#------------------------------------------------------------------------------
#$Date: 2017-01-09 05:09:01 +0200 (Mon, 09 Jan 2017) $
#$Revision: 190087 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/67/7226770.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226770
loop_
_publ_author_name
'Zheng, Sheng-Run'
'Tan, Jing-Bo'
'Cai, Song-Liang'
'Fan, Jun'
'Zhang, Wei-Guang'
_publ_section_title
;
 Construction of six new luminescent Ln(iii)--Zn(ii) heterometallic
 coordination polymers based on heterometallic secondary building units
;
_journal_issue                   44
_journal_name_full               CrystEngComm
_journal_page_first              8672
_journal_paper_doi               10.1039/C6CE01184E
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C22 H12 Eu N3 O15 Zn'
_chemical_formula_weight         775.68
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-10-01 deposited with the CCDC.
2016-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.7440(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.4803(11)
_cell_length_b                   17.8855(19)
_cell_length_c                   17.8364(18)
_cell_measurement_reflns_used    1100
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      22.32
_cell_measurement_theta_min      2.56
_cell_volume                     3217.9(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_av_unetI/netI     0.0421
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            17204
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         1.644
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    2.743
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_description       block
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.160
_exptl_transmission_factor_max   0.788
_exptl_transmission_factor_min   0.729
_refine_diff_density_max         0.966
_refine_diff_density_min         -0.627
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         6288
_refine_ls_number_restraints     144
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0509
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0589P)²+10.2605P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1112
_refine_ls_wR_factor_ref         0.1195
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5076
_reflns_number_total             6288
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce01184e2.cif
_cod_data_source_block           5EuZn
_cod_depositor_comments
'Adding full bibliography for 7226766--7226771.cif.'
_cod_database_code               7226770
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.456
_shelx_estimated_absorpt_t_max   0.668
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7182(6) 0.0413(3) 0.4700(4) 0.0341(14) Uani 1 1 d . . . . .
C2 C 0.8543(6) 0.0723(3) 0.4758(3) 0.0317(13) Uani 1 1 d . . . . .
C3 C 0.8980(6) 0.0811(3) 0.4092(4) 0.0319(13) Uani 1 1 d . . . . .
H3 H 0.8401 0.0721 0.3604 0.038 Uiso 1 1 calc R U . . .
C4 C 1.0278(6) 0.1032(3) 0.4153(4) 0.0326(13) Uani 1 1 d . . . . .
C5 C 1.1111(6) 0.1196(4) 0.4875(4) 0.0399(15) Uani 1 1 d . . . . .
H5 H 1.1979 0.1349 0.4926 0.048 Uiso 1 1 calc R U . . .
C6 C 1.0636(6) 0.1130(4) 0.5519(4) 0.0461(17) Uani 1 1 d . . . . .
C7 C 0.9380(6) 0.0886(4) 0.5479(4) 0.0401(15) Uani 1 1 d . . . . .
H7 H 0.9100 0.0831 0.5928 0.048 Uiso 1 1 calc R U . . .
C8 C 1.0802(6) 0.1053(3) 0.3447(4) 0.0340(14) Uani 1 1 d . . . . .
C9 C 0.3630(6) 0.1716(3) 0.2605(4) 0.0325(13) Uani 1 1 d . . . . .
C10 C 0.4365(6) 0.2421(3) 0.2909(4) 0.0348(14) Uani 1 1 d . . . . .
C11 C 0.3778(6) 0.3109(3) 0.2683(3) 0.0317(13) Uani 1 1 d . . . . .
H11 H 0.2973 0.3130 0.2301 0.038 Uiso 1 1 calc R U . . .
C12 C 0.4368(6) 0.3763(3) 0.3015(3) 0.0346(14) Uani 1 1 d . . . . .
C13 C 0.5579(7) 0.3730(4) 0.3578(4) 0.054(2) Uani 1 1 d . . . . .
H13 H 0.5991 0.4165 0.3810 0.064 Uiso 1 1 calc R U . . .
