#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:57:29 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180524 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/93/7219333.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219333
loop_
_publ_author_name
'Liu, Xuan-Wen'
'Guo, Rui'
'Liu, He'
'Yu, Ye-Qi'
'Qi, Wei Xi'
'Xu, Jing-Yuan'
'Xie, Cheng-Zhi'
_publ_section_title
;
 Two series of novel 3D potentially porous heterometallic Cu--Ln
 coordination frameworks assembled by 3,4-Pyridinedicarboxylic acid with
 different topologies and channels: syntheses, structures, luminescence
 and magnetic properties
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C4RA13533D
_journal_year                    2015
_chemical_formula_sum            'C42 H50 Cu3 Eu2 N6 O40'
_chemical_formula_weight         1773.42
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-01-15 deposited with the CCDC.
2015-01-19 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 98.79(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.945(3)
_cell_length_b                   30.633(6)
_cell_length_c                   20.585(4)
_cell_measurement_reflns_used    20546
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.8784
_cell_measurement_theta_min      1.6203
_cell_volume                     8690(3)
_computing_cell_refinement       crystalclear
_computing_data_collection       crystalclear
_computing_data_reduction        crystalclear
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'rigaku saturn'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0543
_diffrn_reflns_av_unetI/netI     0.0604
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            59176
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.62
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.222
_exptl_absorpt_correction_T_max  0.7764
_exptl_absorpt_correction_T_min  0.6649
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   crystalclear
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.355
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3508
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_platon_squeeze_details
;
;
_refine_diff_density_max         1.590
_refine_diff_density_min         -1.560
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     895
_refine_ls_number_reflns         15079
_refine_ls_number_restraints     118
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0482
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0555P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1055
_refine_ls_wR_factor_ref         0.1096
_reflns_number_gt                12439
_reflns_number_total             15079
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ra13533d2.cif
_cod_data_source_block           1-Eu
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 
;
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7219333
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.476100(11) 0.051250(5) 0.125140(8) 0.01386(4) Uani 1 1 d DU . .
Eu2 Eu 0.961060(11) 0.190230(6) 0.605080(9) 0.01654(4) Uani 1 1 d D . .
Cu1 Cu 1.00815(3) 0.022150(12) 0.28061(2) 0.01452(9) Uani 1 1 d . . .
Cu2 Cu 0.52689(3) 0.184600(11) 0.38903(2) 0.01146(9) Uani 1 1 d . . .
Cu3 Cu 0.99572(2) 0.342560(11) 0.25863(2) 0.01165(9) Uani 1 1 d . . .
O1 O 0.90071(17) -0.02806(7) 0.37388(12) 0.0245(6) Uani 1 1 d . . .
O2 O 0.91865(14) -0.02833(6) 0.26806(11) 0.0166(6) Uani 1 1 d . . .
O3 O 0.96175(15) -0.12011(7) 0.34556(11) 0.0173(6) Uani 1 1 d . . .
O4 O 0.87651(15) -0.18091(6) 0.33262(11) 0.0143(5) Uani 1 1 d . . .
O5 O 0.56805(15) 0.05088(6) 0.24089(11) 0.0158(5) Uani 1 1 d . . .
O6 O 0.64185(16) 0.07952(8) 0.16359(12) 0.0232(6) Uani 1 1 d . . .
O7 O 0.59964(16) 0.14607(7) 0.28410(12) 0.0212(6) Uani 1 1 d . . .
O8 O 0.62456(15) 0.13610(6) 0.39274(11) 0.0153(5) Uani 1 1 d . . .
O9 O 0.21370(17) 0.15328(9) 0.51476(13) 0.0353(7) Uani 1 1 d . . .
O10 O 0.09711(16) 0.14359(8) 0.42877(12) 0.0293(7) Uani 1 1 d . . .
O11 O 0.10157(15) 0.07107(7) 0.29958(12) 0.0181(6) Uani 1 1 d . . .
O12 O 0.13196(18) 0.04548(8) 0.40188(13) 0.0342(7) Uani 1 1 d . . .
O13 O 0.91595(15) 0.29697(7) 0.29326(12) 0.0169(6) Uani 1 1 d . A .
O14 O 0.88860(17) 0.33748(7) 0.37902(12) 0.0261(6) Uani 1 1 d . A .
O15 O 0.96890(15) 0.25030(8) 0.43953(11) 0.0228(6) Uani 1 1 d . . .
O16 O 0.87956(16) 0.23061(7) 0.51549(11) 0.0218(6) Uani 1 1 d . . .
O17 O 1.08352(15) 0.39204(7) 0.24604(11) 0.0176(5) Uani 1 1 d U A .
O18 O 1.16142(16) 0.39093(7) 0.34920(12) 0.0219(6) Uani 1 1 d . A .
O19 O 1.08069(15) 0.48304(7) 0.32164(12) 0.0201(6) Uani 1 1 d . . .
O20 O 1.17151(16) 0.54210(7) 0.32649(14) 0.0279(7) Uani 1 1 d . . .
O21 O 0.80764(16) 0.21834(8) 0.64039(12) 0.0262(6) Uani 1 1 d . . .
O22 O 0.91684(15) 0.19140(7) 0.71897(12) 0.0174(6) Uani 1 1 d . . .
O23 O 0.90866(15) 0.28405(7) 0.77031(12) 0.0209(6) Uani 1 1 d . . .
O24 O 0.92754(15) 0.26665(6) 0.87697(12) 0.0179(6) Uani 1 1 d . . .
O25 O 0.54670(18) 0.18632(7) 0.49891(12) 0.0259(6) Uani 1 1 d D . .
H25A H 0.5047 0.2089 0.5131 0.039 Uiso 1 1 d RD . .
H25B H 0.6146 0.1930 0.5160 0.039 Uiso 1 1 d RD . .
O26 O 0.55908(17) 0.07230(8) 0.03435(13) 0.0338(6) Uani 1 1 d DU . .
H26A H 0.5245(6) 0.0916(3) 0.0124(5) 0.041 Uiso 1 1 d D . .
H26B H 0.6192(5) 0.0778(7) 0.0450(13) 0.041 Uiso 1 1 d D . .
O27 O 0.46027(17) 0.12271(7) 0.17480(12) 0.0249(6) Uani 1 1 d D . .
H27A H 0.4025 0.1240 0.1948 0.030 Uiso 1 1 d RD . .
H27B H 0.5073(5) 0.1277(9) 0.2051(7) 0.030 Uiso 1 1 d D . .
O28 O 0.3627(2) 0.09762(10) 0.05627(15) 0.0584(10) Uani 1 1 d D . .
H28A H 0.3161 0.0797 0.0292 0.088 Uiso 1 1 d RD . .
H28C H 0.3976 0.1150 0.0289 0.088 Uiso 1 1 d R . .
O29 O 0.39101(18) 0.00859(8) 0.03579(12) 0.0293(7) Uani 1 1 d D . .
H29C H 0.3828 -0.0207 0.0508 0.044 Uiso 1 1 d R . .
H29B H 0.382(3) -0.0041(6) -0.0009(6) 0.044 Uiso 1 1 d D . .
O30 O 0.58642(17) -0.00845(7) 0.11481(12) 0.0253(6) Uani 1 1 d D . .
H30B H 0.6384 -0.0073 0.1512 0.030 Uiso 1 1 d RD . .
H30A H 0.5687(10) -0.0346(3) 0.1106(9) 0.030 Uiso 1 1 d D . .
O31 O 0.97674(19) 0.04379(9) 0.17279(13) 0.0384(8) Uani 1 1 d D . .
H31A H 1.0225 0.0301 0.1489 0.058 Uiso 1 1 d RD . .
H31B H 0.9122 0.0350 0.1545 0.058 Uiso 1 1 d RD . .
