#------------------------------------------------------------------------------
#$Date: 2016-03-26 23:06:14 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180529 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/98/7219820.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219820
loop_
_publ_author_name
'Rodpun, Kiattipoom'
'Blackman, Allan G.'
'Gardiner, Michael G.'
'Tan, Eng Wui'
'Meledandri, Carla J.'
'Lucas, Nigel T.'
_publ_section_title
;
 Alkyl linker effects on the coordination topology of ditopic
 di(2-pyridylmethyl)amine carboxylate ligands with ZnIIand CuII: polymers
 vs. macrocycles
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              2974
_journal_paper_doi               10.1039/C5CE00375J
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C16 H18 Cu N3 O2 1+, Cl O4 1-, C H4 O'
_chemical_formula_sum            'C17 H22 Cl Cu N3 O7'
_chemical_formula_weight         479.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_block_code                nl_kr10
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-02-22 deposited with the CCDC.
2015-03-09 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 102.275(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.3751(3)
_cell_length_b                   8.3150(3)
_cell_length_c                   23.5131(11)
_cell_measurement_reflns_used    7518
_cell_measurement_temperature    100(1)
_cell_measurement_theta_max      28.423
_cell_measurement_theta_min      3.151
_cell_volume                     1982.08(13)
_computing_cell_refinement       'CrysAlisPro (Agilent, V 1.171.36.28)'
_computing_data_collection       'CrysAlisPro (Agilent, V 1.171.36.28)'
_computing_data_reduction        'CrysAlisPro (Agilent, V 1.171.36.28)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2008)'
_computing_publication_material  'enCIFer (CCDC, 2014)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(1)
_diffrn_crystal_treatment
; 
Crystal was attached with Paratone N oil to a 0.3 mm CryoLoop supported 
in a copper mounting pin, then quenched in a cold nitrogen gas from a gas
stream from an Oxford Cryosystems Cryostream.
;
_diffrn_detector_area_resol_mean 5.1725
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.875
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0452
_diffrn_reflns_av_sigmaI/netI    0.0405
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19827
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.71
_diffrn_reflns_theta_min         3.17
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.282
_exptl_absorpt_correction_T_max  0.9626
_exptl_absorpt_correction_T_min  0.6023
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies, Version 1.171.36.28.
Empirical absorption correction using spherical harmonics, 
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             988
_exptl_crystal_preparation
;
Crystals were grown by slow diffusion of a methanolic solution of the 
carboxylic acid ligand into an aqueous Cu(II) perchlorate solution 
at room temperature.
;
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Methanol/water'
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.256
_refine_diff_density_min         -1.214
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     270
_refine_ls_number_reflns         4477
_refine_ls_number_restraints     161
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0685
_refine_ls_R_factor_gt           0.0562
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0616P)²+7.5544P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1456
_refine_ls_wR_factor_ref         0.1534
_reflns_number_gt                3726
_reflns_number_total             4477
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce00375j2.cif
_cod_data_source_block           4_Cu-C3
_cod_depositor_comments
'Adding full bibliography for 7219817--7219825.cif.'
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7219820
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.67590(4) 0.09453(6) 0.24726(2) 0.01763(15) Uani 1 1 d . . .
Cl1 Cl 0.3123(2) 0.7093(2) 0.08885(9) 0.0294(4) Uani 0.77 1 d PDU A 1
O1 O 0.6332(2) -0.4283(3) 0.25115(12) 0.0201(6) Uani 1 1 d . . .
O2 O 0.6620(2) -0.1656(3) 0.25628(12) 0.0218(6) Uani 1 1 d . . .
O11 O 0.2598(8) 0.6272(9) 0.1322(3) 0.0571(7) Uani 0.77 1 d PDU A 1
O12 O 0.3397(6) 0.5926(7) 0.0469(2) 0.0571(7) Uani 0.77 1 d PDU A 1
O13 O 0.2216(5) 0.8240(7) 0.0597(2) 0.0571(7) Uani 0.77 1 d PDU A 1
O14 O 0.4336(5) 0.7849(7) 0.1139(2) 0.0571(7) Uani 0.77 1 d PDU A 1
O91 O 0.1603(9) 0.1505(13) 0.0996(5) 0.068(2) Uani 0.55 1 d PDU B 1
H91 H 0.1904 0.0862 0.0781 0.081 Uiso 0.55 1 calc PR B 1
O92 O 0.1374(12) 0.0776(16) 0.1192(5) 0.068(2) Uani 0.45 1 d PDU C 2
H92 H 0.1725 0.0005 0.1051 0.081 Uiso 0.45 1 calc PR C 2
N2 N 0.6266(3) 0.1127(4) 0.16121(15) 0.0228(7) Uani 1 1 d . . .