C14 C 0.6154(7) 0.3044(4) 0.3784(5) 0.060(2) Uani 1 1 d . . . . .
C15 C 0.5580(6) 0.2385(4) 0.3467(4) 0.0476(18) Uani 1 1 d . . . . .
H15 H 0.5992 0.1928 0.3622 0.057 Uiso 1 1 calc R U . . .
C16 C 0.3702(6) 0.4510(4) 0.2785(4) 0.0356(14) Uani 1 1 d . . . . .
C17 C 0.4754(5) 0.1427(3) 0.5275(4) 0.0301(13) Uani 1 1 d . . . . .
C18 C 0.4464(6) 0.2257(3) 0.5313(3) 0.0287(12) Uani 1 1 d . . . . .
C19 C 0.5082(6) 0.2664(3) 0.5972(3) 0.0341(14) Uani 1 1 d . . . . .
H19 H 0.5650 0.2413 0.6387 0.041 Uiso 1 1 calc R U . . .
C20 C 0.4072(7) 0.3752(4) 0.5454(4) 0.0457(17) Uani 1 1 d . . . . .
H20 H 0.3935 0.4262 0.5497 0.055 Uiso 1 1 calc R U . . .
C21 C 0.3398(8) 0.3383(4) 0.4777(4) 0.054(2) Uani 1 1 d . . . . .
H21 H 0.2809 0.3643 0.4378 0.065 Uiso 1 1 calc R U . . .
C22 C 0.3608(7) 0.2632(4) 0.4700(4) 0.0420(16) Uani 1 1 d . . . . .
H22 H 0.3183 0.2381 0.4245 0.050 Uiso 1 1 calc R U . . .
Eu1 Eu 0.40273(3) 0.01465(2) 0.37277(2) 0.02351(11) Uani 1 1 d . . . . .
N1 N 1.1542(7) 0.1291(6) 0.6299(4) 0.084(3) Uani 1 1 d . . . . .
N2 N 0.7234(18) 0.3005(11) 0.4559(11) 0.077(3) Uani 0.5 1 d . U P A 1
O11 O 0.7578(14) 0.3570(8) 0.4936(9) 0.088(3) Uani 0.5 1 d . U P A 1
O12 O 0.7669(14) 0.2419(8) 0.4814(8) 0.078(3) Uani 0.5 1 d . U P A 1
N2' N 0.7551(18) 0.3013(11) 0.4233(11) 0.080(3) Uani 0.5 1 d . U P A 2
O11' O 0.8131(14) 0.3584(8) 0.4491(9) 0.090(3) Uani 0.5 1 d . U P A 2
O12' O 0.8131(14) 0.2449(8) 0.4391(9) 0.084(3) Uani 0.5 1 d . U P A 2
N3 N 0.4909(5) 0.3398(3) 0.6044(3) 0.0342(12) Uani 1 1 d . . . . .
O1 O 0.6386(4) 0.0342(3) 0.4036(3) 0.0432(11) Uani 1 1 d . . . . .
O2 O 0.6940(4) 0.0234(3) 0.5322(3) 0.0473(12) Uani 1 1 d . . . . .
O3 O 0.9986(4) 0.1162(3) 0.2795(3) 0.0494(13) Uani 1 1 d . . . . .
O4 O 1.2007(4) 0.0972(3) 0.3527(3) 0.0406(11) Uani 1 1 d . . . . .
O5 O 1.248(2) 0.1801(11) 0.6291(13) 0.089(5) Uani 0.5 1 d . U P B 1
O6 O 1.1098(17) 0.1349(11) 0.6846(10) 0.083(5) Uani 0.5 1 d . U P B 1
O5' O 1.2684(15) 0.1431(8) 0.6358(10) 0.055(3) Uani 0.5 1 d . U P B 2
O6' O 1.1288(15) 0.0896(9) 0.6863(8) 0.064(4) Uani 0.5 1 d . U P B 2
O7 O 0.4152(4) 0.1098(2) 0.2833(2) 0.0338(9) Uani 1 1 d . . . . .
