#------------------------------------------------------------------------------
#$Date: 2016-11-08 21:35:33 +0200 (Tue, 08 Nov 2016) $
#$Revision: 188109 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/65/7226564.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226564
loop_
_publ_author_name
'Qiang, Dajiao'
'Yang, Xiaogang'
'Deng, Xuebin'
'Sun, Hao-Ling'
_publ_section_title
;
 Two novel eight-connected self-penetrating porous lanthanide--organic
 frameworks: structures, luminescence, and gas adsorption properties
;
_journal_issue                   42
_journal_name_full               CrystEngComm
_journal_page_first              8159
_journal_paper_doi               10.1039/C6CE01527A
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C66 H36 Eu2 N6 O15'
_chemical_formula_weight         1456.93
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yac'
_space_group_name_H-M_alt        'P 1 2/n 1'
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-04-26 deposited with the CCDC.
2016-09-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 103.153(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.742(6)
_cell_length_b                   10.981(5)
_cell_length_c                   23.785(10)
_cell_measurement_reflns_used    5099
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.08
_cell_measurement_theta_min      2.40
_cell_volume                     3495(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0512
_diffrn_reflns_av_unetI/netI     0.0628
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            23632
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.244
_diffrn_reflns_theta_min         1.758
_exptl_absorpt_coefficient_mu    1.842
_exptl_absorpt_correction_T_max  0.75
_exptl_absorpt_correction_T_min  0.64
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.384
_exptl_crystal_description       block
_exptl_crystal_F_000             1440
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.080
_refine_diff_density_max         1.750
_refine_diff_density_min         -0.808
_refine_diff_density_rms         0.121
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     402
_refine_ls_number_reflns         8593
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0605
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0367P)²+5.3872P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0908
_refine_ls_wR_factor_ref         0.0968
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6724
_reflns_number_total             8593
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce01527a2.cif
_cod_data_source_block           140514c_0m_sq_s
_cod_depositor_comments
'Adding full bibliography for 7226564--7226565.cif.'
_cod_database_code               7226564
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.526
_shelx_estimated_absorpt_t_max   0.867
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
C1 C 0.4054(3) 0.5779(4) 1.02613(18) 0.0256(9) Uani 1 1 d . . .
H1 H 0.4747 0.5925 1.0298 0.031 Uiso 1 1 calc R U .
C2 C 0.3771(3) 0.4677(4) 1.04732(19) 0.0271(9) Uani 1 1 d . . .
H2 H 0.4256 0.4090 1.0645 0.033 Uiso 1 1 calc R U .
C3 C 0.2770(3) 0.4470(4) 1.04245(18) 0.0249(9) Uani 1 1 d . . .
H3 H 0.2553 0.3735 1.0568 0.030 Uiso 1 1 calc R U .
C4 C 0.2068(3) 0.5342(3) 1.01631(17) 0.0207(8) Uani 1 1 d . . .
C5 C 0.0992(3) 0.5152(4) 1.00796(17) 0.0200(8) Uani 1 1 d . . .
C6 C 0.0309(3) 0.6026(4) 0.97925(17) 0.0228(9) Uani 1 1 d . . .
C7 C 0.0679(3) 0.7133(4) 0.95680(18) 0.0249(9) Uani 1 1 d . . .
C8 C 0.0026(3) 0.8020(4) 0.9267(2) 0.0341(11) Uani 1 1 d . . .
H8 H -0.0676 0.7931 0.9214 0.041 Uiso 1 1 calc R U .
C9 C 0.0424(3) 0.9021(4) 0.9051(2) 0.0364(11) Uani 1 1 d . . .
H9 H 0.0001 0.9636 0.8845 0.044 Uiso 1 1 calc R U .
C10 C 0.1465(3) 0.9114(4) 0.91391(19) 0.0311(10) Uani 1 1 d . . .
H10 H 0.1730 0.9800 0.8982 0.037 Uiso 1 1 calc R U .
C11 C 0.2419(3) 0.6413(3) 0.99532(16) 0.0209(8) Uani 1 1 d . . .
C12 C 0.1714(3) 0.7315(3) 0.96453(17) 0.0211(8) Uani 1 1 d . . .
C13 C 0.3918(3) 0.7571(4) 0.85909(18) 0.0253(9) Uani 1 1 d . . .
