#------------------------------------------------------------------------------
#$Date: 2017-02-04 15:41:22 +0200 (Sat, 04 Feb 2017) $
#$Revision: 191548 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/72/7227203.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227203
loop_
_publ_author_name
'Wang, Jin'
'Liang, Yanfen'
'Ma, Pengtao'
'Zhang, Dongdi'
'Niu, Jingyang'
'Wang, Jingping'
_publ_section_title
;
 Ligand-controlled formation of covalently modified antimoniomolybdates
 and their photochromic properties
;
_journal_issue                   2
_journal_name_full               CrystEngComm
_journal_page_first              207
_journal_paper_doi               10.1039/C6CE02343F
_journal_volume                  19
_journal_year                    2017
_chemical_formula_sum            'C30 H96 Mo12 N12 O62 Sb2'
_chemical_formula_weight         3011.93
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-01-30 deposited with the CCDC.
2016-11-30 downloaded from the CCDC.
;
_cell_angle_alpha                105.8550(10)
_cell_angle_beta                 103.0330(10)
_cell_angle_gamma                103.1530(10)
_cell_formula_units_Z            1
_cell_length_a                   11.2428(7)
_cell_length_b                   13.9571(9)
_cell_length_c                   19.4780(13)
_cell_measurement_reflns_used    4515
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.11
_cell_measurement_theta_min      2.28
_cell_volume                     2724.7(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0218
_diffrn_reflns_av_sigmaI/netI    0.0462
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            14094
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.94
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.905
_exptl_absorpt_correction_T_max  0.7764
_exptl_absorpt_correction_T_min  0.6176
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.834
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1460
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.544
_refine_diff_density_min         -0.844
_refine_diff_density_rms         0.185
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     442
_refine_ls_number_reflns         9506
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.0777
_refine_ls_R_factor_gt           0.0562
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1138P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1660
_refine_ls_wR_factor_ref         0.1804
_reflns_number_gt                7118
_reflns_number_total             9506
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce02343f2.cif
_cod_data_source_block           njy1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7227202--7227205.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7227203
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.52778(5) 0.17395(4) 0.25653(3) 0.03264(17) Uani 1 1 d . . .
Mo1 Mo 0.26216(7) 0.09906(7) 0.08429(4) 0.0416(2) Uani 1 1 d . . .
Mo2 Mo 0.25104(7) -0.05809(6) 0.18152(4) 0.0406(2) Uani 1 1 d . . .
Mo3 Mo 0.53955(7) -0.05137(6) 0.31318(4) 0.0398(2) Uani 1 1 d . . .
Mo4 Mo 0.81549(7) 0.11552(6) 0.33785(4) 0.0386(2) Uani 1 1 d . . .
Mo5 Mo 0.82958(7) 0.28797(6) 0.22920(4) 0.0405(2) Uani 1 1 d . . .
Mo6 Mo 0.57076(8) 0.27675(7) 0.10750(4) 0.0463(2) Uani 1 1 d . . .
O1 O 0.2974(6) 0.0246(5) 0.0109(3) 0.0538(17) Uani 1 1 d . . .
O2 O 0.1371(6) 0.1365(6) 0.0407(4) 0.0613(19) Uani 1 1 d . . .
O3 O 0.1570(5) -0.0172(5) 0.1037(3) 0.0438(14) Uani 1 1 d . . .
O4 O 0.2287(6) 0.1953(5) 0.1916(3) 0.0497(16) Uani 1 1 d . A .
O5 O 0.4010(6) 0.2236(5) 0.1142(3) 0.0484(15) Uani 1 1 d . . .
O6 O 0.3890(5) 0.0664(4) 0.1703(3) 0.0362(13) Uani 1 1 d . . .
O7 O 0.1189(6) -0.1272(6) 0.1972(4) 0.065(2) Uani 1 1 d . . .
O8 O 0.2931(6) -0.1530(5) 0.1254(4) 0.0586(18) Uani 1 1 d . . .