O8 O 0.2476(4) 0.1799(2) 0.2148(3) 0.0417(11) Uani 1 1 d . . . . .
O9 O 0.2824(5) 0.4549(3) 0.2166(3) 0.0475(12) Uani 1 1 d . . . . .
O10 O 0.4100(5) 0.5042(2) 0.3258(3) 0.0501(13) Uani 1 1 d . . . . .
O13 O 0.4498(4) 0.1154(2) 0.4611(2) 0.0414(11) Uani 1 1 d . . . . .
O14 O 0.5215(5) 0.1101(2) 0.5910(3) 0.0407(11) Uani 1 1 d . . . . .
O1W O 0.4850(6) -0.0447(3) 0.2685(3) 0.0682(16) Uani 1 1 d . . . . .
Zn1 Zn 1.10342(7) 0.10878(4) 0.20214(4) 0.03330(18) Uani 1 1 d . . . . .
H2W H 0.5088 -0.0889 0.2632 0.050 Uiso 1 1 d R U . . .
H1W H 0.5073 -0.0230 0.2325 0.050 Uiso 1 1 d R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O2 124.9(6) . .
O1 C1 C2 118.3(6) . .
O2 C1 C2 116.8(6) . .
C7 C2 C3 119.9(6) . .
C7 C2 C1 119.5(6) . .
C3 C2 C1 120.5(5) . .
C4 C3 C2 120.4(6) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C5 C4 C3 119.5(6) . .
C5 C4 C8 119.7(5) . .
C3 C4 C8 120.8(5) . .
C6 C5 C4 118.8(6) . .
C6 C5 H5 120.6 . .
C4 C5 H5 120.6 . .
C5 C6 C7 122.9(6) . .
C5 C6 N1 118.8(6) . .
C7 C6 N1 118.2(6) . .
C6 C7 C2 118.4(6) . .
C6 C7 H7 120.8 . .
C2 C7 H7 120.8 . .
O4 C8 O3 122.8(6) . .
O4 C8 C4 119.4(5) . .
O3 C8 C4 117.8(5) . .
O7 C9 O8 124.6(6) . .
O7 C9 C10 119.2(5) . .
O8 C9 C10 116.1(5) . .
C11 C10 C15 119.9(6) . .
C11 C10 C9 119.8(5) . .
C15 C10 C9 120.1(6) . .
C10 C11 C12 121.1(5) . .
C10 C11 H11 119.5 . .
C12 C11 H11 119.5 . .
C11 C12 C13 119.4(6) . .
C11 C12 C16 120.9(5) . .
C13 C12 C16 119.8(6) . .
C14 C13 C12 118.6(6) . .
C14 C13 H13 120.7 . .
C12 C13 H13 120.7 . .
N2' C14 C13 118.7(10) . .
N2' C14 C15 117.0(10) . .
C13 C14 C15 123.0(6) . .
C13 C14 N2 116.5(10) . .
C15 C14 N2 117.8(9) . .
C10 C15 C14 118.0(6) . .
C10 C15 H15 121.0 . .
C14 C15 H15 121.0 . .
O9 C16 O10 125.9(6) . .
O9 C16 C12 118.0(6) . .
O10 C16 C12 116.1(5) . .
O13 C17 O14 127.6(6) . .
O13 C17 C18 115.7(5) . .
O14 C17 C18 116.7(5) . .
C19 C18 C22 117.9(6) . .
C19 C18 C17 119.9(5) . .
C22 C18 C17 122.2(5) . .
N3 C19 C18 123.6(5) . .
N3 C19 H19 118.2 . .
C18 C19 H19 118.2 . .
N3 C20 C21 122.0(6) . .
N3 C20 H20 119.0 . .
C21 C20 H20 119.0 . .
C22 C21 C20 119.6(6) . .
C22 C21 H21 120.2 . .
C20 C21 H21 120.2 . .
