#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/30/7223016.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7223016
loop_
_publ_author_name
'Ye, Run-Ping'
'Zhang, Xin'
'Zhai, Ji-Quan'
'Qin, Ye-Yan'
'Zhang, Lei'
'Yao, Yuan-Gen'
'Zhang, Jian'
_publ_section_title
;
 N-donor ligands enhancing luminescence properties of seven Zn/Cd(ii) MOFs
 based on a large rigid π-conjugated carboxylate ligand
;
_journal_issue                   47
_journal_name_full               CrystEngComm
_journal_page_first              9155
_journal_paper_doi               10.1039/C5CE01884F
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C26 H19 N3 O6 Zn, H2 O'
_chemical_formula_sum            'C26 H21 N3 O7 Zn'
_chemical_formula_weight         552.85
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-10-21 deposited with the CCDC.
2015-10-23 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 91.928(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.6783(4)
_cell_length_b                   18.8256(7)
_cell_length_c                   14.1402(6)
_cell_measurement_reflns_used    2666
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.3100
_cell_measurement_theta_min      2.9950
_cell_volume                     2308.84(17)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0440
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8515
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.35
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  0
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    1.119
_exptl_absorpt_correction_T_max  0.865
_exptl_absorpt_correction_T_min  0.502
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   crystalclear
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.590
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1136.0
_exptl_crystal_size_max          0.82
_exptl_crystal_size_mid          0.52
_exptl_crystal_size_min          0.13
_refine_diff_density_max         0.423
_refine_diff_density_min         -0.348
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     338
_refine_ls_number_reflns         4049
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0495
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0288P)²+1.0186P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
_refine_ls_wR_factor_ref         0.0809
_reflns_number_gt                3263
_reflns_number_total             4049
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce01884f2.cif
_cod_data_source_block           Compound-7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7223010--7223016.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7223016
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.32300(3) 0.350143(16) 0.87942(2) 0.02391(11) Uani 1 1 d .
O1 O 0.4373(2) 0.41710(10) 0.80492(14) 0.0390(5) Uani 1 1 d .
O1W O 0.4084(2) 0.37217(11) 1.01701(13) 0.0345(5) Uani 1 1 d .
H1WA H 0.4538 0.4131 1.0188 0.052 Uiso 1 1 d R
H1WB H 0.4746 0.3401 1.0348 0.052 Uiso 1 1 d R
O2 O 0.4176(3) 0.51294(12) 0.89470(15) 0.0570(7) Uani 1 1 d .
O3 O 0.4578(2) 0.74888(11) 0.71631(14) 0.0395(5) Uani 1 1 d .
O4 O 0.6260(2) 0.74874(10) 0.60139(13) 0.0336(5) Uani 1 1 d .
O5 O 0.6712(2) 0.37482(10) 0.54494(14) 0.0395(5) Uani 1 1 d .
N1 N 0.7152(2) 0.49473(12) 0.51600(15) 0.0274(5) Uani 1 1 d .
N2 N 0.1792(2) 0.32316(12) 0.75306(15) 0.0287(5) Uani 1 1 d .
N3 N 0.0951(2) 0.37105(12) 0.91971(16) 0.0289(5) Uani 1 1 d .
C1 C 0.4488(3) 0.48311(15) 0.82033(19) 0.0269(6) Uani 1 1 d .
C2 C 0.5098(3) 0.52577(15) 0.73908(19) 0.0261(6) Uani 1 1 d .
C3 C 0.4947(3) 0.59892(14) 0.73752(18) 0.0261(6) Uani 1 1 d .
H3 H 0.4460 0.6222 0.7863 0.031 Uiso 1 1 calc R
C4 C 0.5525(3) 0.63757(14) 0.66290(19) 0.0256(6) Uani 1 1 d .
C5 C 0.5421(3) 0.71739(14) 0.66093(19) 0.0270(6) Uani 1 1 d .
C6 C 0.6241(3) 0.60211(14) 0.59031(19) 0.0269(6) Uani 1 1 d .
