#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/08/7220882.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7220882
loop_
_publ_author_name
'Wang, Xiu-Li'
'Xu, Na'
'Zhao, Xun-Zhang'
'Zhang, Ju-Wen'
'Gong, Chun-Hua'
'Li, Tian-Jiao'
_publ_section_title
;
 Polyoxometalate-directed assembly and various structures of
 inorganic--organic hybrid compounds based on a semi-rigid
 bis-pyridyl-bis-amide
;
_journal_issue                   37
_journal_name_full               CrystEngComm
_journal_page_first              7038
_journal_paper_doi               10.1039/C5CE00962F
_journal_volume                  17
_journal_year                    2015
_chemical_formula_sum            'C36 H62 Cr Cu4 Mo6 N8 O42'
_chemical_formula_weight         2160.74
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-02 deposited with the CCDC.
2015-06-25 downloaded from the CCDC.
;
_cell_angle_alpha                113.644(3)
_cell_angle_beta                 92.071(4)
_cell_angle_gamma                114.579(3)
_cell_formula_units_Z            1
_cell_length_a                   10.8767(19)
_cell_length_b                   12.698(2)
_cell_length_c                   14.373(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1603.9(5)
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT+ (Bruker, 1999)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (1998)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0349
_diffrn_reflns_av_unetI/netI     0.0699
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9448
_diffrn_reflns_theta_full        25.43
_diffrn_reflns_theta_max         25.43
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    2.698
_exptl_absorpt_correction_T_max  0.6144
_exptl_absorpt_correction_T_min  0.5519
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.237
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1062
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_refine_diff_density_max         3.218
_refine_diff_density_min         -3.844
_refine_diff_density_rms         0.314
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         5879
_refine_ls_number_restraints     894
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.1241
_refine_ls_R_factor_gt           0.0846
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1483P)²+39.0292P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2429
_refine_ls_wR_factor_ref         0.2761
_reflns_number_gt                3923
_reflns_number_total             5879
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce00962f2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7220880--7220883.cif.'
_cod_original_cell_volume        1603.8(5)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7220882
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cr1 Cr 1.0000 1.5000 1.0000 0.0157(6) Uani 1 2 d S
Cu1 Cu 0.50154(19) 1.44468(16) 1.25133(13) 0.0286(5) Uani 1 1 d .
N1 N 0.6005(13) 1.6318(11) 1.2805(9) 0.029(3) Uani 1 1 d .
Mo1 Mo 0.81948(12) 1.39163(11) 1.15377(9) 0.0226(3) Uani 1 1 d .
O1W O 0.7837(16) 1.6498(14) 1.5679(12) 0.072(3) Uani 1 1 d U
C1 C 0.9225(14) 1.8671(12) 0.9628(10) 0.023(3) Uani 1 1 d .
H46A H 0.8700 1.7775 0.9374 0.027 Uiso 1 1 calc R
Mo2 Mo 1.16637(12) 1.56885(12) 1.23395(9) 0.0259(3) Uani 1 1 d .
N2 N 0.4139(12) 1.2534(11) 1.2051(9) 0.025(2) Uani 1 1 d .
Cu2 Cu 0.6068(3) 1.5028(3) 1.5060(2) 0.0695(8) Uani 1 1 d .
O2 O 0.1354(12) 0.8811(9) 1.2457(9) 0.039(2) Uani 1 1 d U
C2 C 0.3538(15) 1.0425(14) 1.0681(12) 0.030(3) Uani 1 1 d .
H45A H 0.3640 0.9923 1.0038 0.036 Uiso 1 1 calc R
O2W O 0.6363(17) 1.3673(15) 1.4732(12) 0.078(3) Uani 1 1 d U
Mo3 Mo 0.65581(12) 1.31566(11) 0.91724(9) 0.0226(3) Uani 1 1 d .
O3W O 0.3907(11) 1.4016(10) 1.1145(8) 0.0334(19) Uani 1 1 d U
O3 O 0.6960(11) 1.4298(10) 1.2054(8) 0.0344(17) Uani 1 1 d U
C3 C 0.0299(16) 0.9078(14) 1.4248(12) 0.032(3) Uani 1 1 d .
