#------------------------------------------------------------------------------
#$Date: 2016-11-08 21:33:28 +0200 (Tue, 08 Nov 2016) $
#$Revision: 188098 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/64/7226421.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226421
loop_
_publ_author_name
'Rong, Jiewei'
'Zhang, Wenwei'
'Bai, Junfeng'
_publ_section_title
;
 Highly thermostable lanthanide(iii) MOFs constructed from
 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoate ligand:
 synthesis, structure, and tunable white-light emission
;
_journal_issue                   40
_journal_name_full               CrystEngComm
_journal_page_first              7728
_journal_paper_doi               10.1039/C6CE01585A
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C65 H73 Eu2 N7 O20 S7'
_chemical_formula_weight         1800.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-03-29 deposited with the CCDC.
2016-08-31 downloaded from the CCDC.
;
_cell_angle_alpha                110.2660(10)
_cell_angle_beta                 111.0240(10)
_cell_angle_gamma                96.7140(10)
_cell_formula_units_Z            2
_cell_length_a                   16.0536(6)
_cell_length_b                   16.3481(7)
_cell_length_c                   17.1341(7)
_cell_measurement_reflns_used    7233
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.1607
_cell_measurement_theta_min      2.2077
_cell_volume                     3785.3(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  bruker-CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0253
_diffrn_reflns_av_sigmaI/netI    0.0507
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            21359
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.50
_exptl_absorpt_coefficient_mu    1.908
_exptl_absorpt_correction_T_max  0.7132
_exptl_absorpt_correction_T_min  0.6901
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.580
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1820
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.19
_refine_diff_density_max         2.825
_refine_diff_density_min         -1.837
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     938
_refine_ls_number_reflns         13224
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0732
_refine_ls_R_factor_gt           0.0543
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1162P)²+5.9070P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1574
_refine_ls_wR_factor_ref         0.1765
_reflns_number_gt                10238
_reflns_number_total             13224
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce01585a2.cif
_cod_data_source_block           ww
_cod_depositor_comments
'Adding full bibliography for 7226417--7226424.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7226421
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.69047(2) -1.17814(2) -0.36403(2) 0.02514(12) Uani 1 1 d . . .
Eu2 Eu 0.30827(2) -0.69372(2) -0.39238(2) 0.02810(13) Uani 1 1 d . . .
O1 O -0.5429(3) -1.0965(4) -0.3550(3) 0.0351(12) Uani 1 1 d . . .
O2 O -0.5313(3) -1.1308(4) -0.2384(3) 0.0372(12) Uani 1 1 d . . .
O3 O 0.1656(4) -0.7552(5) -0.3802(4) 0.0527(16) Uani 1 1 d . . .
O4 O 0.2981(4) -0.7451(5) -0.2744(4) 0.0514(16) Uani 1 1 d . . .
O5 O 0.1922(3) -0.8013(4) 0.4515(3) 0.0351(12) Uani 1 1 d . . .
O6 O 0.3192(3) -0.7268(4) 0.4565(3) 0.0413(13) Uani 1 1 d . . .
O7 O -0.7793(4) -1.2996(4) -0.3438(4) 0.0448(14) Uani 1 1 d . . .
O8 O -0.7062(4) -1.1705(4) -0.2222(4) 0.0476(15) Uani 1 1 d . . .
O9 O -1.5328(4) -1.6557(4) -0.2777(4) 0.0550(16) Uani 1 1 d . . .
O10 O -1.5473(4) -1.5754(4) -0.3584(4) 0.0479(15) Uani 1 1 d . . .
O11 O -0.7294(3) -1.1792(4) 0.4836(3) 0.0361(12) Uani 1 1 d . . .
O12 O -0.8149(4) -1.3001(4) 0.4729(3) 0.0410(13) Uani 1 1 d . . .
O13 O -0.6187(4) -1.2935(4) -0.4190(4) 0.0440(13) Uani 1 1 d . . .
O14 O 0.3536(4) -0.8325(4) -0.4255(4) 0.0512(15) Uani 1 1 d . . .
O15 O -0.8347(3) -1.1405(4) -0.3911(4) 0.0477(14) Uani 1 1 d . . .
O16 O -0.6608(4) -1.0164(4) -0.2771(4) 0.0527(16) Uani 1 1 d . . .
O17 O 0.2174(4) -0.6098(4) -0.4600(5) 0.0589(17) Uani 1 1 d . . .
O18 O 0.3127(6) -0.5632(5) -0.2679(6) 0.093(3) Uani 1 1 d . . .
O19 O 0.6324(7) -0.1878(8) -0.0411(7) 0.136(4) Uani 1 1 d . . .
O20 O 0.4658(9) -0.3257(9) 0.0419(9) 0.139(4) Uani 1 1 d . . .
N1 N -0.0638(4) -0.8979(4) -0.1490(4) 0.0317(14) Uani 1 1 d . . .
N2 N 0.0787(4) -0.8383(5) -0.0172(4) 0.0353(15) Uani 1 1 d . . .
N3 N -0.0556(4) -0.9073(5) -0.0125(4) 0.0346(15) Uani 1 1 d . . .
N4 N -0.9262(4) -1.3273(5) 0.0065(4) 0.0358(15) Uani 1 1 d . . .
N5 N -1.0621(4) -1.3927(5) -0.1337(4) 0.0361(15) Uani 1 1 d . . .
N6 N -1.0640(4) -1.4073(5) 0.0001(4) 0.0391(16) Uani 1 1 d . . .
N7 N 0.4408(7) -0.2240(7) 0.1489(6) 0.070(2) Uani 1 1 d . . .
C1 C -0.4949(5) -1.0940(6) -0.2768(5) 0.0383(18) Uani 1 1 d . . .
C2 C -0.3934(5) -1.0497(6) -0.2312(5) 0.0387(18) Uani 1 1 d . . .
C3 C -0.3501(5) -1.0198(6) -0.2764(5) 0.0387(18) Uani 1 1 d . . .
H3A H -0.3859 -1.0269 -0.3373 0.046 Uiso 1 1 calc R . .
C4 C -0.2558(5) -0.9797(6) -0.2350(5) 0.0382(18) Uani 1 1 d . . .
H4A H -0.2271 -0.9611 -0.2682 0.046 Uiso 1 1 calc R . .
C5 C -0.2028(5) -0.9662(6) -0.1458(5) 0.0379(18) Uani 1 1 d . . .
C6 C -0.2451(5) -0.9969(6) -0.0987(5) 0.0383(18) Uani 1 1 d . . .
H6A H -0.2090 -0.9901 -0.0380 0.046 Uiso 1 1 calc R . .
C7 C -0.3412(5) -1.0377(6) -0.1415(5) 0.0383(18) Uani 1 1 d . . .
H7A H -0.3705 -1.0570 -0.1091 0.046 Uiso 1 1 calc R . .
C8 C -0.1026(5) -0.9216(6) -0.1004(5) 0.0383(18) Uani 1 1 d . . .
C9 C 0.0267(5) -0.8574(6) -0.1055(5) 0.0394(18) Uani 1 1 d . . .
C10 C 0.0744(5) -0.8303(6) -0.1565(5) 0.0403(19) Uani 1 1 d . . .
C11 C 0.0232(5) -0.8408(6) -0.2461(5) 0.042(2) Uani 1 1 d . . .
H11A H -0.0425 -0.8638 -0.2742 0.051 Uiso 1 1 calc R . .
C12 C 0.0678(5) -0.8177(6) -0.2937(5) 0.0421(19) Uani 1 1 d . . .
H12A H 0.0324 -0.8249 -0.3547 0.051 Uiso 1 1 calc R . .
C13 C 0.1621(5) -0.7845(6) -0.2546(5) 0.044(2) Uani 1 1 d . A .
C14 C 0.2136(5) -0.7734(6) -0.1653(5) 0.0420(19) Uani 1 1 d . . .
H14A H 0.2793 -0.7509 -0.1376 0.050 Uiso 1 1 calc R . .
C15 C 0.1687(5) -0.7952(6) -0.1166(5) 0.0420(19) Uani 1 1 d . . .
H15A H 0.2038 -0.7857 -0.0547 0.050 Uiso 1 1 calc R . .
C16 C 0.2112(6) -0.7608(6) -0.3070(6) 0.045(2) Uani 1 1 d . . .
C17 C 0.0347(5) -0.8655(6) 0.0269(5) 0.0391(18) Uani 1 1 d . . .
C18 C 0.0877(5) -0.8444(6) 0.1253(5) 0.0390(18) Uani 1 1 d . . .
C19 C 0.0440(5) -0.8694(6) 0.1723(5) 0.0403(19) Uani 1 1 d . . .
H19A H -0.0199 -0.9020 0.1411 0.048 Uiso 1 1 calc R . .
C20 C 0.0922(5) -0.8475(6) 0.2643(5) 0.0401(19) Uani 1 1 d . . .
H20A H 0.0606 -0.8637 0.2966 0.048 Uiso 1 1 calc R . .
C21 C 0.1869(5) -0.8019(6) 0.3115(5) 0.0390(18) Uani 1 1 d . . .
C22 C 0.2310(5) -0.7801(6) 0.2621(5) 0.0398(19) Uani 1 1 d . . .