C21 C22 C18 118.9(6) . .
C21 C22 H22 120.6 . .
C18 C22 H22 120.6 . .
O2 Eu1 O13 77.78(18) 3_656 .
O2 Eu1 O7 145.83(16) 3_656 .
O13 Eu1 O7 81.98(16) . .
O2 Eu1 O9 85.34(18) 3_656 2_545
O13 Eu1 O9 140.25(16) . 2_545
O7 Eu1 O9 93.17(15) . 2_545
O2 Eu1 O14 72.89(16) 3_656 3_656
O13 Eu1 O14 122.52(15) . 3_656
O7 Eu1 O14 141.09(15) . 3_656
O9 Eu1 O14 85.05(15) 2_545 3_656
O2 Eu1 O1 120.34(16) 3_656 .
O13 Eu1 O1 73.76(16) . .
O7 Eu1 O1 78.91(15) . .
O9 Eu1 O1 144.17(17) 2_545 .
O14 Eu1 O1 80.17(16) 3_656 .
O2 Eu1 O1W 137.3(2) 3_656 .
O13 Eu1 O1W 140.67(19) . .
O7 Eu1 O1W 73.07(17) . .
O9 Eu1 O1W 72.3(2) 2_545 .
O14 Eu1 O1W 69.40(18) 3_656 .
O1 Eu1 O1W 71.97(19) . .
O2 Eu1 O4 75.96(15) 3_656 1_455
O13 Eu1 O4 70.31(15) . 1_455
O7 Eu1 O4 71.39(14) . 1_455
O9 Eu1 O4 70.78(16) 2_545 1_455
O14 Eu1 O4 141.79(15) 3_656 1_455
O1 Eu1 O4 135.77(16) . 1_455
O1W Eu1 O4 126.17(17) . 1_455
O2 Eu1 Eu1 52.33(12) 3_656 3_656
O13 Eu1 Eu1 57.05(11) . 3_656
O7 Eu1 Eu1 132.58(10) . 3_656
O9 Eu1 Eu1 133.23(12) 2_545 3_656
O14 Eu1 Eu1 65.85(10) 3_656 3_656
O1 Eu1 Eu1 68.18(11) . 3_656
O1W Eu1 Eu1 123.58(14) . 3_656
O4 Eu1 Eu1 110.25(10) 1_455 3_656
O5' N1 O6' 116.8(12) . .
O6 N1 O5 113.5(15) . .
O6 N1 C6 119.4(10) . .
O5' N1 C6 119.4(10) . .
O6' N1 C6 113.7(9) . .
O5 N1 C6 113.8(12) . .
O12 N2 C14 120.0(16) . .
O12 N2 O11 120.0(17) . .
C14 N2 O11 119.8(15) . .
C14 N2' O11' 119.9(16) . .
C14 N2' O12' 122.7(17) . .
O11' N2' O12' 117.4(17) . .
C20 N3 C19 118.0(5) . .
C20 N3 Zn1 124.3(4) . 4_566
C19 N3 Zn1 117.6(4) . 4_566
C1 O1 Eu1 127.4(4) . .
C1 O2 Eu1 165.7(4) . 3_656
C8 O3 Zn1 105.4(4) . .
C8 O4 Eu1 150.8(4) . 1_655
C9 O7 Eu1 139.2(4) . .
C9 O8 Zn1 125.0(4) . 1_455
C16 O9 Eu1 153.1(4) . 2
C16 O10 Zn1 124.6(4) . 2_655
C17 O13 Eu1 153.0(4) . .
C17 O14 Eu1 134.3(4) . 3_656
Eu1 O1W H2W 131.0 . .
Eu1 O1W H1W 126.9 . .
H2W O1W H1W 101.4 . .
O10 Zn1 O8 131.7(2) 2_645 1_655
O10 Zn1 O3 103.3(2) 2_645 .
O8 Zn1 O3 115.7(2) 1_655 .
