#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:18:41 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180499 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/68/7216855.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7216855
loop_
_publ_author_name
'Hu, Ting'
'Yang, Jin'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of organometallic networks with multinuclear
 silver(i)--ethynediide supramolecular synthon, trifluoroacetate and
 ligands derived from isomeric dicyanobenzenes
;
_journal_issue                   28
_journal_name_full               CrystEngComm
_journal_page_first              6316
_journal_paper_doi               10.1039/c3ce41671b
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C26 H16 Ag8 F12 N2 O16'
_chemical_formula_weight         1703.37
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.275(2)
_cell_angle_beta                 95.7970(10)
_cell_angle_gamma                97.8950(10)
_cell_formula_units_Z            2
_cell_length_a                   8.2222(7)
_cell_length_b                   16.2247(14)
_cell_length_c                   16.4614(14)
_cell_measurement_reflns_used    38234
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.937
_cell_measurement_theta_min      2.494
_cell_volume                     2158.4(3)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0892
_diffrn_reflns_av_sigmaI/netI    0.0948
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            32274
_diffrn_reflns_theta_full        27.98
_diffrn_reflns_theta_max         27.98
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    3.660
_exptl_absorpt_correction_T_max  0.5587
_exptl_absorpt_correction_T_min  0.5281
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.565
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1556
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_refine_diff_density_max         2.824
_refine_diff_density_min         -2.742
_refine_diff_density_rms         0.496
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     642
_refine_ls_number_reflns         10298
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.1017
_refine_ls_R_factor_gt           0.0901
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1771P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2299
_refine_ls_wR_factor_ref         0.2435
_reflns_number_gt                8480
_reflns_number_total             10298
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41671b.txt
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7216855
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.52053(7) 0.56661(4) 0.55714(4) 0.02057(18) Uani 1 1 d . . .
Ag2 Ag 0.86810(7) 0.60514(4) 0.63444(4) 0.02207(19) Uani 1 1 d . . .
Ag3 Ag 0.81738(8) 0.41957(4) 0.60770(4) 0.02374(19) Uani 1 1 d . . .
Ag4 Ag 0.81583(8) 0.34626(4) 0.44151(4) 0.02375(19) Uani 1 1 d . . .
Ag5 Ag 0.83327(7) 0.49037(4) 0.34775(4) 0.02229(18) Uani 1 1 d . . .
Ag6 Ag 0.84632(8) 0.63660(4) 0.45633(4) 0.02309(19) Uani 1 1 d . . .
Ag7 Ag 0.54569(13) 0.76279(5) 0.68416(7) 0.0494(3) Uani 1 1 d . . .
Ag8 Ag 0.47232(13) 0.36038(6) 0.72300(5) 0.0424(2) Uani 1 1 d . . .
C1 C 0.7646(9) 0.5253(5) 0.5260(5) 0.0178(15) Uani 1 1 d . . .
C2 C 0.7706(9) 0.4729(6) 0.4705(6) 0.0218(17) Uani 1 1 d . . .
C3 C 0.5413(10) 0.5810(5) 0.7400(5) 0.0197(16) Uani 1 1 d . . .
C4 C 0.5528(9) 0.5990(6) 0.8294(5) 0.0207(16) Uani 1 1 d . . .
C5 C 0.4293(11) 0.5615(7) 0.8729(6) 0.029(2) Uani 1 1 d . . .
H5 H 0.3435 0.5234 0.8458 0.035 Uiso 1 1 calc R . .
C6 C 0.4334(12) 0.5806(7) 0.9563(6) 0.034(2) Uani 1 1 d . . .
H6 H 0.3481 0.5581 0.9850 0.041 Uiso 1 1 calc R . .
C7 C 0.5675(13) 0.6339(7) 0.9957(6) 0.035(2) Uani 1 1 d . . .
C8 C 0.6939(14) 0.6716(8) 0.9530(7) 0.042(3) Uani 1 1 d . . .
H8 H 0.7822 0.7076 0.9809 0.050 Uiso 1 1 calc R . .
C9 C 0.6865(11) 0.6551(7) 0.8694(6) 0.035(2) Uani 1 1 d . . .
H9 H 0.7682 0.6805 0.8401 0.042 Uiso 1 1 calc R . .
C10 C 0.5689(13) 0.6502(8) 1.0838(6) 0.038(2) Uani 1 1 d . . .
C11 C 0.5064(9) 0.7213(5) 0.4584(5) 0.0191(16) Uani 1 1 d . . .
C12 C 0.5072(9) 0.8048(5) 0.4261(5) 0.0175(15) Uani 1 1 d . . .
C13 C 0.4004(11) 0.8567(6) 0.4566(6) 0.0266(19) Uani 1 1 d . . .
H13 H 0.3340 0.8391 0.4966 0.032 Uiso 1 1 calc R . .