H22A H 0.2954 -0.7499 0.2920 0.048 Uiso 1 1 calc R . .
C23 C 0.1818(5) -0.8019(6) 0.1700(5) 0.0400(19) Uani 1 1 d . . .
H23A H 0.2130 -0.7876 0.1366 0.048 Uiso 1 1 calc R . .
C24 C 0.2367(5) -0.7755(6) 0.4125(5) 0.0389(18) Uani 1 1 d . . .
C25 C -0.7655(5) -1.2473(6) -0.2642(5) 0.0396(19) Uani 1 1 d . . .
C26 C -0.8188(5) -1.2728(6) -0.2170(5) 0.0395(19) Uani 1 1 d . . .
C27 C -0.7927(5) -1.2233(6) -0.1246(5) 0.0404(19) Uani 1 1 d . . .
H27A H -0.7401 -1.1717 -0.0904 0.049 Uiso 1 1 calc R . .
C28 C -0.8429(5) -1.2485(6) -0.0811(5) 0.0404(19) Uani 1 1 d . . .
H28A H -0.8229 -1.2152 -0.0168 0.048 Uiso 1 1 calc R . .
C29 C -0.9199(5) -1.3198(6) -0.1293(5) 0.0394(18) Uani 1 1 d . . .
C30 C -0.9731(5) -1.3482(6) -0.0829(5) 0.0389(18) Uani 1 1 d . . .
C31 C -0.9491(5) -1.3681(6) -0.2235(5) 0.0408(19) Uani 1 1 d . . .
H31A H -1.0045 -1.4167 -0.2580 0.049 Uiso 1 1 calc R . .
C32 C -0.8986(5) -1.3462(6) -0.2671(5) 0.0407(19) Uani 1 1 d . . .
H32A H -0.9179 -1.3808 -0.3311 0.049 Uiso 1 1 calc R . .
C33 C -0.9756(5) -1.3591(6) 0.0438(5) 0.0386(18) Uani 1 1 d . . .
C34 C -0.9268(5) -1.3361(6) 0.1441(5) 0.0386(18) Uani 1 1 d . . .
C35 C -0.9653(5) -1.3790(6) 0.1860(5) 0.0389(18) Uani 1 1 d . . .
H35A H -1.0223 -1.4254 0.1501 0.047 Uiso 1 1 calc R . .
C36 C -0.9204(5) -1.3537(6) 0.2795(5) 0.0389(18) Uani 1 1 d . . .
H36A H -0.9470 -1.3832 0.3074 0.047 Uiso 1 1 calc R . .
C37 C -0.8368(5) -1.2858(6) 0.3339(5) 0.0383(18) Uani 1 1 d . . .
C38 C -0.7989(5) -1.2441(6) 0.2914(5) 0.0392(18) Uani 1 1 d . . .
H38A H -0.7425 -1.1969 0.3276 0.047 Uiso 1 1 calc R . .
C39 C -0.8417(5) -1.2702(6) 0.1970(5) 0.0389(18) Uani 1 1 d . . .
H39A H -0.8131 -1.2432 0.1687 0.047 Uiso 1 1 calc R . .
C40 C -0.7912(5) -1.2539(6) 0.4369(5) 0.0382(18) Uani 1 1 d . . .
C41 C -1.1060(5) -1.4215(6) -0.0901(5) 0.0397(19) Uani 1 1 d . . .
C42 C -1.2061(5) -1.4670(6) -0.1434(5) 0.0407(19) Uani 1 1 d . . .
C43 C -1.2496(5) -1.5258(6) -0.1178(5) 0.0425(19) Uani 1 1 d . . .
H43A H -1.2153 -1.5359 -0.0655 0.051 Uiso 1 1 calc R . .
C44 C -1.3446(5) -1.5695(6) -0.1706(5) 0.0427(19) Uani 1 1 d . . .
H44A H -1.3740 -1.6122 -0.1560 0.051 Uiso 1 1 calc R . .
C45 C -1.3967(5) -1.5511(6) -0.2446(5) 0.0416(19) Uani 1 1 d . . .
C46 C -1.3516(5) -1.4932(6) -0.2682(5) 0.0423(19) Uani 1 1 d . . .
H46A H -1.3860 -1.4810 -0.3189 0.051 Uiso 1 1 calc R . .
C47 C -1.2574(5) -1.4526(6) -0.2194(5) 0.0420(19) Uani 1 1 d . . .
H47A H -1.2274 -1.4143 -0.2381 0.050 Uiso 1 1 calc R . .
C48 C -1.4992(5) -1.5967(6) -0.2968(5) 0.0418(19) Uani 1 1 d . . .
C49 C -0.5062(6) -1.3888(6) -0.4565(7) 0.058(2) Uani 1 1 d . . .
H49A H -0.4947 -1.4087 -0.4068 0.087 Uiso 1 1 calc R . .
H49B H -0.4526 -1.3866 -0.4712 0.087 Uiso 1 1 calc R . .
H49C H -0.5616 -1.4315 -0.5112 0.087 Uiso 1 1 calc R . .
C50 C -0.5416(6) -1.2596(6) -0.5212(6) 0.053(2) Uani 1 1 d . . .
H50A H -0.5530 -1.2000 -0.5114 0.079 Uiso 1 1 calc R . .
H50B H -0.5953 -1.3067 -0.5743 0.079 Uiso 1 1 calc R . .
H50C H -0.4863 -1.2612 -0.5330 0.079 Uiso 1 1 calc R . .
C51 C 0.2249(7) -0.9802(7) -0.4832(7) 0.063(3) Uani 1 1 d . . .
H51A H 0.1721 -0.9540 -0.4937 0.095 Uiso 1 1 calc R . .
H51B H 0.2522 -0.9728 -0.4192 0.095 Uiso 1 1 calc R . .
H51C H 0.2036 -1.0448 -0.5247 0.095 Uiso 1 1 calc R . .
C52 C 0.3904(7) -0.9867(6) -0.4805(7) 0.060(2) Uani 1 1 d . . .
H52A H 0.4444 -0.9643 -0.4890 0.090 Uiso 1 1 calc R . .
H52B H 0.3614 -1.0510 -0.5224 0.090 Uiso 1 1 calc R . .
H52C H 0.4101 -0.9794 -0.4168 0.090 Uiso 1 1 calc R . .
C53 C -0.9905(6) -1.2647(7) -0.4587(7) 0.063(3) Uani 1 1 d . . .
H53A H -0.9677 -1.3174 -0.4797 0.094 Uiso 1 1 calc R . .
H53B H -1.0570 -1.2793 -0.4977 0.094 Uiso 1 1 calc R . .
H53C H -0.9805 -1.2486 -0.3947 0.094 Uiso 1 1 calc R . .
C54 C -0.9863(6) -1.0918(7) -0.4276(7) 0.061(3) Uani 1 1 d . . .
H54A H -0.9589 -1.0346 -0.4269 0.092 Uiso 1 1 calc R . .
H54B H -0.9784 -1.0821 -0.3653 0.092 Uiso 1 1 calc R . .
H54C H -1.0526 -1.1133 -0.4694 0.092 Uiso 1 1 calc R . .
C55 C -0.7493(7) -0.9836(8) -0.1689(8) 0.075(3) Uani 1 1 d . . .
H55A H -0.8051 -0.9792 -0.2139 0.113 Uiso 1 1 calc R . .
H55B H -0.7402 -0.9452 -0.1065 0.113 Uiso 1 1 calc R . .
H55C H -0.7566 -1.0468 -0.1768 0.113 Uiso 1 1 calc R . .
C56 C -0.5666(7) -0.9648(7) -0.0991(7) 0.070(3) Uani 1 1 d . . .
H56A H -0.5055 -0.9465 -0.0978 0.104 Uiso 1 1 calc R . .
H56B H -0.5817 -1.0292 -0.1117 0.104 Uiso 1 1 calc R . .
H56C H -0.5654 -0.9287 -0.0394 0.104 Uiso 1 1 calc R . .
C57 C 0.2405(10) -0.5271(9) -0.5630(10) 0.120(6) Uani 1 1 d . . .
H57A H 0.2991 -0.5401 -0.5608 0.179 Uiso 1 1 calc R . .
H57B H 0.2379 -0.4705 -0.5704 0.179 Uiso 1 1 calc R . .
H57C H 0.1885 -0.5769 -0.6152 0.179 Uiso 1 1 calc R . .
C58 C 0.1253(9) -0.4986(8) -0.4985(10) 0.111(5) Uani 1 1 d . . .
H58A H 0.0996 -0.4868 -0.4529 0.167 Uiso 1 1 calc R . .
H58B H 0.0838 -0.5529 -0.5541 0.167 Uiso 1 1 calc R . .
H58C H 0.1310 -0.4465 -0.5140 0.167 Uiso 1 1 calc R . .
