#------------------------------------------------------------------------------
#$Date: 2016-10-11 09:30:10 +0300 (Tue, 11 Oct 2016) $
#$Revision: 187257 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/67/7226775.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226775
loop_
_publ_author_name
'Lin, Shuang-Yan'
'Wang, Chunlai'
'Xu, Zhikun'
_publ_section_title
;
 Syntheses, Structures and Magnetic Properties of Symmetrical Schiff-base
 Supported Dinuclear Ln(III) Compounds
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA16669E
_journal_year                    2016
_chemical_formula_sum            'C68 H66 Dy2 N4 O18'
_chemical_formula_weight         1552.25
_chemical_name_systematic        2
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-06-28 deposited with the CCDC.
2016-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                94.2870(10)
_cell_angle_beta                 113.0680(10)
_cell_angle_gamma                97.6950(10)
_cell_formula_units_Z            1
_cell_length_a                   11.1487(7)
_cell_length_b                   11.3872(7)
_cell_length_c                   13.6878(8)
_cell_measurement_reflns_used    7381
_cell_measurement_temperature    185(2)
_cell_measurement_theta_max      26.08
_cell_measurement_theta_min      2.27
_cell_volume                     1568.86(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      185(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0167
_diffrn_reflns_av_sigmaI/netI    0.0316
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            8689
_diffrn_reflns_theta_full        26.08
_diffrn_reflns_theta_max         26.08
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    2.440
_exptl_absorpt_correction_T_max  0.7110
_exptl_absorpt_correction_T_min  0.6542
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.643
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             778
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.661
_refine_diff_density_min         -1.023
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         6090
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0272
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0412P)²+0.5454P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0659
_reflns_number_gt                5692
_reflns_number_total             6090
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ra16669e2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7226775
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.595567(11) 0.175694(11) 0.417854(10) 0.01813(6) Uani 1 1 d .
N1 N 0.6268(2) 0.3579(2) 0.5456(2) 0.0222(5) Uani 1 1 d .
N2 N 1.0043(2) 0.1826(2) 0.4474(2) 0.0263(5) Uani 1 1 d .
O1 O 0.81169(19) 0.26628(18) 0.47698(16) 0.0232(4) Uani 1 1 d .
H1 H 0.8526 0.2276 0.4376 0.028 Uiso 1 1 calc R
O2 O 0.42685(19) 0.16670(18) 0.50449(16) 0.0248(4) Uani 1 1 d .
H2 H 0.3512 0.1050 0.4808 0.030 Uiso 1 1 calc R
O3 O 1.1428(3) 0.2279(3) 0.3062(3) 0.0661(10) Uani 1 1 d .
H3 H 1.2079 0.2120 0.2946 0.099 Uiso 1 1 calc R
O4 O 0.7221(2) 0.0191(2) 0.38679(17) 0.0288(5) Uani 1 1 d .
O5 O 0.6029(2) 0.10362(19) 0.24993(17) 0.0263(4) Uani 1 1 d .
O8 O 0.45261(19) -0.00654(18) 0.36425(16) 0.0250(4) Uani 1 1 d .
O6 O 0.5815(2) 0.35125(19) 0.31910(18) 0.0273(5) Uani 1 1 d .
O7 O 0.3937(2) 0.23768(19) 0.29537(17) 0.0276(5) Uani 1 1 d .
O9 O 0.30633(19) -0.10813(19) 0.41398(17) 0.0256(4) Uani 1 1 d .
C1 C 0.8969(3) 0.3522(3) 0.5457(2) 0.0206(6) Uani 1 1 d .
C2 C 0.8643(3) 0.4350(3) 0.6101(2) 0.0231(6) Uani 1 1 d .
C3 C 0.9636(3) 0.5246(3) 0.6846(2) 0.0250(6) Uani 1 1 d .
H3A H 0.9395 0.5776 0.7279 0.030 Uiso 1 1 calc R
C4 C 1.0965(3) 0.5403(3) 0.6986(3) 0.0269(7) Uani 1 1 d .
C5 C 1.1286(3) 0.4614(3) 0.6341(2) 0.0253(6) Uani 1 1 d .
H5 H 1.2170 0.4716 0.6394 0.030 Uiso 1 1 calc R
C6 C 1.0338(3) 0.3669(3) 0.5611(2) 0.0236(6) Uani 1 1 d .
