#------------------------------------------------------------------------------
#$Date: 2016-03-05 11:09:51 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177757 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/41/7224105.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224105
loop_
_publ_author_name
'Ma, De-Yun'
'Qin, Liang'
'Lei, Jia-Mei'
'Liang, Yun-Qiu'
'Lin, Wei-Jie'
'Yan, Jing-Jing'
'Ding, Wan-Qiu'
'Guo, Hai-Fu'
'Ling, Yun'
_publ_section_title
;
 Structural diversity of a series of coordination polymers built from
 5-substituted isophthalic acid with or without a methyl-functionalized
 N-donor ligand
;
_journal_issue                   8
_journal_name_full               CrystEngComm
_journal_page_first              1363
_journal_paper_doi               10.1039/C5CE02314A
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C64 H24 N8 O62 Zn13'
_chemical_formula_sum            'C64 H24 N8 O62 Zn13'
_chemical_formula_weight         2746.72
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-07-29 deposited with the CCDC.
2016-01-05 downloaded from the CCDC.
;
_cell_angle_alpha                110.255(9)
_cell_angle_beta                 99.167(11)
_cell_angle_gamma                106.390(9)
_cell_formula_units_Z            1
_cell_length_a                   12.882(5)
_cell_length_b                   14.292(6)
_cell_length_c                   16.936(8)
_cell_measurement_reflns_used    496
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      20.99
_cell_measurement_theta_min      1.51
_cell_volume                     2690(2)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2008)'
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Smart Apex Duo CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0633
_diffrn_reflns_av_sigmaI/netI    0.1261
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16833
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.34
_exptl_absorpt_coefficient_mu    2.941
_exptl_absorpt_correction_T_max  0.7132
_exptl_absorpt_correction_T_min  0.5308
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.696
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1350
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         6.564
_refine_diff_density_min         -3.570
_refine_diff_density_rms         0.360
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.470
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     664
_refine_ls_number_reflns         9393
_refine_ls_number_restraints     444
_refine_ls_restrained_S_all      1.505
_refine_ls_R_factor_all          0.2034
_refine_ls_R_factor_gt           0.1636
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.4142
_refine_ls_wR_factor_ref         0.4428
_reflns_number_gt                5550
_reflns_number_total             9393
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce02314a2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7224103--7224111.cif.'
_cod_original_sg_symbol_Hall     'C 2c 2'
_cod_original_sg_symbol_H-M      'C 2 2 21'
_cod_database_code               7224105
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn -0.5000 1.0000 0.5000 0.0245(6) Uani 1 2 d SU
Zn2 Zn 0.09795(15) 1.03329(15) 0.08876(12) 0.0274(5) Uani 1 1 d U
Zn3 Zn 0.07932(16) 0.88004(16) 0.20435(13) 0.0312(6) Uani 1 1 d U
Zn4 Zn 0.15673(16) 1.20102(16) 0.00543(13) 0.0310(5) Uani 1 1 d U
Zn5 Zn -0.67022(19) 0.9387(2) 0.32178(15) 0.0471(7) Uani 1 1 d U
Zn6 Zn -0.3217(2) 0.8642(2) 0.48409(18) 0.0560(8) Uani 1 1 d U
Zn7 Zn -0.5396(3) 0.7833(3) 0.2866(2) 0.0728(9) Uani 1 1 d U
O1 O -0.0335(11) 0.9468(11) 0.2348(9) 0.044(3) Uani 1 1 d U
O2 O -0.0061(9) 1.0648(9) 0.1727(8) 0.033(3) Uani 1 1 d U
O7 O -0.0094(10) 0.7254(10) 0.1556(8) 0.042(3) Uani 1 1 d U
O12 O 0.0442(16) 0.4199(16) 0.1958(13) 0.085(5) Uani 1 1 d U
O11 O -0.0549(14) 0.2663(15) 0.1147(12) 0.073(5) Uani 1 1 d U
O17 O 0.6448(14) 1.4252(13) 0.5153(11) 0.068(4) Uani 1 1 d U
O18 O 0.5499(14) 1.2655(14) 0.4308(11) 0.069(4) Uani 1 1 d U
O13 O 0.2609(12) 1.3040(11) 0.1221(9) 0.050(3) Uani 1 1 d U
O14 O 0.2335(11) 1.1796(11) 0.1788(9) 0.051(4) Uani 1 1 d U
O9 O -0.3280(15) 0.3238(14) -0.1887(12) 0.073(5) Uani 1 1 d U
O10 O -0.2545(13) 0.2051(13) -0.1874(10) 0.063(4) Uani 1 1 d U
O30 O 0.1550(10) 0.9455(10) 0.1444(8) 0.040(3) Uani 1 1 d U
O29 O 0.0261(8) 1.1071(8) 0.0196(6) 0.020(2) Uani 1 1 d U