C59 C 0.399(3) -0.546(3) -0.101(3) 0.106(11) Uani 0.632(16) 1 d P A 1
H59A H 0.4581 -0.5522 -0.1050 0.158 Uiso 0.632(16) 1 calc PR A 1
H59B H 0.3597 -0.6065 -0.1205 0.158 Uiso 0.632(16) 1 calc PR A 1
H59C H 0.4121 -0.5080 -0.0376 0.158 Uiso 0.632(16) 1 calc PR A 1
C59A C 0.362(5) -0.538(6) -0.086(5) 0.106(18) Uani 0.368(16) 1 d P A 2
H59D H 0.3921 -0.5869 -0.0936 0.158 Uiso 0.368(16) 1 calc PR A 2
H59E H 0.3318 -0.5377 -0.0455 0.158 Uiso 0.368(16) 1 calc PR A 2
H59F H 0.4085 -0.4795 -0.0590 0.158 Uiso 0.368(16) 1 calc PR A 2
C60 C 0.238(2) -0.5015(19) -0.1523(18) 0.104(8) Uani 0.632(16) 1 d P A 1
H60A H 0.1969 -0.4736 -0.1861 0.156 Uiso 0.632(16) 1 calc PR A 1
H60B H 0.2563 -0.4686 -0.0862 0.156 Uiso 0.632(16) 1 calc PR A 1
H60C H 0.2056 -0.5649 -0.1729 0.156 Uiso 0.632(16) 1 calc PR A 1
C60A C 0.255(3) -0.446(3) -0.162(3) 0.104(15) Uani 0.368(16) 1 d P A 2
H60D H 0.1955 -0.4535 -0.2111 0.156 Uiso 0.368(16) 1 calc PR A 2
H60E H 0.3037 -0.4006 -0.1575 0.156 Uiso 0.368(16) 1 calc PR A 2
H60F H 0.2498 -0.4268 -0.1033 0.156 Uiso 0.368(16) 1 calc PR A 2
C61 C 0.4592(10) -0.2719(11) -0.1431(10) 0.121(6) Uani 1 1 d . . .
H61A H 0.4433 -0.2233 -0.1616 0.181 Uiso 1 1 calc R . .
H61B H 0.4523 -0.2627 -0.0864 0.181 Uiso 1 1 calc R . .
H61C H 0.4176 -0.3306 -0.1921 0.181 Uiso 1 1 calc R . .
C62 C 0.5848(11) -0.3559(10) -0.0926(10) 0.122(5) Uani 1 1 d . . .
H62A H 0.6469 -0.3643 -0.0806 0.183 Uiso 1 1 calc R . .
H62B H 0.5380 -0.4115 -0.1421 0.183 Uiso 1 1 calc R . .
H62C H 0.5751 -0.3421 -0.0366 0.183 Uiso 1 1 calc R . .
C63 C 0.4925(11) -0.2708(11) 0.1209(11) 0.105(5) Uani 1 1 d . . .
H63 H 0.5538 -0.2618 0.1639 0.126 Uiso 1 1 calc R . .
C64 C 0.4763(10) -0.1688(10) 0.2480(9) 0.115(5) Uani 1 1 d . . .
H64A H 0.5390 -0.1728 0.2797 0.172 Uiso 1 1 calc R . .
H64B H 0.4354 -0.1911 0.2714 0.172 Uiso 1 1 calc R . .
H64C H 0.4782 -0.1054 0.2591 0.172 Uiso 1 1 calc R . .
C65 C 0.3530(10) -0.2279(10) 0.0906(10) 0.113(5) Uani 1 1 d . . .
H65A H 0.3400 -0.2662 0.0269 0.169 Uiso 1 1 calc R . .
H65B H 0.3498 -0.1667 0.0967 0.169 Uiso 1 1 calc R . .
H65C H 0.3070 -0.2537 0.1070 0.169 Uiso 1 1 calc R . .
S1 S -0.52388(14) -1.27947(16) -0.42095(15) 0.0472(5) Uani 1 1 d . . .
S2 S 0.30911(17) -0.92402(16) -0.50485(15) 0.0502(5) Uani 1 1 d . . .
S3 S -0.93062(15) -1.17331(18) -0.46564(17) 0.0539(6) Uani 1 1 d . . .
S4 S -0.65112(18) -0.94680(17) -0.1861(2) 0.0679(7) Uani 1 1 d . . .
S5 S 0.2325(3) -0.5153(2) -0.4536(3) 0.1079(15) Uani 1 1 d . . .
S6 S 0.3427(6) -0.4965(6) -0.1741(4) 0.102(3) Uani 0.632(16) 1 d P A 1
S6A S 0.2835(10) -0.5534(10) -0.1875(7) 0.102(5) Uani 0.368(16) 1 d P A 2
S7 S 0.5752(4) -0.2703(3) -0.1238(3) 0.1355(18) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O15 Eu1 O13 144.16(19) . .
O15 Eu1 O16 70.5(2) . .
O13 Eu1 O16 143.41(19) . .
O15 Eu1 O11 80.50(19) . 1_554
O13 Eu1 O11 82.30(18) . 1_554
O16 Eu1 O11 98.3(2) . 1_554
O15 Eu1 O2 139.62(19) . .
O13 Eu1 O2 75.06(19) . .
O16 Eu1 O2 75.3(2) . .
O11 Eu1 O2 125.92(16) 1_554 .
O15 Eu1 O8 79.7(2) . .
O13 Eu1 O8 113.0(2) . .
O16 Eu1 O8 77.4(2) . .
O11 Eu1 O8 160.05(19) 1_554 .
O2 Eu1 O8 72.28(17) . .
O15 Eu1 O7 79.0(2) . .
O13 Eu1 O7 83.53(19) . .
O16 Eu1 O7 124.6(2) . .
O11 Eu1 O7 121.24(18) 1_554 .
O2 Eu1 O7 104.32(17) . .
O8 Eu1 O7 51.95(18) . .
O15 Eu1 O1 129.90(19) . .
O13 Eu1 O1 73.85(18) . .
O16 Eu1 O1 71.19(19) . .
O11 Eu1 O1 74.33(16) 1_554 .
O2 Eu1 O1 52.47(15) . .
O8 Eu1 O1 121.16(17) . .
O7 Eu1 O1 150.80(18) . .
O15 Eu1 O12 72.29(19) . 1_554
O13 Eu1 O12 72.47(18) . 1_554
O16 Eu1 O12 134.79(19) . 1_554
O11 Eu1 O12 50.57(16) 1_554 1_554
O2 Eu1 O12 147.50(18) . 1_554
O8 Eu1 O12 119.82(17) . 1_554
O7 Eu1 O12 70.77(17) . 1_554
O1 Eu1 O12 117.73(16) . 1_554
O15 Eu1 C25 75.1(2) . .
O13 Eu1 C25 101.2(2) . .
O16 Eu1 C25 100.1(2) . .
O11 Eu1 C25 142.33(19) 1_554 .
O2 Eu1 C25 90.60(19) . .
O8 Eu1 C25 26.3(2) . .
O7 Eu1 C25 26.0(2) . .
O1 Eu1 C25 143.00(18) . .
O12 Eu1 C25 94.27(19) 1_554 .
O15 Eu1 C1 140.8(2) . .
O13 Eu1 C1 73.2(2) . .
O16 Eu1 C1 70.7(2) . .
O11 Eu1 C1 100.26(19) 1_554 .
O2 Eu1 C1 26.25(19) . .
O8 Eu1 C1 96.61(19) . .
O7 Eu1 C1 128.9(2) . .
O1 Eu1 C1 26.23(18) . .
O12 Eu1 C1 137.3(2) 1_554 .
C25 Eu1 C1 116.8(2) . .
O15 Eu1 C40 75.2(2) . 1_554
O13 Eu1 C40 75.8(2) . 1_554
O16 Eu1 C40 118.3(2) . 1_554
O11 Eu1 C40 25.45(19) 1_554 1_554
O2 Eu1 C40 142.08(19) . 1_554
O8 Eu1 C40 142.64(19) . 1_554
O7 Eu1 C40 95.9(2) . 1_554
O1 Eu1 C40 96.19(18) . 1_554
O12 Eu1 C40 25.12(18) 1_554 1_554
C25 Eu1 C40 118.5(2) . 1_554
C1 Eu1 C40 120.3(2) . 1_554
O17 Eu2 O14 144.1(2) . .
O17 Eu2 O18 72.9(3) . .
O14 Eu2 O18 142.6(3) . .
O17 Eu2 O9 134.0(2) . 1_765
O14 Eu2 O9 73.9(2) . 1_765
O18 Eu2 O9 78.8(3) . 1_765
O17 Eu2 O5 72.3(2) . 1_554
O14 Eu2 O5 73.60(18) . 1_554
O18 Eu2 O5 136.7(3) . 1_554
O9 Eu2 O5 144.5(2) 1_765 1_554
O17 Eu2 O4 128.2(2) . .
O14 Eu2 O4 75.2(2) . .
O18 Eu2 O4 73.0(3) . .
O9 Eu2 O4 73.8(2) 1_765 .
O5 Eu2 O4 110.85(19) 1_554 .
O17 Eu2 O3 84.5(2) . .
O14 Eu2 O3 95.5(2) . .
O18 Eu2 O3 79.9(3) . .
O9 Eu2 O3 125.39(19) 1_765 .
O5 Eu2 O3 71.87(18) 1_554 .
O4 Eu2 O3 51.96(18) . .