C14 C 0.3950(12) 0.9345(6) 0.4263(6) 0.032(2) Uani 1 1 d . . .
H14 H 0.3235 0.9687 0.4458 0.038 Uiso 1 1 calc R . .
C15 C 0.4947(13) 0.9617(6) 0.3675(6) 0.030(2) Uani 1 1 d . . .
C16 C 0.6037(13) 0.9100(6) 0.3378(7) 0.034(2) Uani 1 1 d . . .
H16 H 0.6720 0.9279 0.2987 0.041 Uiso 1 1 calc R . .
C17 C 0.6074(11) 0.8320(6) 0.3678(6) 0.0274(19) Uani 1 1 d . . .
H17 H 0.6785 0.7975 0.3484 0.033 Uiso 1 1 calc R . .
C18 C 0.4885(14) 1.0436(6) 0.3405(7) 0.038(2) Uani 1 1 d . . .
C19 C 1.1473(11) 0.6962(6) 0.7560(6) 0.0251(18) Uani 1 1 d . . .
C20 C 1.2034(14) 0.7561(8) 0.8324(7) 0.043(3) Uani 1 1 d . . .
C21 C 0.9848(10) 0.7982(5) 0.5727(6) 0.0235(17) Uani 1 1 d . . .
C22 C 0.9790(13) 0.8915(7) 0.5954(9) 0.044(3) Uani 1 1 d . . .
C23 C 1.0354(12) 0.7320(6) 0.3288(6) 0.033(2) Uani 1 1 d . . .
C24 C 1.0375(15) 0.7997(10) 0.2682(11) 0.066(5) Uani 1 1 d . . .
C25 C 1.0534(11) 0.5384(7) 0.2120(6) 0.031(2) Uani 1 1 d . A .
C26 C 1.0598(15) 0.5493(12) 0.1203(7) 0.059(4) Uani 1 1 d . . .
F1 F 1.1360(18) 0.8202(7) 0.8333(9) 0.138(6) Uani 1 1 d . . .
F2 F 1.1574(15) 0.7202(9) 0.8987(6) 0.110(4) Uani 1 1 d . . .
F3 F 1.3641(10) 0.7735(6) 0.8488(6) 0.082(3) Uani 1 1 d . . .
F4 F 0.8472(13) 0.9151(6) 0.5715(11) 0.134(6) Uani 1 1 d . . .
F5 F 0.984(4) 0.9039(10) 0.6713(10) 0.267(16) Uani 1 1 d . . .
F6 F 1.1032(14) 0.9387(6) 0.5769(13) 0.153(8) Uani 1 1 d . . .
F7 F 1.0144(18) 0.8736(7) 0.3091(10) 0.129(6) Uani 1 1 d . . .
F8 F 0.9183(16) 0.7953(9) 0.2168(9) 0.083(4) Uani 0.75 1 d PU . .
F9 F 1.1839(11) 0.8245(7) 0.2456(7) 0.093(4) Uani 1 1 d . . .
F10 F 0.958(6) 0.594(4) 0.091(3) 0.102(17) Uani 0.53(3) 1 d P A 1
F11 F 1.196(2) 0.5619(17) 0.0953(13) 0.068(6) Uani 0.53(3) 1 d PU A 1
F12 F 0.994(3) 0.4709(16) 0.0814(10) 0.104(11) Uani 0.53(3) 1 d P A 1
F8' F 0.985(5) 0.750(3) 0.190(3) 0.079(11) Uani 0.25 1 d PU . .
F10' F 1.159(3) 0.6309(16) 0.1141(14) 0.089(8) Uani 0.47(3) 1 d PU A 2
F11' F 1.160(4) 0.5119(18) 0.0884(12) 0.083(11) Uani 0.47(3) 1 d P A 2
F12' F 0.928(5) 0.560(4) 0.081(3) 0.072(18) Uani 0.47(3) 1 d P A 2
N1 N 0.5648(12) 0.6595(6) 1.1525(5) 0.042(2) Uani 1 1 d . . .
N2 N 0.4805(14) 1.1095(6) 0.3202(6) 0.047(2) Uani 1 1 d . . .
O1 O 0.4623(7) 0.5120(4) 0.7077(4) 0.0235(13) Uani 1 1 d . . .
O2 O 0.6113(7) 0.6349(4) 0.6963(4) 0.0207(12) Uani 1 1 d . . .
O3 O 0.4747(7) 0.7102(4) 0.5297(4) 0.0214(12) Uani 1 1 d . . .
O4 O 0.5415(8) 0.6616(4) 0.4119(4) 0.0237(13) Uani 1 1 d . . .
O5 O 0.9962(9) 0.6798(6) 0.7412(5) 0.0431(19) Uani 1 1 d . . .
O6 O 1.2552(8) 0.6732(5) 0.7178(4) 0.0349(16) Uani 1 1 d . . .
O7 O 0.8523(9) 0.7554(5) 0.5557(7) 0.060(3) Uani 1 1 d . . .
