#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:45:49 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180517 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/86/7218600.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7218600
loop_
_publ_author_name
'Zhou, Kun'
'Qin, Chao'
'Yan, Li-Kai'
'Wang, Fang-Ming'
'Su, Zhong-Min'
_publ_section_title
;
 Facile assembly of 1D multinuclear Agn (n = 11, 11, 12) alkynly chains
 with CF3COO--/CH3COO-- as auxiliary ligand
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C4RA09876E
_journal_year                    2014
_chemical_formula_sum            'C47 H58 Ag11 F15 O11'
_chemical_formula_weight         2266.47
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.957(4)
_cell_angle_beta                 92.602(4)
_cell_angle_gamma                117.093(3)
_cell_formula_units_Z            2
_cell_length_a                   14.551(4)
_cell_length_b                   14.805(4)
_cell_length_c                   18.520(7)
_cell_measurement_reflns_used    15742
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.62
_cell_volume                     3211.2(17)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0573
_diffrn_reflns_av_sigmaI/netI    0.1671
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15742
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    3.367
_exptl_absorpt_correction_T_max  0.5246
_exptl_absorpt_correction_T_min  0.5114
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.344
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2152
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.596
_refine_diff_density_min         -0.899
_refine_diff_density_rms         0.200
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     492
_refine_ls_number_reflns         11016
_refine_ls_number_restraints     65
_refine_ls_restrained_S_all      0.949
_refine_ls_R_factor_all          0.1989
_refine_ls_R_factor_gt           0.0781
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1667
_refine_ls_wR_factor_ref         0.2233
_reflns_number_gt                4624
_reflns_number_total             11016
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c4ra09876e2.cif
_cod_data_source_block           926484
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7218600
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.05956(12) 0.10769(12) 0.42028(9) 0.0511(4) Uani 1 1 d . . .
Ag2 Ag 0.14817(13) 0.07143(12) 0.03929(9) 0.0561(4) Uani 1 1 d . . .
Ag3 Ag 0.04959(11) 0.02823(12) 0.19730(9) 0.0502(4) Uani 1 1 d . . .
Ag4 Ag 0.20934(13) -0.03981(13) 0.13340(9) 0.0591(5) Uani 1 1 d . . .
Ag5 Ag -0.12504(14) -0.08391(13) 0.29644(10) 0.0665(5) Uani 1 1 d . . .
Ag6 Ag 0.21083(13) 0.07116(14) 0.33675(9) 0.0608(5) Uani 1 1 d . . .
Ag7 Ag 0.17590(15) 0.25168(14) 0.20880(10) 0.0691(5) Uani 1 1 d . . .
Ag8 Ag -0.05718(15) 0.13294(13) 0.28589(10) 0.0678(5) Uani 1 1 d . . .
Ag9 Ag -0.12673(14) -0.01230(16) 0.47848(11) 0.0760(6) Uani 1 1 d . . .
Ag10 Ag 0.12842(15) 0.19001(14) -0.06265(9) 0.0698(5) Uani 1 1 d . . .
Ag11 Ag 0.0320(3) -0.1305(3) -0.1035(2) 0.0723(11) Uani 0.50 1 d PU . 1
Ag11 Ag 0.0066(3) -0.1624(3) -0.0622(3) 0.0720(11) Uani 0.50 1 d PU . 2
C1 C 0.1985(16) 0.3632(15) 0.3866(10) 0.053(5) Uiso 1 1 d D . .
C2 C 0.2538(16) 0.4529(14) 0.4728(10) 0.093(8) Uiso 1 1 d D . .
C3 C 0.3115(14) -0.0841(17) 0.2665(14) 0.059(6) Uiso 1 1 d D . .
C4 C 0.3748(15) -0.1372(15) 0.2827(10) 0.089(8) Uiso 1 1 d D . .
C5 C -0.018(2) 0.3341(19) 0.2516(16) 0.081(7) Uiso 1 1 d D . .
C6 C 0.0008(19) 0.454(2) 0.2889(15) 0.144(13) Uiso 1 1 d D . .
C7 C 0.0238(15) -0.1998(13) 0.1944(12) 0.050(5) Uiso 1 1 d D . .
C8 C 0.0194(13) -0.3085(12) 0.1868(10) 0.076(7) Uiso 1 1 d D . .
C9 C -0.2522(15) -0.3370(15) 0.1723(13) 0.055(5) Uiso 1 1 d D . .
C10 C -0.3263(16) -0.4580(14) 0.1603(11) 0.097(8) Uiso 1 1 d D . .
C11 C 0.1676(15) -0.0679(15) 0.0039(11) 0.056(5) Uiso 1 1 d D . .
C12 C 0.2047(16) -0.1334(16) -0.0052(11) 0.060(6) Uiso 1 1 d D . .
C13 C 0.2528(16) -0.2056(16) -0.0273(10) 0.068(6) Uiso 1 1 d D . .
C14 C 0.184(2) -0.302(2) -0.0057(18) 0.143(12) Uiso 1 1 d D . .
H14A H 0.1117 -0.3424 -0.0375 0.215 Uiso 1 1 calc R . .
H14B H 0.1845 -0.2727 0.0498 0.215 Uiso 1 1 calc R . .
H14C H 0.2113 -0.3522 -0.0160 0.215 Uiso 1 1 calc R . .
C15 C 0.241(2) -0.253(2) -0.1178(11) 0.123(10) Uiso 1 1 d D . .
H15A H 0.1680 -0.2895 -0.1453 0.185 Uiso 1 1 calc R . .
H15B H 0.2659 -0.3054 -0.1327 0.185 Uiso 1 1 calc R . .
H15C H 0.2834 -0.1924 -0.1319 0.185 Uiso 1 1 calc R . .
C16 C 0.362(2) -0.142(3) 0.0216(17) 0.134(11) Uiso 1 1 d . . .
H16A H 0.3621 -0.1150 0.0771 0.201 Uiso 1 1 calc R . .
H16B H 0.4039 -0.0799 0.0094 0.201 Uiso 1 1 calc R . .
H16C H 0.3922 -0.1900 0.0105 0.201 Uiso 1 1 calc R . .
C17 C 0.1107(12) 0.0268(14) -0.1650(10) 0.046(5) Uiso 1 1 d D . .
C18 C 0.2121(11) 0.0699(13) -0.1492(9) 0.034(4) Uiso 1 1 d D . .
C19 C 0.3273(14) 0.1130(12) -0.1286(8) 0.061(6) Uiso 1 1 d D . .
C20 C 0.346(2) 0.0155(18) -0.1406(16) 0.116(10) Uiso 1 1 d D . .
H20A H 0.4217 0.0435 -0.1268 0.174 Uiso 1 1 calc R . .
H20B H 0.3166 -0.0383 -0.1955 0.174 Uiso 1 1 calc R . .