C7 C 0.7310(3) 0.4332(3) 0.6051(2) 0.0248(6) Uani 1 1 d .
H7 H 0.7204 0.4943 0.6508 0.030 Uiso 1 1 calc R
C8 C 0.5036(3) 0.3731(3) 0.5573(3) 0.0267(6) Uani 1 1 d .
H8A H 0.4366 0.3883 0.4887 0.032 Uiso 1 1 calc R
H8B H 0.5212 0.4419 0.6127 0.032 Uiso 1 1 calc R
C9 C 0.4536(3) 0.2594(3) 0.5898(3) 0.0265(6) Uani 1 1 d .
H9A H 0.5213 0.2425 0.6574 0.032 Uiso 1 1 calc R
H9B H 0.3720 0.2664 0.6008 0.032 Uiso 1 1 calc R
C10 C 1.1978(3) 0.6387(3) 0.7807(3) 0.0368(8) Uani 1 1 d .
H10A H 1.2674 0.6037 0.8329 0.055 Uiso 1 1 calc R
H10B H 1.1549 0.6831 0.8178 0.055 Uiso 1 1 calc R
H10C H 1.2372 0.6932 0.7448 0.055 Uiso 1 1 calc R
C11 C 1.0767(3) 0.2823(3) 0.5072(2) 0.0260(6) Uani 1 1 d .
H11 H 1.1660 0.2994 0.5150 0.031 Uiso 1 1 calc R
C12 C 1.0559(3) 0.0926(3) 0.3992(3) 0.0320(7) Uani 1 1 d .
H12A H 1.0010 0.0129 0.3883 0.038 Uiso 1 1 calc R
H12B H 1.1476 0.0891 0.4491 0.038 Uiso 1 1 calc R
C13 C 1.0554(4) 0.1209(4) 0.2937(3) 0.0457(9) Uani 1 1 d .
H13A H 1.0815 0.0543 0.2604 0.055 Uiso 1 1 calc R
H13B H 0.9645 0.1285 0.2450 0.055 Uiso 1 1 calc R
C14 C 0.6705(3) -0.0778(3) 0.2101(2) 0.0250(6) Uani 1 1 d .
C15 C 0.7490(3) -0.1635(3) 0.2471(3) 0.0292(7) Uani 1 1 d .
H15 H 0.8017 -0.1589 0.3216 0.035 Uiso 1 1 calc R
C16 C 0.7507(4) -0.2555(3) 0.1757(3) 0.0367(8) Uani 1 1 d .
H16 H 0.8050 -0.3135 0.2015 0.044 Uiso 1 1 calc R
C17 C 0.6733(4) -0.2633(3) 0.0667(3) 0.0397(8) Uani 1 1 d .
H17 H 0.6745 -0.3265 0.0178 0.048 Uiso 1 1 calc R
C18 C 0.5943(4) -0.1784(4) 0.0296(3) 0.0434(9) Uani 1 1 d .
H18 H 0.5411 -0.1832 -0.0448 0.052 Uiso 1 1 calc R
C19 C 0.5929(4) -0.0864(3) 0.1012(3) 0.0365(8) Uani 1 1 d .
H19 H 0.5383 -0.0286 0.0754 0.044 Uiso 1 1 calc R
C20 C 0.6660(3) 0.0214(3) 0.2869(2) 0.0236(6) Uani 1 1 d .
C21 C 0.2430(3) -0.0963(3) 0.2287(2) 0.0238(6) Uani 1 1 d .
C22 C 0.2725(3) -0.0456(3) 0.1494(3) 0.0362(8) Uani 1 1 d .
H22 H 0.3546 0.0063 0.1679 0.043 Uiso 1 1 calc R
C23 C 0.1814(4) -0.0711(4) 0.0435(3) 0.0530(11) Uani 1 1 d .
H23 H 0.2008 -0.0362 -0.0107 0.064 Uiso 1 1 calc R
C24 C 0.0623(4) -0.1475(4) 0.0166(3) 0.0529(11) Uani 1 1 d .
H24 H 0.0005 -0.1651 -0.0561 0.063 Uiso 1 1 calc R
C25 C 0.0330(4) -0.1980(4) 0.0944(3) 0.0466(10) Uani 1 1 d .
