#------------------------------------------------------------------------------
#$Date: 2016-05-06 03:47:53 +0300 (Fri, 06 May 2016) $
#$Revision: 182639 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/45/7224534.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224534
loop_
_publ_author_name
'Zhu, Yu'
'Fang, Wei-Hui'
'Wei, Qi'
'Yang, Guo-Yu'
_publ_section_title
;
 Extended hybrid architectures based on tetra-CoIIsandwiched
 polyoxotungstates
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              2712
_journal_paper_doi               10.1039/C6CE00374E
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C10 H80 Co6 N10 O84 Si2 W18'
_chemical_formula_weight         5403.72
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-02-20 deposited with the CCDC.
2016-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                102.457(3)
_cell_angle_beta                 96.489(3)
_cell_angle_gamma                113.464(3)
_cell_formula_units_Z            1
_cell_length_a                   11.9641(3)
_cell_length_b                   12.0257(4)
_cell_length_c                   16.0944(5)
_cell_measurement_reflns_used    10549
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.2010
_cell_measurement_theta_min      2.8010
_cell_volume                     2022.34(13)
_computing_cell_refinement
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_data_collection
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_data_reduction
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0912
_diffrn_reflns_av_sigmaI/netI    0.0889
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            14843
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.36
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    26.829
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.49154
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrysAlisPro, Agilent Technologies'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    4.437
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2403
_exptl_crystal_size_max          0.2000
_exptl_crystal_size_mid          0.1500
_exptl_crystal_size_min          0.1500
_refine_diff_density_max         2.909
_refine_diff_density_min         -4.297
_refine_diff_density_rms         0.576
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     536
_refine_ls_number_reflns         7114
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0513
_refine_ls_R_factor_gt           0.0454
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0407P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0955
_refine_ls_wR_factor_ref         0.0998
_reflns_number_gt                6238
_reflns_number_total             7114
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce00374e2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7224532--7224534.cif.'
_cod_original_cell_volume        2022.34(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7224534
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.37971(4) 0.54401(5) 0.15607(3) 0.01036(13) Uani 1 1 d .
W2 W 0.11834(4) 0.69080(5) 0.33217(3) 0.00960(13) Uani 1 1 d .
W3 W 0.30783(4) 0.51825(5) 0.35327(3) 0.01015(13) Uani 1 1 d .
W4 W 0.52204(4) 0.86429(5) 0.12351(3) 0.01012(13) Uani 1 1 d .
W5 W 0.57464(4) 1.12123(5) 0.28987(3) 0.00867(13) Uani 1 1 d .
W6 W 0.60797(4) 0.64608(5) 0.33983(3) 0.00927(13) Uani 1 1 d .
W7 W 0.18667(4) 0.71889(5) 0.13444(3) 0.01050(13) Uani 1 1 d .
W8 W 0.24433(4) 0.97593(5) 0.30308(3) 0.00839(13) Uani 1 1 d .
W9 W 0.74781(4) 0.96220(5) 0.30753(3) 0.00943(13) Uani 1 1 d .
Co1 Co 0.35782(14) 0.93753(15) 0.50502(10) 0.0091(4) Uani 1 1 d .
Co2 Co 0.52050(14) 0.79152(16) 0.51818(11) 0.0099(4) Uani 1 1 d .
Co3 Co -0.21022(15) 0.45319(16) 0.31026(11) 0.0127(4) Uani 1 1 d .
Si1 Si 0.4376(3) 0.8245(3) 0.3279(2) 0.0060(7) Uiso 1 1 d .
O1 O 0.2488(7) 0.5966(8) 0.1372(5) 0.0109(18) Uiso 1 1 d .
O2 O 0.2969(7) 0.8103(7) 0.2898(5) 0.0082(17) Uani 1 1 d U
O3 O 0.4365(7) 0.6837(8) 0.3034(5) 0.0097(18) Uani 1 1 d .
O4 O 0.5475(7) 1.0359(8) 0.1606(5) 0.0112(18) Uiso 1 1 d .
O5 O 0.4779(7) 0.8874(8) 0.4328(5) 0.0093(18) Uani 1 1 d .