O9 O 0.3776(5) -0.0259(4) 0.2748(3) 0.0412(13) Uani 1 1 d . . .
O10 O 0.2193(6) 0.0884(5) 0.2570(3) 0.0513(16) Uani 1 1 d . A .
O11 O 0.5332(7) -0.1473(5) 0.2358(4) 0.0611(18) Uani 1 1 d . . .
O12 O 0.4935(7) -0.1178(6) 0.3692(4) 0.067(2) Uani 1 1 d . . .
O13 O 0.7228(5) -0.0039(5) 0.3631(3) 0.0427(14) Uani 1 1 d . . .
O14 O 0.5528(6) 0.0929(5) 0.4105(3) 0.0467(15) Uani 1 1 d . . .
O15 O 0.6156(5) 0.0731(4) 0.2742(3) 0.0341(12) Uani 1 1 d . . .
O16 O 0.8581(7) 0.0442(6) 0.2665(4) 0.0578(18) Uani 1 1 d . . .
O17 O 0.9499(6) 0.1592(6) 0.4140(4) 0.0623(19) Uani 1 1 d . . .
O18 O 0.8260(5) 0.2406(5) 0.3120(3) 0.0413(14) Uani 1 1 d . . .
O19 O 0.7360(5) 0.2090(5) 0.4244(3) 0.0468(15) Uani 1 1 d . . .
O20 O 0.8660(6) 0.1883(5) 0.1742(4) 0.0532(16) Uani 1 1 d . . .
O21 O 0.9714(6) 0.3888(5) 0.2672(4) 0.0621(18) Uani 1 1 d . . .
O22 O 0.7551(6) 0.3384(5) 0.1501(3) 0.0485(15) Uani 1 1 d . . .
O23 O 0.6277(5) 0.2088(4) 0.1912(3) 0.0360(12) Uani 1 1 d . . .
O24 O 0.7527(6) 0.4069(5) 0.2979(3) 0.0569(17) Uani 1 1 d . . .
O25 O 0.5696(7) 0.1737(6) 0.0368(3) 0.0633(19) Uani 1 1 d . . .
O26 O 0.5448(8) 0.3659(6) 0.0649(5) 0.077(2) Uani 1 1 d . . .
O27 O 0.5781(6) 0.4031(5) 0.2156(4) 0.0567(17) Uani 1 1 d . . .
C1 C 0.2161(8) 0.1732(6) 0.2490(4) 0.0403(19) Uiso 1 1 d D . .
C2A C 0.182(2) 0.2376(17) 0.3125(10) 0.053(7) Uiso 0.50 1 d PD A 1
H2A H 0.2036 0.2165 0.3561 0.064 Uiso 0.50 1 calc PR A 1
H2B H 0.0918 0.2310 0.2982 0.064 Uiso 0.50 1 calc PR A 1
C2B C 0.206(2) 0.2635(14) 0.3083(9) 0.039(5) Uiso 0.50 1 d PD A 2
H2C H 0.2482 0.3285 0.3026 0.047 Uiso 0.50 1 calc PR A 2
H2D H 0.1166 0.2583 0.3013 0.047 Uiso 0.50 1 calc PR A 2
C3 C 0.274(2) 0.3631(17) 0.3304(13) 0.111(7) Uiso 0.75 1 d P A 1
H3A H 0.3638 0.3662 0.3401 0.133 Uiso 0.75 1 calc PR A 1
H3B H 0.2495 0.3830 0.2866 0.133 Uiso 0.75 1 calc PR A 1
C4 C 0.259(2) 0.4400(18) 0.3972(14) 0.121(7) Uiso 0.75 1 d P A 1
H4A H 0.1696 0.4384 0.3863 0.146 Uiso 0.75 1 calc PR A 1
H4B H 0.2792 0.4174 0.4401 0.146 Uiso 0.75 1 calc PR A 1