H25 H -0.0493 -0.2498 0.0756 0.056 Uiso 1 1 calc R
C26 C 0.1237(3) -0.1732(3) 0.2005(3) 0.0328(7) Uani 1 1 d .
H26 H 0.1040 -0.2092 0.2541 0.039 Uiso 1 1 calc R
C27 C 0.3402(3) -0.0677(2) 0.3438(2) 0.0208(6) Uani 1 1 d .
C28 C 0.3834(3) 0.4057(3) 0.1982(2) 0.0225(6) Uani 1 1 d .
C29 C 0.2464(3) 0.3860(3) 0.1527(3) 0.0296(7) Uani 1 1 d .
H29 H 0.1980 0.3171 0.1641 0.035 Uiso 1 1 calc R
C30 C 0.1794(4) 0.4665(4) 0.0905(3) 0.0423(9) Uani 1 1 d .
H30 H 0.0853 0.4528 0.0600 0.051 Uiso 1 1 calc R
C31 C 0.2486(4) 0.5662(4) 0.0730(3) 0.0466(10) Uani 1 1 d .
H31 H 0.2023 0.6222 0.0319 0.056 Uiso 1 1 calc R
C32 C 0.3855(4) 0.5850(3) 0.1149(3) 0.0451(9) Uani 1 1 d .
H32 H 0.4332 0.6523 0.1007 0.054 Uiso 1 1 calc R
C33 C 0.4529(3) 0.5053(3) 0.1779(3) 0.0326(7) Uani 1 1 d .
H33 H 0.5470 0.5186 0.2074 0.039 Uiso 1 1 calc R
C34 C 0.4573(3) 0.3261(3) 0.2744(2) 0.0213(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O8 144.62(7) . .
O1 Dy1 O9 77.70(7) . 2_656
O8 Dy1 O9 86.12(7) . 2_656
O1 Dy1 O5 88.80(7) . .
O8 Dy1 O5 76.64(7) . .
O9 Dy1 O5 127.96(7) 2_656 .
O1 Dy1 O7 129.82(7) . .
O8 Dy1 O7 80.25(7) . .
O9 Dy1 O7 143.50(7) 2_656 .
O5 Dy1 O7 81.47(7) . .
O1 Dy1 O6 76.98(7) . .
O8 Dy1 O6 127.68(7) . .
O9 Dy1 O6 145.24(7) 2_656 .
O5 Dy1 O6 74.78(7) . .
O7 Dy1 O6 52.92(7) . .
O1 Dy1 N1 73.16(7) . .
O8 Dy1 N1 134.02(8) . .
O9 Dy1 N1 78.12(8) 2_656 .
O5 Dy1 N1 144.93(7) . .
O7 Dy1 N1 87.37(8) . .
O6 Dy1 N1 72.01(8) . .
O1 Dy1 O4 72.94(7) . .
O8 Dy1 O4 72.57(7) . .
O9 Dy1 O4 75.13(7) 2_656 .
O5 Dy1 O4 52.92(7) . .
O7 Dy1 O4 130.69(7) . .
O6 Dy1 O4 118.78(7) . .
N1 Dy1 O4 140.36(7) . .
O1 Dy1 O2 132.67(7) . .
O8 Dy1 O2 68.67(7) . .
O9 Dy1 O2 72.42(7) 2_656 .
O5 Dy1 O2 138.52(7) . .
O7 Dy1 O2 71.08(7) . .
O6 Dy1 O2 109.33(7) . .
N1 Dy1 O2 65.42(7) . .
O4 Dy1 O2 130.30(7) . .
O1 Dy1 C20 83.07(8) . .
O8 Dy1 C20 69.46(8) . .
O9 Dy1 C20 101.41(8) 2_656 .
O5 Dy1 C20 26.58(8) . .
O7 Dy1 C20 105.08(8) . .
O6 Dy1 C20 98.75(8) . .
N1 Dy1 C20 155.83(8) . .
O4 Dy1 C20 26.72(8) . .
O2 Dy1 C20 137.97(7) . .
O1 Dy1 C34 103.31(8) . .
O8 Dy1 C34 104.14(8) . .
O9 Dy1 C34 155.82(8) 2_656 .
