#------------------------------------------------------------------------------
#$Date: 2016-04-05 18:33:54 +0300 (Tue, 05 Apr 2016) $
#$Revision: 181619 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/45/7224537.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224537
loop_
_publ_author_name
'Guo, Xianmin'
'Yan, Yongnian'
'Guo, Huadong'
'Qi, Yanjuan'
'Liu, Chunming'
_publ_section_title
;
 Seven entangled coordination polymers assembled from triphenylamine-based
 bisimidazole and dicarboxylates: interpenetration, self-penetration and
 mixed entanglement
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2546
_journal_paper_doi               10.1039/C6CE00102E
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C64 H46 N10 O8 Zn2'
_chemical_formula_sum            'C64 H46 N10 O8 Zn2'
_chemical_formula_weight         1213.85
_chemical_melting_point          ?
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-01-13 deposited with the CCDC.
2016-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                98.310(14)
_cell_angle_beta                 99.091(14)
_cell_angle_gamma                91.291(14)
_cell_formula_units_Z            1
_cell_length_a                   10.015(7)
_cell_length_b                   11.864(9)
_cell_length_c                   12.319(9)
_cell_measurement_reflns_used    7043
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.02
_cell_measurement_theta_min      1.61
_cell_volume                     1428.6(18)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    SHELXP-97
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 9.00cm
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0187
_diffrn_reflns_av_sigmaI/netI    0.0422
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10597
_diffrn_reflns_theta_full        28.39
_diffrn_reflns_theta_max         28.39
_diffrn_reflns_theta_min         1.69
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    0.906
_exptl_absorpt_correction_T_max  0.821
_exptl_absorpt_correction_T_min  0.794
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.411
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             624
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.484
_refine_diff_density_min         -0.376
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         7043
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.106
_refine_ls_R_factor_all          0.0606
_refine_ls_R_factor_gt           0.0383
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0611P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0976
_refine_ls_wR_factor_ref         0.1168
_reflns_number_gt                5358
_reflns_number_total             7043
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce00102e2.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7224535--7224541.cif.
;
_cod_original_cell_volume        1428.5(18)
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7224537
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.9488(2) 0.23840(18) 0.06660(18) 0.0328(5) Uani 1 1 d .
C2 C 0.9772(2) 0.11490(18) 0.03458(17) 0.0298(4) Uani 1 1 d .
C3 C 0.9025(2) 0.02793(18) 0.06718(18) 0.0333(5) Uani 1 1 d .
H3 H 0.8373 0.0464 0.1120 0.040 Uiso 1 1 calc R
C4 C 0.9254(2) -0.08492(19) 0.03295(19) 0.0333(5) Uani 1 1 d .
H4 H 0.8754 -0.1419 0.0551 0.040 Uiso 1 1 calc R
C5 C 0.6708(2) 0.5039(2) 0.3299(2) 0.0398(5) Uani 1 1 d .
C6 C 0.5829(2) 0.50194(19) 0.41857(18) 0.0338(5) Uani 1 1 d .
C7 C 0.5137(2) 0.4014(2) 0.4276(2) 0.0389(5) Uani 1 1 d .
H7 H 0.5223 0.3352 0.3791 0.047 Uiso 1 1 calc R
C8 C 0.4318(2) 0.3995(2) 0.5084(2) 0.0408(5) Uani 1 1 d .
H8 H 0.3864 0.3318 0.5139 0.049 Uiso 1 1 calc R
C9 C 1.0450(4) 0.5138(3) 0.3658(3) 0.0693(10) Uani 1 1 d .
H9 H 1.0254 0.4596 0.4092 0.083 Uiso 1 1 calc R
C10 C 1.1329(4) 0.6039(3) 0.4008(3) 0.0697(10) Uani 1 1 d .
H10 H 1.1838 0.6237 0.4713 0.084 Uiso 1 1 calc R
C11 C 1.0442(2) 0.6034(2) 0.2268(2) 0.0386(5) Uani 1 1 d .
H11 H 1.0250 0.6244 0.1563 0.046 Uiso 1 1 calc R
C12 C 1.2187(2) 0.7576(2) 0.3047(2) 0.0380(5) Uani 1 1 d .
C13 C 1.1895(3) 0.8199(2) 0.2181(2) 0.0418(6) Uani 1 1 d .
H13 H 1.1082 0.8056 0.1691 0.050 Uiso 1 1 calc R
C14 C 1.2811(3) 0.9034(2) 0.2040(2) 0.0435(6) Uani 1 1 d .