O17 Eu2 O6 74.5(2) . 1_554
O14 Eu2 O6 75.88(19) . 1_554
O18 Eu2 O6 136.9(3) . 1_554
O9 Eu2 O6 105.55(19) 1_765 1_554
O5 Eu2 O6 52.33(16) 1_554 1_554
O4 Eu2 O6 150.0(2) . 1_554
O3 Eu2 O6 123.88(17) . 1_554
O17 Eu2 O10 87.0(2) . 1_765
O14 Eu2 O10 103.3(2) . 1_765
O18 Eu2 O10 78.0(3) . 1_765
O9 Eu2 O10 51.60(19) 1_765 1_765
O5 Eu2 O10 124.56(17) 1_554 1_765
O4 Eu2 O10 121.90(18) . 1_765
O3 Eu2 O10 157.9(2) . 1_765
O6 Eu2 O10 72.88(17) 1_554 1_765
O17 Eu2 C24 68.4(2) . 1_554
O14 Eu2 C24 76.0(2) . 1_554
O18 Eu2 C24 141.3(3) . 1_554
O9 Eu2 C24 128.9(2) 1_765 1_554
O5 Eu2 C24 26.40(18) 1_554 1_554
O4 Eu2 C24 134.8(2) . 1_554
O3 Eu2 C24 97.6(2) . 1_554
O6 Eu2 C24 26.26(18) 1_554 1_554
O10 Eu2 C24 98.20(19) 1_765 1_554
O17 Eu2 C16 106.0(2) . .
O14 Eu2 C16 86.3(2) . .
O18 Eu2 C16 73.5(3) . .
O9 Eu2 C16 99.5(2) 1_765 .
O5 Eu2 C16 92.3(2) 1_554 .
O4 Eu2 C16 26.1(2) . .
O3 Eu2 C16 25.9(2) . .
O6 Eu2 C16 143.5(2) 1_554 .
O10 Eu2 C16 143.1(2) 1_765 .
C24 Eu2 C16 118.7(2) 1_554 .
O17 Eu2 C48 111.1(2) . 1_765
O14 Eu2 C48 88.3(2) . 1_765
O18 Eu2 C48 77.2(3) . 1_765
O9 Eu2 C48 25.6(2) 1_765 1_765
O5 Eu2 C48 140.0(2) 1_554 1_765
O4 Eu2 C48 97.9(2) . 1_765
O3 Eu2 C48 146.7(2) . 1_765
O6 Eu2 C48 89.17(19) 1_554 1_765
O10 Eu2 C48 26.0(2) 1_765 1_765
C24 Eu2 C48 115.3(2) 1_554 1_765
C16 Eu2 C48 122.4(2) . 1_765
C1 O1 Eu1 92.8(4) . .
C1 O2 Eu1 93.4(4) . .
C16 O3 Eu2 92.8(5) . .
C16 O4 Eu2 93.1(5) . .
C24 O5 Eu2 93.2(4) . 1_556
C24 O6 Eu2 90.7(4) . 1_556
C25 O7 Eu1 92.9(5) . .
C25 O8 Eu1 93.0(4) . .
C48 O9 Eu2 96.4(5) . 1_345
C48 O10 Eu2 89.6(5) . 1_345
C40 O11 Eu1 97.8(4) . 1_556
C40 O12 Eu1 89.4(4) . 1_556
S1 O13 Eu1 127.4(3) . .
S2 O14 Eu2 132.5(3) . .
S3 O15 Eu1 138.5(4) . .
S4 O16 Eu1 142.5(4) . .
S5 O17 Eu2 136.5(4) . .
S6 O18 S6A 44.3(5) . .
S6 O18 Eu2 158.4(6) . .
S6A O18 Eu2 132.3(7) . .
C9 N1 C8 116.4(6) . .
C9 N2 C17 116.1(6) . .
C17 N3 C8 116.4(6) . .
C30 N4 C33 114.6(6) . .
C30 N5 C41 115.5(6) . .
C33 N6 C41 114.4(6) . .
C63 N7 C65 123.2(12) . .
C63 N7 C64 117.5(11) . .
C65 N7 C64 119.2(12) . .
O1 C1 O2 121.3(7) . .
O1 C1 C2 119.0(6) . .
O2 C1 C2 119.7(7) . .
O1 C1 Eu1 61.0(4) . .
O2 C1 Eu1 60.3(4) . .
C2 C1 Eu1 179.6(7) . .
C3 C2 C7 119.3(7) . .
C3 C2 C1 120.9(7) . .
C7 C2 C1 119.9(7) . .
C2 C3 C4 121.2(7) . .
C2 C3 H3A 119.4 . .
C4 C3 H3A 119.4 . .
C5 C4 C3 120.5(7) . .
C5 C4 H4A 119.7 . .
C3 C4 H4A 119.7 . .
C4 C5 C6 119.3(7) . .
C4 C5 C8 120.8(7) . .
C6 C5 C8 119.9(7) . .
C5 C6 C7 119.8(7) . .
C5 C6 H6A 120.1 . .
C7 C6 H6A 120.1 . .
C2 C7 C6 119.9(7) . .
C2 C7 H7A 120.0 . .
C6 C7 H7A 120.0 . .
N1 C8 N3 123.8(7) . .
N1 C8 C5 118.2(7) . .
N3 C8 C5 118.0(6) . .
N1 C9 N2 124.0(6) . .
N1 C9 C10 119.0(7) . .
N2 C9 C10 117.1(6) . .
C15 C10 C11 119.1(7) . .
C15 C10 C9 120.8(7) . .
C11 C10 C9 120.2(7) . .
C12 C11 C10 119.9(7) . .
C12 C11 H11A 120.0 . .
C10 C11 H11A 120.0 . .
C13 C12 C11 121.0(7) . .
C13 C12 H12A 119.5 . .
C11 C12 H12A 119.5 . .
C12 C13 C14 119.4(7) . .
C12 C13 C16 121.2(7) . .
C14 C13 C16 119.3(7) . .
C15 C14 C13 119.6(7) . .
C15 C14 H14A 120.2 . .
C13 C14 H14A 120.2 . .
C10 C15 C14 120.8(7) . .
C10 C15 H15A 119.6 . .
C14 C15 H15A 119.6 . .
O3 C16 O4 121.8(7) . .
O3 C16 C13 119.5(7) . .
O4 C16 C13 118.7(7) . .
O3 C16 Eu2 61.3(4) . .
O4 C16 Eu2 60.8(4) . .
C13 C16 Eu2 173.2(6) . .
N3 C17 N2 123.3(7) . .
N3 C17 C18 117.9(6) . .
N2 C17 C18 118.8(6) . .
C19 C18 C23 119.4(7) . .
C19 C18 C17 119.9(7) . .
C23 C18 C17 120.7(7) . .
C18 C19 C20 120.2(7) . .
C18 C19 H19A 119.9 . .
C20 C19 H19A 119.9 . .
C19 C20 C21 121.2(7) . .
C19 C20 H20A 119.4 . .
C21 C20 H20A 119.4 . .
C22 C21 C20 117.9(7) . .
C22 C21 C24 122.1(7) . .
C20 C21 C24 120.0(6) . .
C23 C22 C21 120.4(7) . .
C23 C22 H22A 119.8 . .
C21 C22 H22A 119.8 . .
C22 C23 C18 120.9(7) . .
C22 C23 H23A 119.6 . .
C18 C23 H23A 119.6 . .
O6 C24 O5 122.1(7) . .
O6 C24 C21 119.9(6) . .
O5 C24 C21 117.9(6) . .
O6 C24 Eu2 63.0(4) . 1_556
O5 C24 Eu2 60.4(4) . 1_556
C21 C24 Eu2 166.5(6) . 1_556
O7 C25 O8 120.6(7) . .
O7 C25 C26 121.2(7) . .
O8 C25 C26 118.1(7) . .
O7 C25 Eu1 61.1(4) . .
O8 C25 Eu1 60.7(4) . .
C26 C25 Eu1 168.1(6) . .
C27 C26 C32 119.0(7) . .
C27 C26 C25 120.9(7) . .
C32 C26 C25 120.0(7) . .
C26 C27 C28 120.3(7) . .
C26 C27 H27A 119.8 . .
C28 C27 H27A 119.8 . .
C29 C28 C27 120.8(7) . .
C29 C28 H28A 119.6 . .
C27 C28 H28A 119.6 . .
C28 C29 C31 119.4(7) . .
C28 C29 C30 121.1(7) . .
C31 C29 C30 119.5(7) . .
N5 C30 N4 125.6(7) . .
N5 C30 C29 117.7(6) . .
N4 C30 C29 116.8(6) . .
C32 C31 C29 120.6(7) . .
C32 C31 H31A 119.7 . .
C29 C31 H31A 119.7 . .
C31 C32 C26 119.8(7) . .
C31 C32 H32A 120.1 . .
C26 C32 H32A 120.1 . .
N6 C33 N4 126.0(7) . .
N6 C33 C34 117.4(6) . .
N4 C33 C34 116.6(6) . .
C39 C34 C35 119.5(7) . .
C39 C34 C33 119.4(6) . .
C35 C34 C33 121.1(7) . .
C36 C35 C34 119.8(7) . .
C36 C35 H35A 120.1 . .
C34 C35 H35A 120.1 . .
C35 C36 C37 121.4(7) . .