O32 O 0.97270(17) 0.14316(8) 0.51305(12) 0.0307(7) Uani 1 1 d D . .
H32A H 1.0159(7) 0.1446(5) 0.4881(6) 0.037 Uiso 1 1 d D . .
O33 O 0.83872(16) 0.13196(8) 0.59976(12) 0.0280(7) Uani 1 1 d D . .
H33B H 0.7897 0.1369 0.5624 0.034 Uiso 1 1 d RD . .
H33A H 0.8570(10) 0.1055(3) 0.5961(9) 0.034 Uiso 1 1 d D . .
O34 O 0.99523(17) 0.26347(7) 0.65091(12) 0.0287(7) Uani 1 1 d D . .
H34A H 0.9598 0.2845 0.6220 0.034 Uiso 1 1 d RD . .
H34B H 0.9862(16) 0.2696(6) 0.6893(3) 0.034 Uiso 1 1 d D . .
O35 O 1.08586(17) 0.22078(9) 0.54738(13) 0.0394(8) Uani 1 1 d D . .
H35A H 1.1284(8) 0.2109(4) 0.5257(8) 0.047 Uiso 1 1 d D . .
H35B H 1.0826(8) 0.2481(2) 0.5515(8) 0.047 Uiso 1 1 d D . .
O36 O 0.9791(3) 0.32876(11) 0.15027(19) 0.0154(9) Uani 0.60 1 d P A 1
O36A O 0.9615(5) 0.3042(2) 0.1648(3) 0.0280(17) Uani 0.40 1 d P A 2
N1 N 0.62053(17) -0.11850(8) 0.26359(13) 0.0126(6) Uani 1 1 d . . .
N2 N 0.89757(18) 0.05854(8) 0.30309(14) 0.0145(6) Uani 1 1 d . . .
N3 N 0.41416(18) 0.14372(8) 0.38343(13) 0.0141(6) Uani 1 1 d . . .
N4 N 0.63337(18) 0.22567(8) 0.37777(13) 0.0131(6) Uani 1 1 d . . .
N5 N 0.61282(18) 0.19510(8) 0.77895(14) 0.0154(7) Uani 1 1 d . . .
N6 N 1.38281(19) 0.48325(8) 0.23945(15) 0.0205(7) Uani 1 1 d . . .
C1 C 0.8777(2) -0.04039(9) 0.31692(16) 0.0138(5) Uani 1 1 d U . .
C2 C 0.7892(2) -0.06902(10) 0.29886(16) 0.0152(8) Uani 1 1 d . . .
C3 C 0.7005(2) -0.04969(10) 0.27499(18) 0.0209(9) Uani 1 1 d . . .
H3 H 0.6963 -0.0189 0.2705 0.025 Uiso 1 1 calc R . .
C4 C 0.6186(2) -0.07487(9) 0.25775(16) 0.0149(8) Uani 1 1 d . . .
H4 H 0.5590 -0.0609 0.2412 0.018 Uiso 1 1 calc R . .
C5 C 0.7052(2) -0.13701(10) 0.28820(15) 0.0124(7) Uani 1 1 d . . .
H5 H 0.7060 -0.1677 0.2945 0.015 Uiso 1 1 calc R . .
C6 C 0.7921(2) -0.11463(10) 0.30520(16) 0.0126(7) Uani 1 1 d . . .
C7 C 0.8824(2) -0.13966(10) 0.32945(15) 0.0136(7) Uani 1 1 d . . .
C8 C 0.6403(2) 0.06904(9) 0.22290(16) 0.0135(8) Uani 1 1 d . . .
C9 C 0.7300(2) 0.07657(10) 0.27174(16) 0.0144(5) Uani 1 1 d U . .
C10 C 0.8144(2) 0.05620(10) 0.26073(16) 0.0140(8) Uani 1 1 d . . .
H10 H 0.8135 0.0398 0.2215 0.017 Uiso 1 1 calc R . .
C11 C 0.8993(2) 0.08198(9) 0.35828(16) 0.0152(8) Uani 1 1 d . . .
H11 H 0.9577 0.0838 0.3887 0.018 Uiso 1 1 calc R . .
C12 C 0.8173(2) 0.10367(9) 0.37180(17) 0.0147(8) Uani 1 1 d . . .
H12 H 0.8201 0.1200 0.4113 0.018 Uiso 1 1 calc R . .
C13 C 0.7316(2) 0.10163(9) 0.32813(16) 0.0132(7) Uani 1 1 d . . .
C14 C 0.6436(2) 0.12957(9) 0.33534(17) 0.0145(8) Uani 1 1 d . . .
C15 C 0.1834(2) 0.14278(11) 0.45615(17) 0.0181(8) Uani 1 1 d . . .
C16 C 0.2580(2) 0.12908(10) 0.41416(16) 0.0147(8) Uani 1 1 d . . .
C17 C 0.3457(2) 0.15142(10) 0.42091(16) 0.0149(5) Uani 1 1 d U . .
H17 H 0.3576 0.1733 0.4539 0.018 Uiso 1 1 calc R . .
C18 C 0.3984(2) 0.11247(10) 0.33823(18) 0.0200(6) Uani 1 1 d U . .
H18 H 0.4470 0.1066 0.3117 0.024 Uiso 1 1 calc R . .
C19 C 0.3147(2) 0.08851(11) 0.32852(19) 0.0244(6) Uani 1 1 d U . .
H19 H 0.3060 0.0664 0.2958 0.029 Uiso 1 1 calc R . .
C20 C 0.2414(2) 0.09667(11) 0.36702(17) 0.0199(8) Uani 1 1 d . . .
C21 C 0.1508(2) 0.06923(10) 0.35699(18) 0.0203(8) Uani 1 1 d . . .
C22 C 0.8735(2) 0.30512(10) 0.34222(17) 0.0157(6) Uani 1 1 d U . .
C23 C 0.7933(2) 0.27460(10) 0.35451(16) 0.0151(8) Uani 1 1 d . A .
C24 C 0.7071(2) 0.27595(10) 0.31157(17) 0.0211(8) Uani 1 1 d . . .
H24 H 0.7018 0.2936 0.2732 0.025 Uiso 1 1 calc R A .
C25 C 0.6285(2) 0.25160(10) 0.32428(16) 0.0178(8) Uani 1 1 d . A .
H25 H 0.5693 0.2532 0.2945 0.021 Uiso 1 1 calc R . .
C26 C 0.7176(2) 0.22452(9) 0.41963(16) 0.0136(7) Uani 1 1 d . A .
H26 H 0.7215 0.2065 0.4575 0.016 Uiso 1 1 calc R . .
C27 C 0.7983(2) 0.24813(9) 0.41012(16) 0.0135(5) Uani 1 1 d U . .
C28 C 0.8901(2) 0.24298(10) 0.45895(16) 0.0151(8) Uani 1 1 d . A .
C29 C 1.1510(2) 0.40393(10) 0.29126(18) 0.0180(8) Uani 1 1 d . . .
C30 C 1.2285(2) 0.43355(10) 0.27047(19) 0.0203(9) Uani 1 1 d . A .
C31 C 1.3016(2) 0.41489(10) 0.24069(19) 0.0222(9) Uani 1 1 d . . .
H31 H 1.2997 0.3846 0.2307 0.027 Uiso 1 1 calc R A .
C32 C 1.3764(2) 0.44024(10) 0.22573(18) 0.0196(8) Uani 1 1 d . A .
H32 H 1.4254 0.4270 0.2050 0.024 Uiso 1 1 calc R . .
C33 C 1.3126(2) 0.50109(10) 0.26906(17) 0.0194(8) Uani 1 1 d . A .
H33 H 1.3174 0.5312 0.2804 0.023 Uiso 1 1 calc R . .