O6 O 0.3470(7) 0.8206(8) 0.1123(5) 0.0091(17) Uiso 1 1 d .
O7 O 0.3454(8) 0.4290(8) 0.0595(6) 0.019(2) Uani 1 1 d .
O8 O 0.0935(8) 0.6645(9) 0.0330(5) 0.019(2) Uani 1 1 d .
O9 O 0.6957(7) 0.7872(8) 0.2961(5) 0.015(2) Uani 1 1 d .
O10 O 0.7411(7) 1.0008(8) 0.4181(5) 0.0142(19) Uani 1 1 d .
O11 O 0.9053(7) 1.0126(8) 0.3099(5) 0.0132(19) Uani 1 1 d .
O12 O 0.7330(7) 1.1171(8) 0.2962(5) 0.0134(19) Uiso 1 1 d .
O13 O 0.5351(7) 0.9123(8) 0.2790(5) 0.0124(18) Uiso 1 1 d .
O14 O -0.0337(7) 0.6045(8) 0.3423(6) 0.017(2) Uani 1 1 d .
O15 O 0.3275(7) 1.0305(8) 0.4159(6) 0.0136(19) Uani 1 1 d .
O16 O 0.0779(7) 0.6458(8) 0.1992(5) 0.0090(17) Uiso 1 1 d .
O17 O 0.1782(7) 0.8752(8) 0.1754(5) 0.0121(19) Uani 1 1 d .
O18 O 0.4822(8) 0.6962(8) 0.1290(6) 0.017(2) Uani 1 1 d .
O19 O 0.3972(7) 1.0551(8) 0.2648(6) 0.017(2) Uani 1 1 d .
O20 O 0.4674(7) 0.5097(8) 0.3583(6) 0.015(2) Uani 1 1 d .
O21 O 0.7175(7) 0.5857(9) 0.3486(6) 0.017(2) Uani 1 1 d .
O22 O 0.5310(7) 0.5496(8) 0.2106(5) 0.0146(19) Uani 1 1 d .
O23 O 0.1057(7) 0.8460(8) 0.3220(5) 0.0126(19) Uani 1 1 d .
O24 O 0.6888(7) 0.9104(8) 0.1754(5) 0.0100(18) Uiso 1 1 d .
O25 O 0.1802(7) 0.5664(8) 0.3159(5) 0.0136(19) Uani 1 1 d .
O26 O 0.1836(8) 1.0844(9) 0.2989(6) 0.018(2) Uani 1 1 d .
O27 O 0.2232(8) 0.3755(8) 0.3708(6) 0.017(2) Uiso 1 1 d .
O28 O 0.2889(7) 0.4470(8) 0.2230(5) 0.0140(19) Uani 1 1 d .
O29 O 0.6351(7) 0.7468(8) 0.4453(5) 0.015(2) Uani 1 1 d .
O30 O 0.5848(7) 1.1408(8) 0.4043(5) 0.0123(19) Uani 1 1 d .
O31 O 0.2020(7) 0.7700(9) 0.4395(6) 0.015(2) Uani 1 1 d .
O32 O 0.3623(7) 0.6285(8) 0.4586(5) 0.0123(19) Uani 1 1 d .
O33 O 0.6204(7) 1.2740(8) 0.2830(6) 0.0140(19) Uani 1 1 d .
O34 O 0.5315(8) 0.8507(9) 0.0164(6) 0.019(2) Uani 1 1 d .
N1 N -0.2870(12) 0.4329(12) 0.1777(7) 0.031(3) Uani 1 1 d .
H1A H -0.3657 0.3846 0.1587 0.037 Uiso 1 1 d R
N2 N -0.2792(9) 0.6699(11) 0.1213(7) 0.017(2) Uiso 1 1 d .
H2A H -0.3535 0.6116 0.0975 0.020 Uiso 1 1 d R
H2B H -0.2648 0.7482 0.1322 0.020 Uiso 1 1 d R
N3 N 0.1149(10) 0.1893(11) 0.1714(8) 0.023(3) Uani 1 1 d .