H14 H 1.2622 0.9429 0.1439 0.052 Uiso 1 1 calc R
C15 C 1.4005(3) 0.9292(2) 0.2781(2) 0.0443(6) Uani 1 1 d .
C16 C 1.4226(3) 0.8720(3) 0.3691(3) 0.0610(9) Uani 1 1 d .
H16 H 1.4991 0.8916 0.4227 0.073 Uiso 1 1 calc R
C17 C 1.3337(3) 0.7867(3) 0.3822(2) 0.0581(8) Uani 1 1 d .
H17 H 1.3513 0.7487 0.4435 0.070 Uiso 1 1 calc R
C18 C 1.4527(2) 1.1049(2) 0.2063(2) 0.0433(6) Uani 1 1 d .
C19 C 1.3467(3) 1.1668(2) 0.2393(2) 0.0447(6) Uani 1 1 d .
H19 H 1.3021 1.1446 0.2940 0.054 Uiso 1 1 calc R
C20 C 1.3069(3) 1.2618(2) 0.1911(2) 0.0445(6) Uani 1 1 d .
H20 H 1.2349 1.3028 0.2126 0.053 Uiso 1 1 calc R
C21 C 1.3745(2) 1.2950(2) 0.1113(2) 0.0400(5) Uani 1 1 d .
C22 C 1.4779(3) 1.2328(2) 0.0753(3) 0.0561(7) Uani 1 1 d .
H22 H 1.5217 1.2551 0.0202 0.067 Uiso 1 1 calc R
C23 C 1.5159(3) 1.1364(2) 0.1223(3) 0.0570(7) Uani 1 1 d .
H23 H 1.5841 1.0928 0.0973 0.068 Uiso 1 1 calc R
C24 C 1.2937(3) 1.4119(2) -0.0370(2) 0.0439(6) Uani 1 1 d .
H24 H 1.2822 1.3528 -0.0967 0.053 Uiso 1 1 calc R
C25 C 1.2997(3) 1.5778(2) 0.0605(2) 0.0463(6) Uani 1 1 d .
H25 H 1.2926 1.6558 0.0801 0.056 Uiso 1 1 calc R
C26 C 1.3442(3) 1.5053(2) 0.1319(2) 0.0523(7) Uani 1 1 d .
H26 H 1.3721 1.5234 0.2083 0.063 Uiso 1 1 calc R
C27 C 1.6388(3) 0.9962(2) 0.2901(2) 0.0450(6) Uani 1 1 d .
C28 C 1.6911(3) 0.8895(3) 0.2815(3) 0.0612(8) Uani 1 1 d .
H28 H 1.6343 0.8255 0.2527 0.073 Uiso 1 1 calc R
C29 C 1.8276(4) 0.8768(3) 0.3155(3) 0.0737(10) Uani 1 1 d .
H29 H 1.8615 0.8042 0.3114 0.088 Uiso 1 1 calc R
C30 C 1.9125(3) 0.9697(4) 0.3546(3) 0.0759(10) Uani 1 1 d .
H30 H 2.0043 0.9608 0.3770 0.091 Uiso 1 1 calc R
C31 C 1.8620(3) 1.0769(3) 0.3610(3) 0.0676(9) Uani 1 1 d .
H31 H 1.9204 1.1405 0.3872 0.081 Uiso 1 1 calc R
C32 C 1.7257(3) 1.0913(3) 0.3290(2) 0.0538(7) Uani 1 1 d .
H32 H 1.6924 1.1641 0.3335 0.065 Uiso 1 1 calc R
N1 N 0.9880(2) 0.51337(17) 0.25645(17) 0.0425(5) Uani 1 1 d .
N2 N 1.1324(2) 0.66087(17) 0.31089(16) 0.0393(5) Uani 1 1 d .
N3 N 1.4970(2) 1.01018(19) 0.2592(2) 0.0543(6) Uani 1 1 d .
N4 N 1.3399(2) 1.39950(16) 0.06866(17) 0.0397(5) Uani 1 1 d .
N5 N 1.2666(2) 1.51913(16) -0.04531(17) 0.0393(5) Uani 1 1 d .
O1 O 1.00461(18) 0.31296(14) 0.02699(15) 0.0460(4) Uani 1 1 d .
O2 O 0.86206(19) 0.25744(14) 0.13331(15) 0.0480(4) Uani 1 1 d .