O8 O 1.1264(9) 0.7798(4) 0.5747(5) 0.0369(17) Uani 1 1 d . . .
O9 O 0.8982(11) 0.7137(6) 0.3537(6) 0.050(2) Uani 1 1 d . . .
O10 O 1.1634(9) 0.7026(5) 0.3419(6) 0.042(2) Uani 1 1 d . . .
O11 O 0.9137(8) 0.5312(5) 0.2344(4) 0.0335(16) Uani 1 1 d . . .
O12 O 1.1904(9) 0.5360(6) 0.2540(5) 0.0413(19) Uani 1 1 d . . .
O1W O 0.422(7) 0.991(4) 0.129(4) 0.092(15) Uiso 0.25 1 d P . .
O2W O 1.015(6) 1.000(3) 0.129(3) 0.073(12) Uiso 0.25 1 d P . .
O3W O 0.769(7) 0.998(4) 0.867(4) 0.100(17) Uiso 0.25 1 d P . .
O4W O 0.718(7) 0.977(3) 0.122(3) 0.088(15) Uiso 0.25 1 d P . .
O5W O 0.424(6) 0.935(3) 0.090(3) 0.081(13) Uiso 0.25 1 d P . .
O6W O 0.589(7) 0.994(4) 0.129(4) 0.089(15) Uiso 0.25 1 d P . .
O7W O 0.886(6) 0.994(3) 0.132(3) 0.075(12) Uiso 0.25 1 d P . .
O8W O 0.261(6) 0.942(3) 0.093(3) 0.084(14) Uiso 0.25 1 d P . .
O9W O 0.571(6) 0.938(3) 0.086(3) 0.081(13) Uiso 0.25 1 d P . .
O10W O 0.691(7) 0.891(4) 0.047(4) 0.103(17) Uiso 0.25 1 d P . .
O11W O 0.863(6) 0.893(3) 0.045(3) 0.079(13) Uiso 0.25 1 d P . .
O12W O 0.341(8) 0.878(4) 0.046(4) 0.091(15) Uiso 0.25 1 d P . .
O13W O 0.977(7) 0.944(4) 0.087(3) 0.086(14) Uiso 0.25 1 d P . .
O14W O 0.043(6) 0.892(3) 0.045(3) 0.086(14) Uiso 0.25 1 d P . .
O15W O 0.218(6) 0.879(3) 0.045(3) 0.077(13) Uiso 0.25 1 d P . .
O16W O 0.473(8) 0.884(4) 0.045(4) 0.093(16) Uiso 0.25 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C2 141.0(3) . 2_666
C1 Ag1 O3 117.7(2) . .
C2 Ag1 O3 87.4(3) 2_666 .
C1 Ag1 O2 99.7(2) . .
C2 Ag1 O2 114.0(3) 2_666 .
O3 Ag1 O2 81.30(19) . .
C1 Ag1 Ag1 66.3(2) . 2_666
C2 Ag1 Ag1 74.8(2) 2_666 2_666
O3 Ag1 Ag1 125.70(15) . 2_666
O2 Ag1 Ag1 152.76(14) . 2_666
C1 Ag1 Ag2 46.5(2) . .
C2 Ag1 Ag2 165.4(2) 2_666 .
O3 Ag1 Ag2 98.23(14) . .
O2 Ag1 Ag2 54.22(13) . .
Ag1 Ag1 Ag2 111.71(3) 2_666 .
C1 Ag1 Ag4 164.7(2) . 2_666
C2 Ag1 Ag4 41.5(2) 2_666 2_666
O3 Ag1 Ag4 50.07(13) . 2_666
O2 Ag1 Ag4 88.04(13) . 2_666
Ag1 Ag1 Ag4 111.46(3) 2_666 2_666
Ag2 Ag1 Ag4 136.42(3) . 2_666
O5 Ag2 C1 173.8(3) . .
O5 Ag2 O2 83.9(2) . .
C1 Ag2 O2 101.9(2) . .
O5 Ag2 Ag1 136.03(19) . .
C1 Ag2 Ag1 50.1(2) . .
O2 Ag2 Ag1 52.88(14) . .
O5 Ag2 Ag3 127.1(3) . .
C1 Ag2 Ag3 50.0(2) . .
O2 Ag2 Ag3 103.26(14) . .
Ag1 Ag2 Ag3 76.98(2) . .
O5 Ag2 Ag6 131.1(2) . .
C1 Ag2 Ag6 48.6(2) . .
O2 Ag2 Ag6 111.35(14) . .
Ag1 Ag2 Ag6 69.17(2) . .
Ag3 Ag2 Ag6 95.39(3) . .