C14 C 0.3995(3) 0.6953(4) 0.80405(18) 0.0276(10) Uani 1 1 d . . .
C15 C 0.3739(5) 0.7546(5) 0.7517(2) 0.0498(15) Uani 1 1 d . . .
H15 H 0.3486 0.8353 0.7501 0.060 Uiso 1 1 calc R U .
C16 C 0.3848(5) 0.6983(5) 0.7015(2) 0.0533(16) Uani 1 1 d . . .
H16 H 0.3700 0.7410 0.6659 0.064 Uiso 1 1 calc R U .
C17 C 0.4174(4) 0.5790(4) 0.70408(19) 0.0332(10) Uani 1 1 d . . .
C18 C 0.4445(4) 0.5178(4) 0.75577(19) 0.0310(10) Uani 1 1 d . . .
H18 H 0.4688 0.4366 0.7571 0.037 Uiso 1 1 calc R U .
C19 C 0.4358(4) 0.5763(4) 0.80554(19) 0.0290(10) Uani 1 1 d . . .
H19 H 0.4549 0.5351 0.8415 0.035 Uiso 1 1 calc R U .
C20 C 0.3563(3) 0.4366(4) 0.63011(18) 0.0287(10) Uani 1 1 d . . .
C21 C 0.2566(4) 0.4518(4) 0.6322(2) 0.0338(11) Uani 1 1 d . . .
H21 H 0.2372 0.5200 0.6517 0.041 Uiso 1 1 calc R U .
C22 C 0.1861(4) 0.3679(4) 0.60607(19) 0.0351(11) Uani 1 1 d . . .
H22 H 0.1179 0.3804 0.6065 0.042 Uiso 1 1 calc R U .
C23 C 0.2135(3) 0.2647(4) 0.57894(17) 0.0239(9) Uani 1 1 d . . .
C24 C 0.3146(3) 0.2515(4) 0.57722(19) 0.0291(10) Uani 1 1 d . . .
H24 H 0.3345 0.1829 0.5583 0.035 Uiso 1 1 calc R U .
C25 C 0.3854(4) 0.3361(4) 0.60248(19) 0.0290(10) Uani 1 1 d . . .
H25 H 0.4534 0.3258 0.6010 0.035 Uiso 1 1 calc R U .
C26 C 0.1368(3) 0.1719(4) 0.55311(17) 0.0238(9) Uani 1 1 d . . .
C27 C 0.6151(3) 1.0064(4) 0.92525(17) 0.0240(9) Uani 1 1 d . . .
C28 C 0.6537(3) 0.9403(4) 0.88021(19) 0.0290(10) Uani 1 1 d . . .
C29 C 0.6260(5) 0.8243(5) 0.8659(3) 0.0554(16) Uani 1 1 d . . .
H29 H 0.5835 0.7824 0.8858 0.067 Uiso 1 1 calc R U .
C30 C 0.6602(6) 0.7651(6) 0.8211(3) 0.077(2) Uani 1 1 d . . .
H30 H 0.6396 0.6841 0.8105 0.093 Uiso 1 1 calc R U .
C31 C 0.7218(5) 0.8232(5) 0.7939(3) 0.0520(16) Uani 1 1 d . . .
C32 C 0.7620(5) 0.9334(7) 0.8143(3) 0.070(2) Uani 1 1 d . . .
H32 H 0.8117 0.9716 0.7984 0.084 Uiso 1 1 calc R U .
C33 C 0.7283(5) 0.9865(7) 0.8581(3) 0.075(2) Uani 1 1 d . . .
H33 H 0.7590 1.0602 0.8740 0.090 Uiso 1 1 calc R U .
Eu1 Eu 0.40336(2) 0.86813(2) 0.96793(2) 0.02039(7) Uani 1 1 d . . .
N1 N 0.3410(3) 0.6639(3) 1.00111(14) 0.0217(7) Uani 1 1 d . . .
N2 N 0.2103(3) 0.8302(3) 0.94295(14) 0.0232(7) Uani 1 1 d . . .
N3 N 0.0681(3) 0.4125(3) 1.02939(14) 0.0234(7) Uani 1 1 d . . .
O1 O 0.4289(3) 0.7038(3) 0.90619(12) 0.0324(7) Uani 1 1 d . . .
O2 O 0.3511(2) 0.8601(3) 0.85869(12) 0.0315(7) Uani 1 1 d . . .