H6 H 0.6639 0.6280 0.5407 0.032 Uiso 1 1 calc R
C7 C 0.6374(3) 0.52849(14) 0.59054(18) 0.0258(6) Uani 1 1 d .
C8 C 0.5794(3) 0.49016(14) 0.66603(18) 0.0269(6) Uani 1 1 d .
H8 H 0.5875 0.4409 0.6673 0.032 Uiso 1 1 calc R
C9 C 0.7974(3) 0.53732(14) 0.44717(19) 0.0306(7) Uani 1 1 d .
H9A H 0.8713 0.5689 0.4784 0.037 Uiso 1 1 calc R
H9B H 0.7264 0.5652 0.4079 0.037 Uiso 1 1 calc R
C10 C 0.7301(3) 0.42291(15) 0.49983(19) 0.0288(6) Uani 1 1 d .
C11 C 0.8328(3) 0.41582(16) 0.41974(19) 0.0300(6) Uani 1 1 d .
C12 C 0.8765(3) 0.48231(15) 0.39037(19) 0.0308(7) Uani 1 1 d .
C13 C 0.9807(3) 0.49030(17) 0.3194(2) 0.0405(8) Uani 1 1 d .
H13 H 1.0097 0.5352 0.2991 0.049 Uiso 1 1 calc R
C14 C 1.0407(4) 0.43002(19) 0.2795(2) 0.0462(8) Uani 1 1 d .
H14 H 1.1128 0.4343 0.2326 0.055 Uiso 1 1 calc R
C15 C 0.9950(4) 0.36332(18) 0.3080(2) 0.0494(9) Uani 1 1 d .
H15 H 1.0362 0.3234 0.2796 0.059 Uiso 1 1 calc R
C16 C 0.8895(4) 0.35482(17) 0.3778(2) 0.0410(8) Uani 1 1 d .
H16 H 0.8574 0.3099 0.3962 0.049 Uiso 1 1 calc R
C17 C 0.2298(3) 0.29860(16) 0.6708(2) 0.0366(7) Uani 1 1 d .
H17 H 0.3354 0.2976 0.6617 0.044 Uiso 1 1 calc R
C18 C 0.1319(4) 0.27477(18) 0.5994(2) 0.0450(8) Uani 1 1 d .
H18 H 0.1706 0.2579 0.5431 0.054 Uiso 1 1 calc R
C19 C -0.0230(4) 0.27631(18) 0.6126(2) 0.0473(8) Uani 1 1 d .
H19 H -0.0912 0.2597 0.5655 0.057 Uiso 1 1 calc R
C20 C -0.0780(4) 0.30249(17) 0.6957(2) 0.0421(8) Uani 1 1 d .
H20 H -0.1833 0.3042 0.7055 0.051 Uiso 1 1 calc R
C21 C 0.0271(3) 0.32625(15) 0.7649(2) 0.0292(6) Uani 1 1 d .
C22 C -0.0202(3) 0.35639(15) 0.8562(2) 0.0297(7) Uani 1 1 d .
C23 C -0.1725(3) 0.37185(19) 0.8751(2) 0.0475(9) Uani 1 1 d .
H23 H -0.2512 0.3614 0.8310 0.057 Uiso 1 1 calc R
C24 C -0.2049(4) 0.4028(2) 0.9602(3) 0.0557(10) Uani 1 1 d .
H24 H -0.3061 0.4143 0.9736 0.067 Uiso 1 1 calc R
C25 C -0.0896(4) 0.4167(2) 1.0249(2) 0.0506(9) Uani 1 1 d .
H25 H -0.1107 0.4370 1.0830 0.061 Uiso 1 1 calc R
C26 C 0.0587(3) 0.40000(17) 1.0026(2) 0.0399(8) Uani 1 1 d .
