#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:18:41 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180499 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/68/7216852.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7216852
loop_
_publ_author_name
'Hu, Ting'
'Yang, Jin'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of organometallic networks with multinuclear
 silver(i)--ethynediide supramolecular synthon, trifluoroacetate and
 ligands derived from isomeric dicyanobenzenes
;
_journal_issue                   28
_journal_name_full               CrystEngComm
_journal_page_first              6316
_journal_paper_doi               10.1039/c3ce41671b
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C56 H16 Ag15 F30 N9 O23'
_chemical_formula_weight         3370.83
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 119.6360(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.8943(9)
_cell_length_b                   26.2204(12)
_cell_length_c                   17.9454(13)
_cell_measurement_reflns_used    63659
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.94
_cell_measurement_theta_min      2.28
_cell_volume                     8136.4(8)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0747
_diffrn_reflns_av_sigmaI/netI    0.0492
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            56209
_diffrn_reflns_theta_full        27.98
_diffrn_reflns_theta_max         27.98
_diffrn_reflns_theta_min         1.41
_exptl_absorpt_coefficient_mu    3.664
_exptl_absorpt_correction_T_max  0.7108
_exptl_absorpt_correction_T_min  0.5584
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.752
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             6296
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.459
_refine_diff_density_min         -2.238
_refine_diff_density_rms         0.491
_refine_ls_extinction_coef       0.00045(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     630
_refine_ls_number_reflns         9793
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0623
_refine_ls_R_factor_gt           0.0540
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1057P)²+25.0297P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1477
_refine_ls_wR_factor_ref         0.1573
_reflns_number_gt                8515
_reflns_number_total             9793
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41671b.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7216852
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.13908(2) 1.054775(18) 0.20142(3) 0.03699(13) Uani 1 1 d .
Ag2 Ag 1.0000 1.06328(3) 0.2500 0.04428(18) Uani 1 2 d S
Ag3 Ag 0.85293(3) 1.062475(17) 0.06745(3) 0.04096(14) Uani 1 1 d .
Ag4 Ag 0.88510(2) 0.964186(17) 0.13011(3) 0.03828(14) Uani 1 1 d .
Ag5 Ag 1.04091(3) 0.935986(17) 0.15269(3) 0.04115(14) Uani 1 1 d .
Ag6 Ag 1.08234(2) 1.004428(18) 0.04173(3) 0.03632(13) Uani 1 1 d .
Ag7 Ag 1.00439(3) 1.109960(16) 0.07575(3) 0.03634(13) Uani 1 1 d .
Ag8 Ag 0.76198(3) 0.851246(19) 0.10425(4) 0.04542(15) Uani 1 1 d .
C1 C 0.9614(3) 1.0174(2) 0.1181(3) 0.0276(10) Uani 1 1 d .
C2 C 1.0224(3) 1.0256(2) 0.1170(4) 0.0295(10) Uani 1 1 d .
C3 C 1.1347(3) 1.1525(2) 0.2983(4) 0.0318(11) Uani 1 1 d .
C4 C 1.1596(5) 1.2076(3) 0.3323(6) 0.0587(19) Uani 1 1 d .
C5 C 0.7427(4) 0.9794(3) 0.1434(4) 0.0432(14) Uani 1 1 d .
C6 C 0.6561(6) 0.9709(4) 0.1174(8) 0.080(3) Uani 1 1 d .
C7 C 0.8845(3) 0.8688(2) 0.0223(4) 0.0337(11) Uani 1 1 d .
C8 C 0.8565(5) 0.8171(3) -0.0242(5) 0.0523(17) Uani 1 1 d .
C9 C 1.1652(4) 0.8887(3) 0.1318(5) 0.0470(15) Uani 1 1 d .
C10 C 1.2366(8) 0.8561(5) 0.1549(8) 0.097(3) Uani 1 1 d U
C11 C 1.2503(3) 1.0379(2) 0.1199(3) 0.0301(10) Uani 1 1 d .
C12 C 1.3320(4) 1.0397(3) 0.1284(4) 0.0473(15) Uani 1 1 d .
C13 C 0.6794(4) 1.1130(2) -0.0098(4) 0.0378(12) Uani 1 1 d .