H20C H 0.3131 -0.0197 -0.1070 0.174 Uiso 1 1 calc R . .
C21 C 0.380(2) 0.164(2) -0.1851(14) 0.114(10) Uiso 1 1 d D . .
H21A H 0.4549 0.1923 -0.1712 0.171 Uiso 1 1 calc R . .
H21B H 0.3674 0.2242 -0.1801 0.171 Uiso 1 1 calc R . .
H21C H 0.3493 0.1075 -0.2391 0.171 Uiso 1 1 calc R . .
C22 C 0.379(2) 0.2051(18) -0.0428(9) 0.105(9) Uiso 1 1 d D . .
H22A H 0.4541 0.2320 -0.0304 0.158 Uiso 1 1 calc R . .
H22B H 0.3474 0.1749 -0.0064 0.158 Uiso 1 1 calc R . .
H22C H 0.3677 0.2658 -0.0380 0.158 Uiso 1 1 calc R . .
C23 C 0.1591(17) 0.2260(18) 0.0720(12) 0.066(6) Uiso 1 1 d . . .
C24 C 0.1985(16) 0.3255(18) 0.0931(12) 0.061(6) Uiso 1 1 d . . .
C25 C 0.2503(13) 0.4504(16) 0.1180(9) 0.086(7) Uiso 1 1 d D . .
C26 C 0.3498(17) 0.487(2) 0.0853(16) 0.125(10) Uiso 1 1 d D . .
H26A H 0.4006 0.4757 0.1105 0.188 Uiso 1 1 calc R . .
H26B H 0.3810 0.5643 0.0961 0.188 Uiso 1 1 calc R . .
H26C H 0.3301 0.4423 0.0286 0.188 Uiso 1 1 calc R . .
C27 C 0.1699(18) 0.472(2) 0.0817(14) 0.104(9) Uiso 1 1 d D . .
H27A H 0.2009 0.5513 0.0972 0.156 Uiso 1 1 calc R . .
H27B H 0.1068 0.4457 0.1007 0.156 Uiso 1 1 calc R . .
H27C H 0.1517 0.4336 0.0245 0.156 Uiso 1 1 calc R . .
C28 C 0.280(2) 0.508(2) 0.2096(10) 0.105(9) Uiso 1 1 d D . .
H28A H 0.3295 0.4926 0.2306 0.158 Uiso 1 1 calc R . .
H28B H 0.2165 0.4804 0.2284 0.158 Uiso 1 1 calc R . .
H28C H 0.3113 0.5876 0.2272 0.158 Uiso 1 1 calc R . .
C29 C 0.2051(13) 0.1294(16) 0.4645(10) 0.057(5) Uiso 1 1 d D . .
C30 C 0.2946(13) 0.1675(15) 0.5112(10) 0.049(5) Uiso 1 1 d D . .
C31 C 0.4003(14) 0.2263(14) 0.5593(10) 0.068(6) Uiso 1 1 d D . .
C32 C 0.459(3) 0.3519(15) 0.579(2) 0.171(15) Uiso 1 1 d D . .
H32A H 0.4589 0.3617 0.5309 0.257 Uiso 1 1 calc R . .
H32B H 0.5310 0.3865 0.6090 0.257 Uiso 1 1 calc R . .
H32C H 0.4232 0.3862 0.6110 0.257 Uiso 1 1 calc R . .
C33 C 0.466(2) 0.180(3) 0.5136(17) 0.154(13) Uiso 1 1 d D . .
H33A H 0.4731 0.1956 0.4677 0.232 Uiso 1 1 calc R . .
H33B H 0.4300 0.0999 0.4968 0.232 Uiso 1 1 calc R . .
H33C H 0.5350 0.2139 0.5479 0.232 Uiso 1 1 calc R . .
C34 C 0.400(2) 0.199(2) 0.6319(13) 0.121(10) Uiso 1 1 d D . .
H34A H 0.4723 0.2378 0.6633 0.181 Uiso 1 1 calc R . .
H34B H 0.3706 0.1198 0.6140 0.181 Uiso 1 1 calc R . .
H34C H 0.3585 0.2228 0.6637 0.181 Uiso 1 1 calc R . .
C35 C -0.1022(16) 0.0684(17) 0.3911(11) 0.059(5) Uiso 1 1 d . . .
C36 C -0.1421(16) 0.1236(17) 0.4206(11) 0.058(5) Uiso 1 1 d . . .
C37 C -0.1872(13) 0.1994(13) 0.4538(9) 0.074(6) Uiso 1 1 d D . .
C38 C -0.215(2) 0.191(2) 0.5310(12) 0.119(10) Uiso 1 1 d D . .
H38A H -0.2702 0.1156 0.5185 0.179 Uiso 1 1 calc R . .
H38B H -0.2388 0.2420 0.5562 0.179 Uiso 1 1 calc R . .
H38C H -0.1525 0.2089 0.5665 0.179 Uiso 1 1 calc R . .
C39 C -0.2761(17) 0.178(2) 0.3910(13) 0.107(9) Uiso 1 1 d D . .
H39A H -0.3344 0.1029 0.3730 0.160 Uiso 1 1 calc R . .
H39B H -0.2490 0.1885 0.3465 0.160 Uiso 1 1 calc R . .
H39C H -0.3003 0.2300 0.4142 0.160 Uiso 1 1 calc R . .
C40 C -0.0988(16) 0.3208(14) 0.4777(13) 0.088(7) Uiso 1 1 d D . .
H40A H -0.1271 0.3699 0.4962 0.132 Uiso 1 1 calc R . .
H40B H -0.0721 0.3271 0.4322 0.132 Uiso 1 1 calc R . .
H40C H -0.0418 0.3414 0.5195 0.132 Uiso 1 1 calc R . .
C41 C 0.2188(15) 0.1220(15) 0.2330(10) 0.047(5) Uiso 1 1 d . . .
C42 C 0.3139(14) 0.1752(14) 0.2422(10) 0.040(4) Uiso 1 1 d . . .
C43 C 0.4293(16) 0.2455(17) 0.2538(11) 0.055(5) Uiso 1 1 d . . .
C44 C 0.471(3) 0.350(3) 0.321(2) 0.172(15) Uiso 1 1 d . . .
H44A H 0.5464 0.3939 0.3276 0.258 Uiso 1 1 calc R . .
H44B H 0.4585 0.3371 0.3679 0.258 Uiso 1 1 calc R . .
H44C H 0.4368 0.3887 0.3132 0.258 Uiso 1 1 calc R . .
C45 C 0.494(3) 0.187(3) 0.267(2) 0.167(14) Uiso 1 1 d . . .
H45A H 0.5686 0.2354 0.2743 0.250 Uiso 1 1 calc R . .
H45B H 0.4694 0.1174 0.2204 0.250 Uiso 1 1 calc R . .