O5 Dy1 C34 76.11(8) . .
O7 Dy1 C34 26.60(7) . .
O6 Dy1 C34 26.34(8) . .
N1 Dy1 C34 79.11(8) . .
O4 Dy1 C34 128.65(7) . .
O2 Dy1 C34 90.72(7) . .
C20 Dy1 C34 102.69(8) . .
C7 N1 C8 116.5(3) . .
C7 N1 Dy1 131.0(2) . .
C8 N1 Dy1 112.39(18) . .
C11 N2 C12 123.9(3) . .
C1 O1 Dy1 141.28(18) . .
C1 O1 H1 109.4 . .
Dy1 O1 H1 109.4 . .
C9 O2 Dy1 116.22(16) . .
C9 O2 H2 121.9 . .
Dy1 O2 H2 121.9 . .
C13 O3 H3 109.5 . .
C20 O4 Dy1 89.42(17) . .
C20 O5 Dy1 94.46(18) . .
C27 O8 Dy1 150.09(19) . .
C34 O6 Dy1 92.36(17) . .
C34 O7 Dy1 93.46(17) . .
C27 O9 Dy1 138.93(18) . 2_656
O1 C1 C2 123.5(3) . .
O1 C1 C6 119.9(3) . .
C2 C1 C6 116.6(3) . .
C3 C2 C1 119.9(3) . .
C3 C2 C7 116.2(3) . .
C1 C2 C7 123.9(3) . .
C2 C3 C4 123.6(3) . .
C2 C3 H3A 118.2 . .
C4 C3 H3A 118.2 . .
C5 C4 C3 116.8(3) . .
C5 C4 C10 122.6(3) . .
C3 C4 C10 120.5(3) . .
C4 C5 C6 121.8(3) . .
C4 C5 H5 119.1 . .
C6 C5 H5 119.1 . .
C5 C6 C11 118.6(3) . .
C5 C6 C1 121.1(3) . .
C11 C6 C1 120.2(3) . .
N1 C7 C2 126.7(3) . .
N1 C7 H7 116.6 . .
C2 C7 H7 116.6 . .
N1 C8 C9 107.6(2) . .
N1 C8 H8A 110.2 . .
C9 C8 H8A 110.2 . .
N1 C8 H8B 110.2 . .
C9 C8 H8B 110.2 . .
H8A C8 H8B 108.5 . .
O2 C9 C8 106.3(2) . .
O2 C9 H9A 110.5 . .
C8 C9 H9A 110.5 . .
O2 C9 H9B 110.5 . .
C8 C9 H9B 110.5 . .
H9A C9 H9B 108.7 . .
C4 C10 H10A 109.5 . .
C4 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C4 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N2 C11 C6 125.7(3) . .
N2 C11 H11 117.1 . .
C6 C11 H11 117.1 . .
N2 C12 C13 111.8(3) . .
N2 C12 H12A 109.3 . .
C13 C12 H12A 109.3 . .
N2 C12 H12B 109.3 . .
C13 C12 H12B 109.3 . .
H12A C12 H12B 107.9 . .
O3 C13 C12 111.6(3) . .
O3 C13 H13A 109.3 . .
C12 C13 H13A 109.3 . .
O3 C13 H13B 109.3 . .
C12 C13 H13B 109.3 . .
H13A C13 H13B 108.0 . .
C19 C14 C15 119.2(3) . .
C19 C14 C20 120.0(3) . .
C15 C14 C20 120.8(3) . .
C16 C15 C14 120.3(3) . .
C16 C15 H15 119.9 . .
C14 C15 H15 119.9 . .
C15 C16 C17 120.3(3) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
C18 C17 C16 119.6(3) . .
C18 C17 H17 120.2 . .
C16 C17 H17 120.2 . .
C19 C18 C17 120.0(3) . .
C19 C18 H18 120.0 . .
C17 C18 H18 120.0 . .
C18 C19 C14 120.7(3) . .
C18 C19 H19 119.7 . .
C14 C19 H19 119.7 . .
O5 C20 O4 121.4(3) . .
O5 C20 C14 119.1(3) . .
O4 C20 C14 119.5(3) . .
O5 C20 Dy1 58.96(15) . .
O4 C20 Dy1 63.86(16) . .