C34 C 1.2336(2) 0.47763(10) 0.28388(18) 0.0205(8) Uani 1 1 d . . .
C35 C 1.1566(2) 0.50190(11) 0.31273(18) 0.0210(8) Uani 1 1 d . . .
C36 C 0.8349(2) 0.20854(10) 0.69951(18) 0.0189(8) Uani 1 1 d . . .
C37 C 0.7667(2) 0.21479(9) 0.74827(17) 0.0149(8) Uani 1 1 d . . .
C38 C 0.6761(2) 0.19465(10) 0.73578(18) 0.0168(8) Uani 1 1 d . . .
H38 H 0.6584 0.1800 0.6951 0.020 Uiso 1 1 calc R . .
C39 C 0.6375(2) 0.21759(10) 0.83544(18) 0.0196(8) Uani 1 1 d . . .
H39 H 0.5931 0.2182 0.8661 0.024 Uiso 1 1 calc R . .
C40 C 0.7244(2) 0.23978(10) 0.85073(17) 0.0189(8) Uani 1 1 d . . .
H40 H 0.7386 0.2558 0.8906 0.023 Uiso 1 1 calc R . .
C41 C 0.7906(2) 0.23826(10) 0.80672(16) 0.0151(5) Uani 1 1 d U . .
C42 C 0.8833(2) 0.26495(9) 0.81803(17) 0.0162(8) Uani 1 1 d . . .
O37 O 0.99675(16) 0.41063(7) 0.40566(12) 0.0214(6) Uani 1 1 d DU . .
O38 O 0.92686(18) 0.06114(8) 0.54978(13) 0.0329(7) Uani 1 1 d U . .
H38D H 0.8868 0.0356 0.5436 0.049 Uiso 1 1 d R . .
H38C H 0.9792 0.0563 0.5851 0.039 Uiso 1 1 d R . .
O39 O 0.8195(2) 0.99553(10) 0.48260(15) 0.0564(9) Uani 1 1 d DU . .
H39C H 0.7570 0.9872 0.4925 0.085 Uiso 1 1 d R . .
O40 O 0.5171(2) 0.01988(11) 0.36159(15) 0.0578(9) Uani 1 1 d DU . .
H40B H 0.4968(13) -0.0064(3) 0.3625(9) 0.087 Uiso 1 1 d D . .
H39B H 0.829(2) 0.9838(8) 0.4469(7) 0.087 Uiso 1 1 d D . .
H40A H 0.5287(16) 0.0286(6) 0.3243(6) 0.087 Uiso 1 1 d D . .
H37A H 0.9463(5) 0.3944(5) 0.3994(16) 0.087 Uiso 1 1 d D . .
H37B H 1.0473(6) 0.4001(7) 0.3925(11) 0.087 Uiso 1 1 d D . .
H32B H 0.9609(14) 0.1179(3) 0.5273(11) 0.087 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O29 Eu1 O28 70.73(9) . .
O29 Eu1 O30 76.65(8) . .
O28 Eu1 O30 139.49(9) . .
O29 Eu1 O26 78.12(9) . .
O28 Eu1 O26 74.86(10) . .
O30 Eu1 O26 75.48(8) . .
O29 Eu1 O20 84.34(9) . 2_645
O28 Eu1 O20 77.84(10) . 2_645
O30 Eu1 O20 122.49(7) . 2_645
O26 Eu1 O20 151.17(9) . 2_645
O29 Eu1 O27 137.66(8) . .
O28 Eu1 O27 68.01(9) . .
O30 Eu1 O27 144.50(8) . .
O26 Eu1 O27 99.69(9) . .
O20 Eu1 O27 78.22(8) 2_645 .
O29 Eu1 O6 139.20(8) . .
O28 Eu1 O6 118.42(10) . .
O30 Eu1 O6 73.63(8) . .
O26 Eu1 O6 67.86(8) . .
O20 Eu1 O6 135.54(8) 2_645 .
O27 Eu1 O6 72.11(8) . .
O29 Eu1 O5 146.62(7) . .
O28 Eu1 O5 138.40(9) . .
O30 Eu1 O5 80.89(8) . .
O26 Eu1 O5 119.57(8) . .
O20 Eu1 O5 87.30(8) 2_645 .
O27 Eu1 O5 71.00(7) . .
O6 Eu1 O5 52.21(8) . .
O29 Eu1 O19 74.58(8) . 2_645
O28 Eu1 O19 121.13(9) . 2_645
O30 Eu1 O19 70.17(7) . 2_645
O26 Eu1 O19 139.98(8) . 2_645
O20 Eu1 O19 52.46(7) 2_645 2_645
O27 Eu1 O19 120.19(8) . 2_645
O6 Eu1 O19 119.06(7) . 2_645
O5 Eu1 O19 74.73(7) . 2_645
O29 Eu1 C35 77.10(9) . 2_645
O28 Eu1 C35 99.44(11) . 2_645
O30 Eu1 C35 95.96(9) . 2_645
O26 Eu1 C35 155.06(9) . 2_645
O20 Eu1 C35 26.54(8) 2_645 2_645
O27 Eu1 C35 100.49(9) . 2_645
O6 Eu1 C35 132.93(9) . 2_645
O5 Eu1 C35 81.07(9) . 2_645
O19 Eu1 C35 25.96(8) 2_645 2_645
O29 Eu1 C8 152.41(8) . .
O28 Eu1 C8 133.03(9) . .
O30 Eu1 C8 75.78(8) . .
O26 Eu1 C8 93.80(9) . .
O20 Eu1 C8 111.72(9) 2_645 .
O27 Eu1 C8 69.41(8) . .
O6 Eu1 C8 26.19(8) . .
O5 Eu1 C8 26.02(8) . .
O19 Eu1 C8 97.01(8) 2_645 .
C35 Eu1 C8 106.93(10) 2_645 .
O29 Eu1 H26A 76.2(2) . .
O28 Eu1 H26A 58.24(18) . .
O30 Eu1 H26A 91.4(2) . .
O26 Eu1 H26A 16.82(17) . .
O20 Eu1 H26A 135.64(17) 2_645 .
O27 Eu1 H26A 90.0(2) . .
O6 Eu1 H26A 77.3(2) . .
O5 Eu1 H26A 129.1(2) . .
O19 Eu1 H26A 148.3(3) 2_645 .
C35 Eu1 H26A 149.8(2) 2_645 .
C8 Eu1 H26A 103.3(2) . .
O16 Eu2 O32 77.37(8) . .
O16 Eu2 O35 73.32(8) . .
O32 Eu2 O35 72.99(9) . .
O16 Eu2 O4 140.15(7) . 3_756
O32 Eu2 O4 100.06(8) . 3_756
O35 Eu2 O4 68.11(8) . 3_756
O16 Eu2 O34 82.15(8) . .
O32 Eu2 O34 144.96(8) . .
O35 Eu2 O34 74.04(9) . .
O4 Eu2 O34 78.16(7) 3_756 .
O16 Eu2 O33 95.59(8) . .
O32 Eu2 O33 70.11(8) . .
O35 Eu2 O33 142.98(9) . .
O4 Eu2 O33 121.31(7) 3_756 .
O34 Eu2 O33 140.69(8) . .
O16 Eu2 O22 124.28(7) . .
O32 Eu2 O22 142.99(8) . .
O35 Eu2 O22 138.05(8) . .
O4 Eu2 O22 81.49(8) 3_756 .
O34 Eu2 O22 71.89(7) . .
O33 Eu2 O22 77.56(8) . .
O16 Eu2 O21 73.57(8) . .
O32 Eu2 O21 126.55(8) . .
O35 Eu2 O21 135.35(9) . .
O4 Eu2 O21 130.53(8) 3_756 .
O34 Eu2 O21 72.51(8) . .