O20 O 0.2107(11) 1.0132(10) 0.0113(9) 0.044(3) Uani 1 1 d U
O19 O 0.2450(10) 1.1271(10) -0.0550(8) 0.038(3) Uani 1 1 d U
O8 O -0.1289(11) 0.6921(11) 0.0333(9) 0.046(3) Uani 1 1 d U
O25 O -0.5901(10) 1.0746(10) 0.4445(8) 0.040(3) Uani 1 1 d U
O16 O 0.6091(13) 1.7115(13) 0.4384(11) 0.062(4) Uani 1 1 d U
O3 O -0.3683(9) 1.0579(9) 0.4476(7) 0.031(3) Uani 1 1 d U
O21 O 0.5851(11) 0.9949(11) -0.2563(9) 0.046(3) Uani 1 1 d U
O22 O 0.4884(10) 1.1086(10) -0.2375(8) 0.042(3) Uani 1 1 d U
O24 O 0.3905(15) 0.7472(15) -0.0383(12) 0.077(5) Uani 1 1 d U
O23 O 0.5081(14) 0.7488(14) -0.1148(12) 0.073(5) Uani 1 1 d U
O26 O -0.5904(10) 0.8665(10) 0.3798(8) 0.038(3) Uani 1 1 d U
O28 O -0.6667(7) 0.7178(7) 0.3376(6) 0.0129(19) Uani 1 1 d U
O31 O 0.1766(12) 0.9123(11) 0.3202(9) 0.051(4) Uani 1 1 d U
O27 O -0.1734(18) 0.8918(18) 0.5606(15) 0.104(7) Uani 1 1 d U
O4 O -0.2952(17) 0.9362(17) 0.4077(14) 0.095(6) Uani 1 1 d U
O15 O 0.512(2) 1.678(2) 0.3064(17) 0.117(7) Uani 1 1 d U
C7 C -0.0459(13) 1.0260(13) 0.2225(11) 0.029(4) Uani 1 1 d U
N1 N -0.2155(13) 1.3014(13) 0.3019(11) 0.043(4) Uani 1 1 d U
C5 C -0.1985(14) 1.2047(13) 0.3088(11) 0.031(4) Uani 1 1 d U
C6 C -0.1307(13) 1.1659(13) 0.2668(11) 0.028(4) Uani 1 1 d U
H4 H -0.0909 1.2011 0.2377 0.034 Uiso 1 1 calc R
C1 C -0.1204(13) 1.0714(13) 0.2672(11) 0.026(3) Uani 1 1 d U
C2 C -0.1760(15) 1.0298(15) 0.3182(12) 0.040(4) Uani 1 1 d U
H6 H -0.1676 0.9691 0.3226 0.048 Uiso 1 1 calc R
C3 C -0.2431(15) 1.0739(15) 0.3624(12) 0.039(4) Uani 1 1 d U
C4 C -0.2569(15) 1.1619(15) 0.3570(12) 0.040(4) Uani 1 1 d U
H8 H -0.3037 1.1921 0.3845 0.048 Uiso 1 1 calc R
C9 C -0.1040(14) 0.5472(14) 0.0546(11) 0.034(4) Uani 1 1 d U
C15 C -0.0795(14) 0.6623(14) 0.0844(11) 0.032(4) Uani 1 1 d U
C14 C -0.0513(16) 0.5111(15) 0.1088(13) 0.041(4) Uani 1 1 d U
H11 H -0.0004 0.5579 0.1634 0.050 Uiso 1 1 calc R
C13 C -0.0784(17) 0.4010(17) 0.0775(14) 0.047(5) Uani 1 1 d U
N2 N -0.0218(16) 0.3601(16) 0.1335(13) 0.056(5) Uani 1 1 d U
C12 C -0.1413(16) 0.3292(16) -0.0023(13) 0.042(4) Uani 1 1 d U
H14 H -0.1523 0.2570 -0.0200 0.051 Uiso 1 1 calc R
C11 C -0.1905(15) 0.3669(15) -0.0587(12) 0.038(4) Uani 1 1 d U
C10 C -0.1722(14) 0.4777(14) -0.0270(12) 0.034(4) Uani 1 1 d U
H16 H -0.2077 0.5031 -0.0628 0.041 Uiso 1 1 calc R
C22 C 0.4328(15) 1.3177(15) 0.3180(12) 0.038(4) Uani 1 1 d U
H17 H 0.4079 1.2465 0.3101 0.046 Uiso 1 1 calc R
C21 C 0.5228(14) 1.3950(14) 0.3898(11) 0.032(4) Uani 1 1 d U
C20 C 0.5555(15) 1.5015(15) 0.4083(13) 0.040(4) Uani 1 1 d U
H19 H 0.6128 1.5512 0.4589 0.048 Uiso 1 1 calc R
C19 C 0.5024(17) 1.5361(17) 0.3507(14) 0.050(5) Uani 1 1 d U
C18 C 0.4182(17) 1.4560(17) 0.2731(14) 0.052(5) Uani 1 1 d U
H21 H 0.3879 1.4769 0.2313 0.062 Uiso 1 1 calc R
C17 C 0.3797(16) 1.3498(16) 0.2568(13) 0.044(5) Uani 1 1 d U
N3 N 0.5756(13) 1.3573(13) 0.4491(11) 0.042(4) Uani 1 1 d U
C23 C 0.2815(15) 1.2704(14) 0.1777(12) 0.035(4) Uani 1 1 d U
C16 C -0.2622(17) 0.2929(17) -0.1502(14) 0.049(5) Uani 1 1 d U
C32 C 0.5120(14) 1.0357(14) -0.2270(11) 0.032(4) Uani 1 1 d U
C31 C 0.2570(15) 1.0486(15) -0.0371(12) 0.036(4) Uani 1 1 d U
C25 C 0.3344(13) 1.0002(13) -0.0769(11) 0.028(4) Uani 1 1 d U
C30 C 0.3491(13) 0.9161(13) -0.0621(11) 0.031(4) Uani 1 1 d U
H29 H 0.3114 0.8899 -0.0274 0.037 Uiso 1 1 calc R
C27 C 0.4626(13) 0.9930(13) -0.1669(10) 0.027(3) Uani 1 1 d U
C28 C 0.4793(14) 0.9088(14) -0.1540(11) 0.035(4) Uani 1 1 d U
H31 H 0.5269 0.8779 -0.1796 0.041 Uiso 1 1 calc R
C26 C 0.3905(14) 1.0406(14) -0.1270(11) 0.032(4) Uani 1 1 d U
H32 H 0.3815 1.0994 -0.1349 0.039 Uiso 1 1 calc R
C29 C 0.4221(13) 0.8693(13) -0.1002(11) 0.028(4) Uani 1 1 d U
N4 N 0.4402(13) 0.7828(12) -0.0838(10) 0.039(4) Uani 1 1 d U
C24 C 0.536(2) 1.651(2) 0.3713(18) 0.069(7) Uani 1 1 d U
C8 C -0.3100(17) 1.0181(17) 0.4076(14) 0.049(5) Uani 1 1 d U
O6 O -0.2672(14) 1.3442(14) 0.3452(12) 0.074(5) Uani 1 1 d U
O5 O -0.1696(16) 1.3413(16) 0.2554(13) 0.089(6) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O25 Zn1 O25 180.000(5) . 2_476
O25 Zn1 O26 83.0(5) . .
O25 Zn1 O26 97.0(5) 2_476 .
O25 Zn1 O26 97.0(5) . 2_476
O25 Zn1 O26 83.0(5) 2_476 2_476
O26 Zn1 O26 180.000(3) . 2_476
O25 Zn1 O3 92.5(5) . 2_476
O25 Zn1 O3 87.5(5) 2_476 2_476
O26 Zn1 O3 87.7(5) . 2_476
O26 Zn1 O3 92.3(4) 2_476 2_476
O25 Zn1 O3 87.5(5) . .
O25 Zn1 O3 92.5(5) 2_476 .
