#------------------------------------------------------------------------------
#$Date: 2017-01-09 05:09:01 +0200 (Mon, 09 Jan 2017) $
#$Revision: 190087 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/67/7226766.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226766
loop_
_publ_author_name
'Zheng, Sheng-Run'
'Tan, Jing-Bo'
'Cai, Song-Liang'
'Fan, Jun'
'Zhang, Wei-Guang'
_publ_section_title
;
 Construction of six new luminescent Ln(iii)--Zn(ii) heterometallic
 coordination polymers based on heterometallic secondary building units
;
_journal_issue                   44
_journal_name_full               CrystEngComm
_journal_page_first              8672
_journal_paper_doi               10.1039/C6CE01184E
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C18 H12.5 Eu N2.5 O13.5 Zn'
_chemical_formula_weight         697.13
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-10-01 deposited with the CCDC.
2016-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 113.250(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.7602(7)
_cell_length_b                   10.3933(6)
_cell_length_c                   21.0922(11)
_cell_measurement_reflns_used    755
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      19.12
_cell_measurement_theta_min      2.39
_cell_volume                     2167.3(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0200
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            12306
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.000
_diffrn_reflns_theta_min         1.959
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    4.054
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.137
_exptl_crystal_description       block
_exptl_crystal_F_000             1356
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_exptl_transmission_factor_max   0.788
_exptl_transmission_factor_min   0.729
_refine_diff_density_max         0.785
_refine_diff_density_min         -0.544
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         4712
_refine_ls_number_restraints     73
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0236
_refine_ls_R_factor_gt           0.0207
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0263P)²+1.8672P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0499
_refine_ls_wR_factor_ref         0.0515
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4326
_reflns_number_total             4712
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce01184e2.cif
_cod_data_source_block           1EuZn
_cod_depositor_comments
'Adding full bibliography for 7226766--7226771.cif.'
_cod_original_formula_sum        'C18 H12.50 Eu N2.50 O13.50 Zn'
_cod_database_code               7226766
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.419
_shelx_estimated_absorpt_t_max   0.498
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.49654(2) 0.68617(2) -0.01074(2) 0.01623(5) Uani 1 1 d . . . . .
Zn1 Zn 0.78674(3) 0.51547(3) 0.13106(2) 0.01872(7) Uani 1 1 d . . . . .
O1 O 0.6792(2) 0.78907(19) 0.08470(10) 0.0308(5) Uani 1 1 d . . . . .
O1W O 0.4024(2) 0.8752(2) 0.02610(11) 0.0369(5) Uani 1 1 d . . . . .
H1WA H 0.4005 0.9566 0.0292 0.055 Uiso 1 1 d R U . . .
H1WB H 0.3322 0.8455 0.0301 0.055 Uiso 1 1 d R U . . .
O2 O 0.8116(2) 0.68244(17) 0.17908(11) 0.0278(5) Uani 1 1 d . . . . .
O3 O 0.9568(10) 0.9063(7) 0.4001(3) 0.084(3) Uani 0.5 1 d . U P A 1
O4 O 0.9646(10) 1.1070(13) 0.4043(7) 0.063(3) Uani 0.5 1 d . U P A 1
N1 N 0.9283(18) 1.0095(17) 0.3696(10) 0.050(4) Uani 0.5 1 d . . P A 1
O3' O 0.8528(10) 0.9126(7) 0.3941(3) 0.076(2) Uani 0.5 1 d . U P A 2
O4' O 0.8989(11) 1.1075(12) 0.4020(7) 0.061(3) Uani 0.5 1 d . U P A 2
N1' N 0.8750(17) 1.0105(17) 0.3722(9) 0.048(4) Uani 0.5 1 d . . P A 2
O2W O 0.40823(19) 0.48671(16) -0.07394(10) 0.0185(4) Uani 1 1 d D . . . .
H2W H 0.442(3) 0.487(3) -0.0999(16) 0.028 Uiso 1 1 d D U . . .
O5 O 0.82531(19) 1.36513(17) 0.19545(10) 0.0257(4) Uani 1 1 d . . . . .
O6 O 0.73436(19) 1.26799(18) 0.09372(9) 0.0240(4) Uani 1 1 d . . . . .
O7 O 0.5510(2) 0.87534(19) -0.07015(10) 0.0302(5) Uani 1 1 d . . . . .
O8 O 0.4903(2) 0.70170(18) -0.13420(10) 0.0293(5) Uani 1 1 d . . . . .