O33 Eu2 O21 69.29(8) . .
O22 Eu2 O21 52.03(8) . .
O16 Eu2 O3 151.35(8) . 3_756
O32 Eu2 O3 74.52(8) . 3_756
O35 Eu2 O3 103.22(8) . 3_756
O4 Eu2 O3 52.40(6) 3_756 3_756
O34 Eu2 O3 124.99(8) . 3_756
O33 Eu2 O3 69.72(7) . 3_756
O22 Eu2 O3 77.80(7) . 3_756
O21 Eu2 O3 120.04(7) . 3_756
O16 Eu2 C7 153.93(8) . 3_756
O32 Eu2 C7 84.69(9) . 3_756
O35 Eu2 C7 83.49(9) . 3_756
O4 Eu2 C7 26.41(8) 3_756 3_756
O34 Eu2 C7 103.07(8) . 3_756
O33 Eu2 C7 95.90(8) . 3_756
O22 Eu2 C7 81.12(8) . 3_756
O21 Eu2 C7 132.47(8) . 3_756
O3 Eu2 C7 26.25(8) 3_756 3_756
O16 Eu2 C36 98.91(9) . .
O32 Eu2 C36 140.60(9) . .
O35 Eu2 C36 144.29(9) . .
O4 Eu2 C36 106.40(9) 3_756 .
O34 Eu2 C36 70.35(8) . .
O33 Eu2 C36 71.29(8) . .
O22 Eu2 C36 26.14(8) . .
O21 Eu2 C36 25.89(9) . .
O3 Eu2 C36 99.22(8) 3_756 .
C7 Eu2 C36 106.93(9) 3_756 .
O16 Eu2 H35B 66.9(3) . .
O32 Eu2 H35B 87.2(3) . .
O35 Eu2 H35B 16.87(17) . .
O4 Eu2 H35B 73.3(3) 3_756 .
O34 Eu2 H35B 58.5(2) . .
O33 Eu2 H35B 154.3(3) . .
O22 Eu2 H35B 127.5(3) . .
O21 Eu2 H35B 119.40(18) . .
O3 Eu2 H35B 116.7(2) 3_756 .
C7 Eu2 H35B 93.7(3) 3_756 .
C36 Eu2 H35B 128.0(2) . .
O16 Eu2 H32B 90.6(4) . .
O32 Eu2 H32B 17.6(3) . .
O35 Eu2 H32B 87.8(3) . .
O4 Eu2 H32B 97.5(4) 3_756 .
O34 Eu2 H32B 161.7(3) . .
O33 Eu2 H32B 56.5(3) . .
O22 Eu2 H32B 125.4(3) . .
O21 Eu2 H32B 121.5(4) . .
O3 Eu2 H32B 60.8(4) 3_756 .
C7 Eu2 H32B 76.6(4) 3_756 .
C36 Eu2 H32B 127.6(3) . .
H35B Eu2 H32B 103.3(4) . .
O2 Cu1 O11 175.86(10) . 1_655
O2 Cu1 N2 88.44(9) . .
O11 Cu1 N2 92.26(9) 1_655 .
O2 Cu1 N6 89.53(9) . 2_745
O11 Cu1 N6 89.64(9) 1_655 2_745
N2 Cu1 N6 177.30(11) . 2_745
O2 Cu1 O31 94.36(10) . .
O11 Cu1 O31 89.70(10) 1_655 .
N2 Cu1 O31 91.30(11) . .
N6 Cu1 O31 90.64(11) 2_745 .
N4 Cu2 N3 170.08(11) . .
N4 Cu2 O8 87.61(9) . .
N3 Cu2 O8 93.53(9) . .
N4 Cu2 O24 91.62(9) . 4_565
N3 Cu2 O24 86.43(9) . 4_565
O8 Cu2 O24 175.19(10) . 4_565
N4 Cu2 O25 97.12(10) . .
N3 Cu2 O25 92.73(10) . .
O8 Cu2 O25 90.04(9) . .
O24 Cu2 O25 94.76(10) 4_565 .
O13 Cu3 O17 166.54(10) . .
O13 Cu3 N5 90.20(10) . 4_665
O17 Cu3 N5 88.14(10) . 4_665
O13 Cu3 N1 91.29(9) . 2_655
O17 Cu3 N1 90.53(9) . 2_655
N5 Cu3 N1 178.42(11) 4_665 2_655
O13 Cu3 O36 104.23(11) . .
O17 Cu3 O36 89.20(11) . .
N5 Cu3 O36 93.22(12) 4_665 .
N1 Cu3 O36 85.91(12) 2_655 .
O13 Cu3 O36A 83.36(19) . .
O17 Cu3 O36A 109.86(19) . .
N5 Cu3 O36A 86.40(18) 4_665 .
N1 Cu3 O36A 93.25(18) 2_655 .
O36 Cu3 O36A 22.01(18) . .
C1 O2 Cu1 118.0(2) . .
C7 O3 Eu2 90.28(18) . 3_756
C7 O4 Eu2 94.66(17) . 3_756
C8 O5 Eu1 91.98(19) . .
C8 O6 Eu1 93.85(18) . .
C14 O8 Cu2 108.62(19) . .
C21 O11 Cu1 113.2(2) . 1_455
C22 O13 Cu3 120.12(19) . .
C28 O16 Eu2 140.5(2) . .
C29 O17 Cu3 121.6(2) . .
C35 O19 Eu1 90.56(19) . 2_655
C35 O20 Eu1 94.73(19) . 2_655
C36 O21 Eu2 93.04(19) . .
C36 O22 Eu2 92.8(2) . .
C42 O24 Cu2 111.7(2) . 4_666
Cu2 O25 H25A 109.3 . .
Cu2 O25 H25B 109.4 . .
H25A O25 H25B 109.5 . .
Eu1 O26 H26A 107.2(6) . .
Eu1 O26 H26B 114.9(18) . .
H26A O26 H26B 117.2(14) . .
Eu1 O27 H27A 110.6 . .
Eu1 O27 H27B 111.1(18) . .
H27A O27 H27B 106.5 . .
Eu1 O28 H28A 109.2 . .
Eu1 O28 H28C 109.0 . .
H28A O28 H28C 109.5 . .
Eu1 O29 H29C 109.3 . .
Eu1 O29 H29B 157(3) . .
H29C O29 H29B 81.2 . .
Eu1 O30 H30B 108.5 . .
Eu1 O30 H30A 123.4(11) . .
H30B O30 H30A 107.0 . .
Cu1 O31 H31A 109.1 . .
Cu1 O31 H31B 109.1 . .
H31A O31 H31B 109.5 . .
Eu2 O32 H32A 125.7(11) . .
Eu2 O32 H32B 103.5(14) . .
H32A O32 H32B 116.5(13) . .
Eu2 O33 H33B 109.0 . .
Eu2 O33 H33A 118.5(10) . .
H33B O33 H33A 105.2 . .
Eu2 O34 H34A 108.8 . .
Eu2 O34 H34B 121.2(15) . .
H34A O34 H34B 107.3 . .
Eu2 O35 H35A 136.4(9) . .
Eu2 O35 H35B 106.2(7) . .
H35A O35 H35B 117.4(11) . .
C5 N1 C4 117.4(3) . .
C5 N1 Cu3 118.0(2) . 2_645
C4 N1 Cu3 124.5(2) . 2_645
C11 N2 C10 118.7(3) . .
C11 N2 Cu1 125.2(2) . .
C10 N2 Cu1 115.9(2) . .
C18 N3 C17 118.3(3) . .
C18 N3 Cu2 122.4(2) . .
C17 N3 Cu2 118.7(2) . .
C26 N4 C25 117.9(3) . .
C26 N4 Cu2 120.2(2) . .
C25 N4 Cu2 121.4(2) . .