H45C H 0.4823 0.1717 0.3128 0.250 Uiso 1 1 calc R . .
C46 C 0.447(3) 0.249(3) 0.1775(19) 0.160(14) Uiso 1 1 d . . .
H46A H 0.5221 0.2960 0.1836 0.239 Uiso 1 1 calc R . .
H46B H 0.4086 0.2795 0.1611 0.239 Uiso 1 1 calc R . .
H46C H 0.4231 0.1749 0.1378 0.239 Uiso 1 1 calc R . .
C47 C 0.088(2) 0.270(2) 0.6134(14) 0.100(8) Uiso 1 1 d . . .
H47A H 0.1302 0.3138 0.6677 0.150 Uiso 1 1 calc R . .
H47B H 0.0504 0.3031 0.6010 0.150 Uiso 1 1 calc R . .
H47C H 0.1344 0.2663 0.5782 0.150 Uiso 1 1 calc R . .
O1 O 0.2382(12) 0.3828(11) 0.3359(8) 0.077(4) Uani 1 1 d . . .
O2 O 0.1152(11) 0.2746(11) 0.3806(9) 0.074(4) Uani 1 1 d . . .
O3 O 0.2897(16) -0.0949(15) 0.2013(9) 0.106(6) Uani 1 1 d . . .
O4 O 0.2963(13) -0.0281(14) 0.3257(9) 0.090(5) Uani 1 1 d . . .
O5 O -0.0827(15) 0.2701(14) 0.2819(9) 0.097(5) Uani 1 1 d . . .
O6 O 0.0216(13) 0.3050(12) 0.1988(9) 0.084(5) Uani 1 1 d . . .
O7 O 0.0244(10) -0.1366(10) 0.2602(7) 0.056(3) Uani 1 1 d . . .
O8 O 0.0247(11) -0.1899(11) 0.1285(8) 0.064(4) Uani 1 1 d . . .
O9 O -0.2260(11) -0.2687(11) 0.2430(8) 0.069(4) Uani 1 1 d . . .
O10 O -0.2265(13) -0.3222(13) 0.1125(9) 0.093(5) Uani 1 1 d . . .
O11 O 0.0132(12) 0.1578(13) 0.6031(8) 0.079(4) Uiso 1 1 d . . .
F1 F 0.267(3) 0.5464(19) 0.4740(17) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F2 F 0.3482(18) 0.464(2) 0.4862(17) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F3 F 0.221(2) 0.421(2) 0.5282(14) 0.109(4) Uiso 0.550(13) 1 d PD A 1
F1' F 0.184(2) 0.469(3) 0.5099(18) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F2' F 0.327(2) 0.5542(19) 0.488(2) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F3' F 0.295(3) 0.423(3) 0.5168(18) 0.109(4) Uiso 0.450(13) 1 d PD A 2
F4 F 0.360(3) -0.2268(19) 0.2227(14) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F5 F 0.368(3) -0.144(3) 0.3506(13) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F6 F 0.4751(17) -0.073(2) 0.2896(18) 0.100(4) Uiso 0.524(15) 1 d PD B 1
F4' F 0.389(3) -0.187(3) 0.2139(13) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F5' F 0.319(2) -0.215(2) 0.306(2) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F6' F 0.453(2) -0.069(2) 0.3468(15) 0.100(4) Uiso 0.476(15) 1 d PD B 2
F7 F 0.101(2) 0.533(3) 0.320(3) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F8 F -0.058(3) 0.467(4) 0.338(3) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F9 F -0.023(5) 0.476(4) 0.231(2) 0.147(6) Uiso 0.46(3) 1 d PD C 1
F7' F 0.045(4) 0.499(3) 0.242(2) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F8' F 0.074(3) 0.493(3) 0.3529(18) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F9' F -0.088(2) 0.453(3) 0.297(3) 0.147(6) Uiso 0.54(3) 1 d PD C 2
F10 F 0.0751(18) -0.2870(18) 0.2544(11) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F11 F 0.055(2) -0.3544(19) 0.1299(12) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F12 F -0.0762(14) -0.3887(17) 0.1760(15) 0.086(3) Uiso 0.586(11) 1 d PD D 1
F10' F -0.047(2) -0.355(3) 0.2245(19) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F11' F 0.1107(17) -0.303(3) 0.198(2) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F12' F -0.035(3) -0.391(2) 0.1160(12) 0.086(3) Uiso 0.414(11) 1 d PD D 2
F13 F -0.348(3) -0.532(2) 0.0878(12) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F14 F -0.409(2) -0.465(2) 0.1887(17) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F15 F -0.280(2) -0.488(2) 0.2024(16) 0.111(4) Uiso 0.560(16) 1 d PD E 1
F13' F -0.300(3) -0.528(3) 0.114(2) 0.111(4) Uiso 0.440(16) 1 d PD E 2
F14' F -0.421(2) -0.496(3) 0.120(2) 0.111(4) Uiso 0.440(16) 1 d PD E 2
F15' F -0.323(3) -0.473(3) 0.2254(15) 0.111(4) Uiso 0.440(16) 1 d PD E 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C29 Ag1 C35 167.9(7) . .
C29 Ag1 Ag6 50.2(5) . .
C35 Ag1 Ag6 137.7(5) . .
C29 Ag1 Ag5 131.0(5) . .
C35 Ag1 Ag5 48.3(5) . .
Ag6 Ag1 Ag5 94.26(7) . .
C29 Ag1 Ag9 118.2(5) . .
C35 Ag1 Ag9 49.6(5) . .
Ag6 Ag1 Ag9 140.34(7) . .
Ag5 Ag1 Ag9 64.94(6) . .
C29 Ag1 Ag9 46.9(5) . 2_556
C35 Ag1 Ag9 121.2(5) . 2_556
Ag6 Ag1 Ag9 82.66(6) . 2_556
Ag5 Ag1 Ag9 105.06(7) . 2_556
Ag9 Ag1 Ag9 71.93(7) . 2_556
C29 Ag1 Ag8 141.5(5) . .
C35 Ag1 Ag8 50.5(5) . .
Ag6 Ag1 Ag8 96.45(6) . .
Ag5 Ag1 Ag8 58.68(6) . .
Ag9 Ag1 Ag8 99.74(7) . .
Ag9 Ag1 Ag8 163.68(7) 2_556 .
C23 Ag2 C11 168.7(8) . .
C23 Ag2 Ag11 130.7(6) . .
C11 Ag2 Ag11 53.3(5) . .
C23 Ag2 Ag11 141.0(6) . .
C11 Ag2 Ag11 47.3(5) . .
Ag11 Ag2 Ag11 20.82(9) . .
C23 Ag2 Ag11 43.3(6) . 2
C11 Ag2 Ag11 147.6(5) . 2
Ag11 Ag2 Ag11 102.38(12) . 2
Ag11 Ag2 Ag11 101.93(11) . 2
C23 Ag2 Ag10 49.1(6) . .