C5 C 0.340(2) 0.5490(18) 0.4174(14) 0.123 Uiso 0.75 1 d P A 1
H5A H 0.3279 0.5689 0.3729 0.148 Uiso 0.75 1 calc PR A 1
H5B H 0.4297 0.5525 0.4347 0.148 Uiso 0.75 1 calc PR A 1
C6 C 0.310(2) 0.6289(17) 0.4798(13) 0.113(7) Uiso 0.75 1 d P A 1
H6A H 0.2196 0.6219 0.4640 0.135 Uiso 0.75 1 calc PR A 1
H6B H 0.3289 0.6122 0.5254 0.135 Uiso 0.75 1 calc PR A 1
C7 C 0.2673(19) 0.2665(15) 0.3871(10) 0.095(6) Uiso 0.75 1 d PD A 2
H7A H 0.2334 0.1983 0.3908 0.114 Uiso 0.75 1 calc PR A 2
H7B H 0.3592 0.2808 0.3964 0.114 Uiso 0.75 1 calc PR A 2
C8 C 0.243(2) 0.3479(16) 0.4458(10) 0.116(7) Uiso 0.75 1 d PD A 2
H8A H 0.2668 0.4143 0.4377 0.140 Uiso 0.75 1 calc PR A 2
H8B H 0.1519 0.3286 0.4400 0.140 Uiso 0.75 1 calc PR A 2
C9 C 0.315(2) 0.3618(19) 0.5241(11) 0.125(8) Uiso 0.75 1 d PD A 2
H9A H 0.2888 0.2971 0.5341 0.150 Uiso 0.75 1 calc PR A 2
H9B H 0.4065 0.3797 0.5306 0.150 Uiso 0.75 1 calc PR A 2
C10 C 0.288(2) 0.4458(18) 0.5763(13) 0.116(7) Uiso 0.75 1 d P A 2
H10A H 0.1965 0.4261 0.5697 0.139 Uiso 0.75 1 calc PR A 2
H10B H 0.3104 0.5089 0.5638 0.139 Uiso 0.75 1 calc PR A 2
C11 C 0.3882(11) 0.7424(9) 0.4963(7) 0.069(3) Uiso 1 1 d . . .
H11A H 0.4788 0.7487 0.5096 0.082 Uiso 1 1 calc R A 1
H11B H 0.3663 0.7604 0.4514 0.082 Uiso 1 1 calc R A 1
C12 C 0.3636(8) 0.8186(7) 0.5594(5) 0.0396(19) Uiso 1 1 d . . .
C13 C 0.3644(15) 0.4716(12) 0.6633(9) 0.103(5) Uiso 1 1 d . . .
H13A H 0.3411 0.4082 0.6753 0.124 Uiso 1 1 calc R A 2
H13B H 0.4555 0.4897 0.6691 0.124 Uiso 1 1 calc R A 2
C14 C 0.3417(10) 0.5608(8) 0.7220(6) 0.055(2) Uiso 1 1 d . . .
C15 C 0.6931(11) 1.0028(9) 0.5467(7) 0.066(3) Uiso 1 1 d . . .
H15A H 0.6123 1.0104 0.5311 0.079 Uiso 1 1 calc R . .
C16 C 0.8525(15) 0.9758(12) 0.6133(10) 0.104(5) Uiso 1 1 d . . .
H16A H 0.9098 0.9697 0.6533 0.125 Uiso 1 1 calc R . .
C17 C 0.8608(16) 0.9656(12) 0.5415(10) 0.108(5) Uiso 1 1 d . . .
H17A H 0.9205 0.9412 0.5217 0.129 Uiso 1 1 calc R . .
N1 N 0.7387(8) 0.9970(7) 0.6102(5) 0.063(2) Uiso 1 1 d . . .
H1A H 0.7042 1.0051 0.6457 0.075 Uiso 1 1 calc R . .