O3 O 0.71386(18) 0.40655(15) 0.29330(14) 0.0466(4) Uani 1 1 d .
O4 O 0.6970(2) 0.59408(17) 0.29771(18) 0.0657(6) Uani 1 1 d .
Zn1 Zn 0.82550(3) 0.41611(2) 0.17688(2) 0.03407(10) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O2 124.5(2) . .
O1 C1 C2 120.0(2) . .
O2 C1 C2 115.51(19) . .
C4 C2 C3 118.8(2) 2_755 .
C4 C2 C1 120.29(19) 2_755 .
C3 C2 C1 120.88(19) . .
C4 C3 C2 120.2(2) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C2 121.0(2) . 2_755
C3 C4 H4 119.5 . .
C2 C4 H4 119.5 2_755 .
O4 C5 O3 124.5(2) . .
O4 C5 C6 120.4(2) . .
O3 C5 C6 115.1(2) . .
C7 C6 C8 119.0(2) . 2_666
C7 C6 C5 120.3(2) . .
C8 C6 C5 120.8(2) 2_666 .
C8 C7 C6 120.4(2) . .
C8 C7 H7 119.8 . .
C6 C7 H7 119.8 . .
C7 C8 C6 120.6(2) . 2_666
C7 C8 H8 119.7 . .
C6 C8 H8 119.7 2_666 .
C10 C9 N1 110.2(2) . .
C10 C9 H9 124.9 . .
N1 C9 H9 124.9 . .
C9 C10 N2 106.0(3) . .
C9 C10 H10 127.0 . .
N2 C10 H10 127.0 . .
N1 C11 N2 111.6(2) . .
N1 C11 H11 124.2 . .
N2 C11 H11 124.2 . .
C17 C12 C13 119.1(2) . .
C17 C12 N2 120.7(2) . .
C13 C12 N2 120.1(2) . .
C12 C13 C14 120.1(2) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C13 C14 C15 121.1(2) . .
C13 C14 H14 119.5 . .
C15 C14 H14 119.5 . .
C14 C15 C16 117.8(2) . .
C14 C15 N3 120.4(2) . .
C16 C15 N3 121.8(2) . .
C17 C16 C15 121.5(2) . .
C17 C16 H16 119.3 . .
C15 C16 H16 119.3 . .
C16 C17 C12 120.1(2) . .
C16 C17 H17 119.9 . .
C12 C17 H17 119.9 . .
C19 C18 C23 119.6(2) . .
C19 C18 N3 120.1(2) . .
C23 C18 N3 120.3(2) . .
C18 C19 C20 120.2(2) . .
C18 C19 H19 119.9 . .
C20 C19 H19 119.9 . .
C21 C20 C19 119.5(2) . .
C21 C20 H20 120.2 . .
C19 C20 H20 120.2 . .
C20 C21 C22 121.0(2) . .
C20 C21 N4 119.0(2) . .
C22 C21 N4 119.9(2) . .
C21 C22 C23 119.3(3) . .
C21 C22 H22 120.4 . .
C23 C22 H22 120.4 . .
C18 C23 C22 120.2(3) . .
C18 C23 H23 119.9 . .
C22 C23 H23 119.9 . .
N5 C24 N4 111.1(2) . .
N5 C24 H24 124.5 . .
N4 C24 H24 124.5 . .
C26 C25 N5 109.9(2) . .
C26 C25 H25 125.0 . .
N5 C25 H25 125.0 . .
C25 C26 N4 105.9(2) . .
C25 C26 H26 127.0 . .
N4 C26 H26 127.0 . .
C28 C27 C32 119.2(3) . .
C28 C27 N3 121.0(2) . .
C32 C27 N3 119.8(2) . .
C27 C28 C29 120.5(3) . .
C27 C28 H28 119.8 . .
C29 C28 H28 119.8 . .
C30 C29 C28 120.4(3) . .
C30 C29 H29 119.8 . .
C28 C29 H29 119.8 . .
C29 C30 C31 119.7(3) . .
C29 C30 H30 120.2 . .
C31 C30 H30 120.2 . .
C30 C31 C32 120.8(3) . .
C30 C31 H31 119.6 . .
C32 C31 H31 119.6 . .
C31 C32 C27 119.5(3) . .
C31 C32 H32 120.3 . .
C27 C32 H32 120.3 . .
C11 N1 C9 105.1(2) . .
C11 N1 Zn1 128.64(17) . .
C9 N1 Zn1 124.87(17) . .
C11 N2 C10 107.0(2) . .