N1 N 0.6919(3) 0.1341(4) 0.33137(15) 0.0219(7) Uani 1 1 d . . .
N3 N 0.4840(3) 0.1602(4) 0.24168(14) 0.0202(7) Uani 1 1 d . . .
C21 C 0.4521(4) 0.2647(5) 0.18899(18) 0.0257(9) Uani 1 1 d . . .
H21A H 0.4849 0.3751 0.1990 0.031 Uiso 1 1 calc R . .
H21B H 0.3553 0.2700 0.1747 0.031 Uiso 1 1 calc R . .
C22 C 0.5155(4) 0.1973(5) 0.14218(18) 0.0244(8) Uani 1 1 d . . .
C23 C 0.4688(4) 0.2277(6) 0.08295(19) 0.0310(10) Uani 1 1 d . . .
H23 H 0.3892 0.2859 0.0700 0.037 Uiso 1 1 calc R . .
C24 C 0.5390(5) 0.1727(6) 0.0438(2) 0.0355(10) Uani 1 1 d . . .
H24 H 0.5098 0.1946 0.0034 0.043 Uiso 1 1 calc R . .
C25 C 0.6539(4) 0.0842(6) 0.0637(2) 0.0323(10) Uani 1 1 d . . .
H25 H 0.7038 0.0444 0.0372 0.039 Uiso 1 1 calc R . .
C26 C 0.6932(4) 0.0559(5) 0.12221(19) 0.0271(9) Uani 1 1 d . . .
H26 H 0.7705 -0.0062 0.1358 0.032 Uiso 1 1 calc R . .
C11 C 0.4756(4) 0.2496(5) 0.29569(18) 0.0235(8) Uani 1 1 d . . .
H11A H 0.3886 0.2300 0.3053 0.028 Uiso 1 1 calc R . .
H11B H 0.4839 0.3664 0.2892 0.028 Uiso 1 1 calc R . .
C12 C 0.5840(4) 0.1962(5) 0.34599(18) 0.0239(8) Uani 1 1 d . . .
C13 C 0.5745(4) 0.2105(6) 0.4038(2) 0.0355(11) Uani 1 1 d . . .
H13 H 0.4977 0.2546 0.4137 0.043 Uiso 1 1 calc R . .
C14 C 0.6795(5) 0.1590(7) 0.4467(2) 0.0415(12) Uani 1 1 d . . .
H14 H 0.6746 0.1667 0.4865 0.050 Uiso 1 1 calc R . .
C15 C 0.7907(5) 0.0967(7) 0.4319(2) 0.0366(11) Uani 1 1 d . . .
H15 H 0.8634 0.0616 0.4610 0.044 Uiso 1 1 calc R . .
C16 C 0.7938(4) 0.0866(5) 0.37314(18) 0.0254(8) Uani 1 1 d . . .
H16 H 0.8704 0.0448 0.3623 0.031 Uiso 1 1 calc R . .
C31 C 0.3935(4) 0.0177(5) 0.2316(2) 0.0256(9) Uani 1 1 d . . .
H31A H 0.4063 -0.0386 0.1961 0.031 Uiso 1 1 calc R . .
H31B H 0.3014 0.0568 0.2240 0.031 Uiso 1 1 calc R . .
C32 C 0.4124(4) -0.1034(5) 0.2813(2) 0.0275(9) Uani 1 1 d . . .
H32A H 0.3294 -0.1102 0.2956 0.033 Uiso 1 1 calc R . .
H32B H 0.4819 -0.0629 0.3137 0.033 Uiso 1 1 calc R . .
C33 C 0.4502(4) -0.2719(5) 0.26522(19) 0.0252(9) Uani 1 1 d . . .
