#------------------------------------------------------------------------------
#$Date: 2016-05-06 03:55:03 +0300 (Fri, 06 May 2016) $
#$Revision: 182650 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/47/7224773.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224773
loop_
_publ_author_name
'Meng, Xiang-min'
'Fan, Chuan-bin'
'Bi, Cai-feng'
'Zong, Zi-ao'
'Zhang, Xia'
'Fan, Yu-hua'
_publ_section_title
;
 Syntheses, structural diversity and photocatalytic properties of various
 Co(ii) coordination polymers based on a “V”-shaped
 1,3-di(4′-carboxyl-phenyl)benzene acid and different imidazole
 bridging ligands
;
_journal_issue                   16
_journal_name_full               CrystEngComm
_journal_page_first              2901
_journal_paper_doi               10.1039/C5CE02473K
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C70 H52 Co2 N12 O10'
_chemical_formula_weight         1339.10
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-05-25 deposited with the CCDC.
2016-03-14 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 116.928(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   32.800(3)
_cell_length_b                   12.5860(11)
_cell_length_c                   16.0471(14)
_cell_measurement_reflns_used    2471
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      22.709
_cell_measurement_theta_min      2.456
_cell_volume                     5906.3(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0518
_diffrn_reflns_av_sigmaI/netI    0.0757
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            14741
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.46
_exptl_absorpt_coefficient_mu    0.638
_exptl_absorpt_correction_T_max  0.9390
_exptl_absorpt_correction_T_min  0.8672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.506
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2760
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.651
_refine_diff_density_min         -0.497
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         5205
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0844
_refine_ls_R_factor_gt           0.0492
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0367P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1045
_refine_ls_wR_factor_ref         0.1122
_reflns_number_gt                3168
_reflns_number_total             5205
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce02473k2.cif
_cod_data_source_block           150520d
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7224771--7224774.cif.
;
_cod_original_cell_volume        5906.4(9)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7224773
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.7500 0.2500 0.5000 0.0322(2) Uani 1 2 d S
Co2 Co 0.5000 1.09442(6) 0.2500 0.0395(2) Uani 1 2 d S
N1 N 0.71307(10) 0.5813(2) 0.48708(19) 0.0378(8) Uani 1 1 d .
N2 N 0.74087(10) 0.4207(2) 0.48591(19) 0.0383(8) Uani 1 1 d .
N3 N 0.61316(10) 0.8890(2) 0.38084(19) 0.0351(7) Uani 1 1 d .
N4 N 0.55654(10) 0.9985(2) 0.2978(2) 0.0411(8) Uani 1 1 d .
N5 N 0.67095(10) 0.7682(2) 0.70164(19) 0.0371(8) Uani 1 1 d .
N6 N 0.70059(9) 0.7676(2) 0.85598(19) 0.0364(8) Uani 1 1 d .
O1 O 0.70166(9) 0.2558(2) 0.55051(17) 0.0510(7) Uani 1 1 d .
O2 O 0.64929(13) 0.1361(3) 0.5281(3) 0.1197(17) Uani 1 1 d .
O3 O 0.51206(11) 0.1969(3) 1.1729(3) 0.0831(11) Uani 1 1 d .
O4 O 0.48792(13) 0.0758(3) 1.0646(3) 0.0958(12) Uani 1 1 d .
O5 O 0.40503(19) 0.0265(4) 0.9225(3) 0.166(2) Uani 1 1 d .
H5C H 0.3861 0.0602 0.9352 0.199 Uiso 1 1 d R
H5D H 0.4318 0.0392 0.9652 0.199 Uiso 1 1 d R
C1 C 0.66828(14) 0.2221(4) 0.5587(3) 0.0518(11) Uani 1 1 d .
C2 C 0.64953(12) 0.2913(3) 0.6103(2) 0.0408(10) Uani 1 1 d .
C3 C 0.60526(13) 0.2770(3) 0.5972(3) 0.0513(11) Uani 1 1 d .
H3 H 0.5866 0.2274 0.5537 0.062 Uiso 1 1 calc R
C4 C 0.58835(13) 0.3349(3) 0.6474(3) 0.0464(10) Uani 1 1 d .
H4 H 0.5583 0.3241 0.6366 0.056 Uiso 1 1 calc R
C5 C 0.61503(12) 0.4090(3) 0.7139(2) 0.0358(9) Uani 1 1 d .