C14 C 0.6045(3) 1.1366(2) -0.0554(4) 0.0370(12) Uani 1 1 d .
C15 C 0.5417(4) 1.1077(3) -0.1091(5) 0.0505(16) Uani 1 1 d .
H15 H 0.5471 1.0730 -0.1156 0.061 Uiso 1 1 calc R
C16 C 0.4699(4) 1.1311(3) -0.1539(6) 0.063(2) Uani 1 1 d .
H16 H 0.4269 1.1117 -0.1903 0.075 Uiso 1 1 calc R
C17 C 0.4613(4) 1.1812(3) -0.1454(5) 0.0568(19) Uani 1 1 d .
H17 H 0.4127 1.1961 -0.1757 0.068 Uiso 1 1 calc R
C18 C 0.5259(3) 1.2114(2) -0.0907(4) 0.0399(13) Uani 1 1 d .
C19 C 0.5981(3) 1.1884(2) -0.0455(4) 0.0351(11) Uani 1 1 d .
H19 H 0.6415 1.2076 -0.0093 0.042 Uiso 1 1 calc R
C20 C 0.5175(4) 1.2647(2) -0.0848(5) 0.0475(15) Uani 1 1 d .
C21 C 0.5760(4) 0.8349(2) -0.0488(5) 0.0473(15) Uani 1 1 d .
C22 C 0.4946(3) 0.8341(2) -0.1072(4) 0.0386(12) Uani 1 1 d .
C23 C 0.4499(4) 0.8758(2) -0.1100(4) 0.0417(13) Uani 1 1 d .
H23 H 0.4733 0.9037 -0.0744 0.050 Uiso 1 1 calc R
C24 C 0.3707(4) 0.8757(3) -0.1658(4) 0.0456(14) Uani 1 1 d .
H24 H 0.3411 0.9037 -0.1679 0.055 Uiso 1 1 calc R
C25 C 0.3356(4) 0.8339(3) -0.2186(4) 0.0421(13) Uani 1 1 d .
H25 H 0.2824 0.8332 -0.2549 0.051 Uiso 1 1 calc R
C26 C 0.3812(4) 0.7933(2) -0.2162(4) 0.0409(13) Uani 1 1 d .
C27 C 0.4610(4) 0.7922(2) -0.1597(4) 0.0407(13) Uani 1 1 d .
H27 H 0.4906 0.7642 -0.1575 0.049 Uiso 1 1 calc R
C28 C 0.3456(4) 0.7500(3) -0.2720(5) 0.0515(16) Uani 1 1 d .
F1 F 1.2078(7) 1.2261(3) 0.3137(9) 0.201(7) Uani 1 1 d .
F2 F 1.1001(4) 1.23923(18) 0.3014(4) 0.0816(17) Uani 1 1 d .
F3 F 1.1869(4) 1.2097(2) 0.4158(4) 0.108(3) Uani 1 1 d .
F4 F 0.6267(4) 0.9286(3) 0.0777(6) 0.123(3) Uani 1 1 d .
F5 F 0.6458(6) 0.9742(3) 0.1828(7) 0.154(5) Uani 1 1 d .
F6 F 0.6113(4) 1.0098(3) 0.0627(8) 0.137(4) Uani 1 1 d .
F7 F 0.7939(6) 0.8022(4) -0.0298(7) 0.168(5) Uani 1 1 d .
F8 F 0.9119(6) 0.78230(19) 0.0170(4) 0.136(4) Uani 1 1 d .
F9 F 0.8468(3) 0.81795(19) -0.1020(3) 0.0640(12) Uani 1 1 d .
F10 F 1.2713(4) 0.8375(3) 0.2301(4) 0.115(3) Uani 1 1 d .
F11 F 1.2347(6) 0.8293(3) 0.0966(6) 0.119(3) Uani 1 1 d .
F12 F 1.2977(4) 0.8933(5) 0.1631(5) 0.141(4) Uani 1 1 d .