O5 Ag2 Ag4 84.51(19) . 2_766
C1 Ag2 Ag4 90.8(2) . 2_766
O2 Ag2 Ag4 154.01(14) . 2_766
Ag1 Ag2 Ag4 130.21(3) . 2_766
Ag3 Ag2 Ag4 102.29(2) . 2_766
Ag6 Ag2 Ag4 61.27(2) . 2_766
O5 Ag2 Ag5 83.9(2) . 2_766
C1 Ag2 Ag5 90.2(2) . 2_766
O2 Ag2 Ag5 144.79(14) . 2_766
Ag1 Ag2 Ag5 135.39(3) . 2_766
Ag3 Ag2 Ag5 60.12(2) . 2_766
Ag6 Ag2 Ag5 101.49(2) . 2_766
Ag4 Ag2 Ag5 56.11(2) 2_766 2_766
O10 Ag3 C1 165.1(3) 2_766 .
O10 Ag3 O12 83.3(3) 2_766 2_766
C1 Ag3 O12 109.6(3) . 2_766
O10 Ag3 C2 136.9(3) 2_766 .
C1 Ag3 C2 29.3(3) . .
O12 Ag3 C2 138.7(3) 2_766 .
O10 Ag3 Ag4 90.9(2) 2_766 .
C1 Ag3 Ag4 75.9(2) . .
O12 Ag3 Ag4 173.8(2) 2_766 .
C2 Ag3 Ag4 46.6(2) . .
O10 Ag3 Ag2 148.5(2) 2_766 .
C1 Ag3 Ag2 46.3(2) . .
O12 Ag3 Ag2 68.0(2) 2_766 .
C2 Ag3 Ag2 74.0(2) . .
Ag4 Ag3 Ag2 118.10(3) . .
O10 Ag3 Ag5 101.4(2) 2_766 2_766
C1 Ag3 Ag5 88.8(2) . 2_766
O12 Ag3 Ag5 78.79(19) 2_766 2_766
C2 Ag3 Ag5 97.06(18) . 2_766
Ag4 Ag3 Ag5 104.62(3) . 2_766
Ag2 Ag3 Ag5 61.47(2) . 2_766
O10 Ag3 Ag6 75.2(2) 2_766 2_766
C1 Ag3 Ag6 102.93(19) . 2_766
O12 Ag3 Ag6 121.12(18) 2_766 2_766
C2 Ag3 Ag6 85.23(18) . 2_766
Ag4 Ag3 Ag6 58.99(2) . 2_766
Ag2 Ag3 Ag6 107.98(2) . 2_766
Ag5 Ag3 Ag6 53.90(2) 2_766 2_766
O8 Ag4 C2 174.1(3) 2_766 .
O8 Ag4 O3 90.5(2) 2_766 2_666
C2 Ag4 O3 90.4(2) . 2_666
O8 Ag4 Ag5 136.0(2) 2_766 .
C2 Ag4 Ag5 48.3(2) . .
O3 Ag4 Ag5 113.91(14) 2_666 .
O8 Ag4 Ag3 118.5(2) 2_766 .
C2 Ag4 Ag3 55.9(2) . .
O3 Ag4 Ag3 79.60(14) 2_666 .
Ag5 Ag4 Ag3 102.17(3) . .
O8 Ag4 Ag2 84.50(19) 2_766 2_766
C2 Ag4 Ag2 96.0(2) . 2_766
O3 Ag4 Ag2 165.98(14) 2_666 2_766
Ag5 Ag4 Ag2 62.88(2) . 2_766
Ag3 Ag4 Ag2 114.29(3) . 2_766
O8 Ag4 Ag6 79.1(2) 2_766 2_766
C2 Ag4 Ag6 96.1(2) . 2_766
O3 Ag4 Ag6 132.87(14) 2_666 2_766
Ag5 Ag4 Ag6 104.71(3) . 2_766
Ag3 Ag4 Ag6 66.39(2) . 2_766
Ag2 Ag4 Ag6 58.92(2) 2_766 2_766
O8 Ag4 Ag1 136.20(19) 2_766 2_666
C2 Ag4 Ag1 46.6(2) . 2_666
O3 Ag4 Ag1 48.25(14) 2_666 2_666
Ag5 Ag4 Ag1 68.63(2) . 2_666
Ag3 Ag4 Ag1 73.61(2) . 2_666
Ag2 Ag4 Ag1 131.48(3) 2_766 2_666
Ag6 Ag4 Ag1 137.07(3) 2_766 2_666
O11 Ag5 C2 169.3(3) . .
O11 Ag5 O1 90.7(2) . 2_666
C2 Ag5 O1 92.6(2) . 2_666
O11 Ag5 Ag4 140.1(2) . .
C2 Ag5 Ag4 48.7(2) . .
O1 Ag5 Ag4 102.12(15) 2_666 .
O11 Ag5 Ag6 107.3(2) . .
C2 Ag5 Ag6 62.3(2) . .
O1 Ag5 Ag6 94.90(15) 2_666 .
Ag4 Ag5 Ag6 109.02(3) . .