C6 C 0.65846(13) 0.4263(3) 0.7234(3) 0.0442(10) Uani 1 1 d .
H6 H 0.6767 0.4783 0.7647 0.053 Uiso 1 1 calc R
C7 C 0.67560(13) 0.3685(3) 0.6731(3) 0.0452(10) Uani 1 1 d .
H7 H 0.7052 0.3816 0.6817 0.054 Uiso 1 1 calc R
C8 C 0.50470(15) 0.1640(4) 1.0936(4) 0.0586(13) Uani 1 1 d .
C9 C 0.51802(12) 0.2366(3) 1.0357(3) 0.0434(10) Uani 1 1 d .
C10 C 0.51570(12) 0.2027(3) 0.9513(3) 0.0451(10) Uani 1 1 d .
H10 H 0.5055 0.1344 0.9300 0.054 Uiso 1 1 calc R
C11 C 0.52834(12) 0.2693(3) 0.8990(3) 0.0419(10) Uani 1 1 d .
H11 H 0.5261 0.2452 0.8422 0.050 Uiso 1 1 calc R
C12 C 0.54440(12) 0.3718(3) 0.9288(2) 0.0370(9) Uani 1 1 d .
C13 C 0.54640(13) 0.4046(3) 1.0133(3) 0.0477(11) Uani 1 1 d .
H13 H 0.5569 0.4726 1.0353 0.057 Uiso 1 1 calc R
C14 C 0.53314(13) 0.3385(4) 1.0651(3) 0.0505(11) Uani 1 1 d .
H14 H 0.5344 0.3631 1.1209 0.061 Uiso 1 1 calc R
C15 C 0.59759(12) 0.4621(3) 0.7743(2) 0.0369(9) Uani 1 1 d .
C16 C 0.57611(11) 0.4008(3) 0.8143(2) 0.0356(9) Uani 1 1 d .
H16 H 0.5713 0.3291 0.7989 0.043 Uiso 1 1 calc R
C17 C 0.56144(12) 0.4422(3) 0.8765(2) 0.0362(9) Uani 1 1 d .
C18 C 0.56608(14) 0.5514(3) 0.8926(3) 0.0518(11) Uani 1 1 d .
H18 H 0.5551 0.5827 0.9310 0.062 Uiso 1 1 calc R
C19 C 0.58686(14) 0.6136(3) 0.8518(3) 0.0560(12) Uani 1 1 d .
H19 H 0.5895 0.6864 0.8628 0.067 Uiso 1 1 calc R
C20 C 0.60364(13) 0.5695(3) 0.7950(3) 0.0487(11) Uani 1 1 d .
H20 H 0.6190 0.6117 0.7707 0.058 Uiso 1 1 calc R
C21 C 0.71194(13) 0.4762(3) 0.5047(2) 0.0425(10) Uani 1 1 d .
H21 H 0.6930 0.4467 0.5275 0.051 Uiso 1 1 calc R
C22 C 0.76175(14) 0.4939(3) 0.4556(3) 0.0501(11) Uani 1 1 d .
H22 H 0.7845 0.4784 0.4381 0.060 Uiso 1 1 calc R
C23 C 0.74479(14) 0.5919(3) 0.4545(3) 0.0516(11) Uani 1 1 d .
H23 H 0.7531 0.6544 0.4353 0.062 Uiso 1 1 calc R
C24 C 0.57996(12) 0.9528(3) 0.3796(3) 0.0421(10) Uani 1 1 d .
H24 H 0.5743 0.9635 0.4308 0.050 Uiso 1 1 calc R
C25 C 0.57605(13) 0.9622(3) 0.2434(3) 0.0457(10) Uani 1 1 d .
H25 H 0.5668 0.9814 0.1815 0.055 Uiso 1 1 calc R
C26 C 0.61040(13) 0.8950(3) 0.2927(3) 0.0465(10) Uani 1 1 d .
H26 H 0.6288 0.8594 0.2715 0.056 Uiso 1 1 calc R
C27 C 0.70627(12) 0.7374(3) 0.7841(2) 0.0400(10) Uani 1 1 d .
H27 H 0.7315 0.6993 0.7887 0.048 Uiso 1 1 calc R
C28 C 0.65960(13) 0.8211(3) 0.8190(3) 0.0431(10) Uani 1 1 d .