C14 C20 Dy1 166.1(2) . .
C26 C21 C22 119.6(3) . .
C26 C21 C27 120.4(3) . .
C22 C21 C27 120.0(3) . .
C23 C22 C21 119.7(3) . .
C23 C22 H22 120.2 . .
C21 C22 H22 120.2 . .
C24 C23 C22 120.1(4) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C25 C24 C23 120.5(3) . .
C25 C24 H24 119.8 . .
C23 C24 H24 119.8 . .
C24 C25 C26 119.8(3) . .
C24 C25 H25 120.1 . .
C26 C25 H25 120.1 . .
C21 C26 C25 120.4(3) . .
C21 C26 H26 119.8 . .
C25 C26 H26 119.8 . .
O9 C27 O8 123.8(3) . .
O9 C27 C21 118.3(3) . .
O8 C27 C21 117.9(3) . .
C29 C28 C33 119.1(3) . .
C29 C28 C34 120.8(3) . .
C33 C28 C34 119.9(3) . .
C28 C29 C30 120.3(3) . .
C28 C29 H29 119.9 . .
C30 C29 H29 119.9 . .
C31 C30 C29 120.3(3) . .
C31 C30 H30 119.9 . .
C29 C30 H30 119.9 . .
C30 C31 C32 120.1(3) . .
C30 C31 H31 120.0 . .
C32 C31 H31 120.0 . .
C31 C32 C33 119.8(3) . .
C31 C32 H32 120.1 . .
C33 C32 H32 120.1 . .
C32 C33 C28 120.4(3) . .
C32 C33 H33 119.8 . .
C28 C33 H33 119.8 . .
O6 C34 O7 121.2(3) . .
O6 C34 C28 118.9(3) . .
O7 C34 C28 119.8(3) . .
O6 C34 Dy1 61.31(15) . .
O7 C34 Dy1 59.94(14) . .
C28 C34 Dy1 179.8(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.2817(19) .
Dy1 O8 2.314(2) .
Dy1 O9 2.367(2) 2_656
Dy1 O5 2.418(2) .
Dy1 O7 2.453(2) .
Dy1 O6 2.484(2) .
Dy1 N1 2.504(2) .
Dy1 O4 2.526(2) .
Dy1 O2 2.583(2) .
Dy1 C20 2.814(3) .
Dy1 C34 2.829(3) .
N1 C7 1.279(4) .
N1 C8 1.475(4) .
N2 C11 1.306(4) .
N2 C12 1.474(4) .
O1 C1 1.287(3) .
O1 H1 0.9500 .
O2 C9 1.424(4) .
O2 H2 0.9500 .
O3 C13 1.408(5) .
O3 H3 0.8400 .
O4 C20 1.265(4) .
O5 C20 1.263(4) .
O8 C27 1.263(3) .
O6 C34 1.256(4) .
O7 C34 1.269(4) .
O9 C27 1.257(4) .
O9 Dy1 2.367(2) 2_656
C1 C2 1.421(4) .
C1 C6 1.441(4) .
C2 C3 1.400(4) .
C2 C7 1.458(4) .
C3 C4 1.402(4) .
C3 H3A 0.9500 .
C4 C5 1.389(5) .
C4 C10 1.507(4) .
C5 C6 1.408(4) .
C5 H5 0.9500 .
C6 C11 1.413(4) .
C7 H7 0.9500 .
C8 C9 1.507(4) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11 0.9500 .
C12 C13 1.501(5) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C19 1.388(4) .
C14 C15 1.389(4) .
C14 C20 1.504(4) .
C15 C16 1.386(5) .
C15 H15 0.9500 .
C16 C17 1.389(5) .
C16 H16 0.9500 .
C17 C18 1.386(5) .
C17 H17 0.9500 .
C18 C19 1.385(5) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C21 C26 1.386(4) .
C21 C22 1.393(4) .
C21 C27 1.502(4) .
C22 C23 1.386(5) .
C22 H22 0.9500 .
C23 C24 1.383(6) .
C23 H23 0.9500 .
C24 C25 1.374(6) .
C24 H24 0.9500 .
C25 C26 1.386(5) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C28 C29 1.383(4) .
C28 C33 1.394(4) .
C28 C34 1.501(4) .
C29 C30 1.388(5) .