O11 Ag5 Ag3 74.69(18) . 2_766
C2 Ag5 Ag3 97.9(2) . 2_766
O1 Ag5 Ag3 151.51(15) 2_666 2_766
Ag4 Ag5 Ag3 104.71(3) . 2_766
Ag6 Ag5 Ag3 67.38(2) . 2_766
O11 Ag5 Ag2 87.97(19) . 2_766
C2 Ag5 Ag2 94.7(2) . 2_766
O1 Ag5 Ag2 147.05(15) 2_666 2_766
Ag4 Ag5 Ag2 61.01(2) . 2_766
Ag6 Ag5 Ag2 116.88(3) . 2_766
Ag3 Ag5 Ag2 58.41(2) 2_766 2_766
O9 Ag6 C1 160.6(4) . .
O9 Ag6 O7 94.7(4) . .
C1 Ag6 O7 103.6(3) . .
O9 Ag6 C2 134.3(3) . .
C1 Ag6 C2 27.0(3) . .
O7 Ag6 C2 130.7(3) . .
O9 Ag6 Ag5 88.9(3) . .
C1 Ag6 Ag5 72.7(2) . .
O7 Ag6 Ag5 176.4(3) . .
C2 Ag6 Ag5 45.70(19) . .
O9 Ag6 Ag2 152.9(3) . .
C1 Ag6 Ag2 46.2(2) . .
O7 Ag6 Ag2 61.9(3) . .
C2 Ag6 Ag2 71.18(19) . .
Ag5 Ag6 Ag2 114.65(3) . .
O9 Ag6 Ag4 102.8(2) . 2_766
C1 Ag6 Ag4 88.2(2) . 2_766
O7 Ag6 Ag4 74.49(19) . 2_766
C2 Ag6 Ag4 95.21(17) . 2_766
Ag5 Ag6 Ag4 104.99(3) . 2_766
Ag2 Ag6 Ag4 59.80(2) . 2_766
O9 Ag6 Ag3 74.7(2) . 2_766
C1 Ag6 Ag3 99.80(19) . 2_766
O7 Ag6 Ag3 122.56(18) . 2_766
C2 Ag6 Ag3 82.76(16) . 2_766
Ag5 Ag6 Ag3 58.72(2) . 2_766
Ag2 Ag6 Ag3 105.29(3) . 2_766
Ag4 Ag6 Ag3 54.61(2) 2_766 2_766
N2 Ag7 O2 171.6(4) 2_676 .
N1 Ag8 O4 160.3(3) 2_667 2_666
N1 Ag8 O1 106.0(3) 2_667 .
O4 Ag8 O1 89.9(2) 2_666 .
C2 C1 Ag2 153.6(7) . .
C2 C1 Ag6 95.9(6) . .
Ag2 C1 Ag6 85.2(3) . .
C2 C1 Ag1 122.4(6) . .
Ag2 C1 Ag1 83.5(3) . .
Ag6 C1 Ag1 96.3(3) . .
C2 C1 Ag3 83.4(6) . .
Ag2 C1 Ag3 83.6(3) . .
Ag6 C1 Ag3 152.2(4) . .
Ag1 C1 Ag3 107.6(3) . .
C1 C2 Ag5 129.0(7) . .
C1 C2 Ag4 144.7(7) . .
Ag5 C2 Ag4 82.9(3) . .
C1 C2 Ag1 95.8(6) . 2_666
Ag5 C2 Ag1 99.9(3) . 2_666
Ag4 C2 Ag1 91.9(3) . 2_666
C1 C2 Ag3 67.3(5) . .
Ag5 C2 Ag3 152.4(4) . .
Ag4 C2 Ag3 77.5(3) . .
Ag1 C2 Ag3 100.0(3) 2_666 .
C1 C2 Ag6 57.1(5) . .
Ag5 C2 Ag6 72.0(3) . .
Ag4 C2 Ag6 149.2(4) . .
Ag1 C2 Ag6 109.5(3) 2_666 .
Ag3 C2 Ag6 118.3(3) . .
O1 C3 O2 121.2(8) . .
O1 C3 C4 119.4(7) . .
O2 C3 C4 119.4(8) . .
C5 C4 C9 120.8(8) . .
C5 C4 C3 119.6(8) . .
C9 C4 C3 119.6(7) . .
C6 C5 C4 120.5(9) . .
C7 C6 C5 118.3(9) . .
C6 C7 C8 121.9(9) . .
C6 C7 C10 116.4(9) . .
C8 C7 C10 121.7(10) . .
C9 C8 C7 119.7(9) . .
C8 C9 C4 118.6(9) . .
N1 C10 C7 176.7(13) . .
O3 C11 O4 121.0(8) . .
O3 C11 C12 120.4(8) . .
O4 C11 C12 118.6(7) . .
C17 C12 C13 120.0(8) . .
C17 C12 C11 122.3(7) . .