H28 H 0.6465 0.8520 0.8537 0.052 Uiso 1 1 calc R
C29 C 0.64119(13) 0.8220(3) 0.7247(3) 0.0465(11) Uani 1 1 d .
H29 H 0.6137 0.8532 0.6835 0.056 Uiso 1 1 calc R
C30 C 0.68882(12) 0.6646(3) 0.5058(3) 0.0371(9) Uani 1 1 d .
C31 C 0.66440(11) 0.7362(3) 0.4352(2) 0.0360(9) Uani 1 1 d .
H31 H 0.6636 0.7301 0.3767 0.043 Uiso 1 1 calc R
C32 C 0.64119(12) 0.8174(3) 0.4541(2) 0.0357(9) Uani 1 1 d .
C33 C 0.64361(11) 0.8284(3) 0.5420(2) 0.0369(9) Uani 1 1 d .
H33 H 0.6290 0.8848 0.5549 0.044 Uiso 1 1 calc R
C34 C 0.66805(11) 0.7544(3) 0.6108(2) 0.0359(9) Uani 1 1 d .
C35 C 0.69037(12) 0.6718(3) 0.5928(2) 0.0406(10) Uani 1 1 d .
H35 H 0.7063 0.6216 0.6387 0.049 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 O1 180.00(5) 7_656 .
O1 Co1 N6 85.08(10) 7_656 6_565
O1 Co1 N6 94.92(10) . 6_565
O1 Co1 N6 94.92(10) 7_656 4_646
O1 Co1 N6 85.08(10) . 4_646
N6 Co1 N6 180.000(1) 6_565 4_646
O1 Co1 N2 84.98(11) 7_656 7_656
O1 Co1 N2 95.02(11) . 7_656
N6 Co1 N2 90.63(11) 6_565 7_656
N6 Co1 N2 89.37(11) 4_646 7_656
O1 Co1 N2 95.02(11) 7_656 .
O1 Co1 N2 84.98(11) . .
N6 Co1 N2 89.37(11) 6_565 .
N6 Co1 N2 90.63(11) 4_646 .
N2 Co1 N2 180.000(1) 7_656 .
O3 Co2 O3 97.1(2) 1_564 2_666
O3 Co2 N4 102.62(13) 1_564 .
O3 Co2 N4 124.19(14) 2_666 .
O3 Co2 N4 124.19(14) 1_564 2_655
O3 Co2 N4 102.62(13) 2_666 2_655
N4 Co2 N4 107.77(17) . 2_655
C21 N1 C23 105.8(3) . .
C21 N1 C30 127.0(3) . .
C23 N1 C30 127.0(3) . .
C21 N2 C22 104.8(3) . .
C21 N2 Co1 125.5(3) . .
C22 N2 Co1 129.7(3) . .
C24 N3 C26 106.0(3) . .
C24 N3 C32 126.9(3) . .
C26 N3 C32 126.5(3) . .
C24 N4 C25 105.1(3) . .
C24 N4 Co2 130.7(3) . .
C25 N4 Co2 124.1(2) . .
C27 N5 C29 105.9(3) . .
C27 N5 C34 126.3(3) . .
C29 N5 C34 127.6(3) . .
C27 N6 C28 105.3(3) . .
C27 N6 Co1 125.4(2) . 4_656
C28 N6 Co1 128.9(2) . 4_656
C1 O1 Co1 153.7(3) . .
C8 O3 Co2 115.2(3) . 1_546
H5C O5 H5D 108.3 . .
O2 C1 O1 124.8(4) . .
O2 C1 C2 117.8(4) . .
O1 C1 C2 117.4(4) . .
C3 C2 C7 117.5(4) . .
C3 C2 C1 120.2(4) . .
C7 C2 C1 122.3(3) . .
C4 C3 C2 121.1(4) . .
C4 C3 H3 119.4 . .
C2 C3 H3 119.4 . .
C3 C4 C5 121.6(4) . .
C3 C4 H4 119.2 . .
C5 C4 H4 119.2 . .
C6 C5 C4 116.8(3) . .
C6 C5 C15 122.6(3) . .
C4 C5 C15 120.5(3) . .
C5 C6 C7 121.7(4) . .
C5 C6 H6 119.2 . .