H26 H 0.1377 0.4092 1.0470 0.048 Uiso 1 1 calc R
O2W O 0.4088(3) 0.73061(12) 0.90698(15) 0.0482(6) Uani 1 1 d G
H2WA H 0.4165 0.7323 0.8473 0.072 Uiso 1 1 d G
H2WB H 0.4009 0.7725 0.9287 0.072 Uiso 1 1 d G
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O4 125.94(8) . 2_646
O1 Zn1 O1W 101.78(8) . .
O4 Zn1 O1W 89.61(8) 2_646 .
O1 Zn1 N3 121.75(9) . .
O4 Zn1 N3 110.49(8) 2_646 .
O1W Zn1 N3 91.02(8) . .
O1 Zn1 N2 89.73(9) . .
O4 Zn1 N2 90.38(8) 2_646 .
O1W Zn1 N2 165.74(7) . .
N3 Zn1 N2 75.65(8) . .
C1 O1 Zn1 125.77(17) . .
Zn1 O1W H1WA 110.5 . .
Zn1 O1W H1WB 110.0 . .
H1WA O1W H1WB 108.4 . .
C5 O4 Zn1 119.08(17) . 2_656
C10 N1 C7 127.7(2) . .
C10 N1 C9 112.1(2) . .
C7 N1 C9 120.2(2) . .
C21 N2 C17 118.5(3) . .
C21 N2 Zn1 115.02(18) . .
C17 N2 Zn1 126.20(19) . .
C26 N3 C22 118.3(2) . .
C26 N3 Zn1 124.16(19) . .
C22 N3 Zn1 117.51(17) . .
O2 C1 O1 125.3(3) . .
O2 C1 C2 120.0(2) . .
O1 C1 C2 114.7(2) . .
C3 C2 C8 120.8(2) . .
C3 C2 C1 120.4(2) . .
C8 C2 C1 118.8(2) . .
C2 C3 C4 119.8(2) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C6 C4 C3 119.4(3) . .
C6 C4 C5 119.6(2) . .
C3 C4 C5 120.9(2) . .
O3 C5 O4 123.9(3) . .
O3 C5 C4 120.1(2) . .
O4 C5 C4 116.0(2) . .
C4 C6 C7 121.1(2) . .
C4 C6 H6 119.5 . .
C7 C6 H6 119.5 . .
C6 C7 C8 119.0(2) . .
C6 C7 N1 119.0(2) . .
C8 C7 N1 121.9(2) . .
C2 C8 C7 119.8(3) . .
C2 C8 H8 120.1 . .
C7 C8 H8 120.1 . .
N1 C9 C12 102.8(2) . .
N1 C9 H9A 111.2 . .
C12 C9 H9A 111.2 . .
N1 C9 H9B 111.2 . .
C12 C9 H9B 111.2 . .
H9A C9 H9B 109.1 . .
O5 C10 N1 126.4(3) . .
O5 C10 C11 127.3(3) . .
N1 C10 C11 106.2(2) . .
C12 C11 C16 121.2(3) . .
C12 C11 C10 109.3(2) . .
C16 C11 C10 129.5(3) . .
C11 C12 C13 120.8(3) . .
C11 C12 C9 109.4(2) . .
C13 C12 C9 129.8(3) . .
C14 C13 C12 118.3(3) . .
C14 C13 H13 120.9 . .
C12 C13 H13 120.9 . .
C13 C14 C15 120.9(3) . .
C13 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
C16 C15 C14 121.3(3) . .
C16 C15 H15 119.4 . .
C14 C15 H15 119.4 . .
C15 C16 C11 117.6(3) . .
C15 C16 H16 121.2 . .
C11 C16 H16 121.2 . .
N2 C17 C18 122.6(3) . .
N2 C17 H17 118.7 . .
C18 C17 H17 118.7 . .
C19 C18 C17 118.7(3) . .
C19 C18 H18 120.6 . .
C17 C18 H18 120.6 . .
C18 C19 C20 119.8(3) . .
C18 C19 H19 120.1 . .
C20 C19 H19 120.1 . .
C19 C20 C21 118.6(3) . .
C19 C20 H20 120.7 . .
C21 C20 H20 120.7 . .
N2 C21 C20 121.7(3) . .