H3A H 0.1643 0.2270 0.2221 0.028 Uiso 1 1 d R
H3B H 0.0390 0.1797 0.1642 0.028 Uiso 1 1 d R
N4 N 0.3108(11) 0.0501(12) 0.0912(8) 0.028(3) Uani 1 1 d .
H4A H 0.2467 -0.0189 0.0623 0.033 Uiso 1 1 d R
H4B H 0.3832 0.0506 0.1016 0.033 Uiso 1 1 d R
N5 N 0.1001(11) 0.1427(14) 0.4668(8) 0.040(3) Uani 1 1 d .
H5A H 0.1258 0.1037 0.4279 0.047 Uiso 1 1 calc R
H5B H 0.1243 0.2229 0.4771 0.047 Uiso 1 1 calc R
C1 C -0.2238(16) 0.4900(17) 0.1180(10) 0.038(4) Uani 1 1 d .
H1C H -0.2789 0.4521 0.0605 0.045 Uiso 1 1 calc R
H1D H -0.1517 0.4724 0.1150 0.045 Uiso 1 1 calc R
C2 C -0.1791(12) 0.6366(16) 0.1431(10) 0.034(4) Uani 1 1 d .
H2C H -0.1435 0.6721 0.2053 0.041 Uiso 1 1 calc R
H2D H -0.1141 0.6732 0.1129 0.041 Uiso 1 1 calc R
C3 C 0.1603(17) 0.140(2) 0.0965(12) 0.056(6) Uani 1 1 d .
H3C H 0.1505 0.1790 0.0509 0.067 Uiso 1 1 calc R
H3D H 0.1101 0.0497 0.0732 0.067 Uiso 1 1 calc R
C4 C 0.2967(13) 0.1678(16) 0.1231(11) 0.035(4) Uani 1 1 d .
H4C H 0.3477 0.2321 0.0983 0.042 Uiso 1 1 calc R
H4D H 0.3244 0.1993 0.1862 0.042 Uiso 1 1 calc R
C5 C 0.0152(13) 0.0726(15) 0.5155(9) 0.027(4) Uani 1 1 d .
H5C H -0.0617 0.0821 0.5061 0.033 Uiso 1 1 calc R
H5D H 0.0533 0.1067 0.5774 0.033 Uiso 1 1 calc R
O1W O -0.1135(8) 0.3399(9) 0.2797(7) 0.025(2) Uani 1 1 d .
O2W O -0.1819(8) 0.4451(9) 0.4373(6) 0.023(2) Uani 1 1 d .
O3W O 0.5714(8) 0.7074(8) 0.6062(6) 0.019(2) Uani 1 1 d .
O4W O 0.0006(9) 0.6767(11) 0.5436(7) 0.037(3) Uani 1 1 d .
O5W O 0.9507(11) 0.9026(12) 0.1491(8) 0.050(3) Uani 1 1 d .
O6W O 0.8563(9) 0.0672(10) 0.0907(7) 0.034(3) Uani 1 1 d .
O7W O 0.0121(8) 0.3651(9) 0.1455(6) 0.021(2) Uani 1 1 d .
O8W O 0.7104(9) 0.1888(10) 0.0783(6) 0.029(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 W1 O28 101.0(4) . .
O7 W1 O22 99.7(4) . .
O28 W1 O22 92.2(4) . .
O7 W1 O1 101.9(4) . .
O28 W1 O1 88.2(4) . .
O22 W1 O1 157.9(4) . .
O7 W1 O18 102.2(4) . .
O28 W1 O18 156.7(4) . .
O22 W1 O18 86.3(4) . .
O1 W1 O18 84.7(3) . .
O7 W1 O3 170.7(3) . .
O28 W1 O3 73.2(3) . .
O22 W1 O3 73.7(3) . .
O1 W1 O3 85.3(3) . .
O18 W1 O3 84.1(3) . .
O31 W2 O14 104.0(4) . .
O31 W2 O25 95.6(4) . .
O14 W2 O25 101.9(4) . .
O31 W2 O23 89.3(4) . .
O14 W2 O23 98.9(4) . .
O25 W2 O23 156.7(3) . .
O31 W2 O16 159.1(4) . .