H33A H 0.4387 -0.3472 0.2964 0.030 Uiso 1 1 calc R . .
H33B H 0.3888 -0.3054 0.2289 0.030 Uiso 1 1 calc R . .
C34 C 0.5903(3) -0.2862(5) 0.25645(16) 0.0194(8) Uani 1 1 d . . .
C91 C 0.026(2) 0.194(3) 0.0719(12) 0.068(3) Uani 0.55 1 d PDU B 1
H91A H -0.0336 0.1636 0.0972 0.102 Uiso 0.55 1 calc PR B 1
H91B H 0.0006 0.1379 0.0346 0.102 Uiso 0.55 1 calc PR B 1
H91C H 0.0211 0.3106 0.0653 0.102 Uiso 0.55 1 calc PR B 1
C92 C 0.037(3) 0.152(3) 0.0734(14) 0.068(3) Uani 0.45 1 d PDU C 2
H92A H 0.0388 0.2689 0.0786 0.102 Uiso 0.45 1 calc PR C 2
H92B H -0.0505 0.1109 0.0758 0.102 Uiso 0.45 1 calc PR C 2
H92C H 0.0548 0.1256 0.0352 0.102 Uiso 0.45 1 calc PR C 2
O13' O 0.1919(14) 0.675(2) 0.0296(6) 0.0571(7) Uani 0.23 1 d PDU D 2
O12' O 0.4042(14) 0.590(2) 0.0682(8) 0.0571(7) Uani 0.23 1 d PDU D 2
O11' O 0.254(2) 0.603(3) 0.1287(8) 0.0571(7) Uani 0.23 1 d PDU D 2
O14' O 0.3302(16) 0.8383(17) 0.0926(7) 0.0571(7) Uani 0.23 1 d PDU D 2
Cl1' Cl 0.2888(8) 0.6704(11) 0.0804(4) 0.0294(4) Uani 0.23 1 d PDU D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Cu1 O1 97.25(12) . 2_655
N1 Cu1 N2 162.94(14) . .
O1 Cu1 N2 93.79(12) 2_655 .
N1 Cu1 N3 83.86(13) . .
O1 Cu1 N3 169.62(12) 2_655 .
N2 Cu1 N3 82.98(13) . .
N1 Cu1 O2 93.51(13) . .
O1 Cu1 O2 89.42(10) 2_655 .
N2 Cu1 O2 99.58(13) . .
N3 Cu1 O2 100.83(12) . .
O13 Cl1 O14 110.1(3) . .
O13 Cl1 O11 110.8(4) . .
O14 Cl1 O11 110.8(4) . .
O13 Cl1 O12 109.1(3) . .
O14 Cl1 O12 107.0(3) . .
O11 Cl1 O12 109.0(4) . .
C34 O1 Cu1 106.1(2) . 2_645
C34 O2 Cu1 148.0(2) . .
C92 O92 H92 109.5 . .
C22 N2 C26 119.0(4) . .
C22 N2 Cu1 113.3(3) . .
C26 N2 Cu1 127.6(3) . .
C16 N1 C12 119.8(4) . .
C16 N1 Cu1 124.7(3) . .
C12 N1 Cu1 115.0(3) . .
C11 N3 C21 112.0(3) . .
C11 N3 C31 112.5(3) . .
C21 N3 C31 107.9(3) . .
C11 N3 Cu1 108.1(2) . .
C21 N3 Cu1 104.5(2) . .
C31 N3 Cu1 111.6(2) . .
N3 C21 C22 109.6(3) . .
N3 C21 H21A 109.7 . .
C22 C21 H21A 109.7 . .
N3 C21 H21B 109.7 . .
C22 C21 H21B 109.7 . .
H21A C21 H21B 108.2 . .
N2 C22 C23 121.2(4) . .
N2 C22 C21 115.4(4) . .
C23 C22 C21 123.3(4) . .
C24 C23 C22 119.3(4) . .
C24 C23 H23 120.4 . .
C22 C23 H23 120.4 . .
C23 C24 C25 119.3(4) . .
C23 C24 H24 120.4 . .
C25 C24 H24 120.4 . .
C26 C25 C24 118.7(4) . .
C26 C25 H25 120.7 . .
C24 C25 H25 120.7 . .