C38 N5 C39 117.9(3) . .
C38 N5 Cu3 117.1(2) . 4_566
C39 N5 Cu3 124.7(2) . 4_566
C33 N6 C32 117.6(3) . .
C33 N6 Cu1 118.3(2) . 2_755
C32 N6 Cu1 124.1(2) . 2_755
O1 C1 O2 125.2(3) . .
O1 C1 C2 119.8(3) . .
O2 C1 C2 114.7(3) . .
C3 C2 C6 117.9(3) . .
C3 C2 C1 119.2(3) . .
C6 C2 C1 122.9(3) . .
C4 C3 C2 120.6(3) . .
C4 C3 H3 119.7 . .
C2 C3 H3 119.7 . .
N1 C4 C3 122.0(3) . .
N1 C4 H4 119.0 . .
C3 C4 H4 119.0 . .
N1 C5 C6 124.9(3) . .
N1 C5 H5 117.6 . .
C6 C5 H5 117.6 . .
C5 C6 C2 117.1(3) . .
C5 C6 C7 119.3(3) . .
C2 C6 C7 123.6(3) . .
O3 C7 O4 121.5(3) . .
O3 C7 C6 120.5(3) . .
O4 C7 C6 118.1(3) . .
O3 C7 Eu2 63.47(16) . 3_756
O4 C7 Eu2 58.93(15) . 3_756
C6 C7 Eu2 170.2(2) . 3_756
O5 C8 O6 122.0(3) . .
O5 C8 C9 119.7(3) . .
O6 C8 C9 118.2(3) . .
O5 C8 Eu1 62.00(16) . .
O6 C8 Eu1 59.95(16) . .
C9 C8 Eu1 176.4(2) . .
C10 C9 C13 118.8(3) . .
C10 C9 C8 117.7(3) . .
C13 C9 C8 123.5(3) . .
N2 C10 C9 122.9(3) . .
N2 C10 H10 118.6 . .
C9 C10 H10 118.6 . .
N2 C11 C12 121.2(3) . .
N2 C11 H11 119.4 . .
C12 C11 H11 119.4 . .
C13 C12 C11 120.3(3) . .
C13 C12 H12 119.8 . .
C11 C12 H12 119.8 . .
C12 C13 C9 118.1(3) . .
C12 C13 C14 122.7(3) . .
C9 C13 C14 118.8(3) . .
O7 C14 O8 125.5(3) . .
O7 C14 C13 116.5(3) . .
O8 C14 C13 117.9(3) . .
O10 C15 O9 125.9(3) . .
O10 C15 C16 116.6(3) . .
O9 C15 C16 117.4(3) . .
C20 C16 C17 118.3(3) . .
C20 C16 C15 123.0(3) . .
C17 C16 C15 118.6(3) . .
N3 C17 C16 123.4(3) . .
N3 C17 H17 118.3 . .
C16 C17 H17 118.3 . .
N3 C18 C19 122.3(3) . .
N3 C18 H18 118.8 . .
C19 C18 H18 118.8 . .
C18 C19 C20 120.0(3) . .
C18 C19 H19 120.0 . .
C20 C19 H19 120.0 . .
C16 C20 C19 117.7(3) . .
C16 C20 C21 123.0(3) . .
C19 C20 C21 119.3(3) . .
O12 C21 O11 125.0(3) . .
O12 C21 C20 119.8(3) . .
O11 C21 C20 115.1(3) . .
O14 C22 O13 125.7(3) . .
O14 C22 C23 116.9(3) . .
O13 C22 C23 117.3(3) . .
C24 C23 C27 118.2(3) . .
C24 C23 C22 118.0(3) . .
C27 C23 C22 123.5(3) . .
C23 C24 C25 120.1(3) . .
C23 C24 H24 120.0 . .
C25 C24 H24 120.0 . .
N4 C25 C24 121.9(3) . .
N4 C25 H25 119.1 . .
C24 C25 H25 119.1 . .
N4 C26 C27 123.2(3) . .
N4 C26 H26 118.4 . .
C27 C26 H26 118.4 . .
C26 C27 C23 118.9(3) . .
C26 C27 C28 118.6(3) . .
C23 C27 C28 122.5(3) . .
O15 C28 O16 125.9(3) . .
O15 C28 C27 117.9(3) . .
O16 C28 C27 116.2(3) . .
O18 C29 O17 125.1(3) . .
O18 C29 C30 118.4(3) . .
O17 C29 C30 116.3(3) . .
C34 C30 C31 118.2(3) . .
C34 C30 C29 123.0(3) . .
C31 C30 C29 118.6(3) . .
C32 C31 C30 120.0(3) . .
C32 C31 H31 120.0 . .
C30 C31 H31 120.0 . .
N6 C32 C31 122.3(3) . .
N6 C32 H32 118.9 . .
C31 C32 H32 118.9 . .
N6 C33 C34 123.1(3) . .
N6 C33 H33 118.4 . .
C34 C33 H33 118.5 . .
C30 C34 C33 118.8(3) . .
C30 C34 C35 123.1(3) . .
C33 C34 C35 118.1(3) . .
O19 C35 O20 122.0(3) . .
O19 C35 C34 120.3(3) . .
O20 C35 C34 117.6(3) . .
O19 C35 Eu1 63.47(17) . 2_655
O20 C35 Eu1 58.73(17) . 2_655
C34 C35 Eu1 175.1(2) . 2_655
O21 C36 O22 122.1(3) . .
O21 C36 C37 119.3(3) . .
O22 C36 C37 118.5(3) . .
O21 C36 Eu2 61.06(17) . .
O22 C36 Eu2 61.06(18) . .
C37 C36 Eu2 175.9(2) . .
C38 C37 C41 118.5(3) . .
C38 C37 C36 118.1(3) . .
C41 C37 C36 123.4(3) . .
N5 C38 C37 122.8(3) . .
N5 C38 H38 118.6 . .
C37 C38 H38 118.6 . .
N5 C39 C40 123.1(3) . .
N5 C39 H39 118.5 . .
C40 C39 H39 118.5 . .
C39 C40 C41 118.8(3) . .
C39 C40 H40 120.6 . .
C41 C40 H40 120.6 . .
C40 C41 C37 118.9(3) . .
C40 C41 C42 121.1(3) . .
C37 C41 C42 119.7(3) . .
O23 C42 O24 125.4(3) . .
O23 C42 C41 118.2(3) . .
O24 C42 C41 116.4(3) . .
H37A O37 H37B 115.6(16) . .
H38D O38 H38C 109.5 . .
H39C O39 H39B 109.8 . .
H40B O40 H40A 115.1(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O29 2.415(2) .
Eu1 O28 2.417(3) .
Eu1 O30 2.420(2) .
Eu1 O26 2.431(3) .
Eu1 O20 2.436(2) 2_645
Eu1 O27 2.440(2) .
Eu1 O6 2.482(2) .
Eu1 O5 2.528(2) .
Eu1 O19 2.541(2) 2_645
Eu1 C35 2.840(3) 2_645
Eu1 C8 2.861(3) .
Eu1 H26A 2.802(8) .
Eu2 O16 2.363(2) .
Eu2 O32 2.406(2) .
Eu2 O35 2.439(3) .
Eu2 O4 2.443(2) 3_756
Eu2 O34 2.452(2) .
Eu2 O33 2.460(2) .
Eu2 O22 2.514(2) .
Eu2 O21 2.514(2) .
Eu2 O3 2.544(2) 3_756
Eu2 C7 2.843(3) 3_756
Eu2 C36 2.869(4) .
Eu2 H35B 2.794(9) .
Eu2 H32B 2.734(18) .
Cu1 O2 1.979(2) .
Cu1 O11 1.985(2) 1_655
Cu1 N2 2.013(3) .