N2 C21 C22 115.4(2) . .
C20 C21 C22 122.8(3) . .
N3 C22 C23 121.2(3) . .
N3 C22 C21 115.9(2) . .
C23 C22 C21 122.8(3) . .
C24 C23 C22 118.8(3) . .
C24 C23 H23 120.6 . .
C22 C23 H23 120.6 . .
C25 C24 C23 120.2(3) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C24 C25 C26 118.5(3) . .
C24 C25 H25 120.7 . .
C26 C25 H25 120.7 . .
N3 C26 C25 123.0(3) . .
N3 C26 H26 118.5 . .
C25 C26 H26 118.5 . .
H2WA O2W H2WB 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.9372(18) .
Zn1 O4 1.9763(19) 2_646
Zn1 O1W 2.0999(18) .
Zn1 N3 2.114(2) .
Zn1 N2 2.204(2) .
O1 C1 1.265(3) .
O1W H1WA 0.8662 .
O1W H1WB 0.8655 .
O2 C1 1.230(3) .
O3 C5 1.240(3) .
O4 C5 1.276(3) .
O4 Zn1 1.9763(19) 2_656
O5 C10 1.229(3) .
N1 C10 1.378(3) .
N1 C7 1.421(3) .
N1 C9 1.465(3) .
N2 C21 1.337(3) .
N2 C17 1.339(3) .
N3 C26 1.339(3) .
N3 C22 1.350(3) .
C1 C2 1.512(4) .
C2 C3 1.383(4) .
C2 C8 1.387(4) .
C3 C4 1.389(4) .
C3 H3 0.9300 .
C4 C6 1.389(4) .
C4 C5 1.506(3) .
C6 C7 1.391(4) .
C6 H6 0.9300 .
C7 C8 1.396(4) .
C8 H8 0.9300 .
C9 C12 1.492(4) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.471(4) .
C11 C12 1.376(4) .
C11 C16 1.390(4) .
C12 C13 1.382(4) .
C13 C14 1.377(4) .
C13 H13 0.9300 .
C14 C15 1.381(5) .
C14 H14 0.9300 .
C15 C16 1.378(4) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C18 1.373(4) .
C17 H17 0.9300 .
C18 C19 1.364(4) .
C18 H18 0.9300 .
C19 C20 1.375(4) .
C19 H19 0.9300 .
C20 C21 1.388(4) .
C20 H20 0.9300 .
C21 C22 1.482(4) .
C22 C23 1.388(4) .
C23 C24 1.375(4) .
C23 H23 0.9300 .
C24 C25 1.358(4) .
C24 H24 0.9300 .
C25 C26 1.372(4) .
C25 H25 0.9300 .
C26 H26 0.9300 .
O2W H2WA 0.8497 .
O2W H2WB 0.8501 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O4 Zn1 O1 C1 -149.5(2) 2_646
O1W Zn1 O1 C1 -51.3(2) .
N3 Zn1 O1 C1 47.3(3) .
N2 Zn1 O1 C1 120.2(2) .
O1 Zn1 N2 C21 -128.7(2) .
O4 Zn1 N2 C21 105.3(2) 2_646
O1W Zn1 N2 C21 15.4(5) .
N3 Zn1 N2 C21 -5.76(19) .
O1 Zn1 N2 C17 57.5(2) .
O4 Zn1 N2 C17 -68.4(2) 2_646
O1W Zn1 N2 C17 -158.3(3) .
N3 Zn1 N2 C17 -179.5(3) .
O1 Zn1 N3 C26 -94.5(2) .
O4 Zn1 N3 C26 100.0(2) 2_646
O1W Zn1 N3 C26 10.0(2) .
N2 Zn1 N3 C26 -175.1(3) .
O1 Zn1 N3 C22 83.1(2) .
O4 Zn1 N3 C22 -82.4(2) 2_646
O1W Zn1 N3 C22 -172.3(2) .
N2 Zn1 N3 C22 2.58(19) .
Zn1 O1 C1 O2 16.1(4) .