O26 Zn1 O3 92.3(4) . .
O26 Zn1 O3 87.7(5) 2_476 .
O3 Zn1 O3 180.000(2) 2_476 .
O25 Zn1 Zn5 43.1(3) . .
O25 Zn1 Zn5 136.9(3) 2_476 .
O26 Zn1 Zn5 40.0(3) . .
O26 Zn1 Zn5 140.0(3) 2_476 .
O3 Zn1 Zn5 92.3(3) 2_476 .
O3 Zn1 Zn5 87.7(3) . .
O25 Zn1 Zn5 136.9(3) . 2_476
O25 Zn1 Zn5 43.1(3) 2_476 2_476
O26 Zn1 Zn5 140.0(3) . 2_476
O26 Zn1 Zn5 40.0(3) 2_476 2_476
O3 Zn1 Zn5 87.7(3) 2_476 2_476
O3 Zn1 Zn5 92.3(3) . 2_476
Zn5 Zn1 Zn5 180.000(1) . 2_476
O30 Zn2 O29 173.4(4) . .
O30 Zn2 O20 87.0(5) . .
O29 Zn2 O20 92.3(5) . .
O30 Zn2 O2 93.6(5) . .
O29 Zn2 O2 87.6(4) . .
O20 Zn2 O2 175.8(5) . .
O30 Zn2 O14 92.4(5) . .
O29 Zn2 O14 94.2(5) . .
O20 Zn2 O14 85.8(5) . .
O2 Zn2 O14 90.0(5) . .
O30 Zn2 O29 92.9(5) . 2_575
O29 Zn2 O29 80.5(4) . 2_575
O20 Zn2 O29 85.6(4) . 2_575
O2 Zn2 O29 98.5(4) . 2_575
O14 Zn2 O29 169.7(5) . 2_575
O30 Zn2 Zn4 146.6(4) . .
O29 Zn2 Zn4 36.8(3) . .
O20 Zn2 Zn4 65.5(4) . .
O2 Zn2 Zn4 112.4(3) . .
O14 Zn2 Zn4 68.2(4) . .
O29 Zn2 Zn4 102.9(3) 2_575 .
O30 Zn3 O7 123.9(5) . .
O30 Zn3 O31 112.5(6) . .
O7 Zn3 O31 104.7(6) . .
O30 Zn3 O1 107.2(6) . .
O7 Zn3 O1 103.3(5) . .
O31 Zn3 O1 103.2(6) . .
O19 Zn4 O29 113.8(5) . .
O19 Zn4 O8 114.7(6) . 2_575
O29 Zn4 O8 115.1(5) . 2_575
O19 Zn4 O13 105.4(5) . .
O29 Zn4 O13 109.5(5) . .
O8 Zn4 O13 96.2(6) 2_575 .
O19 Zn4 Zn2 89.5(4) . .
O29 Zn4 Zn2 40.4(3) . .
O8 Zn4 Zn2 153.5(4) 2_575 .
O13 Zn4 Zn2 87.0(4) . .
O31 Zn5 O21 128.7(6) 1_455 2_575
O31 Zn5 O26 116.3(6) 1_455 .
O21 Zn5 O26 113.9(5) 2_575 .
O31 Zn5 O25 99.8(5) 1_455 .
O21 Zn5 O25 94.5(5) 2_575 .
O26 Zn5 O25 84.4(5) . .
O31 Zn5 O10 83.8(6) 1_455 2_465
O21 Zn5 O10 82.5(6) 2_575 2_465
O26 Zn5 O10 94.8(5) . 2_465
O25 Zn5 O10 176.3(5) . 2_465
O31 Zn5 Zn7 130.3(4) 1_455 .
O21 Zn5 Zn7 86.4(4) 2_575 .
O26 Zn5 Zn7 37.8(4) . .
O25 Zn5 Zn7 112.7(4) . .
O10 Zn5 Zn7 65.1(4) 2_465 .
O31 Zn5 Zn1 116.8(4) 1_455 .
O21 Zn5 Zn1 106.8(4) 2_575 .
O26 Zn5 Zn1 42.2(3) . .
O25 Zn5 Zn1 42.3(3) . .
O10 Zn5 Zn1 136.5(4) 2_465 .
Zn7 Zn5 Zn1 73.10(8) . .
O16 Zn6 O4 121.4(8) 1_445 .
O16 Zn6 O25 107.7(6) 1_445 2_476
O4 Zn6 O25 107.8(8) . 2_476
O16 Zn6 O27 101.9(8) 1_445 .
O4 Zn6 O27 107.9(9) . .
O25 Zn6 O27 109.7(8) 2_476 .
O15 Zn7 O26 116.0(9) 1_445 .
O15 Zn7 O9 93.6(9) 1_445 2_465
O26 Zn7 O9 109.1(6) . 2_465
O15 Zn7 O22 135.7(9) 1_445 2_575
O26 Zn7 O22 98.8(5) . 2_575
O9 Zn7 O22 100.1(7) 2_465 2_575
O15 Zn7 O28 80.6(8) 1_445 .
O26 Zn7 O28 55.0(4) . .
O9 Zn7 O28 70.9(6) 2_465 .
O22 Zn7 O28 143.6(5) 2_575 .
O15 Zn7 Zn5 153.3(8) 1_445 .
O26 Zn7 Zn5 39.3(4) . .
O9 Zn7 Zn5 88.8(5) 2_465 .
O22 Zn7 Zn5 69.4(4) 2_575 .
O28 Zn7 Zn5 75.0(3) . .
C7 O1 Zn3 127.7(12) . .
C7 O2 Zn2 136.2(11) . .
C15 O7 Zn3 132.6(13) . .
C23 O13 Zn4 118.3(13) . .
C23 O14 Zn2 135.0(13) . .
C16 O9 Zn7 119.2(16) . 2_465
C16 O10 Zn5 138.7(15) . 2_465
Zn3 O30 Zn2 123.5(6) . .
Zn4 O29 Zn2 102.8(4) . .
Zn4 O29 Zn2 122.8(5) . 2_575
Zn2 O29 Zn2 99.5(4) . 2_575
C31 O20 Zn2 142.6(13) . .
C31 O19 Zn4 116.9(11) . .
C15 O8 Zn4 154.1(13) . 2_575
Zn6 O25 Zn1 113.6(6) 2_476 .
Zn6 O25 Zn5 121.1(6) 2_476 .