C13 C12 C11 117.7(7) . .
C14 C13 C12 119.3(8) . .
C15 C14 C13 120.8(9) . .
C14 C15 C16 119.8(9) . .
C14 C15 C18 118.5(9) . .
C16 C15 C18 121.7(9) . .
C17 C16 C15 119.1(9) . .
C12 C17 C16 121.0(8) . .
N2 C18 C15 178.3(12) . .
O6 C19 O5 129.2(9) . .
O6 C19 C20 117.2(8) . .
O5 C19 C20 113.5(8) . .
F1 C20 F3 111.9(12) . .
F1 C20 F2 103.0(13) . .
F3 C20 F2 103.1(11) . .
F1 C20 C19 114.0(11) . .
F3 C20 C19 113.8(9) . .
F2 C20 C19 109.9(10) . .
O7 C21 O8 130.4(9) . .
O7 C21 C22 115.5(8) . .
O8 C21 C22 114.0(8) . .
F4 C22 F5 101.9(17) . .
F4 C22 F6 112.7(14) . .
F5 C22 F6 104.5(18) . .
F4 C22 C21 114.0(10) . .
F5 C22 C21 109.8(12) . .
F6 C22 C21 112.9(9) . .
O10 C23 O9 131.0(10) . .
O10 C23 C24 116.0(9) . .
O9 C23 C24 113.0(9) . .
F8 C24 F9 117.7(14) . .
F8 C24 F7 96.7(14) . .
F9 C24 F7 98.3(13) . .
F8 C24 F8' 46.0(18) . .
F9 C24 F8' 92(2) . .
F7 C24 F8' 141(2) . .
F8 C24 C23 117.1(12) . .
F9 C24 C23 114.1(10) . .
F7 C24 C23 108.6(13) . .
F8' C24 C23 101(2) . .
O11 C25 O12 128.7(9) . .
O11 C25 C26 115.0(9) . .
O12 C25 C26 116.3(9) . .
F11 C26 F11' 39.1(15) . .
F11 C26 F12' 125(3) . .
F11' C26 F12' 121(4) . .
F11 C26 F10 115(3) . .
F11' C26 F10 132(3) . .
F12' C26 F10 27(4) . .
F11 C26 F12 102.2(18) . .
F11' C26 F12 65(2) . .
F12' C26 F12 75(3) . .
F10 C26 F12 101(3) . .
F11 C26 F10' 53.5(15) . .
F11' C26 F10' 92(2) . .
F12' C26 F10' 100(3) . .
F10 C26 F10' 75(3) . .
F12 C26 F10' 147.0(15) . .
F11 C26 C25 117.9(14) . .
F11' C26 C25 114.8(14) . .
F12' C26 C25 116(3) . .
F10 C26 C25 113(3) . .
F12 C26 C25 104.9(13) . .
F10' C26 C25 106.5(14) . .
F8' F8 C24 80(2) . .
F8 F8' C24 54(2) . .
C10 N1 Ag8 163.3(10) . 2_667
C18 N2 Ag7 164.5(10) . 2_676
C3 O1 Ag8 136.9(5) . .
C3 O1 Ag5 117.7(5) . 2_666
Ag8 O1 Ag5 101.2(2) . 2_666
C3 O2 Ag7 124.5(5) . .
C3 O2 Ag1 100.4(5) . .
Ag7 O2 Ag1 102.4(2) . .
C3 O2 Ag2 118.8(5) . .
Ag7 O2 Ag2 116.0(2) . .
Ag1 O2 Ag2 72.90(15) . .
C11 O3 Ag1 107.1(5) . .
C11 O3 Ag4 120.7(5) . 2_666
Ag1 O3 Ag4 81.68(18) . 2_666
C11 O4 Ag8 132.7(5) . 2_666
C19 O5 Ag2 124.8(6) . .
C21 O7 Ag6 115.7(7) . .
C21 O8 Ag4 124.7(6) . 2_766
C23 O9 Ag6 125.9(7) . .
C23 O10 Ag3 124.9(7) . 2_766
C25 O11 Ag5 129.2(6) . .
C25 O12 Ag3 111.3(6) . 2_766
O5W O1W O6W 81(5) . .
O5W O1W O8W 62(5) . .
O6W O1W O8W 142(6) . .
O5W O1W O3W 107(6) . 2_676
O6W O1W O3W 172(6) . 2_676
O8W O1W O3W 46(3) . 2_676
O5W O1W O9W 42(4) . .
O6W O1W O9W 39(3) . .
O8W O1W O9W 104(4) . .
O3W O1W O9W 149(5) 2_676 .
O7W O2W O13W 81(5) . .
O7W O2W O3W 174(6) . 2_776
O13W O2W O3W 98(5) . 2_776
O8W O3W O1W 62(4) 2_676 2_676
O8W O3W O2W 110(5) 2_676 2_776
O1W O3W O2W 172(5) 2_676 2_776
O6W O4W O9W 52(4) . .