N2 C26 C25 122.5(4) . .
N2 C26 H26 118.7 . .
C25 C26 H26 118.7 . .
N3 C11 C12 110.6(3) . .
N3 C11 H11A 109.5 . .
C12 C11 H11A 109.5 . .
N3 C11 H11B 109.5 . .
C12 C11 H11B 109.5 . .
H11A C11 H11B 108.1 . .
N1 C12 C13 121.3(4) . .
N1 C12 C11 115.7(4) . .
C13 C12 C11 123.0(4) . .
C14 C13 C12 118.6(4) . .
C14 C13 H13 120.7 . .
C12 C13 H13 120.7 . .
C15 C14 C13 120.2(4) . .
C15 C14 H14 119.9 . .
C13 C14 H14 119.9 . .
C14 C15 C16 118.2(4) . .
C14 C15 H15 120.9 . .
C16 C15 H15 120.9 . .
N1 C16 C15 121.9(4) . .
N1 C16 H16 119.1 . .
C15 C16 H16 119.1 . .
N3 C31 C32 115.2(3) . .
N3 C31 H31A 108.5 . .
C32 C31 H31A 108.5 . .
N3 C31 H31B 108.5 . .
C32 C31 H31B 108.5 . .
H31A C31 H31B 107.5 . .
C31 C32 C33 114.5(4) . .
C31 C32 H32A 108.6 . .
C33 C32 H32A 108.6 . .
C31 C32 H32B 108.6 . .
C33 C32 H32B 108.6 . .
H32A C32 H32B 107.6 . .
C34 C33 C32 114.3(3) . .
C34 C33 H33A 108.7 . .
C32 C33 H33A 108.7 . .
C34 C33 H33B 108.7 . .
C32 C33 H33B 108.7 . .
H33A C33 H33B 107.6 . .
O2 C34 O1 121.4(3) . .
O2 C34 C33 121.8(3) . .
O1 C34 C33 116.8(3) . .
O92 C92 H92A 109.5 . .
O92 C92 H92B 109.5 . .
H92A C92 H92B 109.5 . .
O92 C92 H92C 109.5 . .
H92A C92 H92C 109.5 . .
H92B C92 H92C 109.5 . .
O11' Cl1' O13' 116.9(10) . .
O11' Cl1' O12' 110.1(10) . .
O13' Cl1' O12' 108.7(9) . .
O11' Cl1' O14' 110.0(10) . .
O13' Cl1' O14' 105.7(9) . .
O12' Cl1' O14' 104.8(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 N1 1.977(3) .
Cu1 O1 1.982(3) 2_655
Cu1 N2 1.985(3) .
Cu1 N3 2.042(3) .
Cu1 O2 2.181(3) .
Cl1 O13 1.411(6) .
Cl1 O14 1.419(5) .
Cl1 O11 1.427(6) .
Cl1 O12 1.455(5) .
O1 C34 1.278(5) .
O1 Cu1 1.982(3) 2_645
O2 C34 1.249(5) .
O91 C91 1.451(15) .
O91 H91 0.8400 .
O92 C92 1.467(16) .
O92 H92 0.8400 .
N2 C22 1.343(5) .
N2 C26 1.346(5) .
N1 C16 1.341(5) .
N1 C12 1.343(5) .
N3 C11 1.489(5) .
N3 C21 1.492(5) .
N3 C31 1.499(5) .
C21 C22 1.506(6) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C23 1.397(6) .
C23 C24 1.369(7) .
C23 H23 0.9500 .
C24 C25 1.393(7) .
C24 H24 0.9500 .
C25 C26 1.369(6) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C11 C12 1.514(6) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.389(6) .
C13 C14 1.386(7) .
C13 H13 0.9500 .
C14 C15 1.376(7) .
C14 H14 0.9500 .
C15 C16 1.391(6) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C31 C32 1.524(6) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C33 1.524(6) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 C34 1.515(5) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C91 H91A 0.9800 .
C91 H91B 0.9800 .
C91 H91C 0.9800 .
C92 H92A 0.9800 .
C92 H92B 0.9800 .
C92 H92C 0.9800 .
O13' Cl1' 1.388(12) .
O12' Cl1' 1.450(13) .
O11' Cl1' 1.380(13) .