O9 O 0.5275(14) 1.2856(17) -0.1942(8) 0.093(5) Uani 0.5 1 d . U P B 1
O9' O 0.4689(12) 1.2851(13) -0.2070(6) 0.054(3) Uani 0.5 1 d . U P B 2
O10 O 0.66444(19) 0.38318(19) -0.03834(10) 0.0262(4) Uani 1 1 d . . . . .
O11 O 0.69340(19) 0.59481(19) -0.01998(11) 0.0293(4) Uani 1 1 d . . . . .
N2 N 0.5000 1.2312(4) -0.2500 0.0547(13) Uani 1 2 d S T P . .
N3 N 1.0463(2) 0.4878(2) -0.10778(12) 0.0237(5) Uani 1 1 d . . . . .
C1 C 0.7556(3) 0.7828(3) 0.14677(14) 0.0217(5) Uani 1 1 d . . . . .
C2 C 0.7883(3) 0.9057(2) 0.18808(13) 0.0202(5) Uani 1 1 d . . . . .
C3 C 0.8343(3) 0.8998(3) 0.25943(14) 0.0307(7) Uani 1 1 d . . . . .
H3 H 0.8482 0.8211 0.2822 0.037 Uiso 1 1 calc R U . . .
C4 C 0.8589(4) 1.0143(3) 0.29578(15) 0.0355(8) Uani 1 1 d . . . . .
C5 C 0.8449(3) 1.1332(3) 0.26492(14) 0.0269(6) Uani 1 1 d . . . . .
H5 H 0.8641 1.2082 0.2911 0.032 Uiso 1 1 calc R U . . .
C6 C 0.8016(3) 1.1378(2) 0.19391(13) 0.0198(5) Uani 1 1 d . . . . .
C7 C 0.7707(3) 1.0247(2) 0.15556(14) 0.0209(5) Uani 1 1 d . . . . .
H7 H 0.7381 1.0287 0.1077 0.025 Uiso 1 1 calc R U . . .
C8 C 0.7851(3) 1.2660(2) 0.15857(14) 0.0203(5) Uani 1 1 d . . . . .
C9 C 0.5208(3) 0.8180(3) -0.12743(14) 0.0228(6) Uani 1 1 d . . . . .
C10 C 0.5150(3) 0.8920(3) -0.18986(13) 0.0233(6) Uani 1 1 d . . . . .
C11 C 0.5165(3) 1.0256(3) -0.18977(15) 0.0285(6) Uani 1 1 d . . . . .
H11 H 0.5284 1.0715 -0.1499 0.034 Uiso 1 1 calc R U . B .
C12 C 0.5000 1.0888(4) -0.2500 0.0311(9) Uani 1 2 d S T P B .
C13 C 0.5000 0.8258(4) -0.2500 0.0238(8) Uani 1 2 d S T P . .
H13 H 0.5000 0.7363 -0.2500 0.029 Uiso 1 2 calc R U P . .
C14 C 0.7181(3) 0.4887(3) -0.04078(14) 0.0216(6) Uani 1 1 d . . . . .
C15 C 0.8271(3) 0.4886(3) -0.06931(14) 0.0231(6) Uani 1 1 d . . . . .
C16 C 0.8773(4) 0.3761(3) -0.0835(2) 0.0484(10) Uani 1 1 d . . . . .
H16 H 0.8377 0.2979 -0.0806 0.058 Uiso 1 1 calc R U . . .
C17 C 0.9868(4) 0.3791(3) -0.1020(2) 0.0455(9) Uani 1 1 d . . . . .
H17 H 1.0204 0.3017 -0.1108 0.055 Uiso 1 1 calc R U . . .
C18 C 0.9945(3) 0.5983(3) -0.09628(19) 0.0389(8) Uani 1 1 d . . . . .
H18 H 1.0336 0.6754 -0.1012 0.047 Uiso 1 1 calc R U . . .
C19 C 0.8853(3) 0.6021(3) -0.07732(19) 0.0387(8) Uani 1 1 d . . . . .
H19 H 0.8516 0.6806 -0.0700 0.046 Uiso 1 1 calc R U . . .
O3W O 0.8466(18) 0.049(2) 0.5263(9) 0.097(5) Uani 0.25 1 d . U P C 1
O3W' O 0.819(3) -0.008(2) 0.4883(14) 0.136(8) Uani 0.25 1 d . U P D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Eu1 O1 77.92(7) . .
O11 Eu1 O2W 77.62(7) . .
O1 Eu1 O2W 146.71(7) . .