F13 F 1.3386(8) 1.0116(7) 0.0718(11) 0.081(5) Uani 0.50 1 d P
F14 F 1.3845(6) 1.0267(9) 0.2028(9) 0.086(5) Uani 0.50 1 d P
F15 F 1.3467(9) 1.0847(6) 0.1124(16) 0.102(6) Uani 0.50 1 d P
F13' F 1.3689(8) 0.9936(6) 0.1618(12) 0.086(4) Uani 0.50 1 d P
F14' F 1.3774(8) 1.0718(9) 0.1783(14) 0.100(6) Uani 0.50 1 d P
F15' F 1.3305(9) 1.0433(8) 0.0571(10) 0.082(5) Uani 0.50 1 d P
N1 N 0.7388(3) 1.0949(2) 0.0246(4) 0.0459(12) Uani 1 1 d .
N2 N 0.5100(3) 1.3079(2) -0.0826(4) 0.0475(13) Uani 1 1 d .
N3 N 0.6403(4) 0.8362(2) -0.0006(5) 0.0642(19) Uani 1 1 d .
N4 N 0.3173(4) 0.7162(2) -0.3143(5) 0.0646(19) Uani 1 1 d .
N5 N 1.0000 0.8553(3) 0.2500 0.0453(18) Uani 1 2 d S
O1 O 1.1644(3) 1.13583(16) 0.2580(3) 0.0434(10) Uani 1 1 d .
O2 O 1.0880(3) 1.13267(18) 0.3170(3) 0.0425(9) Uani 1 1 d .
O3 O 0.7650(3) 1.02228(19) 0.1687(3) 0.0553(13) Uani 1 1 d .
O4 O 0.7757(3) 0.94282(18) 0.1308(3) 0.0480(11) Uani 1 1 d .
O5 O 0.8532(3) 0.88369(17) 0.0630(3) 0.0418(10) Uani 1 1 d .
O6 O 0.9382(3) 0.88984(16) 0.0165(3) 0.0398(9) Uani 1 1 d .
O7 O 1.1536(4) 0.8962(3) 0.1920(4) 0.0709(18) Uani 1 1 d .
O8 O 1.1279(3) 0.9033(2) 0.0564(3) 0.0486(11) Uani 1 1 d .
O9 O 1.2041(2) 1.00790(17) 0.0637(3) 0.0424(10) Uani 1 1 d .
O10 O 1.2408(3) 1.0658(2) 0.1685(3) 0.0514(12) Uani 1 1 d .
O11 O 1.0000 0.9042(2) 0.2500 0.0383(12) Uani 1 2 d S
O12 O 0.9882(4) 0.8327(2) 0.3031(4) 0.0734(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 Ag1 O1 123.63(18) . .
C2 Ag1 O3 129.1(2) . 2_755
O1 Ag1 O3 90.25(18) . 2_755
C2 Ag1 O10 127.53(19) . .
O1 Ag1 O10 88.25(16) . .
O3 Ag1 O10 85.2(2) 2_755 .
C2 Ag1 Ag6 51.77(14) . .
O1 Ag1 Ag6 140.09(12) . .
O3 Ag1 Ag6 124.22(13) 2_755 .
O10 Ag1 Ag6 76.66(11) . .
C2 Ag1 Ag7 51.61(14) . .
O1 Ag1 Ag7 78.36(13) . .
O3 Ag1 Ag7 161.62(14) 2_755 .
O10 Ag1 Ag7 108.52(15) . .
Ag6 Ag1 Ag7 72.102(17) . .
C2 Ag1 Ag2 57.65(14) . .
O1 Ag1 Ag2 81.38(11) . .
O3 Ag1 Ag2 98.04(15) 2_755 .
O10 Ag1 Ag2 169.12(13) . .
Ag6 Ag1 Ag2 109.419(16) . .
Ag7 Ag1 Ag2 66.258(14) . .
O2 Ag2 O2 81.1(2) . 2_755
O2 Ag2 C1 132.00(17) . .
O2 Ag2 C1 94.97(16) 2_755 .
O2 Ag2 C1 94.97(16) . 2_755
O2 Ag2 C1 132.01(16) 2_755 2_755
C1 Ag2 C1 120.3(3) . 2_755
O2 Ag2 Ag3 53.66(11) . 2_755
O2 Ag2 Ag3 127.07(11) 2_755 2_755
C1 Ag2 Ag3 134.52(12) . 2_755
C1 Ag2 Ag3 44.94(11) 2_755 2_755
O2 Ag2 Ag3 127.07(11) . .