O14' Cl1' 1.472(12) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N1 Cu1 O2 C34 90.2(5) .
O1 Cu1 O2 C34 -172.6(5) 2_655
N2 Cu1 O2 C34 -78.8(5) .
N3 Cu1 O2 C34 5.8(5) .
N1 Cu1 N2 C22 -22.3(6) .
O1 Cu1 N2 C22 -152.6(3) 2_655
N3 Cu1 N2 C22 17.5(3) .
O2 Cu1 N2 C22 117.4(3) .
N1 Cu1 N2 C26 155.3(4) .
O1 Cu1 N2 C26 25.0(4) 2_655
N3 Cu1 N2 C26 -165.0(4) .
O2 Cu1 N2 C26 -65.1(4) .
O1 Cu1 N1 C16 -24.4(3) 2_655
N2 Cu1 N1 C16 -154.3(4) .
N3 Cu1 N1 C16 166.0(3) .
O2 Cu1 N1 C16 65.5(3) .
O1 Cu1 N1 C12 163.8(3) 2_655
N2 Cu1 N1 C12 33.9(6) .
N3 Cu1 N1 C12 -5.8(3) .
O2 Cu1 N1 C12 -106.3(3) .
N1 Cu1 N3 C11 18.7(3) .
O1 Cu1 N3 C11 -78.0(7) 2_655
N2 Cu1 N3 C11 -150.4(3) .
O2 Cu1 N3 C11 111.1(2) .
N1 Cu1 N3 C21 138.2(3) .
O1 Cu1 N3 C21 41.5(8) 2_655
N2 Cu1 N3 C21 -31.0(2) .
O2 Cu1 N3 C21 -129.4(2) .
N1 Cu1 N3 C31 -105.5(3) .
O1 Cu1 N3 C31 157.8(6) 2_655
N2 Cu1 N3 C31 85.4(3) .
O2 Cu1 N3 C31 -13.1(3) .
C11 N3 C21 C22 155.8(3) .
C31 N3 C21 C22 -79.9(4) .
Cu1 N3 C21 C22 39.0(3) .
C26 N2 C22 C23 -0.3(6) .
Cu1 N2 C22 C23 177.4(3) .
C26 N2 C22 C21 -176.4(4) .
Cu1 N2 C22 C21 1.4(4) .
N3 C21 C22 N2 -28.3(5) .
N3 C21 C22 C23 155.7(4) .
N2 C22 C23 C24 -1.2(7) .
C21 C22 C23 C24 174.5(4) .
C22 C23 C24 C25 1.5(7) .
C23 C24 C25 C26 -0.4(7) .
C22 N2 C26 C25 1.6(6) .
Cu1 N2 C26 C25 -175.8(3) .
C24 C25 C26 N2 -1.3(7) .
C21 N3 C11 C12 -142.0(3) .
C31 N3 C11 C12 96.2(4) .
Cu1 N3 C11 C12 -27.4(4) .
C16 N1 C12 C13 -0.9(6) .
Cu1 N1 C12 C13 171.4(3) .
C16 N1 C12 C11 178.7(4) .
Cu1 N1 C12 C11 -9.0(5) .
N3 C11 C12 N1 24.9(5) .
N3 C11 C12 C13 -155.5(4) .
N1 C12 C13 C14 0.0(7) .
C11 C12 C13 C14 -179.6(4) .
C12 C13 C14 C15 0.6(8) .
C13 C14 C15 C16 -0.3(8) .
C12 N1 C16 C15 1.2(6) .
Cu1 N1 C16 C15 -170.3(3) .
C14 C15 C16 N1 -0.6(7) .
C11 N3 C31 C32 -56.1(4) .
C21 N3 C31 C32 179.9(3) .
Cu1 N3 C31 C32 65.6(4) .
N3 C31 C32 C33 -119.4(4) .
C31 C32 C33 C34 72.3(5) .
Cu1 O2 C34 O1 163.5(3) .
Cu1 O2 C34 C33 -18.9(7) .
Cu1 O1 C34 O2 6.2(4) 2_645
Cu1 O1 C34 C33 -171.5(3) 2_645
C32 C33 C34 O2 -7.4(6) .
C32 C33 C34 O1 170.3(4) .