O3 O 0.4300(2) 0.5205(3) 0.65362(13) 0.0361(8) Uani 1 1 d . . .
O4 O 0.0481(2) 0.2082(3) 0.53303(12) 0.0270(7) Uani 1 1 d . . .
O5 O 0.1664(2) 0.0630(2) 0.55350(13) 0.0258(6) Uani 1 1 d . . .
O6 O 0.5394(2) 0.9666(3) 0.94219(12) 0.0287(7) Uani 1 1 d . . .
O7 O 0.6610(2) 1.1001(3) 0.94672(12) 0.0304(7) Uani 1 1 d . . .
O8 O 0.7500 0.7576(5) 0.7500 0.069(2) Uani 1 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 124.1(4) . .
N1 C1 H1 117.9 . .
C2 C1 H1 117.9 . .
C3 C2 C1 117.9(4) . .
C3 C2 H2 121.0 . .
C1 C2 H2 121.0 . .
C2 C3 C4 120.0(4) . .
C2 C3 H3 120.0 . .
C4 C3 H3 120.0 . .
C3 C4 C11 118.2(4) . .
C3 C4 C5 122.4(4) . .
C11 C4 C5 119.3(4) . .
N3 C5 C6 121.4(4) . .
N3 C5 C4 117.8(4) . .
C6 C5 C4 120.8(3) . .
N3 C6 C5 122.1(4) 3_567 .
N3 C6 C7 118.2(4) 3_567 .
C5 C6 C7 119.6(4) . .
C8 C7 C12 118.6(4) . .
C8 C7 C6 121.7(4) . .
C12 C7 C6 119.7(4) . .
C9 C8 C7 118.8(4) . .
C9 C8 H8 120.6 . .
C7 C8 H8 120.6 . .
C8 C9 C10 118.7(4) . .
C8 C9 H9 120.7 . .
C10 C9 H9 120.7 . .
N2 C10 C9 124.0(4) . .
N2 C10 H10 118.0 . .
C9 C10 H10 118.0 . .
N1 C11 C4 122.3(4) . .
N1 C11 C12 117.5(3) . .
C4 C11 C12 120.2(3) . .
N2 C12 C7 122.4(4) . .
N2 C12 C11 117.2(3) . .
C7 C12 C11 120.3(3) . .
O2 C13 O1 120.7(4) . .
O2 C13 C14 121.2(4) . .
O1 C13 C14 118.0(4) . .
O2 C13 Eu1 63.5(2) . .
O1 C13 Eu1 57.5(2) . .
C14 C13 Eu1 172.8(3) . .
C15 C14 C19 118.8(4) . .
C15 C14 C13 121.4(4) . .
C19 C14 C13 119.8(4) . .
C14 C15 C16 120.9(5) . .
C14 C15 H15 119.6 . .
C16 C15 H15 119.6 . .
C17 C16 C15 119.0(5) . .
C17 C16 H16 120.5 . .
C15 C16 H16 120.5 . .
C18 C17 C16 121.4(4) . .
C18 C17 O3 118.6(4) . .
C16 C17 O3 119.9(4) . .
C19 C18 C17 118.8(4) . .
C19 C18 H18 120.6 . .
C17 C18 H18 120.6 . .
C18 C19 C14 121.0(4) . .
C18 C19 H19 119.5 . .
C14 C19 H19 119.5 . .
C25 C20 O3 117.0(4) . .
C25 C20 C21 120.3(4) . .
O3 C20 C21 122.7(4) . .
C22 C21 C20 120.0(4) . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
C21 C22 C23 121.0(4) . .
C21 C22 H22 119.5 . .
C23 C22 H22 119.5 . .
C22 C23 C24 117.9(4) . .
C22 C23 C26 120.3(4) . .
C24 C23 C26 121.8(4) . .
C25 C24 C23 121.4(4) . .
C25 C24 H24 119.3 . .
C23 C24 H24 119.3 . .
C24 C25 C20 119.3(4) . .
C24 C25 H25 120.3 . .
C20 C25 H25 120.3 . .
O5 C26 O4 125.5(4) . .
O5 C26 C23 116.6(4) . .
O4 C26 C23 117.9(3) . .
O7 C27 O6 121.6(4) . .
O7 C27 C28 117.8(4) . .
O6 C27 C28 120.7(4) . .