C35 C36 H36A 119.3 . .
C37 C36 H36A 119.3 . .
C38 C37 C36 118.2(7) . .
C38 C37 C40 120.4(7) . .
C36 C37 C40 121.3(7) . .
C39 C38 C37 121.4(7) . .
C39 C38 H38A 119.3 . .
C37 C38 H38A 119.3 . .
C38 C39 C34 119.6(7) . .
C38 C39 H39A 120.2 . .
C34 C39 H39A 120.2 . .
O12 C40 O11 122.2(7) . .
O12 C40 C37 120.2(7) . .
O11 C40 C37 117.7(6) . .
O12 C40 Eu1 65.4(4) . 1_556
O11 C40 Eu1 56.7(4) . 1_556
C37 C40 Eu1 174.3(5) . 1_556
N5 C41 N6 123.9(7) . .
N5 C41 C42 116.7(6) . .
N6 C41 C42 119.3(6) . .
C47 C42 C43 119.7(7) . .
C47 C42 C41 120.3(7) . .
C43 C42 C41 119.9(7) . .
C42 C43 C44 118.9(7) . .
C42 C43 H43A 120.6 . .
C44 C43 H43A 120.6 . .
C43 C44 C45 120.9(7) . .
C43 C44 H44A 119.6 . .
C45 C44 H44A 119.6 . .
C46 C45 C44 118.6(7) . .
C46 C45 C48 122.4(7) . .
C44 C45 C48 119.0(7) . .
C45 C46 C47 121.2(7) . .
C45 C46 H46A 119.4 . .
C47 C46 H46A 119.4 . .
C46 C47 C42 120.5(7) . .
C46 C47 H47A 119.7 . .
C42 C47 H47A 119.7 . .
O9 C48 O10 122.4(7) . .
O9 C48 C45 118.3(7) . .
O10 C48 C45 119.2(7) . .
O9 C48 Eu2 57.9(4) . 1_345
O10 C48 Eu2 64.5(4) . 1_345
C45 C48 Eu2 176.0(6) . 1_345
S1 C49 H49A 109.5 . .
S1 C49 H49B 109.5 . .
H49A C49 H49B 109.5 . .
S1 C49 H49C 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
S1 C50 H50A 109.5 . .
S1 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
S1 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
S2 C51 H51A 109.5 . .
S2 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
S2 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
S2 C52 H52A 109.5 . .
S2 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
S2 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
S3 C53 H53A 109.5 . .
S3 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
S3 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
S3 C54 H54A 109.5 . .
S3 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
S3 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
S4 C55 H55A 109.5 . .
S4 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
S4 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
S4 C56 H56A 109.5 . .
S4 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
S4 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
S5 C57 H57A 109.5 . .
S5 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
S5 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
S5 C58 H58A 109.5 . .
S5 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
S5 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
S6 C59 H59A 109.5 . .
S6 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
S6 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
S6A C59A H59D 109.5 . .
S6A C59A H59E 109.5 . .
H59D C59A H59E 109.5 . .
S6A C59A H59F 109.5 . .
H59D C59A H59F 109.5 . .
H59E C59A H59F 109.5 . .
S6 C60 H60A 109.5 . .
S6 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
S6 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
S6A C60A H60D 109.5 . .
S6A C60A H60E 109.5 . .
H60D C60A H60E 109.5 . .
S6A C60A H60F 109.5 . .
H60D C60A H60F 109.5 . .
H60E C60A H60F 109.5 . .
S7 C61 H61A 109.5 . .
S7 C61 H61B 109.5 . .
H61A C61 H61B 109.5 . .
S7 C61 H61C 109.5 . .
H61A C61 H61C 109.5 . .
H61B C61 H61C 109.5 . .
S7 C62 H62A 109.5 . .
S7 C62 H62B 109.5 . .
H62A C62 H62B 109.5 . .
S7 C62 H62C 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
O20 C63 N7 122.7(15) . .
O20 C63 H63 118.7 . .
N7 C63 H63 118.7 . .
N7 C64 H64A 109.5 . .
N7 C64 H64B 109.5 . .
H64A C64 H64B 109.5 . .
N7 C64 H64C 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
N7 C65 H65A 109.5 . .
N7 C65 H65B 109.5 . .
H65A C65 H65B 109.5 . .
N7 C65 H65C 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
O13 S1 C49 105.4(4) . .
O13 S1 C50 105.4(4) . .
C49 S1 C50 100.3(4) . .
O14 S2 C51 105.7(4) . .
O14 S2 C52 104.3(4) . .
C51 S2 C52 97.3(5) . .
O15 S3 C53 107.7(4) . .
O15 S3 C54 104.9(4) . .
C53 S3 C54 99.6(5) . .
O16 S4 C56 106.4(4) . .
O16 S4 C55 107.8(4) . .
C56 S4 C55 98.1(6) . .
O17 S5 C58 107.3(5) . .
O17 S5 C57 104.0(5) . .
C58 S5 C57 87.7(7) . .
O18 S6 C59 106.5(15) . .
O18 S6 C60 105.8(10) . .
C59 S6 C60 96.7(14) . .
O18 S6A C59A 120(2) . .
O18 S6A C60A 103.2(18) . .
C59A S6A C60A 102(3) . .
O19 S7 C62 106.2(8) . .
O19 S7 C61 105.7(7) . .
C62 S7 C61 100.0(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O15 2.390(5) .
Eu1 O13 2.414(5) .
Eu1 O16 2.429(6) .
Eu1 O11 2.451(5) 1_554
Eu1 O2 2.490(5) .
Eu1 O8 2.495(5) .
Eu1 O7 2.503(5) .
Eu1 O1 2.504(5) .
Eu1 O12 2.642(5) 1_554
Eu1 C25 2.856(7) .
Eu1 C1 2.860(7) .
Eu1 C40 2.904(7) 1_554
Eu2 O17 2.389(6) .
Eu2 O14 2.405(6) .
Eu2 O18 2.411(7) .
Eu2 O9 2.438(5) 1_765
Eu2 O5 2.473(5) 1_554
Eu2 O4 2.490(5) .
Eu2 O3 2.501(5) .
Eu2 O6 2.531(5) 1_554
Eu2 O10 2.580(5) 1_765
Eu2 C24 2.841(8) 1_554
Eu2 C16 2.849(8) .
Eu2 C48 2.858(8) 1_765
O1 C1 1.266(9) .
O2 C1 1.267(9) .
O3 C16 1.246(9) .
O4 C16 1.256(9) .
O5 C24 1.265(8) .
O5 Eu2 2.473(5) 1_556
O6 C24 1.257(9) .
O6 Eu2 2.531(5) 1_556
O7 C25 1.254(9) .
O8 C25 1.266(9) .
O9 C48 1.245(10) .
O9 Eu2 2.438(5) 1_345
O10 C48 1.251(10) .
O10 Eu2 2.580(5) 1_345
O11 C40 1.260(9) .
O11 Eu1 2.451(5) 1_556
O12 C40 1.233(9) .
O12 Eu1 2.642(5) 1_556
O13 S1 1.527(5) .
O14 S2 1.498(6) .
O15 S3 1.488(5) .
O16 S4 1.519(7) .
O17 S5 1.495(7) .
O18 S6 1.453(10) .
O18 S6A 1.572(16) .
O19 S7 1.458(10) .
O20 C63 1.214(17) .
N1 C9 1.326(9) .
N1 C8 1.330(9) .
N2 C9 1.337(9) .
N2 C17 1.346(9) .
N3 C17 1.331(9) .
N3 C8 1.338(9) .
N4 C30 1.335(9) .
N4 C33 1.345(9) .
N5 C30 1.324(9) .
N5 C41 1.350(9) .
N6 C33 1.327(9) .
N6 C41 1.365(10) .
N7 C63 1.298(18) .
N7 C65 1.383(15) .
N7 C64 1.465(16) .
C1 C2 1.487(10) .
C2 C3 1.375(10) .
C2 C7 1.390(11) .
C3 C4 1.379(10) .
C3 H3A 0.9500 .
C4 C5 1.378(10) .
C4 H4A 0.9500 .
C5 C6 1.399(10) .
C5 C8 1.470(10) .
C6 C7 1.403(10) .
C6 H6A 0.9500 .
C7 H7A 0.9500 .
C9 C10 1.488(10) .
C10 C15 1.368(10) .
C10 C11 1.393(11) .
C11 C12 1.374(10) .
C11 H11A 0.9500 .
C12 C13 1.365(11) .
C12 H12A 0.9500 .
C13 C14 1.387(11) .
C13 C16 1.503(10) .
C14 C15 1.386(10) .
C14 H14A 0.9500 .
C15 H15A 0.9500 .
C17 C18 1.478(10) .
C18 C19 1.369(10) .
C18 C23 1.380(10) .
C19 C20 1.372(10) .
C19 H19A 0.9500 .
C20 C21 1.399(10) .
C20 H20A 0.9500 .
C21 C22 1.387(10) .
C21 C24 1.494(10) .
C22 C23 1.375(10) .
C22 H22A 0.9500 .
C23 H23A 0.9500 .
C24 Eu2 2.841(8) 1_556
C25 C26 1.485(10) .
C26 C27 1.376(11) .