O14 W2 O16 96.3(4) . .
O25 W2 O16 85.2(3) . .
O23 W2 O16 82.3(3) . .
O31 W2 O2 87.0(3) . .
O14 W2 O2 166.6(3) . .
O25 W2 O2 84.3(3) . .
O23 W2 O2 73.2(3) . .
O16 W2 O2 72.2(3) . .
O27 W3 O32 104.4(4) . .
O27 W3 O25 102.4(4) . .
O32 W3 O25 95.0(4) . .
O27 W3 O20 98.4(4) . .
O32 W3 O20 91.5(4) . .
O25 W3 O20 155.9(4) . .
O27 W3 O28 95.7(4) . .
O32 W3 O28 159.5(4) . .
O25 W3 O28 83.9(3) . .
O20 W3 O28 82.0(3) . .
O27 W3 O3 166.1(3) . .
O32 W3 O3 87.0(3) . .
O25 W3 O3 84.1(3) . .
O20 W3 O3 73.1(3) . .
O28 W3 O3 72.6(3) . .
O34 W4 O24 100.5(4) . .
O34 W4 O4 99.9(4) . .
O24 W4 O4 91.0(3) . .
O34 W4 O18 101.6(4) . .
O24 W4 O18 88.5(4) . .
O4 W4 O18 158.2(4) . .
O34 W4 O6 99.7(4) . .
O24 W4 O6 159.8(3) . .
O4 W4 O6 86.1(3) . .
O18 W4 O6 86.9(4) . .
O34 W4 O13 171.7(4) . .
O24 W4 O13 74.1(3) . .
O4 W4 O13 74.3(3) . .
O18 W4 O13 84.7(3) . .
O6 W4 O13 85.9(3) . .
O33 W5 O30 102.7(4) . .
O33 W5 O19 102.5(4) . .
O30 W5 O19 92.8(4) . .
O33 W5 O12 98.1(4) . .
O30 W5 O12 92.5(4) . .
O19 W5 O12 157.0(4) . .
O33 W5 O4 97.3(4) . .
O30 W5 O4 160.0(4) . .
O19 W5 O4 83.9(3) . .
O12 W5 O4 83.5(3) . .
O33 W5 O13 169.0(3) . .
O30 W5 O13 85.8(3) . .
O19 W5 O13 83.7(3) . .
O12 W5 O13 74.4(3) . .
O4 W5 O13 74.2(3) . .
O21 W6 O29 104.7(4) . .
O21 W6 O20 98.9(4) . .
O29 W6 O20 92.8(4) . .
O21 W6 O9 100.5(4) . .
O29 W6 O9 92.3(4) . .
O20 W6 O9 157.9(3) . .
O21 W6 O22 94.6(4) . .
O29 W6 O22 160.7(3) . .
O20 W6 O22 83.8(4) . .
O9 W6 O22 84.3(3) . .
O21 W6 O3 167.0(4) . .
O29 W6 O3 86.9(3) . .
O20 W6 O3 74.2(3) . .
O9 W6 O3 84.7(3) . .
O22 W6 O3 73.9(3) . .
O8 W7 O16 102.6(4) . .
O8 W7 O1 103.8(4) . .
O16 W7 O1 87.9(3) . .
O8 W7 O17 100.1(4) . .
O16 W7 O17 91.4(4) . .
O1 W7 O17 155.7(3) . .
O8 W7 O6 100.9(4) . .
O16 W7 O6 156.5(3) . .
O1 W7 O6 85.8(3) . .
O17 W7 O6 85.2(3) . .
O8 W7 O2 170.5(3) . .
O16 W7 O2 72.0(3) . .
O1 W7 O2 84.1(3) . .
O17 W7 O2 72.7(3) . .
O6 W7 O2 84.8(3) . .
O26 W8 O15 102.1(4) . .
O26 W8 O23 99.5(4) . .
O15 W8 O23 93.3(4) . .
O26 W8 O19 99.7(4) . .
O15 W8 O19 91.9(4) . .
O23 W8 O19 158.5(4) . .
O26 W8 O17 96.9(4) . .
