749(4) 6_565
Ge1 O1 1.801(5) .
O1 Mo1 2.260(3) 5_665
O3 Mo4 2.210(4) 6_565
O4 Mo4 1.936(3) 6_565
O5 Mo3 1.8929(9) 6_565
O7 Na2 2.787(7) 7
O8 Na1 2.369(6) .
O8 Na4 2.791(8) 2_656
O9 Na1 2.442(6) 1_554
O9 Na4 2.771(8) 2_655
O10 Mo5 1.948(4) 2_655
O11 Mo3 2.174(4) 5_665
O11 Mo5 2.220(4) 6_565
O12 Na4 2.644(8) .
O12 Na4 2.842(8) 2_656
O16 Na2 2.867(8) .
Na1 O7W 2.334(10) .
Na1 O9W 2.353(7) .
Na1 O8W 2.392(9) .
Na1 O7W 2.403(8) 7_556
Na1 O9 2.442(6) 1_556
Na1 Na1 3.487(9) 7_556
Na1 Na4 3.928(8) 2_656
Na2 O3W 2.766(8) .
Na2 O7 2.787(7) 7
Na2 O1W 2.870(10) .
Na2 Na2 3.568(12) 7
Na3 O3W 2.390(5) 6_565
Na3 O3W 2.390(5) .
Na3 O4W 2.395(9) .
Na3 O5W 2.415(9) .
Na3 O2W 2.430(9) 5_565
Na3 O2W 2.439(8) .
Na3 Na3 3.498(8) 5_565
Na4 Na4 2.081(12) 2_656
Na4 O9 2.771(8) 2_655
Na4 O8 2.791(8) 2_656
Na4 O12 2.842(8) 2_656
Na4 Na4 3.506(14) 6_565
Na4 Na1 3.928(8) 2_656
Na4 Na4 4.077(14) 5_666
O11W O11W 1.59(4) 6_565
O2W Na3 2.430(9) 5_565
O7W Na1 2.403(8) 7_556
O9W Na1 2.353(7) 6_565