C26 C32 1.398(10) .
C27 C28 1.394(10) .
C27 H27A 0.9500 .
C28 C29 1.353(10) .
C28 H28A 0.9500 .
C29 C31 1.391(11) .
C29 C30 1.493(10) .
C31 C32 1.379(10) .
C31 H31A 0.9500 .
C32 H32A 0.9500 .
C33 C34 1.491(10) .
C34 C39 1.393(10) .
C34 C35 1.399(10) .
C35 C36 1.378(10) .
C35 H35A 0.9500 .
C36 C37 1.393(10) .
C36 H36A 0.9500 .
C37 C38 1.389(10) .
C37 C40 1.505(10) .
C38 C39 1.387(10) .
C38 H38A 0.9500 .
C39 H39A 0.9500 .
C40 Eu1 2.904(7) 1_556
C41 C42 1.471(10) .
C42 C47 1.386(11) .
C42 C43 1.400(11) .
C43 C44 1.401(10) .
C43 H43A 0.9500 .
C44 C45 1.401(11) .
C44 H44A 0.9500 .
C45 C46 1.377(11) .
C45 C48 1.503(10) .
C46 C47 1.378(10) .
C46 H46A 0.9500 .
C47 H47A 0.9500 .
C48 Eu2 2.858(8) 1_345
C49 S1 1.770(9) .
C49 H49A 0.9800 .
C49 H49B 0.9800 .
C49 H49C 0.9800 .
C50 S1 1.787(9) .
C50 H50A 0.9800 .
C50 H50B 0.9800 .
C50 H50C 0.9800 .
C51 S2 1.764(10) .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C52 S2 1.773(9) .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 S3 1.744(10) .
C53 H53A 0.9800 .
C53 H53B 0.9800 .
C53 H53C 0.9800 .
C54 S3 1.759(10) .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 S4 1.780(11) .
C55 H55A 0.9800 .
C55 H55B 0.9800 .
C55 H55C 0.9800 .
C56 S4 1.760(11) .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 S5 1.869(17) .
C57 H57A 0.9800 .
C57 H57B 0.9800 .
C57 H57C 0.9800 .
C58 S5 1.713(13) .
C58 H58A 0.9800 .
C58 H58B 0.9800 .
C58 H58C 0.9800 .
C59 S6 1.77(5) .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C59A S6A 1.65(8) .
C59A H59D 0.9800 .
C59A H59E 0.9800 .
C59A H59F 0.9800 .
C60 S6 1.85(3) .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C60A S6A 1.81(5) .
C60A H60D 0.9800 .
C60A H60E 0.9800 .
C60A H60F 0.9800 .
C61 S7 1.765(16) .
C61 H61A 0.9800 .
C61 H61B 0.9800 .
C61 H61C 0.9800 .
C62 S7 1.666(16) .
C62 H62A 0.9800 .
C62 H62B 0.9800 .
C62 H62C 0.9800 .
C63 H63 0.9500 .
C64 H64A 0.9800 .
C64 H64B 0.9800 .
C64 H64C 0.9800 .
C65 H65A 0.9800 .
C65 H65B 0.9800 .
C65 H65C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O15 Eu1 O1 C1 126.2(5) . .
O13 Eu1 O1 C1 -84.7(5) . .
O16 Eu1 O1 C1 84.2(5) . .
O11 Eu1 O1 C1 -171.1(5) 1_554 .
O2 Eu1 O1 C1 -1.4(5) . .
O8 Eu1 O1 C1 22.7(5) . .
O7 Eu1 O1 C1 -44.1(6) . .
O12 Eu1 O1 C1 -144.3(5) 1_554 .
C25 Eu1 O1 C1 2.6(7) . .
C40 Eu1 O1 C1 -157.9(5) 1_554 .
O15 Eu1 O2 C1 -108.8(5) . .
O13 Eu1 O2 C1 82.3(5) . .
O16 Eu1 O2 C1 -75.9(5) . .
O11 Eu1 O2 C1 13.7(5) 1_554 .
O8 Eu1 O2 C1 -157.1(5) . .
O7 Eu1 O2 C1 161.4(5) . .
O1 Eu1 O2 C1 1.4(5) . .
O12 Eu1 O2 C1 84.9(6) 1_554 .
C25 Eu1 O2 C1 -176.2(5) . .
C40 Eu1 O2 C1 41.5(6) 1_554 .
O17 Eu2 O3 C16 -146.4(6) . .
O14 Eu2 O3 C16 69.7(6) . .
O18 Eu2 O3 C16 -72.8(6) . .
O9 Eu2 O3 C16 -4.4(7) 1_765 .
O5 Eu2 O3 C16 140.4(6) 1_554 .
O4 Eu2 O3 C16 3.4(5) . .
O6 Eu2 O3 C16 146.4(5) 1_554 .
O10 Eu2 O3 C16 -78.4(8) 1_765 .
C24 Eu2 O3 C16 146.3(6) 1_554 .
C48 Eu2 O3 C16 -25.6(8) 1_765 .
O17 Eu2 O4 C16 36.3(6) . .
O14 Eu2 O4 C16 -112.8(6) . .
O18 Eu2 O4 C16 87.1(6) . .
O9 Eu2 O4 C16 170.0(6) 1_765 .
O5 Eu2 O4 C16 -47.2(6) 1_554 .
O3 Eu2 O4 C16 -3.4(5) . .
O6 Eu2 O4 C16 -96.8(6) 1_554 .
O10 Eu2 O4 C16 150.6(5) 1_765 .
C24 Eu2 O4 C16 -60.7(6) 1_554 .
C48 Eu2 O4 C16 161.1(6) 1_765 .
O15 Eu1 O7 C25 -78.6(5) . .
O13 Eu1 O7 C25 132.8(5) . .
O16 Eu1 O7 C25 -21.8(6) . .
O11 Eu1 O7 C25 -150.3(5) 1_554 .
O2 Eu1 O7 C25 60.1(5) . .
O8 Eu1 O7 C25 6.9(5) . .
O1 Eu1 O7 C25 93.8(6) . .
O12 Eu1 O7 C25 -153.5(5) 1_554 .
C1 Eu1 O7 C25 70.5(5) . .
C40 Eu1 O7 C25 -152.3(5) 1_554 .
O15 Eu1 O8 C25 77.2(5) . .
O13 Eu1 O8 C25 -67.7(5) . .
O16 Eu1 O8 C25 149.4(5) . .
O11 Eu1 O8 C25 70.1(8) 1_554 .
O2 Eu1 O8 C25 -132.2(5) . .
O7 Eu1 O8 C25 -6.8(5) . .
O1 Eu1 O8 C25 -152.1(5) . .
O12 Eu1 O8 C25 14.6(6) 1_554 .
C1 Eu1 O8 C25 -142.2(5) . .
C40 Eu1 O8 C25 28.9(7) 1_554 .
O15 Eu1 O13 S1 142.6(4) . .
O16 Eu1 O13 S1 -12.8(6) . .
O11 Eu1 O13 S1 80.7(4) 1_554 .
O2 Eu1 O13 S1 -49.7(4) . .
O8 Eu1 O13 S1 -112.7(4) . .
O7 Eu1 O13 S1 -156.5(4) . .
O1 Eu1 O13 S1 4.9(4) . .
O12 Eu1 O13 S1 131.7(4) 1_554 .
C25 Eu1 O13 S1 -137.3(4) . .
C1 Eu1 O13 S1 -22.5(4) . .
C40 Eu1 O13 S1 105.8(4) 1_554 .
O17 Eu2 O14 S2 -23.9(7) . .
O18 Eu2 O14 S2 145.1(5) . .
O9 Eu2 O14 S2 -170.3(5) 1_765 .
O5 Eu2 O14 S2 -4.8(5) 1_554 .
O4 Eu2 O14 S2 112.7(5) . .
O3 Eu2 O14 S2 64.4(5) . .
O6 Eu2 O14 S2 -59.1(5) 1_554 .
O10 Eu2 O14 S2 -127.4(5) 1_765 .
C24 Eu2 O14 S2 -32.0(5) 1_554 .
C16 Eu2 O14 S2 88.7(5) . .
C48 Eu2 O14 S2 -148.7(5) 1_765 .
O13 Eu1 O15 S3 -14.3(8) . .
O16 Eu1 O15 S3 150.4(6) . .
O11 Eu1 O15 S3 48.1(5) 1_554 .
O2 Eu1 O15 S3 -175.7(4) . .
O8 Eu1 O15 S3 -129.5(6) . .
O7 Eu1 O15 S3 -76.5(6) . .
O1 Eu1 O15 S3 108.3(5) . .
O12 Eu1 O15 S3 -3.4(5) 1_554 .
C25 Eu1 O15 S3 -102.9(6) . .
C1 Eu1 O15 S3 142.7(5) . .
C40 Eu1 O15 S3 22.6(5) 1_554 .
O15 Eu1 O16 S4 86.5(6) . .
O13 Eu1 O16 S4 -108.5(6) . .
O11 Eu1 O16 S4 163.3(6) 1_554 .
O2 Eu1 O16 S4 -71.6(6) . .
O8 Eu1 O16 S4 3.1(6) . .
O7 Eu1 O16 S4 25.9(7) . .