Zn1 O25 Zn5 94.5(5) . .
C24 O16 Zn6 128.6(18) . 1_665
C8 O3 Zn1 134.2(13) . .
C32 O21 Zn5 116.5(12) . 2_575
C32 O22 Zn7 139.8(12) . 2_575
Zn7 O26 Zn5 102.9(6) . .
Zn7 O26 Zn1 131.4(6) . .
Zn5 O26 Zn1 97.8(5) . .
Zn5 O31 Zn3 112.4(7) 1_655 .
C8 O4 Zn6 131.1(18) . .
C24 O15 Zn7 138(2) . 1_665
O2 C7 O1 126.5(16) . .
O2 C7 C1 117.8(15) . .
O1 C7 C1 115.6(15) . .
O6 N1 O5 120.0(19) . .
O6 N1 C5 119.8(17) . .
O5 N1 C5 120.1(17) . .
C6 C5 C4 125.3(17) . .
C6 C5 N1 118.1(15) . .
C4 C5 N1 116.6(15) . .
C5 C6 C1 118.8(16) . .
C5 C6 H4 120.6 . .
C1 C6 H4 120.6 . .
C2 C1 C6 116.1(15) . .
C2 C1 C7 122.8(16) . .
C6 C1 C7 120.8(15) . .
C3 C2 C1 123.1(19) . .
C3 C2 H6 118.4 . .
C1 C2 H6 118.4 . .
C4 C3 C2 119.6(19) . .
C4 C3 C8 120.0(18) . .
C2 C3 C8 120.0(18) . .
C3 C4 C5 116.8(18) . .
C3 C4 H8 121.6 . .
C5 C4 H8 121.6 . .
C10 C9 C14 120.4(17) . .
C10 C9 C15 120.6(17) . .
C14 C9 C15 118.9(16) . .
O7 C15 O8 123.0(17) . .
O7 C15 C9 119.8(16) . .
O8 C15 C9 117.1(16) . .
C9 C14 C13 116.4(18) . .
C9 C14 H11 121.8 . .
C13 C14 H11 121.8 . .
C12 C13 C14 126(2) . .
C12 C13 N2 115.9(19) . .
C14 C13 N2 117.6(18) . .
O12 N2 O11 123(2) . .
O12 N2 C13 118(2) . .
O11 N2 C13 119(2) . .
C13 C12 C11 117.0(19) . .
C13 C12 H14 121.5 . .
C11 C12 H14 121.5 . .
C12 C11 C10 118.7(17) . .
C12 C11 C16 121.4(18) . .
C10 C11 C16 119.9(18) . .
C9 C10 C11 121.0(18) . .
C9 C10 H16 119.5 . .
C11 C10 H16 119.5 . .
C21 C22 C17 118.7(18) . .
C21 C22 H17 120.6 . .
C17 C22 H17 120.6 . .
C20 C21 C22 122.6(17) . .
C20 C21 N3 120.9(16) . .
C22 C21 N3 116.4(16) . .
C21 C20 C19 119.8(18) . .
C21 C20 H19 120.1 . .
C19 C20 H19 120.1 . .
C20 C19 C18 117(2) . .
C20 C19 C24 120(2) . .
C18 C19 C24 123(2) . .
C17 C18 C19 123(2) . .
C17 C18 H21 118.4 . .
C19 C18 H21 118.4 . .
C18 C17 C22 117.9(19) . .
C18 C17 C23 120.4(19) . .
C22 C17 C23 121.6(18) . .
O18 N3 O17 123.8(19) . .
O18 N3 C21 120.2(17) . .
O17 N3 C21 116.0(17) . .
O13 C23 O14 130.2(18) . .
O13 C23 C17 113.8(17) . .
O14 C23 C17 116.0(17) . .
O10 C16 O9 121(2) . .
O10 C16 C11 121(2) . .
O9 C16 C11 118.1(19) . .
O22 C32 O21 127.7(17) . .
O22 C32 C27 118.2(15) . .
O21 C32 C27 113.8(15) . .
O20 C31 O19 125.3(17) . .
O20 C31 C25 118.5(17) . .
O19 C31 C25 116.2(16) . .
C30 C25 C26 121.0(16) . .
C30 C25 C31 119.2(15) . .
C26 C25 C31 119.9(16) . .
C25 C30 C29 119.4(16) . .
C25 C30 H29 120.3 . .
C29 C30 H29 120.3 . .
C28 C27 C26 120.7(16) . .
C28 C27 C32 122.7(15) . .
C26 C27 C32 116.4(15) . .
C27 C28 C29 118.4(16) . .
C27 C28 H31 120.8 . .
C29 C28 H31 120.8 . .
C25 C26 C27 120.1(16) . .
C25 C26 H32 120.0 . .
C27 C26 H32 120.0 . .
C30 C29 C28 120.4(16) . .
C30 C29 N4 120.0(15) . .
C28 C29 N4 119.6(15) . .
O23 N4 O24 122.5(19) . .
O23 N4 C29 117.3(16) . .
O24 N4 C29 120.2(16) . .
O16 C24 O15 122(3) . .
O16 C24 C19 117(2) . .
O15 C24 C19 117(2) . .
O3 C8 O4 123(2) . .
O3 C8 C3 119.9(19) . .
O4 C8 C3 116(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O25 2.100(13) .
Zn1 O25 2.100(13) 2_476
Zn1 O26 2.107(12) .
Zn1 O26 2.107(12) 2_476
Zn1 O3 2.132(11) 2_476
Zn1 O3 2.132(11) .
Zn1 Zn5 3.109(3) .
Zn1 Zn5 3.109(3) 2_476
Zn2 O30 2.029(13) .
Zn2 O29 2.098(10) .
Zn2 O20 2.121(13) .
Zn2 O2 2.127(12) .
Zn2 O14 2.152(14) .
Zn2 O29 2.158(10) 2_575
Zn2 Zn4 3.157(3) .
Zn3 O30 1.821(13) .
Zn3 O7 1.971(13) .
Zn3 O31 1.974(15) .
Zn3 O1 1.992(13) .
Zn4 O19 1.938(12) .
Zn4 O29 1.940(10) .
Zn4 O8 1.954(14) 2_575
Zn4 O13 1.975(14) .
Zn5 O31 1.895(14) 1_455
Zn5 O21 1.965(14) 2_575
Zn5 O26 2.017(13) .