O15 W8 O17 160.9(3) . .
O23 W8 O17 85.2(4) . .
O19 W8 O17 83.0(3) . .
O26 W8 O2 170.5(4) . .
O15 W8 O2 86.4(3) . .
O23 W8 O2 75.5(3) . .
O19 W8 O2 84.0(3) . .
O17 W8 O2 74.8(3) . .
O11 W9 O10 104.2(4) . .
O11 W9 O9 101.3(4) . .
O10 W9 O9 94.4(4) . .
O11 W9 O12 98.7(4) . .
O10 W9 O12 90.3(4) . .
O9 W9 O12 157.6(3) . .
O11 W9 O24 96.7(3) . .
O10 W9 O24 158.4(3) . .
O9 W9 O24 86.4(3) . .
O12 W9 O24 81.4(3) . .
O11 W9 O13 167.6(3) . .
O10 W9 O13 85.2(3) . .
O9 W9 O13 85.7(3) . .
O12 W9 O13 72.9(3) . .
O24 W9 O13 73.4(3) . .
O10 Co1 O31 92.2(3) 2_676 .
O10 Co1 O15 91.3(3) 2_676 .
O31 Co1 O15 93.2(3) . .
O10 Co1 O30 93.2(3) 2_676 2_676
O31 Co1 O30 93.4(3) . 2_676
O15 Co1 O30 171.9(3) . 2_676
O10 Co1 O5 174.4(3) 2_676 .
O31 Co1 O5 93.2(3) . .
O15 Co1 O5 89.7(3) . .
O30 Co1 O5 85.3(3) 2_676 .
O10 Co1 O5 89.7(3) 2_676 2_676
O31 Co1 O5 177.3(3) . 2_676
O15 Co1 O5 84.8(3) . 2_676
O30 Co1 O5 88.4(3) 2_676 2_676
O5 Co1 O5 84.9(3) . 2_676
O32 Co2 O29 96.3(3) . .
O32 Co2 O3W 90.8(3) . .
O29 Co2 O3W 87.7(3) . .
O32 Co2 O5 92.6(3) . .
O29 Co2 O5 92.2(3) . .
O3W Co2 O5 176.6(3) . .
O32 Co2 O15 174.1(3) . 2_676
O29 Co2 O15 89.2(3) . 2_676
O3W Co2 O15 91.6(3) . 2_676
O5 Co2 O15 85.0(3) . 2_676
O32 Co2 O30 89.4(3) . 2_676
O29 Co2 O30 173.7(4) . 2_676
O3W Co2 O30 95.0(3) . 2_676
O5 Co2 O30 84.7(3) . 2_676
O15 Co2 O30 85.0(3) 2_676 2_676
O2W Co3 O14 88.3(4) . .
O2W Co3 O21 89.3(4) . 1_455
O14 Co3 O21 87.9(3) . 1_455
O2W Co3 O1W 88.8(4) . .
O14 Co3 O1W 84.7(3) . .
O21 Co3 O1W 172.4(4) 1_455 .
O2W Co3 N1 165.8(4) . .
O14 Co3 N1 105.4(4) . .
O21 Co3 N1 87.3(4) 1_455 .
O1W Co3 N1 96.2(4) . .
O2W Co3 O33 86.7(4) . 1_445
O14 Co3 O33 169.9(3) . 1_445
O21 Co3 O33 100.8(3) 1_455 1_445
O1W Co3 O33 86.5(3) . 1_445
N1 Co3 O33 80.4(4) . 1_445
O5 Si1 O13 111.1(4) . .
O5 Si1 O3 110.1(4) . .
O13 Si1 O3 108.4(4) . .
O5 Si1 O2 110.1(4) . .
O13 Si1 O2 107.9(4) . .
O3 Si1 O2 109.3(4) . .
W7 O1 W1 153.8(5) . .
Si1 O2 W8 124.6(4) . .
Si1 O2 W2 123.7(4) . .
W8 O2 W2 91.8(3) . .
Si1 O2 W7 124.4(4) . .
W8 O2 W7 91.5(3) . .
W2 O2 W7 91.1(3) . .