C29 H29 0.9500 .
C30 C31 1.376(6) .
C30 H30 0.9500 .
C31 C32 1.383(6) .
C31 H31 0.9500 .
C32 C33 1.387(5) .
C32 H32 0.9500 .
C33 H33 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O1 Dy1 N1 C7 -5.5(3) .
O8 Dy1 N1 C7 147.7(2) .
O9 Dy1 N1 C7 75.1(3) 2_656
O5 Dy1 N1 C7 -67.5(3) .
O7 Dy1 N1 C7 -138.6(3) .
O6 Dy1 N1 C7 -86.9(3) .
O4 Dy1 N1 C7 26.8(3) .
O2 Dy1 N1 C7 151.0(3) .
C20 Dy1 N1 C7 -16.3(4) .
C34 Dy1 N1 C7 -113.1(3) .
O1 Dy1 N1 C8 179.3(2) .
O8 Dy1 N1 C8 -27.6(2) .
O9 Dy1 N1 C8 -100.12(19) 2_656
O5 Dy1 N1 C8 117.3(2) .
O7 Dy1 N1 C8 46.17(19) .
O6 Dy1 N1 C8 97.88(19) .
O4 Dy1 N1 C8 -148.45(18) .
O2 Dy1 N1 C8 -24.20(18) .
C20 Dy1 N1 C8 168.43(19) .
C34 Dy1 N1 C8 71.66(19) .
O8 Dy1 O1 C1 -138.4(3) .
O9 Dy1 O1 C1 -73.6(3) 2_656
O5 Dy1 O1 C1 157.0(3) .
O7 Dy1 O1 C1 79.2(3) .
O6 Dy1 O1 C1 82.4(3) .
N1 Dy1 O1 C1 7.5(3) .
O4 Dy1 O1 C1 -151.6(3) .
O2 Dy1 O1 C1 -22.0(3) .
C20 Dy1 O1 C1 -177.0(3) .
C34 Dy1 O1 C1 81.6(3) .
O1 Dy1 O2 C9 21.6(2) .
O8 Dy1 O2 C9 167.74(19) .
O9 Dy1 O2 C9 75.02(18) 2_656
O5 Dy1 O2 C9 -156.98(17) .
O7 Dy1 O2 C9 -105.61(19) .
O6 Dy1 O2 C9 -68.32(19) .
N1 Dy1 O2 C9 -9.67(17) .
O4 Dy1 O2 C9 126.58(18) .
C20 Dy1 O2 C9 162.64(18) .
C34 Dy1 O2 C9 -87.35(18) .
O1 Dy1 O4 C20 -109.21(18) .
O8 Dy1 O4 C20 78.80(17) .
O9 Dy1 O4 C20 169.36(18) 2_656
O5 Dy1 O4 C20 -7.41(16) .
O7 Dy1 O4 C20 19.1(2) .
O6 Dy1 O4 C20 -45.15(19) .
N1 Dy1 O4 C20 -141.50(17) .
O2 Dy1 O4 C20 118.78(17) .
C34 Dy1 O4 C20 -15.6(2) .
O1 Dy1 O5 C20 76.83(17) .
O8 Dy1 O5 C20 -70.64(17) .
O9 Dy1 O5 C20 3.5(2) 2_656
O7 Dy1 O5 C20 -152.57(18) .
O6 Dy1 O5 C20 153.66(18) .
N1 Dy1 O5 C20 134.55(18) .
O4 Dy1 O5 C20 7.44(16) .
O2 Dy1 O5 C20 -104.22(18) .
C34 Dy1 O5 C20 -179.15(18) .
O1 Dy1 O8 C27 165.0(3) .
O9 Dy1 O8 C27 102.7(4) 2_656
O5 Dy1 O8 C27 -126.8(4) .
O7 Dy1 O8 C27 -43.3(4) .
O6 Dy1 O8 C27 -68.4(4) .
N1 Dy1 O8 C27 33.3(4) .
O4 Dy1 O8 C27 178.3(4) .
O2 Dy1 O8 C27 30.1(4) .
C20 Dy1 O8 C27 -153.6(4) .
C34 Dy1 O8 C27 -55.1(4) .
O1 Dy1 O6 C34 -178.30(18) .
O8 Dy1 O6 C34 30.2(2) .