C11 Ag2 Ag10 127.6(5) . .
Ag11 Ag2 Ag10 85.74(10) . .
Ag11 Ag2 Ag10 103.72(11) . .
Ag11 Ag2 Ag10 60.77(10) 2 .
C23 Ag2 Ag4 133.8(6) . .
C11 Ag2 Ag4 46.9(5) . .
Ag11 Ag2 Ag4 94.50(10) . .
Ag11 Ag2 Ag4 78.84(10) . .
Ag11 Ag2 Ag4 129.59(11) 2 .
Ag10 Ag2 Ag4 169.01(7) . .
C23 Ag2 Ag7 49.4(6) . .
C11 Ag2 Ag7 132.9(5) . .
Ag11 Ag2 Ag7 154.99(12) . .
Ag11 Ag2 Ag7 138.48(11) . .
Ag11 Ag2 Ag7 59.89(9) 2 .
Ag10 Ag2 Ag7 98.38(6) . .
Ag4 Ag2 Ag7 86.05(6) . .
C23 Ag2 Ag11 55.1(6) . 2
C11 Ag2 Ag11 136.1(6) . 2
Ag11 Ag2 Ag11 104.62(11) . 2
Ag11 Ag2 Ag11 97.51(11) . 2
Ag11 Ag2 Ag11 18.46(8) 2 2
Ag10 Ag2 Ag11 79.20(9) . 2
Ag4 Ag2 Ag11 111.26(10) . 2
Ag7 Ag2 Ag11 52.76(8) . 2
C17 Ag3 C41 166.2(7) 2 .
C17 Ag3 Ag8 54.8(5) 2 .
C41 Ag3 Ag8 116.1(5) . .
C17 Ag3 Ag7 110.4(5) 2 .
C41 Ag3 Ag7 56.0(5) . .
Ag8 Ag3 Ag7 79.57(6) . .
C17 Ag3 Ag4 138.5(5) 2 .
C41 Ag3 Ag4 50.9(5) . .
Ag8 Ag3 Ag4 166.75(7) . .
Ag7 Ag3 Ag4 92.73(6) . .
C17 Ag3 Ag10 50.5(5) 2 2
C41 Ag3 Ag10 138.7(5) . 2
Ag8 Ag3 Ag10 104.85(7) . 2
Ag7 Ag3 Ag10 132.34(7) . 2
Ag4 Ag3 Ag10 88.32(6) . 2
C17 Ag3 Ag6 138.5(5) 2 .
C41 Ag3 Ag6 48.0(5) . .
Ag8 Ag3 Ag6 99.35(7) . .
Ag7 Ag3 Ag6 92.87(6) . .
Ag4 Ag3 Ag6 70.06(5) . .
Ag10 Ag3 Ag6 131.41(7) 2 .
C17 Ag3 Ag11 59.3(5) 2 2
C41 Ag3 Ag11 108.9(5) . 2
Ag8 Ag3 Ag11 68.61(9) . 2
Ag7 Ag3 Ag11 56.23(9) . 2
Ag4 Ag3 Ag11 115.97(10) . 2
Ag10 Ag3 Ag11 80.77(9) 2 2
Ag6 Ag3 Ag11 147.76(9) . 2
C17 Ag3 Ag5 57.0(5) 2 .
C41 Ag3 Ag5 129.3(5) . .
Ag8 Ag3 Ag5 56.61(5) . .
Ag7 Ag3 Ag5 133.93(7) . .
Ag4 Ag3 Ag5 126.92(6) . .
Ag10 Ag3 Ag5 77.47(6) 2 .
Ag6 Ag3 Ag5 81.95(6) . .
Ag11 Ag3 Ag5 111.75(10) 2 .
O3 Ag4 C11 136.6(6) . .
O3 Ag4 C41 104.5(6) . .
C11 Ag4 C41 116.4(6) . .
O3 Ag4 C12 105.4(5) . .
C11 Ag4 C12 31.3(3) . .
C41 Ag4 C12 145.7(6) . .
O3 Ag4 O8 91.2(6) . .
C11 Ag4 O8 95.6(6) . .
C41 Ag4 O8 99.6(5) . .
C12 Ag4 O8 96.2(6) . .
O3 Ag4 C42 94.3(6) . .
C11 Ag4 C42 115.7(6) . .
C41 Ag4 C42 26.6(5) . .
C12 Ag4 C42 134.0(6) . .
O8 Ag4 C42 125.0(5) . .
O3 Ag4 Ag3 120.4(4) . .
C11 Ag4 Ag3 99.8(4) . .
C41 Ag4 Ag3 43.8(5) . .
C12 Ag4 Ag3 127.1(4) . .
O8 Ag4 Ag3 60.2(3) . .
C42 Ag4 Ag3 70.2(4) . .
O3 Ag4 Ag2 167.6(5) . .
C11 Ag4 Ag2 41.8(4) . .
C41 Ag4 Ag2 74.7(4) . .
C12 Ag4 Ag2 72.5(4) . .
O8 Ag4 Ag2 101.1(3) . .
C42 Ag4 Ag2 79.6(3) . .
Ag3 Ag4 Ag2 67.81(5) . .
C35 Ag5 O9 142.9(7) . .
C35 Ag5 Ag1 47.4(5) . .
O9 Ag5 Ag1 144.5(4) . .
C35 Ag5 Ag8 54.1(5) . .
O9 Ag5 Ag8 149.5(4) . .
Ag1 Ag5 Ag8 65.39(6) . .
C35 Ag5 Ag9 46.4(5) . .
O9 Ag5 Ag9 103.5(4) . .
Ag1 Ag5 Ag9 58.95(5) . .
Ag8 Ag5 Ag9 100.21(6) . .
C35 Ag5 Ag3 99.7(5) . .
O9 Ag5 Ag3 117.1(4) . .
Ag1 Ag5 Ag3 75.32(6) . .
Ag8 Ag5 Ag3 52.87(5) . .
Ag9 Ag5 Ag3 134.08(7) . .
C29 Ag6 O4 103.9(6) . .
C29 Ag6 C41 141.3(7) . .
O4 Ag6 C41 109.7(6) . .
C29 Ag6 Ag1 45.6(4) . .
O4 Ag6 Ag1 137.8(4) . .
C41 Ag6 Ag1 110.7(4) . .
C29 Ag6 Ag3 125.5(4) . .
O4 Ag6 Ag3 124.1(4) . .
C41 Ag6 Ag3 43.5(5) . .
Ag1 Ag6 Ag3 80.13(6) . .
O1 Ag7 C23 143.2(6) . .
O1 Ag7 C41 96.8(5) . .
C23 Ag7 C41 112.6(6) . .
O1 Ag7 C24 116.8(6) . .