C11 N2 C12 126.1(2) . .
C10 N2 C12 126.7(2) . .
C15 N3 C18 119.7(2) . .
C15 N3 C27 120.7(2) . .
C18 N3 C27 119.6(2) . .
C24 N4 C26 107.4(2) . .
C24 N4 C21 127.4(2) . .
C26 N4 C21 125.2(2) . .
C24 N5 C25 105.6(2) . .
C24 N5 Zn1 128.66(18) . 2_775
C25 N5 Zn1 125.27(17) . 2_775
C1 O2 Zn1 116.17(15) . .
C5 O3 Zn1 112.57(15) . .
O2 Zn1 O3 102.23(7) . .
O2 Zn1 N5 110.00(9) . 2_775
O3 Zn1 N5 114.47(9) . 2_775
O2 Zn1 N1 114.34(9) . .
O3 Zn1 N1 103.64(9) . .
N5 Zn1 N1 111.77(9) 2_775 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.234(3) .
C1 O2 1.289(3) .
C1 C2 1.507(3) .
C2 C4 1.398(3) 2_755
C2 C3 1.402(3) .
C3 C4 1.380(3) .
C3 H3 0.9300 .
C4 C2 1.398(3) 2_755
C4 H4 0.9300 .
C5 O4 1.230(3) .
C5 O3 1.288(3) .
C5 C6 1.509(3) .
C6 C7 1.393(3) .
C6 C8 1.394(3) 2_666
C7 C8 1.389(3) .
C7 H7 0.9300 .
C8 C6 1.394(3) 2_666
C8 H8 0.9300 .
C9 C10 1.345(4) .
C9 N1 1.376(4) .
C9 H9 0.9300 .
C10 N2 1.378(3) .
C10 H10 0.9300 .
C11 N1 1.319(3) .
C11 N2 1.340(3) .
C11 H11 0.9300 .
C12 C17 1.377(4) .
C12 C13 1.382(3) .
C12 N2 1.439(3) .
C13 C14 1.383(3) .
C13 H13 0.9300 .
C14 C15 1.384(3) .
C14 H14 0.9300 .
C15 C16 1.384(3) .
C15 N3 1.416(3) .
C16 C17 1.376(4) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.384(4) .
C18 C23 1.385(4) .
C18 N3 1.424(3) .
C19 C20 1.386(3) .
C19 H19 0.9300 .
C20 C21 1.375(4) .
C20 H20 0.9300 .
C21 C22 1.378(4) .
C21 N4 1.443(3) .
C22 C23 1.389(4) .
C22 H22 0.9300 .
C23 H23 0.9300 .
C24 N5 1.322(3) .
C24 N4 1.341(3) .
C24 H24 0.9300 .
C25 C26 1.350(4) .
C25 N5 1.373(3) .
C25 H25 0.9300 .
C26 N4 1.375(3) .
C26 H26 0.9300 .
C27 C28 1.378(4) .
C27 C32 1.388(4) .
C27 N3 1.431(3) .
C28 C29 1.383(4) .
C28 H28 0.9300 .
C29 C30 1.358(5) .
C29 H29 0.9300 .
C30 C31 1.376(5) .
C30 H30 0.9300 .
C31 C32 1.382(4) .
C31 H31 0.9300 .
C32 H32 0.9300 .
N1 Zn1 2.006(2) .
N5 Zn1 1.997(2) 2_775
O2 Zn1 1.941(2) .
O3 Zn1 1.9667(19) .
Zn1 N5 1.997(2) 2_775
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C4 5.1(3) . 2_755
O2 C1 C2 C4 -176.8(2) . 2_755
O1 C1 C2 C3 -171.8(2) . .
O2 C1 C2 C3 6.3(3) . .
C4 C2 C3 C4 0.1(4) 2_755 .
C1 C2 C3 C4 177.0(2) . .
C2 C3 C4 C2 -0.1(4) . 2_755
O4 C5 C6 C7 156.9(3) . .
O3 C5 C6 C7 -23.2(3) . .
O4 C5 C6 C8 -22.2(4) . 2_666
O3 C5 C6 C8 157.6(2) . 2_666
C8 C6 C7 C8 -0.3(4) 2_666 .
C5 C6 C7 C8 -179.5(2) . .
C6 C7 C8 C6 0.3(4) . 2_666
N1 C9 C10 N2 -0.6(4) . .
C17 C12 C13 C14 5.9(4) . .