O2 Ag2 Ag3 53.66(11) 2_755 .
C1 Ag2 Ag3 44.94(11) . .
C1 Ag2 Ag3 134.52(12) 2_755 .
Ag3 Ag2 Ag3 179.23(3) 2_755 .
O2 Ag2 Ag1 114.79(11) . 2_755
O2 Ag2 Ag1 71.55(11) 2_755 2_755
C1 Ag2 Ag1 108.88(12) . 2_755
C1 Ag2 Ag1 66.99(12) 2_755 2_755
Ag3 Ag2 Ag1 101.254(12) 2_755 2_755
Ag3 Ag2 Ag1 78.693(13) . 2_755
O2 Ag2 Ag1 71.54(11) . .
O2 Ag2 Ag1 114.79(11) 2_755 .
C1 Ag2 Ag1 66.99(12) . .
C1 Ag2 Ag1 108.88(12) 2_755 .
Ag3 Ag2 Ag1 78.693(13) 2_755 .
Ag3 Ag2 Ag1 101.255(13) . .
Ag1 Ag2 Ag1 172.24(3) 2_755 .
N1 Ag3 C1 169.7(2) . .
N1 Ag3 O2 89.21(19) . 2_755
C1 Ag3 O2 94.92(16) . 2_755
N1 Ag3 O8 97.55(19) . 5_775
C1 Ag3 O8 90.61(17) . 5_775
O2 Ag3 O8 103.88(16) 2_755 5_775
N1 Ag3 Ag4 120.03(16) . .
C1 Ag3 Ag4 49.73(14) . .
O2 Ag3 Ag4 114.66(11) 2_755 .
O8 Ag3 Ag4 124.77(12) 5_775 .
N1 Ag3 Ag2 129.65(16) . .
C1 Ag3 Ag2 50.18(13) . .
O2 Ag3 Ag2 48.40(10) 2_755 .
O8 Ag3 Ag2 115.89(10) 5_775 .
Ag4 Ag3 Ag2 70.81(2) . .
N1 Ag3 Ag7 131.19(16) . .
C1 Ag3 Ag7 59.04(14) . .
O2 Ag3 Ag7 68.90(10) 2_755 .
O8 Ag3 Ag7 50.97(10) 5_775 .
Ag4 Ag3 Ag7 108.772(17) . .
Ag2 Ag3 Ag7 64.976(14) . .
N1 Ag3 Ag6 129.62(16) . 5_775
C1 Ag3 Ag6 51.73(13) . 5_775
O2 Ag3 Ag6 133.95(10) 2_755 5_775
O8 Ag3 Ag6 54.16(12) 5_775 5_775
Ag4 Ag3 Ag6 70.611(16) . 5_775
Ag2 Ag3 Ag6 100.719(16) . 5_775
Ag7 Ag3 Ag6 66.557(14) . 5_775
C1 Ag4 O4 153.32(18) . .
C1 Ag4 O5 123.74(17) . .
O4 Ag4 O5 76.32(16) . .
C1 Ag4 Ag3 52.06(13) . .
O4 Ag4 Ag3 101.80(13) . .
O5 Ag4 Ag3 132.77(12) . .
C1 Ag4 Ag5 56.13(13) . .
O4 Ag4 Ag5 150.53(13) . .
O5 Ag4 Ag5 81.24(10) . .
Ag3 Ag4 Ag5 107.465(18) . .
O7 Ag5 O11 104.69(19) . .
O7 Ag5 C2 122.2(2) . .
O11 Ag5 C2 117.85(18) . .
O7 Ag5 C1 150.4(2) . .
O11 Ag5 C1 94.30(17) . .
C2 Ag5 C1 28.88(17) . .
O7 Ag5 O6 106.2(2) . .
O11 Ag5 O6 97.53(12) . .
C2 Ag5 O6 105.01(16) . .
C1 Ag5 O6 93.26(15) . .
O7 Ag5 Ag4 163.08(19) . .
O11 Ag5 Ag4 59.27(7) . .
C2 Ag5 Ag4 73.38(12) . .
C1 Ag5 Ag4 44.52(12) . .
O6 Ag5 Ag4 73.02(10) . .
O7 Ag5 Ag6 85.93(18) . .
O11 Ag5 Ag6 164.55(13) . .