O6W O4W O7W 152(6) . .
O9W O4W O7W 155(6) . .
O6W O4W O10W 107(5) . .
O9W O4W O10W 55(4) . .
O7W O4W O10W 100(4) . .
O1W O5W O9W 101(6) . .
O1W O5W O16W 161(7) . .
O9W O5W O16W 60(4) . .
O1W O5W O12W 146(7) . .
O9W O5W O12W 112(6) . .
O16W O5W O12W 52(4) . .
O1W O5W O8W 75(5) . .
O9W O5W O8W 174(6) . .
O16W O5W O8W 124(6) . .
O12W O5W O8W 72(5) . .
O1W O5W O6W 58(4) . .
O9W O5W O6W 44(3) . .
O16W O5W O6W 104(5) . .
O12W O5W O6W 156(6) . .
O8W O5W O6W 132(5) . .
O9W O6W O4W 73(5) . .
O9W O6W O1W 91(5) . .
O4W O6W O1W 163(7) . .
O9W O6W O5W 49(4) . .
O4W O6W O5W 122(6) . .
O1W O6W O5W 41(3) . .
O2W O7W O4W 168(6) . .
O2W O7W O13W 50(4) . .
O4W O7W O13W 118(5) . .
O3W O8W O15W 151(6) 2_676 .
O3W O8W O5W 117(6) 2_676 .
O15W O8W O5W 92(5) . .
O3W O8W O1W 73(5) 2_676 .
O15W O8W O1W 136(5) . .
O5W O8W O1W 44(3) . .
O3W O8W O12W 167(6) 2_676 .
O15W O8W O12W 42(3) . .
O5W O8W O12W 50(4) . .
O1W O8W O12W 94(4) . .
O6W O9W O5W 87(6) . .
O6W O9W O16W 147(7) . .
O5W O9W O16W 60(4) . .
O6W O9W O4W 55(4) . .
O5W O9W O4W 141(6) . .
O16W O9W O4W 158(6) . .
O6W O9W O10W 132(6) . .
O5W O9W O10W 141(6) . .
O16W O9W O10W 81(5) . .
O4W O9W O10W 78(4) . .
O6W O9W O1W 51(4) . .
O5W O9W O1W 36(3) . .
O16W O9W O1W 96(5) . .
O4W O9W O1W 105(5) . .
O10W O9W O1W 177(5) . .
O11W O10W O9W 140(6) . .
O11W O10W O16W 177(6) . .
O9W O10W O16W 43(3) . .
O11W O10W O4W 93(4) . .
O9W O10W O4W 47(3) . .
O16W O10W O4W 90(4) . .
O13W O11W O10W 126(5) . .
O13W O11W O14W 54(3) . 1_655
O10W O11W O14W 177(6) . 1_655
O15W O12W O16W 173(8) . .
O15W O12W O5W 113(7) . .
O16W O12W O5W 64(5) . .
O15W O12W O8W 54(4) . .
O16W O12W O8W 122(6) . .
O5W O12W O8W 58(4) . .
O2W O13W O14W 138(6) . 1_655
O2W O13W O11W 150(6) . .
O14W O13W O11W 71(5) 1_655 .
O2W O13W O7W 48(4) . .
O14W O13W O7W 173(6) 1_655 .
O11W O13W O7W 102(5) . .
O13W O14W O15W 132(5) 1_455 .
O13W O14W O11W 55(4) 1_455 1_455
O15W O14W O11W 172(5) . 1_455
O12W O15W O8W 84(5) . .
O12W O15W O14W 173(7) . .
O8W O15W O14W 90(5) . .
O12W O16W O9W 124(7) . .
O12W O16W O5W 64(5) . .
O9W O16W O5W 60(4) . .
O12W O16W O10W 177(7) . .
O9W O16W O10W 56(4) . .
O5W O16W O10W 116(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.298(8) .
Ag1 C2 2.382(8) 2_666
Ag1 O3 2.470(6) .
Ag1 O2 2.483(6) .
Ag1 Ag1 2.7444(13) 2_666
Ag1 Ag2 2.9767(9) .
Ag1 Ag4 3.2757(9) 2_666
Ag2 O5 2.168(7) .
Ag2 C1 2.172(8) .
Ag2 O2 2.526(5) .
Ag2 Ag3 2.9832(10) .
Ag2 Ag6 2.9964(10) .
Ag2 Ag4 3.0239(9) 2_766
Ag2 Ag5 3.0770(9) 2_766
Ag3 O10 2.211(7) 2_766
Ag3 C1 2.300(8) .
Ag3 O12 2.358(8) 2_766
Ag3 C2 2.477(9) .
Ag3 Ag4 2.9183(10) .
Ag3 Ag5 3.0369(10) 2_766
Ag3 Ag6 3.2801(9) 2_766
Ag4 O8 2.170(7) 2_766
Ag4 C2 2.173(9) .