O11 Eu1 O10 135.40(7) . 3_665
O1 Eu1 O10 104.72(7) . 3_665
O2W Eu1 O10 78.09(6) . 3_665
O11 Eu1 O2W 68.96(7) . 3_665
O1 Eu1 O2W 75.59(6) . 3_665
O2W Eu1 O2W 74.74(7) . 3_665
O10 Eu1 O2W 68.83(6) 3_665 3_665
O11 Eu1 O6 134.14(7) . 3_675
O1 Eu1 O6 139.73(6) . 3_675
O2W Eu1 O6 73.13(6) . 3_675
O10 Eu1 O6 70.92(6) 3_665 3_675
O2W Eu1 O6 132.45(6) 3_665 3_675
O11 Eu1 O1W 145.57(7) . .
O1 Eu1 O1W 71.84(7) . .
O2W Eu1 O1W 136.55(7) . .
O10 Eu1 O1W 69.84(7) 3_665 .
O2W Eu1 O1W 117.27(7) 3_665 .
O6 Eu1 O1W 69.21(7) 3_675 .
O11 Eu1 O7 83.25(7) . .
O1 Eu1 O7 78.37(7) . .
O2W Eu1 O7 120.45(6) . .
O10 Eu1 O7 141.32(7) 3_665 .
O2W Eu1 O7 145.12(7) 3_665 .
O6 Eu1 O7 82.11(6) 3_675 .
O1W Eu1 O7 74.98(7) . .
O11 Eu1 O8 67.37(7) . .
O1 Eu1 O8 119.80(7) . .
O2W Eu1 O8 69.73(6) . .
O10 Eu1 O8 134.64(7) 3_665 .
O2W Eu1 O8 128.07(6) 3_665 .
O6 Eu1 O8 69.70(6) 3_675 .
O1W Eu1 O8 114.61(7) . .
O7 Eu1 O8 50.88(6) . .
O11 Eu1 C9 75.01(7) . .
O1 Eu1 C9 100.33(7) . .
O2W Eu1 C9 94.77(7) . .
O10 Eu1 C9 143.90(7) 3_665 .
O2W Eu1 C9 143.82(7) 3_665 .
O6 Eu1 C9 73.13(7) 3_675 .
O1W Eu1 C9 94.37(7) . .
O7 Eu1 C9 25.69(7) . .
O8 Eu1 C9 25.25(7) . .
O11 Eu1 Zn1 103.43(5) . 3_665
O1 Eu1 Zn1 168.88(5) . 3_665
O2W Eu1 Zn1 28.19(4) . 3_665
O10 Eu1 Zn1 66.40(5) 3_665 3_665
O2W Eu1 Zn1 94.46(4) 3_665 3_665
O6 Eu1 Zn1 45.69(4) 3_675 3_665
O1W Eu1 Zn1 109.45(5) . 3_665
O7 Eu1 Zn1 112.73(5) . 3_665
O8 Eu1 Zn1 70.22(4) . 3_665
C9 Eu1 Zn1 90.63(5) . 3_665
O11 Eu1 Zn1 53.28(5) . .
O1 Eu1 Zn1 53.91(5) . .
O2W Eu1 Zn1 93.15(4) . .
O10 Eu1 Zn1 91.63(5) 3_665 .
O2W Eu1 Zn1 27.01(4) 3_665 .
O6 Eu1 Zn1 159.46(4) 3_675 .
O1W Eu1 Zn1 115.76(5) . .
O7 Eu1 Zn1 118.35(5) . .
O8 Eu1 Zn1 120.55(5) . .
C9 Eu1 Zn1 124.29(5) . .
Zn1 Eu1 Zn1 117.898(7) 3_665 .
O11 Eu1 H1WB 161.1 . .
O1 Eu1 H1WB 83.5 . .
O2W Eu1 H1WB 120.9 . .
O10 Eu1 H1WB 53.5 3_665 .
O2W Eu1 H1WB 110.0 3_665 .
O6 Eu1 H1WB 61.3 3_675 .
O1W Eu1 H1WB 17.2 . .
O7 Eu1 H1WB 89.4 . .
O8 Eu1 H1WB 120.4 . .
C9 Eu1 H1WB 105.1 . .
Zn1 Eu1 H1WB 95.5 3_665 .
Zn1 Eu1 H1WB 117.2 . .
O11 Eu1 H2W 66.1(7) . .
O1 Eu1 H2W 142.5(7) . .
O2W Eu1 H2W 16.2(5) . .