H44A H 0.0512 0.8471 1.3761 0.039 Uiso 1 1 calc R
O4W O 0.5064(13) 1.4854(11) 1.3959(9) 0.048(2) Uani 1 1 d U
O4 O 0.8490(11) 1.7200(10) 1.0827(8) 0.0334(19) Uani 1 1 d U
C4 C 1.0017(15) 1.9154(13) 0.9029(12) 0.030(3) Uani 1 1 d .
H4A H 1.0030 1.8583 0.8379 0.035 Uiso 1 1 calc R
O5W O 0.6877(14) 2.0520(13) 1.2017(11) 0.062(3) Uani 1 1 d U
H4WA H 0.7214 2.0016 1.1649 0.074 Uiso 1 1 d R
H4WB H 0.7341 2.1241 1.1993 0.074 Uiso 1 1 d R
N5 N 0.8409(13) 1.9098(11) 1.1270(10) 0.030(3) Uani 1 1 d .
O5 O 0.9798(11) 1.5465(10) 1.2447(8) 0.0342(17) Uani 1 1 d U
C5 C 0.0696(14) 1.0281(13) 1.4273(11) 0.025(3) Uani 1 1 d .
N6 N 0.1456(12) 1.0697(11) 1.3592(9) 0.028(3) Uani 1 1 d .
O6 O 0.5697(11) 1.1667(10) 0.8126(8) 0.038(2) Uani 1 1 d U
C6 C 0.8138(13) 1.8010(13) 1.1389(11) 0.024(3) Uani 1 1 d .
O6W O 1.2460(16) 1.8069(14) 1.5493(11) 0.073(3) Uani 1 1 d U
O7W O 0.5464(18) 1.9796(16) 1.5880(13) 0.089(4) Uani 1 1 d U
O7 O 0.5325(11) 1.3524(11) 0.9684(8) 0.037(2) Uani 1 1 d U
C7 C 0.2738(15) 0.9855(13) 1.1207(11) 0.028(3) Uani 1 1 d .
H39A H 0.2268 0.8952 1.0925 0.033 Uiso 1 1 calc R
O8 O 0.8302(12) 1.2869(10) 1.1933(9) 0.040(2) Uani 1 1 d U
C8 C 0.4199(16) 1.1759(14) 1.1109(11) 0.030(3) Uani 1 1 d .
H38A H 0.4714 1.2144 1.0727 0.036 Uiso 1 1 calc R
O9 O 1.0071(10) 1.4036(9) 1.0763(8) 0.0289(16) Uani 1 1 d U
C9 C -0.0418(16) 0.8804(13) 1.4963(11) 0.029(3) Uani 1 1 d .
H9A H -0.0724 0.7987 1.4933 0.035 Uiso 1 1 calc R
O10 O 1.1748(12) 1.4573(11) 1.2672(8) 0.039(2) Uani 1 1 d U
C10 C 0.9202(14) 1.9508(13) 1.0610(12) 0.028(3) Uani 1 1 d .
C11 C 0.1759(14) 0.9969(12) 1.2752(10) 0.022(3) Uani 1 1 d .
O12 O 1.2973(11) 1.5693(10) 1.1461(8) 0.0306(17) Uani 1 1 d U
C12 C 0.7390(13) 1.7836(13) 1.2186(10) 0.021(3) Uani 1 1 d .
O13 O 1.2606(12) 1.7195(11) 1.3410(9) 0.044(2) Uani 1 1 d U
C13 C 0.5947(16) 1.7287(14) 1.3592(11) 0.032(3) Uani 1 1 d .
H29A H 0.5420 1.7099 1.4053 0.039 Uiso 1 1 calc R
O14 O 0.8646(10) 1.3451(9) 0.8756(8) 0.0268(16) Uani 1 1 d U
C14 C 0.7319(16) 1.8828(14) 1.3028(11) 0.031(3) Uani 1 1 d .