C23 Ag7 C24 26.5(6) . .
C41 Ag7 C24 132.6(6) . .
O1 Ag7 Ag11 129.9(4) . 2
C23 Ag7 Ag11 60.7(5) . 2
C41 Ag7 Ag11 110.0(5) . 2
C24 Ag7 Ag11 74.1(5) . 2
O1 Ag7 Ag3 112.3(4) . .
C23 Ag7 Ag3 104.0(5) . .
C41 Ag7 Ag3 46.1(4) . .
C24 Ag7 Ag3 129.8(5) . .
Ag11 Ag7 Ag3 67.04(10) 2 .
O1 Ag7 Ag11 136.3(4) . 2
C23 Ag7 Ag11 42.7(5) . 2
C41 Ag7 Ag11 119.9(4) . 2
C24 Ag7 Ag11 54.9(5) . 2
Ag11 Ag7 Ag11 19.29(10) 2 2
Ag3 Ag7 Ag11 82.60(10) . 2
O1 Ag7 Ag2 164.6(4) . .
C23 Ag7 Ag2 40.8(5) . .
C41 Ag7 Ag2 73.2(4) . .
C24 Ag7 Ag2 66.1(4) . .
Ag11 Ag7 Ag2 65.38(10) 2 .
Ag3 Ag7 Ag2 69.39(6) . .
Ag11 Ag7 Ag2 58.67(8) 2 .
O5 Ag8 C17 118.1(6) . 2
O5 Ag8 O2 89.4(6) . .
C17 Ag8 O2 132.8(5) 2 .
O5 Ag8 C35 120.6(6) . .
C17 Ag8 C35 107.6(6) 2 .
O2 Ag8 C35 85.6(6) . .
O5 Ag8 Ag3 130.7(4) . .
C17 Ag8 Ag3 45.5(4) 2 .
O2 Ag8 Ag3 87.4(4) . .
C35 Ag8 Ag3 108.3(5) . .
O5 Ag8 Ag5 153.9(5) . .
C17 Ag8 Ag5 62.8(4) 2 .
O2 Ag8 Ag5 108.7(3) . .
C35 Ag8 Ag5 45.8(5) . .
Ag3 Ag8 Ag5 70.52(6) . .
O5 Ag8 Ag1 134.2(4) . .
C17 Ag8 Ag1 107.4(4) 2 .
O2 Ag8 Ag1 53.6(3) . .
C35 Ag8 Ag1 42.3(5) . .
Ag3 Ag8 Ag1 79.10(6) . .
Ag5 Ag8 Ag1 55.93(5) . .
C29 Ag9 C35 160.7(7) 2_556 .
C29 Ag9 C30 30.1(3) 2_556 2_556
C35 Ag9 C30 130.9(6) . 2_556
C29 Ag9 O11 98.4(5) 2_556 .
C35 Ag9 O11 99.1(6) . .
C30 Ag9 O11 121.6(5) 2_556 .
C29 Ag9 C36 145.6(6) 2_556 .
C35 Ag9 C36 26.5(6) . .
C30 Ag9 C36 119.9(6) 2_556 .
O11 Ag9 C36 90.3(5) . .
C29 Ag9 Ag1 149.4(4) 2_556 .
C35 Ag9 Ag1 45.6(5) . .
C30 Ag9 Ag1 161.8(4) 2_556 .
O11 Ag9 Ag1 74.3(3) . .
C36 Ag9 Ag1 64.9(4) . .
C29 Ag9 Ag1 42.4(4) 2_556 2_556
C35 Ag9 Ag1 152.9(5) . 2_556
C30 Ag9 Ag1 71.4(4) 2_556 2_556
O11 Ag9 Ag1 74.2(3) . 2_556
C36 Ag9 Ag1 164.4(4) . 2_556
Ag1 Ag9 Ag1 108.07(7) . 2_556
C29 Ag9 Ag5 125.8(5) 2_556 .
C35 Ag9 Ag5 43.4(5) . .
C30 Ag9 Ag5 108.0(4) 2_556 .
O11 Ag9 Ag5 130.2(3) . .
C36 Ag9 Ag5 66.8(4) . .
Ag1 Ag9 Ag5 56.11(5) . .
Ag1 Ag9 Ag5 122.10(8) 2_556 .
C23 Ag10 O10 124.0(7) . 2
C23 Ag10 C17 122.8(7) . .
O10 Ag10 C17 99.3(5) 2 .
C23 Ag10 O8 121.0(6) . 2
O10 Ag10 O8 82.5(5) 2 2
C17 Ag10 O8 98.0(5) . 2
C23 Ag10 C24 26.8(6) . .
O10 Ag10 C24 99.1(6) 2 .
C17 Ag10 C24 146.1(6) . .
O8 Ag10 C24 112.4(5) 2 .
C23 Ag10 C18 113.8(6) . .
O10 Ag10 C18 85.5(5) 2 .
C17 Ag10 C18 28.2(3) . .
O8 Ag10 C18 120.6(4) 2 .
C24 Ag10 C18 126.9(5) . .
C23 Ag10 Ag3 125.1(6) . 2
O10 Ag10 Ag3 110.8(4) 2 2
C17 Ag10 Ag3 42.2(4) . 2
O8 Ag10 Ag3 60.7(3) 2 2
C24 Ag10 Ag3 147.2(5) . 2
C18 Ag10 Ag3 70.3(3) . 2
C23 Ag10 Ag2 42.2(5) . .
O10 Ag10 Ag2 144.0(4) 2 .
C17 Ag10 Ag2 80.7(4) . .
O8 Ag10 Ag2 133.4(3) 2 .
C24 Ag10 Ag2 67.9(4) . .
C18 Ag10 Ag2 77.8(3) . .
Ag3 Ag10 Ag2 93.38(7) 2 .
C23 Ag10 Ag11 42.9(5) . 2
O10 Ag10 Ag11 140.7(4) 2 2
C17 Ag10 Ag11 118.5(4) . 2
O8 Ag10 Ag11 81.9(3) 2 2
C24 Ag10 Ag11 55.2(5) . 2
C18 Ag10 Ag11 133.1(3) . 2
Ag3 Ag10 Ag11 92.24(9) 2 2
Ag2 Ag10 Ag11 59.61(9) . 2
O6 Ag11 C11 114.0(6) 2 .
O6 Ag11 C23 85.7(6) 2 2
C11 Ag11 C23 110.5(7) . 2
O6 Ag11 Ag2 160.1(4) 2 .
C11 Ag11 Ag2 46.2(4) . .
C23 Ag11 Ag2 101.3(5) 2 .