Ag4 O3 2.539(6) 2_666
Ag4 Ag5 2.8696(10) .
Ag4 Ag2 3.0239(9) 2_766
Ag4 Ag6 3.0680(10) 2_766
Ag4 Ag1 3.2757(9) 2_666
Ag5 O11 2.151(7) .
Ag5 C2 2.160(9) .
Ag5 O1 2.503(6) 2_666
Ag5 Ag6 2.8709(10) .
Ag5 Ag3 3.0369(9) 2_766
Ag5 Ag2 3.0770(9) 2_766
Ag6 O9 2.200(8) .
Ag6 C1 2.255(8) .
Ag6 O7 2.448(9) .
Ag6 C2 2.673(9) .
Ag6 Ag4 3.0680(10) 2_766
Ag6 Ag3 3.2801(9) 2_766
Ag7 N2 2.117(9) 2_676
Ag7 O2 2.230(6) .
Ag8 N1 2.138(9) 2_667
Ag8 O4 2.218(6) 2_666
Ag8 O1 2.498(7) .
C1 C2 1.221(12) .
C2 Ag1 2.382(8) 2_666
C3 O1 1.274(11) .
C3 O2 1.276(10) .
C3 C4 1.475(12) .
C4 C5 1.394(11) .
C4 C9 1.408(12) .
C5 C6 1.385(13) .
C6 C7 1.384(15) .
C7 C8 1.404(15) .
C7 C10 1.457(13) .
C8 C9 1.381(14) .
C10 N1 1.138(13) .
C11 O3 1.246(10) .
C11 O4 1.283(10) .
C11 C12 1.483(11) .
C12 C17 1.379(12) .
C12 C13 1.405(11) .
C13 C14 1.387(14) .
C14 C15 1.384(14) .
C15 C16 1.412(14) .
C15 C18 1.432(13) .
C16 C17 1.388(14) .
C18 N2 1.145(14) .
C19 O6 1.224(11) .
C19 O5 1.231(11) .
C19 C20 1.536(13) .
C20 F1 1.244(15) .
C20 F3 1.309(14) .
C20 F2 1.330(17) .
C21 O7 1.206(12) .
C21 O8 1.239(11) .
C21 C22 1.546(13) .
C22 F4 1.233(15) .
C22 F5 1.25(2) .
C22 F6 1.264(14) .
C23 O10 1.219(12) .
C23 O9 1.243(13) .
C23 C24 1.525(15) .
C24 F8 1.220(18) .
C24 F9 1.313(14) .
C24 F7 1.39(2) .
C24 F8' 1.48(5) .
C25 O11 1.234(11) .
C25 O12 1.268(12) .
C25 C26 1.535(15) .
C26 F11 1.23(2) .
C26 F11' 1.23(2) .
C26 F12' 1.24(5) .
C26 F10 1.26(6) .
C26 F12 1.40(3) .
C26 F10' 1.47(3) .
F8 F8' 1.08(4) .
N1 Ag8 2.138(9) 2_667
N2 Ag7 2.117(9) 2_676
O1 Ag5 2.503(6) 2_666
O3 Ag4 2.539(6) 2_666
O4 Ag8 2.218(6) 2_666
O8 Ag4 2.170(7) 2_766
O10 Ag3 2.211(7) 2_766
O12 Ag3 2.358(8) 2_766
O1W O5W 1.07(7) .
O1W O6W 1.37(7) .
O1W O8W 1.49(7) .
O1W O3W 1.62(8) 2_676
O1W O9W 1.77(8) .
O2W O7W 1.06(6) .
O2W O13W 1.09(6) .
O2W O3W 1.76(7) 2_776
O3W O8W 1.21(7) 2_676
O3W O1W 1.62(8) 2_676
O3W O2W 1.76(7) 2_776
O4W O6W 1.14(7) .
O4W O9W 1.34(7) .
O4W O7W 1.36(7) .
O4W O10W 1.79(8) .
O5W O9W 1.22(7) .
O5W O16W 1.22(7) .
O5W O12W 1.23(7) .
O5W O8W 1.36(7) .
O5W O6W 1.60(8) .
O6W O9W 1.10(7) .
O7W O13W 1.41(7) .
O8W O3W 1.21(7) 2_676
O8W O15W 1.24(7) .
O8W O12W 1.52(8) .
O9W O16W 1.23(7) .
O9W O10W 1.50(8) .
O10W O11W 1.41(7) .
O10W O16W 1.78(9) .
O11W O13W 1.28(7) .
O11W O14W 1.48(7) 1_655
O12W O15W 1.02(6) .
O12W O16W 1.08(7) .
O13W O14W 1.27(7) 1_655
O14W O13W 1.27(7) 1_455
O14W O15W 1.48(7) .
O14W O11W 1.48(7) 1_455