Zn1 O1 C1 C2 -165.33(17) .
O2 C1 C2 C3 -16.4(4) .
O1 C1 C2 C3 164.9(2) .
O2 C1 C2 C8 164.2(3) .
O1 C1 C2 C8 -14.5(4) .
C8 C2 C3 C4 -1.3(4) .
C1 C2 C3 C4 179.4(2) .
C2 C3 C4 C6 0.4(4) .
C2 C3 C4 C5 -178.1(2) .
Zn1 O4 C5 O3 19.2(4) 2_656
Zn1 O4 C5 C4 -159.44(17) 2_656
C6 C4 C5 O3 168.4(2) .
C3 C4 C5 O3 -13.1(4) .
C6 C4 C5 O4 -12.9(4) .
C3 C4 C5 O4 165.5(2) .
C3 C4 C6 C7 0.7(4) .
C5 C4 C6 C7 179.2(2) .
C4 C6 C7 C8 -1.0(4) .
C4 C6 C7 N1 -178.3(2) .
C10 N1 C7 C6 -174.7(3) .
C9 N1 C7 C6 8.0(4) .
C10 N1 C7 C8 8.0(4) .
C9 N1 C7 C8 -169.3(2) .
C3 C2 C8 C7 1.0(4) .
C1 C2 C8 C7 -179.6(2) .
C6 C7 C8 C2 0.1(4) .
N1 C7 C8 C2 177.4(2) .
C10 N1 C9 C12 -4.4(3) .
C7 N1 C9 C12 173.4(2) .
C7 N1 C10 O5 4.0(5) .
C9 N1 C10 O5 -178.4(3) .
C7 N1 C10 C11 -174.7(2) .
C9 N1 C10 C11 2.8(3) .
O5 C10 C11 C12 -178.7(3) .
N1 C10 C11 C12 0.1(3) .
O5 C10 C11 C16 -1.5(5) .
N1 C10 C11 C16 177.3(3) .
C16 C11 C12 C13 -1.4(4) .
C10 C11 C12 C13 176.1(3) .
C16 C11 C12 C9 179.7(3) .
C10 C11 C12 C9 -2.9(3) .
N1 C9 C12 C11 4.3(3) .
N1 C9 C12 C13 -174.5(3) .
C11 C12 C13 C14 -0.5(4) .
C9 C12 C13 C14 178.2(3) .
C12 C13 C14 C15 1.5(5) .
C13 C14 C15 C16 -0.6(5) .
C14 C15 C16 C11 -1.2(5) .
C12 C11 C16 C15 2.2(4) .
C10 C11 C16 C15 -174.7(3) .
C21 N2 C17 C18 -1.8(4) .
Zn1 N2 C17 C18 171.8(2) .
N2 C17 C18 C19 0.2(5) .
C17 C18 C19 C20 1.0(5) .
C18 C19 C20 C21 -0.6(5) .
C17 N2 C21 C20 2.3(4) .
Zn1 N2 C21 C20 -172.0(2) .
C17 N2 C21 C22 -177.9(3) .
Zn1 N2 C21 C22 7.9(3) .
C19 C20 C21 N2 -1.1(5) .
C19 C20 C21 C22 179.0(3) .
C26 N3 C22 C23 1.1(4) .
Zn1 N3 C22 C23 -176.7(2) .
C26 N3 C22 C21 178.4(3) .
Zn1 N3 C22 C21 0.6(3) .
N2 C21 C22 N3 -5.8(4) .
C20 C21 C22 N3 174.1(3) .
N2 C21 C22 C23 171.5(3) .
C20 C21 C22 C23 -8.6(5) .
N3 C22 C23 C24 0.2(5) .
C21 C22 C23 C24 -177.0(3) .
C22 C23 C24 C25 -1.2(6) .
C23 C24 C25 C26 0.9(6) .
C22 N3 C26 C25 -1.4(5) .
Zn1 N3 C26 C25 176.3(2) .
C24 C25 C26 N3 0.4(5) .