Zn5 O25 2.132(13) .
Zn5 O10 2.298(16) 2_465
Zn5 Zn7 3.104(4) .
Zn6 O16 1.916(17) 1_445
Zn6 O4 1.93(2) .
Zn6 O25 1.946(13) 2_476
Zn6 O27 1.98(2) .
Zn7 O15 1.91(3) 1_445
Zn7 O26 1.951(12) .
Zn7 O9 1.967(18) 2_465
Zn7 O22 2.000(14) 2_575
Zn7 O28 2.110(9) .
O1 C7 1.27(2) .
O2 C7 1.26(2) .
O7 C15 1.23(2) .
O12 N2 1.12(2) .
O11 N2 1.19(2) .
O17 N3 1.20(2) .
O18 N3 1.17(2) .
O13 C23 1.22(2) .
O14 C23 1.28(2) .
O9 C16 1.25(3) .
O9 Zn7 1.967(18) 2_465
O10 C16 1.23(2) .
O10 Zn5 2.298(16) 2_465
O29 Zn2 2.158(10) 2_575
O20 C31 1.25(2) .
O19 C31 1.30(2) .
O8 C15 1.25(2) .
O8 Zn4 1.954(14) 2_575
O25 Zn6 1.946(13) 2_476
O16 C24 1.20(3) .
O16 Zn6 1.916(16) 1_665
O3 C8 1.22(2) .
O21 C32 1.32(2) .
O21 Zn5 1.965(14) 2_575
O22 C32 1.22(2) .
O22 Zn7 2.000(14) 2_575
O24 N4 1.23(2) .
O23 N4 1.22(2) .
O31 Zn5 1.895(14) 1_655
O4 C8 1.24(3) .
O15 C24 1.31(3) .
O15 Zn7 1.91(3) 1_665
C7 C1 1.47(2) .
N1 O6 1.20(2) .
N1 O5 1.25(2) .
N1 C5 1.50(2) .
C5 C6 1.33(2) .
C5 C4 1.37(3) .
C6 C1 1.40(2) .
C6 H4 0.9300 .
C1 C2 1.39(2) .
C2 C3 1.37(3) .
C2 H6 0.9300 .
C3 C4 1.35(3) .
C3 C8 1.49(3) .
C4 H8 0.9300 .
C9 C10 1.36(2) .
C9 C14 1.38(3) .
C9 C15 1.46(2) .
C14 C13 1.39(3) .
C14 H11 0.9300 .
C13 C12 1.33(3) .
C13 N2 1.48(3) .
C12 C11 1.40(3) .
C12 H14 0.9300 .
C11 C10 1.42(3) .
C11 C16 1.49(3) .
C10 H16 0.9300 .
C22 C21 1.39(2) .
C22 C17 1.43(3) .
C22 H17 0.9300 .
C21 C20 1.36(3) .
C21 N3 1.46(2) .
C20 C19 1.41(3) .
C20 H19 0.9300 .
C19 C18 1.42(3) .
C19 C24 1.47(3) .
C18 C17 1.37(3) .
C18 H21 0.9300 .
C17 C23 1.51(3) .
C32 C27 1.49(2) .
C31 C25 1.49(2) .
C25 C30 1.36(2) .
C25 C26 1.37(2) .
C30 C29 1.41(2) .
C30 H29 0.9300 .
C27 C28 1.36(2) .
C27 C26 1.42(2) .
C28 C29 1.42(2) .
C28 H31 0.9300 .
C26 H32 0.9300 .
C29 N4 1.43(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O30 Zn2 Zn4 O19 40.9(7) . .
O29 Zn2 Zn4 O19 -129.3(6) . .
O20 Zn2 Zn4 O19 3.6(5) . .
O2 Zn2 Zn4 O19 179.6(5) . .
O14 Zn2 Zn4 O19 99.1(5) . .
O29 Zn2 Zn4 O19 -75.4(4) 2_575 .
O30 Zn2 Zn4 O29 170.2(8) . .
O20 Zn2 Zn4 O29 132.9(6) . .
O2 Zn2 Zn4 O29 -51.1(6) . .
O14 Zn2 Zn4 O29 -131.6(6) . .
O29 Zn2 Zn4 O29 53.9(6) 2_575 .
O30 Zn2 Zn4 O8 -162.5(11) . 2_575
O29 Zn2 Zn4 O8 27.3(10) . 2_575
O20 Zn2 Zn4 O8 160.2(10) . 2_575
O2 Zn2 Zn4 O8 -23.8(9) . 2_575
O14 Zn2 Zn4 O8 -104.3(10) . 2_575
O29 Zn2 Zn4 O8 81.2(9) 2_575 2_575
O30 Zn2 Zn4 O13 -64.6(8) . .
O29 Zn2 Zn4 O13 125.2(6) . .
O20 Zn2 Zn4 O13 -101.9(6) . .
O2 Zn2 Zn4 O13 74.1(5) . .
O14 Zn2 Zn4 O13 -6.4(6) . .
O29 Zn2 Zn4 O13 179.1(5) 2_575 .
O25 Zn1 Zn5 O31 -74.3(7) . 1_455
O25 Zn1 Zn5 O31 105.7(7) 2_476 1_455
O26 Zn1 Zn5 O31 100.6(7) . 1_455
O26 Zn1 Zn5 O31 -79.4(7) 2_476 1_455
O3 Zn1 Zn5 O31 16.9(6) 2_476 1_455
O3 Zn1 Zn5 O31 -163.1(6) . 1_455
Zn5 Zn1 Zn5 O31 128(100) 2_476 1_455
O25 Zn1 Zn5 O21 77.9(7) . 2_575
O25 Zn1 Zn5 O21 -102.1(7) 2_476 2_575
O26 Zn1 Zn5 O21 -107.3(7) . 2_575
O26 Zn1 Zn5 O21 72.7(7) 2_476 2_575
O3 Zn1 Zn5 O21 169.0(5) 2_476 2_575
O3 Zn1 Zn5 O21 -11.0(5) . 2_575
Zn5 Zn1 Zn5 O21 -80(100) 2_476 2_575
O25 Zn1 Zn5 O26 -174.8(7) . .
O25 Zn1 Zn5 O26 5.2(7) 2_476 .
O26 Zn1 Zn5 O26 180.000(5) 2_476 .
O3 Zn1 Zn5 O26 -83.6(6) 2_476 .