C2 Ag5 Ag6 46.85(13) . .
C1 Ag5 Ag6 71.73(12) . .
O6 Ag5 Ag6 90.02(10) . .
Ag4 Ag5 Ag6 110.882(18) . .
O9 Ag6 C2 136.17(17) . .
O9 Ag6 C1 86.91(16) . 5_775
C2 Ag6 C1 135.94(17) . 5_775
O9 Ag6 C2 113.59(16) . 5_775
C2 Ag6 C2 110.04(15) . 5_775
C1 Ag6 C2 27.09(16) 5_775 5_775
O9 Ag6 Ag1 87.04(11) . .
C2 Ag6 Ag1 49.29(13) . .
C1 Ag6 Ag1 163.94(12) 5_775 .
C2 Ag6 Ag1 157.19(11) 5_775 .
O9 Ag6 Ag6 161.44(12) . 5_775
C2 Ag6 Ag6 61.86(13) . 5_775
C1 Ag6 Ag6 74.60(11) 5_775 5_775
C2 Ag6 Ag6 48.18(11) 5_775 5_775
Ag1 Ag6 Ag6 110.35(2) . 5_775
O9 Ag6 Ag5 121.21(13) . .
C2 Ag6 Ag5 51.00(13) . .
C1 Ag6 Ag5 122.08(12) 5_775 .
C2 Ag6 Ag5 101.50(11) 5_775 .
Ag1 Ag6 Ag5 73.608(18) . .
Ag6 Ag6 Ag5 71.81(2) 5_775 .
O9 Ag6 Ag3 55.18(11) . 5_775
C2 Ag6 Ag3 161.83(13) . 5_775
C1 Ag6 Ag3 41.80(11) 5_775 5_775
C2 Ag6 Ag3 62.86(11) 5_775 5_775
Ag1 Ag6 Ag3 139.863(19) . 5_775
Ag6 Ag6 Ag3 109.00(2) 5_775 5_775
Ag5 Ag6 Ag3 112.252(19) . 5_775
O9 Ag6 Ag7 119.06(11) . .
C2 Ag6 Ag7 42.86(13) . .
C1 Ag6 Ag7 116.42(11) 5_775 .
C2 Ag6 Ag7 104.35(11) 5_775 .
Ag1 Ag6 Ag7 54.796(14) . .
Ag6 Ag6 Ag7 69.580(19) 5_775 .
Ag5 Ag6 Ag7 93.845(16) . .
Ag3 Ag6 Ag7 152.36(2) 5_775 .
N2 Ag7 C2 158.9(2) 7_675 .
N2 Ag7 O6 98.91(19) 7_675 5_775
C2 Ag7 O6 99.77(17) . 5_775
N2 Ag7 O8 94.8(2) 7_675 5_775
C2 Ag7 O8 95.37(17) . 5_775
O6 Ag7 O8 89.04(15) 5_775 5_775
N2 Ag7 Ag1 123.05(17) 7_675 .
C2 Ag7 Ag1 48.15(13) . .
O6 Ag7 Ag1 88.04(11) 5_775 .
O8 Ag7 Ag1 142.08(12) 5_775 .
N2 Ag7 Ag3 103.90(15) 7_675 .
C2 Ag7 Ag3 68.54(13) . .
O6 Ag7 Ag3 135.94(10) 5_775 .
O8 Ag7 Ag3 52.25(11) 5_775 .
Ag1 Ag7 Ag3 109.256(18) . .
N2 Ag7 Ag6 154.71(15) 7_675 .
C2 Ag7 Ag6 42.07(13) . .
O6 Ag7 Ag6 57.70(10) 5_775 .
O8 Ag7 Ag6 94.34(12) 5_775 .
Ag1 Ag7 Ag6 53.102(13) . .
Ag3 Ag7 Ag6 100.330(16) . .
N4 Ag8 N3 113.0(2) 8_566 .
N4 Ag8 O5 106.2(2) 8_566 .
N3 Ag8 O5 117.6(2) . .
N4 Ag8 O4 133.5(2) 8_566 .
N3 Ag8 O4 107.9(2) . .
O5 Ag8 O4 71.71(15) . .
C2 C1 Ag4 149.0(4) . .