O6 Ag11 Ag7 62.6(4) 2 2
C11 Ag11 Ag7 160.5(5) . 2
C23 Ag11 Ag7 51.3(4) 2 2
Ag2 Ag11 Ag7 135.69(15) . 2
O6 Ag11 Ag3 102.7(4) 2 2
C11 Ag11 Ag3 138.4(5) . 2
C23 Ag11 Ag3 90.5(4) 2 2
Ag2 Ag11 Ag3 95.85(12) . 2
Ag7 Ag11 Ag3 56.74(8) 2 2
O6 Ag11 Ag2 119.0(5) 2 2
C11 Ag11 Ag2 109.8(5) . 2
C23 Ag11 Ag2 39.2(5) 2 2
Ag2 Ag11 Ag2 75.38(11) . 2
Ag7 Ag11 Ag2 61.86(9) 2 2
Ag3 Ag11 Ag2 64.81(8) 2 2
C11 Ag11 C23 152.8(8) . 2
C11 Ag11 O6 112.3(6) . 2
C23 Ag11 O6 93.5(7) 2 2
C11 Ag11 Ag2 46.4(4) . .
C23 Ag11 Ag2 117.3(6) 2 .
O6 Ag11 Ag2 139.1(4) 2 .
C11 Ag11 Ag2 123.5(5) . 2
C23 Ag11 Ag2 42.1(6) 2 2
O6 Ag11 Ag2 117.8(4) 2 2
Ag2 Ag11 Ag2 78.07(11) . 2
C11 Ag11 Ag10 105.6(5) . 2
C23 Ag11 Ag10 48.3(5) 2 2
O6 Ag11 Ag10 129.2(4) 2 2
Ag2 Ag11 Ag10 91.73(12) . 2
Ag2 Ag11 Ag10 59.62(9) 2 2
C11 Ag11 Ag7 153.6(5) . 2
C23 Ag11 Ag7 50.3(5) 2 2
O6 Ag11 Ag7 56.4(4) 2 2
Ag2 Ag11 Ag7 123.78(15) . 2
Ag2 Ag11 Ag7 61.44(9) 2 2
Ag10 Ag11 Ag7 98.65(12) 2 2
O1 C1 O2 129.0(17) . .
O1 C1 C2 117.4(19) . .
O2 C1 C2 113.5(17) . .
F2' C2 F3' 105(3) . .
F2' C2 F3 123(2) . .
F3' C2 F3 49.8(18) . .
F2' C2 F1 38.1(17) . .
F3' C2 F1 137(3) . .
F3 C2 F1 122(2) . .
F2' C2 F2 70(2) . .
F3' C2 F2 48.7(19) . .
F3 C2 F2 97(2) . .
F1 C2 F2 108(2) . .
F2' C2 F1' 103(3) . .
F3' C2 F1' 103(2) . .
F3 C2 F1' 54.3(17) . .
F1 C2 F1' 76(2) . .
F2 C2 F1' 142(2) . .
F2' C2 C1 121(2) . .
F3' C2 C1 113(2) . .
F3 C2 C1 116(2) . .
F1 C2 C1 107.1(19) . .
F2 C2 C1 104.7(19) . .
F1' C2 C1 111(2) . .
O3 C3 O4 127.2(18) . .
O3 C3 C4 117.9(19) . .
O4 C3 C4 114.6(18) . .
F6 C4 F5' 137(2) . .
F6 C4 F5 106(2) . .
F5' C4 F5 43.9(16) . .
F6 C4 F6' 50.6(16) . .
F5' C4 F6' 99(2) . .
F5 C4 F6' 57.6(18) . .
F6 C4 F4 98(2) . .
F5' C4 F4 79(2) . .
F5 C4 F4 116(2) . .
F6' C4 F4 129(2) . .
F6 C4 F4' 77(2) . .
F5' C4 F4' 107(2) . .
F5 C4 F4' 140(2) . .
F6' C4 F4' 122(3) . .
F4 C4 F4' 28.1(19) . .
F6 C4 C3 109.7(19) . .
F5' C4 C3 111(2) . .
F5 C4 C3 110.0(19) . .
F6' C4 C3 112.4(19) . .
F4 C4 C3 116(2) . .
F4' C4 C3 106(2) . .
O6 C5 O5 126(2) . .
O6 C5 C6 122(2) . .
O5 C5 C6 112(2) . .
F9' C6 F7 132(3) . .
F9' C6 F7' 113(3) . .
F7 C6 F7' 65(2) . .
F9' C6 F9 77(3) . .
F7 C6 F9 100(3) . .
F7' C6 F9 39(2) . .
F9' C6 F8 34(2) . .
F7 C6 F8 112(3) . .
F7' C6 F8 137(3) . .
F9 C6 F8 108(3) . .
F9' C6 F8' 119(3) . .
F7 C6 F8' 44(2) . .
F7' C6 F8' 109(3) . .
F9 C6 F8' 143(3) . .
F8 C6 F8' 85(3) . .
F9' C6 C5 111(3) . .
F7 C6 C5 115(3) . .
F7' C6 C5 106(3) . .
F9 C6 C5 108(3) . .
F8 C6 C5 113(3) . .
F8' C6 C5 98(2) . .
O7 C7 O8 129.6(15) . .
O7 C7 C8 118.0(16) . .
O8 C7 C8 112.4(16) . .
F11' C8 F12 131(2) . .
F11' C8 F10' 116(2) . .
F12 C8 F10' 37.2(15) . .
F11' C8 F11 56.0(16) . .
F12 C8 F11 104.2(18) . .
F10' C8 F11 129(2) . .
F11' C8 F12' 105(2) . .
F12 C8 F12' 58.9(17) . .
F10' C8 F12' 95(2) . .
F11 C8 F12' 52.0(16) . .
F11' C8 F10 53.8(16) . .
F12 C8 F10 106.2(18) . .
F10' C8 F10 72.2(19) . .
F11 C8 F10 107.1(17) . .
F12' C8 F10 140(2) . .
F11' C8 C7 115.7(19) . .
F12 C8 C7 113.4(16) . .
F10' C8 C7 110.5(19) . .
F11 C8 C7 117.7(17) . .
F12' C8 C7 112.1(19) . .
F10 C8 C7 107.6(16) . .
O9 C9 O10 130.4(18) . .
O9 C9 C10 112.2(17) . .
O10 C9 C10 117.4(19) . .
F14' C10 F15' 115(3) . .
F14' C10 F13 68(2) . .
F15' C10 F13 127(3) . .
F14' C10 F13' 101(3) . .
F15' C10 F13' 103(3) . .
F13 C10 F13' 35.4(18) . .
F14' C10 F14 53.3(17) . .
F15' C10 F14 68(2) . .
F13 C10 F14 116(2) . .
F13' C10 F14 137(3) . .
F14' C10 F15 138(3) . .
F15' C10 F15 37.5(18) . .
F13 C10 F15 102(2) . .
F13' C10 F15 70(2) . .
F14 C10 F15 104(2) . .
F14' C10 C9 110(2) . .
F15' C10 C9 114(2) . .