O10 Eu1 H2W 94.2(6) 3_665 .
O2W Eu1 H2W 81.8(7) 3_665 .
O6 Eu1 H2W 76.9(7) 3_675 .
O1W Eu1 H2W 145.6(7) . .
O7 Eu1 H2W 106.3(6) . .
O8 Eu1 H2W 55.6(6) . .
C9 Eu1 H2W 80.8(6) . .
Zn1 Eu1 H2W 37.3(7) 3_665 .
Zn1 Eu1 H2W 94.2(7) . .
H1WB Eu1 H2W 132.8 . .
O2W Zn1 O2 102.74(8) 3_665 .
O2W Zn1 O5 106.98(8) 3_665 1_545
O2 Zn1 O5 112.83(8) . 1_545
O2W Zn1 N3 132.90(9) 3_665 3_765
O2 Zn1 N3 100.61(9) . 3_765
O5 Zn1 N3 100.58(9) 1_545 3_765
O2W Zn1 Eu1 36.01(5) 3_665 3_665
O2 Zn1 Eu1 138.53(6) . 3_665
O5 Zn1 Eu1 85.31(5) 1_545 3_665
N3 Zn1 Eu1 112.71(7) 3_765 3_665
O2W Zn1 Eu1 34.57(5) 3_665 .
O2 Zn1 Eu1 84.05(6) . .
O5 Zn1 Eu1 141.52(6) 1_545 .
N3 Zn1 Eu1 110.24(7) 3_765 .
Eu1 Zn1 Eu1 62.102(7) 3_665 .
C1 O1 Eu1 146.10(19) . .
Eu1 O1W H1WA 147.2 . .
Eu1 O1W H1WB 103.5 . .
H1WA O1W H1WB 107.7 . .
C1 O2 Zn1 120.72(18) . .
O3 N1 O4 117.2(17) . .
O3 N1 C4 121.0(14) . .
O4 N1 C4 121.8(15) . .
O4' N1' O3' 124.9(14) . .
O4' N1' C4 116.7(14) . .
O3' N1' C4 118.1(13) . .
Zn1 O2W Eu1 115.81(8) 3_665 .
Zn1 O2W Eu1 118.42(8) 3_665 3_665
Eu1 O2W Eu1 105.26(7) . 3_665
Zn1 O2W H2W 105(3) 3_665 .
Eu1 O2W H2W 101(2) . .
Eu1 O2W H2W 110(2) 3_665 .
C8 O5 Zn1 106.88(17) . 1_565
C8 O6 Eu1 131.41(17) . 3_675
C9 O7 Eu1 94.84(16) . .
C9 O8 Eu1 92.53(17) . .
C14 O10 Eu1 133.69(17) . 3_665
C14 O11 Eu1 133.87(18) . .
O9 N2 O9 125.3(18) . 2_654
O9' N2 O9' 125.4(14) . 2_654
O9 N2 C12 117.3(9) . .
O9 N2 C12 117.3(9) 2_654 .
O9' N2 C12 117.3(7) . .
O9' N2 C12 117.3(7) 2_654 .
C17 N3 C18 117.6(3) . .
C17 N3 Zn1 120.6(2) . 3_765
C18 N3 Zn1 121.74(19) . 3_765
O1 C1 O2 126.1(3) . .
O1 C1 C2 118.1(2) . .
O2 C1 C2 115.8(2) . .
C3 C2 C7 119.7(2) . .
C3 C2 C1 119.5(2) . .
C7 C2 C1 120.9(2) . .
C4 C3 C2 118.1(3) . .
C4 C3 H3 120.9 . .
C2 C3 H3 120.9 . .
N1 C4 C5 117.2(7) . .
N1 C4 C3 118.3(7) . .
C5 C4 C3 123.3(3) . .
C5 C4 N1' 117.4(7) . .
C3 C4 N1' 118.2(7) . .
C4 C5 C6 118.1(3) . .
C4 C5 H5 121.0 . .
C6 C5 H5 121.0 . .
C5 C6 C7 120.1(2) . .
C5 C6 C8 119.4(2) . .
C7 C6 C8 120.4(2) . .
C2 C7 C6 120.7(2) . .
C2 C7 H7 119.7 . .
C6 C7 H7 119.7 . .
O6 C8 O5 123.7(2) . .
O6 C8 C6 118.0(2) . .
O5 C8 C6 118.3(2) . .
O8 C9 O7 121.5(3) . .
O8 C9 C10 118.5(2) . .