C2 C1 Ag3 131.3(4) . .
Ag4 C1 Ag3 78.21(16) . .
C2 C1 Ag2 95.2(4) . .
Ag4 C1 Ag2 97.1(2) . .
Ag3 C1 Ag2 84.88(16) . .
C2 C1 Ag5 69.8(3) . .
Ag4 C1 Ag5 79.35(17) . .
Ag3 C1 Ag5 155.0(2) . .
Ag2 C1 Ag5 108.70(19) . .
C2 C1 Ag6 79.5(3) . 5_775
Ag4 C1 Ag6 95.68(18) . 5_775
Ag3 C1 Ag6 86.47(16) . 5_775
Ag2 C1 Ag6 162.8(2) . 5_775
Ag5 C1 Ag6 85.00(15) . 5_775
C1 C2 Ag1 139.3(4) . .
C1 C2 Ag6 140.6(4) . .
Ag1 C2 Ag6 78.94(17) . .
C1 C2 Ag7 100.0(4) . .
Ag1 C2 Ag7 80.24(17) . .
Ag6 C2 Ag7 95.1(2) . .
C1 C2 Ag5 81.3(3) . .
Ag1 C2 Ag5 100.7(2) . .
Ag6 C2 Ag5 82.16(17) . .
Ag7 C2 Ag5 176.8(3) . .
C1 C2 Ag6 73.4(3) . 5_775
Ag1 C2 Ag6 147.0(2) . 5_775
Ag6 C2 Ag6 69.96(15) . 5_775
Ag7 C2 Ag6 91.45(18) . 5_775
Ag5 C2 Ag6 86.13(16) . 5_775
O1 C3 O2 130.9(5) . .
O1 C3 C4 114.4(5) . .
O2 C3 C4 114.7(5) . .
F1 C4 F3 110.2(10) . .
F1 C4 F2 106.7(9) . .
F3 C4 F2 103.3(6) . .
F1 C4 C3 113.1(6) . .
F3 C4 C3 111.0(7) . .
F2 C4 C3 112.0(7) . .
O3 C5 O4 130.9(6) . .
O3 C5 C6 112.9(7) . .
O4 C5 C6 116.1(6) . .
F5 C6 F4 109.1(8) . .
F5 C6 F6 105.0(9) . .
F4 C6 F6 106.5(11) . .
F5 C6 C5 111.5(10) . .
F4 C6 C5 114.7(7) . .
F6 C6 C5 109.5(7) . .
O5 C7 O6 127.7(5) . .
O5 C7 C8 116.5(5) . .
O6 C7 C8 115.8(5) . .
F7 C8 F9 107.5(7) . .
F7 C8 F8 110.0(9) . .
F9 C8 F8 104.4(7) . .
F7 C8 C7 113.1(7) . .
F9 C8 C7 112.7(6) . .
F8 C8 C7 108.8(6) . .
O7 C9 O8 129.7(6) . .
O7 C9 C10 114.0(7) . .
O8 C9 C10 116.3(7) . .
F11 C10 F10 116.9(10) . .
F11 C10 F12 97.8(9) . .
F10 C10 F12 99.0(11) . .
F11 C10 C9 116.7(10) . .
F10 C10 C9 116.4(8) . .
F12 C10 C9 105.2(9) . .
O10 C11 O9 130.0(5) . .
O10 C11 C12 115.7(5) . .
O9 C11 C12 114.3(5) . .
F14' C12 F14 59.6(13) . .
F14' C12 F15' 108.9(14) . .
F14 C12 F15' 132.7(11) . .
F14' C12 F15 50.9(12) . .
F14 C12 F15 108.8(13) . .
F15' C12 F15 66.4(13) . .
F14' C12 F13 128.7(9) . .
F14 C12 F13 108.6(13) . .
F15' C12 F13 38.9(8) . .
F15 C12 F13 102.8(13) . .
F14' C12 F13' 103.8(14) . .
F14 C12 F13' 47.7(10) . .
F15' C12 F13' 104.1(12) . .
F15 C12 F13' 140.1(10) . .
F13 C12 F13' 67.2(11) . .
F14' C12 C11 116.4(7) . .
F14 C12 C11 111.7(7) . .
F15' C12 C11 113.7(9) . .