O3 Zn1 Zn5 O26 96.4(6) . .
Zn5 Zn1 Zn5 O26 27(100) 2_476 .
O25 Zn1 Zn5 O25 180.000(6) 2_476 .
O26 Zn1 Zn5 O25 174.8(7) . .
O26 Zn1 Zn5 O25 -5.2(7) 2_476 .
O3 Zn1 Zn5 O25 91.2(6) 2_476 .
O3 Zn1 Zn5 O25 -88.8(6) . .
Zn5 Zn1 Zn5 O25 -158(100) 2_476 .
O25 Zn1 Zn5 O10 174.8(8) . 2_465
O25 Zn1 Zn5 O10 -5.2(8) 2_476 2_465
O26 Zn1 Zn5 O10 -10.4(8) . 2_465
O26 Zn1 Zn5 O10 169.6(8) 2_476 2_465
O3 Zn1 Zn5 O10 -94.1(7) 2_476 2_465
O3 Zn1 Zn5 O10 85.9(7) . 2_465
Zn5 Zn1 Zn5 O10 17(100) 2_476 2_465
O25 Zn1 Zn5 Zn7 158.6(5) . .
O25 Zn1 Zn5 Zn7 -21.4(5) 2_476 .
O26 Zn1 Zn5 Zn7 -26.5(5) . .
O26 Zn1 Zn5 Zn7 153.5(5) 2_476 .
O3 Zn1 Zn5 Zn7 -110.2(3) 2_476 .
O3 Zn1 Zn5 Zn7 69.8(3) . .
Zn5 Zn1 Zn5 Zn7 1(100) 2_476 .
O31 Zn5 Zn7 O15 -54.5(18) 1_455 1_445
O21 Zn5 Zn7 O15 165.3(17) 2_575 1_445
O26 Zn5 Zn7 O15 27.2(18) . 1_445
O25 Zn5 Zn7 O15 72.0(17) . 1_445
O10 Zn5 Zn7 O15 -111.3(17) 2_465 1_445
Zn1 Zn5 Zn7 O15 56.6(17) . 1_445
O31 Zn5 Zn7 O26 -81.8(8) 1_455 .
O21 Zn5 Zn7 O26 138.1(7) 2_575 .
O25 Zn5 Zn7 O26 44.7(7) . .
O10 Zn5 Zn7 O26 -138.5(7) 2_465 .
Zn1 Zn5 Zn7 O26 29.3(6) . .
O31 Zn5 Zn7 O9 41.1(8) 1_455 2_465
O21 Zn5 Zn7 O9 -99.0(7) 2_575 2_465
O26 Zn5 Zn7 O9 122.9(8) . 2_465
O25 Zn5 Zn7 O9 167.6(7) . 2_465
O10 Zn5 Zn7 O9 -15.6(7) 2_465 2_465
Zn1 Zn5 Zn7 O9 152.2(5) . 2_465
O31 Zn5 Zn7 O22 142.4(7) 1_455 2_575
O21 Zn5 Zn7 O22 2.3(5) 2_575 2_575
O26 Zn5 Zn7 O22 -135.8(7) . 2_575
O25 Zn5 Zn7 O22 -91.1(5) . 2_575
O10 Zn5 Zn7 O22 85.7(6) 2_465 2_575
Zn1 Zn5 Zn7 O22 -106.5(4) . 2_575
O31 Zn5 Zn7 O28 -29.4(6) 1_455 .
O21 Zn5 Zn7 O28 -169.6(5) 2_575 .
O26 Zn5 Zn7 O28 52.4(6) . .
O25 Zn5 Zn7 O28 97.1(5) . .
O10 Zn5 Zn7 O28 -86.2(5) 2_465 .
Zn1 Zn5 Zn7 O28 81.7(3) . .
O30 Zn3 O1 C7 -5.6(16) . .
O7 Zn3 O1 C7 -137.9(14) . .
O31 Zn3 O1 C7 113.3(15) . .
O30 Zn2 O2 C7 -17.0(16) . .
O29 Zn2 O2 C7 156.5(15) . .
O20 Zn2 O2 C7 -115(6) . .
O14 Zn2 O2 C7 -109.3(16) . .
O29 Zn2 O2 C7 76.5(15) 2_575 .
Zn4 Zn2 O2 C7 -175.7(14) . .
O30 Zn3 O7 C15 -46.2(18) . .
O31 Zn3 O7 C15 -176.8(16) . .
O1 Zn3 O7 C15 75.5(17) . .
O19 Zn4 O13 C23 -77.8(15) . .
O29 Zn4 O13 C23 45.0(15) . .
O8 Zn4 O13 C23 164.4(14) 2_575 .
Zn2 Zn4 O13 C23 10.8(14) . .
O30 Zn2 O14 C23 156.9(17) . .
O29 Zn2 O14 C23 -21.9(18) . .
O20 Zn2 O14 C23 70.1(17) . .
O2 Zn2 O14 C23 -109.5(17) . .
O29 Zn2 O14 C23 36(4) 2_575 .
Zn4 Zn2 O14 C23 4.8(16) . .
O7 Zn3 O30 Zn2 102.7(8) . .
O31 Zn3 O30 Zn2 -129.8(7) . .
O1 Zn3 O30 Zn2 -17.1(9) . .
O29 Zn2 O30 Zn3 -77(4) . .
O20 Zn2 O30 Zn3 -161.4(8) . .
O2 Zn2 O30 Zn3 22.8(8) . .
O14 Zn2 O30 Zn3 112.9(8) . .
O29 Zn2 O30 Zn3 -76.0(7) 2_575 .
Zn4 Zn2 O30 Zn3 165.1(3) . .
O19 Zn4 O29 Zn2 57.7(6) . .
O8 Zn4 O29 Zn2 -166.9(5) 2_575 .
O13 Zn4 O29 Zn2 -60.0(6) . .
O19 Zn4 O29 Zn2 -52.6(7) . 2_575
O8 Zn4 O29 Zn2 82.7(7) 2_575 2_575
O13 Zn4 O29 Zn2 -170.3(6) . 2_575
Zn2 Zn4 O29 Zn2 -110.4(7) . 2_575
O30 Zn2 O29 Zn4 -126(4) . .
O20 Zn2 O29 Zn4 -41.8(5) . .
O2 Zn2 O29 Zn4 134.0(5) . .
O14 Zn2 O29 Zn4 44.2(5) . .