O7 C27 Eu1 53.1(2) . 3_677
O6 C27 Eu1 69.6(2) . 3_677
C28 C27 Eu1 164.2(3) . 3_677
C29 C28 C33 116.8(5) . .
C29 C28 C27 121.1(4) . .
C33 C28 C27 121.5(4) . .
C28 C29 C30 120.0(5) . .
C28 C29 H29 120.0 . .
C30 C29 H29 120.0 . .
C31 C30 C29 120.0(6) . .
C31 C30 H30 120.0 . .
C29 C30 H30 120.0 . .
C30 C31 C32 119.8(5) . .
C30 C31 O8 115.5(5) . .
C32 C31 O8 124.2(5) . .
C33 C32 C31 117.9(6) . .
C33 C32 H32 121.0 . .
C31 C32 H32 121.0 . .
C28 C33 C32 123.7(6) . .
C28 C33 H33 118.1 . .
C32 C33 H33 118.1 . .
O5 Eu1 O6 80.47(11) 2_566 .
O5 Eu1 O4 134.48(10) 2_566 4_666
O6 Eu1 O4 74.66(11) . 4_666
O5 Eu1 O1 131.29(10) 2_566 .
O6 Eu1 O1 87.18(11) . .
O4 Eu1 O1 85.20(11) 4_666 .
O5 Eu1 O7 80.92(11) 2_566 3_677
O6 Eu1 O7 127.96(10) . 3_677
O4 Eu1 O7 85.15(11) 4_666 3_677
O1 Eu1 O7 138.94(10) . 3_677
O5 Eu1 O2 78.65(10) 2_566 .
O6 Eu1 O2 78.83(10) . .
O4 Eu1 O2 130.92(10) 4_666 .
O1 Eu1 O2 52.70(10) . .
O7 Eu1 O2 142.53(11) 3_677 .
O5 Eu1 N1 135.06(11) 2_566 .
O6 Eu1 N1 144.46(11) . .
O4 Eu1 N1 77.40(10) 4_666 .
O1 Eu1 N1 68.89(11) . .
O7 Eu1 N1 70.06(10) 3_677 .
O2 Eu1 N1 104.25(10) . .
O5 Eu1 N2 75.75(10) 2_566 .
O6 Eu1 N2 146.81(11) . .
O4 Eu1 N2 138.27(10) 4_666 .
O1 Eu1 N2 91.34(11) . .
O7 Eu1 N2 70.61(11) 3_677 .
O2 Eu1 N2 74.08(11) . .
N1 Eu1 N2 62.76(11) . .
O5 Eu1 O6 66.59(10) 2_566 3_677
O6 Eu1 O6 78.33(10) . 3_677
O4 Eu1 O6 71.37(10) 4_666 3_677
O1 Eu1 O6 154.94(10) . 3_677
O7 Eu1 O6 49.69(9) 3_677 3_677
O2 Eu1 O6 140.91(9) . 3_677
N1 Eu1 O6 112.77(10) . 3_677
N2 Eu1 O6 111.95(10) . 3_677
O5 Eu1 C13 104.96(11) 2_566 .
O6 Eu1 C13 80.96(11) . .
O4 Eu1 C13 107.93(12) 4_666 .
O1 Eu1 C13 26.33(11) . .
O7 Eu1 C13 150.99(11) 3_677 .
O2 Eu1 C13 26.42(11) . .
N1 Eu1 C13 87.25(11) . .
N2 Eu1 C13 83.17(12) . .
O6 Eu1 C13 158.66(10) 3_677 .
O5 Eu1 C27 69.60(11) 2_566 3_677
O6 Eu1 C27 103.77(11) . 3_677
O4 Eu1 C27 80.04(11) 4_666 3_677
O1 Eu1 C27 158.44(11) . 3_677
O7 Eu1 C27 24.50(10) 3_677 3_677
O2 Eu1 C27 147.02(11) . 3_677
N1 Eu1 C27 92.45(11) . 3_677
N2 Eu1 C27 89.33(11) . 3_677
O6 Eu1 C27 25.51(9) 3_677 3_677
C13 Eu1 C27 171.71(12) . 3_677
O5 Eu1 Eu1 68.01(7) 2_566 3_677
O6 Eu1 Eu1 42.98(7) . 3_677
O4 Eu1 Eu1 67.75(7) 4_666 3_677
O1 Eu1 Eu1 126.98(8) . 3_677
O7 Eu1 Eu1 85.01(7) 3_677 3_677
O2 Eu1 Eu1 115.20(7) . 3_677
N1 Eu1 Eu1 138.61(8) . 3_677
N2 Eu1 Eu1 138.99(8) . 3_677
O6 Eu1 Eu1 35.35(6) 3_677 3_677
C13 Eu1 Eu1 123.75(9) . 3_677
C27 Eu1 Eu1 60.81(8) 3_677 3_677
C1 N1 C11 117.5(3) . .