F15 C12 C11 110.4(8) . .
F13 C12 C11 114.1(8) . .
F13' C12 C11 108.7(8) . .
N1 C13 C14 178.2(7) . .
C15 C14 C19 121.6(6) . .
C15 C14 C13 119.4(6) . .
C19 C14 C13 119.0(6) . .
C14 C15 C16 118.9(6) . .
C17 C16 C15 121.1(7) . .
C16 C17 C18 120.3(6) . .
C19 C18 C17 119.1(6) . .
C19 C18 C20 120.7(6) . .
C17 C18 C20 120.2(6) . .
C14 C19 C18 118.9(6) . .
N2 C20 C18 177.9(8) . .
N3 C21 C22 178.0(9) . .
C27 C22 C23 120.8(6) . .
C27 C22 C21 120.1(6) . .
C23 C22 C21 119.1(6) . .
C24 C23 C22 120.0(6) . .
C23 C24 C25 120.1(6) . .
C26 C25 C24 119.0(6) . .
C25 C26 C27 121.9(6) . .
C25 C26 C28 119.5(6) . .
C27 C26 C28 118.6(6) . .
C22 C27 C26 118.1(6) . .
N4 C28 C26 178.7(10) . .
F15' F13 C12 67.8(15) . .
F15' F13 F13' 123(2) . .
C12 F13 F13' 58.7(9) . .
F13' F14 F14' 125.2(16) . .
F13' F14 C12 71.8(12) . .
F14' F14 C12 58.8(9) . .
F14' F15 C12 62.3(10) . .
F14' F15 F15' 109.9(16) . .
C12 F15 F15' 56.3(9) . .
F14 F13' C12 60.5(10) . .
F14 F13' F13 108.1(14) . .
C12 F13' F13 54.1(8) . .
F15 F14' C12 66.8(11) . .
F15 F14' F14 126.0(16) . .
C12 F14' F14 61.6(10) . .
F13 F15' C12 73.3(16) . .
F13 F15' F15 126(2) . .
C12 F15' F15 57.3(10) . .
C13 N1 Ag3 168.9(6) . .
C20 N2 Ag7 178.7(6) . 7_675
C21 N3 Ag8 169.5(6) . .
C28 N4 Ag8 179.0(7) . 8_465
O12 N5 O12 122.7(9) . 2_755
O12 N5 O11 118.6(5) . .
O12 N5 O11 118.6(5) 2_755 .
C3 O1 Ag1 121.9(4) . .
C3 O2 Ag2 129.7(4) . .
C3 O2 Ag3 114.2(4) . 2_755
Ag2 O2 Ag3 77.94(13) . 2_755
C5 O3 Ag1 133.1(5) . 2_755
C5 O4 Ag4 114.0(4) . .
C5 O4 Ag8 141.0(4) . .
Ag4 O4 Ag8 105.01(19) . .
C7 O5 Ag4 119.9(4) . .
C7 O5 Ag8 137.9(4) . .
Ag4 O5 Ag8 102.15(16) . .
C7 O6 Ag7 140.0(4) . 5_775
C7 O6 Ag5 115.8(4) . .
Ag7 O6 Ag5 103.01(15) 5_775 .
C9 O7 Ag5 113.1(4) . .
C9 O8 Ag7 139.4(5) . 5_775
C9 O8 Ag3 141.3(5) . 5_775
Ag7 O8 Ag3 76.78(13) 5_775 5_775
C11 O9 Ag6 117.5(4) . .
C11 O10 Ag1 123.5(4) . .
N5 O11 Ag5 110.25(13) . .
N5 O11 Ag5 110.25(13) . 2_755
Ag5 O11 Ag5 139.5(3) . 2_755
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C2 2.189(5) .
Ag1 O1 2.301(4) .
Ag1 O3 2.324(5) 2_755
Ag1 O10 2.389(5) .
Ag1 Ag6 2.8338(6) .
Ag1 Ag7 2.8954(6) .
Ag1 Ag2 3.2940(5) .
Ag2 O2 2.395(5) .
Ag2 O2 2.395(5) 2_755
Ag2 C1 2.416(5) .
Ag2 C1 2.416(5) 2_755
Ag2 Ag3 3.1327(5) 2_755
Ag2 Ag3 3.1327(5) .