O10 Zn1 N3 103.4(2) 2_645 4_665
O8 Zn1 N3 93.16(18) 1_655 4_665
O3 Zn1 N3 105.2(2) . 4_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.256(7) .
C1 O2 1.245(8) .
C1 C2 1.508(8) .
C2 C7 1.377(9) .
C2 C3 1.392(8) .
C3 C4 1.393(8) .
C3 H3 0.9300 .
C4 C5 1.377(9) .
C4 C8 1.506(9) .
C5 C6 1.376(9) .
C5 H5 0.9300 .
C6 C7 1.370(9) .
C6 N1 1.484(9) .
C7 H7 0.9300 .
C8 O4 1.240(7) .
C8 O3 1.257(7) .
C9 O7 1.252(7) .
C9 O8 1.270(7) .
C9 C10 1.500(8) .
C10 C11 1.386(8) .
C10 C15 1.389(8) .
C11 C12 1.378(8) .
C11 H11 0.9300 .
C12 C13 1.390(8) .
C12 C16 1.512(8) .
C13 C14 1.373(10) .
C13 H13 0.9300 .
C14 N2' 1.466(19) .
C14 C15 1.373(10) .
C14 N2 1.532(18) .
C15 H15 0.9300 .
C16 O9 1.233(7) .
C16 O10 1.265(8) .
C17 O13 1.242(7) .
C17 O14 1.249(7) .
C17 C18 1.519(8) .
C18 C19 1.386(8) .
C18 C22 1.384(8) .
C19 N3 1.335(8) .
C19 H19 0.9300 .
C20 N3 1.333(8) .
C20 C21 1.389(9) .
C20 H20 0.9300 .
C21 C22 1.374(9) .
C21 H21 0.9300 .
C22 H22 0.9300 .
Eu1 O2 2.301(5) 3_656
Eu1 O13 2.355(4) .
Eu1 O7 2.361(4) .
Eu1 O9 2.402(4) 2_545
Eu1 O14 2.397(4) 3_656
Eu1 O1 2.408(4) .
Eu1 O1W 2.491(5) .
Eu1 O4 2.526(4) 1_455
Eu1 Eu1 4.4731(7) 3_656
N1 O6 1.194(18) .
N1 O5' 1.199(17) .
N1 O6' 1.313(17) .
N1 O5 1.35(2) .
N2 O12 1.18(2) .
N2 O11 1.21(2) .
N2' O11' 1.21(2) .
N2' O12' 1.17(2) .
N3 Zn1 2.041(5) 4_566
O2 Eu1 2.301(5) 3_656
O3 Zn1 1.988(5) .
O4 Eu1 2.526(4) 1_655
O8 Zn1 1.941(4) 1_455
O9 Eu1 2.402(4) 2
O10 Zn1 1.931(5) 2_655
O14 Eu1 2.397(4) 3_656
O1W H2W 0.8406 .
O1W H1W 0.8366 .
Zn1 O10 1.931(5) 2_645
Zn1 O8 1.941(4) 1_655
Zn1 N3 2.041(5) 4_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O1 C1 C2 C7 172.7(6) .
O2 C1 C2 C7 -8.4(9) .
O1 C1 C2 C3 -10.5(9) .
O2 C1 C2 C3 168.5(6) .
C7 C2 C3 C4 2.7(9) .
C1 C2 C3 C4 -174.1(6) .
C2 C3 C4 C5 -2.9(9) .
C2 C3 C4 C8 173.7(6) .
C3 C4 C5 C6 0.6(10) .
C8 C4 C5 C6 -176.1(6) .
C4 C5 C6 C7 2.1(11) .
C4 C5 C6 N1 178.6(7) .
C5 C6 C7 C2 -2.3(11) .
N1 C6 C7 C2 -178.8(7) .
C3 C2 C7 C6 -0.2(10) .
C1 C2 C7 C6 176.7(6) .
C5 C4 C8 O4 23.6(9) .
C3 C4 C8 O4 -153.1(6) .
C5 C4 C8 O3 -155.5(6) .