C1 N1 Eu1 121.1(3) . .
C11 N1 Eu1 121.4(3) . .
C10 N2 C12 117.5(4) . .
C10 N2 Eu1 121.7(3) . .
C12 N2 Eu1 120.4(3) . .
C6 N3 C5 116.4(4) 3_567 .
C13 O1 Eu1 96.2(3) . .
C13 O2 Eu1 90.1(2) . .
C20 O3 C17 115.2(4) . .
C26 O4 Eu1 136.4(3) . 4_565
C26 O5 Eu1 138.2(3) . 2_546
C27 O6 Eu1 172.4(3) . .
C27 O6 Eu1 84.9(2) . 3_677
Eu1 O6 Eu1 101.67(10) . 3_677
C27 O7 Eu1 102.4(3) . 3_677
C31 O8 C31 117.8(5) . 2_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.337(5) .
C1 C2 1.400(6) .
C1 H1 0.9500 .
C2 C3 1.373(6) .
C2 H2 0.9500 .
C3 C4 1.400(6) .
C3 H3 0.9500 .
C4 C11 1.405(5) .
C4 C5 1.461(5) .
C5 N3 1.346(5) .
C5 C6 1.407(6) .
C6 N3 1.340(5) 3_567
C6 C7 1.465(5) .
C7 C8 1.404(6) .
C7 C12 1.406(6) .
C8 C9 1.380(6) .
C8 H8 0.9500 .
C9 C10 1.401(6) .
C9 H9 0.9500 .
C10 N2 1.329(6) .
C10 H10 0.9500 .
C11 N1 1.360(5) .
C11 C12 1.461(6) .
C12 N2 1.359(5) .
C13 O2 1.261(5) .
C13 O1 1.264(5) .
C13 C14 1.499(6) .
C13 Eu1 2.833(4) .
C14 C15 1.377(6) .
C14 C19 1.397(6) .
C15 C16 1.382(7) .
C15 H15 0.9500 .
C16 C17 1.382(7) .
C16 H16 0.9500 .
C17 C18 1.376(6) .
C17 O3 1.406(5) .
C18 C19 1.376(6) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C25 1.389(6) .
C20 O3 1.390(6) .
C20 C21 1.392(7) .
C21 C22 1.378(7) .
C21 H21 0.9500 .
C22 C23 1.397(6) .
C22 H22 0.9500 .
C23 C24 1.407(6) .
C23 C26 1.495(6) .
C24 C25 1.380(6) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 O5 1.262(5) .
C26 O4 1.267(5) .
C27 O7 1.253(5) .
C27 O6 1.276(5) .
C27 C28 1.488(6) .
C27 Eu1 2.952(4) 3_677
C28 C29 1.352(7) .
C28 C33 1.353(7) .
C29 C30 1.415(8) .
C29 H29 0.9500 .
C30 C31 1.338(8) .
C30 H30 0.9500 .
C31 C32 1.373(9) .
C31 O8 1.394(5) .
C32 C33 1.364(8) .
C32 H32 0.9500 .
C33 H33 0.9500 .
Eu1 O5 2.353(3) 2_566
Eu1 O6 2.358(3) .
Eu1 O4 2.378(3) 4_666
Eu1 O1 2.403(3) .
Eu1 O7 2.417(3) 3_677
Eu1 O2 2.535(3) .
Eu1 N1 2.587(3) .
Eu1 N2 2.617(4) .
Eu1 O6 2.778(3) 3_677
Eu1 C27 2.952(4) 3_677
Eu1 Eu1 3.9907(12) 3_677
N3 C6 1.340(5) 3_567
O4 Eu1 2.378(3) 4_565
O5 Eu1 2.353(3) 2_546
O6 Eu1 2.778(3) 3_677
O7 Eu1 2.417(3) 3_677
O8 C31 1.395(6) 2_656