O9 Dy1 O6 C34 -134.08(17) 2_656
O5 Dy1 O6 C34 89.37(18) .
O7 Dy1 O6 C34 -1.37(16) .
N1 Dy1 O6 C34 -102.03(18) .
O4 Dy1 O6 C34 119.78(17) .
O2 Dy1 O6 C34 -47.30(18) .
C20 Dy1 O6 C34 100.96(18) .
O1 Dy1 O7 C34 5.3(2) .
O8 Dy1 O7 C34 -153.77(18) .
O9 Dy1 O7 C34 136.59(17) 2_656
O5 Dy1 O7 C34 -75.96(17) .
O6 Dy1 O7 C34 1.36(16) .
N1 Dy1 O7 C34 70.69(17) .
O4 Dy1 O7 C34 -97.04(18) .
O2 Dy1 O7 C34 135.58(18) .
C20 Dy1 O7 C34 -88.29(18) .
Dy1 O1 C1 C2 -6.3(5) .
Dy1 O1 C1 C6 172.9(2) .
O1 C1 C2 C3 178.7(3) .
C6 C1 C2 C3 -0.5(4) .
O1 C1 C2 C7 -0.7(5) .
C6 C1 C2 C7 -179.9(3) .
C1 C2 C3 C4 1.6(5) .
C7 C2 C3 C4 -178.9(3) .
C2 C3 C4 C5 0.0(5) .
C2 C3 C4 C10 -179.8(3) .
C3 C4 C5 C6 -2.6(4) .
C10 C4 C5 C6 177.2(3) .
C4 C5 C6 C11 -172.9(3) .
C4 C5 C6 C1 3.7(4) .
O1 C1 C6 C5 178.7(3) .
C2 C1 C6 C5 -2.0(4) .
O1 C1 C6 C11 -4.8(4) .
C2 C1 C6 C11 174.5(3) .
C8 N1 C7 C2 178.3(3) .
Dy1 N1 C7 C2 3.2(5) .
C3 C2 C7 N1 -178.0(3) .
C1 C2 C7 N1 1.5(5) .
C7 N1 C8 C9 -120.9(3) .
Dy1 N1 C8 C9 55.1(3) .
Dy1 O2 C9 C8 40.1(3) .
N1 C8 C9 O2 -61.8(3) .
C12 N2 C11 C6 -175.2(3) .
C5 C6 C11 N2 171.3(3) .
C1 C6 C11 N2 -5.3(5) .
C11 N2 C12 C13 -85.7(4) .
N2 C12 C13 O3 64.9(4) .
C19 C14 C15 C16 0.7(5) .
C20 C14 C15 C16 179.0(3) .
C14 C15 C16 C17 -0.4(5) .
C15 C16 C17 C18 0.0(6) .
C16 C17 C18 C19 0.0(6) .
C17 C18 C19 C14 0.2(6) .
C15 C14 C19 C18 -0.6(5) .
C20 C14 C19 C18 -179.0(3) .
Dy1 O5 C20 O4 -14.0(3) .
Dy1 O5 C20 C14 164.0(2) .
Dy1 O4 C20 O5 13.3(3) .
Dy1 O4 C20 C14 -164.7(2) .
C19 C14 C20 O5 -7.9(4) .
C15 C14 C20 O5 173.7(3) .
C19 C14 C20 O4 170.1(3) .
C15 C14 C20 O4 -8.2(4) .
C19 C14 C20 Dy1 70.0(9) .
C15 C14 C20 Dy1 -108.4(8) .
O1 Dy1 C20 O5 -101.29(17) .
O8 Dy1 C20 O5 101.40(18) .
O9 Dy1 C20 O5 -177.20(16) 2_656
O7 Dy1 C20 O5 28.15(18) .
O6 Dy1 C20 O5 -25.67(18) .
N1 Dy1 C20 O5 -90.8(3) .
O4 Dy1 C20 O5 -166.7(3) .
O2 Dy1 C20 O5 106.47(18) .
C34 Dy1 C20 O5 0.85(18) .
O1 Dy1 C20 O4 65.42(17) .
O8 Dy1 C20 O4 -91.89(17) .
O9 Dy1 C20 O4 -10.49(18) 2_656
O5 Dy1 C20 O4 166.7(3) .