Ag2 Ag1 3.2940(5) 2_755
Ag3 N1 2.177(5) .
Ag3 C1 2.222(5) .
Ag3 O2 2.580(5) 2_755
Ag3 O8 2.595(5) 5_775
Ag3 Ag4 2.7576(7) .
Ag3 Ag7 3.1949(7) .
Ag3 Ag6 3.3271(6) 5_775
Ag4 C1 2.149(5) .
Ag4 O4 2.254(4) .
Ag4 O5 2.357(4) .
Ag4 Ag5 3.0128(6) .
Ag5 O7 2.245(5) .
Ag5 O11 2.411(2) .
Ag5 C2 2.416(5) .
Ag5 C1 2.545(5) .
Ag5 O6 2.584(4) .
Ag5 Ag6 3.0802(7) .
Ag6 O9 2.256(4) .
Ag6 C2 2.268(5) .
Ag6 C1 2.617(5) 5_775
Ag6 C2 2.684(5) 5_775
Ag6 Ag6 2.8595(8) 5_775
Ag6 Ag3 3.3271(6) 5_775
Ag6 Ag7 3.3720(6) .
Ag7 N2 2.184(5) 7_675
Ag7 C2 2.303(5) .
Ag7 O6 2.431(4) 5_775
Ag7 O8 2.549(5) 5_775
Ag8 N4 2.210(6) 8_566
Ag8 N3 2.247(6) .
Ag8 O5 2.429(4) .
Ag8 O4 2.437(5) .
C1 C2 1.243(7) .
C1 Ag6 2.617(5) 5_775
C2 Ag6 2.684(5) 5_775
C3 O1 1.220(7) .
C3 O2 1.247(7) .
C3 C4 1.550(8) .
C4 F1 1.261(10) .
C4 F3 1.318(11) .
C4 F2 1.322(10) .
C5 O3 1.212(8) .
C5 O4 1.244(8) .
C5 C6 1.563(11) .
C6 F5 1.291(12) .
C6 F4 1.293(9) .
C6 F6 1.390(16) .
C7 O5 1.232(7) .
C7 O6 1.253(7) .
C7 C8 1.545(8) .
C8 F7 1.262(9) .
C8 F9 1.311(9) .
C8 F8 1.337(11) .
C9 O7 1.228(9) .
C9 O8 1.239(8) .
C9 C10 1.529(12) .
C10 F11 1.245(14) .
C10 F10 1.271(12) .
C10 F12 1.507(18) .
C11 O10 1.223(7) .
C11 O9 1.250(7) .
C11 C12 1.557(8) .
C12 F14' 1.235(13) .
C12 F14 1.270(13) .
C12 F15' 1.269(15) .
C12 F15 1.283(14) .
C12 F13 1.313(14) .
C12 F13' 1.386(15) .
C13 N1 1.131(8) .
C13 C14 1.439(8) .
C14 C15 1.368(10) .
C14 C19 1.384(8) .
C15 C16 1.389(10) .
C16 C17 1.344(12) .
C17 C18 1.411(10) .
C18 C19 1.389(8) .
C18 C20 1.418(9) .
C20 N2 1.146(8) .
C21 N3 1.136(9) .
C21 C22 1.430(9) .
C22 C27 1.385(8) .
C22 C23 1.394(9) .
C23 C24 1.388(9) .
C24 C25 1.390(9) .
C25 C26 1.387(9) .
C26 C27 1.398(8) .
C26 C28 1.446(9) .
C28 N4 1.120(9) .
F13 F15' 0.861(18) .
F13 F13' 1.49(2) .
F14 F13' 1.08(2) .
F14 F14' 1.25(3) .
F15 F14' 1.08(2) .
F15 F15' 1.40(3) .
N2 Ag7 2.184(5) 7_675
N4 Ag8 2.210(6) 8_465
N5 O12 1.240(7) .
N5 O12 1.240(7) 2_755
N5 O11 1.280(10) .
O2 Ag3 2.580(5) 2_755
O3 Ag1 2.324(5) 2_755
O6 Ag7 2.431(4) 5_775
O8 Ag7 2.549(5) 5_775
O8 Ag3 2.595(5) 5_775
O11 Ag5 2.411(2) 2_755