C7 C6 H6 119.2 . .
C6 C7 C2 121.0(4) . .
C6 C7 H7 119.5 . .
C2 C7 H7 119.5 . .
O4 C8 O3 121.8(4) . .
O4 C8 C9 121.3(5) . .
O3 C8 C9 116.8(5) . .
C14 C9 C10 118.1(4) . .
C14 C9 C8 121.0(4) . .
C10 C9 C8 120.9(4) . .
C11 C10 C9 120.7(4) . .
C11 C10 H10 119.7 . .
C9 C10 H10 119.7 . .
C10 C11 C12 121.6(4) . .
C10 C11 H11 119.2 . .
C12 C11 H11 119.2 . .
C13 C12 C11 117.0(3) . .
C13 C12 C17 120.6(4) . .
C11 C12 C17 122.3(3) . .
C14 C13 C12 121.4(4) . .
C14 C13 H13 119.3 . .
C12 C13 H13 119.3 . .
C13 C14 C9 121.2(4) . .
C13 C14 H14 119.4 . .
C9 C14 H14 119.4 . .
C16 C15 C20 118.8(4) . .
C16 C15 C5 118.5(4) . .
C20 C15 C5 122.6(3) . .
C15 C16 C17 122.6(4) . .
C15 C16 H16 118.7 . .
C17 C16 H16 118.7 . .
C16 C17 C18 117.3(3) . .
C16 C17 C12 121.4(4) . .
C18 C17 C12 121.2(3) . .
C19 C18 C17 120.4(4) . .
C19 C18 H18 119.8 . .
C17 C18 H18 119.8 . .
C20 C19 C18 121.1(4) . .
C20 C19 H19 119.4 . .
C18 C19 H19 119.4 . .
C19 C20 C15 119.7(4) . .
C19 C20 H20 120.2 . .
C15 C20 H20 120.2 . .
N2 C21 N1 112.2(3) . .
N2 C21 H21 123.9 . .
N1 C21 H21 123.9 . .
C23 C22 N2 110.6(4) . .
C23 C22 H22 124.7 . .
N2 C22 H22 124.7 . .
C22 C23 N1 106.6(4) . .
C22 C23 H23 126.7 . .
N1 C23 H23 126.7 . .
N4 C24 N3 112.2(3) . .
N4 C24 H24 123.9 . .
N3 C24 H24 123.9 . .
C26 C25 N4 110.0(3) . .
C26 C25 H25 125.0 . .
N4 C25 H25 125.0 . .
C25 C26 N3 106.7(3) . .
C25 C26 H26 126.7 . .
N3 C26 H26 126.7 . .
N6 C27 N5 112.1(3) . .
N6 C27 H27 123.9 . .
N5 C27 H27 123.9 . .
C29 C28 N6 110.0(3) . .
C29 C28 H28 125.0 . .
N6 C28 H28 125.0 . .
C28 C29 N5 106.6(3) . .
C28 C29 H29 126.7 . .
N5 C29 H29 126.7 . .
C35 C30 C31 121.9(3) . .
C35 C30 N1 119.6(3) . .
C31 C30 N1 118.5(3) . .
C30 C31 C32 118.2(3) . .
C30 C31 H31 120.9 . .
C32 C31 H31 120.9 . .
C33 C32 C31 120.9(3) . .
C33 C32 N3 119.5(3) . .
C31 C32 N3 119.6(3) . .
C32 C33 C34 119.3(3) . .
C32 C33 H33 120.3 . .
C34 C33 H33 120.3 . .
C35 C34 C33 120.7(3) . .
C35 C34 N5 120.7(3) . .
C33 C34 N5 118.5(3) . .
C34 C35 C30 118.9(3) . .
C34 C35 H35 120.5 . .
C30 C35 H35 120.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.083(2) 7_656
Co1 O1 2.083(2) .
Co1 N6 2.150(3) 6_565
Co1 N6 2.150(3) 4_646
Co1 N2 2.167(3) 7_656
Co1 N2 2.167(3) .
Co2 O3 1.948(3) 1_564
Co2 O3 1.948(3) 2_666
Co2 N4 2.049(3) .
Co2 N4 2.049(3) 2_655
N1 C21 1.357(4) .
N1 C23 1.366(4) .
N1 C30 1.428(4) .