Cu1 N6 2.023(3) 2_745
Cu1 O31 2.294(3) .
Cu2 N4 1.987(2) .
Cu2 N3 1.999(3) .
Cu2 O8 2.009(2) .
Cu2 O24 2.026(2) 4_565
Cu2 O25 2.237(3) .
Cu3 O13 1.985(2) .
Cu3 O17 1.990(2) .
Cu3 N5 1.991(3) 4_665
Cu3 N1 2.008(2) 2_655
Cu3 O36 2.247(4) .
Cu3 O36A 2.249(6) .
O1 C1 1.227(4) .
O2 C1 1.285(4) .
O3 C7 1.257(4) .
O3 Eu2 2.544(2) 3_756
O4 C7 1.269(4) .
O4 Eu2 2.443(2) 3_756
O5 C8 1.256(4) .
O6 C8 1.266(4) .
O7 C14 1.244(4) .
O8 C14 1.266(4) .
O9 C15 1.258(4) .
O10 C15 1.249(4) .
O11 C21 1.274(4) .
O11 Cu1 1.985(2) 1_455
O12 C21 1.236(4) .
O13 C22 1.269(4) .
O14 C22 1.246(4) .
O15 C28 1.245(4) .
O16 C28 1.254(4) .
O17 C29 1.271(4) .
O18 C29 1.245(4) .
O19 C35 1.244(4) .
O19 Eu1 2.541(2) 2_655
O20 C35 1.274(4) .
O20 Eu1 2.436(2) 2_655
O21 C36 1.255(4) .
O22 C36 1.265(4) .
O23 C42 1.240(4) .
O24 C42 1.275(4) .
O24 Cu2 2.026(2) 4_666
O25 H25A 0.9798 .
O25 H25B 0.9799 .
O26 H26A 0.849(7) .
O26 H26B 0.851(8) .
O27 H27A 0.9600 .
O27 H27B 0.846(8) .
O28 H28A 0.9603 .
O28 H28C 0.9599 .
O29 H29C 0.9600 .
O29 H29B 0.842(9) .
O30 H30B 0.9600 .
O30 H30A 0.840(7) .
O31 H31A 0.9597 .
O31 H31B 0.9598 .
O32 H32A 0.850(8) .
O32 H32B 0.852(8) .
O33 H33B 0.9600 .
O33 H33A 0.857(8) .
O34 H34A 0.9604 .
O34 H34B 0.841(8) .
O35 H35A 0.851(8) .
O35 H35B 0.844(6) .
N1 C5 1.338(4) .
N1 C4 1.342(4) .
N1 Cu3 2.008(2) 2_645
N2 C11 1.341(4) .
N2 C10 1.343(4) .
N3 C18 1.330(4) .
N3 C17 1.337(4) .
N4 C26 1.347(4) .
N4 C25 1.351(4) .
N5 C38 1.345(4) .
N5 C39 1.350(4) .
N5 Cu3 1.991(3) 4_566
N6 C33 1.346(4) .
N6 C32 1.348(4) .
N6 Cu1 2.023(3) 2_755
C1 C2 1.514(4) .
C2 C3 1.391(4) .
C2 C6 1.403(4) .
C3 C4 1.379(4) .
C3 H3 0.9500 .
C4 H4 0.9500 .
C5 C6 1.390(4) .
C5 H5 0.9500 .
C6 C7 1.494(4) .
C7 Eu2 2.843(3) 3_756
C8 C9 1.498(4) .
C9 C10 1.381(4) .
C9 C13 1.389(4) .
C10 H10 0.9500 .
C11 C12 1.386(4) .
C11 H11 0.9500 .
C12 C13 1.383(4) .
C12 H12 0.9500 .
C13 C14 1.522(4) .
C15 C16 1.510(5) .
C16 C20 1.383(5) .
C16 C17 1.390(4) .
C17 H17 0.9500 .
C18 C19 1.368(5) .
C18 H18 0.9500 .
C19 C20 1.408(5) .
C19 H19 0.9500 .
C20 C21 1.505(4) .
C22 C23 1.508(4) .
C23 C24 1.380(5) .
C23 C27 1.396(4) .
C24 C25 1.384(4) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 C27 1.376(4) .
C26 H26 0.9500 .
C27 C28 1.511(4) .
C29 C30 1.522(4) .
C30 C34 1.378(4) .
C30 C31 1.390(5) .
C31 C32 1.373(4) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 C34 1.388(4) .
C33 H33 0.9500 .
C34 C35 1.502(5) .
C35 Eu1 2.840(3) 2_655
C36 C37 1.497(5) .
C37 C38 1.393(4) .
C37 C41 1.398(5) .
C38 H38 0.9500 .
C39 C40 1.383(4) .
C39 H39 0.9500 .
C40 C41 1.389(5) .
C40 H40 0.9500 .
C41 C42 1.517(4) .
O37 H37A 0.854(8) .
O37 H37B 0.856(9) .
O38 H38D 0.9600 .
O38 H38C 0.9599 .
O39 H39C 0.9600 .
O39 H39B 0.848(10) .
O40 H40B 0.856(8) .
O40 H40A 0.851(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O11 Cu1 O2 C1 40.9(13) 1_655 .
N2 Cu1 O2 C1 -58.9(2) . .
N6 Cu1 O2 C1 119.3(2) 2_745 .
O31 Cu1 O2 C1 -150.1(2) . .
O29 Eu1 O5 C8 124.25(19) . .
O28 Eu1 O5 C8 -92.0(2) . .
O30 Eu1 O5 C8 76.20(17) . .
O26 Eu1 O5 C8 8.72(19) . .
O20 Eu1 O5 C8 -160.28(17) 2_645 .
O27 Eu1 O5 C8 -81.81(17) . .
O6 Eu1 O5 C8 -0.10(16) . .
O19 Eu1 O5 C8 147.99(17) 2_645 .
C35 Eu1 O5 C8 173.77(18) 2_645 .
O29 Eu1 O6 C8 -135.87(18) . .
O28 Eu1 O6 C8 131.11(18) . .
O30 Eu1 O6 C8 -90.99(18) . .
O26 Eu1 O6 C8 -171.6(2) . .
O20 Eu1 O6 C8 29.0(2) 2_645 .
O27 Eu1 O6 C8 79.58(18) . .
O5 Eu1 O6 C8 0.10(16) . .
O19 Eu1 O6 C8 -35.6(2) 2_645 .
C35 Eu1 O6 C8 -8.2(2) 2_645 .
N4 Cu2 O8 C14 -73.9(2) . .
N3 Cu2 O8 C14 96.3(2) . .
O24 Cu2 O8 C14 7.0(11) 4_565 .
O25 Cu2 O8 C14 -171.01(19) . .
O17 Cu3 O13 C22 35.6(5) . .
N5 Cu3 O13 C22 118.5(2) 4_665 .
N1 Cu3 O13 C22 -62.0(2) 2_655 .
O36 Cu3 O13 C22 -148.2(2) . .
O36A Cu3 O13 C22 -155.2(3) . .
O32 Eu2 O16 C28 -48.3(3) . .
O35 Eu2 O16 C28 27.5(3) . .
O4 Eu2 O16 C28 42.3(4) 3_756 .
O34 Eu2 O16 C28 103.1(3) . .
O33 Eu2 O16 C28 -116.4(3) . .
O22 Eu2 O16 C28 164.8(3) . .
O21 Eu2 O16 C28 177.1(3) . .
O3 Eu2 O16 C28 -59.6(4) 3_756 .
C7 Eu2 O16 C28 -0.6(4) 3_756 .
C36 Eu2 O16 C28 171.7(3) . .
O13 Cu3 O17 C29 26.0(5) . .
N5 Cu3 O17 C29 -57.1(2) 4_665 .