F13 C10 C9 113(2) . .
F13' C10 C9 113(2) . .
F14 C10 C9 109.7(19) . .
F15 C10 C9 111(2) . .
C12 C11 Ag2 164.4(17) . .
C12 C11 Ag11 109.2(15) . .
Ag2 C11 Ag11 86.4(6) . .
C12 C11 Ag4 80.3(12) . .
Ag2 C11 Ag4 91.4(7) . .
Ag11 C11 Ag4 120.3(9) . .
C12 C11 Ag11 113.7(14) . .
Ag2 C11 Ag11 80.5(6) . .
Ag11 C11 Ag11 26.5(3) . .
Ag4 C11 Ag11 145.5(9) . .
C11 C12 C13 170(2) . .
C11 C12 Ag4 68.4(12) . .
C13 C12 Ag4 119.9(12) . .
C16 C13 C12 108.9(19) . .
C16 C13 C14 110(2) . .
C12 C13 C14 103.7(18) . .
C16 C13 C15 115(2) . .
C12 C13 C15 109.6(18) . .
C14 C13 C15 109(2) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 Ag3 172.4(14) . 2
C18 C17 Ag8 101.0(12) . 2
Ag3 C17 Ag8 79.8(5) 2 2
C18 C17 Ag10 90.7(11) . .
Ag3 C17 Ag10 87.2(6) 2 .
Ag8 C17 Ag10 164.4(7) 2 .
C17 C18 C19 175.6(16) . .
C17 C18 Ag10 61.0(10) . .
C19 C18 Ag10 120.3(10) . .
C18 C19 C21 109.8(16) . .
C18 C19 C22 110.7(15) . .
C21 C19 C22 108.0(17) . .
C18 C19 C20 109.2(16) . .
C21 C19 C20 107.3(17) . .
C22 C19 C20 111.7(17) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C19 C21 H21A 109.5 . .
C19 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C19 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 Ag2 159.5(19) . .
C24 C23 Ag11 105.9(17) . 2
Ag2 C23 Ag11 94.6(9) . 2
C24 C23 Ag10 92.3(15) . .
Ag2 C23 Ag10 88.7(8) . .
Ag11 C23 Ag10 88.8(8) 2 .
C24 C23 Ag7 90.6(15) . .
Ag2 C23 Ag7 89.8(7) . .
Ag11 C23 Ag7 86.9(7) 2 .
Ag10 C23 Ag7 175.3(11) . .
C24 C23 Ag11 113.5(16) . 2
Ag2 C23 Ag11 85.7(7) . 2
Ag11 C23 Ag11 20.9(3) 2 2
Ag10 C23 Ag11 107.4(8) . 2
Ag7 C23 Ag11 68.1(5) . 2
C23 C24 C25 178(2) . .
C23 C24 Ag10 60.8(13) . .
C25 C24 Ag10 118.2(12) . .
C23 C24 Ag7 62.9(13) . .
C25 C24 Ag7 118.2(12) . .
Ag10 C24 Ag7 123.6(8) . .
C24 C25 C27 108.1(16) . .
C24 C25 C28 107.6(17) . .
C27 C25 C28 111.4(17) . .
C24 C25 C26 107.5(17) . .
C27 C25 C26 110.6(18) . .
C28 C25 C26 111.4(17) . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 C27 H27A 109.5 . .
C25 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C25 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C25 C28 H28A 109.5 . .
C25 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C25 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C30 C29 Ag1 161.4(16) . .
C30 C29 Ag6 111.7(14) . .
Ag1 C29 Ag6 84.2(6) . .
C30 C29 Ag9 88.5(13) . 2_556
Ag1 C29 Ag9 90.7(7) . 2_556
Ag6 C29 Ag9 123.3(8) . 2_556
C29 C30 C31 170(2) . .
C29 C30 Ag9 61.5(11) . 2_556
C31 C30 Ag9 128.3(12) . 2_556
C30 C31 C34 110.1(17) . .
C30 C31 C33 109.3(18) . .
C34 C31 C33 102.9(19) . .
C30 C31 C32 113.0(19) . .
C34 C31 C32 114.7(19) . .
C33 C31 C32 106(2) . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 H33A 109.5 . .
C31 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C31 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C31 C34 H34A 109.5 . .
C31 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C31 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C36 C35 Ag1 129.4(17) . .
C36 C35 Ag5 146.1(18) . .
Ag1 C35 Ag5 84.3(7) . .
C36 C35 Ag9 95.4(15) . .
Ag1 C35 Ag9 84.8(7) . .
Ag5 C35 Ag9 90.2(7) . .
C36 C35 Ag8 96.6(15) . .
Ag1 C35 Ag8 87.1(7) . .
Ag5 C35 Ag8 80.1(6) . .
Ag9 C35 Ag8 168.0(10) . .
C35 C36 C37 175(2) . .
C35 C36 Ag9 58.1(12) . .
C37 C36 Ag9 126.8(12) . .
C36 C37 C40 108.3(16) . .
C36 C37 C38 106.8(16) . .
C40 C37 C38 107.0(16) . .
C36 C37 C39 112.5(16) . .
C40 C37 C39 104.9(17) . .
C38 C37 C39 117.0(18) . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C37 C39 H39A 109.5 . .
C37 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C37 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C37 C40 H40A 109.5 . .
C37 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C37 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C42 C41 Ag3 170.3(15) . .
C42 C41 Ag6 100.9(13) . .
Ag3 C41 Ag6 88.4(7) . .
C42 C41 Ag4 91.0(13) . .
Ag3 C41 Ag4 85.3(6) . .
Ag6 C41 Ag4 97.9(6) . .
C42 C41 Ag7 97.3(13) . .
Ag3 C41 Ag7 77.9(6) . .
Ag6 C41 Ag7 131.9(8) . .
Ag4 C41 Ag7 126.0(7) . .
C41 C42 C43 176.8(18) . .
C41 C42 Ag4 62.3(11) . .
C43 C42 Ag4 120.1(11) . .
C44 C43 C46 117(2) . .
C44 C43 C42 111(2) . .
C46 C43 C42 107.6(19) . .
C44 C43 C45 108(2) . .
C46 C43 C45 101(2) . .
C42 C43 C45 112.3(19) . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C43 C45 H45A 109.5 . .
C43 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C43 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C43 C46 H46A 109.5 . .
C43 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C43 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
O11 C47 H47A 109.5 . .
O11 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
O11 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C1 O1 Ag7 121.0(13) . .
C1 O2 Ag8 137.9(12) . .
C3 O3 Ag4 139.0(14) . .
C3 O4 Ag6 129.4(13) . .
C5 O5 Ag8 116.8(15) . .
C5 O6 Ag11 129.7(16) . 2
C5 O6 Ag11 147.1(17) . 2
Ag11 O6 Ag11 24.31(19) 2 2
C7 O8 Ag10 119.1(11) . 2
C7 O8 Ag4 111.0(11) . .