N2 N 0.7671(9) 0.9971(7) 0.5052(6) 0.068(2) Uiso 1 1 d . . .
H2E H 0.7592 1.0103 0.4640 0.082 Uiso 1 1 calc R . .
N3 N 0.4254(8) 0.0183(7) 0.8924(5) 0.059(2) Uiso 1 1 d . . .
N4 N 0.9225(8) 0.9891(7) 0.1264(5) 0.061(2) Uiso 1 1 d . . .
N5 N 0.8784(14) 0.2061(12) 0.0287(9) 0.048(4) Uiso 0.50 1 d P . .
N6 N 0.8076(19) 0.8149(15) 0.3234(11) 0.072(5) Uiso 0.50 1 d P . .
N7 N 0.295(2) 0.1913(18) 0.9043(14) 0.092(7) Uiso 0.50 1 d P . .
N8 N 0.968(2) 0.491(2) 0.4429(13) 0.083(6) Uiso 0.50 1 d P . .
O1W O 0.9509(14) 0.4224(12) 0.4474(9) 0.060(4) Uiso 0.50 1 d P . .
O2W O 0.411(2) 0.6783(18) 0.0871(14) 0.123(7) Uiso 0.50 1 d P . .
O3W O 0.1164(19) 0.3378(16) 0.1535(12) 0.101(6) Uiso 0.50 1 d P . .
O4W O 0.015(2) 0.2328(19) 0.5768(14) 0.126(8) Uiso 0.50 1 d P . .
O5W O 0.223(3) -0.253(2) 0.2897(16) 0.145(9) Uiso 0.50 1 d P . .
O6W O -0.025(2) 0.384(2) 0.6854(15) 0.135(8) Uiso 0.50 1 d P . .
O7W O 0.955(2) 0.4228(19) 0.4989(16) 0.116(7) Uiso 0.50 1 d P . .
O8W O 0.339(3) 0.451(2) 0.1601(18) 0.173(11) Uiso 0.50 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O15 Sb1 O23 91.5(2) . .
O15 Sb1 O6 92.6(2) . .
O23 Sb1 O6 91.6(2) . .
O1 Mo1 O2 103.3(3) . .
O1 Mo1 O5 99.1(3) . .
O2 Mo1 O5 100.6(3) . .
O1 Mo1 O3 96.8(3) . .
O2 Mo1 O3 97.1(3) . .
O5 Mo1 O3 152.6(2) . .
O1 Mo1 O6 95.7(3) . .
O2 Mo1 O6 159.8(3) . .
O5 Mo1 O6 82.9(2) . .
O3 Mo1 O6 73.5(2) . .
O1 Mo1 O4 174.3(3) . .
O2 Mo1 O4 82.3(3) . .
O5 Mo1 O4 80.2(3) . .
O3 Mo1 O4 81.7(2) . .
O6 Mo1 O4 78.6(2) . .
O8 Mo2 O7 103.4(3) . .
O8 Mo2 O9 100.3(3) . .
O7 Mo2 O9 100.2(3) . .
O8 Mo2 O3 98.0(3) . .
O7 Mo2 O3 96.3(3) . .
O9 Mo2 O3 151.8(2) . .
O8 Mo2 O6 93.2(3) . .
O7 Mo2 O6 162.0(3) . .
O9 Mo2 O6 83.4(2) . .
O3 Mo2 O6 74.2(2) . .
O8 Mo2 O10 171.7(3) . .
O7 Mo2 O10 84.9(3) . .
O9 Mo2 O10 77.8(2) . .
O3 Mo2 O10 81.1(2) . .
O6 Mo2 O10 78.6(2) . .
O11 Mo3 O12 103.6(4) . .
O11 Mo3 O13 99.0(3) . .
O12 Mo3 O13 97.9(3) . .
O11 Mo3 O9 99.1(3) . .
O12 Mo3 O9 98.3(3) . .
O13 Mo3 O9 152.0(2) . .