C3 C4 C8 O3 27.8(9) .
O7 C9 C10 C11 -177.7(6) .
O8 C9 C10 C11 -0.5(9) .
O7 C9 C10 C15 -3.1(10) .
O8 C9 C10 C15 174.0(6) .
C15 C10 C11 C12 -1.4(10) .
C9 C10 C11 C12 173.2(6) .
C10 C11 C12 C13 0.8(10) .
C10 C11 C12 C16 -177.9(6) .
C11 C12 C13 C14 0.3(12) .
C16 C12 C13 C14 179.1(7) .
C12 C13 C14 N2' 165.9(11) .
C12 C13 C14 C15 -0.9(14) .
C12 C13 C14 N2 -161.8(11) .
C11 C10 C15 C14 0.7(11) .
C9 C10 C15 C14 -173.8(7) .
N2' C14 C15 C10 -166.6(11) .
C13 C14 C15 C10 0.4(14) .
N2 C14 C15 C10 161.1(10) .
C11 C12 C16 O9 -19.0(10) .
C13 C12 C16 O9 162.2(7) .
C11 C12 C16 O10 160.5(6) .
C13 C12 C16 O10 -18.2(10) .
O13 C17 C18 C19 -159.3(6) .
O14 C17 C18 C19 21.0(8) .
O13 C17 C18 C22 19.5(9) .
O14 C17 C18 C22 -160.2(6) .
C22 C18 C19 N3 -0.7(10) .
C17 C18 C19 N3 178.2(6) .
N3 C20 C21 C22 -1.1(13) .
C20 C21 C22 C18 1.8(12) .
C19 C18 C22 C21 -0.9(10) .
C17 C18 C22 C21 -179.8(7) .
C5 C6 N1 O6 168.5(14) .
C7 C6 N1 O6 -14.9(18) .
C5 C6 N1 O5' -4.3(16) .
C7 C6 N1 O5' 172.4(11) .
C5 C6 N1 O6' -148.7(10) .
C7 C6 N1 O6' 27.9(14) .
C5 C6 N1 O5 30.0(15) .
C7 C6 N1 O5 -153.3(12) .
C13 C14 N2 O12 171.7(16) .
C15 C14 N2 O12 10(2) .
C13 C14 N2 O11 -3(2) .
C15 C14 N2 O11 -165.3(17) .
C13 C14 N2' O11' 8(3) .
C15 C14 N2' O11' 176.1(17) .
C13 C14 N2' O12' -175.5(18) .
C15 C14 N2' O12' -8(3) .
C21 C20 N3 C19 -0.5(11) .
C21 C20 N3 Zn1 175.3(6) 4_566
C18 C19 N3 C20 1.4(10) .
C18 C19 N3 Zn1 -174.7(5) 4_566
O2 C1 O1 Eu1 16.5(9) .
C2 C1 O1 Eu1 -164.7(4) .
O1 C1 O2 Eu1 -7(2) 3_656
C2 C1 O2 Eu1 174.5(15) 3_656
O4 C8 O3 Zn1 4.3(8) .
C4 C8 O3 Zn1 -176.6(4) .
O3 C8 O4 Eu1 -101.8(9) 1_655
C4 C8 O4 Eu1 79.2(10) 1_655
O8 C9 O7 Eu1 -75.9(9) .
C10 C9 O7 Eu1 101.0(7) .
O7 C9 O8 Zn1 25.3(9) 1_455
C10 C9 O8 Zn1 -151.7(4) 1_455
O10 C16 O9 Eu1 -15.3(16) 2
C12 C16 O9 Eu1 164.2(7) 2
O9 C16 O10 Zn1 -25.1(10) 2_655
C12 C16 O10 Zn1 155.4(5) 2_655
O14 C17 O13 Eu1 20.5(13) .
C18 C17 O13 Eu1 -159.2(6) .
O13 C17 O14 Eu1 3.6(10) 3_656
C18 C17 O14 Eu1 -176.7(4) 3_656