H28A H 0.7732 1.9673 1.3107 0.038 Uiso 1 1 calc R
O15 O 0.7147(11) 1.2658(10) 1.0126(8) 0.0313(17) Uani 1 1 d U
C15 C 0.2618(14) 1.0620(13) 1.2170(11) 0.025(3) Uani 1 1 d .
O16 O 0.8352(11) 1.4958(10) 1.0528(8) 0.0306(16) Uani 1 1 d U
C16 C 0.6695(14) 1.6586(13) 1.2098(10) 0.022(3) Uani 1 1 d .
H25A H 0.6706 1.5903 1.1526 0.027 Uiso 1 1 calc R
C17 C 0.6612(17) 1.8534(15) 1.3759(12) 0.036(4) Uani 1 1 d .
H24A H 0.6602 1.9193 1.4353 0.043 Uiso 1 1 calc R
C18 C 0.3363(14) 1.1950(12) 1.2572(10) 0.023(3) Uani 1 1 d .
H21A H 0.3326 1.2468 1.3235 0.028 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 Cr1 O14 179.998(4) . 2_787
O14 Cr1 O16 95.6(4) . 2_787
O14 Cr1 O16 84.4(4) 2_787 2_787
O14 Cr1 O16 84.4(4) . .
O14 Cr1 O16 95.6(4) 2_787 .
O16 Cr1 O16 180.0(3) 2_787 .
O14 Cr1 O9 85.4(4) . 2_787
O14 Cr1 O9 94.6(4) 2_787 2_787
O16 Cr1 O9 85.3(4) 2_787 2_787
O16 Cr1 O9 94.7(4) . 2_787
O14 Cr1 O9 94.6(4) . .
O14 Cr1 O9 85.4(4) 2_787 .
O16 Cr1 O9 94.7(4) 2_787 .
O16 Cr1 O9 85.3(4) . .
O9 Cr1 O9 179.999(6) 2_787 .
O4W Cu1 N2 92.9(5) . .
O4W Cu1 N1 94.1(5) . .
N2 Cu1 N1 172.1(5) . .
O4W Cu1 O3W 146.0(5) . .
N2 Cu1 O3W 87.3(4) . .
N1 Cu1 O3W 88.9(5) . .
O4W Cu1 O3 112.2(5) . .
N2 Cu1 O3 86.5(4) . .
N1 Cu1 O3 87.5(4) . .
O3W Cu1 O3 101.7(4) . .
C13 N1 C16 117.9(12) . .
C13 N1 Cu1 124.8(10) . .
C16 N1 Cu1 117.1(9) . .
O8 Mo1 O3 106.9(5) . .
O8 Mo1 O5 100.8(5) . .
O3 Mo1 O5 98.9(5) . .
O8 Mo1 O15 97.1(5) . .
O3 Mo1 O15 100.7(5) . .
O5 Mo1 O15 148.2(4) . .
O8 Mo1 O16 159.1(4) . .
O3 Mo1 O16 92.2(4) . .
O5 Mo1 O16 84.2(4) . .
O15 Mo1 O16 70.4(4) . .
O8 Mo1 O9 92.0(4) . .
O3 Mo1 O9 160.3(4) . .
O5 Mo1 O9 71.5(4) . .
O15 Mo1 O9 81.9(4) . .
O16 Mo1 O9 70.1(3) . .
C4 C1 C10 120.8(12) . .
C4 C1 H46A 119.6 . .
C10 C1 H46A 119.6 . .
O10 Mo2 O13 107.2(6) . .
O10 Mo2 O12 96.6(5) . .
O13 Mo2 O12 101.6(5) . .
O10 Mo2 O5 102.5(5) . .
O13 Mo2 O5 98.3(5) . .
O12 Mo2 O5 146.8(4) . .
O10 Mo2 O9 90.8(5) . .
O13 Mo2 O9 160.8(5) . .
O12 Mo2 O9 82.3(4) . .
O5 Mo2 O9 70.7(4) . .
O10 Mo2 O14 157.6(5) . 2_787
O13 Mo2 O14 93.7(5) . 2_787
O12 Mo2 O14 70.7(4) . 2_787
O5 Mo2 O14 81.7(4) . 2_787
O9 Mo2 O14 69.6(3) . 2_787
C18 N2 C8 117.0(12) . .