N2 C21 1.319(4) .
N2 C22 1.362(5) .
N3 C24 1.346(4) .
N3 C26 1.377(4) .
N3 C32 1.436(4) .
N4 C24 1.315(4) .
N4 C25 1.374(4) .
N5 C27 1.362(4) .
N5 C29 1.370(4) .
N5 C34 1.428(4) .
N6 C27 1.305(4) .
N6 C28 1.374(4) .
N6 Co1 2.150(3) 4_656
O1 C1 1.236(4) .
O2 C1 1.233(5) .
O3 C8 1.253(5) .
O3 Co2 1.948(3) 1_546
O4 C8 1.234(6) .
O5 H5C 0.8500 .
O5 H5D 0.8500 .
C1 C2 1.511(5) .
C2 C3 1.382(5) .
C2 C7 1.382(5) .
C3 C4 1.375(5) .
C3 H3 0.9300 .
C4 C5 1.388(5) .
C4 H4 0.9300 .
C5 C6 1.380(5) .
C5 C15 1.489(5) .
C6 C7 1.381(5) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.501(5) .
C9 C14 1.379(5) .
C9 C10 1.389(5) .
C10 C11 1.376(5) .
C10 H10 0.9300 .
C11 C12 1.395(5) .
C11 H11 0.9300 .
C12 C13 1.389(5) .
C12 C17 1.492(5) .
C13 C14 1.379(5) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 C16 1.383(5) .
C15 C20 1.384(5) .
C16 C17 1.391(5) .
C16 H16 0.9300 .
C17 C18 1.395(5) .
C18 C19 1.382(5) .
C18 H18 0.9300 .
C19 C20 1.375(5) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 C23 1.350(5) .
C22 H22 0.9300 .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.343(5) .
C25 H25 0.9300 .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.351(5) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 C35 1.377(5) .
C30 C31 1.384(5) .
C31 C32 1.387(5) .
C31 H31 0.9300 .
C32 C33 1.383(4) .
C33 C34 1.388(5) .
C33 H33 0.9300 .
C34 C35 1.375(5) .
C35 H35 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O1 Co1 N2 C21 177.6(3) 7_656
O1 Co1 N2 C21 -2.4(3) .
N6 Co1 N2 C21 92.6(3) 6_565
N6 Co1 N2 C21 -87.4(3) 4_646
N2 Co1 N2 C21 64(100) 7_656
O1 Co1 N2 C22 -1.2(3) 7_656
O1 Co1 N2 C22 178.8(3) .
N6 Co1 N2 C22 -86.2(3) 6_565
N6 Co1 N2 C22 93.8(3) 4_646
N2 Co1 N2 C22 -115(100) 7_656
O3 Co2 N4 C24 142.3(3) 1_564
O3 Co2 N4 C24 34.6(4) 2_666
N4 Co2 N4 C24 -85.1(3) 2_655
O3 Co2 N4 C25 -42.7(3) 1_564
O3 Co2 N4 C25 -150.5(3) 2_666
N4 Co2 N4 C25 89.9(3) 2_655
O1 Co1 O1 C1 -32(100) 7_656
N6 Co1 O1 C1 52.1(6) 6_565
N6 Co1 O1 C1 -127.9(6) 4_646
N2 Co1 O1 C1 -39.0(6) 7_656
N2 Co1 O1 C1 141.0(6) .
Co1 O1 C1 O2 6.4(10) .
Co1 O1 C1 C2 -173.8(4) .
O2 C1 C2 C3 -20.8(6) .
O1 C1 C2 C3 159.4(4) .
O2 C1 C2 C7 157.6(4) .
O1 C1 C2 C7 -22.2(6) .
C7 C2 C3 C4 -2.3(6) .
C1 C2 C3 C4 176.2(4) .
C2 C3 C4 C5 -0.7(6) .
C3 C4 C5 C6 3.6(6) .
C3 C4 C5 C15 -173.4(4) .
C4 C5 C6 C7 -3.6(6) .
C15 C5 C6 C7 173.4(4) .
C5 C6 C7 C2 0.7(6) .
C3 C2 C7 C6 2.3(6) .
C1 C2 C7 C6 -176.2(4) .
Co2 O3 C8 O4 5.0(6) 1_546
Co2 O3 C8 C9 -174.0(3) 1_546
O4 C8 C9 C14 174.5(4) .