O1 Eu1 O16 S4 -126.4(6) . .
O12 Eu1 O16 S4 122.8(6) 1_554 .
C25 Eu1 O16 S4 16.4(6) . .
C1 Eu1 O16 S4 -98.6(6) . .
C40 Eu1 O16 S4 146.7(5) 1_554 .
O14 Eu2 O17 S5 -130.2(6) . .
O18 Eu2 O17 S5 56.8(7) . .
O9 Eu2 O17 S5 2.2(8) 1_765 .
O5 Eu2 O17 S5 -149.4(7) 1_554 .
O4 Eu2 O17 S5 107.7(6) . .
O3 Eu2 O17 S5 138.0(7) . .
O6 Eu2 O17 S5 -94.6(7) 1_554 .
O10 Eu2 O17 S5 -21.6(7) 1_765 .
C24 Eu2 O17 S5 -121.6(7) 1_554 .
C16 Eu2 O17 S5 123.4(6) . .
C48 Eu2 O17 S5 -11.7(7) 1_765 .
O17 Eu2 O18 S6 -167.8(19) . .
O14 Eu2 O18 S6 19(2) . .
O9 Eu2 O18 S6 -24.5(19) 1_765 .
O5 Eu2 O18 S6 154.4(17) 1_554 .
O4 Eu2 O18 S6 51.8(19) . .
O3 Eu2 O18 S6 104.9(19) . .
O6 Eu2 O18 S6 -125.3(18) 1_554 .
O10 Eu2 O18 S6 -77.2(19) 1_765 .
C24 Eu2 O18 S6 -165.4(17) 1_554 .
C16 Eu2 O18 S6 79.1(19) . .
C48 Eu2 O18 S6 -50.7(19) 1_765 .
O17 Eu2 O18 S6A 121.7(10) . .
O14 Eu2 O18 S6A -51.6(11) . .
O9 Eu2 O18 S6A -95.0(10) 1_765 .
O5 Eu2 O18 S6A 83.9(10) 1_554 .
O4 Eu2 O18 S6A -18.7(9) . .
O3 Eu2 O18 S6A 34.4(9) . .
O6 Eu2 O18 S6A 164.1(8) 1_554 .
O10 Eu2 O18 S6A -147.8(10) 1_765 .
C24 Eu2 O18 S6A 124.0(9) 1_554 .
C16 Eu2 O18 S6A 8.6(9) . .
C48 Eu2 O18 S6A -121.2(10) 1_765 .
Eu1 O1 C1 O2 2.6(8) . .
Eu1 O1 C1 C2 -179.6(7) . .
Eu1 O2 C1 O1 -2.6(8) . .
Eu1 O2 C1 C2 179.6(7) . .
O15 Eu1 C1 O1 -78.8(6) . .
O13 Eu1 C1 O1 87.4(5) . .
O16 Eu1 C1 O1 -86.5(5) . .
O11 Eu1 C1 O1 8.7(5) 1_554 .
O2 Eu1 C1 O1 177.5(8) . .
O8 Eu1 C1 O1 -160.6(5) . .
O7 Eu1 C1 O1 154.1(4) . .
O12 Eu1 C1 O1 49.6(6) 1_554 .
C25 Eu1 C1 O1 -178.3(4) . .
C40 Eu1 C1 O1 25.6(6) 1_554 .
O15 Eu1 C1 O2 103.7(5) . .
O13 Eu1 C1 O2 -90.1(5) . .
O16 Eu1 C1 O2 96.0(5) . .
O11 Eu1 C1 O2 -168.8(4) 1_554 .
O8 Eu1 C1 O2 21.9(5) . .
O7 Eu1 C1 O2 -23.3(6) . .
O1 Eu1 C1 O2 -177.5(8) . .
O12 Eu1 C1 O2 -127.9(4) 1_554 .
C25 Eu1 C1 O2 4.2(6) . .
C40 Eu1 C1 O2 -151.9(4) 1_554 .
O15 Eu1 C1 C2 11(100) . .
O13 Eu1 C1 C2 177(100) . .
O16 Eu1 C1 C2 3(100) . .
O11 Eu1 C1 C2 99(100) 1_554 .
O2 Eu1 C1 C2 -93(100) . .
O8 Eu1 C1 C2 -71(100) . .
O7 Eu1 C1 C2 -116(100) . .
O1 Eu1 C1 C2 90(100) . .
O12 Eu1 C1 C2 140(100) 1_554 .
C25 Eu1 C1 C2 -88(100) . .
C40 Eu1 C1 C2 116(100) 1_554 .
O1 C1 C2 C3 -6.5(13) . .
O2 C1 C2 C3 171.4(8) . .
Eu1 C1 C2 C3 -96(100) . .
O1 C1 C2 C7 173.1(8) . .
O2 C1 C2 C7 -9.0(12) . .
Eu1 C1 C2 C7 83(100) . .
C7 C2 C3 C4 1.2(13) . .
C1 C2 C3 C4 -179.2(8) . .
C2 C3 C4 C5 -1.8(13) . .
C3 C4 C5 C6 2.4(13) . .
C3 C4 C5 C8 -178.6(8) . .
C4 C5 C6 C7 -2.4(13) . .
C8 C5 C6 C7 178.6(8) . .
C3 C2 C7 C6 -1.2(13) . .
C1 C2 C7 C6 179.2(8) . .
C5 C6 C7 C2 1.8(13) . .
C9 N1 C8 N3 -0.5(12) . .
C9 N1 C8 C5 179.7(8) . .
C17 N3 C8 N1 1.2(12) . .
C17 N3 C8 C5 -179.0(8) . .
C4 C5 C8 N1 -2.7(13) . .
C6 C5 C8 N1 176.3(8) . .
C4 C5 C8 N3 177.5(8) . .
C6 C5 C8 N3 -3.5(12) . .
C8 N1 C9 N2 -1.3(12) . .
C8 N1 C9 C10 179.3(8) . .
C17 N2 C9 N1 2.1(12) . .
C17 N2 C9 C10 -178.4(7) . .
N1 C9 C10 C15 -174.6(8) . .
N2 C9 C10 C15 5.9(13) . .
N1 C9 C10 C11 5.1(13) . .
N2 C9 C10 C11 -174.4(8) . .
C15 C10 C11 C12 1.3(14) . .
C9 C10 C11 C12 -178.4(8) . .
C10 C11 C12 C13 0.1(14) . .
C11 C12 C13 C14 -0.5(14) . .
C11 C12 C13 C16 178.9(8) . .
C12 C13 C14 C15 -0.6(14) . .
C16 C13 C14 C15 180.0(8) . .
C11 C10 C15 C14 -2.4(14) . .
C9 C10 C15 C14 177.3(8) . .
C13 C14 C15 C10 2.1(14) . .
Eu2 O3 C16 O4 -6.2(10) . .
Eu2 O3 C16 C13 172.3(7) . .
Eu2 O4 C16 O3 6.3(10) . .
Eu2 O4 C16 C13 -172.2(7) . .
C12 C13 C16 O3 13.2(14) . .
C14 C13 C16 O3 -167.4(9) . .
C12 C13 C16 O4 -168.3(9) . .
C14 C13 C16 O4 11.1(13) . .
C12 C13 C16 Eu2 108(5) . .
C14 C13 C16 Eu2 -73(5) . .
O17 Eu2 C16 O3 35.0(6) . .
O14 Eu2 C16 O3 -110.7(6) . .
O18 Eu2 C16 O3 101.1(6) . .
O9 Eu2 C16 O3 176.3(5) 1_765 .
O5 Eu2 C16 O3 -37.3(6) 1_554 .
O4 Eu2 C16 O3 -173.9(9) . .
O6 Eu2 C16 O3 -50.5(7) 1_554 .
O10 Eu2 C16 O3 142.0(5) 1_765 .
C24 Eu2 C16 O3 -38.8(6) 1_554 .
C48 Eu2 C16 O3 163.7(5) 1_765 .
O17 Eu2 C16 O4 -151.1(5) . .
O14 Eu2 C16 O4 63.2(5) . .
O18 Eu2 C16 O4 -84.9(6) . .
O9 Eu2 C16 O4 -9.7(6) 1_765 .
O5 Eu2 C16 O4 136.6(5) 1_554 .
O3 Eu2 C16 O4 173.9(9) . .
O6 Eu2 C16 O4 123.4(5) 1_554 .
O10 Eu2 C16 O4 -44.1(7) 1_765 .
C24 Eu2 C16 O4 135.1(5) 1_554 .
C48 Eu2 C16 O4 -22.4(6) 1_765 .
O17 Eu2 C16 C13 -64(5) . .
O14 Eu2 C16 C13 151(5) . .
O18 Eu2 C16 C13 3(5) . .
O9 Eu2 C16 C13 78(5) 1_765 .
O5 Eu2 C16 C13 -136(5) 1_554 .
O4 Eu2 C16 C13 88(5) . .
O3 Eu2 C16 C13 -99(5) . .
O6 Eu2 C16 C13 -149(5) 1_554 .
O10 Eu2 C16 C13 43(5) 1_765 .
C24 Eu2 C16 C13 -137(5) 1_554 .
C48 Eu2 C16 C13 65(5) 1_765 .