C18 N2 Cu1 124.1(9) . .
C8 N2 Cu1 118.5(9) . .
O2W Cu2 O4W 110.8(7) . .
O2W Cu2 O1W 105.7(7) . .
O4W Cu2 O1W 116.6(7) . .
O2W Cu2 O4W 112.0(7) . 2_688
O4W Cu2 O4W 103.0(5) . 2_688
O1W Cu2 O4W 108.9(6) . 2_688
O2W Cu2 Cu2 125.9(6) . 2_688
O4W Cu2 Cu2 54.1(4) . 2_688
O1W Cu2 Cu2 128.0(5) . 2_688
O4W Cu2 Cu2 48.8(4) 2_688 2_688
C7 C2 C8 118.8(13) . .
C7 C2 H45A 120.6 . .
C8 C2 H45A 120.6 . .
O6 Mo3 O7 106.5(5) . .
O6 Mo3 O15 98.3(5) . .
O7 Mo3 O15 101.5(5) . .
O6 Mo3 O12 102.7(5) . 2_787
O7 Mo3 O12 94.8(5) . 2_787
O15 Mo3 O12 148.5(4) . 2_787
O6 Mo3 O14 91.9(4) . .
O7 Mo3 O14 159.5(5) . .
O15 Mo3 O14 84.2(4) . .
O12 Mo3 O14 71.9(4) 2_787 .
O6 Mo3 O16 159.1(4) . .
O7 Mo3 O16 93.2(5) . .
O15 Mo3 O16 70.4(4) . .
O12 Mo3 O16 82.1(4) 2_787 .
O14 Mo3 O16 70.0(4) . .
Mo1 O3 Cu1 169.7(6) . .
C9 C3 C5 118.4(13) . .
C9 C3 H44A 120.8 . .
C5 C3 H44A 120.8 . .
Cu2 O4W Cu2 77.0(5) . 2_688
Cu2 O4W Cu1 140.4(7) . .
Cu2 O4W Cu1 141.7(8) 2_688 .
C1 C4 C10 120.5(14) . 2_797
C1 C4 H4A 119.8 . .
C10 C4 H4A 119.8 2_797 .
H4WA O5W H4WB 104.9 . .
C6 N5 C10 126.5(12) . .
Mo1 O5 Mo2 121.5(5) . .
C3 C5 C9 119.7(12) . 2_578
C3 C5 N6 124.3(12) . .
C9 C5 N6 115.9(12) 2_578 .
C11 N6 C5 127.0(12) . .
O4 C6 N5 121.0(12) . .
O4 C6 C12 121.9(12) . .
N5 C6 C12 117.1(12) . .
C2 C7 C15 119.7(13) . .
C2 C7 H39A 120.2 . .
C15 C7 H39A 120.2 . .
N2 C8 C2 123.2(12) . .
N2 C8 H38A 118.4 . .
C2 C8 H38A 118.4 . .
Cr1 O9 Mo2 102.4(4) . .
Cr1 O9 Mo1 101.4(4) . .
Mo2 O9 Mo1 91.5(3) . .
C3 C9 C5 121.8(13) . 2_578
C3 C9 H9A 119.1 . .
C5 C9 H9A 119.1 2_578 .
C4 C10 C1 118.8(13) 2_797 .
C4 C10 N5 116.6(13) 2_797 .
C1 C10 N5 124.6(12) . .
O2 C11 N6 122.2(12) . .
O2 C11 C15 119.8(12) . .
N6 C11 C15 118.0(11) . .
Mo3 O12 Mo2 119.4(5) 2_787 .
C14 C12 C16 117.2(12) . .
C14 C12 C6 124.8(12) . .
C16 C12 C6 118.1(12) . .
N1 C13 C17 123.3(14) . .
N1 C13 H29A 118.3 . .
C17 C13 H29A 118.3 . .
Cr1 O14 Mo3 103.1(4) . .