Si1 O3 W6 124.5(4) . .
Si1 O3 W3 122.6(4) . .
W6 O3 W3 92.1(3) . .
Si1 O3 W1 124.6(4) . .
W6 O3 W1 92.0(3) . .
W3 O3 W1 91.6(3) . .
W4 O4 W5 119.5(4) . .
Si1 O5 Co2 121.4(5) . .
Si1 O5 Co1 122.3(4) . .
Co2 O5 Co1 94.4(3) . .
Si1 O5 Co1 122.4(5) . 2_676
Co2 O5 Co1 93.9(3) . 2_676
Co1 O5 Co1 95.1(3) . 2_676
W4 O6 W7 149.3(4) . .
W9 O9 W6 146.8(5) . .
W9 O10 Co1 139.8(4) . 2_676
W5 O12 W9 119.4(4) . .
Si1 O13 W5 123.6(4) . .
Si1 O13 W9 122.5(4) . .
W5 O13 W9 92.3(3) . .
Si1 O13 W4 125.5(4) . .
W5 O13 W4 91.9(3) . .
W9 O13 W4 91.6(3) . .
W2 O14 Co3 156.8(5) . .
W8 O15 Co1 133.2(5) . .
W8 O15 Co2 127.5(5) . 2_676
Co1 O15 Co2 95.9(3) . 2_676
W7 O16 W2 124.5(4) . .
W7 O17 W8 120.7(4) . .
W4 O18 W1 151.9(5) . .
W5 O19 W8 147.1(5) . .
W6 O20 W3 119.5(4) . .
W6 O21 Co3 154.4(5) . 1_655
W1 O22 W6 120.1(4) . .
W8 O23 W2 118.7(4) . .
W4 O24 W9 120.9(4) . .
W2 O25 W3 147.6(5) . .
W1 O28 W3 122.5(4) . .
W6 O29 Co2 133.6(4) . .
W5 O30 Co1 135.5(5) . 2_676
W5 O30 Co2 126.6(4) . 2_676
Co1 O30 Co2 95.1(3) 2_676 2_676
W2 O31 Co1 137.1(5) . .
W3 O32 Co2 134.2(5) . .
W5 O33 Co3 140.6(4) . 1_665
C1 N1 Co3 127.7(10) . .
C1 N1 H1A 116.1 . .
Co3 N1 H1A 116.1 . .
C2 N2 H2A 120.0 . .
C2 N2 H2B 120.0 . .
H2A N2 H2B 120.0 . .
C3 N3 H3A 120.1 . .
C3 N3 H3B 120.0 . .
H3A N3 H3B 120.0 . .
C4 N4 H4A 120.0 . .
C4 N4 H4B 120.0 . .
H4A N4 H4B 120.0 . .
C5 N5 H5A 120.0 . .
C5 N5 H5B 120.0 . .
H5A N5 H5B 120.0 . .
N1 C1 C2 113.4(13) . .
N1 C1 H1C 108.9 . .
C2 C1 H1C 108.9 . .
N1 C1 H1D 108.9 . .
C2 C1 H1D 108.9 . .
H1C C1 H1D 107.7 . .
N2 C2 C1 112.4(12) . .
N2 C2 H2C 109.1 . .
C1 C2 H2C 109.1 . .
N2 C2 H2D 109.1 . .
C1 C2 H2D 109.1 . .
H2C C2 H2D 107.9 . .
N3 C3 C4 111.5(14) . .
N3 C3 H3C 109.3 . .
C4 C3 H3C 109.3 . .
N3 C3 H3D 109.3 . .
C4 C3 H3D 109.3 . .
H3C C3 H3D 108.0 . .
N4 C4 C3 109.2(14) . .
N4 C4 H4C 109.8 . .
C3 C4 H4C 109.8 . .
N4 C4 H4D 109.8 . .
C3 C4 H4D 109.8 . .
H4C C4 H4D 108.3 . .
N5 C5 C5 110.3(13) . 2_556
N5 C5 H5C 109.6 . .
C5 C5 H5C 109.6 2_556 .
N5 C5 H5D 109.6 . .
C5 C5 H5D 109.6 2_556 .