N1 Cu3 O17 C29 123.7(2) 2_655 .
O36 Cu3 O17 C29 -150.4(2) . .
O36A Cu3 O17 C29 -142.6(3) . .
O16 Eu2 O21 C36 -167.7(2) . .
O32 Eu2 O21 C36 132.48(19) . .
O35 Eu2 O21 C36 -124.08(19) . .
O4 Eu2 O21 C36 -24.4(2) 3_756 .
O34 Eu2 O21 C36 -80.90(19) . .
O33 Eu2 O21 C36 89.62(19) . .
O22 Eu2 O21 C36 -0.55(17) . .
O3 Eu2 O21 C36 39.9(2) 3_756 .
C7 Eu2 O21 C36 11.0(2) 3_756 .
O16 Eu2 O22 C36 15.5(2) . .
O32 Eu2 O22 C36 -102.2(2) . .
O35 Eu2 O22 C36 119.34(19) . .
O4 Eu2 O22 C36 162.41(18) 3_756 .
O34 Eu2 O22 C36 82.15(18) . .
O33 Eu2 O22 C36 -72.77(18) . .
O21 Eu2 O22 C36 0.54(17) . .
O3 Eu2 O22 C36 -144.38(18) 3_756 .
C7 Eu2 O22 C36 -170.88(18) 3_756 .
O2 Cu1 N2 C11 125.4(3) . .
O11 Cu1 N2 C11 -50.5(3) 1_655 .
N6 Cu1 N2 C11 84(2) 2_745 .
O31 Cu1 N2 C11 -140.2(3) . .
O2 Cu1 N2 C10 -49.8(2) . .
O11 Cu1 N2 C10 134.2(2) 1_655 .
N6 Cu1 N2 C10 -91(2) 2_745 .
O31 Cu1 N2 C10 44.5(2) . .
N4 Cu2 N3 C18 42.7(7) . .
O8 Cu2 N3 C18 -53.6(3) . .
O24 Cu2 N3 C18 121.6(3) 4_565 .
O25 Cu2 N3 C18 -143.8(3) . .
N4 Cu2 N3 C17 -128.7(6) . .
O8 Cu2 N3 C17 135.0(2) . .
O24 Cu2 N3 C17 -49.8(2) 4_565 .
O25 Cu2 N3 C17 44.8(2) . .
N3 Cu2 N4 C26 -147.9(5) . .
O8 Cu2 N4 C26 -51.1(2) . .
O24 Cu2 N4 C26 133.7(2) 4_565 .
O25 Cu2 N4 C26 38.7(2) . .
N3 Cu2 N4 C25 24.0(7) . .
O8 Cu2 N4 C25 120.9(2) . .
O24 Cu2 N4 C25 -54.4(2) 4_565 .
O25 Cu2 N4 C25 -149.4(2) . .
Cu1 O2 C1 O1 -12.6(4) . .
Cu1 O2 C1 C2 162.02(19) . .
O1 C1 C2 C3 94.0(4) . .
O2 C1 C2 C3 -80.9(4) . .
O1 C1 C2 C6 -85.9(4) . .
O2 C1 C2 C6 99.2(4) . .
C6 C2 C3 C4 -0.5(5) . .
C1 C2 C3 C4 179.6(3) . .
C5 N1 C4 C3 1.3(5) . .
Cu3 N1 C4 C3 178.7(3) 2_645 .
C2 C3 C4 N1 0.5(5) . .
C4 N1 C5 C6 -3.2(5) . .
Cu3 N1 C5 C6 179.2(2) 2_645 .
N1 C5 C6 C2 3.2(5) . .
N1 C5 C6 C7 -177.3(3) . .
C3 C2 C6 C5 -1.2(5) . .
C1 C2 C6 C5 178.7(3) . .
C3 C2 C6 C7 179.3(3) . .
C1 C2 C6 C7 -0.8(5) . .
Eu2 O3 C7 O4 -10.9(3) 3_756 .
Eu2 O3 C7 C6 169.7(3) 3_756 .
Eu2 O4 C7 O3 11.4(3) 3_756 .
Eu2 O4 C7 C6 -169.2(2) 3_756 .
C5 C6 C7 O3 -179.5(3) . .
C2 C6 C7 O3 0.0(5) . .
C5 C6 C7 O4 1.1(4) . .
C2 C6 C7 O4 -179.4(3) . .
C5 C6 C7 Eu2 -68.5(13) . 3_756
C2 C6 C7 Eu2 110.9(12) . 3_756
Eu1 O5 C8 O6 0.2(3) . .
Eu1 O5 C8 C9 -176.4(2) . .
Eu1 O6 C8 O5 -0.2(3) . .
Eu1 O6 C8 C9 176.5(2) . .
O29 Eu1 C8 O5 -101.0(2) . .
O28 Eu1 C8 O5 114.81(18) . .
O30 Eu1 C8 O5 -98.44(17) . .
O26 Eu1 C8 O5 -172.41(17) . .
O20 Eu1 C8 O5 21.27(18) 2_645 .
O27 Eu1 C8 O5 88.66(17) . .
O6 Eu1 C8 O5 179.8(3) . .
O19 Eu1 C8 O5 -31.01(17) 2_645 .
C35 Eu1 C8 O5 -6.44(18) 2_645 .
O29 Eu1 C8 O6 79.2(3) . .
O28 Eu1 C8 O6 -65.0(2) . .
O30 Eu1 C8 O6 81.74(18) . .
O26 Eu1 C8 O6 7.77(18) . .
O20 Eu1 C8 O6 -158.55(17) 2_645 .
O27 Eu1 C8 O6 -91.16(18) . .
O5 Eu1 C8 O6 -179.8(3) . .
O19 Eu1 C8 O6 149.17(17) 2_645 .
C35 Eu1 C8 O6 173.74(17) 2_645 .
O29 Eu1 C8 C9 19(4) . .
O28 Eu1 C8 C9 -126(4) . .
O30 Eu1 C8 C9 21(4) . .
O26 Eu1 C8 C9 -53(4) . .
O20 Eu1 C8 C9 141(4) 2_645 .
O27 Eu1 C8 C9 -152(4) . .
O6 Eu1 C8 C9 -61(4) . .
O5 Eu1 C8 C9 120(4) . .
O19 Eu1 C8 C9 89(4) 2_645 .
C35 Eu1 C8 C9 113(4) 2_645 .
O5 C8 C9 C10 117.9(3) . .
O6 C8 C9 C10 -58.8(4) . .
Eu1 C8 C9 C10 0(4) . .
O5 C8 C9 C13 -59.9(4) . .
O6 C8 C9 C13 123.4(3) . .
Eu1 C8 C9 C13 -178(100) . .
C11 N2 C10 C9 -0.6(5) . .
Cu1 N2 C10 C9 175.0(2) . .
C13 C9 C10 N2 1.9(5) . .
C8 C9 C10 N2 -176.0(3) . .
C10 N2 C11 C12 -0.3(4) . .
Cu1 N2 C11 C12 -175.4(2) . .
N2 C11 C12 C13 -0.2(5) . .
C11 C12 C13 C9 1.5(5) . .
C11 C12 C13 C14 -171.3(3) . .
C10 C9 C13 C12 -2.2(4) . .
C8 C9 C13 C12 175.6(3) . .
C10 C9 C13 C14 170.8(3) . .
C8 C9 C13 C14 -11.4(4) . .
Cu2 O8 C14 O7 -9.1(4) . .
Cu2 O8 C14 C13 166.6(2) . .
C12 C13 C14 O7 137.7(3) . .
C9 C13 C14 O7 -35.0(4) . .
C12 C13 C14 O8 -38.4(4) . .
C9 C13 C14 O8 148.9(3) . .
O10 C15 C16 C20 -37.7(5) . .