Cr1 O14 Mo2 102.6(4) . 2_787
Mo3 O14 Mo2 92.5(3) . 2_787
C12 C14 C17 118.8(13) . .
C12 C14 H28A 120.6 . .
C17 C14 H28A 120.6 . .
Mo3 O15 Mo1 121.3(5) . .
C18 C15 C7 118.2(12) . .
C18 C15 C11 122.9(12) . .
C7 C15 C11 118.8(12) . .
Cr1 O16 Mo1 103.1(4) . .
Cr1 O16 Mo3 102.5(4) . .
Mo1 O16 Mo3 93.5(3) . .
N1 C16 C12 123.1(12) . .
N1 C16 H25A 118.4 . .
C12 C16 H25A 118.4 . .
C13 C17 C14 119.4(14) . .
C13 C17 H24A 120.3 . .
C14 C17 H24A 120.3 . .
N2 C18 C15 122.9(12) . .
N2 C18 H21A 118.5 . .
C15 C18 H21A 118.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cr1 O14 1.953(10) .
Cr1 O14 1.953(10) 2_787
Cr1 O16 1.961(10) 2_787
Cr1 O16 1.961(10) .
Cr1 O9 1.965(9) 2_787
Cr1 O9 1.965(9) .
Cu1 O4W 1.923(11) .
Cu1 N2 1.996(11) .
Cu1 N1 2.005(12) .
Cu1 O3W 2.009(11) .
Cu1 O3 2.297(10) .
N1 C13 1.324(18) .
N1 C16 1.353(17) .
Mo1 O8 1.684(10) .
Mo1 O3 1.707(10) .
Mo1 O5 1.881(11) .
Mo1 O15 1.920(11) .
Mo1 O16 2.291(9) .
Mo1 O9 2.339(9) .
O1W Cu2 1.880(15) .
C1 C4 1.377(19) .
C1 C10 1.39(2) .
C1 H46A 0.9300 .
Mo2 O10 1.701(10) .
Mo2 O13 1.724(12) .
Mo2 O12 1.937(10) .
Mo2 O5 1.949(10) .
Mo2 O9 2.327(11) .
Mo2 O14 2.330(9) 2_787
N2 C18 1.338(16) .
N2 C8 1.341(18) .
Cu2 O2W 1.761(17) .
Cu2 O4W 1.771(13) .
Cu2 O4W 1.907(12) 2_688
Cu2 Cu2 2.293(7) 2_688
O2 C11 1.219(16) .
C2 C7 1.348(19) .
C2 C8 1.372(19) .
C2 H45A 0.9300 .
Mo3 O6 1.691(11) .
Mo3 O7 1.694(10) .
Mo3 O15 1.913(10) .
Mo3 O12 1.925(9) 2_787
Mo3 O14 2.286(9) .
Mo3 O16 2.296(11) .
C3 C9 1.379(19) .
C3 C5 1.389(19) .
C3 H44A 0.9300 .
O4W Cu2 1.907(12) 2_688
O4 C6 1.242(17) .
C4 C10 1.392(19) 2_797
C4 H4A 0.9300 .
O5W H4WA 0.8724 .
O5W H4WB 0.8586 .
N5 C6 1.371(17) .
N5 C10 1.413(17) .
C5 C9 1.393(19) 2_578
C5 N6 1.425(16) .
N6 C11 1.344(17) .
C6 C12 1.465(18) .
C7 C15 1.383(19) .
C7 H39A 0.9300 .
C8 H38A 0.9300 .
C9 C5 1.393(19) 2_578
C9 H9A 0.9300 .
C10 C4 1.392(19) 2_797
C11 C15 1.492(18) .
O12 Mo3 1.925(9) 2_787
C12 C14 1.39(2) .
C12 C16 1.393(18) .
C13 C17 1.35(2) .
C13 H29A 0.9300 .
O14 Mo2 2.330(9) 2_787
C14 C17 1.40(2) .
C14 H28A 0.9300 .
C15 C18 1.374(18) .
C16 H25A 0.9300 .
C17 H24A 0.9300 .
C18 H21A 0.9300 .