O11 Mo3 O15 93.7(3) . .
O12 Mo3 O15 162.2(3) . .
O13 Mo3 O15 75.1(2) . .
O9 Mo3 O15 82.6(2) . .
O11 Mo3 O14 173.1(3) . .
O12 Mo3 O14 83.3(3) . .
O13 Mo3 O14 80.7(2) . .
O9 Mo3 O14 78.8(2) . .
O15 Mo3 O14 79.5(2) . .
O16 Mo4 O17 104.2(3) . .
O16 Mo4 O18 99.2(3) . .
O17 Mo4 O18 100.7(3) . .
O16 Mo4 O13 97.7(3) . .
O17 Mo4 O13 96.2(3) . .
O18 Mo4 O13 152.3(2) . .
O16 Mo4 O15 95.3(3) . .
O17 Mo4 O15 159.2(3) . .
O18 Mo4 O15 82.8(2) . .
O13 Mo4 O15 73.9(2) . .
O16 Mo4 O19 173.5(3) . .
O17 Mo4 O19 82.2(3) . .
O18 Mo4 O19 78.8(2) . .
O13 Mo4 O19 82.0(2) . .
O15 Mo4 O19 78.3(2) . .
O20 Mo5 O21 104.2(3) . .
O20 Mo5 O18 99.1(3) . .
O21 Mo5 O18 100.7(3) . .
O20 Mo5 O22 97.6(3) . .
O21 Mo5 O22 95.6(3) . .
O18 Mo5 O22 153.0(2) . .
O20 Mo5 O23 94.7(3) . .
O21 Mo5 O23 159.6(3) . .
O18 Mo5 O23 83.7(2) . .
O22 Mo5 O23 73.9(2) . .
O20 Mo5 O24 172.2(3) . .
O21 Mo5 O24 83.6(3) . .
O18 Mo5 O24 79.3(2) . .
O22 Mo5 O24 81.3(3) . .
O23 Mo5 O24 77.5(2) . .
O25 Mo6 O26 103.7(4) . .
O25 Mo6 O5 99.4(3) . .
O26 Mo6 O5 99.5(3) . .
O25 Mo6 O22 97.5(3) . .
O26 Mo6 O22 96.9(3) . .
O5 Mo6 O22 152.9(2) . .
O25 Mo6 O23 93.1(3) . .
O26 Mo6 O23 162.0(3) . .
O5 Mo6 O23 84.0(2) . .
O22 Mo6 O23 74.2(2) . .
O25 Mo6 O27 171.4(3) . .
O26 Mo6 O27 84.9(3) . .
O5 Mo6 O27 79.0(3) . .
O22 Mo6 O27 81.1(2) . .
O23 Mo6 O27 78.4(2) . .
Mo2 O3 Mo1 113.7(3) . .
C1 O4 Mo1 130.9(5) . .
Mo1 O5 Mo6 142.6(4) . .
Sb1 O6 Mo2 122.8(3) . .
Sb1 O6 Mo1 124.6(3) . .
Mo2 O6 Mo1 98.5(2) . .
Mo2 O9 Mo3 139.2(3) . .
C1 O10 Mo2 131.9(5) . .
Mo3 O13 Mo4 112.5(3) . .
C12 O14 Mo3 130.5(5) 2_666 .
Sb1 O15 Mo3 123.5(2) . .
Sb1 O15 Mo4 124.1(3) . .
Mo3 O15 Mo4 98.4(2) . .
Mo5 O18 Mo4 140.6(3) . .
C12 O19 Mo4 130.0(6) 2_666 .
Mo6 O22 Mo5 113.2(3) . .
Sb1 O23 Mo5 124.2(3) . .
Sb1 O23 Mo6 125.0(3) . .
Mo5 O23 Mo6 98.8(2) . .
C14 O24 Mo5 130.6(6) 2_666 .
C14 O27 Mo6 129.8(7) 2_666 .