N2 C12 C13 C14 -171.7(2) . .
C12 C13 C14 C15 -2.4(4) . .
C13 C14 C15 C16 -2.6(4) . .
C13 C14 C15 N3 176.3(3) . .
C14 C15 C16 C17 4.4(5) . .
N3 C15 C16 C17 -174.6(3) . .
C15 C16 C17 C12 -1.0(5) . .
C13 C12 C17 C16 -4.2(5) . .
N2 C12 C17 C16 173.4(3) . .
C23 C18 C19 C20 -2.0(4) . .
N3 C18 C19 C20 177.4(2) . .
C18 C19 C20 C21 -0.8(4) . .
C19 C20 C21 C22 2.6(4) . .
C19 C20 C21 N4 -174.7(2) . .
C20 C21 C22 C23 -1.4(5) . .
N4 C21 C22 C23 175.9(3) . .
C19 C18 C23 C22 3.2(4) . .
N3 C18 C23 C22 -176.2(3) . .
C21 C22 C23 C18 -1.6(5) . .
N5 C25 C26 N4 0.7(3) . .
C32 C27 C28 C29 2.5(5) . .
N3 C27 C28 C29 -177.6(3) . .
C27 C28 C29 C30 -1.9(5) . .
C28 C29 C30 C31 0.3(6) . .
C29 C30 C31 C32 0.6(5) . .
C30 C31 C32 C27 0.1(5) . .
C28 C27 C32 C31 -1.6(5) . .
N3 C27 C32 C31 178.5(3) . .
N2 C11 N1 C9 -0.4(3) . .
N2 C11 N1 Zn1 166.59(17) . .
C10 C9 N1 C11 0.6(4) . .
C10 C9 N1 Zn1 -167.0(3) . .
N1 C11 N2 C10 0.0(3) . .
N1 C11 N2 C12 174.9(2) . .
C9 C10 N2 C11 0.4(4) . .
C9 C10 N2 C12 -174.4(3) . .
C17 C12 N2 C11 -158.6(3) . .
C13 C12 N2 C11 19.0(4) . .
C17 C12 N2 C10 15.3(4) . .
C13 C12 N2 C10 -167.1(3) . .
C14 C15 N3 C18 33.1(4) . .
C16 C15 N3 C18 -148.0(3) . .
C14 C15 N3 C27 -145.3(3) . .
C16 C15 N3 C27 33.6(4) . .
C19 C18 N3 C15 45.8(4) . .
C23 C18 N3 C15 -134.8(3) . .
C19 C18 N3 C27 -135.9(3) . .
C23 C18 N3 C27 43.6(4) . .
C28 C27 N3 C15 35.2(4) . .
C32 C27 N3 C15 -144.9(3) . .
C28 C27 N3 C18 -143.2(3) . .
C32 C27 N3 C18 36.7(4) . .
N5 C24 N4 C26 -0.7(3) . .
N5 C24 N4 C21 177.1(2) . .
C25 C26 N4 C24 0.0(3) . .
C25 C26 N4 C21 -177.8(2) . .
C20 C21 N4 C24 -120.2(3) . .
C22 C21 N4 C24 62.5(4) . .
C20 C21 N4 C26 57.1(3) . .
C22 C21 N4 C26 -120.1(3) . .
N4 C24 N5 C25 1.1(3) . .
N4 C24 N5 Zn1 -171.57(16) . 2_775
C26 C25 N5 C24 -1.1(3) . .
C26 C25 N5 Zn1 171.89(19) . 2_775
O1 C1 O2 Zn1 -2.6(3) . .
C2 C1 O2 Zn1 179.35(13) . .
O4 C5 O3 Zn1 -0.9(3) . .
C6 C5 O3 Zn1 179.25(15) . .
C1 O2 Zn1 O3 -171.53(17) . .
C1 O2 Zn1 N5 66.47(19) . 2_775
C1 O2 Zn1 N1 -60.25(19) . .
C5 O3 Zn1 O2 -176.11(17) . .
C5 O3 Zn1 N5 -57.22(19) . 2_775
C5 O3 Zn1 N1 64.77(19) . .
C11 N1 Zn1 O2 119.0(2) . .
C9 N1 Zn1 O2 -76.5(3) . .
C11 N1 Zn1 O3 -130.6(2) . .
C9 N1 Zn1 O3 34.0(3) . .
C11 N1 Zn1 N5 -6.8(2) . 2_775
C9 N1 Zn1 N5 157.7(2) . 2_775
