#------------------------------------------------------------------------------
#$Date: 2015-10-10 04:54:10 +0300 (Sat, 10 Oct 2015) $
#$Revision: 164329 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/26/7222699.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7222699
loop_
_publ_author_name
'Wickleder, C.'
_publ_section_title
;
 A new mixed valent europium chloride: Na5 Eu7 Cl22
;
_journal_name_full
;
Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische 
Chemie (42,1987-)
;
_journal_page_first              901
_journal_page_last               907
_journal_volume                  57
_journal_year                    2002
_chemical_formula_sum            'Cl22 Eu7 Na5'
_chemical_name_systematic        'Na5 Eu7 Cl22'
_space_group_IT_number           59
_symmetry_space_group_name_Hall  '-P 2ab 2a'
_symmetry_space_group_name_H-M   'P m m n :2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   25.259
_cell_length_b                   8.4691
_cell_length_c                   7.8172
_cell_volume                     1672.263
_citation_journal_id_ASTM        ZNBSEN
_cod_data_source_file            Wickleder_ZNBSEN_2002_783.cif
_cod_data_source_block           Cl22Eu7Na5
_cod_database_code               7222699
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x+1/2,-y+1/2,z
x+1/2,-y,-z
-x,y+1/2,-z
-x,-y,-z
x-1/2,y-1/2,-z
-x-1/2,y,z
x,-y-1/2,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Cl6 Cl-1 -0.37293 0.25 0.2689 1 0.0
Cl8 Cl-1 -0.50028 0.25 0.4411 1 0.0
Na2 Na+1 -0.58012 0.0029 -0.5094 1 0.0
Eu2 Eu+2 -0.75 0.25 -0.51062 1 0.0
Eu1 Eu+3 -0.49186 0.25 0.08751 1 0.0
Cl1 Cl-1 -0.75 -0.0367 -0.2729 1 0.0
Cl7 Cl-1 -0.75 -0.25 -0.9123 1 0.0
Cl10 Cl-1 -0.41124 0.25 -0.1429 1 0.0
Cl3 Cl-1 -0.68028 -0.0176 -0.6415 1 0.0
Eu4 Eu+2 -0.662591 0.00187 -0.02354 0.769 0.0
Na1 Na+1 -0.662591 0.00187 -0.02354 0.231 0.0
Eu3 Eu+3 -0.75 -0.25 -0.5414 1 0.0
Cl4 Cl-1 -0.5374 0.0492 -0.1638 1 0.0
Cl2 Cl-1 -0.59914 0.25 0.1596 1 0.0
Cl5 Cl-1 -0.65104 0.25 -0.2949 1 0.0
Cl9 Cl-1 -0.75 0.25 -0.9257 1 0.0