O29 Zn2 O29 Zn4 -127.0(6) 2_575 .
O30 Zn2 O29 Zn2 1(4) . 2_575
O20 Zn2 O29 Zn2 85.2(5) . 2_575
O2 Zn2 O29 Zn2 -99.1(4) . 2_575
O14 Zn2 O29 Zn2 171.1(5) . 2_575
O29 Zn2 O29 Zn2 0.0 2_575 2_575
Zn4 Zn2 O29 Zn2 127.0(6) . 2_575
O30 Zn2 O20 C31 -165(2) . .
O29 Zn2 O20 C31 22(2) . .
O2 Zn2 O20 C31 -66(7) . .
O14 Zn2 O20 C31 -72(2) . .
O29 Zn2 O20 C31 102(2) 2_575 .
Zn4 Zn2 O20 C31 -4.1(18) . .
O29 Zn4 O19 C31 -38.5(13) . .
O8 Zn4 O19 C31 -174.0(12) 2_575 .
O13 Zn4 O19 C31 81.6(13) . .
Zn2 Zn4 O19 C31 -5.2(12) . .
O25 Zn1 O25 Zn6 -153(100) 2_476 2_476
O26 Zn1 O25 Zn6 123.5(7) . 2_476
O26 Zn1 O25 Zn6 -56.5(7) 2_476 2_476
O3 Zn1 O25 Zn6 36.1(6) 2_476 2_476
O3 Zn1 O25 Zn6 -143.9(6) . 2_476
Zn5 Zn1 O25 Zn6 126.8(8) . 2_476
Zn5 Zn1 O25 Zn6 -53.2(8) 2_476 2_476
O25 Zn1 O25 Zn5 80(100) 2_476 .
O26 Zn1 O25 Zn5 -3.3(5) . .
O26 Zn1 O25 Zn5 176.7(5) 2_476 .
O3 Zn1 O25 Zn5 -90.7(5) 2_476 .
O3 Zn1 O25 Zn5 89.3(5) . .
Zn5 Zn1 O25 Zn5 180.000(5) 2_476 .
O31 Zn5 O25 Zn6 -1.8(9) 1_455 2_476
O21 Zn5 O25 Zn6 128.8(8) 2_575 2_476
O26 Zn5 O25 Zn6 -117.6(8) . 2_476
O10 Zn5 O25 Zn6 164(8) 2_465 2_476
Zn7 Zn5 O25 Zn6 -143.3(6) . 2_476
Zn1 Zn5 O25 Zn6 -121.1(9) . 2_476
O31 Zn5 O25 Zn1 119.3(6) 1_455 .
O21 Zn5 O25 Zn1 -110.1(5) 2_575 .
O26 Zn5 O25 Zn1 3.5(5) . .
O10 Zn5 O25 Zn1 -74(9) 2_465 .
Zn7 Zn5 O25 Zn1 -22.2(5) . .
O25 Zn1 O3 C8 -134.2(18) . .
O25 Zn1 O3 C8 45.8(18) 2_476 .
O26 Zn1 O3 C8 -51.3(18) . .
O26 Zn1 O3 C8 128.7(18) 2_476 .
O3 Zn1 O3 C8 36(100) 2_476 .
Zn5 Zn1 O3 C8 -91.0(18) . .
Zn5 Zn1 O3 C8 89.0(18) 2_476 .
O15 Zn7 O26 Zn5 -166.8(9) 1_445 .
O9 Zn7 O26 Zn5 -62.7(8) 2_465 .
O22 Zn7 O26 Zn5 41.3(6) 2_575 .
O28 Zn7 O26 Zn5 -111.0(6) . .
O15 Zn7 O26 Zn1 80.4(12) 1_445 .
O9 Zn7 O26 Zn1 -175.5(9) 2_465 .
O22 Zn7 O26 Zn1 -71.5(9) 2_575 .
O28 Zn7 O26 Zn1 136.2(10) . .
Zn5 Zn7 O26 Zn1 -112.8(11) . .
O31 Zn5 O26 Zn7 122.6(6) 1_455 .
O21 Zn5 O26 Zn7 -46.9(7) 2_575 .
O25 Zn5 O26 Zn7 -139.3(6) . .
O10 Zn5 O26 Zn7 37.1(6) 2_465 .
Zn1 Zn5 O26 Zn7 -135.8(8) . .
O31 Zn5 O26 Zn1 -101.7(6) 1_455 .
O21 Zn5 O26 Zn1 88.9(6) 2_575 .
O25 Zn5 O26 Zn1 -3.5(5) . .
O10 Zn5 O26 Zn1 172.8(5) 2_465 .
Zn7 Zn5 O26 Zn1 135.8(8) . .
O25 Zn1 O26 Zn7 118.5(9) . .
O25 Zn1 O26 Zn7 -61.5(9) 2_476 .
O26 Zn1 O26 Zn7 -33(100) 2_476 .
O3 Zn1 O26 Zn7 -148.7(9) 2_476 .
O3 Zn1 O26 Zn7 31.3(9) . .
Zn5 Zn1 O26 Zn7 114.9(11) . .
Zn5 Zn1 O26 Zn7 -65.1(11) 2_476 .
O25 Zn1 O26 Zn5 3.6(5) . .
O25 Zn1 O26 Zn5 -176.4(5) 2_476 .
O26 Zn1 O26 Zn5 -148(100) 2_476 .
O3 Zn1 O26 Zn5 96.3(5) 2_476 .
O3 Zn1 O26 Zn5 -83.7(5) . .
Zn5 Zn1 O26 Zn5 180.000(5) 2_476 .
O30 Zn3 O31 Zn5 -29.5(9) . 1_655
O7 Zn3 O31 Zn5 107.5(7) . 1_655
O1 Zn3 O31 Zn5 -144.7(7) . 1_655
O16 Zn6 O4 C8 136(2) 1_445 .
O25 Zn6 O4 C8 12(2) 2_476 .
O27 Zn6 O4 C8 -107(2) . .
Zn2 O2 C7 O1 -2(3) . .
Zn2 O2 C7 C1 -177.5(11) . .
Zn3 O1 C7 O2 16(3) . .
Zn3 O1 C7 C1 -168.1(11) . .
O6 N1 C5 C6 -173.1(17) . .
O5 N1 C5 C6 2(3) . .
O6 N1 C5 C4 8(3) . .
O5 N1 C5 C4 -176.3(18) . .