O10 C1 O4 123.5(7) . .
O10 C1 C2A 109.7(12) . .
O4 C1 C2A 126.5(12) . .
O10 C1 C2B 123.9(11) . .
O4 C1 C2B 112.5(11) . .
C2A C1 C2B 16.8(12) . .
C1 C2A C3 103.9(15) . .
C1 C2A H2A 111.0 . .
C3 C2A H2A 111.0 . .
C1 C2A H2B 111.0 . .
C3 C2A H2B 111.0 . .
H2A C2A H2B 109.0 . .
C7 C2B C1 112.5(14) . .
C7 C2B H2C 109.1 . .
C1 C2B H2C 109.1 . .
C7 C2B H2D 109.1 . .
C1 C2B H2D 109.1 . .
H2C C2B H2D 107.8 . .
C4 C3 C2A 111.5(16) . .
C4 C3 H3A 109.3 . .
C2A C3 H3A 109.3 . .
C4 C3 H3B 109.3 . .
C2A C3 H3B 109.3 . .
H3A C3 H3B 108.0 . .
C5 C4 C3 114(2) . .
C5 C4 H4A 108.8 . .
C3 C4 H4A 108.8 . .
C5 C4 H4B 108.8 . .
C3 C4 H4B 108.8 . .
H4A C4 H4B 107.7 . .
C4 C5 C6 113(2) . .
C4 C5 H5A 109.0 . .
C6 C5 H5A 109.0 . .
C4 C5 H5B 109.0 . .
C6 C5 H5B 109.0 . .
H5A C5 H5B 107.8 . .
C11 C6 C5 112.7(17) . .
C11 C6 H6A 109.1 . .
C5 C6 H6A 109.1 . .
C11 C6 H6B 109.1 . .
C5 C6 H6B 109.1 . .
H6A C6 H6B 107.8 . .
C8 C7 C2B 112.5(15) . .
C8 C7 H7A 109.1 . .
C2B C7 H7A 109.1 . .
C8 C7 H7B 109.1 . .
C2B C7 H7B 109.1 . .
H7A C7 H7B 107.8 . .
C9 C8 C7 113.7(18) . .
C9 C8 H8A 108.8 . .
C7 C8 H8A 108.8 . .
C9 C8 H8B 108.8 . .
C7 C8 H8B 108.8 . .
H8A C8 H8B 107.7 . .
C10 C9 C8 108.8(18) . .
C10 C9 H9A 109.9 . .
C8 C9 H9A 109.9 . .
C10 C9 H9B 109.9 . .
C8 C9 H9B 109.9 . .
H9A C9 H9B 108.3 . .
C9 C10 C13 113.8(17) . .
C9 C10 H10A 108.8 . .
C13 C10 H10A 108.8 . .
C9 C10 H10B 108.8 . .
C13 C10 H10B 108.8 . .
H10A C10 H10B 107.7 . .
C12 C11 C6 112.3(12) . .
C12 C11 H11A 109.1 . .
C6 C11 H11A 109.1 . .
C12 C11 H11B 109.1 . .
C6 C11 H11B 109.1 . .
H11A C11 H11B 107.9 . .
O19 C12 O14 125.7(8) 2_666 2_666
O19 C12 C11 118.8(8) 2_666 .
O14 C12 C11 115.4(8) 2_666 .
C14 C13 C10 116.7(13) . .
C14 C13 H13A 108.1 . .
C10 C13 H13A 108.1 . .
C14 C13 H13B 108.1 . .
C10 C13 H13B 108.1 . .
H13A C13 H13B 107.3 . .
O27 C14 O24 125.3(10) 2_666 2_666
O27 C14 C13 115.6(10) 2_666 .
O24 C14 C13 119.1(10) 2_666 .
N1 C15 N2 114.5(11) . .
N1 C15 H15A 122.7 . .
N2 C15 H15A 122.7 . .
N1 C16 C17 102.6(14) . .