H5C C5 H5D 108.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O7 1.724(9) .
W1 O28 1.870(9) .
W1 O22 1.889(8) .
W1 O1 1.926(7) .
W1 O18 1.929(9) .
W1 O3 2.432(8) .
W2 O31 1.742(8) .
W2 O14 1.747(8) .
W2 O25 1.900(8) .
W2 O23 1.971(8) .
W2 O16 2.041(8) .
W2 O2 2.324(8) .
W3 O27 1.715(9) .
W3 O32 1.775(8) .
W3 O25 1.917(7) .
W3 O20 1.946(8) .
W3 O28 2.036(8) .
W3 O3 2.345(8) .
W4 O34 1.717(9) .
W4 O24 1.879(7) .
W4 O4 1.907(8) .
W4 O18 1.908(9) .
W4 O6 1.922(7) .
W4 O13 2.416(8) .
W5 O33 1.728(8) .
W5 O30 1.790(8) .
W5 O19 1.904(8) .
W5 O12 1.907(8) .
W5 O4 2.037(8) .
W5 O13 2.326(8) .
W6 O21 1.739(8) .
W6 O29 1.769(9) .
W6 O20 1.932(9) .
W6 O9 1.934(9) .
W6 O22 2.048(8) .
W6 O3 2.310(7) .
W7 O8 1.698(8) .
W7 O16 1.829(8) .
W7 O1 1.899(8) .
W7 O17 1.900(8) .
W7 O6 1.943(8) .
W7 O2 2.472(8) .
W8 O26 1.737(8) .
W8 O15 1.809(8) .
W8 O23 1.881(8) .
W8 O19 1.937(8) .
W8 O17 2.028(8) .
W8 O2 2.292(8) .
W9 O11 1.727(8) .
W9 O10 1.759(8) .
W9 O9 1.901(9) .
W9 O12 1.984(8) .
W9 O24 2.036(8) .
W9 O13 2.335(8) .
Co1 O10 2.029(9) 2_676
Co1 O31 2.072(9) .
Co1 O15 2.083(9) .
Co1 O30 2.090(8) 2_676
Co1 O5 2.132(8) .
Co1 O5 2.156(8) 2_676
Co2 O32 2.042(8) .
Co2 O29 2.055(9) .
Co2 O3W 2.077(8) .
Co2 O5 2.115(8) .
Co2 O15 2.121(8) 2_676
Co2 O30 2.131(8) 2_676
Co3 O2W 2.064(9) .
Co3 O14 2.079(8) .
Co3 O21 2.112(8) 1_455
Co3 O1W 2.129(9) .
Co3 N1 2.147(11) .
Co3 O33 2.204(8) 1_445
Si1 O5 1.621(8) .
Si1 O13 1.637(9) .
Si1 O3 1.647(8) .
Si1 O2 1.653(7) .
O5 Co1 2.156(8) 2_676
O10 Co1 2.029(9) 2_676
O15 Co2 2.121(8) 2_676
O21 Co3 2.112(8) 1_655
O30 Co1 2.090(8) 2_676
O30 Co2 2.131(8) 2_676
O33 Co3 2.204(8) 1_665
N1 C1 1.415(19) .
N1 H1A 0.8602 .
N2 C2 1.437(17) .
N2 H2A 0.8600 .
N2 H2B 0.8600 .
N3 C3 1.48(2) .
N3 H3A 0.8600 .
N3 H3B 0.8600 .
N4 C4 1.481(19) .
N4 H4A 0.8600 .
N4 H4B 0.8599 .
N5 C5 1.462(18) .
N5 H5A 0.8600 .
N5 H5B 0.8600 .
C1 C2 1.56(2) .
C1 H1C 0.9700 .
C1 H1D 0.9700 .
C2 H2C 0.9700 .
C2 H2D 0.9700 .
C3 C4 1.52(2) .
C3 H3C 0.9700 .
C3 H3D 0.9700 .
C4 H4C 0.9700 .
C4 H4D 0.9700 .
C5 C5 1.58(3) 2_556
C5 H5C 0.9700 .
C5 H5D 0.9700 .