C8 N3 C17 N2 -0.3(12) . .
C8 N3 C17 C18 176.9(8) . .
C9 N2 C17 N3 -1.2(12) . .
C9 N2 C17 C18 -178.4(8) . .
N3 C17 C18 C19 1.1(13) . .
N2 C17 C18 C19 178.5(8) . .
N3 C17 C18 C23 179.3(8) . .
N2 C17 C18 C23 -3.3(13) . .
C23 C18 C19 C20 3.9(13) . .
C17 C18 C19 C20 -177.9(8) . .
C18 C19 C20 C21 -1.9(13) . .
C19 C20 C21 C22 -0.6(13) . .
C19 C20 C21 C24 177.5(8) . .
C20 C21 C22 C23 0.9(13) . .
C24 C21 C22 C23 -177.1(8) . .
C21 C22 C23 C18 1.1(13) . .
C19 C18 C23 C22 -3.5(13) . .
C17 C18 C23 C22 178.3(8) . .
Eu2 O6 C24 O5 -12.8(8) 1_556 .
Eu2 O6 C24 C21 164.9(7) 1_556 .
Eu2 O5 C24 O6 13.1(9) 1_556 .
Eu2 O5 C24 C21 -164.7(7) 1_556 .
C22 C21 C24 O6 5.0(13) . .
C20 C21 C24 O6 -172.9(8) . .
C22 C21 C24 O5 -177.2(8) . .
C20 C21 C24 O5 4.9(12) . .
C22 C21 C24 Eu2 104(2) . 1_556
C20 C21 C24 Eu2 -74(2) . 1_556
Eu1 O7 C25 O8 -12.5(8) . .
Eu1 O7 C25 C26 166.5(7) . .
Eu1 O8 C25 O7 12.5(8) . .
Eu1 O8 C25 C26 -166.5(7) . .
O15 Eu1 C25 O7 95.4(5) . .
O13 Eu1 C25 O7 -48.0(5) . .
O16 Eu1 C25 O7 161.9(5) . .
O11 Eu1 C25 O7 44.0(7) 1_554 .
O2 Eu1 C25 O7 -122.9(5) . .
O8 Eu1 C25 O7 -167.7(8) . .
O1 Eu1 C25 O7 -126.0(5) . .
O12 Eu1 C25 O7 25.0(5) 1_554 .
C1 Eu1 C25 O7 -124.7(5) . .
C40 Eu1 C25 O7 31.8(6) 1_554 .
O15 Eu1 C25 O8 -96.9(5) . .
O13 Eu1 C25 O8 119.7(5) . .
O16 Eu1 C25 O8 -30.3(5) . .
O11 Eu1 C25 O8 -148.3(4) 1_554 .
O2 Eu1 C25 O8 44.9(5) . .
O7 Eu1 C25 O8 167.7(8) . .
O1 Eu1 C25 O8 41.7(7) . .
O12 Eu1 C25 O8 -167.3(5) 1_554 .
C1 Eu1 C25 O8 43.0(6) . .
C40 Eu1 C25 O8 -160.5(5) 1_554 .
O15 Eu1 C25 C26 -9(3) . .
O13 Eu1 C25 C26 -152(3) . .
O16 Eu1 C25 C26 57(3) . .
O11 Eu1 C25 C26 -61(3) 1_554 .
O2 Eu1 C25 C26 133(3) . .
O8 Eu1 C25 C26 88(3) . .
O7 Eu1 C25 C26 -104(3) . .
O1 Eu1 C25 C26 130(3) . .
O12 Eu1 C25 C26 -79(3) 1_554 .
C1 Eu1 C25 C26 131(3) . .
C40 Eu1 C25 C26 -73(3) 1_554 .
O7 C25 C26 C27 168.4(8) . .
O8 C25 C26 C27 -12.6(12) . .
Eu1 C25 C26 C27 -94(3) . .
O7 C25 C26 C32 -13.7(13) . .
O8 C25 C26 C32 165.3(8) . .
Eu1 C25 C26 C32 84(3) . .
C32 C26 C27 C28 2.7(13) . .
C25 C26 C27 C28 -179.4(8) . .
C26 C27 C28 C29 -2.3(13) . .
C27 C28 C29 C31 -0.3(13) . .
C27 C28 C29 C30 178.9(8) . .
C41 N5 C30 N4 -2.8(13) . .
C41 N5 C30 C29 176.3(8) . .
C33 N4 C30 N5 3.0(13) . .
C33 N4 C30 C29 -176.1(7) . .
C28 C29 C30 N5 155.2(8) . .
C31 C29 C30 N5 -25.7(12) . .
C28 C29 C30 N4 -25.6(12) . .
C31 C29 C30 N4 153.5(8) . .
C28 C29 C31 C32 2.5(13) . .
C30 C29 C31 C32 -176.7(8) . .
C29 C31 C32 C26 -2.1(13) . .
C27 C26 C32 C31 -0.4(13) . .
C25 C26 C32 C31 -178.4(8) . .
C41 N6 C33 N4 -2.2(13) . .
C41 N6 C33 C34 176.4(8) . .
C30 N4 C33 N6 -0.3(13) . .
C30 N4 C33 C34 -178.9(7) . .
N6 C33 C34 C39 -166.2(8) . .
N4 C33 C34 C39 12.5(12) . .
N6 C33 C34 C35 13.2(13) . .
N4 C33 C34 C35 -168.1(8) . .
C39 C34 C35 C36 2.1(13) . .
C33 C34 C35 C36 -177.4(8) . .
C34 C35 C36 C37 0.1(13) . .
C35 C36 C37 C38 -0.5(13) . .
C35 C36 C37 C40 175.8(8) . .
C36 C37 C38 C39 -1.2(13) . .
C40 C37 C38 C39 -177.5(8) . .
C37 C38 C39 C34 3.3(13) . .
C35 C34 C39 C38 -3.7(13) . .
C33 C34 C39 C38 175.7(8) . .
Eu1 O12 C40 O11 -1.2(8) 1_556 .
Eu1 O12 C40 C37 179.1(7) 1_556 .
Eu1 O11 C40 O12 1.3(9) 1_556 .
Eu1 O11 C40 C37 -179.0(6) 1_556 .
C38 C37 C40 O12 -167.4(8) . .
C36 C37 C40 O12 16.4(13) . .
C38 C37 C40 O11 13.0(12) . .
C36 C37 C40 O11 -163.2(8) . .
C38 C37 C40 Eu1 5(7) . 1_556
C36 C37 C40 Eu1 -172(6) . 1_556
C30 N5 C41 N6 -0.1(13) . .
C30 N5 C41 C42 177.0(8) . .
C33 N6 C41 N5 2.4(13) . .
C33 N6 C41 C42 -174.6(8) . .
N5 C41 C42 C47 -22.1(13) . .
N6 C41 C42 C47 155.2(8) . .
N5 C41 C42 C43 157.4(8) . .
N6 C41 C42 C43 -25.4(13) . .
C47 C42 C43 C44 0.6(13) . .
C41 C42 C43 C44 -178.9(8) . .
C42 C43 C44 C45 -3.7(13) . .
C43 C44 C45 C46 3.9(13) . .
C43 C44 C45 C48 -177.4(8) . .
C44 C45 C46 C47 -1.1(13) . .
C48 C45 C46 C47 -179.7(8) . .
C45 C46 C47 C42 -2.0(14) . .
C43 C42 C47 C46 2.2(13) . .
C41 C42 C47 C46 -178.3(8) . .
Eu2 O9 C48 O10 0.5(10) 1_345 .
Eu2 O9 C48 C45 -178.3(7) 1_345 .
Eu2 O10 C48 O9 -0.5(9) 1_345 .
Eu2 O10 C48 C45 178.3(7) 1_345 .
C46 C45 C48 O9 172.1(8) . .
C44 C45 C48 O9 -6.5(13) . .
C46 C45 C48 O10 -6.8(13) . .
C44 C45 C48 O10 174.6(8) . .
C46 C45 C48 Eu2 151(8) . 1_345
C44 C45 C48 Eu2 -28(9) . 1_345
C65 N7 C63 O20 -4(3) . .
C64 N7 C63 O20 172.2(16) . .
Eu1 O13 S1 C49 173.6(4) . .
Eu1 O13 S1 C50 -80.8(5) . .
Eu2 O14 S2 C51 -81.8(6) . .
Eu2 O14 S2 C52 176.2(5) . .
Eu1 O15 S3 C53 82.2(7) . .
Eu1 O15 S3 C54 -172.3(6) . .
Eu1 O16 S4 C56 54.1(7) . .
Eu1 O16 S4 C55 -50.3(8) . .
Eu2 O17 S5 C58 -163.1(7) . .
Eu2 O17 S5 C57 104.9(7) . .
S6A O18 S6 C59 70.7(15) . .
Eu2 O18 S6 C59 -21(2) . .
S6A O18 S6 C60 -31.4(12) . .
Eu2 O18 S6 C60 -123.0(19) . .
S6 O18 S6A C59A -55(4) . .
Eu2 O18 S6A C59A 95(4) . .
S6 O18 S6A C60A 57.0(17) . .
Eu2 O18 S6A C60A -152.9(17) . .