O7 C9 C10 120.0(2) . .
O8 C9 Eu1 62.22(15) . .
O7 C9 Eu1 59.47(14) . .
C10 C9 Eu1 172.63(19) . .
C11 C10 C13 119.5(3) . .
C11 C10 C9 120.9(2) . .
C13 C10 C9 119.5(3) . .
C12 C11 C10 118.5(3) . .
C12 C11 H11 120.7 . .
C10 C11 H11 120.7 . .
C11 C12 C11 123.1(4) . 2_654
C11 C12 N2 118.45(19) . .
C11 C12 N2 118.45(19) 2_654 .
C10 C13 C10 120.9(4) 2_654 .
C10 C13 H13 119.6 2_654 .
C10 C13 H13 119.6 . .
O10 C14 O11 126.3(3) . .
O10 C14 C15 117.3(2) . .
O11 C14 C15 116.4(2) . .
C16 C15 C19 117.8(3) . .
C16 C15 C14 121.4(3) . .
C19 C15 C14 120.6(2) . .
C15 C16 C17 119.8(3) . .
C15 C16 H16 120.1 . .
C17 C16 H16 120.1 . .
N3 C17 C16 122.7(3) . .
N3 C17 H17 118.6 . .
C16 C17 H17 118.6 . .
N3 C18 C19 122.6(3) . .
N3 C18 H18 118.7 . .
C19 C18 H18 118.7 . .
C15 C19 C18 119.3(3) . .
C15 C19 H19 120.3 . .
C18 C19 H19 120.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O11 2.3984(19) .
Eu1 O1 2.4364(19) .
Eu1 O2W 2.4448(17) .
Eu1 O10 2.4510(18) 3_665
Eu1 O2W 2.4543(18) 3_665
Eu1 O6 2.4557(19) 3_675
Eu1 O1W 2.472(2) .
Eu1 O7 2.5215(19) .
Eu1 O8 2.583(2) .
Eu1 C9 2.917(3) .
Eu1 Zn1 3.7438(4) 3_665
Eu1 Zn1 3.8040(4) .
Eu1 H1WB 2.7952 .
Eu1 H2W 2.70(3) .
Zn1 O2W 1.9642(19) 3_665
Zn1 O2 1.9736(18) .
Zn1 O5 2.0034(18) 1_545
Zn1 N3 2.041(2) 3_765
Zn1 Eu1 3.7438(4) 3_665
O1 C1 1.243(3) .
O1W H1WA 0.8498 .
O1W H1WB 0.8499 .
O2 C1 1.262(3) .
O3 N1 1.226(19) .
O4 N1 1.22(2) .
N1 C4 1.44(2) .
O3' N1' 1.181(18) .
O4' N1' 1.16(2) .
N1' C4 1.552(15) .
O2W Zn1 1.9642(19) 3_665
O2W Eu1 2.4544(18) 3_665
O2W H2W 0.77(2) .
O5 C8 1.260(3) .
O5 Zn1 2.0033(18) 1_565
O6 C8 1.257(3) .
O6 Eu1 2.4556(19) 3_675
O7 C9 1.269(3) .
O8 C9 1.246(3) .
O9 N2 1.231(15) .
O9' N2 1.220(11) .
O10 C14 1.250(3) .
O10 Eu1 2.4510(18) 3_665
O11 C14 1.254(3) .
N2 O9 1.231(15) 2_654
N2 O9' 1.220(11) 2_654
N2 C12 1.480(6) .
N3 C17 1.328(4) .
N3 C18 1.339(4) .
N3 Zn1 2.042(2) 3_765
C1 C2 1.507(4) .
C2 C3 1.388(4) .
C2 C7 1.390(4) .
C3 C4 1.384(4) .
C3 H3 0.9300 .
C4 C5 1.376(4) .
C5 C6 1.382(4) .
C5 H5 0.9300 .
C6 C7 1.391(4) .
C6 C8 1.503(4) .
C7 H7 0.9300 .
C9 C10 1.505(4) .
C10 C11 1.389(4) .
C10 C13 1.395(3) .
C11 C12 1.378(3) .
C11 H11 0.9300 .
C12 C11 1.378(3) 2_654
C13 C10 1.395(3) 2_654
C13 H13 0.9300 .
C14 C15 1.514(4) .
C15 C16 1.369(4) .
C15 C19 1.378(4) .
C16 C17 1.381(4) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.383(4) .
C18 H18 0.9300 .
C19 H19 0.9300 .