O7 Dy1 C20 O4 -165.13(16) .
O6 Dy1 C20 O4 141.04(17) .
N1 Dy1 C20 O4 75.9(3) .
O2 Dy1 C20 O4 -86.82(19) .
C34 Dy1 C20 O4 167.56(17) .
O1 Dy1 C20 C14 172.8(9) .
O8 Dy1 C20 C14 15.5(8) .
O9 Dy1 C20 C14 96.9(9) 2_656
O5 Dy1 C20 C14 -85.9(9) .
O7 Dy1 C20 C14 -57.8(9) .
O6 Dy1 C20 C14 -111.6(9) .
N1 Dy1 C20 C14 -176.7(8) .
O4 Dy1 C20 C14 107.4(9) .
O2 Dy1 C20 C14 20.6(9) .
C34 Dy1 C20 C14 -85.1(9) .
C26 C21 C22 C23 1.0(6) .
C27 C21 C22 C23 -179.1(4) .
C21 C22 C23 C24 -0.6(7) .
C22 C23 C24 C25 0.3(8) .
C23 C24 C25 C26 -0.6(7) .
C22 C21 C26 C25 -1.2(5) .
C27 C21 C26 C25 178.9(3) .
C24 C25 C26 C21 1.0(6) .
Dy1 O9 C27 O8 -30.6(5) 2_656
Dy1 O9 C27 C21 147.8(2) 2_656
Dy1 O8 C27 O9 -83.4(4) .
Dy1 O8 C27 C21 98.3(4) .
C26 C21 C27 O9 -5.2(4) .
C22 C21 C27 O9 175.0(3) .
C26 C21 C27 O8 173.2(3) .
C22 C21 C27 O8 -6.6(4) .
C33 C28 C29 C30 -2.1(5) .
C34 C28 C29 C30 173.9(3) .
C28 C29 C30 C31 0.5(6) .
C29 C30 C31 C32 1.7(6) .
C30 C31 C32 C33 -2.3(6) .
C31 C32 C33 C28 0.7(6) .
C29 C28 C33 C32 1.5(5) .
C34 C28 C33 C32 -174.6(3) .
Dy1 O6 C34 O7 2.5(3) .
Dy1 O6 C34 C28 179.9(2) .
Dy1 O7 C34 O6 -2.5(3) .
Dy1 O7 C34 C28 -179.9(2) .
C29 C28 C34 O6 -175.7(3) .
C33 C28 C34 O6 0.3(4) .
C29 C28 C34 O7 1.8(4) .
C33 C28 C34 O7 177.8(3) .
C29 C28 C34 Dy1 -10(64) .
C33 C28 C34 Dy1 166(100) .
O1 Dy1 C34 O6 1.70(18) .
O8 Dy1 C34 O6 -155.75(17) .
O9 Dy1 C34 O6 91.3(2) 2_656
O5 Dy1 C34 O6 -83.67(17) .
O7 Dy1 C34 O6 177.6(3) .
N1 Dy1 C34 O6 71.30(18) .
O4 Dy1 C34 O6 -76.94(19) .
O2 Dy1 C34 O6 136.09(17) .
C20 Dy1 C34 O6 -84.06(18) .
O1 Dy1 C34 O7 -175.85(16) .
O8 Dy1 C34 O7 26.70(18) .
O9 Dy1 C34 O7 -86.3(2) 2_656
O5 Dy1 C34 O7 98.77(18) .
O6 Dy1 C34 O7 -177.6(3) .
N1 Dy1 C34 O7 -106.25(18) .
O4 Dy1 C34 O7 105.51(17) .
O2 Dy1 C34 O7 -41.47(17) .
C20 Dy1 C34 O7 98.38(17) .
O1 Dy1 C34 C28 -164(100) .
O8 Dy1 C34 C28 39(64) .
O9 Dy1 C34 C28 -74(64) 2_656
O5 Dy1 C34 C28 111(64) .
O7 Dy1 C34 C28 12(64) .
O6 Dy1 C34 C28 -165(100) .
N1 Dy1 C34 C28 -94(64) .
O4 Dy1 C34 C28 118(64) .
O2 Dy1 C34 C28 -29(64) .
C20 Dy1 C34 C28 111(64) .