O3 C8 C9 C14 -6.5(6) .
O4 C8 C9 C10 -5.9(6) .
O3 C8 C9 C10 173.1(4) .
C14 C9 C10 C11 0.2(5) .
C8 C9 C10 C11 -179.4(3) .
C9 C10 C11 C12 0.9(6) .
C10 C11 C12 C13 -1.0(5) .
C10 C11 C12 C17 175.4(3) .
C11 C12 C13 C14 0.1(6) .
C17 C12 C13 C14 -176.4(3) .
C12 C13 C14 C9 1.0(6) .
C10 C9 C14 C13 -1.2(6) .
C8 C9 C14 C13 178.5(3) .
C6 C5 C15 C16 -132.2(4) .
C4 C5 C15 C16 44.7(5) .
C6 C5 C15 C20 45.2(5) .
C4 C5 C15 C20 -137.9(4) .
C20 C15 C16 C17 -1.8(5) .
C5 C15 C16 C17 175.7(3) .
C15 C16 C17 C18 4.7(5) .
C15 C16 C17 C12 -171.2(3) .
C13 C12 C17 C16 155.2(3) .
C11 C12 C17 C16 -21.1(5) .
C13 C12 C17 C18 -20.5(5) .
C11 C12 C17 C18 163.2(4) .
C16 C17 C18 C19 -3.5(6) .
C12 C17 C18 C19 172.4(3) .
C17 C18 C19 C20 -0.4(6) .
C18 C19 C20 C15 3.4(6) .
C16 C15 C20 C19 -2.3(6) .
C5 C15 C20 C19 -179.7(4) .
C22 N2 C21 N1 0.6(4) .
Co1 N2 C21 N1 -178.5(2) .
C23 N1 C21 N2 0.3(4) .
C30 N1 C21 N2 -175.1(3) .
C21 N2 C22 C23 -1.3(4) .
Co1 N2 C22 C23 177.8(3) .
N2 C22 C23 N1 1.5(5) .
C21 N1 C23 C22 -1.1(4) .
C30 N1 C23 C22 174.4(3) .
C25 N4 C24 N3 -0.4(4) .
Co2 N4 C24 N3 175.3(2) .
C26 N3 C24 N4 0.0(4) .
C32 N3 C24 N4 -171.7(3) .
C24 N4 C25 C26 0.6(4) .
Co2 N4 C25 C26 -175.4(3) .
N4 C25 C26 N3 -0.6(4) .
C24 N3 C26 C25 0.4(4) .
C32 N3 C26 C25 172.1(3) .
C28 N6 C27 N5 -0.1(4) .
Co1 N6 C27 N5 -174.0(2) 4_656
C29 N5 C27 N6 0.2(4) .
C34 N5 C27 N6 175.4(3) .
C27 N6 C28 C29 0.0(4) .
Co1 N6 C28 C29 173.6(3) 4_656
N6 C28 C29 N5 0.1(4) .
C27 N5 C29 C28 -0.2(4) .
C34 N5 C29 C28 -175.3(3) .
C21 N1 C30 C35 49.4(5) .
C23 N1 C30 C35 -125.1(4) .
C21 N1 C30 C31 -130.8(4) .
C23 N1 C30 C31 54.7(5) .
C35 C30 C31 C32 0.3(5) .
N1 C30 C31 C32 -179.6(3) .
C30 C31 C32 C33 2.1(5) .
C30 C31 C32 N3 -176.0(3) .
C24 N3 C32 C33 -16.5(5) .
C26 N3 C32 C33 173.5(3) .
C24 N3 C32 C31 161.7(3) .
C26 N3 C32 C31 -8.3(5) .
C31 C32 C33 C34 -2.8(5) .
N3 C32 C33 C34 175.3(3) .
C32 C33 C34 C35 1.1(5) .
C32 C33 C34 N5 178.8(3) .
C27 N5 C34 C35 27.9(5) .
C29 N5 C34 C35 -157.9(4) .
C27 N5 C34 C33 -149.7(4) .
C29 N5 C34 C33 24.4(5) .
C33 C34 C35 C30 1.2(5) .
N5 C34 C35 C30 -176.4(3) .
C31 C30 C35 C34 -1.9(5) .
N1 C30 C35 C34 178.0(3) .