C4 C5 C6 C1 3(3) . .
N1 C5 C6 C1 -175.4(14) . .
C5 C6 C1 C2 -5(2) . .
C5 C6 C1 C7 -179.4(15) . .
O2 C7 C1 C2 174.9(16) . .
O1 C7 C1 C2 -1(2) . .
O2 C7 C1 C6 -11(2) . .
O1 C7 C1 C6 172.8(15) . .
C6 C1 C2 C3 4(3) . .
C7 C1 C2 C3 177.9(17) . .
C1 C2 C3 C4 0(3) . .
C1 C2 C3 C8 173.3(17) . .
C2 C3 C4 C5 -2(3) . .
C8 C3 C4 C5 -175.4(17) . .
C6 C5 C4 C3 1(3) . .
N1 C5 C4 C3 179.1(16) . .
Zn3 O7 C15 O8 -17(3) . .
Zn3 O7 C15 C9 159.5(12) . .
Zn4 O8 C15 O7 6(4) 2_575 .
Zn4 O8 C15 C9 -171(2) 2_575 .
C10 C9 C15 O7 -173.5(17) . .
C14 C9 C15 O7 3(3) . .
C10 C9 C15 O8 4(3) . .
C14 C9 C15 O8 179.9(17) . .
C10 C9 C14 C13 -4(3) . .
C15 C9 C14 C13 179.5(16) . .
C9 C14 C13 C12 7(3) . .
C9 C14 C13 N2 179.0(17) . .
C12 C13 N2 O12 169(2) . .
C14 C13 N2 O12 -4(3) . .
C12 C13 N2 O11 -18(3) . .
C14 C13 N2 O11 169.1(19) . .
C14 C13 C12 C11 -4(3) . .
N2 C13 C12 C11 -176.3(17) . .
C13 C12 C11 C10 -1(3) . .
C13 C12 C11 C16 179.5(19) . .
C14 C9 C10 C11 0(3) . .
C15 C9 C10 C11 175.8(16) . .
C12 C11 C10 C9 3(3) . .
C16 C11 C10 C9 -177.4(17) . .
C17 C22 C21 C20 6(3) . .
C17 C22 C21 N3 -178.6(16) . .
C22 C21 C20 C19 -4(3) . .
N3 C21 C20 C19 -179.3(17) . .
C21 C20 C19 C18 -2(3) . .
C21 C20 C19 C24 178.8(19) . .
C20 C19 C18 C17 7(3) . .
C24 C19 C18 C17 -174(2) . .
C19 C18 C17 C22 -5(3) . .
C19 C18 C17 C23 173.4(18) . .
C21 C22 C17 C18 -2(3) . .
C21 C22 C17 C23 -179.8(16) . .
C20 C21 N3 O18 -177.0(18) . .
C22 C21 N3 O18 8(3) . .
C20 C21 N3 O17 3(3) . .
C22 C21 N3 O17 -172.5(17) . .
Zn4 O13 C23 O14 -12(3) . .
Zn4 O13 C23 C17 167.7(11) . .
Zn2 O14 C23 O13 2(3) . .
Zn2 O14 C23 C17 -177.3(12) . .
C18 C17 C23 O13 17(3) . .
C22 C17 C23 O13 -165.1(18) . .
C18 C17 C23 O14 -163.3(18) . .
C22 C17 C23 O14 15(3) . .
Zn5 O10 C16 O9 1(4) 2_465 .
Zn5 O10 C16 C11 -177.5(13) 2_465 .
Zn7 O9 C16 O10 25(3) 2_465 .
Zn7 O9 C16 C11 -157.3(14) 2_465 .
C12 C11 C16 O10 -21(3) . .
C10 C11 C16 O10 159.6(19) . .
C12 C11 C16 O9 160.6(19) . .
C10 C11 C16 O9 -19(3) . .
Zn7 O22 C32 O21 -7(3) 2_575 .
Zn7 O22 C32 C27 166.1(12) 2_575 .
Zn5 O21 C32 O22 2(2) 2_575 .
Zn5 O21 C32 C27 -171.4(10) 2_575 .
Zn2 O20 C31 O19 1(3) . .
Zn2 O20 C31 C25 179.9(12) . .
Zn4 O19 C31 O20 5(2) . .
Zn4 O19 C31 C25 -173.9(11) . .
O20 C31 C25 C30 3(2) . .
O19 C31 C25 C30 -178.7(15) . .
O20 C31 C25 C26 -177.0(16) . .
O19 C31 C25 C26 2(2) . .
C26 C25 C30 C29 -1(3) . .
C31 C25 C30 C29 179.6(15) . .
O22 C32 C27 C28 176.8(16) . .
O21 C32 C27 C28 -9(2) . .
O22 C32 C27 C26 1(2) . .
O21 C32 C27 C26 174.7(14) . .
C26 C27 C28 C29 1(2) . .
C32 C27 C28 C29 -175.6(15) . .
C30 C25 C26 C27 2(3) . .
C31 C25 C26 C27 -178.5(15) . .
C28 C27 C26 C25 -2(2) . .
C32 C27 C26 C25 174.5(15) . .
C25 C30 C29 C28 0(2) . .
C25 C30 C29 N4 178.6(15) . .
C27 C28 C29 C30 1(2) . .
C27 C28 C29 N4 -178.5(15) . .
C30 C29 N4 O23 -176.6(16) . .
C28 C29 N4 O23 2(2) . .
C30 C29 N4 O24 2(3) . .
C28 C29 N4 O24 -179.3(16) . .
Zn6 O16 C24 O15 19(4) 1_665 .
Zn6 O16 C24 C19 177.2(14) 1_665 .
Zn7 O15 C24 O16 -61(4) 1_665 .
Zn7 O15 C24 C19 141(2) 1_665 .
C20 C19 C24 O16 0(3) . .
C18 C19 C24 O16 -179(2) . .
C20 C19 C24 O15 159(2) . .
C18 C19 C24 O15 -20(4) . .
Zn1 O3 C8 O4 -20(3) . .
Zn1 O3 C8 C3 165.8(12) . .
Zn6 O4 C8 O3 -16(4) . .
Zn6 O4 C8 C3 157.9(15) . .
C4 C3 C8 O3 -8(3) . .
C2 C3 C8 O3 179.1(18) . .
C4 C3 C8 O4 178(2) . .
C2 C3 C8 O4 5(3) . .