N1 C16 H16A 128.7 . .
C17 C16 H16A 128.7 . .
N2 C17 C16 108.7(15) . .
N2 C17 H17A 125.6 . .
C16 C17 H17A 125.6 . .
C15 N1 C16 108.7(12) . .
C15 N1 H1A 125.7 . .
C16 N1 H1A 125.7 . .
C15 N2 C17 103.9(11) . .
C15 N2 H2E 128.1 . .
C17 N2 H2E 128.1 . .
O1W N8 O7W 121(2) . 2_766
O1W N8 O7W 33.5(15) . .
O7W N8 O7W 91.2(19) 2_766 .
N8 O1W O7W 114(2) . .
O1W O7W N8 118(2) . 2_766
O1W O7W N8 32.4(13) . .
N8 O7W N8 88.8(19) 2_766 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 O15 1.954(5) .
Sb1 O23 1.963(5) .
Sb1 O6 1.971(5) .
Mo1 O1 1.707(6) .
Mo1 O2 1.735(6) .
Mo1 O5 1.897(6) .
Mo1 O3 1.959(6) .
Mo1 O6 2.164(5) .
Mo1 O4 2.316(6) .
Mo2 O8 1.703(7) .
Mo2 O7 1.716(6) .
Mo2 O9 1.904(6) .
Mo2 O3 1.941(6) .
Mo2 O6 2.146(5) .
Mo2 O10 2.323(6) .
Mo3 O11 1.695(6) .
Mo3 O12 1.705(7) .
Mo3 O13 1.937(6) .
Mo3 O9 1.956(6) .
Mo3 O15 2.159(5) .
Mo3 O14 2.306(6) .
Mo4 O16 1.707(6) .
Mo4 O17 1.712(6) .
Mo4 O18 1.931(6) .
Mo4 O13 1.998(6) .
Mo4 O15 2.163(5) .
Mo4 O19 2.312(5) .
Mo5 O20 1.701(6) .
Mo5 O21 1.717(6) .
Mo5 O18 1.907(6) .
Mo5 O22 1.962(6) .
Mo5 O23 2.138(5) .
Mo5 O24 2.291(6) .
Mo6 O25 1.693(7) .
Mo6 O26 1.715(7) .
Mo6 O5 1.932(6) .
Mo6 O22 1.936(6) .
Mo6 O23 2.149(5) .
Mo6 O27 2.320(7) .
O4 C1 1.268(10) .
O10 C1 1.243(10) .
O14 C12 1.258(10) 2_666
O19 C12 1.238(10) 2_666
O24 C14 1.268(11) 2_666
O27 C14 1.228(12) 2_666
C1 C2A 1.496(9) .
C1 C2B 1.503(9) .
C2A C3 1.71(3) .
C2A H2A 0.9700 .
C2A H2B 0.9700 .
C2B C7 1.52(3) .
C2B H2C 0.9700 .
C2B H2D 0.9700 .
C3 C4 1.52(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.48(3) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 C6 1.57(3) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C11 1.53(2) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 C8 1.498(10) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C9 1.493(10) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 C10 1.47(3) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C13 1.62(3) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.513(14) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 O19 1.238(10) 2_666
C12 O14 1.258(10) 2_666
C13 C14 1.555(18) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 O27 1.228(12) 2_666
C14 O24 1.268(11) 2_666
C15 N1 1.259(13) .
C15 N2 1.285(13) .
C15 H15A 0.9300 .
C16 N1 1.369(16) .
C16 C17 1.39(2) .
C16 H16A 0.9300 .
C17 N2 1.361(17) .
C17 H17A 0.9300 .
N1 H1A 0.8600 .
N2 H2E 0.8600 .
N8 O1W 0.96(2) .
N8 O7W 1.35(3) 2_766
N8 O7W 1.64(3) .
O1W O7W 0.99(2) .
O7W N8 1.35(3) 2_766