Ag10 O8 Ag4 115.2(5) 2 .
C9 O9 Ag5 129.0(12) . .
C9 O10 Ag10 146.2(14) . 2
C47 O11 Ag9 130.1(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C29 2.072(16) .
Ag1 C35 2.14(2) .
Ag1 Ag6 2.885(2) .
Ag1 Ag5 2.893(2) .
Ag1 Ag9 2.986(2) .
Ag1 Ag9 3.074(2) 2_556
Ag1 Ag8 3.175(2) .
Ag2 C23 2.07(2) .
Ag2 C11 2.085(16) .
Ag2 Ag11 2.850(4) .
Ag2 Ag11 2.874(4) .
Ag2 Ag11 3.083(4) 2
Ag2 Ag10 3.084(2) .
Ag2 Ag4 3.129(2) .
Ag2 Ag7 3.170(2) .
Ag2 Ag11 3.268(5) 2
Ag3 C17 2.063(15) 2
Ag3 C41 2.124(19) .
Ag3 Ag8 2.849(2) .
Ag3 Ag7 2.879(2) .
Ag3 Ag4 3.058(2) .
Ag3 Ag10 3.065(2) 2
Ag3 Ag6 3.082(2) .
Ag3 Ag11 3.170(4) 2
Ag3 Ag5 3.368(2) .
Ag4 O3 2.255(15) .
Ag4 C11 2.285(18) .
Ag4 C41 2.382(17) .
Ag4 C12 2.423(19) .
Ag4 O8 2.561(13) .
Ag4 C42 2.689(17) .
Ag5 C35 2.17(2) .
Ag5 O9 2.212(13) .
Ag5 Ag8 2.983(2) .
Ag5 Ag9 3.157(3) .
Ag6 C29 2.230(18) .
Ag6 O4 2.285(14) .
Ag6 C41 2.291(17) .
Ag7 O1 2.250(13) .
Ag7 C23 2.41(2) .
Ag7 C41 2.441(17) .
Ag7 C24 2.70(2) .
Ag7 Ag11 2.862(4) 2
Ag7 Ag11 3.122(5) 2
Ag8 O5 2.250(14) .
Ag8 C17 2.364(17) 2
Ag8 O2 2.438(14) .
Ag8 C35 2.453(19) .
Ag9 C29 2.245(19) 2_556
Ag9 C35 2.284(19) .
Ag9 C30 2.555(18) 2_556
Ag9 O11 2.561(15) .
Ag9 C36 2.679(19) .
Ag9 Ag1 3.074(2) 2_556
Ag10 C23 2.33(2) .
Ag10 O10 2.364(17) 2
Ag10 C17 2.369(17) .
Ag10 O8 2.490(13) 2
Ag10 C24 2.67(2) .
Ag10 C18 2.707(15) .
Ag10 Ag3 3.065(2) 2
Ag10 Ag11 3.119(5) 2
Ag11 O6 2.274(15) 2
Ag11 C11 2.317(19) .
Ag11 C23 2.69(2) 2
Ag11 Ag7 2.862(4) 2
Ag11 Ag3 3.170(4) 2
Ag11 Ag2 3.268(5) 2
Ag11 C11 2.115(19) .
Ag11 C23 2.12(2) 2
Ag11 O6 2.513(16) 2
Ag11 Ag2 3.083(4) 2
Ag11 Ag10 3.119(5) 2
Ag11 Ag7 3.122(5) 2
C1 O1 1.18(2) .
C1 O2 1.28(2) .
C1 C2 1.5350(11) .
C2 F2' 1.298(10) .
C2 F3' 1.299(10) .
C2 F3 1.300(10) .
C2 F1 1.302(10) .
C2 F2 1.306(10) .
C2 F1' 1.312(10) .
C3 O3 1.17(2) .
C3 O4 1.22(2) .
C3 C4 1.5350(11) .
C4 F6 1.298(10) .
C4 F5' 1.302(10) .
C4 F5 1.302(10) .
C4 F6' 1.302(10) .
C4 F4 1.305(10) .
C4 F4' 1.306(10) .
C5 O6 1.20(3) .
C5 O5 1.31(3) .
C5 C6 1.5352(11) .
C6 F9' 1.299(10) .
C6 F7 1.303(10) .
C6 F7' 1.304(10) .
C6 F9 1.306(10) .
C6 F8 1.306(10) .
C6 F8' 1.307(10) .
C7 O7 1.239(19) .
C7 O8 1.28(2) .
C7 C8 1.5350(11) .
C8 F11' 1.296(10) .
C8 F12 1.298(10) .
C8 F10' 1.301(10) .
C8 F11 1.306(10) .
C8 F12' 1.310(10) .
C8 F10 1.310(10) .
C9 O9 1.24(2) .
C9 O10 1.25(2) .
C9 C10 1.5351(11) .
C10 F14' 1.301(10) .
C10 F15' 1.302(10) .
C10 F13 1.303(10) .
C10 F13' 1.305(10) .
C10 F14 1.305(10) .
C10 F15 1.307(10) .
C11 C12 1.276(9) .
C12 C13 1.48(2) .
C13 C16 1.46(3) .
C13 C14 1.5350(8) .
C13 C15 1.5350(12) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.281(9) .
C17 Ag3 2.063(15) 2
C17 Ag8 2.364(17) 2
C18 C19 1.47(2) .
C19 C21 1.5349(11) .
C19 C22 1.5350(11) .
C19 C20 1.5350(11) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.20(3) .
C23 Ag11 2.12(2) 2
C23 Ag11 2.69(2) 2
C24 C25 1.51(3) .
C25 C27 1.5350(11) .
C25 C28 1.5350(12) .
C25 C26 1.5350(11) .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 C30 1.281(9) .
C29 Ag9 2.245(19) 2_556
C30 C31 1.42(2) .
C30 Ag9 2.555(18) 2_556
C31 C34 1.5348(11) .
C31 C33 1.5349(11) .
C31 C32 1.5350(12) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
C35 C36 1.20(2) .
C36 C37 1.51(3) .
C37 C40 1.5349(11) .
C37 C38 1.5350(12) .
C37 C39 1.5350(11) .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
C39 H39A 0.9600 .
C39 H39B 0.9600 .
C39 H39C 0.9600 .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 C42 1.20(2) .
C42 C43 1.47(2) .
C43 C44 1.42(3) .
C43 C46 1.47(3) .
C43 C45 1.60(3) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 O11 1.44(3) .
C47 H47A 0.9600 .
C47 H47B 0.9600 .
C47 H47C 0.9600 .
O6 Ag11 2.274(15) 2
O6 Ag11 2.513(16) 2
O8 Ag10 2.490(13) 2
O10 Ag10 2.364(17) 2