O9 C15 C16 C20 143.9(3) . .
O10 C15 C16 C17 139.1(3) . .
O9 C15 C16 C17 -39.2(4) . .
C18 N3 C17 C16 -1.4(5) . .
Cu2 N3 C17 C16 170.4(2) . .
C20 C16 C17 N3 1.2(5) . .
C15 C16 C17 N3 -175.8(3) . .
C17 N3 C18 C19 0.7(5) . .
Cu2 N3 C18 C19 -170.7(3) . .
N3 C18 C19 C20 0.2(5) . .
C17 C16 C20 C19 -0.3(5) . .
C15 C16 C20 C19 176.6(3) . .
C17 C16 C20 C21 177.7(3) . .
C15 C16 C20 C21 -5.5(5) . .
C18 C19 C20 C16 -0.4(5) . .
C18 C19 C20 C21 -178.4(3) . .
Cu1 O11 C21 O12 -13.8(4) 1_455 .
Cu1 O11 C21 C20 162.4(2) 1_455 .
C16 C20 C21 O12 -62.1(5) . .
C19 C20 C21 O12 115.8(4) . .
C16 C20 C21 O11 121.5(4) . .
C19 C20 C21 O11 -60.6(4) . .
Cu3 O13 C22 O14 -12.3(4) . .
Cu3 O13 C22 C23 163.5(2) . .
O14 C22 C23 C24 104.9(4) . .
O13 C22 C23 C24 -71.3(4) . .
O14 C22 C23 C27 -68.8(4) . .
O13 C22 C23 C27 115.0(4) . .
C27 C23 C24 C25 0.2(5) . .
C22 C23 C24 C25 -173.9(3) . .
C26 N4 C25 C24 0.9(5) . .
Cu2 N4 C25 C24 -171.2(2) . .
C23 C24 C25 N4 -0.8(5) . .
C25 N4 C26 C27 -0.5(4) . .
Cu2 N4 C26 C27 171.7(2) . .
N4 C26 C27 C23 -0.1(5) . .
N4 C26 C27 C28 -177.7(3) . .
C24 C23 C27 C26 0.2(5) . .
C22 C23 C27 C26 174.0(3) . .
C24 C23 C27 C28 177.7(3) . .
C22 C23 C27 C28 -8.6(5) . .
Eu2 O16 C28 O15 -28.8(5) . .
Eu2 O16 C28 C27 149.4(2) . .
C26 C27 C28 O15 153.9(3) . .
C23 C27 C28 O15 -23.6(4) . .
C26 C27 C28 O16 -24.6(4) . .
C23 C27 C28 O16 158.0(3) . .
Cu3 O17 C29 O18 -10.3(4) . .
Cu3 O17 C29 C30 164.58(19) . .
O18 C29 C30 C34 -79.6(4) . .
O17 C29 C30 C34 105.1(4) . .
O18 C29 C30 C31 95.7(4) . .
O17 C29 C30 C31 -79.6(4) . .
C34 C30 C31 C32 0.3(5) . .
C29 C30 C31 C32 -175.2(3) . .
C33 N6 C32 C31 0.3(5) . .
Cu1 N6 C32 C31 179.4(3) 2_755 .
C30 C31 C32 N6 0.6(6) . .
C32 N6 C33 C34 -2.1(5) . .
Cu1 N6 C33 C34 178.7(3) 2_755 .
C31 C30 C34 C33 -2.0(5) . .
C29 C30 C34 C33 173.3(3) . .
C31 C30 C34 C35 176.8(3) . .
C29 C30 C34 C35 -7.9(6) . .
N6 C33 C34 C30 3.0(5) . .
N6 C33 C34 C35 -175.9(3) . .
Eu1 O19 C35 O20 -4.7(3) 2_655 .
Eu1 O19 C35 C34 176.4(3) 2_655 .
Eu1 O20 C35 O19 4.9(4) 2_655 .
Eu1 O20 C35 C34 -176.1(3) 2_655 .
C30 C34 C35 O19 -4.9(5) . .
C33 C34 C35 O19 173.9(3) . .
C30 C34 C35 O20 176.2(3) . .
C33 C34 C35 O20 -5.1(5) . .
C30 C34 C35 Eu1 134(3) . 2_655
C33 C34 C35 Eu1 -47(3) . 2_655
Eu2 O21 C36 O22 1.0(3) . .
Eu2 O21 C36 C37 -175.3(2) . .
Eu2 O22 C36 O21 -1.0(3) . .
Eu2 O22 C36 C37 175.4(2) . .
O16 Eu2 C36 O21 11.97(19) . .
O32 Eu2 C36 O21 -69.0(2) . .
O35 Eu2 C36 O21 85.7(2) . .
O4 Eu2 C36 O21 160.87(18) 3_756 .
O34 Eu2 C36 O21 90.27(19) . .
O33 Eu2 C36 O21 -80.96(19) . .
O22 Eu2 C36 O21 179.0(3) . .
O3 Eu2 C36 O21 -145.76(18) 3_756 .
C7 Eu2 C36 O21 -171.55(18) 3_756 .
O16 Eu2 C36 O22 -167.05(17) . .
O32 Eu2 C36 O22 112.02(19) . .
O35 Eu2 C36 O22 -93.3(2) . .
O4 Eu2 C36 O22 -18.16(18) 3_756 .
O34 Eu2 C36 O22 -88.76(18) . .
O33 Eu2 C36 O22 100.02(18) . .
O21 Eu2 C36 O22 -179.0(3) . .
O3 Eu2 C36 O22 35.22(18) 3_756 .
C7 Eu2 C36 O22 9.42(19) 3_756 .
O16 Eu2 C36 C37 109(3) . .
O32 Eu2 C36 C37 28(3) . .
O35 Eu2 C36 C37 -178(100) . .
O4 Eu2 C36 C37 -102(3) 3_756 .
O34 Eu2 C36 C37 -173(3) . .
O33 Eu2 C36 C37 16(3) . .
O22 Eu2 C36 C37 -84(3) . .
O21 Eu2 C36 C37 97(3) . .
O3 Eu2 C36 C37 -49(3) 3_756 .
C7 Eu2 C36 C37 -75(3) 3_756 .
O21 C36 C37 C38 55.5(4) . .
O22 C36 C37 C38 -121.0(3) . .
Eu2 C36 C37 C38 -39(3) . .
O21 C36 C37 C41 -127.1(3) . .
O22 C36 C37 C41 56.4(4) . .
Eu2 C36 C37 C41 138(3) . .
C39 N5 C38 C37 2.7(5) . .
Cu3 N5 C38 C37 -171.2(2) 4_566 .
C41 C37 C38 N5 -3.3(5) . .
C36 C37 C38 N5 174.2(3) . .
C38 N5 C39 C40 -0.3(5) . .
Cu3 N5 C39 C40 173.1(2) 4_566 .
N5 C39 C40 C41 -1.4(5) . .
C39 C40 C41 C37 0.7(5) . .
C39 C40 C41 C42 174.8(3) . .
C38 C37 C41 C40 1.5(4) . .
C36 C37 C41 C40 -175.8(3) . .
C38 C37 C41 C42 -172.8(3) . .
C36 C37 C41 C42 9.9(4) . .
Cu2 O24 C42 O23 13.6(4) 4_666 .
Cu2 O24 C42 C41 -164.6(2) 4_666 .
C40 C41 C42 O23 -137.3(3) . .
C37 C41 C42 O23 36.8(4) . .
C40 C41 C42 O24 41.0(4) . .
C37 C41 C42 O24 -144.9(3) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.000 1311 509 ' '
2 0.500 0.500 0.500 1311 509 ' '
3 0.000 0.500 0.000 294 124 ' '
4 0.500 1.000 0.500 294 124 ' '
